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The title compounds, Na[{AmO2}(C2H3O2)3], (I), and (CH6N3)[{AmO2}(C4H5O2)3], (II), contain complex anions in which AmO22+ cations are surrounded by three bidentate-chelating carboxyl­ate groups. The atoms of the AmO2 group and the Na atoms in (I) are situated on threefold axes. All the atoms in (II) occupy general positions. Both compounds are isomorphous with earlier studied analogous compounds of previous members of the actinide (An) series.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S010827011101701X/yf3001sup1.cif
Contains datablocks global, I, II

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010827011101701X/yf3001Isup2.hkl
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010827011101701X/yf3001IIsup3.hkl
Contains datablock II

CCDC references: 833409; 833410

Computing details top

For both compounds, data collection: APEX2 (Bruker, 2006); cell refinement: SAINT-Plus (Bruker, 1998); data reduction: SAINT-Plus (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

(I) Sodium tris(acetato-κ2O,O')dioxidoamericate(VI) top
Crystal data top
Na[Am(C2H3O2)3O2]Dx = 2.652 Mg m3
Mr = 475.12Mo Kα radiation, λ = 0.71073 Å
Cubic, P213Cell parameters from 1202 reflections
Hall symbol: P 2ac 2ab 3θ = 3.3–23.3°
a = 10.5967 (2) ŵ = 6.51 mm1
V = 1189.90 (4) Å3T = 100 K
Z = 4Fragment, brown-yellow
F(000) = 8600.04 × 0.04 × 0.04 mm
Data collection top
Bruker Kappa APEXII area-detector
diffractometer
1167 independent reflections
Radiation source: fine-focus sealed tube1017 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.135
ω and φ scansθmax = 30.0°, θmin = 4.7°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)
h = 1413
Tmin = 0.640, Tmax = 0.810k = 1414
15606 measured reflectionsl = 1414
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.032H-atom parameters constrained
wR(F2) = 0.056 w = 1/[σ2(Fo2) + (0.0213P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max < 0.001
1167 reflectionsΔρmax = 0.97 e Å3
50 parametersΔρmin = 0.86 e Å3
0 restraintsAbsolute structure: Flack (1983), 502 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.02 (4)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Am10.81974 (2)0.81974 (2)0.81974 (2)0.01028 (10)
Na10.5769 (3)0.9231 (3)1.0769 (3)0.0126 (10)
O10.9143 (5)0.9143 (5)0.9143 (5)0.019 (2)
O20.7248 (5)0.7248 (5)0.7248 (5)0.019 (2)
O30.7481 (5)1.0049 (4)0.6986 (5)0.0147 (11)
O40.6371 (4)0.9549 (5)0.8651 (4)0.0160 (11)
C10.6545 (6)1.0244 (7)0.7685 (7)0.0141 (16)
C20.5646 (8)1.1291 (8)0.7403 (8)0.026 (2)
H2A0.61191.20690.72420.039*
H2B0.50831.14170.81260.039*
H2C0.51451.10740.66560.039*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Am10.01028 (10)0.01028 (10)0.01028 (10)0.00018 (11)0.00018 (11)0.00018 (11)
