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We report on the synthesis of a new metal-organic framework (MOF) composed of Sn(OCH3)2-tetra­kis­(pyridin-4-yl)porphyrin linkers, Cu+ connecting nodes and [CuCl2]- counter-ions, namely poly[[bis­(methano­lato-[kappa]O)[[mu]5-5,10,15,20-tetra­kis­(pyridin-4-yl)porphyrin-[kappa]81[kappa]N5:1'[kappa]N10:1''[kappa]N15:1'''[kappa]N20:2[kappa]4N21,N22,N23,N24]copper(I)tin(II)] di­chlorido­cuprate(I)], [CuSn(C40H24N8)(CH3O)2][CuCl2]. Its crystal structure consists of a single-framework coordination polymer of the organic ligand and the CuI ions. The latter are characterized by a tetra­hedral coordination geometry [with CN (coordination number) = 4], linking to the pyridyl N-atom sites of four different ligands and imparting to the positively charged polymeric assembly a diamondoid PtS-type topology. Correspondingly, every porphyrin unit is coordinated to four different CuI connectors. The [CuCl2]- anions occupy the intra-lattice voids, along with disordered mol­ecules of the water crystallization solvent. The asymmetric unit of this structure consists of two halves of the porphyrin scaffold, located on centres of crystallographic inversion, and the Cu+ and [CuCl2]- ions. This report provides unique structural evidence for the formation of tetra­pyridyl­porphyrin-based three-dimensional MOFs with a diamondoid architecture that have been observed earlier only on rare occasions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229615013327/yo3011sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2053229615013327/yo3011Isup2.hkl
Contains datablock I

CCDC reference: 1412136

Computing details top

Data collection: Apex2, Bruker-AXS (Bruker, 2008); cell refinement: Saint, Bruker-AXS (Bruker, 2008); data reduction: Saint, Bruker-AXS (Bruker, 2008); program(s) used to solve structure: SHELXTL2014 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014/7 (Sheldrick, 2015b); molecular graphics: Mercury, Crystal Structure Visualization Software (Macrae et al., 2006); software used to prepare material for publication: SHELXL2014/7 (Sheldrick, 2015b).

Poly[]bis(methanolato-κO)[µ5-5,10,15,20-tetrakis(pyridin-4-yl)porphyrin-κ81κN5:1'κN10:1''κN15:1'''κN20:2κ4N21,N22,N23,N24]copper(I)tin(II)] dichloridocuprate(I)], top
Crystal data top
[CuSn(C40H24N8)(CH3O)2][CuCl2]F(000) = 1984
Mr = 995.41Dx = 1.585 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 10.3340 (2) ÅCell parameters from 6950 reflections
