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metal-organic compounds
In the crystal structure of the title compound, [Sn2(C6H5)6(C4H4O4)(H2O)2]·2C12H8N2, each Sn atom in the centrosymmetric μ-succinato-bis(aquatriphenyltin) molecule interacts with an o-phenanthroline indirectly through the coordinated water molecule [SnOwater = 2.612 (1) Å], which forms a short hydrogen bond with one of the o-phenanthroline N atoms [OwaterN = 2.899 (2) Å]; the five-coordinate Sn atom shows trans–C3SnO2 trigonal bipyramidal coordination. The weak hydrogen bond involving the second H atom of the water molecule and the carbonyl O atom of an adjacent molecule of μ-succinato-bis(aquatriphenyltin) [OOi = 3.123 (2) Å; symmetry code: (i) x, ½ − y, ½ + z] links the molecules into infinite layers parallel to the bc plane of the crystal.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802022213/ya6143sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802022213/ya6143Isup2.hkl |
CCDC reference: 202976
Key indicators
- Single-crystal X-ray study
- T = 168 K
- Mean (C-C) = 0.002 Å
- R factor = 0.017
- wR factor = 0.048
- Data-to-parameter ratio = 15.1
checkCIF results
No syntax errors found ADDSYM reports no extra symmetry
Alert Level C:
PLAT_702 Alert C Angle Calc 117.23(5), Rep 117.30(10), Dev. 1.40 Sigma C1 -SN1 -C13 1.555 1.555 1.555
0 Alert Level A = Potentially serious problem
0 Alert Level B = Potential problem
1 Alert Level C = Please check
Computing details top
Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
µ-Succinato-bis(aquatriphenyltin) bis(o-phenanthroline) top
Crystal data top
[Sn2(C6H5)6(H2O)2]·2C12H8N2 | F(000) = 1228 |
Mr = 1212.49 | Dx = 1.535 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
a = 13.5958 (8) Å | Cell parameters from 7254 reflections |
b = 13.6077 (8) Å | θ = 2.1–26.4° |
c = 14.4444 (9) Å | µ = 1.01 mm−1 |
β = 101.014 (1)° | T = 168 K |
V = 2623.1 (3) Å3 | Block, colorless |
Z = 2 | 0.50 × 0.45 × 0.20 mm |
Data collection top
Bruker CCD area-detector diffractometer | 5303 independent reflections |
Radiation source: fine-focus sealed tube | 4570 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.026 |
ω scans | θmax = 26.4°, θmin = 2.1° |
Absorption correction: empirical (SADABS; Sheldrick, 1996) | h = −16→16 |
Tmin = 0.632, Tmax = 0.823 | k = −16→16 |
