Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229616016326/yf3111sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229616016326/yf3111Isup2.hkl |
CCDC reference: 1469524
Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2005); data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2001); software used to prepare material for publication: publCIF (Westrip, 2010).
[Cd(C7H6NO5S)2(C14H14N4O2)2(H2O)2]·C14H14N4O2·4H2O | Z = 1 |
Mr = 1463.78 | F(000) = 756 |
Triclinic, P1 | Dx = 1.548 Mg m−3 |
Hall symbol: -P1 | Mo Kα radiation, λ = 0.71073 Å |
a = 10.8873 (12) Å | Cell parameters from 9883 reflections |
b = 11.4736 (12) Å | θ = 2.5–27.5° |
c = 13.4521 (15) Å | µ = 0.50 mm−1 |
α = 87.806 (3)° | T = 293 K |
β = 88.438 (3)° | Block, colourless |
γ = 69.247 (3)° | 0.25 × 0.20 × 0.15 mm |
V = 1570.0 (3) Å3 |
Bruker APEXII area-detector diffractometer | 7122 independent reflections |
Radiation source: fine-focus sealed tube | 6299 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.023 |
Detector resolution: 8.3 pixels mm-1 | θmax = 27.5°, θmin = 1.9° |
φ and ω scans | h = −14→14 |
Absorption correction: multi-scan SADABS | k = −14→14 |
Tmin = 0.886, Tmax = 0.927 | l = −17→16 |
23608 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.031 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.079 | H-atom parameters constrained |
S = 0.95 | w = 1/[σ2(Fo2) + (0.049P)2 + 0.5959P] where P = (Fo2 + 2Fc2)/3 |
7122 reflections | (Δ/σ)max < 0.001 |
431 parameters | Δρmax = 0.54 e Å−3 |
9 restraints | Δρmin = −0.52 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
C1 | 0.08609 (17) | 0.75195 (16) | −0.33652 (13) | 0.0267 (4) | |
C2 | 0.02217 (18) | 0.66425 (17) | −0.32628 (14) | 0.0297 (4) | |
C3 | 0.00848 (19) | 0.61690 (18) | −0.22982 (14) | 0.0333 (4) | |
H3 | −0.0351 | 0.5606 | −0.2214 | 0.040* | |
C4 | 0.05798 (18) | 0.65216 (17) | −0.14863 (14) | 0.0300 (4) | |
H4 | 0.0470 | 0.6203 | −0.0858 | 0.036* | |
C5 | 0.12483 (17) | 0.73551 (16) | −0.15937 (13) | 0.0253 (3) | |
C6 | 0.13684 (17) | 0.78558 (16) | −0.25222 (13) | 0.0263 (4) | |
H6 | 0.1795 | 0.8428 | −0.2590 | 0.032* | |
C7 | 0.1033 (2) | 0.80629 (18) | −0.43550 (14) | 0.0327 (4) | |
C8 | 0.70739 (19) | 0.61642 (17) | 0.06845 (15) | 0.0336 (4) | |
H8 | 0.7592 | 0.5528 | 0.0282 | 0.040* | |
C9 | 0.76566 (19) | 0.68803 (17) | 0.11402 (14) | 0.0324 (4) | |
