Di­bromo­di­carbonyl­bis­(tri­phenyl­phosphine)­ruthenium(II) di­chloro­methane solvate

Lozano Diz, E.; Therrien, B.; Neels, A.; Süss-Fink, G.

doi:10.1107/S160053680201190X

Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate

E. Lozano Diz, B. Therrien, A. Neels and G. Süss-Fink

The title mononuclear ruthenium compound, [RuBr₂(CO)₂(PPh₃)₂]·CH₂Cl₂, has been prepared by a new synthetic route; it is the last complex of the series [RuX₂(CO)₂(PPh₃)₂] (X = F, Cl, Br, I) to be characterized by X-ray structure analysis. As expected, the cis-Br₂-cis-(CO)₂-trans-(PPh₃)₂ configuration is observed around the metal.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680201190X/ya6114sup1.cif Contains datablocks 3, global
	Structure factor file (CIF format) https://doi.org/10.1107/S160053680201190X/ya61143sup2.hkl Contains datablock 3

CCDC reference: 193702

checkCIF report

Key indicators

Single-crystal X-ray study
T = 153 K
Mean (C-C) = 0.008 Å
R factor = 0.038
wR factor = 0.090
Data-to-parameter ratio = 14.3

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level A:



REFLT_03
         From the CIF: _diffrn_reflns_theta_max           25.90
         From the CIF: _reflns_number_total               6181
         TEST2: Reflns within _diffrn_reflns_theta_max
         Count of symmetry unique reflns         7393
         Completeness (_total/calc)             83.61%
          Alert A: < 85% complete (theta max?)


 Alert Level C:



PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     85
                   O2  -C2  -RU1 -C1    -83.00 13.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     86
                   O2  -C2  -RU1 -P1   -174.00 13.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     87
                   O2  -C2  -RU1 -P2      9.00 13.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     88
                   O2  -C2  -RU1 -BR2    98.00 13.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     89
                   O2  -C2  -RU1 -BR1   -66.00 14.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     90
                   O1  -C1  -RU1 -C2    -30.00 22.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     91
                   O1  -C1  -RU1 -P1     61.00 22.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     92
                   O1  -C1  -RU1 -P2   -121.00 22.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     93
                   O1  -C1  -RU1 -BR2    -8.00 24.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     94
                   O1  -C1  -RU1 -BR1   151.00100.00   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    101
                   C9  -P1  -RU1 -P2   -138.60  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    102
                   C3  -P1  -RU1 -P2    -15.60  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    103
                   C15 -P1  -RU1 -P2    102.90  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    116
                   C27 -P2  -RU1 -P1   -107.30  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    117
                   C33 -P2  -RU1 -P1     15.10  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    118
                   C21 -P2  -RU1 -P1    133.90  0.50   1.555   1.555   1.555   1.555

General Notes



ABSTM_02  When printed, the submitted absorption T values will be replaced
          by the scaled T values. Since the ratio of scaled T's is
          identical to the ratio of reported T values, the scaling does
          not imply a change to the absorption corrections used in the
          study.
          Ratio of Tmax expected/reported      1.226
          Tmax scaled      0.499 Tmin scaled      0.416


 1 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 16 Alert Level C = Please check

Computing details top

Data collection: EXPOSE in IPDS (Stoe & Cie, 2000); cell refinement: CELL in IPDS; data reduction: INTEGRATE in IPDS; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate top

Crystal data top

[RuBr₂(CO)₂(PPh₃)₂]·CH₂Cl₂	F(000) = 1840
M_r = 926.38	D_x = 1.622 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
a = 10.2056 (6) Å	Cell parameters from 8000 reflections
b = 40.436 (3) Å	θ = 2.0–25.9°
c = 10.3584 (6) Å	µ = 2.78 mm⁻¹
β = 117.423 (6)°	T = 153 K
V = 3794.3 (4) Å³	Block, yellow
Z = 4	0.45 × 0.25 × 0.25 mm