33422 measured reflections | l = −15→17 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.017 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.048 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.02 | w = 1/[σ2(Fo2) + (0.0316P)2] where P = (Fo2 + 2Fc2)/3 |
5303 reflections | (Δ/σ)max = 0.001 |
351 parameters | Δρmax = 0.27 e Å−3 |
2 restraints | Δρmin = −0.44 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Sn1 | 0.628173 (8) | 0.299052 (8) | 0.780640 (7) | 0.01809 (4) | |
O1 | 0.5309 (1) | 0.3859 (1) | 0.6818 (1) | 0.0231 (2) | |
O2 | 0.6431 (1) | 0.3986 (1) | 0.5878 (1) | 0.0280 (3) | |
O1w | 0.7256 (1) | 0.1950 (1) | 0.9205 (1) | 0.0263 (3) | |
N1 | 0.9258 (1) | 0.1270 (1) | 0.9120 (1) | 0.0215 (3) | |
N2 | 0.9625 (1) | 0.1966 (1) | 1.0940 (1) | 0.0258 (3) | |
C1 | 0.5117 (1) | 0.2760 (1) | 0.8576 (1) | 0.0193 (3) | |
C2 | 0.4255 (1) | 0.2241 (1) | 0.8189 (1) | 0.0251 (4) | |
C3 | 0.3479 (1) | 0.2115 (1) | 0.8681 (1) | 0.0306 (4) | |
C4 | 0.3550 (1) | 0.2534 (1) | 0.9562 (1) | 0.0324 (4) | |
C5 | 0.4400 (2) | 0.3054 (1) | 0.9958 (1) | 0.0334 (4) | |
C6 | 0.5182 (1) | 0.3163 (1) | 0.9475 (1) | 0.0265 (4) | |
C7 | 0.6653 (1) | 0.1787 (1) | 0.7006 (1) | 0.0197 (3) | |
C8 | 0.7319 (1) | 0.1894 (1) | 0.6390 (1) | 0.0240 (4) | |
C9 | 0.7618 (1) | 0.1083 (1) | 0.5929 (1) | 0.0310 (4) | |
C10 | 0.7238 (2) | 0.0165 (1) | 0.6061 (1) | 0.0351 (5) | |
C11 | 0.6562 (1) | 0.0045 (1) | 0.6659 (1) | 0.0316 (4) | |
C12 | 0.6284 (1) | 0.0849 (1) | 0.7142 (1) | 0.0251 (4) | |
C13 | 0.7351 (1) | 0.4102 (1) | 0.8305 (1) | 0.0206 (3) | |
C14 | 0.8366 (1) | 0.3899 (1) | 0.8649 (1) | 0.0241 (4) | |
C15 | 0.9027 (1) | 0.4652 (1) | 0.8981 (1) | 0.0302 (4) | |
C16 | 0.8700 (2) | 0.5614 (1) | 0.8982 (1) | 0.0339 (4) | |
C17 | 0.7696 (2) | 0.5827 (1) | 0.8639 (1) | 0.0328 (4) | |
C18 | 0.7031 (1) | 0.5079 (1) | 0.8309 (1) | 0.0276 (4) | |
C19 | 0.5607 (1) | 0.4179 (1) | 0.6065 (1) | 0.0205 (3) | |
C20 | 0.4842 (1) | 0.4816 (1) | 0.5443 (1) | 0.0227 (4) | |
C21 | 0.9097 (1) | 0.0891 (1) | 0.8264 (1) | 0.0244 (4) | |
C22 | 0.9827 (1) | 0.0426 (1) | 0.7859 (1) | 0.0260 (4) | |
C23 | 1.0775 (1) | 0.0324 (1) | 0.8377 (1) | 0.0253 (4) | |
C24 | 1.0982 (1) | 0.0690 (1) | 0.9305 (1) | 0.0211 (3) | |
C25 | 1.1947 (1) | 0.0570 (1) | 0.9899 (1) | 0.0253 (4) | |
