μ-Succinato-bis­(aqua­tri­phenyl­tin)bis(o-phenanthroline)

Chee, C.F.; Lo, K.M.; Ng, S.W.

doi:10.1107/S1600536802022213

μ-Succinato-bis(aquatriphenyltin)bis(o-phenanthroline)

In the crystal structure of the title compound, [Sn₂(C₆H₅)₆(C₄H₄O₄)(H₂O)₂]·2C₁₂H₈N₂, each Sn atom in the centrosymmetric μ-succinato-bis(aquatriphenyltin) molecule interacts with an o-phenanthroline indirectly through the coordinated water molecule [Sn $\leftarrow$ O_water = 2.612 (1) Å], which forms a short hydrogen bond with one of the o-phenanthroline N atoms [O_water

N = 2.899 (2) Å]; the five-coordinate Sn atom shows trans–C₃SnO₂ trigonal bipyramidal coordination. The weak hydrogen bond involving the second H atom of the water molecule and the carbonyl O atom of an adjacent molecule of μ-succinato-bis(aquatriphenyltin) [O

Oⁱ = 3.123 (2) Å; symmetry code: (i) x, ½ − y, ½ + z] links the molecules into infinite layers parallel to the bc plane of the crystal.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802022213/ya6143sup1.cif Contains datablocks I, ccf02m
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536802022213/ya6143Isup2.hkl Contains datablock I

CCDC reference: 202976

checkCIF report

Key indicators

Single-crystal X-ray study
T = 168 K
Mean (C-C) = 0.002 Å
R factor = 0.017
wR factor = 0.048
Data-to-parameter ratio = 15.1

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



PLAT_702  Alert C Angle   Calc   117.23(5), Rep  117.30(10), Dev.      1.40 Sigma
                     C1   -SN1  -C13     1.555   1.555   1.555


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 1 Alert Level C = Please check

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

µ-Succinato-bis(aquatriphenyltin) bis(o-phenanthroline) top

Crystal data top

[Sn₂(C₆H₅)₆(H₂O)₂]·2C₁₂H₈N₂	F(000) = 1228
M_r = 1212.49	D_x = 1.535 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 13.5958 (8) Å	Cell parameters from 7254 reflections
b = 13.6077 (8) Å	θ = 2.1–26.4°
c = 14.4444 (9) Å	µ = 1.01 mm⁻¹
β = 101.014 (1)°	T = 168 K
V = 2623.1 (3) Å³	Block, colorless
Z = 2	0.50 × 0.45 × 0.20 mm

Data collection top

Bruker CCD area-detector diffractometer	5303 independent reflections
Radiation source: fine-focus sealed tube	4570 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.026
ω scans	θ_max = 26.4°, θ_min = 2.1°
Absorption correction: empirical (SADABS; Sheldrick, 1996)	h = −16→16
T_min = 0.632, T_max = 0.823	k = −16→16
33422 measured reflections	l = −15→17