Data collection top

Stoe IPDS diffractometer	6181 independent reflections
Radiation source: fine-focus sealed tube	4461 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.050
Detector resolution: 0.81 pixels mm^-1	θ_max = 25.9°, θ_min = 2.0°
φ scans	h = −12→11
Absorption correction: multi-scan (Blessing, 1995)	k = −49→49
T_min = 0.339, T_max = 0.407	l = −12→12
15317 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.090	H-atom parameters constrained
S = 0.93	w = 1/[σ²(F_o²) + (0.0511P)²] where P = (F_o² + 2F_c²)/3
6181 reflections	(Δ/σ)_max = 0.001
433 parameters	Δρ_max = 1.12 e Å⁻³
0 restraints	Δρ_min = −0.87 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic)

treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
C1	0.6298 (6)	0.11952 (12)	1.0279 (5)	0.0206 (11)
C2	0.6255 (6)	0.14837 (11)	0.7931 (4)	0.0187 (11)
C3	0.3664 (5)	0.05038 (11)	0.6337 (4)	0.0174 (10)
C4	0.2212 (6)	0.05998 (13)	0.5860 (5)	0.0238 (11)
H4A	0.2005	0.0803	0.6191	0.029*
C5	0.1056 (6)	0.04036 (14)	0.4904 (5)	0.0297 (12)
H5A	0.0065	0.0473	0.4582	0.036*
C6	0.1345 (6)	0.01070 (14)	0.4422 (5)	0.0305 (13)
H6A	0.0553	−0.0025	0.3751	0.037*
C7	0.2780 (6)	0.00030 (13)	0.4914 (5)	0.0268 (12)
H7A	0.2977	−0.0204	0.4601	0.032*
C8	0.3931 (6)	0.01976 (12)	0.5857 (5)	0.0218 (11)
H8A	0.4918	0.0124	0.6188	0.026*
C9	0.6347 (6)	0.04536 (11)	0.8965 (4)	0.0193 (11)
C10	0.7313 (6)	0.02316 (13)	0.8830 (5)	0.0294 (12)
H10A	0.7515	0.0249	0.8024	0.035*
C11	0.7992 (7)	−0.00163 (14)	0.9853 (6)	0.0375 (14)
H11A	0.8661	−0.0164	0.9752	0.045*
C12	0.7689 (7)	−0.00468 (15)	1.1018 (6)	0.0404 (15)
H12A	0.8133	−0.0219	1.1707	0.049*
C13	0.6760 (7)	0.01692 (15)	1.1177 (5)	0.0361 (14)
H13A	0.6584	0.0151	1.1999	0.043*
C14	0.6056 (6)	0.04182 (13)	1.0154 (5)	0.0278 (12)
H14A	0.5381	0.0563	1.0265	0.033*
C15	0.6277 (6)	0.08074 (11)	0.6500 (5)	0.0193 (11)
C16	0.5474 (6)	0.08283 (12)	0.4962 (5)	0.0229 (11)
H16A	0.4434	0.0797	0.4474	0.028*
C17	0.6262 (7)	0.08961 (13)	0.4183 (5)	0.0309 (13)
H17A	0.5746	0.0913	0.3153	0.037*
C18	0.7749 (7)	0.09383 (13)	0.4875 (6)	0.0347 (15)
H18A	0.8257	0.0982	0.4322	0.042*
C19	0.8533 (7)	0.09186 (14)	0.6370 (6)	0.0332 (13)
H19A	0.9575	0.0945	0.6846	0.040*
C20	0.7768 (6)	0.08584 (13)	0.7176 (5)	0.0260 (12)
H20A	0.8295	0.0853	0.8207	0.031*
C21	0.4980 (5)	0.18277 (11)	1.1024 (4)	0.0168 (10)
C22	0.6485 (6)	0.18601 (12)	1.1934 (4)	0.0217 (11)
H22A	0.7135	0.1899	1.1526	0.026*
C23	0.7051 (6)	0.18368 (13)	1.3441 (5)	0.0279 (12)
H23A	0.8079	0.1862	1.4061	0.033*
C24	0.6080 (6)	0.17756 (13)	1.4023 (5)	0.0259 (12)