b = 15.9714 (4) Åθ = 2.1–26.4°
c = 25.3074 (7) ŵ = 1.78 mm1
β = 93.277 (1)°T = 110 K
V = 4170.12 (18) Å3Plate, red
Z = 40.15 × 0.15 × 0.10 mm
Data collection top
ApexDuo, Bruker-AXS
diffractometer
8510 independent reflections
Radiation source: ImuS micro-focus6906 reflections with I > 2σ(I)
Detector resolution: 1.75 pixels mm-1Rint = 0.034
1 deg. φ and ω scansθmax = 26.4°, θmin = 2.1°
Absorption correction: multi-scan
Sadabs, Bruker-AXS (Bruker, 2001)
h = 1212
Tmin = 0.776, Tmax = 0.842k = 1919
35433 measured reflectionsl = 2231
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.050Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.135H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0567P)2 + 27.5733P]
where P = (Fo2 + 2Fc2)/3
8510 reflections(Δ/σ)max = 0.001
519 parametersΔρmax = 3.04 e Å3
0 restraintsΔρmin = 2.05 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.00000.00000.00000.01109 (11)
Sn21.50000.50000.00000.01409 (12)
Cu10.76038 (5)0.21429 (4)0.16676 (2)0.01493 (14)
O10.0967 (3)0.1038 (2)0.02501 (15)0.0219 (8)
C20.1309 (7)0.1677 (4)0.0074 (3)0.0423 (17)
H2A0.19330.14700.03210.063*
H2B0.17030.21310.01400.063*
H2C0.05350.18870.02740.063*
N30.0688 (4)0.0097 (2)0.07638 (16)0.0140 (8)
N40.1649 (4)0.0710 (2)0.02472 (16)0.0137 (8)
C50.0101 (5)0.0534 (3)0.11793 (19)0.0154 (10)
C60.0895 (5)0.0449 (3)0.1626 (2)0.0224 (11)
H60.07200.06830.19680.027*
C70.1937 (5)0.0025 (3)0.1472 (2)0.0224 (11)
H70.26220.01830.16860.027*
C80.1817 (4)0.0248 (3)0.09234 (19)0.0152 (10)
C90.2706 (4)0.0718 (3)0.06015 (19)0.0138 (9)
C100.2613 (4)0.0938 (3)0.00687 (19)0.0138 (9)
C110.3497 (5)0.1477 (3)0.0242 (2)0.0180 (10)
H110.42630.17280.01230.022*
C120.3042 (5)0.1559 (3)0.0724 (2)0.0174 (10)
H120.34260.18780.10090.021*
C130.1865 (4)0.1075 (3)0.07346 (19)0.0136 (9)
C140.1063 (5)0.0990 (3)0.11650 (19)0.0153 (10)
C150.1458 (4)0.1453 (3)0.16624 (19)0.0144 (9)
C160.2599 (5)0.1255 (3)0.19579 (19)0.0170 (10)
H160.31860.08540.18320.020*
C170.2858 (5)0.1654 (3)0.2437 (2)0.0173 (10)
H170.36230.15040.26400.021*
N180.2089 (4)0.2242 (3)0.26299 (16)0.0172 (9)
C190.1023 (5)0.2465 (3)0.2324 (2)0.0198 (11)
H190.04890.29010.24440.024*
C200.0681 (5)0.2087 (3)0.1846 (2)0.0210 (11)
H200.00770.22580.16450.025*
C210.3874 (4)0.1034 (3)0.08650 (19)0.0133 (9)
C220.5112 (5)0.0731 (3)0.0732 (2)0.0186 (10)
H220.52320.02990.04760.022*
C230.6168 (5)0.1058 (3)0.0974 (2)0.0190 (10)
H230.70050.08420.08770.023*
N240.6058 (4)0.1672 (2)0.13399 (15)0.0140 (8)