H9 | 0.8551 | 0.6720 | 0.1048 | 0.039* | |
C10 | 0.69097 (18) | 0.78450 (15) | 0.17387 (13) | 0.0267 (4) | |
C11 | 0.55913 (19) | 0.80238 (16) | 0.18463 (14) | 0.0302 (4) | |
H11 | 0.5052 | 0.8654 | 0.2243 | 0.036* | |
C12 | 0.50767 (18) | 0.72651 (16) | 0.13636 (14) | 0.0304 (4) | |
H12 | 0.4184 | 0.7407 | 0.1441 | 0.036* | |
C13 | 0.7565 (2) | 0.86203 (18) | 0.22443 (15) | 0.0338 (4) | |
H13A | 0.7956 | 0.8185 | 0.2854 | 0.041* | |
H13B | 0.8271 | 0.8683 | 0.1815 | 0.041* | |
C14 | 0.61362 (19) | 1.01456 (17) | 0.33667 (13) | 0.0298 (4) | |
C15 | 0.5343 (2) | 1.15399 (17) | 0.34664 (14) | 0.0316 (4) | |
C16 | 0.3789 (2) | 1.30411 (19) | 0.45589 (16) | 0.0402 (5) | |
H16A | 0.2935 | 1.3005 | 0.4741 | 0.048* | |
H16B | 0.3680 | 1.3587 | 0.3973 | 0.048* | |
C17 | 0.4275 (2) | 1.35853 (17) | 0.53972 (14) | 0.0334 (4) | |
C18 | 0.5591 (2) | 1.3303 (2) | 0.55632 (17) | 0.0447 (5) | |
H18 | 0.6218 | 1.2741 | 0.5164 | 0.054* | |
C19 | 0.5972 (3) | 1.3860 (2) | 0.63254 (19) | 0.0517 (6) | |
H19 | 0.6866 | 1.3663 | 0.6423 | 0.062* | |
C20 | 0.3874 (3) | 1.4928 (2) | 0.67703 (17) | 0.0558 (7) | |
H20 | 0.3270 | 1.5493 | 0.7182 | 0.067* | |
C21 | 0.3400 (2) | 1.4417 (2) | 0.60283 (18) | 0.0518 (6) | |
H21 | 0.2500 | 1.4629 | 0.5952 | 0.062* | |
C22 | 0.2425 (2) | 0.0481 (2) | 0.36350 (15) | 0.0396 (5) | |
H22 | 0.2768 | 0.0756 | 0.4166 | 0.048* | |
C23 | 0.2560 (2) | 0.0937 (2) | 0.26845 (15) | 0.0371 (4) | |
H23 | 0.2984 | 0.1509 | 0.2587 | 0.045* | |
C24 | 0.20651 (17) | 0.05399 (17) | 0.18835 (13) | 0.0284 (4) | |
C25 | 0.1446 (2) | −0.0313 (2) | 0.20738 (15) | 0.0397 (5) | |
H25 | 0.1101 | −0.0611 | 0.1557 | 0.048* | |
C26 | 0.1349 (2) | −0.0713 (2) | 0.30430 (16) | 0.0434 (5) | |
H26 | 0.0926 | −0.1281 | 0.3164 | 0.052* | |
C27 | 0.21655 (18) | 0.10326 (19) | 0.08347 (13) | 0.0334 (4) | |
H27A | 0.1392 | 0.1080 | 0.0470 | 0.040* | |
H27B | 0.2184 | 0.1870 | 0.0863 | 0.040* | |
C28 | 0.44615 (17) | 0.04503 (17) | 0.03265 (12) | 0.0270 (4) | |
Cd1 | 0.5000 | 0.5000 | 0.0000 | 0.02595 (7) | |
N1 | 0.57979 (15) | 0.63372 (13) | 0.07909 (11) | 0.0285 (3) | |
N2 | 0.67090 (17) | 0.98639 (14) | 0.24834 (11) | 0.0323 (3) | |
H2 | 0.6565 | 1.0447 | 0.2032 | 0.048* | |
N3 | 0.46717 (17) | 1.18011 (15) | 0.43155 (12) | 0.0351 (4) | |
H3A | 0.4764 | 1.1203 | 0.4746 | 0.053* | |
N4 | 0.5132 (2) | 1.46647 (17) | 0.69309 (14) | 0.0487 (5) | |