Na10.0126 (10)0.0126 (10)0.0126 (10)0.0003 (11)0.0003 (11)0.0003 (11)
O10.019 (2)0.019 (2)0.019 (2)0.003 (2)0.003 (2)0.003 (2)
O20.019 (2)0.019 (2)0.019 (2)0.002 (2)0.002 (2)0.002 (2)
O30.013 (2)0.014 (2)0.017 (3)0.0049 (19)0.002 (2)0.000 (2)
O40.018 (3)0.015 (3)0.015 (3)0.005 (2)0.003 (2)0.002 (2)
C10.014 (4)0.011 (3)0.016 (3)0.001 (3)0.004 (3)0.003 (3)
C20.020 (4)0.033 (5)0.025 (4)0.012 (4)0.004 (3)0.008 (4)
Geometric parameters (Å, º) top
Am1—O11.735 (9)Na1—O3v2.384 (6)
Am1—O21.742 (9)Na1—O3vi2.384 (6)
Am1—O32.464 (5)Na1—O3ii2.384 (6)
Am1—O42.455 (5)O3—C11.255 (8)
Am1—O4i2.455 (5)O3—Na1vii2.384 (6)
Am1—O4ii2.455 (5)O4—C11.274 (8)
Am1—O3i2.464 (5)C1—C21.492 (9)
Am1—O3ii2.464 (5)C2—H2A0.9800
Na1—O4iii2.358 (5)C2—H2B0.9800
Na1—O4iv2.358 (5)C2—H2C0.9800
Na1—O42.358 (5)
O1—Am1—O2180.00O4iii—Na1—O499.21 (19)
O3—Am1—O452.74 (16)O4iv—Na1—O499.21 (19)
O4i—Am1—O367.26 (16)O4iii—Na1—O3v70.13 (16)
O1—Am1—O4ii90.30 (12)O4iv—Na1—O3v154.76 (17)
O2—Am1—O4ii89.70 (12)O4—Na1—O3v104.99 (17)
O1—Am1—O4i90.30 (12)O4iii—Na1—O3vi104.99 (16)
O2—Am1—O4i89.70 (12)O4iv—Na1—O3vi70.13 (16)
O4ii—Am1—O4i119.997 (2)O4—Na1—O3vi154.75 (17)
O1—Am1—O490.30 (12)O3v—Na1—O3vi90.1 (2)
O2—Am1—O489.70 (12)O4iii—Na1—O3ii154.75 (17)
O4ii—Am1—O4119.997 (2)O4iv—Na1—O3ii104.99 (17)
O4i—Am1—O4119.997 (2)O4—Na1—O3ii70.13 (16)
O1—Am1—O3i91.09 (12)O3v—Na1—O3ii90.1 (2)
O2—Am1—O3i88.91 (12)O3vi—Na1—O3ii90.1 (2)
O4ii—Am1—O3i67.26 (16)C1—O3—Na1vii151.8 (5)
O4i—Am1—O3i52.74 (16)C1—O3—Am193.9 (4)
O4—Am1—O3i172.61 (16)Na1vii—O3—Am1107.28 (19)
O1—Am1—O391.09 (12)C1—O4—Na1152.4 (5)
O2—Am1—O388.91 (12)C1—O4—Am193.8 (4)
O4ii—Am1—O3172.61 (16)Na1—O4—Am1108.4 (2)
O3i—Am1—O3119.964 (8)O3—C1—O4119.5 (6)
O1—Am1—O3ii91.09 (12)O3—C1—C2120.6 (7)
O2—Am1—O3ii88.91 (12)O4—C1—C2119.9 (6)
O4ii—Am1—O3ii52.74 (16)C1—C2—H2A109.5
O4i—Am1—O3ii172.61 (16)C1—C2—H2B109.5
O4—Am1—O3ii67.26 (16)H2A—C2—H2B109.5
O3i—Am1—O3ii119.964 (8)C1—C2—H2C109.5
O3—Am1—O3ii119.964 (8)H2A—C2—H2C109.5
O4iii—Na1—O4iv99.21 (19)H2B—C2—H2C109.5
O1—Am1—O3—C191.1 (4)O4ii—Am1—O4—C1176.8 (3)
O2—Am1—O3—C188.9 (4)O4i—Am1—O4—C12.1 (5)
O4i—Am1—O3—C1179.0 (5)O3—Am1—O4—C11.5 (4)
O4—Am1—O3—C11.5 (4)O3ii—Am1—O4—C1176.3 (4)
O3i—Am1—O3—C1177.0 (3)C1i—Am1—O4—C10.4 (4)
O3ii—Am1—O3—C10.8 (6)C1ii—Am1—O4—C1175.9 (5)
C1i—Am1—O3—C1177.4 (5)Na1vii—O3—C1—O4136.3 (7)
C1ii—Am1—O3—C13.1 (4)Am1—O3—C1—O42.7 (7)
O4iii—Na1—O4—C16.3 (10)Na1vii—O3—C1—C243.0 (14)
O4iv—Na1—O4—C194.6 (9)Am1—O3—C1—C2178.0 (7)
O3v—Na1—O4—C178.1 (10)Na1—O4—C1—O3141.5 (8)
O3vi—Na1—O4—C1157.0 (9)Am1—O4—C1—O32.7 (7)
O3ii—Na1—O4—C1162.6 (10)Na1—O4—C1—C237.8 (14)
O1—Am1—O4—C192.7 (4)Am1—O4—C1—C2178.0 (7)
O2—Am1—O4—C187.3 (4)
Symmetry codes: (i) y, z, x; (ii) z, x, y; (iii) y+3/2, z+2, x+1/2; (iv) z1/2, x+3/2, y+2; (v) x+3/2, y+2, z+1/2; (vi) y1/2, z+3/2, x+2; (vii) x+3/2, y+2, z1/2.