H24A	0.6453	0.1756	1.5046	0.031*
C25	0.4596 (6)	0.17435 (12)	1.3130 (5)	0.0253 (12)
H25A	0.3953	0.1701	1.3544	0.030*
C26	0.4014 (6)	0.17713 (12)	1.1630 (4)	0.0192 (10)
H26A	0.2981	0.1753	1.1022	0.023*
C27	0.5042 (5)	0.21808 (11)	0.8625 (4)	0.0178 (10)
C28	0.4872 (6)	0.22132 (13)	0.7205 (5)	0.0276 (13)
H28A	0.4459	0.2037	0.6528	0.033*
C29	0.5306 (7)	0.25019 (14)	0.6796 (5)	0.0358 (14)
H29A	0.5183	0.2523	0.5833	0.043*
C30	0.5917 (7)	0.27610 (15)	0.7761 (6)	0.0421 (16)
H30A	0.6221	0.2956	0.7465	0.051*
C31	0.6082 (7)	0.27346 (15)	0.9152 (6)	0.0379 (14)
H31A	0.6484	0.2913	0.9814	0.046*
C32	0.5660 (6)	0.24467 (13)	0.9586 (5)	0.0261 (12)
H32A	0.5791	0.2429	1.0553	0.031*
C33	0.2338 (5)	0.19357 (12)	0.8350 (4)	0.0164 (10)
C34	0.1996 (6)	0.22518 (12)	0.8635 (5)	0.0214 (11)
H34A	0.2770	0.2404	0.9159	0.026*
C35	0.0545 (6)	0.23484 (13)	0.8170 (5)	0.0250 (12)
H35A	0.0332	0.2566	0.8367	0.030*
C36	−0.0587 (6)	0.21294 (13)	0.7423 (5)	0.0233 (11)
H36A	−0.1582	0.2194	0.7113	0.028*
C37	−0.0264 (6)	0.18132 (13)	0.7124 (5)	0.0220 (11)
H37A	−0.1043	0.1661	0.6608	0.026*
C38	0.1176 (5)	0.17185 (12)	0.7570 (4)	0.0190 (11)
H38A	0.1382	0.1503	0.7345	0.023*
C39	1.1354 (8)	0.11030 (17)	1.1757 (6)	0.0494 (18)
H39A	1.2198	0.1074	1.1543	0.059*
H39B	1.1749	0.1164	1.2796	0.059*
O1	0.7191 (4)	0.11406 (9)	1.1430 (3)	0.0323 (9)
O2	0.7099 (4)	0.16123 (9)	0.7685 (4)	0.0312 (9)
P1	0.52572 (14)	0.07514 (3)	0.75479 (11)	0.0154 (3)
P2	0.42684 (13)	0.18169 (3)	0.90546 (11)	0.0139 (3)
Br1	0.30457 (6)	0.101341 (12)	0.91778 (5)	0.02463 (13)
Br2	0.29855 (6)	0.141022 (12)	0.56888 (4)	0.02115 (12)
Ru1	0.48525 (4)	0.128456 (9)	0.83685 (3)	0.01324 (10)
Cl1	1.0354 (3)	0.07323 (5)	1.1416 (2)	0.0712 (6)
Cl2	1.0192 (2)	0.14216 (5)	1.0657 (2)	0.0621 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.024 (3)	0.019 (2)	0.024 (2)	−0.002 (2)	0.015 (2)	−0.0030 (19)
C2	0.024 (3)	0.017 (2)	0.015 (2)	0.000 (2)	0.008 (2)	−0.0001 (17)
C3	0.021 (3)	0.017 (2)	0.015 (2)	−0.007 (2)	0.009 (2)	−0.0023 (17)
C4	0.024 (3)	0.023 (3)	0.027 (2)	−0.002 (2)	0.013 (2)	0.001 (2)
C5	0.016 (3)	0.035 (3)	0.034 (3)	−0.004 (3)	0.008 (2)	−0.002 (2)
C6	0.025 (4)	0.035 (3)	0.026 (2)	−0.010 (3)	0.008 (2)	−0.005 (2)
C7	0.035 (4)	0.025 (3)	0.024 (2)	−0.007 (3)	0.017 (2)	−0.006 (2)
C8	0.020 (3)	0.025 (3)	0.020 (2)	0.000 (2)	0.009 (2)	−0.0013 (19)
C9	0.024 (3)	0.014 (2)	0.016 (2)	−0.002 (2)	0.006 (2)	−0.0008 (17)
C10	0.029 (4)	0.028 (3)	0.025 (2)	0.004 (3)	0.006 (2)	0.002 (2)
C11	0.030 (4)	0.026 (3)	0.045 (3)	0.011 (3)	0.008 (3)	0.007 (2)