C250.4862 (5)0.1953 (3)0.1468 (2)0.0181 (10)
H250.47640.23810.17280.022*
C260.3765 (4)0.1660 (3)0.12460 (19)0.0169 (10)
H260.29400.18850.13520.020*
N270.8937 (4)0.2770 (2)0.12257 (17)0.0166 (8)
C280.9949 (5)0.2358 (3)0.1009 (2)0.0181 (10)
H280.99690.17660.10430.022*
C291.0978 (5)0.2753 (3)0.0737 (2)0.0203 (11)
H291.16770.24320.05840.024*
C301.0984 (5)0.3614 (3)0.06900 (19)0.0164 (10)
C310.9911 (6)0.4046 (3)0.0898 (3)0.0317 (14)
H310.98620.46380.08640.038*
C320.8908 (5)0.3603 (3)0.1155 (3)0.0298 (14)
H320.81650.39030.12880.036*
C331.2164 (5)0.4058 (3)0.0462 (2)0.0180 (10)
C341.2377 (5)0.4066 (3)0.0086 (2)0.0170 (10)
C351.1560 (5)0.3705 (3)0.0466 (2)0.0209 (11)
H351.07520.34350.03890.025*
C361.2148 (5)0.3820 (3)0.0956 (2)0.0200 (11)
H361.18330.36350.12820.024*
C371.3338 (5)0.4273 (3)0.0891 (2)0.0166 (10)
C381.4244 (5)0.4532 (3)0.1294 (2)0.0193 (10)
C391.5413 (5)0.4973 (3)0.1226 (2)0.0203 (11)
C401.6274 (6)0.5300 (4)0.1640 (2)0.0302 (13)
H401.61670.52540.20090.036*
C411.7260 (6)0.5683 (4)0.1412 (2)0.0311 (13)
H411.79770.59520.15920.037*
C421.2961 (5)0.4386 (3)0.0851 (2)0.0190 (10)
C431.4001 (5)0.4286 (3)0.18511 (19)0.0174 (10)
C441.2894 (5)0.4536 (3)0.2097 (2)0.0218 (11)
H441.22670.48820.19150.026*
C451.2721 (5)0.4276 (3)0.2608 (2)0.0207 (11)
H451.19670.44620.27710.025*
N461.3541 (4)0.3781 (3)0.28868 (17)0.0190 (9)
C471.4625 (5)0.3557 (3)0.2655 (2)0.0224 (11)
H471.52460.32230.28500.027*
C481.4877 (5)0.3794 (3)0.2142 (2)0.0211 (11)
H481.56530.36170.19920.025*
N491.4106 (4)0.4815 (3)0.07523 (16)0.0169 (9)
N501.3443 (4)0.4413 (3)0.03592 (16)0.0174 (9)
O511.5961 (4)0.3889 (2)0.00144 (15)0.0263 (8)
C521.5754 (8)0.3290 (4)0.0402 (3)0.053 (2)
H52A1.48280.31550.04400.080*
H52B1.62470.27840.03040.080*
H52C1.60400.35060.07390.080*
Cu21.85333 (7)0.62527 (6)0.26033 (3)0.0407 (2)
Cl11.74574 (15)0.73684 (12)0.25157 (8)0.0466 (4)
Cl21.95335 (15)0.51048 (11)0.26176 (8)0.0450 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.0098 (2)0.0161 (2)0.0077 (2)0.00263 (16)0.00339 (16)0.00134 (17)
Sn20.0147 (2)0.0169 (2)0.0103 (2)0.00555 (17)0.00201 (17)0.00054 (18)
Cu10.0118 (3)0.0231 (3)0.0099 (3)0.0063 (2)0.0011 (2)0.0018 (2)
O10.0223 (18)0.0211 (18)0.022 (2)0.0007 (14)0.0008 (16)0.0048 (15)
C20.057 (4)0.037 (3)0.034 (4)0.024 (3)0.014 (3)0.007 (3)
N30.0134 (18)0.020 (2)0.009 (2)0.0050 (15)0.0052 (15)0.0032 (16)
N40.0131 (18)0.019 (2)0.009 (2)0.0039 (15)0.0041 (15)0.0034 (16)
C50.017 (2)0.023 (2)0.006 (2)0.0013 (19)0.0036 (19)0.0049 (19)