(II) guanidinium tris(cyclopropanecarboxylato-κ2O,O')dioxidoamericate(VI) top
Crystal data top
(CH6N3)[Am(C4H5O2)3O2]F(000) = 1116
Mr = 590.33Dx = 2.170 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 3266 reflections
a = 9.5421 (3) Åθ = 2.9–24.8°
b = 13.2830 (4) ŵ = 4.29 mm1
c = 14.2737 (4) ÅT = 100 K
β = 92.927 (2)°Plate, light brown–yellow
V = 1806.80 (9) Å30.14 × 0.06 × 0.02 mm
Z = 4
Data collection top
Bruker Kappa APEXII area-detector
diffractometer
5218 independent reflections
Radiation source: fine-focus sealed tube3801 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.088
ω and φ scansθmax = 30.0°, θmin = 4.5°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)
h = 1213
Tmin = 0.712, Tmax = 0.924k = 1818
26314 measured reflectionsl = 1920
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.065H-atom parameters constrained
S = 1.00 w = 1/[σ2(Fo2) + (0.0204P)2]
where P = (Fo2 + 2Fc2)/3
5218 reflections(Δ/σ)max = 0.001
226 parametersΔρmax = 1.27 e Å3
0 restraintsΔρmin = 1.16 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Am10.32846 (2)0.674070 (12)0.458603 (12)0.00981 (5)
O10.2598 (4)0.7756 (3)0.3931 (3)0.0206 (9)
O20.3939 (4)0.5731 (3)0.5251 (3)0.0176 (8)
O110.5585 (4)0.7484 (3)0.4467 (3)0.0230 (9)
O120.4502 (4)0.7899 (3)0.5730 (3)0.0185 (8)
O210.1770 (4)0.7172 (3)0.5872 (3)0.0174 (8)
O220.0937 (4)0.6078 (3)0.4841 (2)0.0143 (8)
O310.2392 (4)0.5609 (3)0.3325 (3)0.0161 (8)
O320.4620 (4)0.6001 (3)0.3305 (2)0.0143 (8)
N10.3197 (5)0.9135 (3)0.8850 (3)0.0194 (10)
H1A0.39340.93920.91600.023*
H1B0.23680.91580.90920.023*
N20.2207 (5)0.8355 (3)0.7548 (3)0.0197 (10)
H2A0.22800.80900.69870.024*
H2B0.13840.83830.77980.024*
N30.4572 (5)0.8667 (3)0.7637 (3)0.0146 (9)
H3A0.46420.84020.70770.018*
H3B0.53230.89030.79460.018*
C10.3338 (6)0.8711 (4)0.8015 (4)0.0141 (11)
C110.5533 (6)0.8004 (4)0.5205 (4)0.0177 (12)
C120.6643 (7)0.8757 (4)0.5448 (4)0.0227 (12)
H12A0.66900.90170.61060.027*
C130.8005 (7)0.8694 (4)0.4970 (4)0.0238 (13)
H13A0.88710.88900.53360.029*
H13B0.81220.81320.45250.029*
C140.7009 (8)0.9497 (4)0.4688 (4)0.0310 (16)
H14A0.65010.94360.40680.037*
H14B0.72491.01940.48810.037*
C210.0830 (6)0.6533 (3)0.5619 (4)0.0134 (11)
C220.0328 (6)0.6278 (4)0.6216 (4)0.0143 (11)
H22A0.09830.57380.59770.017*
C230.0963 (7)0.7101 (4)0.6809 (4)0.0195 (12)