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.017	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.048	H atoms treated by a mixture of independent and constrained refinement
S = 1.02	w = 1/[σ²(F_o²) + (0.0316P)²] where P = (F_o² + 2F_c²)/3
5303 reflections	(Δ/σ)_max = 0.001
351 parameters	Δρ_max = 0.27 e Å⁻³
2 restraints	Δρ_min = −0.44 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Sn1	0.628173 (8)	0.299052 (8)	0.780640 (7)	0.01809 (4)
O1	0.5309 (1)	0.3859 (1)	0.6818 (1)	0.0231 (2)
O2	0.6431 (1)	0.3986 (1)	0.5878 (1)	0.0280 (3)
O1w	0.7256 (1)	0.1950 (1)	0.9205 (1)	0.0263 (3)
N1	0.9258 (1)	0.1270 (1)	0.9120 (1)	0.0215 (3)
N2	0.9625 (1)	0.1966 (1)	1.0940 (1)	0.0258 (3)
C1	0.5117 (1)	0.2760 (1)	0.8576 (1)	0.0193 (3)
C2	0.4255 (1)	0.2241 (1)	0.8189 (1)	0.0251 (4)
C3	0.3479 (1)	0.2115 (1)	0.8681 (1)	0.0306 (4)
C4	0.3550 (1)	0.2534 (1)	0.9562 (1)	0.0324 (4)
C5	0.4400 (2)	0.3054 (1)	0.9958 (1)	0.0334 (4)
C6	0.5182 (1)	0.3163 (1)	0.9475 (1)	0.0265 (4)
C7	0.6653 (1)	0.1787 (1)	0.7006 (1)	0.0197 (3)
C8	0.7319 (1)	0.1894 (1)	0.6390 (1)	0.0240 (4)
C9	0.7618 (1)	0.1083 (1)	0.5929 (1)	0.0310 (4)
C10	0.7238 (2)	0.0165 (1)	0.6061 (1)	0.0351 (5)
C11	0.6562 (1)	0.0045 (1)	0.6659 (1)	0.0316 (4)
C12	0.6284 (1)	0.0849 (1)	0.7142 (1)	0.0251 (4)
C13	0.7351 (1)	0.4102 (1)	0.8305 (1)	0.0206 (3)
C14	0.8366 (1)	0.3899 (1)	0.8649 (1)	0.0241 (4)
C15	0.9027 (1)	0.4652 (1)	0.8981 (1)	0.0302 (4)
C16	0.8700 (2)	0.5614 (1)	0.8982 (1)	0.0339 (4)
C17	0.7696 (2)	0.5827 (1)	0.8639 (1)	0.0328 (4)
C18	0.7031 (1)	0.5079 (1)	0.8309 (1)	0.0276 (4)
C19	0.5607 (1)	0.4179 (1)	0.6065 (1)	0.0205 (3)
C20	0.4842 (1)	0.4816 (1)	0.5443 (1)	0.0227 (4)
C21	0.9097 (1)	0.0891 (1)	0.8264 (1)	0.0244 (4)
C22	0.9827 (1)	0.0426 (1)	0.7859 (1)	0.0260 (4)
C23	1.0775 (1)	0.0324 (1)	0.8377 (1)	0.0253 (4)
C24	1.0982 (1)	0.0690 (1)	0.9305 (1)	0.0211 (3)
C25	1.1947 (1)	0.0570 (1)	0.9899 (1)	0.0253 (4)
C26	1.2131 (1)	0.0910 (1)	1.0790 (1)	0.0260 (4)
C27	1.1358 (1)	0.1399 (1)	1.1168 (1)	0.0235 (4)
C28	1.1512 (1)	0.1721 (1)	1.2108 (1)	0.0290 (4)
C29	1.0740 (2)	0.2141 (1)	1.2442 (1)	0.0328 (4)
C30	0.9814 (1)	0.2248 (1)	1.1831 (1)	0.0309 (4)
C31	1.0394 (1)	0.1534 (1)	1.0610 (1)	0.0206 (3)
C32	1.0202 (1)	0.1169 (1)	0.9647 (1)	0.0195 (3)
H1w1	0.786 (1)	0.179 (2)	0.931 (2)	0.041 (6)*
H1w2	0.699 (2)	0.170 (2)	0.963 (1)	0.054 (7)*
H2	0.4196	0.1967	0.7576	0.030*
H3	0.2903	0.1744	0.8412	0.037*
H4	0.3016	0.2464	0.9895	0.039*
H5	0.4448	0.3338	1.0566	0.040*
H6	0.5766	0.3516	0.9757	0.032*
H8	0.7571	0.2527	0.6285	0.029*
H9	0.8084	0.1161	0.5521	0.037*
H10	0.7440	−0.0387	0.5741	0.042*
H11	0.6289	−0.0586	0.6737	0.038*
H12	0.5839	0.0761	0.7568	0.030*
H14	0.8603	0.3242	0.8654	0.029*
H15	0.9714	0.4504	0.9210	0.036*
H16	0.9157	0.6125	0.9215	0.041*
H17	0.7467	0.6486	0.8632	0.039*
H18	0.6346	0.5232	0.8081	0.033*
H20a	0.4213	0.4436	0.5261	0.027*