N5 | 0.18288 (17) | −0.03280 (16) | 0.38145 (12) | 0.0366 (4) | |
N6 | 0.33291 (14) | 0.02541 (15) | 0.03052 (11) | 0.0293 (3) | |
H6A | 0.3285 | −0.0351 | −0.0032 | 0.044* | |
N7 | −0.02861 (19) | 0.62481 (18) | −0.40401 (13) | 0.0452 (4) | |
H7A | −0.0679 | 0.5722 | −0.3938 | 0.068* | |
H7B | −0.0214 | 0.6524 | −0.4634 | 0.068* | |
O1 | 0.30163 (15) | 0.66064 (14) | −0.02385 (12) | 0.0480 (4) | |
O2 | 0.09167 (14) | 0.80146 (15) | 0.02366 (10) | 0.0440 (4) | |
O3 | 0.23235 (17) | 0.87654 (14) | −0.08170 (11) | 0.0470 (4) | |
O4 | 0.15928 (16) | 0.88928 (14) | −0.43527 (10) | 0.0411 (3) | |
H4A | 0.1645 | 0.9150 | −0.4924 | 0.062* | |
O5 | 0.0675 (2) | 0.77610 (17) | −0.51241 (11) | 0.0594 (5) | |
O6 | 0.46607 (14) | 0.12562 (14) | 0.07951 (10) | 0.0390 (3) | |
O7 | 0.61981 (16) | 0.93940 (13) | 0.40575 (11) | 0.0438 (4) | |
O8 | 0.53583 (17) | 1.22861 (13) | 0.28007 (11) | 0.0482 (4) | |
O1W | 0.58224 (15) | 0.56164 (14) | −0.14583 (10) | 0.0426 (3) | |
H1WA | 0.5587 | 0.6395 | −0.1508 | 0.064* | |
H1WB | 0.5533 | 0.5310 | −0.1966 | 0.064* | |
O2W | 0.1393 (2) | 0.5968 (2) | 0.15763 (16) | 0.0816 (6) | |
H2WB | 0.1290 | 0.6700 | 0.1203 | 0.122* | |
H2WA | 0.2234 | 0.5504 | 0.1404 | 0.122* | |
O3W | 0.0494 (4) | 0.6150 (3) | 0.34867 (17) | 0.1385 (15) | |
H3WA | 0.0651 | 0.6191 | 0.2828 | 0.208* | |
H3WB | 0.0545 | 0.6790 | 0.3869 | 0.208* | |
S1 | 0.19292 (4) | 0.77277 (4) | −0.05318 (3) | 0.02649 (10) |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.0280 (9) | 0.0268 (9) | 0.0243 (8) | −0.0086 (7) | 0.0000 (7) | −0.0005 (7) |
C2 | 0.0304 (9) | 0.0296 (9) | 0.0293 (9) | −0.0104 (7) | −0.0022 (7) | −0.0033 (7) |
C3 | 0.0375 (10) | 0.0324 (10) | 0.0355 (10) | −0.0194 (8) | −0.0008 (8) | −0.0003 (8) |
C4 | 0.0341 (10) | 0.0296 (9) | 0.0260 (9) | −0.0113 (8) | 0.0003 (7) | 0.0030 (7) |
C5 | 0.0257 (8) | 0.0242 (8) | 0.0238 (8) | −0.0060 (7) | −0.0023 (7) | −0.0017 (7) |
C6 | 0.0257 (8) | 0.0245 (8) | 0.0282 (9) | −0.0082 (7) | 0.0011 (7) | −0.0016 (7) |
C7 | 0.0389 (10) | 0.0329 (10) | 0.0265 (9) | −0.0131 (8) | 0.0017 (8) | −0.0029 (8) |
C8 | 0.0335 (10) | 0.0267 (9) | 0.0384 (10) | −0.0070 (8) | −0.0009 (8) | −0.0102 (8) |
C9 | 0.0286 (9) | 0.0306 (9) | 0.0382 (10) | −0.0101 (7) | −0.0009 (8) | −0.0075 (8) |
C10 | 0.0358 (9) | 0.0211 (8) | 0.0240 (8) | −0.0110 (7) | −0.0032 (7) | −0.0005 (7) |