H23A0.05820.77910.67580.023*
H23B0.19820.70660.69060.023*
C240.0044 (6)0.6323 (4)0.7277 (4)0.0165 (11)
H24A0.04950.58090.76630.020*
H24B0.09040.65330.75150.020*
C310.3591 (6)0.5470 (4)0.2996 (3)0.0118 (10)
C320.3763 (6)0.4668 (4)0.2292 (4)0.0162 (11)
H32A0.28810.43170.20660.019*
C330.5054 (8)0.4020 (4)0.2384 (4)0.0301 (16)
H33A0.57580.41790.28970.036*
H33B0.49490.32940.22400.036*
C340.4895 (6)0.4740 (4)0.1592 (4)0.0195 (12)
H34A0.46880.44620.09570.023*
H34B0.54980.53480.16130.023*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Am10.00979 (9)0.01152 (7)0.00818 (9)0.00111 (9)0.00105 (6)0.00023 (8)
O10.024 (2)0.0205 (19)0.018 (2)0.0043 (17)0.0036 (18)0.0028 (15)
O20.012 (2)0.0222 (19)0.019 (2)0.0038 (16)0.0001 (16)0.0049 (15)
O110.015 (2)0.035 (2)0.020 (2)0.0095 (18)0.0054 (18)0.0116 (17)
O120.017 (2)0.0243 (19)0.015 (2)0.0068 (16)0.0047 (17)0.0068 (15)
O210.015 (2)0.0195 (18)0.019 (2)0.0053 (16)0.0059 (17)0.0058 (15)
O220.011 (2)0.0193 (18)0.0131 (19)0.0003 (15)0.0030 (16)0.0037 (14)
O310.011 (2)0.0218 (18)0.016 (2)0.0002 (15)0.0018 (16)0.0035 (15)
O320.011 (2)0.0182 (18)0.0146 (19)0.0010 (15)0.0046 (16)0.0030 (14)
N10.012 (3)0.031 (3)0.016 (2)0.002 (2)0.001 (2)0.0092 (19)
N20.013 (2)0.031 (3)0.015 (2)0.000 (2)0.0005 (19)0.008 (2)
N30.013 (2)0.019 (2)0.011 (2)0.0008 (18)0.0059 (19)0.0038 (17)
C10.015 (3)0.012 (2)0.015 (3)0.002 (2)0.003 (2)0.0002 (19)
C110.019 (3)0.021 (3)0.013 (3)0.005 (2)0.000 (2)0.003 (2)
C120.021 (3)0.030 (3)0.018 (3)0.010 (3)0.003 (2)0.011 (3)
C130.022 (3)0.033 (3)0.016 (3)0.016 (3)0.002 (3)0.004 (2)
C140.038 (4)0.027 (3)0.027 (4)0.011 (3)0.001 (3)0.004 (3)
C210.013 (3)0.016 (3)0.012 (3)0.0000 (19)0.004 (2)0.0010 (18)
C220.014 (3)0.012 (2)0.017 (3)0.006 (2)0.005 (2)0.004 (2)
C230.018 (3)0.023 (3)0.019 (3)0.000 (2)0.009 (2)0.004 (2)
C240.018 (3)0.021 (2)0.010 (3)0.004 (2)0.005 (2)0.002 (2)
C310.012 (3)0.014 (2)0.010 (3)0.0032 (19)0.005 (2)0.0015 (18)
C320.018 (3)0.018 (2)0.013 (3)0.001 (2)0.004 (2)0.004 (2)
C330.041 (4)0.024 (3)0.026 (4)0.015 (3)0.002 (3)0.005 (2)
C340.018 (3)0.023 (3)0.017 (3)0.005 (2)0.001 (2)0.008 (2)
Geometric parameters (Å, º) top
Am1—O11.749 (4)C12—C141.517 (8)
Am1—O21.740 (4)C12—H12A1.0000
Am1—O112.421 (4)C13—C141.471 (9)
Am1—O122.488 (4)C13—H13A0.9900
Am1—O212.461 (4)C13—H13B0.9900
Am1—O222.451 (4)C14—H14A0.9900