H20b	0.4693	0.5390	0.5815	0.027*
H21	0.8439	0.0937	0.7898	0.029*
H22	0.9667	0.0183	0.7231	0.031*
H23	1.1284	0.0012	0.8114	0.030*
H25	1.2465	0.0246	0.9660	0.030*
H26	1.2776	0.0826	1.1172	0.031*
H28	1.2149	0.1645	1.2508	0.035*
H29	1.0828	0.2358	1.3078	0.039*
H30	0.9284	0.2545	1.2074	0.037*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.01672 (6)	0.01943 (6)	0.01804 (7)	−0.00052 (4)	0.00312 (4)	0.00068 (4)
O1	0.024 (1)	0.028 (1)	0.018 (1)	0.001 (1)	0.004 (1)	0.007 (1)
O2	0.020 (1)	0.034 (1)	0.031 (1)	0.004 (1)	0.006 (1)	0.011 (1)
O1w	0.022 (1)	0.034 (1)	0.023 (1)	0.007 (1)	0.003 (1)	0.006 (1)
N1	0.020 (1)	0.021 (1)	0.023 (1)	0.001 (1)	0.004 (1)	0.004 (1)
N2	0.025 (1)	0.023 (1)	0.030 (1)	0.004 (1)	0.005 (1)	−0.003 (1)
C1	0.018 (1)	0.020 (1)	0.021 (1)	0.005 (1)	0.003 (1)	0.007 (1)
C2	0.026 (1)	0.024 (1)	0.025 (1)	−0.001 (1)	0.003 (1)	0.001 (1)
C3	0.020 (1)	0.030 (1)	0.042 (1)	−0.003 (1)	0.005 (1)	0.007 (1)
C4	0.029 (1)	0.036 (1)	0.036 (1)	0.002 (1)	0.015 (1)	0.011 (1)
C5	0.035 (1)	0.045 (1)	0.022 (1)	0.003 (1)	0.009 (1)	0.001 (1)
C6	0.021 (1)	0.034 (1)	0.022 (1)	−0.001 (1)	0.000 (1)	0.002 (1)
C7	0.019 (1)	0.022 (1)	0.016 (1)	0.002 (1)	−0.002 (1)	0.001 (1)
C8	0.024 (1)	0.029 (1)	0.018 (1)	0.004 (1)	0.001 (1)	0.005 (1)
C9	0.031 (1)	0.044 (1)	0.018 (1)	0.011 (1)	0.004 (1)	0.001 (1)
C10	0.040 (1)	0.035 (1)	0.026 (1)	0.012 (1)	−0.003 (1)	−0.011 (1)
C11	0.034 (1)	0.023 (1)	0.034 (1)	0.001 (1)	−0.004 (1)	−0.004 (1)
C12	0.021 (1)	0.028 (1)	0.026 (1)	−0.002 (1)	0.001 (1)	0.001 (1)
C13	0.022 (1)	0.025 (1)	0.016 (1)	−0.003 (1)	0.004 (1)	0.001 (1)
C14	0.024 (1)	0.029 (1)	0.020 (1)	−0.001 (1)	0.004 (1)	0.003 (1)
C15	0.023 (1)	0.045 (1)	0.022 (1)	−0.009 (1)	0.001 (1)	0.004 (1)
C16	0.039 (1)	0.037 (1)	0.024 (1)	−0.018 (1)	0.003 (1)	−0.002 (1)
C17	0.044 (1)	0.023 (1)	0.031 (1)	−0.005 (1)	0.006 (1)	0.000 (1)
C18	0.027 (1)	0.027 (1)	0.027 (1)	0.001 (1)	0.003 (1)	0.001 (1)
C19	0.021 (1)	0.019 (1)	0.020 (1)	−0.004 (1)	0.001 (1)	0.001 (1)
C20	0.019 (1)	0.027 (1)	0.022 (1)	0.003 (1)	0.003 (1)	0.005 (1)
C21	0.024 (1)	0.024 (1)	0.024 (1)	−0.001 (1)	0.002 (1)	0.005 (1)
C22	0.032 (1)	0.025 (1)	0.021 (1)	−0.002 (1)	0.008 (1)	0.001 (1)
C23	0.027 (1)	0.022 (1)	0.031 (1)	0.002 (1)	0.014 (1)	0.004 (1)
C24	0.022 (1)	0.016 (1)	0.027 (1)	0.000 (1)	0.009 (1)	0.005 (1)
C25	0.019 (1)	0.024 (1)	0.036 (1)	0.002 (1)	0.010 (1)	0.007 (1)
C26	0.017 (1)	0.025 (1)	0.035 (1)	0.001 (1)	0.003 (1)	0.007 (1)
C27	0.022 (1)	0.019 (1)	0.029 (1)	−0.003 (1)	0.003 (1)	0.004 (1)
C28	0.028 (1)	0.024 (1)	0.031 (1)	−0.002 (1)	−0.003 (1)	0.000 (1)
C29	0.043 (1)	0.025 (1)	0.029 (1)	0.000 (1)	0.003 (1)	−0.006 (1)
C30	0.032 (1)	0.027 (1)	0.034 (1)	0.004 (1)	0.009 (1)	−0.007 (1)
C31	0.021 (1)	0.015 (1)	0.026 (1)	0.000 (1)	0.006 (1)	0.003 (1)
C32	0.020 (1)	0.016 (1)	0.024 (1)	−0.001 (1)	0.006 (1)	0.005 (1)