C11 | 0.0341 (9) | 0.0240 (9) | 0.0310 (9) | −0.0080 (7) | 0.0019 (7) | −0.0070 (7) |
C12 | 0.0290 (9) | 0.0265 (9) | 0.0345 (9) | −0.0083 (7) | −0.0019 (7) | −0.0014 (7) |
C13 | 0.0391 (10) | 0.0331 (10) | 0.0334 (10) | −0.0171 (8) | −0.0014 (8) | −0.0095 (8) |
C14 | 0.0402 (10) | 0.0279 (9) | 0.0265 (9) | −0.0184 (8) | −0.0026 (7) | −0.0012 (7) |
C15 | 0.0433 (11) | 0.0276 (9) | 0.0296 (9) | −0.0190 (8) | −0.0043 (8) | −0.0029 (8) |
C16 | 0.0393 (11) | 0.0339 (10) | 0.0453 (12) | −0.0097 (9) | −0.0011 (9) | −0.0087 (9) |
C17 | 0.0398 (10) | 0.0231 (9) | 0.0337 (10) | −0.0070 (8) | 0.0028 (8) | −0.0015 (7) |
C18 | 0.0393 (11) | 0.0444 (12) | 0.0503 (13) | −0.0136 (9) | 0.0078 (10) | −0.0166 (10) |
C19 | 0.0485 (13) | 0.0528 (14) | 0.0543 (14) | −0.0173 (11) | −0.0013 (11) | −0.0122 (11) |
C20 | 0.0649 (16) | 0.0412 (13) | 0.0401 (12) | 0.0089 (11) | −0.0016 (11) | −0.0137 (10) |
C21 | 0.0423 (12) | 0.0492 (13) | 0.0469 (13) | 0.0060 (10) | −0.0003 (10) | −0.0129 (11) |
C22 | 0.0417 (11) | 0.0511 (12) | 0.0296 (9) | −0.0208 (10) | −0.0046 (8) | 0.0023 (9) |
C23 | 0.0355 (10) | 0.0470 (12) | 0.0335 (10) | −0.0209 (9) | −0.0015 (8) | 0.0042 (9) |
C24 | 0.0228 (8) | 0.0319 (9) | 0.0250 (8) | −0.0034 (7) | 0.0040 (7) | 0.0007 (7) |
C25 | 0.0519 (12) | 0.0426 (11) | 0.0298 (10) | −0.0226 (10) | 0.0021 (9) | −0.0054 (9) |
C26 | 0.0606 (14) | 0.0406 (11) | 0.0371 (11) | −0.0282 (10) | 0.0029 (10) | 0.0008 (9) |
C27 | 0.0249 (9) | 0.0424 (11) | 0.0271 (9) | −0.0053 (8) | 0.0030 (7) | 0.0049 (8) |
C28 | 0.0265 (9) | 0.0354 (9) | 0.0185 (8) | −0.0107 (7) | −0.0001 (7) | 0.0030 (7) |
Cd1 | 0.03037 (11) | 0.02300 (10) | 0.02547 (10) | −0.01008 (7) | −0.00620 (7) | −0.00223 (7) |
N1 | 0.0340 (8) | 0.0224 (7) | 0.0293 (8) | −0.0097 (6) | −0.0063 (6) | −0.0017 (6) |
N2 | 0.0504 (10) | 0.0259 (8) | 0.0254 (7) | −0.0191 (7) | −0.0007 (7) | −0.0034 (6) |
N3 | 0.0465 (10) | 0.0267 (8) | 0.0335 (8) | −0.0146 (7) | 0.0036 (7) | −0.0030 (7) |
N4 | 0.0711 (14) | 0.0343 (9) | 0.0365 (9) | −0.0127 (9) | −0.0062 (9) | −0.0034 (8) |
N5 | 0.0433 (10) | 0.0383 (9) | 0.0272 (8) | −0.0137 (8) | 0.0012 (7) | 0.0033 (7) |
N6 | 0.0252 (7) | 0.0387 (9) | 0.0237 (7) | −0.0113 (6) | 0.0036 (6) | −0.0020 (6) |
N7 | 0.0603 (12) | 0.0564 (11) | 0.0333 (9) | −0.0376 (10) | −0.0078 (8) | −0.0018 (8) |