C26 | 1.2131 (1) | 0.0910 (1) | 1.0790 (1) | 0.0260 (4) | |
C27 | 1.1358 (1) | 0.1399 (1) | 1.1168 (1) | 0.0235 (4) | |
C28 | 1.1512 (1) | 0.1721 (1) | 1.2108 (1) | 0.0290 (4) | |
C29 | 1.0740 (2) | 0.2141 (1) | 1.2442 (1) | 0.0328 (4) | |
C30 | 0.9814 (1) | 0.2248 (1) | 1.1831 (1) | 0.0309 (4) | |
C31 | 1.0394 (1) | 0.1534 (1) | 1.0610 (1) | 0.0206 (3) | |
C32 | 1.0202 (1) | 0.1169 (1) | 0.9647 (1) | 0.0195 (3) | |
H1w1 | 0.786 (1) | 0.179 (2) | 0.931 (2) | 0.041 (6)* | |
H1w2 | 0.699 (2) | 0.170 (2) | 0.963 (1) | 0.054 (7)* | |
H2 | 0.4196 | 0.1967 | 0.7576 | 0.030* | |
H3 | 0.2903 | 0.1744 | 0.8412 | 0.037* | |
H4 | 0.3016 | 0.2464 | 0.9895 | 0.039* | |
H5 | 0.4448 | 0.3338 | 1.0566 | 0.040* | |
H6 | 0.5766 | 0.3516 | 0.9757 | 0.032* | |
H8 | 0.7571 | 0.2527 | 0.6285 | 0.029* | |
H9 | 0.8084 | 0.1161 | 0.5521 | 0.037* | |
H10 | 0.7440 | −0.0387 | 0.5741 | 0.042* | |
H11 | 0.6289 | −0.0586 | 0.6737 | 0.038* | |
H12 | 0.5839 | 0.0761 | 0.7568 | 0.030* | |
H14 | 0.8603 | 0.3242 | 0.8654 | 0.029* | |
H15 | 0.9714 | 0.4504 | 0.9210 | 0.036* | |
H16 | 0.9157 | 0.6125 | 0.9215 | 0.041* | |
H17 | 0.7467 | 0.6486 | 0.8632 | 0.039* | |
H18 | 0.6346 | 0.5232 | 0.8081 | 0.033* | |
H20a | 0.4213 | 0.4436 | 0.5261 | 0.027* | |
H20b | 0.4693 | 0.5390 | 0.5815 | 0.027* | |
H21 | 0.8439 | 0.0937 | 0.7898 | 0.029* | |
H22 | 0.9667 | 0.0183 | 0.7231 | 0.031* | |
H23 | 1.1284 | 0.0012 | 0.8114 | 0.030* | |
H25 | 1.2465 | 0.0246 | 0.9660 | 0.030* | |
H26 | 1.2776 | 0.0826 | 1.1172 | 0.031* | |
H28 | 1.2149 | 0.1645 | 1.2508 | 0.035* | |
H29 | 1.0828 | 0.2358 | 1.3078 | 0.039* | |
H30 | 0.9284 | 0.2545 | 1.2074 | 0.037* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.01672 (6) | 0.01943 (6) | 0.01804 (7) | −0.00052 (4) | 0.00312 (4) | 0.00068 (4) |
O1 | 0.024 (1) | 0.028 (1) | 0.018 (1) | 0.001 (1) | 0.004 (1) | 0.007 (1) |
O2 | 0.020 (1) | 0.034 (1) | 0.031 (1) | 0.004 (1) | 0.006 (1) | 0.011 (1) |
O1w | 0.022 (1) | 0.034 (1) | 0.023 (1) | 0.007 (1) | 0.003 (1) | 0.006 (1) |
N1 | 0.020 (1) | 0.021 (1) | 0.023 (1) | 0.001 (1) | 0.004 (1) | 0.004 (1) |
N2 | 0.025 (1) | 0.023 (1) | 0.030 (1) | 0.004 (1) | 0.005 (1) | −0.003 (1) |
C1 | 0.018 (1) | 0.020 (1) | 0.021 (1) | 0.005 (1) | 0.003 (1) | 0.007 (1) |
C2 | 0.026 (1) | 0.024 (1) | 0.025 (1) | −0.001 (1) | 0.003 (1) | 0.001 (1) |