C12	0.031 (4)	0.031 (3)	0.035 (3)	0.001 (3)	−0.005 (3)	0.015 (2)
C13	0.032 (4)	0.045 (4)	0.023 (2)	−0.007 (3)	0.007 (2)	0.014 (2)
C14	0.030 (4)	0.028 (3)	0.026 (2)	−0.004 (3)	0.014 (2)	0.005 (2)
C15	0.021 (3)	0.018 (2)	0.022 (2)	0.005 (2)	0.013 (2)	−0.0003 (18)
C16	0.029 (3)	0.023 (3)	0.023 (2)	0.003 (2)	0.017 (2)	0.0045 (19)
C17	0.044 (4)	0.028 (3)	0.029 (2)	0.010 (3)	0.024 (3)	0.012 (2)
C18	0.051 (5)	0.029 (3)	0.043 (3)	0.000 (3)	0.038 (3)	0.002 (2)
C19	0.025 (4)	0.029 (3)	0.053 (3)	−0.006 (3)	0.024 (3)	−0.007 (3)
C20	0.022 (3)	0.028 (3)	0.032 (3)	−0.001 (3)	0.016 (2)	−0.005 (2)
C21	0.023 (3)	0.014 (2)	0.0156 (19)	−0.001 (2)	0.010 (2)	−0.0017 (17)
C22	0.019 (3)	0.027 (3)	0.018 (2)	−0.003 (2)	0.008 (2)	−0.0029 (19)
C23	0.024 (3)	0.034 (3)	0.018 (2)	−0.001 (3)	0.003 (2)	−0.004 (2)
C24	0.031 (4)	0.027 (3)	0.016 (2)	−0.002 (3)	0.008 (2)	0.0019 (19)
C25	0.034 (4)	0.027 (3)	0.022 (2)	0.000 (3)	0.019 (2)	0.005 (2)
C26	0.017 (3)	0.022 (3)	0.017 (2)	−0.004 (2)	0.006 (2)	−0.0022 (18)
C27	0.014 (3)	0.020 (2)	0.021 (2)	−0.002 (2)	0.009 (2)	0.0000 (18)
C28	0.034 (4)	0.032 (3)	0.020 (2)	−0.002 (3)	0.014 (2)	0.001 (2)
C29	0.046 (4)	0.036 (3)	0.031 (3)	−0.004 (3)	0.023 (3)	0.007 (2)
C30	0.044 (4)	0.032 (3)	0.051 (3)	−0.010 (3)	0.023 (3)	0.013 (3)
C31	0.039 (4)	0.032 (3)	0.039 (3)	−0.010 (3)	0.015 (3)	−0.002 (2)
C32	0.027 (3)	0.028 (3)	0.022 (2)	−0.007 (3)	0.011 (2)	−0.001 (2)
C33	0.018 (3)	0.024 (2)	0.0101 (18)	−0.001 (2)	0.0081 (19)	0.0033 (17)
C34	0.013 (3)	0.024 (3)	0.026 (2)	0.000 (2)	0.007 (2)	0.001 (2)
C35	0.026 (3)	0.023 (3)	0.029 (2)	0.007 (2)	0.016 (2)	0.004 (2)
C36	0.013 (3)	0.031 (3)	0.026 (2)	0.006 (2)	0.008 (2)	0.009 (2)
C37	0.016 (3)	0.031 (3)	0.016 (2)	−0.002 (2)	0.005 (2)	0.0013 (19)
C38	0.017 (3)	0.025 (3)	0.017 (2)	0.000 (2)	0.010 (2)	−0.0017 (19)
C39	0.045 (5)	0.064 (5)	0.030 (3)	0.001 (4)	0.010 (3)	−0.006 (3)
O1	0.032 (2)	0.041 (2)	0.0146 (16)	0.009 (2)	0.0022 (16)	0.0021 (15)
O2	0.030 (2)	0.034 (2)	0.0384 (19)	−0.005 (2)	0.0227 (18)	0.0015 (17)
P1	0.0162 (7)	0.0174 (6)	0.0135 (5)	−0.0006 (5)	0.0075 (5)	−0.0006 (4)
P2	0.0130 (7)	0.0181 (6)	0.0109 (5)	−0.0032 (5)	0.0057 (5)	−0.0017 (4)
Br1	0.0268 (3)	0.0258 (3)	0.0290 (2)	−0.0024 (2)	0.0194 (2)	0.0009 (2)
Br2	0.0241 (3)	0.0240 (2)	0.0133 (2)	0.0014 (2)	0.00687 (19)	−0.00018 (17)
Ru1	0.0141 (2)	0.01665 (18)	0.01062 (15)	−0.00124 (17)	0.00713 (14)	−0.00055 (13)
Cl1	0.0972 (18)	0.0474 (11)	0.0716 (11)	0.0030 (11)	0.0410 (12)	0.0070 (9)
Cl2	0.0443 (12)	0.0506 (11)	0.0817 (12)	−0.0070 (10)	0.0209 (9)	0.0027 (9)