Geometric parameters (Å, º) top

Sn1—O1	2.113 (1)	C24—C25	1.434 (2)
Sn1—O1w	2.612 (1)	C25—C26	1.345 (2)
Sn1—C1	2.124 (2)	C26—C27	1.436 (2)
Sn1—C7	2.121 (2)	C27—C28	1.404 (2)
Sn1—C13	2.125 (2)	C27—C31	1.414 (2)
O1—C19	1.305 (2)	C28—C29	1.363 (3)
O2—C19	1.230 (2)	C29—C30	1.401 (3)
N1—C21	1.320 (2)	C31—C32	1.452 (2)
N1—C32	1.369 (2)	O1w—H1w1	0.83 (1)
N2—C30	1.320 (2)	O1w—H1w2	0.84 (1)
N2—C31	1.363 (2)	C2—H2	0.9500
C1—C2	1.390 (2)	C3—H3	0.9500
C1—C6	1.397 (2)	C4—H4	0.9500
C2—C3	1.391 (2)	C5—H5	0.9500
C3—C4	1.381 (3)	C6—H6	0.9500
C4—C5	1.382 (3)	C8—H8	0.9500
C5—C6	1.388 (3)	C9—H9	0.9500
C7—C8	1.393 (2)	C10—H10	0.9500
C7—C12	1.399 (2)	C11—H11	0.9500
C8—C9	1.390 (2)	C12—H12	0.9500
C9—C10	1.379 (3)	C14—H14	0.9500
C10—C11	1.386 (3)	C15—H15	0.9500
C11—C12	1.388 (2)	C16—H16	0.9500
C13—C18	1.399 (2)	C17—H17	0.9500
C13—C14	1.402 (2)	C18—H18	0.9500
C14—C15	1.386 (2)	C20—H20a	0.9900
C15—C16	1.383 (3)	C20—H20b	0.9900
C16—C17	1.390 (3)	C21—H21	0.9500
C17—C18	1.384 (2)	C22—H22	0.9500
C19—C20	1.512 (2)	C23—H23	0.9500
C20—C20ⁱ	1.511 (3)	C25—H25	0.9500
C21—C22	1.396 (2)	C26—H26	0.9500
C22—C23	1.368 (2)	C28—H28	0.9500
C23—C24	1.408 (2)	C29—H29	0.9500
C24—C32	1.412 (2)	C30—H30	0.9500

C1—Sn1—C7	116.7 (1)	N1—C32—C24	122.6 (2)
C1—Sn1—C13	117.3 (1)	N1—C32—C31	118.5 (1)
C1—Sn1—O1	90.2 (1)	C24—C32—C31	118.9 (1)
C1—Sn1—O1w	80.4 (1)	Sn1—O1w—H1w1	128 (2)
C7—Sn1—C13	121.0 (1)	Sn1—O1w—H1w2	123 (2)
C7—Sn1—O1	104.3 (1)	H1w1—O1w—H1w2	108 (2)
C7—Sn1—O1w	82.2 (1)	C1—C2—H2	119.3
C13—Sn1—O1	97.5 (1)	C3—C2—H2	119.3
C13—Sn1—O1w	84.9 (1)	C4—C3—H3	120.2
O1—Sn1—O1w	170.3 (1)	C2—C3—H3	120.2
C19—O1—Sn1	119.7 (1)	C3—C4—H4	120.0
C21—N1—C32	116.9 (1)	C5—C4—H4	120.0
C30—N2—C31	116.6 (2)	C4—C5—H5	119.8
C2—C1—C6	118.1 (2)	C6—C5—H5	119.8
C2—C1—Sn1	121.3 (1)	C5—C6—H6	119.8
C6—C1—Sn1	120.5 (1)	C1—C6—H6	119.8
C1—C2—C3	121.4 (2)	C9—C8—H8	119.7
C4—C3—C2	119.5 (2)	C7—C8—H8	119.7
C3—C4—C5	120.0 (2)	C10—C9—H9	119.9
C4—C5—C6	120.4 (2)	C8—C9—H9	119.9
C5—C6—C1	120.5 (2)	C9—C10—H10	119.9
C8—C7—C12	118.7 (2)	C11—C10—H10	119.9
C8—C7—Sn1	121.2 (1)	C10—C11—H11	120.1
C12—C7—Sn1	120.0 (1)	C12—C11—H11	120.1
C9—C8—C7	120.5 (2)	C11—C12—H12	119.7
C10—C9—C8	120.1 (2)	C7—C12—H12	119.7
C9—C10—C11	120.3 (2)	C15—C14—H14	119.8
C10—C11—C12	119.8 (2)	C13—C14—H14	119.8
C11—C12—C7	120.6 (2)	C16—C15—H15	119.6
C18—C13—C14	118.1 (2)	C14—C15—H15	119.6
C18—C13—Sn1	119.0 (1)	C15—C16—H16	120.3
C14—C13—Sn1	122.9 (1)	C17—C16—H16	120.3
C15—C14—C13	120.4 (2)	C18—C17—H17	119.9
C16—C15—C14	120.8 (2)	C16—C17—H17	119.9
C15—C16—C17	119.4 (2)	C17—C18—H18	119.4
C18—C17—C16	120.1 (2)	C13—C18—H18	119.4
C17—C18—C13	121.2 (2)	C20ⁱ—C20—H20a	108.6
O2—C19—O1	123.6 (2)	C19—C20—H20a	108.6
O2—C19—C20	122.9 (1)	C20ⁱ—C20—H20b	108.6
O1—C19—C20	113.5 (1)	C19—C20—H20b	108.6
C20ⁱ—C20—C19	114.7 (2)	H20a—C20—H20b	107.6
N1—C21—C22	124.5 (2)	N1—C21—H21	117.8
C23—C22—C21	119.2 (2)	C22—C21—H21	117.8
C22—C23—C24	118.8 (2)	C23—C22—H22	120.4
C23—C24—C32	118.0 (2)	C21—C22—H22	120.4
C23—C24—C25	121.6 (2)	C22—C23—H23	120.6
C32—C24—C25	120.4 (2)	C24—C23—H23	120.6
C26—C25—C24	121.0 (2)	C26—C25—H25	119.5
C25—C26—C27	120.5 (2)	C24—C25—H25	119.5
C28—C27—C31	117.5 (2)	C25—C26—H26	119.7
C28—C27—C26	121.8 (2)	C27—C26—H26	119.7
C31—C27—C26	120.6 (2)	C29—C28—H28	120.3
C29—C28—C27	119.4 (2)	C27—C28—H28	120.3
C28—C29—C30	118.8 (2)	C28—C29—H29	120.6
N2—C30—C29	124.6 (2)	C30—C29—H29	120.6
N2—C31—C27	123.1 (2)	N2—C30—H30	117.7
N2—C31—C32	118.2 (1)	C29—C30—H30	117.7
C27—C31—C32	118.7 (2)

C7—Sn1—O1—C19	−56.6 (1)	C18—C13—C14—C15	0.0 (2)
C1—Sn1—O1—C19	−174.3 (1)	Sn1—C13—C14—C15	−178.9 (1)
C13—Sn1—O1—C19	68.2 (1)	C13—C14—C15—C16	0.2 (3)
O1—Sn1—C1—C2	65.1 (1)	C14—C15—C16—C17	−0.4 (3)
C7—Sn1—C1—C2	−41.1 (1)	C15—C16—C17—C18	0.6 (3)
C13—Sn1—C1—C2	163.6 (1)	C16—C17—C18—C13	−0.5 (3)
O1w—Sn1—C1—C2	−117.3 (1)	C14—C13—C18—C17	0.2 (2)
O1—Sn1—C1—C6	−112.3 (1)	Sn1—C13—C18—C17	179.1 (1)
C7—Sn1—C1—C6	141.6 (1)	Sn1—O1—C19—O2	1.6 (2)
C13—Sn1—C1—C6	−13.7 (2)	Sn1—O1—C19—C20	−178.1 (1)
O1w—Sn1—C1—C6	65.4 (1)	O2—C19—C20—C20ⁱ	1.3 (3)
C6—C1—C2—C3	−0.6 (2)	O1—C19—C20—C20ⁱ	−179.0 (2)
Sn1—C1—C2—C3	−178.0 (1)	C32—N1—C21—C22	−1.9 (2)
C1—C2—C3—C4	1.6 (3)	N1—C21—C22—C23	1.7 (3)
C2—C3—C4—C5	−1.5 (3)	C21—C22—C23—C24	0.2 (2)
C3—C4—C5—C6	0.3 (3)	C22—C23—C24—C32	−1.6 (2)
C4—C5—C6—C1	0.8 (3)	C22—C23—C24—C25	177.3 (2)
C2—C1—C6—C5	−0.6 (2)	C23—C24—C25—C26	−179.0 (2)
Sn1—C1—C6—C5	176.8 (1)	C32—C24—C25—C26	0.0 (2)
O1—Sn1—C7—C8	74.7 (1)	C24—C25—C26—C27	0.2 (3)
C1—Sn1—C7—C8	172.3 (1)	C25—C26—C27—C28	176.9 (2)
C13—Sn1—C7—C8	−33.4 (2)	C25—C26—C27—C31	−0.2 (2)
O1w—Sn1—C7—C8	−112.6 (1)	C31—C27—C28—C29	0.1 (2)
O1—Sn1—C7—C12	−110.0 (1)	C26—C27—C28—C29	−177.1 (2)
C1—Sn1—C7—C12	−12.4 (1)	C27—C28—C29—C30	−0.6 (3)
C13—Sn1—C7—C12	142.0 (1)	C31—N2—C30—C29	0.6 (3)
O1w—Sn1—C7—C12	62.8 (1)	C28—C29—C30—N2	0.2 (3)
C12—C7—C8—C9	−0.7 (2)	C30—N2—C31—C27	−1.1 (2)
Sn1—C7—C8—C9	174.8 (1)	C30—N2—C31—C32	177.0 (2)
C7—C8—C9—C10	1.5 (2)	C28—C27—C31—N2	0.7 (2)
C8—C9—C10—C11	−0.4 (3)	C26—C27—C31—N2	178.0 (2)
C9—C10—C11—C12	−1.5 (3)	C28—C27—C31—C32	−177.3 (2)
C10—C11—C12—C7	2.2 (2)	C26—C27—C31—C32	0.0 (2)
C8—C7—C12—C11	−1.2 (2)	C21—N1—C32—C24	0.3 (2)
Sn1—C7—C12—C11	−176.7 (1)	C21—N1—C32—C31	−177.0 (1)
O1—Sn1—C13—C18	30.6 (1)	C23—C24—C32—N1	1.4 (2)
C7—Sn1—C13—C18	142.3 (1)	C25—C24—C32—N1	−177.6 (2)
C1—Sn1—C13—C18	−63.5 (1)	C23—C24—C32—C31	178.8 (2)
O1w—Sn1—C13—C18	−140.0 (1)	C25—C24—C32—C31	−0.2 (2)
O1—Sn1—C13—C14	−150.6 (1)	N2—C31—C32—N1	−0.4 (2)
C7—Sn1—C13—C14	−38.9 (2)	C27—C31—C32—N1	177.7 (1)
C1—Sn1—C13—C14	115.3 (1)	N2—C31—C32—C24	−177.9 (1)
O1w—Sn1—C13—C14	38.8 (1)	C27—C31—C32—C24	0.3 (2)

Symmetry code: (i) −x+1, −y+1, −z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1w1···N1	0.83 (1)	2.10 (1)	2.899 (2)	161 (2)
O1w—H1w2···O2ⁱⁱ	0.84 (1)	2.29 (1)	3.123 (2)	173 (2)

Symmetry code: (ii) x, −y+1/2, z+1/2.

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μ-Succinato-bis­(aqua­tri­phenyl­tin)bis(o-phenanthroline)

Supporting information

Key indicators

checkCIF results

μ-Succinato-bis(aquatriphenyltin)bis(o-phenanthroline)