C60.026 (3)0.034 (3)0.008 (2)0.009 (2)0.008 (2)0.005 (2)
C70.021 (2)0.034 (3)0.013 (3)0.006 (2)0.008 (2)0.004 (2)
C80.014 (2)0.020 (2)0.012 (2)0.0005 (18)0.0054 (19)0.0002 (19)
C90.012 (2)0.017 (2)0.012 (2)0.0014 (17)0.0051 (18)0.0003 (19)
C100.014 (2)0.016 (2)0.011 (2)0.0020 (17)0.0024 (19)0.0014 (18)
C110.016 (2)0.021 (2)0.017 (3)0.0042 (19)0.002 (2)0.001 (2)
C120.015 (2)0.025 (2)0.013 (2)0.0057 (19)0.0032 (19)0.004 (2)
C130.011 (2)0.017 (2)0.012 (2)0.0025 (17)0.0003 (18)0.0039 (19)
C140.019 (2)0.021 (2)0.007 (2)0.0030 (19)0.0007 (19)0.0008 (19)
C150.016 (2)0.018 (2)0.010 (2)0.0030 (18)0.0052 (19)0.0001 (19)
C160.019 (2)0.019 (2)0.013 (2)0.0018 (19)0.004 (2)0.000 (2)
C170.016 (2)0.018 (2)0.018 (3)0.0028 (18)0.003 (2)0.000 (2)
N180.0168 (19)0.024 (2)0.011 (2)0.0029 (17)0.0010 (16)0.0056 (17)
C190.013 (2)0.028 (3)0.018 (3)0.0042 (19)0.001 (2)0.008 (2)
C200.018 (2)0.032 (3)0.013 (3)0.000 (2)0.001 (2)0.003 (2)
C210.014 (2)0.017 (2)0.010 (2)0.0039 (17)0.0036 (18)0.0032 (18)
C220.018 (2)0.022 (2)0.016 (3)0.0002 (19)0.005 (2)0.011 (2)
C230.011 (2)0.025 (3)0.021 (3)0.0029 (19)0.002 (2)0.004 (2)
N240.0150 (19)0.019 (2)0.009 (2)0.0030 (15)0.0036 (16)0.0015 (16)
C250.021 (2)0.020 (2)0.013 (2)0.0007 (19)0.005 (2)0.006 (2)
C260.013 (2)0.024 (2)0.015 (3)0.0037 (18)0.0042 (19)0.007 (2)
N270.0142 (19)0.018 (2)0.017 (2)0.0045 (16)0.0008 (16)0.0022 (17)
C280.022 (2)0.013 (2)0.018 (3)0.0047 (18)0.003 (2)0.0022 (19)
C290.016 (2)0.025 (3)0.019 (3)0.001 (2)0.007 (2)0.001 (2)
C300.020 (2)0.019 (2)0.010 (2)0.0040 (19)0.0015 (19)0.0057 (19)
C310.030 (3)0.018 (3)0.046 (4)0.004 (2)0.011 (3)0.000 (3)
C320.023 (3)0.018 (3)0.046 (4)0.003 (2)0.016 (3)0.004 (2)
C330.018 (2)0.019 (2)0.017 (3)0.0051 (19)0.001 (2)0.001 (2)
C340.016 (2)0.021 (2)0.014 (3)0.0036 (18)0.003 (2)0.000 (2)
C350.017 (2)0.022 (2)0.024 (3)0.0037 (19)0.000 (2)0.000 (2)
C360.022 (2)0.023 (2)0.015 (3)0.004 (2)0.001 (2)0.005 (2)
C370.016 (2)0.020 (2)0.013 (2)0.0024 (19)0.0012 (19)0.0011 (19)
C380.023 (2)0.023 (3)0.012 (3)0.005 (2)0.000 (2)0.000 (2)
C390.023 (3)0.023 (2)0.014 (3)0.007 (2)0.003 (2)0.000 (2)
C400.033 (3)0.044 (3)0.014 (3)0.017 (3)0.002 (2)0.001 (2)
C410.033 (3)0.040 (3)0.019 (3)0.019 (3)0.008 (2)0.002 (3)
C420.022 (2)0.020 (2)0.014 (3)0.010 (2)0.005 (2)0.000 (2)
C430.022 (2)0.019 (2)0.011 (2)0.0071 (19)0.003 (2)0.0018 (19)
C440.026 (3)0.018 (2)0.022 (3)0.004 (2)0.001 (2)0.003 (2)
C450.022 (2)0.019 (2)0.021 (3)0.003 (2)0.005 (2)0.002 (2)
N460.019 (2)0.023 (2)0.016 (2)0.0020 (17)0.0039 (17)0.0005 (17)
C470.021 (2)0.028 (3)0.018 (3)0.001 (2)0.003 (2)0.003 (2)
C480.017 (2)0.033 (3)0.014 (3)0.003 (2)0.007 (2)0.001 (2)
N490.019 (2)0.020 (2)0.011 (2)0.0075 (16)0.0023 (17)0.0014 (16)
N500.0169 (19)0.022 (2)0.012 (2)0.0063 (16)0.0024 (17)0.0001 (17)
O510.029 (2)0.0251 (19)0.023 (2)0.0025 (16)0.0081 (17)0.0041 (16)
C520.067 (5)0.037 (4)0.055 (5)0.018 (3)0.007 (4)0.014 (3)
Cu20.0279 (4)0.0577 (5)0.0364 (5)0.0080 (4)0.0005 (3)0.0040 (4)
Cl10.0303 (8)0.0598 (11)0.0488 (10)0.0091 (7)0.0062 (7)0.0070 (8)
Cl20.0239 (7)0.0563 (10)0.0549 (11)0.0021 (7)0.0040 (7)0.0077 (8)
Geometric parameters (Å, º) top
Sn1—O12.019 (3)C21—C261.390 (7)
Sn1—O1i2.019 (3)C21—C221.390 (7)
Sn1—N32.103 (4)C22—C231.383 (7)
Sn1—N3i2.103 (4)C23—N241.350 (6)
Sn1—N42.112 (4)N24—C251.337 (6)
Sn1—N4i2.112 (4)C25—C261.375 (7)
Sn2—O512.035 (4)N27—C281.327 (6)
Sn2—O51ii2.035 (4)N27—C321.342 (7)
Sn2—N492.089 (4)C28—C291.385 (7)
Sn2—N49ii2.089 (4)C29—C301.379 (7)
Sn2—N502.112 (4)C30—C311.384 (7)
Sn2—N50ii2.112 (4)C30—C331.498 (6)
Cu1—N241.989 (4)C31—C321.387 (7)
Cu1—N271.994 (4)C33—C341.392 (7)
Cu1—N18iii2.074 (4)C33—C421.420 (7)
Cu1—N46iv2.124 (4)C34—N501.383 (6)
O1—C21.368 (7)C34—C351.436 (7)
N3—C81.372 (6)C35—C361.363 (7)
N3—C51.374 (6)C36—C371.445 (7)
N4—C101.363 (6)C37—N501.374 (6)
N4—C131.371 (6)C37—C381.407 (7)
C5—C141.409 (7)C38—C391.417 (7)
C5—C61.441 (7)C38—C431.498 (7)
C6—C71.355 (7)C39—N49ii1.366 (7)
C7—C81.445 (7)C39—C401.434 (7)
C8—C91.409 (7)C40—C411.347 (8)
C9—C101.402 (7)C41—C42ii1.429 (7)
C9—C211.500 (6)C42—N491.377 (6)
C10—C111.453 (6)C42—C41ii1.429 (7)
C11—C121.340 (7)C43—C481.380 (7)
C12—C131.442 (6)C43—C441.391 (7)
C13—C14i1.413 (7)C44—C451.380 (7)
C14—C13i1.413 (7)C45—N461.332 (6)
C14—C151.496 (6)N46—C471.342 (7)
C15—C201.389 (7)N46—Cu1vi2.124 (4)
C15—C161.396 (7)C47—C481.391 (7)
C16—C171.382 (7)N49—C39ii1.366 (7)
C17—N181.340 (6)O51—C521.379 (8)
N18—C191.357 (6)Cu2—Cl22.104 (2)
N18—Cu1v2.074 (4)Cu2—Cl12.105 (2)
C19—C201.379 (7)
O1—Sn1—O1i180.0C17—C16—C15118.7 (4)
O1—Sn1—N387.70 (15)N18—C17—C16123.7 (4)
O1i—Sn1—N392.30 (15)C17—N18—C19117.0 (4)
O1—Sn1—N3i92.30 (15)C17—N18—Cu1v121.1 (3)
O1i—Sn1—N3i87.70 (15)C19—N18—Cu1v121.6 (3)
N3—Sn1—N3i180.0N18—C19—C20123.0 (5)
O1—Sn1—N491.60 (15)C19—C20—C15119.3 (5)
O1i—Sn1—N488.40 (15)C26—C21—C22117.0 (4)
N3—Sn1—N490.15 (15)C26—C21—C9121.0 (4)
N3i—Sn1—N489.85 (15)C22—C21—C9121.9 (4)
O1—Sn1—N4i88.40 (15)C23—C22—C21120.0 (4)
O1i—Sn1—N4i91.59 (15)N24—C23—C22122.7 (4)
N3—Sn1—N4i89.85 (15)C25—N24—C23116.8 (4)
N3i—Sn1—N4i90.15 (15)C25—N24—Cu1121.6 (3)
N4—Sn1—N4i180.0C23—N24—Cu1121.5 (3)
O51—Sn2—O51ii180.0N24—C25—C26123.9 (4)
O51—Sn2—N4992.94 (16)C25—C26—C21119.5 (4)
O51ii—Sn2—N4987.06 (16)C28—N27—C32117.4 (4)
O51—Sn2—N49ii87.06 (16)C28—N27—Cu1119.0 (3)
O51ii—Sn2—N49ii92.95 (16)C32—N27—Cu1123.5 (3)
N49—Sn2—N49ii180.0N27—C28—C29122.9 (4)
O51—Sn2—N5090.30 (16)C30—C29—C28119.7 (5)
O51ii—Sn2—N5089.71 (16)C29—C30—C31117.7 (5)
N49—Sn2—N5091.22 (15)C29—C30—C33120.4 (4)
N49ii—Sn2—N5088.78 (15)C31—C30—C33121.8 (4)
O51—Sn2—N50ii89.70 (16)C30—C31—C32119.0 (5)
O51ii—Sn2—N50ii90.30 (16)N27—C32—C31123.1 (5)
N49—Sn2—N50ii88.78 (15)C34—C33—C42128.5 (4)
N49ii—Sn2—N50ii91.22 (15)C34—C33—C30117.8 (4)
N50—Sn2—N50ii180.0C42—C33—C30113.6 (4)
N24—Cu1—N27120.13 (17)N50—C34—C33125.4 (4)
N24—Cu1—N18iii111.32 (16)N50—C34—C35107.9 (4)
N27—Cu1—N18iii112.20 (16)C33—C34—C35126.7 (4)
N24—Cu1—N46iv111.10 (16)C36—C35—C34107.9 (4)
N27—Cu1—N46iv108.98 (16)C35—C36—C37107.5 (5)
N18iii—Cu1—N46iv88.65 (17)N50—C37—C38125.2 (4)
C2—O1—Sn1124.4 (4)N50—C37—C36108.0 (4)
C8—N3—C5108.9 (4)C38—C37—C36126.8 (5)
C8—N3—Sn1125.4 (3)C37—C38—C39126.4 (5)
C5—N3—Sn1125.7 (3)C37—C38—C43117.7 (4)
C10—N4—C13109.1 (4)C39—C38—C43115.8 (4)
C10—N4—Sn1125.1 (3)N49ii—C39—C38125.9 (4)
C13—N4—Sn1125.6 (3)N49ii—C39—C40108.0 (4)
N3—C5—C14125.7 (4)C38—C39—C40126.1 (5)
N3—C5—C6107.9 (4)C41—C40—C39107.8 (5)
C14—C5—C6126.5 (4)C40—C41—C42ii107.9 (5)
C7—C6—C5107.7 (4)N49—C42—C33125.7 (4)
C6—C7—C8107.8 (4)N49—C42—C41ii107.8 (4)
N3—C8—C9125.5 (4)C33—C42—C41ii126.4 (4)
N3—C8—C7107.7 (4)C48—C43—C44117.1 (5)
C9—C8—C7126.7 (4)C48—C43—C38120.8 (5)
C10—C9—C8127.7 (4)C44—C43—C38122.1 (5)
C10—C9—C21116.4 (4)C45—C44—C43119.1 (5)
C8—C9—C21115.9 (4)N46—C45—C44124.2 (5)
N4—C10—C9126.2 (4)C45—N46—C47116.6 (4)
N4—C10—C11107.4 (4)C45—N46—Cu1vi113.4 (3)
C9—C10—C11126.4 (4)C47—N46—Cu1vi117.7 (3)
C12—C11—C10107.9 (4)N46—C47—C48122.7 (5)
C11—C12—C13107.7 (4)C43—C48—C47120.1 (5)
N4—C13—C14i125.4 (4)C39ii—N49—C42108.4 (4)
N4—C13—C12107.8 (4)C39ii—N49—Sn2126.9 (3)
C14i—C13—C12126.7 (4)C42—N49—Sn2124.5 (3)
C5—C14—C13i127.5 (4)C37—N50—C34108.7 (4)
C5—C14—C15115.2 (4)C37—N50—Sn2126.7 (3)
C13i—C14—C15117.2 (4)C34—N50—Sn2124.5 (3)
C20—C15—C16118.2 (4)C52—O51—Sn2124.2 (4)
C20—C15—C14120.5 (4)Cl2—Cu2—Cl1174.45 (8)
C16—C15—C14121.3 (4)
Symmetry codes: (i) x, y, z; (ii) x+3, y+1, z; (iii) x+1/2, y+1/2, z1/2; (iv) x1/2, y+1/2, z1/2; (v) x+1/2, y1/2, z1/2; (vi) x+1/2, y+1/2, z+1/2.
 

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