Geometric parameters (Å, º) top

C1—O1	1.140 (6)	C21—C26	1.410 (6)
C1—Ru1	1.880 (5)	C21—P2	1.824 (4)
C2—O2	1.131 (6)	C22—C23	1.396 (6)
C2—Ru1	1.871 (5)	C23—C24	1.399 (7)
C3—C4	1.384 (7)	C24—C25	1.369 (7)
C3—C8	1.407 (6)	C25—C26	1.389 (6)
C3—P1	1.828 (5)	C27—C32	1.402 (7)
C4—C5	1.387 (7)	C27—C28	1.405 (6)
C5—C6	1.382 (7)	C27—P2	1.820 (5)
C6—C7	1.377 (8)	C28—C29	1.383 (7)
C7—C8	1.377 (7)	C29—C30	1.383 (8)
C9—C10	1.388 (7)	C30—C31	1.376 (7)
C9—C14	1.401 (6)	C31—C32	1.385 (7)
C9—P1	1.827 (5)	C33—C34	1.392 (6)
C10—C11	1.390 (7)	C33—C38	1.395 (7)
C11—C12	1.383 (8)	C33—P2	1.822 (5)
C12—C13	1.354 (8)	C34—C35	1.385 (7)
C13—C14	1.397 (7)	C35—C36	1.376 (7)
C15—C20	1.366 (7)	C36—C37	1.390 (7)
C15—C16	1.419 (6)	C37—C38	1.377 (7)
C15—P1	1.832 (4)	C39—Cl1	1.756 (7)
C16—C17	1.405 (7)	C39—Cl2	1.767 (7)
C17—C18	1.358 (8)	P1—Ru1	2.4215 (12)
C18—C19	1.379 (8)	P2—Ru1	2.4255 (12)
C19—C20	1.402 (7)	Br1—Ru1	2.5940 (6)
C21—C22	1.389 (7)	Br2—Ru1	2.5927 (6)