C3 | 0.020 (1) | 0.030 (1) | 0.042 (1) | −0.003 (1) | 0.005 (1) | 0.007 (1) |
C4 | 0.029 (1) | 0.036 (1) | 0.036 (1) | 0.002 (1) | 0.015 (1) | 0.011 (1) |
C5 | 0.035 (1) | 0.045 (1) | 0.022 (1) | 0.003 (1) | 0.009 (1) | 0.001 (1) |
C6 | 0.021 (1) | 0.034 (1) | 0.022 (1) | −0.001 (1) | 0.000 (1) | 0.002 (1) |
C7 | 0.019 (1) | 0.022 (1) | 0.016 (1) | 0.002 (1) | −0.002 (1) | 0.001 (1) |
C8 | 0.024 (1) | 0.029 (1) | 0.018 (1) | 0.004 (1) | 0.001 (1) | 0.005 (1) |
C9 | 0.031 (1) | 0.044 (1) | 0.018 (1) | 0.011 (1) | 0.004 (1) | 0.001 (1) |
C10 | 0.040 (1) | 0.035 (1) | 0.026 (1) | 0.012 (1) | −0.003 (1) | −0.011 (1) |
C11 | 0.034 (1) | 0.023 (1) | 0.034 (1) | 0.001 (1) | −0.004 (1) | −0.004 (1) |
C12 | 0.021 (1) | 0.028 (1) | 0.026 (1) | −0.002 (1) | 0.001 (1) | 0.001 (1) |
C13 | 0.022 (1) | 0.025 (1) | 0.016 (1) | −0.003 (1) | 0.004 (1) | 0.001 (1) |
C14 | 0.024 (1) | 0.029 (1) | 0.020 (1) | −0.001 (1) | 0.004 (1) | 0.003 (1) |
C15 | 0.023 (1) | 0.045 (1) | 0.022 (1) | −0.009 (1) | 0.001 (1) | 0.004 (1) |
C16 | 0.039 (1) | 0.037 (1) | 0.024 (1) | −0.018 (1) | 0.003 (1) | −0.002 (1) |
C17 | 0.044 (1) | 0.023 (1) | 0.031 (1) | −0.005 (1) | 0.006 (1) | 0.000 (1) |
C18 | 0.027 (1) | 0.027 (1) | 0.027 (1) | 0.001 (1) | 0.003 (1) | 0.001 (1) |
C19 | 0.021 (1) | 0.019 (1) | 0.020 (1) | −0.004 (1) | 0.001 (1) | 0.001 (1) |
C20 | 0.019 (1) | 0.027 (1) | 0.022 (1) | 0.003 (1) | 0.003 (1) | 0.005 (1) |
C21 | 0.024 (1) | 0.024 (1) | 0.024 (1) | −0.001 (1) | 0.002 (1) | 0.005 (1) |
C22 | 0.032 (1) | 0.025 (1) | 0.021 (1) | −0.002 (1) | 0.008 (1) | 0.001 (1) |
C23 | 0.027 (1) | 0.022 (1) | 0.031 (1) | 0.002 (1) | 0.014 (1) | 0.004 (1) |
C24 | 0.022 (1) | 0.016 (1) | 0.027 (1) | 0.000 (1) | 0.009 (1) | 0.005 (1) |
C25 | 0.019 (1) | 0.024 (1) | 0.036 (1) | 0.002 (1) | 0.010 (1) | 0.007 (1) |
C26 | 0.017 (1) | 0.025 (1) | 0.035 (1) | 0.001 (1) | 0.003 (1) | 0.007 (1) |
C27 | 0.022 (1) | 0.019 (1) | 0.029 (1) | −0.003 (1) | 0.003 (1) | 0.004 (1) |
C28 | 0.028 (1) | 0.024 (1) | 0.031 (1) | −0.002 (1) | −0.003 (1) | 0.000 (1) |
C29 | 0.043 (1) | 0.025 (1) | 0.029 (1) | 0.000 (1) | 0.003 (1) | −0.006 (1) |
C30 | 0.032 (1) | 0.027 (1) | 0.034 (1) | 0.004 (1) | 0.009 (1) | −0.007 (1) |
C31 | 0.021 (1) | 0.015 (1) | 0.026 (1) | 0.000 (1) | 0.006 (1) | 0.003 (1) |
C32 | 0.020 (1) | 0.016 (1) | 0.024 (1) | −0.001 (1) | 0.006 (1) | 0.005 (1) |
Geometric parameters (Å, º) top
Sn1—O1 | 2.113 (1) | C24—C25 | 1.434 (2) |
Sn1—O1w | 2.612 (1) | C25—C26 | 1.345 (2) |
Sn1—C1 | 2.124 (2) | C26—C27 | 1.436 (2) |
Sn1—C7 | 2.121 (2) | C27—C28 | 1.404 (2) |
Sn1—C13 | 2.125 (2) | C27—C31 | 1.414 (2) |
O1—C19 | 1.305 (2) | C28—C29 | 1.363 (3) |
O2—C19 | 1.230 (2) | C29—C30 | 1.401 (3) |
N1—C21 | 1.320 (2) | C31—C32 | 1.452 (2) |
N1—C32 | 1.369 (2) | O1w—H1w1 | 0.83 (1) |
N2—C30 | 1.320 (2) | O1w—H1w2 | 0.84 (1) |
N2—C31 | 1.363 (2) | C2—H2 | 0.9500 |
C1—C2 | 1.390 (2) | C3—H3 | 0.9500 |
C1—C6 | 1.397 (2) | C4—H4 | 0.9500 |
C2—C3 | 1.391 (2) | C5—H5 | 0.9500 |
C3—C4 | 1.381 (3) | C6—H6 | 0.9500 |
C4—C5 | 1.382 (3) | C8—H8 | 0.9500 |
C5—C6 | 1.388 (3) | C9—H9 | 0.9500 |
C7—C8 | 1.393 (2) | C10—H10 | 0.9500 |
C7—C12 | 1.399 (2) | C11—H11 | 0.9500 |
C8—C9 | 1.390 (2) | C12—H12 | 0.9500 |
C9—C10 | 1.379 (3) | C14—H14 | 0.9500 |
C10—C11 | 1.386 (3) | C15—H15 | 0.9500 |
C11—C12 | 1.388 (2) | C16—H16 | 0.9500 |
C13—C18 | 1.399 (2) | C17—H17 | 0.9500 |
C13—C14 | 1.402 (2) | C18—H18 | 0.9500 |
C14—C15 | 1.386 (2) | C20—H20a | 0.9900 |
C15—C16 | 1.383 (3) | C20—H20b | 0.9900 |
C16—C17 | 1.390 (3) | C21—H21 | 0.9500 |
C17—C18 | 1.384 (2) | C22—H22 | 0.9500 |
C19—C20 | 1.512 (2) | C23—H23 | 0.9500 |
C20—C20i | 1.511 (3) | C25—H25 | 0.9500 |
C21—C22 | 1.396 (2) | C26—H26 | 0.9500 |
C22—C23 | 1.368 (2) | C28—H28 | 0.9500 |
C23—C24 | 1.408 (2) | C29—H29 | 0.9500 |
C24—C32 | 1.412 (2) | C30—H30 | 0.9500 |
C1—Sn1—C7 | 116.7 (1) | N1—C32—C24 | 122.6 (2) |
C1—Sn1—C13 | 117.3 (1) | N1—C32—C31 | 118.5 (1) |
C1—Sn1—O1 | 90.2 (1) | C24—C32—C31 | 118.9 (1) |
C1—Sn1—O1w | 80.4 (1) | Sn1—O1w—H1w1 | 128 (2) |
C7—Sn1—C13 | 121.0 (1) | Sn1—O1w—H1w2 | 123 (2) |
C7—Sn1—O1 | 104.3 (1) | H1w1—O1w—H1w2 | 108 (2) |
C7—Sn1—O1w | 82.2 (1) | C1—C2—H2 | 119.3 |
C13—Sn1—O1 | 97.5 (1) | C3—C2—H2 | 119.3 |
C13—Sn1—O1w | 84.9 (1) | C4—C3—H3 | 120.2 |
O1—Sn1—O1w | 170.3 (1) | C2—C3—H3 | 120.2 |
C19—O1—Sn1 | 119.7 (1) | C3—C4—H4 | 120.0 |
C21—N1—C32 | 116.9 (1) | C5—C4—H4 | 120.0 |
C30—N2—C31 | 116.6 (2) | C4—C5—H5 | 119.8 |
C2—C1—C6 | 118.1 (2) | C6—C5—H5 | 119.8 |
C2—C1—Sn1 | 121.3 (1) | C5—C6—H6 | 119.8 |
C6—C1—Sn1 | 120.5 (1) | C1—C6—H6 | 119.8 |
C1—C2—C3 | 121.4 (2) | C9—C8—H8 | 119.7 |
C4—C3—C2 | 119.5 (2) | C7—C8—H8 | 119.7 |
C3—C4—C5 | 120.0 (2) | C10—C9—H9 | 119.9 |
C4—C5—C6 | 120.4 (2) | C8—C9—H9 | 119.9 |
C5—C6—C1 | 120.5 (2) | C9—C10—H10 | 119.9 |
C8—C7—C12 | 118.7 (2) | C11—C10—H10 | 119.9 |
C8—C7—Sn1 | 121.2 (1) | C10—C11—H11 | 120.1 |
C12—C7—Sn1 | 120.0 (1) | C12—C11—H11 | 120.1 |
C9—C8—C7 | 120.5 (2) | C11—C12—H12 | 119.7 |
C10—C9—C8 | 120.1 (2) | C7—C12—H12 | 119.7 |
C9—C10—C11 | 120.3 (2) | C15—C14—H14 | 119.8 |
C10—C11—C12 | 119.8 (2) | C13—C14—H14 | 119.8 |
C11—C12—C7 | 120.6 (2) | C16—C15—H15 | 119.6 |
C18—C13—C14 | 118.1 (2) | C14—C15—H15 | 119.6 |
C18—C13—Sn1 | 119.0 (1) | C15—C16—H16 | 120.3 |
C14—C13—Sn1 | 122.9 (1) | C17—C16—H16 | 120.3 |
C15—C14—C13 | 120.4 (2) | C18—C17—H17 | 119.9 |
C16—C15—C14 | 120.8 (2) | C16—C17—H17 | 119.9 |
C15—C16—C17 | 119.4 (2) | C17—C18—H18 | 119.4 |
C18—C17—C16 | 120.1 (2) | C13—C18—H18 | 119.4 |
C17—C18—C13 | 121.2 (2) | C20i—C20—H20a | 108.6 |
O2—C19—O1 | 123.6 (2) | C19—C20—H20a | 108.6 |
O2—C19—C20 | 122.9 (1) | C20i—C20—H20b | 108.6 |
O1—C19—C20 | 113.5 (1) | C19—C20—H20b | 108.6 |
C20i—C20—C19 | 114.7 (2) | H20a—C20—H20b | 107.6 |
N1—C21—C22 | 124.5 (2) | N1—C21—H21 | 117.8 |
C23—C22—C21 | 119.2 (2) | C22—C21—H21 | 117.8 |
C22—C23—C24 | 118.8 (2) | C23—C22—H22 | 120.4 |
C23—C24—C32 | 118.0 (2) | C21—C22—H22 | 120.4 |
C23—C24—C25 | 121.6 (2) | C22—C23—H23 | 120.6 |
C32—C24—C25 | 120.4 (2) | C24—C23—H23 | 120.6 |
C26—C25—C24 | 121.0 (2) | C26—C25—H25 | 119.5 |
C25—C26—C27 | 120.5 (2) | C24—C25—H25 | 119.5 |
C28—C27—C31 | 117.5 (2) | C25—C26—H26 | 119.7 |
C28—C27—C26 | 121.8 (2) | C27—C26—H26 | 119.7 |
C31—C27—C26 | 120.6 (2) | C29—C28—H28 | 120.3 |
C29—C28—C27 | 119.4 (2) | C27—C28—H28 | 120.3 |
C28—C29—C30 | 118.8 (2) | C28—C29—H29 | 120.6 |
N2—C30—C29 | 124.6 (2) | C30—C29—H29 | 120.6 |
N2—C31—C27 | 123.1 (2) | N2—C30—H30 | 117.7 |
N2—C31—C32 | 118.2 (1) | C29—C30—H30 | 117.7 |
C27—C31—C32 | 118.7 (2) | ||
C7—Sn1—O1—C19 | −56.6 (1) | C18—C13—C14—C15 | 0.0 (2) |
C1—Sn1—O1—C19 | −174.3 (1) | Sn1—C13—C14—C15 | −178.9 (1) |
C13—Sn1—O1—C19 | 68.2 (1) | C13—C14—C15—C16 | 0.2 (3) |
O1—Sn1—C1—C2 | 65.1 (1) | C14—C15—C16—C17 | −0.4 (3) |
C7—Sn1—C1—C2 | −41.1 (1) | C15—C16—C17—C18 | 0.6 (3) |
C13—Sn1—C1—C2 | 163.6 (1) | C16—C17—C18—C13 | −0.5 (3) |
O1w—Sn1—C1—C2 | −117.3 (1) | C14—C13—C18—C17 | 0.2 (2) |
O1—Sn1—C1—C6 | −112.3 (1) | Sn1—C13—C18—C17 | 179.1 (1) |
C7—Sn1—C1—C6 | 141.6 (1) | Sn1—O1—C19—O2 | 1.6 (2) |
C13—Sn1—C1—C6 | −13.7 (2) | Sn1—O1—C19—C20 | −178.1 (1) |
O1w—Sn1—C1—C6 | 65.4 (1) | O2—C19—C20—C20i | 1.3 (3) |
C6—C1—C2—C3 | −0.6 (2) | O1—C19—C20—C20i | −179.0 (2) |
Sn1—C1—C2—C3 | −178.0 (1) | C32—N1—C21—C22 | −1.9 (2) |
C1—C2—C3—C4 | 1.6 (3) | N1—C21—C22—C23 | 1.7 (3) |
C2—C3—C4—C5 | −1.5 (3) | C21—C22—C23—C24 | 0.2 (2) |
C3—C4—C5—C6 | 0.3 (3) | C22—C23—C24—C32 | −1.6 (2) |
C4—C5—C6—C1 | 0.8 (3) | C22—C23—C24—C25 | 177.3 (2) |
C2—C1—C6—C5 | −0.6 (2) | C23—C24—C25—C26 | −179.0 (2) |
Sn1—C1—C6—C5 | 176.8 (1) | C32—C24—C25—C26 | 0.0 (2) |
O1—Sn1—C7—C8 | 74.7 (1) | C24—C25—C26—C27 | 0.2 (3) |
C1—Sn1—C7—C8 | 172.3 (1) | C25—C26—C27—C28 | 176.9 (2) |
C13—Sn1—C7—C8 | −33.4 (2) | C25—C26—C27—C31 | −0.2 (2) |
O1w—Sn1—C7—C8 | −112.6 (1) | C31—C27—C28—C29 | 0.1 (2) |
O1—Sn1—C7—C12 | −110.0 (1) | C26—C27—C28—C29 | −177.1 (2) |
C1—Sn1—C7—C12 | −12.4 (1) | C27—C28—C29—C30 | −0.6 (3) |
C13—Sn1—C7—C12 | 142.0 (1) | C31—N2—C30—C29 | 0.6 (3) |
O1w—Sn1—C7—C12 | 62.8 (1) | C28—C29—C30—N2 | 0.2 (3) |
C12—C7—C8—C9 | −0.7 (2) | C30—N2—C31—C27 | −1.1 (2) |
Sn1—C7—C8—C9 | 174.8 (1) | C30—N2—C31—C32 | 177.0 (2) |
C7—C8—C9—C10 | 1.5 (2) | C28—C27—C31—N2 | 0.7 (2) |
C8—C9—C10—C11 | −0.4 (3) | C26—C27—C31—N2 | 178.0 (2) |
C9—C10—C11—C12 | −1.5 (3) | C28—C27—C31—C32 | −177.3 (2) |
C10—C11—C12—C7 | 2.2 (2) | C26—C27—C31—C32 | 0.0 (2) |
C8—C7—C12—C11 | −1.2 (2) | C21—N1—C32—C24 | 0.3 (2) |
Sn1—C7—C12—C11 | −176.7 (1) | C21—N1—C32—C31 | −177.0 (1) |
O1—Sn1—C13—C18 | 30.6 (1) | C23—C24—C32—N1 | 1.4 (2) |
C7—Sn1—C13—C18 | 142.3 (1) | C25—C24—C32—N1 | −177.6 (2) |
C1—Sn1—C13—C18 | −63.5 (1) | C23—C24—C32—C31 | 178.8 (2) |
O1w—Sn1—C13—C18 | −140.0 (1) | C25—C24—C32—C31 | −0.2 (2) |
O1—Sn1—C13—C14 | −150.6 (1) | N2—C31—C32—N1 | −0.4 (2) |
C7—Sn1—C13—C14 | −38.9 (2) | C27—C31—C32—N1 | 177.7 (1) |
C1—Sn1—C13—C14 | 115.3 (1) | N2—C31—C32—C24 | −177.9 (1) |
O1w—Sn1—C13—C14 | 38.8 (1) | C27—C31—C32—C24 | 0.3 (2) |
Symmetry code: (i) −x+1, −y+1, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O1w—H1w1···N1 | 0.83 (1) | 2.10 (1) | 2.899 (2) | 161 (2) |
O1w—H1w2···O2ii | 0.84 (1) | 2.29 (1) | 3.123 (2) | 173 (2) |
Symmetry code: (ii) x, −y+1/2, z+1/2. |
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