Am1—O312.464 (4)C14—H14B0.9900
Am1—O322.483 (3)C21—C221.469 (7)
O11—C111.263 (6)C22—C241.526 (7)
O12—C111.275 (7)C22—C231.527 (7)
O21—C211.274 (6)C22—H22A1.0000
O22—C211.273 (6)C23—C241.491 (8)
O31—C311.272 (6)C23—H23A0.9900
O32—C311.270 (6)C23—H23B0.9900
N1—C11.331 (6)C24—H24A0.9900
N1—H1A0.8800C24—H24B0.9900
N1—H1B0.8800C31—C321.479 (7)
N2—C11.327 (7)C32—C331.503 (8)
N2—H2A0.8800C32—C341.512 (8)
N2—H2B0.8800C32—H32A1.0000
N3—C11.321 (7)C33—C341.483 (8)
N3—H3A0.8800C33—H33A0.9900
N3—H3B0.8800C33—H33B0.9900
C11—C121.486 (8)C34—H34A0.9900
C12—C131.500 (9)C34—H34B0.9900
O1—Am1—O2178.85 (18)C14—C13—C1261.4 (4)
O2—Am1—O1192.93 (17)C14—C13—H13A117.6
O1—Am1—O1187.97 (17)C12—C13—H13A117.6
O2—Am1—O2286.99 (16)C14—C13—H13B117.6
O1—Am1—O2292.05 (16)C12—C13—H13B117.6
O11—Am1—O22174.70 (12)H13A—C13—H13B114.7
O2—Am1—O2188.88 (16)C13—C14—C1260.3 (4)
O1—Am1—O2190.04 (16)C13—C14—H14A117.7
O11—Am1—O21121.77 (12)C12—C14—H14A117.7
O11—Am1—O1253.09 (12)C13—C14—H14B117.7
O21—Am1—O2252.93 (12)C12—C14—H14B117.7
O31—Am1—O3252.55 (12)H14A—C14—H14B114.9
O11—Am1—O3266.94 (12)O22—C21—O21118.5 (5)
O22—Am1—O3166.72 (12)O22—C21—C22119.5 (5)
O21—Am1—O1268.81 (13)O21—C21—C22121.9 (4)
O2—Am1—O3191.69 (15)C21—C22—C24117.8 (5)
O1—Am1—O3188.51 (15)C21—C22—C23119.2 (4)
O11—Am1—O31118.57 (12)C24—C22—C2358.5 (3)
O21—Am1—O31119.54 (13)C21—C22—H22A116.3
O2—Am1—O3285.04 (15)C24—C22—H22A116.3
O1—Am1—O3295.97 (15)C23—C22—H22A116.3
O22—Am1—O32118.31 (12)C24—C23—C2260.7 (4)
O21—Am1—O32169.72 (11)C24—C23—H23A117.7
O2—Am1—O1288.61 (16)C22—C23—H23A117.7
O1—Am1—O1291.35 (16)C24—C23—H23B117.7
O22—Am1—O12121.62 (12)C22—C23—H23B117.7
O31—Am1—O12171.65 (13)H23A—C23—H23B114.8
O32—Am1—O12119.21 (13)C23—C24—C2260.8 (3)
C11—O11—Am195.2 (3)C23—C24—H24A117.7
C11—O12—Am191.7 (3)C22—C24—H24A117.7
C21—O21—Am193.7 (3)C23—C24—H24B117.7
C21—O22—Am194.2 (3)C22—C24—H24B117.7
C31—O31—Am194.3 (3)H24A—C24—H24B114.8
C31—O32—Am193.4 (3)O32—C31—O31119.0 (4)
C1—N1—H1A120.0O32—C31—C32121.8 (5)
C1—N1—H1B120.0O31—C31—C32119.2 (5)
H1A—N1—H1B120.0C31—C32—C33118.1 (5)
C1—N2—H2A120.0C31—C32—C34120.7 (5)
C1—N2—H2B120.0C33—C32—C3458.9 (4)
H2A—N2—H2B120.0C31—C32—H32A115.7
C1—N3—H3A120.0C33—C32—H32A115.7
C1—N3—H3B120.0C34—C32—H32A115.7
H3A—N3—H3B120.0C34—C33—C3260.8 (4)
N3—C1—N2119.8 (5)C34—C33—H33A117.7
N3—C1—N1121.2 (5)C32—C33—H33A117.7
N2—C1—N1119.0 (5)C34—C33—H33B117.7
O11—C11—O12119.7 (5)C32—C33—H33B117.7
O11—C11—C12120.3 (5)H33A—C33—H33B114.8
O12—C11—C12119.9 (5)C33—C34—C3260.2 (4)
C11—C12—C13118.7 (5)C33—C34—H34A117.7
C11—C12—C14117.2 (5)C32—C34—H34A117.7
C13—C12—C1458.3 (4)C33—C34—H34B117.7
C11—C12—H12A116.6C32—C34—H34B117.7
C13—C12—H12A116.6H34A—C34—H34B114.9
C14—C12—H12A116.6
O2—Am1—O11—C1189.4 (4)O22—Am1—O32—C317.1 (3)
O1—Am1—O11—C1189.9 (4)O21—Am1—O32—C3137.0 (8)
O21—Am1—O11—C111.1 (4)O31—Am1—O32—C315.0 (3)
O31—Am1—O11—C11177.1 (3)O12—Am1—O32—C31176.6 (3)
O32—Am1—O11—C11172.7 (4)Am1—O11—C11—O126.0 (6)
O12—Am1—O11—C113.3 (3)Am1—O11—C11—C12172.1 (5)
O2—Am1—O12—C1198.0 (3)Am1—O12—C11—O115.8 (5)
O1—Am1—O12—C1183.1 (3)Am1—O12—C11—C12172.3 (5)
O11—Am1—O12—C113.3 (3)O11—C11—C12—C1317.0 (9)
O22—Am1—O12—C11176.4 (3)O12—C11—C12—C13165.0 (5)
O21—Am1—O12—C11172.7 (3)O11—C11—C12—C1450.0 (8)
O32—Am1—O12—C1114.5 (4)O12—C11—C12—C14128.1 (6)
O2—Am1—O21—C2182.5 (3)C11—C12—C13—C14106.0 (6)
O1—Am1—O21—C2197.1 (3)C11—C12—C14—C13108.5 (6)
O11—Am1—O21—C21175.3 (3)Am1—O22—C21—O218.0 (5)
O22—Am1—O21—C214.6 (3)Am1—O22—C21—C22169.3 (4)
O31—Am1—O21—C218.8 (3)Am1—O21—C21—O228.0 (5)
O32—Am1—O21—C2128.8 (9)Am1—O21—C21—C22169.3 (4)
O12—Am1—O21—C21171.5 (3)O22—C21—C22—C24145.8 (5)
O2—Am1—O22—C2186.3 (3)O21—C21—C22—C2431.4 (7)
O1—Am1—O22—C2193.1 (3)O22—C21—C22—C23146.7 (5)
O21—Am1—O22—C214.6 (3)O21—C21—C22—C2336.0 (8)
O31—Am1—O22—C21179.4 (3)C21—C22—C23—C24106.4 (6)
O32—Am1—O22—C21169.0 (3)C21—C22—C24—C23108.9 (5)
O12—Am1—O22—C210.2 (3)Am1—O32—C31—O318.8 (5)
O2—Am1—O31—C3177.4 (3)Am1—O32—C31—C32168.6 (4)
O1—Am1—O31—C31103.7 (3)Am1—O31—C31—O328.9 (5)
O11—Am1—O31—C3116.8 (3)Am1—O31—C31—C32168.6 (4)
O22—Am1—O31—C31163.4 (3)O32—C31—C32—C3339.8 (7)
O21—Am1—O31—C31167.1 (3)O31—C31—C32—C33137.7 (5)
O32—Am1—O31—C315.0 (3)O32—C31—C32—C3428.9 (8)
O2—Am1—O32—C3190.9 (3)O31—C31—C32—C34153.6 (5)
O1—Am1—O32—C3188.5 (3)C31—C32—C33—C34110.7 (5)
O11—Am1—O32—C31173.7 (3)C31—C32—C34—C33106.4 (6)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1A···O22i0.882.192.922 (6)140
N2—H2A···O210.882.042.874 (6)157
N2—H2B···O32ii0.882.042.876 (6)159
N3—H3A···O120.882.032.904 (6)171
N3—H3B···O31i0.882.122.977 (6)164
Symmetry codes: (i) x+1/2, y+3/2, z+1/2; (ii) x1/2, y+3/2, z+1/2.
 

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