O1—C1—Ru1	179.0 (5)	C31—C30—C29	119.7 (5)
O2—C2—Ru1	178.0 (4)	C30—C31—C32	119.9 (5)
C4—C3—C8	118.1 (4)	C31—C32—C27	121.3 (4)
C4—C3—P1	124.0 (4)	C34—C33—C38	118.1 (5)
C8—C3—P1	118.0 (4)	C34—C33—P2	119.2 (4)
C3—C4—C5	120.9 (5)	C38—C33—P2	122.6 (4)
C6—C5—C4	120.1 (5)	C35—C34—C33	121.2 (5)
C7—C6—C5	119.9 (5)	C36—C35—C34	120.0 (5)
C6—C7—C8	120.2 (5)	C35—C36—C37	119.6 (5)
C7—C8—C3	120.9 (5)	C38—C37—C36	120.5 (5)
C10—C9—C14	118.1 (4)	C37—C38—C33	120.7 (5)
C10—C9—P1	122.9 (3)	Cl1—C39—Cl2	109.7 (4)
C14—C9—P1	118.5 (4)	C9—P1—C3	102.1 (2)
C9—C10—C11	121.2 (5)	C9—P1—C15	104.8 (2)
C12—C11—C10	119.8 (5)	C3—P1—C15	103.3 (2)
C13—C12—C11	120.0 (5)	C9—P1—Ru1	116.34 (14)
C12—C13—C14	121.1 (5)	C3—P1—Ru1	119.14 (16)
C13—C14—C9	119.8 (5)	C15—P1—Ru1	109.48 (15)
C20—C15—C16	119.9 (4)	C27—P2—C33	101.5 (2)
C20—C15—P1	121.2 (3)	C27—P2—C21	105.1 (2)
C16—C15—P1	118.7 (4)	C33—P2—C21	104.02 (19)
C17—C16—C15	118.0 (5)	C27—P2—Ru1	116.94 (14)
C18—C17—C16	121.2 (5)	C33—P2—Ru1	118.88 (15)
C17—C18—C19	121.0 (5)	C21—P2—Ru1	108.91 (15)
C18—C19—C20	119.0 (6)	C2—Ru1—C1	91.2 (2)
C15—C20—C19	121.0 (5)	C2—Ru1—P1	91.43 (14)
C22—C21—C26	119.6 (4)	C1—Ru1—P1	91.15 (14)
C22—C21—P2	120.5 (3)	C2—Ru1—P2	90.44 (14)
C26—C21—P2	119.6 (4)	C1—Ru1—P2	92.41 (14)
C21—C22—C23	120.7 (4)	P1—Ru1—P2	175.94 (4)
C22—C23—C24	118.9 (5)	C2—Ru1—Br2	85.61 (14)
C25—C24—C23	120.5 (4)	C1—Ru1—Br2	176.52 (14)
C24—C25—C26	121.2 (4)	P1—Ru1—Br2	87.63 (3)
C25—C26—C21	119.0 (5)	P2—Ru1—Br2	88.92 (3)
C32—C27—C28	118.0 (4)	C2—Ru1—Br1	175.74 (13)
C32—C27—P2	123.4 (3)	C1—Ru1—Br1	84.77 (14)
C28—C27—P2	118.2 (3)	P1—Ru1—Br1	89.93 (3)
C29—C28—C27	119.8 (5)	P2—Ru1—Br1	88.46 (3)
C28—C29—C30	121.3 (4)	Br2—Ru1—Br1	98.48 (2)