O1 | 0.0409 (8) | 0.0403 (8) | 0.0522 (9) | 0.0003 (6) | −0.0192 (7) | −0.0026 (7) |
O2 | 0.0395 (8) | 0.0600 (10) | 0.0296 (7) | −0.0133 (7) | 0.0029 (6) | −0.0108 (7) |
O3 | 0.0678 (10) | 0.0474 (9) | 0.0397 (8) | −0.0371 (8) | −0.0094 (7) | −0.0006 (7) |
O4 | 0.0588 (9) | 0.0484 (8) | 0.0261 (7) | −0.0320 (7) | −0.0003 (6) | 0.0062 (6) |
O5 | 0.1040 (15) | 0.0705 (11) | 0.0254 (7) | −0.0573 (11) | −0.0048 (8) | 0.0000 (7) |
O6 | 0.0364 (7) | 0.0479 (8) | 0.0359 (7) | −0.0179 (6) | 0.0042 (6) | −0.0126 (6) |
O7 | 0.0619 (10) | 0.0317 (7) | 0.0348 (7) | −0.0142 (7) | 0.0073 (7) | 0.0050 (6) |
O8 | 0.0784 (11) | 0.0276 (7) | 0.0365 (8) | −0.0171 (7) | 0.0039 (7) | 0.0034 (6) |
O1W | 0.0562 (9) | 0.0400 (8) | 0.0321 (7) | −0.0176 (7) | −0.0044 (7) | 0.0046 (6) |
O2W | 0.0802 (14) | 0.0853 (15) | 0.0748 (13) | −0.0282 (12) | 0.0282 (11) | 0.0197 (11) |
O3W | 0.296 (4) | 0.138 (2) | 0.0589 (13) | −0.172 (3) | 0.0531 (19) | −0.0370 (15) |
S1 | 0.0272 (2) | 0.0261 (2) | 0.0249 (2) | −0.00740 (17) | −0.00423 (17) | −0.00164 (17) |
C1—C6 | 1.400 (2) | C20—N4 | 1.316 (3) |
C1—C2 | 1.413 (3) | C20—C21 | 1.376 (3) |
C1—C7 | 1.484 (3) | C20—H20 | 0.9300 |
C2—N7 | 1.360 (2) | C21—H21 | 0.9300 |
C2—C3 | 1.412 (3) | C22—N5 | 1.320 (3) |
C3—C4 | 1.366 (3) | C22—C23 | 1.387 (3) |
C3—H3 | 0.9300 | C22—H22 | 0.9300 |
C4—C5 | 1.393 (2) | C23—C24 | 1.379 (3) |
C4—H4 | 0.9300 | C23—H23 | 0.9300 |
C5—C6 | 1.377 (2) | C24—C25 | 1.384 (3) |
C5—S1 | 1.7613 (17) | C24—C27 | 1.515 (2) |
C6—H6 | 0.9300 | C25—C26 | 1.379 (3) |
C7—O5 | 1.219 (2) | C25—H25 | 0.9300 |
C7—O4 | 1.300 (2) | C26—N5 | 1.332 (3) |
C8—N1 | 1.336 (2) | C26—H26 | 0.9300 |
C8—C9 | 1.372 (3) | C27—N6 | 1.452 (2) |
C8—H8 | 0.9300 | C27—H27A | 0.9700 |
C9—C10 | 1.389 (3) | C27—H27B | 0.9700 |
C9—H9 | 0.9300 | C28—O6 | 1.222 (2) |
C10—C11 | 1.380 (3) | C28—N6 | 1.331 (2) |
C10—C13 | 1.512 (2) | C28—C28i | 1.539 (3) |
C11—C12 | 1.379 (3) | Cd1—O1 | 2.3100 (14) |
C11—H11 | 0.9300 | Cd1—O1ii | 2.3100 (14) |
C12—N1 | 1.334 (2) | Cd1—N1 | 2.3153 (15) |
C12—H12 | 0.9300 | Cd1—N1ii | 2.3153 (15) |
C13—N2 | 1.444 (2) | Cd1—O1Wii | 2.3232 (14) |
C13—H13A | 0.9700 | Cd1—O1W | 2.3232 (14) |
C13—H13B | 0.9700 | N2—H2 | 0.8600 |
C14—O7 | 1.230 (2) | N3—H3A | 0.8600 |
C14—N2 | 1.323 (2) | N6—H6A | 0.8600 |
C14—C15 | 1.534 (3) | N7—H7A | 0.8600 |
C15—O8 | 1.219 (2) | N7—H7B | 0.8600 |
C15—N3 | 1.325 (2) | O1—S1 | 1.4557 (15) |
C16—N3 | 1.451 (3) | O2—S1 | 1.4488 (15) |
C16—C17 | 1.504 (3) | O3—S1 | 1.4377 (15) |
C16—H16A | 0.9700 | O4—H4A | 0.8200 |
C16—H16B | 0.9700 | O1W—H1WA | 0.8379 |
C17—C18 | 1.375 (3) | O1W—H1WB | 0.8937 |
C17—C21 | 1.383 (3) | O2W—H2WB | 0.9348 |
C18—C19 | 1.376 (3) | O2W—H2WA | 0.9107 |
C18—H18 | 0.9300 | O3W—H3WA | 0.9010 |
C19—N4 | 1.331 (3) | O3W—H3WB | 0.9299 |
C19—H19 | 0.9300 | ||
C6—C1—C2 | 119.36 (16) | N5—C22—C23 | 122.53 (19) |
C6—C1—C7 | 119.58 (16) | N5—C22—H22 | 118.7 |
C2—C1—C7 | 121.04 (16) | C23—C22—H22 | 118.7 |
N7—C2—C3 | 118.43 (17) | C22—C23—C24 | 119.84 (18) |
N7—C2—C1 | 123.50 (17) | C22—C23—H23 | 120.1 |
C3—C2—C1 | 118.06 (16) | C24—C23—H23 | 120.1 |
C4—C3—C2 | 121.35 (17) | C25—C24—C23 | 117.48 (17) |
C4—C3—H3 | 119.3 | C25—C24—C27 | 120.85 (17) |
C2—C3—H3 | 119.3 | C23—C24—C27 | 121.66 (17) |
C3—C4—C5 | 120.47 (17) | C26—C25—C24 | 118.86 (19) |
C3—C4—H4 | 119.8 | C26—C25—H25 | 120.6 |
C5—C4—H4 | 119.8 | C24—C25—H25 | 120.6 |
C6—C5—C4 | 119.44 (16) | N5—C26—C25 | 123.50 (19) |
C6—C5—S1 | 121.85 (14) | N5—C26—H26 | 118.3 |
C4—C5—S1 | 118.71 (13) | C25—C26—H26 | 118.3 |
C5—C6—C1 | 121.27 (16) | N6—C27—C24 | 112.43 (15) |
C5—C6—H6 | 119.4 | N6—C27—H27A | 109.1 |
C1—C6—H6 | 119.4 | C24—C27—H27A | 109.1 |
O5—C7—O4 | 121.63 (18) | N6—C27—H27B | 109.1 |
O5—C7—C1 | 122.85 (18) | C24—C27—H27B | 109.1 |
O4—C7—C1 | 115.51 (16) | H27A—C27—H27B | 107.8 |
N1—C8—C9 | 123.12 (17) | O6—C28—N6 | 125.43 (16) |
N1—C8—H8 | 118.4 | O6—C28—C28i | 121.8 (2) |
C9—C8—H8 | 118.4 | N6—C28—C28i | 112.77 (19) |
C8—C9—C10 | 119.93 (18) | O1—Cd1—O1ii | 180.00 (7) |
C8—C9—H9 | 120.0 | O1—Cd1—N1 | 90.11 (5) |
C10—C9—H9 | 120.0 | O1ii—Cd1—N1 | 89.89 (5) |
C11—C10—C9 | 116.87 (16) | O1—Cd1—N1ii | 89.89 (5) |
C11—C10—C13 | 123.67 (16) | O1ii—Cd1—N1ii | 90.11 (5) |
C9—C10—C13 | 119.45 (17) | N1—Cd1—N1ii | 180.00 (6) |
C12—C11—C10 | 119.83 (16) | O1—Cd1—O1Wii | 90.04 (6) |
C12—C11—H11 | 120.1 | O1ii—Cd1—O1Wii | 89.96 (6) |
C10—C11—H11 | 120.1 | N1—Cd1—O1Wii | 93.98 (5) |
N1—C12—C11 | 123.14 (17) | N1ii—Cd1—O1Wii | 86.02 (5) |
N1—C12—H12 | 118.4 | O1—Cd1—O1W | 89.96 (6) |
C11—C12—H12 | 118.4 | O1ii—Cd1—O1W | 90.04 (6) |
N2—C13—C10 | 115.14 (16) | N1—Cd1—O1W | 86.02 (5) |
N2—C13—H13A | 108.5 | N1ii—Cd1—O1W | 93.98 (5) |
C10—C13—H13A | 108.5 | O1Wii—Cd1—O1W | 180.00 (8) |
N2—C13—H13B | 108.5 | C12—N1—C8 | 117.11 (15) |
C10—C13—H13B | 108.5 | C12—N1—Cd1 | 124.64 (12) |
H13A—C13—H13B | 107.5 | C8—N1—Cd1 | 118.25 (12) |
O7—C14—N2 | 125.29 (18) | C14—N2—C13 | 122.82 (16) |
O7—C14—C15 | 121.30 (17) | C14—N2—H2 | 118.6 |
N2—C14—C15 | 113.41 (15) | C13—N2—H2 | 118.6 |
O8—C15—N3 | 126.17 (18) | C15—N3—C16 | 123.54 (17) |
O8—C15—C14 | 120.65 (17) | C15—N3—H3A | 118.2 |
N3—C15—C14 | 113.17 (16) | C16—N3—H3A | 118.2 |
N3—C16—C17 | 112.86 (17) | C20—N4—C19 | 116.7 (2) |
N3—C16—H16A | 109.0 | C22—N5—C26 | 117.79 (17) |
C17—C16—H16A | 109.0 | C28—N6—C27 | 121.91 (16) |
N3—C16—H16B | 109.0 | C28—N6—H6A | 119.0 |
C17—C16—H16B | 109.0 | C27—N6—H6A | 119.0 |
H16A—C16—H16B | 107.8 | C2—N7—H7A | 120.0 |
C18—C17—C21 | 117.1 (2) | C2—N7—H7B | 120.0 |
C18—C17—C16 | 122.22 (18) | H7A—N7—H7B | 120.0 |
C21—C17—C16 | 120.70 (19) | S1—O1—Cd1 | 167.77 (11) |
C17—C18—C19 | 119.4 (2) | C7—O4—H4A | 109.5 |
C17—C18—H18 | 120.3 | Cd1—O1W—H1WA | 111.0 |
C19—C18—H18 | 120.3 | Cd1—O1W—H1WB | 107.6 |
N4—C19—C18 | 123.7 (2) | H1WA—O1W—H1WB | 111.3 |
N4—C19—H19 | 118.2 | H2WB—O2W—H2WA | 100.0 |
C18—C19—H19 | 118.2 | H3WA—O3W—H3WB | 117.7 |
N4—C20—C21 | 123.8 (2) | O3—S1—O2 | 113.39 (10) |
N4—C20—H20 | 118.1 | O3—S1—O1 | 113.74 (10) |
C21—C20—H20 | 118.1 | O2—S1—O1 | 109.50 (10) |
C20—C21—C17 | 119.4 (2) | O3—S1—C5 | 106.64 (9) |
C20—C21—H21 | 120.3 | O2—S1—C5 | 106.68 (8) |
C17—C21—H21 | 120.3 | O1—S1—C5 | 106.36 (8) |
C6—C1—C2—N7 | −179.13 (18) | C24—C25—C26—N5 | −0.4 (3) |
C7—C1—C2—N7 | −0.8 (3) | C25—C24—C27—N6 | −88.4 (2) |
C6—C1—C2—C3 | 2.0 (3) | C23—C24—C27—N6 | 92.9 (2) |
C7—C1—C2—C3 | −179.61 (17) | C11—C12—N1—C8 | −0.7 (3) |
N7—C2—C3—C4 | 179.59 (18) | C11—C12—N1—Cd1 | 178.17 (14) |
C1—C2—C3—C4 | −1.5 (3) | C9—C8—N1—C12 | 0.7 (3) |
C2—C3—C4—C5 | −0.6 (3) | C9—C8—N1—Cd1 | −178.28 (15) |
C3—C4—C5—C6 | 2.2 (3) | O1—Cd1—N1—C12 | 34.53 (15) |
C3—C4—C5—S1 | −177.28 (14) | O1ii—Cd1—N1—C12 | −145.47 (15) |
C4—C5—C6—C1 | −1.7 (3) | O1Wii—Cd1—N1—C12 | −55.51 (15) |
S1—C5—C6—C1 | 177.81 (13) | O1W—Cd1—N1—C12 | 124.49 (15) |
C2—C1—C6—C5 | −0.5 (3) | O1—Cd1—N1—C8 | −146.58 (14) |
C7—C1—C6—C5 | −178.87 (16) | O1ii—Cd1—N1—C8 | 33.42 (14) |
C6—C1—C7—O5 | 176.1 (2) | O1Wii—Cd1—N1—C8 | 123.37 (14) |
C2—C1—C7—O5 | −2.3 (3) | O1W—Cd1—N1—C8 | −56.63 (14) |
C6—C1—C7—O4 | −4.0 (3) | O7—C14—N2—C13 | −4.2 (3) |
C2—C1—C7—O4 | 177.61 (17) | C15—C14—N2—C13 | 176.32 (16) |
N1—C8—C9—C10 | −0.6 (3) | C10—C13—N2—C14 | 95.1 (2) |
C8—C9—C10—C11 | 0.4 (3) | O8—C15—N3—C16 | 2.9 (3) |
C8—C9—C10—C13 | 179.45 (18) | C14—C15—N3—C16 | −176.31 (17) |
C9—C10—C11—C12 | −0.4 (3) | C17—C16—N3—C15 | −112.7 (2) |
C13—C10—C11—C12 | −179.44 (17) | C21—C20—N4—C19 | 0.4 (4) |
C10—C11—C12—N1 | 0.6 (3) | C18—C19—N4—C20 | −0.3 (4) |
C11—C10—C13—N2 | −26.2 (3) | C23—C22—N5—C26 | 0.2 (3) |
C9—C10—C13—N2 | 154.82 (17) | C25—C26—N5—C22 | 0.1 (3) |
O7—C14—C15—O8 | 175.22 (19) | O6—C28—N6—C27 | 1.9 (3) |
N2—C14—C15—O8 | −5.3 (3) | C28i—C28—N6—C27 | −177.35 (17) |
O7—C14—C15—N3 | −5.5 (3) | C24—C27—N6—C28 | −90.4 (2) |
N2—C14—C15—N3 | 173.97 (16) | N1—Cd1—O1—S1 | 67.7 (5) |
N3—C16—C17—C18 | 31.2 (3) | N1ii—Cd1—O1—S1 | −112.3 (5) |
N3—C16—C17—C21 | −149.9 (2) | O1Wii—Cd1—O1—S1 | 161.7 (5) |
C21—C17—C18—C19 | −0.8 (3) | O1W—Cd1—O1—S1 | −18.3 (5) |
C16—C17—C18—C19 | 178.1 (2) | Cd1—O1—S1—O3 | −27.8 (5) |
C17—C18—C19—N4 | 0.5 (4) | Cd1—O1—S1—O2 | −155.8 (4) |
N4—C20—C21—C17 | −0.7 (4) | Cd1—O1—S1—C5 | 89.3 (5) |
C18—C17—C21—C20 | 0.9 (3) | C6—C5—S1—O3 | 11.42 (18) |
C16—C17—C21—C20 | −178.1 (2) | C4—C5—S1—O3 | −169.11 (14) |
N5—C22—C23—C24 | −0.2 (3) | C6—C5—S1—O2 | 132.89 (15) |
C22—C23—C24—C25 | −0.1 (3) | C4—C5—S1—O2 | −47.63 (16) |
C22—C23—C24—C27 | 178.73 (18) | C6—C5—S1—O1 | −110.29 (16) |
C23—C24—C25—C26 | 0.4 (3) | C4—C5—S1—O1 | 69.19 (16) |
C27—C24—C25—C26 | −178.42 (19) |
Symmetry codes: (i) −x+1, −y, −z; (ii) −x+1, −y+1, −z. |
D—H···A | D—H | H···A | D···A | D—H···A |
O1W—H1WA···O8iii | 0.84 | 2.27 | 2.882 (2) | 130 |
N2—H2···O6iv | 0.86 | 2.58 | 3.187 (2) | 129 |
N2—H2···O3iii | 0.86 | 2.35 | 3.063 (2) | 141 |
O1W—H1WB···N4v | 0.89 | 1.81 | 2.702 (2) | 173 |
O2W—H2WB···O2 | 0.93 | 1.89 | 2.810 (3) | 167 |
N3—H3A···O7vi | 0.86 | 2.12 | 2.854 (2) | 143 |
O2W—H2WA···O1Wii | 0.91 | 2.05 | 2.935 (3) | 163 |
O4—H4A···N5vii | 0.82 | 1.81 | 2.628 (2) | 178 |
O3W—H3WA···O2W | 0.90 | 1.83 | 2.714 (3) | 165 |
O3W—H3WB···O5viii | 0.93 | 1.83 | 2.737 (3) | 166 |
N6—H6A···O3ix | 0.86 | 2.03 | 2.830 (2) | 154 |
N7—H7A···O3Wx | 0.86 | 2.15 | 2.907 (4) | 147 |
N7—H7B···O5 | 0.86 | 2.06 | 2.692 (3) | 129 |
C27—H27A···O2x | 0.97 | 2.55 | 3.475 (2) | 159 |
Symmetry codes: (ii) −x+1, −y+1, −z; (iii) −x+1, −y+2, −z; (iv) x, y+1, z; (v) x, y−1, z−1; (vi) −x+1, −y+2, −z+1; (vii) x, y+1, z−1; (viii) x, y, z+1; (ix) x, y−1, z; (x) −x, −y+1, −z. |