C8—C3—C4—C5	−1.7 (6)	C20—C15—P1—C3	−153.3 (4)
P1—C3—C4—C5	178.0 (3)	C16—C15—P1—C3	32.5 (4)
C3—C4—C5—C6	0.3 (7)	C20—C15—P1—Ru1	78.8 (4)
C4—C5—C6—C7	1.4 (7)	C16—C15—P1—Ru1	−95.3 (4)
C5—C6—C7—C8	−1.6 (7)	C32—C27—P2—C33	91.5 (5)
C6—C7—C8—C3	0.2 (7)	C28—C27—P2—C33	−81.4 (4)
C4—C3—C8—C7	1.5 (6)	C32—C27—P2—C21	−16.6 (5)
P1—C3—C8—C7	−178.3 (3)	C28—C27—P2—C21	170.5 (4)
C14—C9—C10—C11	−0.9 (8)	C32—C27—P2—Ru1	−137.5 (4)
P1—C9—C10—C11	−172.4 (4)	C28—C27—P2—Ru1	49.6 (4)
C9—C10—C11—C12	0.9 (9)	C34—C33—P2—C27	−44.7 (3)
C10—C11—C12—C13	−1.5 (9)	C38—C33—P2—C27	137.5 (3)
C11—C12—C13—C14	2.1 (9)	C34—C33—P2—C21	64.2 (4)
C12—C13—C14—C9	−2.1 (9)	C38—C33—P2—C21	−113.5 (3)
C10—C9—C14—C13	1.5 (8)	C34—C33—P2—Ru1	−174.5 (3)
P1—C9—C14—C13	173.4 (4)	C38—C33—P2—Ru1	7.7 (4)
C20—C15—C16—C17	1.1 (7)	C22—C21—P2—C27	−52.1 (4)
P1—C15—C16—C17	175.3 (4)	C26—C21—P2—C27	133.9 (4)
C15—C16—C17—C18	0.4 (8)	C22—C21—P2—C33	−158.4 (4)
C16—C17—C18—C19	−0.5 (8)	C26—C21—P2—C33	27.7 (4)
C17—C18—C19—C20	−0.9 (8)	C22—C21—P2—Ru1	73.9 (4)
C16—C15—C20—C19	−2.5 (7)	C26—C21—P2—Ru1	−100.0 (4)
P1—C15—C20—C19	−176.6 (4)	O2—C2—Ru1—C1	−83 (13)
C18—C19—C20—C15	2.4 (8)	O2—C2—Ru1—P1	−174 (13)
C26—C21—C22—C23	0.1 (7)	O2—C2—Ru1—P2	9 (13)
P2—C21—C22—C23	−173.8 (4)	O2—C2—Ru1—Br2	98 (13)
C21—C22—C23—C24	0.9 (8)	O2—C2—Ru1—Br1	−66 (14)
C22—C23—C24—C25	−0.9 (8)	O1—C1—Ru1—C2	−30 (22)
C23—C24—C25—C26	−0.2 (8)	O1—C1—Ru1—P1	61 (22)
C24—C25—C26—C21	1.2 (7)	O1—C1—Ru1—P2	−121 (22)
C22—C21—C26—C25	−1.2 (7)	O1—C1—Ru1—Br2	−8 (24)
P2—C21—C26—C25	172.8 (4)	O1—C1—Ru1—Br1	151 (100)
C32—C27—C28—C29	−0.1 (8)	C9—P1—Ru1—C2	104.0 (2)
P2—C27—C28—C29	173.2 (4)	C3—P1—Ru1—C2	−133.0 (2)
C27—C28—C29—C30	0.3 (9)	C15—P1—Ru1—C2	−14.6 (2)
C28—C29—C30—C31	−0.8 (9)	C9—P1—Ru1—C1	12.8 (2)
C29—C30—C31—C32	1.1 (9)	C3—P1—Ru1—C1	135.8 (2)
C30—C31—C32—C27	−1.0 (9)	C15—P1—Ru1—C1	−105.8 (2)
C28—C27—C32—C31	0.5 (8)	C9—P1—Ru1—P2	−138.6 (5)
P2—C27—C32—C31	−172.5 (4)	C3—P1—Ru1—P2	−15.6 (6)
C38—C33—C34—C35	0.4 (6)	C15—P1—Ru1—P2	102.9 (6)
P2—C33—C34—C35	−177.4 (3)	C9—P1—Ru1—Br2	−170.45 (18)
C33—C34—C35—C36	0.6 (6)	C3—P1—Ru1—Br2	−47.45 (15)
C34—C35—C36—C37	−0.8 (6)	C15—P1—Ru1—Br2	70.98 (17)
C35—C36—C37—C38	0.0 (6)	C9—P1—Ru1—Br1	−71.96 (18)
C36—C37—C38—C33	1.1 (6)	C3—P1—Ru1—Br1	51.04 (15)
C34—C33—C38—C37	−1.3 (6)	C15—P1—Ru1—Br1	169.47 (17)
P2—C33—C38—C37	176.5 (3)	C27—P2—Ru1—C2	10.2 (2)
C10—C9—P1—C3	83.8 (5)	C33—P2—Ru1—C2	132.57 (19)
C14—C9—P1—C3	−87.7 (4)	C21—P2—Ru1—C2	−108.7 (2)
C10—C9—P1—C15	−23.7 (5)	C27—P2—Ru1—C1	101.3 (2)
C14—C9—P1—C15	164.9 (4)	C33—P2—Ru1—C1	−136.3 (2)
C10—C9—P1—Ru1	−144.7 (4)	C21—P2—Ru1—C1	−17.5 (2)
C14—C9—P1—Ru1	43.8 (4)	C27—P2—Ru1—P1	−107.3 (6)
C4—C3—P1—C9	128.9 (4)	C33—P2—Ru1—P1	15.1 (6)
C8—C3—P1—C9	−51.3 (4)	C21—P2—Ru1—P1	133.9 (5)
C4—C3—P1—C15	−122.4 (4)	C27—P2—Ru1—Br2	−75.43 (17)
C8—C3—P1—C15	57.4 (4)	C33—P2—Ru1—Br2	46.96 (14)
C4—C3—P1—Ru1	−0.8 (4)	C21—P2—Ru1—Br2	165.73 (17)
C8—C3—P1—Ru1	179.0 (3)	C27—P2—Ru1—Br1	−173.95 (17)
C20—C15—P1—C9	−46.7 (5)	C33—P2—Ru1—Br1	−51.55 (14)
C16—C15—P1—C9	139.2 (4)	C21—P2—Ru1—Br1	67.21 (17)

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Di­bromo­di­carbonyl­bis­(tri­phenyl­phosphine)­ruthenium(II) di­chloro­methane solvate

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Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate