Tetra­kis(μ-phenyl­acetato-κ²O:O′)bis­[(N,N-dimethyl­formamide-κO)copper(II)]

In the crystal structure of the title complex, [Cu₂(C₈H₇O₂)₄(C₃H₇NO)₂], two independent dinuclear Cu^II complex mol­ecules, bridged by phenyl­acetate anions, are located on inversion centres. The Cu...Cu separations of 2.6414 (8) and 2.6261 (8) Å suggest no bonding between the Cu atoms. The Cu^II ions exist in a square-pyramidal coordination environment, defined by one N,N-dimethyl­formamide and four phenyl­acetate O atoms.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.043
• wR factor = 0.114
• Data-to-parameter ratio = 18.2

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   O1      ..       5.86 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   O9      ..       5.80 su
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         N1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C3
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         N2

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: RAPID AUTO (Rigaku, 1998); cell refinement: RAPID AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Tetrakis(µ-phenylacetato-κ²O:O')bis[(N,N-dimethylformamide-κO)copper(II)]

Crystal data

[Cu2(C8H7O2)4(C3H7NO)2]	F(000) = 1688
Mr = 813.84	Dx = 1.433 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 34692 reflections
a = 14.291 (3) Å	θ = 3.0–27.5°
b = 17.569 (4) Å	µ = 1.19 mm^−1
c = 15.791 (3) Å	T = 295 K
β = 107.95 (3)°	Prism, blue
V = 3771.7 (15) Å^3	0.42 × 0.31 × 0.18 mm
Z = 4

Data collection

Rigaku R-AXIS RAPID diffractometer	8596 independent reflections
Radiation source: fine-focus sealed tube	6302 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.058
Detector resolution: 10 pixels mm^-1	θmax = 27.5°, θmin = 3.0°
ω scans	h = −17→18
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	k = −22→22
Tmin = 0.636, Tmax = 0.815	l = −20→20
35794 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.043	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.114	H-atom parameters constrained
S = 1.05	w = 1/[σ^2(Fo^2) + (0.0605P)^2] where P = (Fo^2 + 2Fc^2)/3
8596 reflections	(Δ/σ)max = 0.001
473 parameters	Δρmax = 0.51 e Å^−3
0 restraints	Δρmin = −0.29 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.497788 (19)	0.574370 (16)	0.511441 (17)	0.03829 (10)
Cu2	0.97899 (2)	0.497977 (14)	0.413011 (17)	0.03428 (9)
O1	0.37237 (13)	0.57093 (10)	0.41522 (11)	0.0509 (4)
O2	0.37429 (13)	0.44490 (11)	0.39688 (12)	0.0569 (5)
O3	0.43085 (13)	0.54261 (10)	0.59805 (11)	0.0492 (4)
O4	0.43474 (13)	0.41718 (10)	0.57863 (12)	0.0535 (4)
O5	0.88654 (12)	0.58054 (9)	0.41186 (11)	0.0481 (4)
O6	0.92088 (13)	0.58323 (9)	0.55919 (11)	0.0512 (4)
O7	1.08309 (12)	0.57367 (9)	0.42903 (11)	0.0481 (4)
O8	1.12007 (13)	0.57733 (10)	0.57700 (11)	0.0524 (4)
O9	0.50020 (14)	0.69287 (10)	0.55525 (11)	0.0530 (4)
O10	0.94822 (14)	0.47746 (10)	0.27213 (11)	0.0517 (4)
N1	0.53690 (16)	0.76952 (12)	0.67616 (14)	0.0546 (5)
N2	0.91959 (17)	0.38631 (14)	0.16610 (14)	0.0591 (6)
C1	0.33644 (18)	0.50958 (15)	0.37824 (16)	0.0452 (6)
C2	0.23712 (19)	0.51564 (17)	0.30678 (18)	0.0569 (7)
C3	0.21685 (16)	0.45633 (15)	0.23500 (16)	0.0455 (6)
C4	0.2287 (2)	0.47139 (18)	0.15323 (19)	0.0594 (7)
C5	0.2105 (3)	0.4164 (2)	0.0874 (2)	0.0746 (9)
C6	0.1815 (2)	0.3455 (2)	0.1018 (2)	0.0824 (10)
C7	0.1691 (3)	0.3294 (2)	0.1822 (3)	0.0901 (11)
C8	0.1855 (2)	0.38396 (19)	0.2472 (2)	0.0717 (9)
C9	0.41372 (17)	0.47575 (15)	0.61507 (15)	0.0410 (5)
C10	0.36085 (18)	0.46227 (16)	0.68315 (16)	0.0490 (6)
C11	0.39440 (19)	0.51024 (13)	0.76655 (16)	0.0418 (5)
C12	0.4921 (2)	0.52791 (19)	0.8061 (2)	0.0630 (7)
C13	0.5215 (3)	0.5677 (2)	0.8853 (2)	0.0883 (11)
C14	0.4542 (3)	0.5898 (2)	0.9251 (2)	0.0941 (12)
C15	0.3573 (3)	0.5736 (2)	0.8869 (2)	0.0829 (10)
C16	0.3272 (2)	0.53394 (17)	0.8073 (2)	0.0600 (7)
C17	0.5753 (3)	0.7763 (2)	0.7724 (2)	0.0831 (10)
C18	0.5032 (3)	0.83763 (17)	0.6263 (2)	0.0834 (10)
C19	0.5307 (2)	0.70298 (15)	0.63599 (18)	0.0543 (6)
C20	0.87769 (17)	0.60719 (13)	0.48263 (16)	0.0404 (5)
C21	0.80627 (19)	0.67191 (15)	0.47338 (17)	0.0542 (6)
C22	0.83293 (17)	0.72966 (13)	0.54742 (16)	0.0432 (5)
C23	0.9271 (2)	0.75778 (15)	0.58063 (19)	0.0570 (7)
C24	0.9504 (2)	0.81083 (17)	0.6484 (2)	0.0726 (9)
C25	0.8807 (3)	0.83638 (18)	0.6837 (2)	0.0785 (9)
C26	0.7863 (3)	0.80964 (18)	0.6502 (2)	0.0736 (9)
C27	0.7627 (2)	0.75633 (15)	0.58260 (18)	0.0544 (7)
C28	1.13198 (17)	0.59721 (13)	0.50498 (15)	0.0390 (5)
C29	1.21402 (19)	0.65304 (14)	0.50843 (17)	0.0483 (6)
C30	1.23100 (16)	0.71385 (13)	0.57853 (15)	0.0394 (5)
C31	1.1891 (2)	0.78444 (15)	0.55946 (19)	0.0553 (6)
C32	1.2075 (2)	0.84116 (17)	0.6226 (2)	0.0717 (9)
C33	1.2676 (2)	0.82774 (19)	0.7067 (2)	0.0695 (9)
C34	1.3083 (2)	0.7574 (2)	0.7274 (2)	0.0730 (9)
C35	1.2913 (2)	0.70066 (16)	0.66416 (18)	0.0582 (7)
C36	0.9026 (3)	0.3069 (2)	0.1433 (2)	0.0952 (12)
C37	0.9222 (3)	0.4390 (2)	0.0972 (2)	0.0912 (11)
C38	0.93405 (19)	0.41085 (16)	0.24806 (17)	0.0536 (6)
H2A	0.1860	0.5127	0.3353	0.068*
H2B	0.2325	0.5654	0.2792	0.068*
H4	0.2493	0.5195	0.1421	0.071*
H5	0.2183	0.4282	0.0326	0.090*
H6	0.1704	0.3084	0.0578	0.099*
H7	0.1491	0.2809	0.1929	0.108*
H8	0.1754	0.3719	0.3011	0.086*
H10A	0.3685	0.4091	0.7004	0.059*
H10B	0.2912	0.4714	0.6549	0.059*
H12	0.5386	0.5130	0.7792	0.076*
H13	0.5876	0.5793	0.9115	0.106*
H14	0.4745	0.6161	0.9788	0.113*
H15	0.3113	0.5891	0.9141	0.099*
H16	0.2608	0.5232	0.7812	0.072*
H17A	0.5842	0.7264	0.7986	0.125*
H17B	0.5297	0.8045	0.7939	0.125*
H17C	0.6373	0.8023	0.7883	0.125*
H18A	0.4929	0.8279	0.5642	0.125*
H18B	0.5516	0.8770	0.6464	0.125*
H18C	0.4425	0.8536	0.6347	0.125*
H19	0.5512	0.6603	0.6718	0.065*
H21A	0.7423	0.6508	0.4694	0.065*
H21B	0.8000	0.6980	0.4178	0.065*
H23	0.9756	0.7408	0.5571	0.068*
H24	1.0144	0.8292	0.6701	0.087*
H25	0.8968	0.8715	0.7300	0.094*
H26	0.7378	0.8275	0.6731	0.088*
H27	0.6985	0.7383	0.5608	0.065*
H29A	1.2746	0.6246	0.5182	0.058*
H29B	1.1996	0.6776	0.4508	0.058*
H30	1.1472	0.7943	0.5025	0.066*
H32	1.1788	0.8888	0.6078	0.086*
H33	1.2807	0.8661	0.7494	0.083*
H34	1.3482	0.7475	0.7851	0.088*
H35	1.3207	0.6532	0.6792	0.070*
H36A	0.9043	0.2783	0.1955	0.143*
H36B	0.9528	0.2885	0.1198	0.143*
H36C	0.8394	0.3010	0.0993	0.143*
H37A	0.9239	0.4901	0.1191	0.137*
H37B	0.8646	0.4323	0.0468	0.137*
H37C	0.9799	0.4297	0.0798	0.137*
H38	0.9335	0.3748	0.2911	0.064*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.04045 (17)	0.03807 (17)	0.03390 (15)	0.00232 (12)	0.00785 (12)	−0.00292 (11)
Cu2	0.04072 (16)	0.03234 (16)	0.02752 (14)	0.00120 (11)	0.00719 (12)	−0.00264 (10)
O1	0.0512 (10)	0.0533 (11)	0.0420 (9)	0.0082 (8)	0.0051 (8)	−0.0021 (8)
O2	0.0465 (10)	0.0562 (11)	0.0542 (11)	0.0065 (9)	−0.0046 (8)	−0.0083 (9)
O3	0.0637 (11)	0.0443 (10)	0.0445 (9)	−0.0015 (8)	0.0242 (9)	−0.0003 (8)
O4	0.0608 (11)	0.0473 (10)	0.0591 (11)	−0.0054 (8)	0.0285 (10)	−0.0017 (8)
O5	0.0517 (10)	0.0501 (10)	0.0376 (9)	0.0153 (8)	0.0065 (8)	−0.0028 (7)
O6	0.0653 (11)	0.0469 (10)	0.0385 (9)	0.0208 (9)	0.0117 (9)	−0.0004 (7)
O7	0.0538 (10)	0.0492 (10)	0.0410 (9)	−0.0120 (8)	0.0140 (8)	−0.0049 (7)
O8	0.0627 (11)	0.0540 (11)	0.0410 (9)	−0.0206 (9)	0.0169 (9)	−0.0069 (8)
O9	0.0670 (11)	0.0453 (10)	0.0431 (10)	−0.0002 (8)	0.0118 (9)	−0.0063 (8)
O10	0.0678 (12)	0.0510 (10)	0.0320 (8)	0.0017 (9)	0.0091 (8)	−0.0063 (8)
N1	0.0611 (14)	0.0467 (12)	0.0514 (13)	−0.0031 (11)	0.0107 (11)	−0.0121 (10)
N2	0.0641 (14)	0.0671 (15)	0.0393 (11)	−0.0048 (12)	0.0062 (11)	−0.0147 (11)
C1	0.0410 (13)	0.0605 (17)	0.0331 (12)	0.0084 (12)	0.0100 (11)	−0.0014 (11)
C2	0.0445 (14)	0.078 (2)	0.0420 (14)	0.0150 (13)	0.0045 (12)	−0.0023 (13)
C3	0.0322 (12)	0.0590 (16)	0.0387 (12)	0.0032 (11)	0.0013 (10)	0.0041 (11)
C4	0.0611 (17)	0.0649 (18)	0.0498 (15)	−0.0017 (15)	0.0137 (14)	0.0054 (14)
C5	0.083 (2)	0.092 (3)	0.0429 (16)	0.0112 (19)	0.0117 (16)	−0.0052 (16)
C6	0.074 (2)	0.078 (2)	0.071 (2)	0.0124 (19)	−0.0125 (18)	−0.0206 (19)
C7	0.093 (3)	0.056 (2)	0.096 (3)	−0.0137 (18)	−0.007 (2)	0.0070 (19)
C8	0.0679 (19)	0.080 (2)	0.0582 (18)	−0.0101 (17)	0.0067 (16)	0.0155 (16)
C9	0.0365 (12)	0.0504 (14)	0.0330 (11)	−0.0038 (11)	0.0060 (10)	−0.0046 (10)
C10	0.0472 (14)	0.0582 (16)	0.0425 (13)	−0.0089 (12)	0.0153 (12)	−0.0052 (11)
C11	0.0464 (13)	0.0417 (13)	0.0380 (12)	0.0024 (10)	0.0138 (11)	0.0048 (9)
C12	0.0477 (15)	0.082 (2)	0.0553 (17)	0.0002 (15)	0.0100 (14)	−0.0157 (15)
C13	0.076 (2)	0.116 (3)	0.065 (2)	−0.014 (2)	0.0104 (18)	−0.033 (2)
C14	0.123 (3)	0.100 (3)	0.060 (2)	−0.015 (3)	0.028 (2)	−0.0344 (19)
C15	0.107 (3)	0.078 (2)	0.082 (2)	0.008 (2)	0.057 (2)	−0.0158 (19)
C16	0.0582 (17)	0.0629 (18)	0.0646 (18)	0.0031 (14)	0.0273 (15)	−0.0022 (14)
C17	0.101 (3)	0.090 (2)	0.0547 (18)	−0.013 (2)	0.0185 (18)	−0.0226 (17)
C18	0.099 (3)	0.0539 (19)	0.084 (2)	0.0097 (18)	0.009 (2)	−0.0116 (17)
C19	0.0638 (17)	0.0456 (15)	0.0520 (15)	−0.0014 (13)	0.0156 (14)	−0.0043 (12)
C20	0.0411 (12)	0.0367 (12)	0.0403 (12)	0.0026 (10)	0.0078 (11)	−0.0040 (10)
C21	0.0551 (15)	0.0533 (16)	0.0476 (14)	0.0175 (13)	0.0062 (12)	−0.0038 (12)
C22	0.0510 (14)	0.0335 (12)	0.0446 (13)	0.0079 (10)	0.0140 (11)	0.0044 (10)
C23	0.0561 (16)	0.0502 (15)	0.0684 (18)	0.0013 (13)	0.0246 (14)	−0.0036 (13)
C24	0.069 (2)	0.0540 (18)	0.091 (2)	−0.0145 (15)	0.0175 (18)	−0.0131 (16)
C25	0.103 (3)	0.0512 (18)	0.080 (2)	−0.0021 (18)	0.027 (2)	−0.0250 (16)
C26	0.088 (2)	0.0623 (19)	0.082 (2)	0.0111 (17)	0.044 (2)	−0.0143 (17)
C27	0.0554 (15)	0.0481 (15)	0.0613 (17)	0.0064 (12)	0.0201 (14)	−0.0010 (12)
C28	0.0457 (13)	0.0336 (12)	0.0410 (12)	0.0000 (10)	0.0185 (11)	−0.0049 (9)
C29	0.0541 (14)	0.0461 (14)	0.0498 (14)	−0.0079 (12)	0.0235 (12)	−0.0069 (11)
C30	0.0401 (12)	0.0362 (12)	0.0447 (12)	−0.0041 (10)	0.0174 (11)	−0.0010 (10)
C31	0.0604 (16)	0.0480 (15)	0.0537 (15)	0.0076 (13)	0.0119 (13)	0.0034 (12)
C32	0.088 (2)	0.0437 (16)	0.088 (2)	0.0077 (15)	0.033 (2)	−0.0098 (15)
C33	0.077 (2)	0.070 (2)	0.069 (2)	−0.0173 (17)	0.0344 (18)	−0.0315 (17)
C34	0.071 (2)	0.097 (3)	0.0442 (16)	−0.0094 (19)	0.0071 (15)	−0.0107 (16)
C35	0.0646 (17)	0.0528 (16)	0.0533 (16)	0.0064 (14)	0.0125 (14)	0.0062 (13)
C36	0.124 (3)	0.072 (2)	0.078 (2)	−0.010 (2)	0.014 (2)	−0.0353 (19)
C37	0.130 (3)	0.101 (3)	0.0390 (16)	−0.007 (2)	0.0209 (19)	−0.0054 (17)
C38	0.0605 (16)	0.0589 (17)	0.0364 (13)	−0.0036 (13)	0.0076 (12)	−0.0069 (11)

Geometric parameters (Å, º)

Cu1—O1	1.9611 (19)	C12—H12	0.9300
Cu1—O2^i	1.9802 (19)	C12—C13	1.380 (4)
Cu1—O3	1.9756 (17)	C13—H13	0.9300
Cu1—O4^i	1.9546 (17)	C13—C14	1.359 (5)
Cu1—O9	2.1907 (17)	C14—H14	0.9300
Cu1—Cu1^i	2.6414 (8)	C14—C15	1.360 (5)
Cu2—O5	1.9583 (16)	C15—C16	1.384 (4)
Cu2—O6^ii	1.9719 (16)	C15—H15	0.9300
Cu2—O7	1.9529 (16)	C16—H16	0.9300
Cu2—O8^ii	1.9791 (17)	C17—H17A	0.9600
Cu2—O10	2.1609 (17)	C17—H17B	0.9600
Cu2—Cu2^ii	2.6261 (8)	C17—H17C	0.9600
O1—C1	1.258 (3)	C18—H18A	0.9600
O2—C1	1.254 (3)	C18—H18B	0.9600
O2—Cu1^i	1.9802 (19)	C18—H18C	0.9600
O3—C9	1.246 (3)	C19—H19	0.9300
O4—C9	1.260 (3)	C20—C21	1.505 (3)
O4—Cu1^i	1.9546 (17)	C21—C22	1.506 (3)
O5—C20	1.254 (3)	C21—H21A	0.9700
O6—C20	1.249 (3)	C21—H21B	0.9700
O6—Cu2^ii	1.9719 (16)	C22—C23	1.377 (3)
O7—C28	1.257 (3)	C22—C27	1.371 (3)
O8—C28	1.251 (3)	C23—C24	1.381 (4)
O8—Cu2^ii	1.9791 (17)	C23—H23	0.9300
O9—C19	1.227 (3)	C24—H24	0.9300
O10—C38	1.228 (3)	C24—C25	1.359 (4)
N1—C17	1.453 (3)	C25—C26	1.372 (5)
N1—C18	1.432 (4)	C25—H25	0.9300
N1—C19	1.320 (3)	C26—H26	0.9300
N2—C36	1.443 (4)	C26—C27	1.381 (4)
N2—C37	1.437 (4)	C27—H27	0.9300
N2—C38	1.319 (3)	C28—C29	1.517 (3)
C1—C2	1.521 (3)	C29—H29A	0.9700
C2—C3	1.501 (4)	C29—H29B	0.9700
C2—H2A	0.9700	C29—C30	1.503 (3)
C2—H2B	0.9700	C30—C31	1.370 (3)
C3—C4	1.379 (4)	C30—C35	1.381 (3)
C3—C8	1.381 (4)	C31—H30	0.9300
C4—H4	0.9300	C31—C32	1.376 (4)
C4—C5	1.384 (4)	C32—C33	1.361 (4)
C5—H5	0.9300	C32—H32	0.9300
C5—C6	1.354 (5)	C33—H33	0.9300
C6—H6	0.9300	C33—C34	1.362 (5)
C6—C7	1.364 (5)	C34—C35	1.379 (4)
C7—H7	0.9300	C34—H34	0.9300
C7—C8	1.372 (5)	C35—H35	0.9300
C8—H8	0.9300	C36—H36A	0.9600
C9—C10	1.511 (3)	C36—H36B	0.9600
C10—H10A	0.9700	C36—H36C	0.9600
C10—H10B	0.9700	C37—H37A	0.9600
C10—C11	1.512 (3)	C37—H37B	0.9600
C11—C12	1.378 (4)	C37—H37C	0.9600
C11—C16	1.375 (4)	C38—H38	0.9300
O4^i—Cu1—O1	88.65 (8)	C13—C14—H14	119.9
O4^i—Cu1—O3	167.94 (7)	C15—C14—H14	119.9
O1—Cu1—O3	90.33 (8)	C14—C15—C16	119.8 (3)
O4^i—Cu1—O2^i	89.64 (8)	C14—C15—H15	120.1
O1—Cu1—O2^i	168.10 (8)	C16—C15—H15	120.1
O3—Cu1—O2^i	88.88 (8)	C11—C16—C15	120.8 (3)
O4^i—Cu1—O9	101.21 (7)	C11—C16—H16	119.6
O1—Cu1—O9	101.28 (7)	C15—C16—H16	119.6
O3—Cu1—O9	90.78 (7)	N1—C17—H17A	109.5
O2^i—Cu1—O9	90.60 (7)	N1—C17—H17B	109.5
O7—Cu2—O5	88.94 (8)	H17A—C17—H17B	109.5
O7—Cu2—O6^ii	89.56 (8)	N1—C17—H17C	109.5
O5—Cu2—O6^ii	168.28 (7)	H17A—C17—H17C	109.5
O7—Cu2—O8^ii	168.51 (7)	H17B—C17—H17C	109.5
O5—Cu2—O8^ii	89.94 (9)	N1—C18—H18A	109.5
O6^ii—Cu2—O8^ii	89.22 (8)	N1—C18—H18B	109.5
O7—Cu2—O10	98.75 (7)	H18A—C18—H18B	109.5
O5—Cu2—O10	101.03 (7)	N1—C18—H18C	109.5
O6^ii—Cu2—O10	90.69 (7)	H18A—C18—H18C	109.5
O8^ii—Cu2—O10	92.69 (7)	H18B—C18—H18C	109.5
O4^i—Cu1—Cu1^i	86.42 (5)	O9—C19—N1	125.3 (3)
O1—Cu1—Cu1^i	85.31 (5)	O9—C19—H19	117.4
O3—Cu1—Cu1^i	81.51 (5)	N1—C19—H19	117.4
O2^i—Cu1—Cu1^i	82.84 (6)	O6—C20—O5	125.6 (2)
O9—Cu1—Cu1^i	169.94 (5)	O6—C20—C21	117.8 (2)
O7—Cu2—Cu2^ii	85.79 (5)	O5—C20—C21	116.6 (2)
O5—Cu2—Cu2^ii	85.74 (5)	C20—C21—C22	115.6 (2)
O6^ii—Cu2—Cu2^ii	82.55 (5)	C20—C21—H21A	108.4
O8^ii—Cu2—Cu2^ii	82.72 (5)	C22—C21—H21A	108.4
O10—Cu2—Cu2^ii	171.85 (5)	C20—C21—H21B	108.4
C1—O1—Cu1	122.08 (16)	C22—C21—H21B	108.4
C1—O2—Cu1^i	124.11 (17)	H21A—C21—H21B	107.4
C9—O3—Cu1	125.79 (15)	C27—C22—C23	118.3 (2)
C9—O4—Cu1^i	120.72 (16)	C27—C22—C21	120.2 (2)
C20—O5—Cu2	121.43 (15)	C23—C22—C21	121.4 (2)
C20—O6—Cu2^ii	124.58 (15)	C22—C23—C24	120.8 (3)
C28—O7—Cu2	121.64 (15)	C22—C23—H23	119.6
C28—O8—Cu2^ii	124.07 (15)	C24—C23—H23	119.6
C19—O9—Cu1	115.58 (17)	C25—C24—C23	120.6 (3)
C38—O10—Cu2	116.08 (17)	C25—C24—H24	119.7
C19—N1—C18	120.9 (2)	C23—C24—H24	119.7
C19—N1—C17	121.5 (3)	C24—C25—C26	119.1 (3)
C18—N1—C17	117.5 (2)	C24—C25—H25	120.4
C38—N2—C37	120.0 (3)	C26—C25—H25	120.4
C38—N2—C36	121.7 (3)	C25—C26—C27	120.5 (3)
C37—N2—C36	118.4 (3)	C25—C26—H26	119.8
O2—C1—O1	125.6 (2)	C27—C26—H26	119.8
O2—C1—C2	118.3 (2)	C22—C27—C26	120.7 (3)
O1—C1—C2	116.0 (2)	C22—C27—H27	119.7
C3—C2—C1	115.5 (2)	C26—C27—H27	119.7
C3—C2—H2A	108.4	O8—C28—O7	125.8 (2)
C1—C2—H2A	108.4	O8—C28—C29	117.9 (2)
C3—C2—H2B	108.4	O7—C28—C29	116.3 (2)
C1—C2—H2B	108.4	C30—C29—C28	115.70 (19)
H2A—C2—H2B	107.5	C30—C29—H29A	108.4
C4—C3—C8	116.5 (3)	C28—C29—H29A	108.4
C4—C3—C2	121.6 (3)	C30—C29—H29B	108.4
C8—C3—C2	121.9 (3)	C28—C29—H29B	108.4
C3—C4—C5	121.4 (3)	H29A—C29—H29B	107.4
C3—C4—H4	119.3	C31—C30—C35	117.8 (2)
C5—C4—H4	119.3	C31—C30—C29	121.4 (2)
C6—C5—C4	120.8 (3)	C35—C30—C29	120.8 (2)
C6—C5—H5	119.6	C30—C31—C32	121.5 (3)
C4—C5—H5	119.6	C30—C31—H30	119.2
C5—C6—C7	118.8 (3)	C32—C31—H30	119.2
C5—C6—H6	120.6	C33—C32—C31	120.2 (3)
C7—C6—H6	120.6	C33—C32—H32	119.9
C6—C7—C8	120.7 (3)	C31—C32—H32	119.9
C6—C7—H7	119.6	C32—C33—C34	119.1 (3)
C8—C7—H7	119.6	C32—C33—H33	120.5
C7—C8—C3	121.8 (3)	C34—C33—H33	120.5
C7—C8—H8	119.1	C33—C34—C35	121.0 (3)
C3—C8—H8	119.1	C33—C34—H34	119.5
O3—C9—O4	125.5 (2)	C35—C34—H34	119.5
O3—C9—C10	118.4 (2)	C34—C35—C30	120.4 (3)
O4—C9—C10	116.0 (2)	C34—C35—H35	119.8
C9—C10—C11	116.0 (2)	C30—C35—H35	119.8
C9—C10—H10A	108.3	N2—C36—H36A	109.5
C11—C10—H10A	108.3	N2—C36—H36B	109.5
C9—C10—H10B	108.3	H36A—C36—H36B	109.5
C11—C10—H10B	108.3	N2—C36—H36C	109.5
H10A—C10—H10B	107.4	H36A—C36—H36C	109.5
C16—C11—C12	118.4 (3)	H36B—C36—H36C	109.5
C16—C11—C10	119.8 (2)	N2—C37—H37A	109.5
C12—C11—C10	121.7 (2)	N2—C37—H37B	109.5
C11—C12—C13	120.5 (3)	H37A—C37—H37B	109.5
C11—C12—H12	119.8	N2—C37—H37C	109.5
C13—C12—H12	119.8	H37A—C37—H37C	109.5
C14—C13—C12	120.2 (3)	H37B—C37—H37C	109.5
C14—C13—H13	119.9	O10—C38—N2	125.2 (3)
C12—C13—H13	119.9	O10—C38—H38	117.4
C13—C14—C15	120.3 (3)	N2—C38—H38	117.4
Cu1^i—O2—C1—O1	−1.3 (4)	O8^ii—Cu2—O7—C28	2.2 (5)
Cu1^i—O2—C1—C2	−179.41 (17)	O8^ii—Cu2—O10—C38	−40.0 (2)
Cu1—O1—C1—O2	−0.1 (4)	O9—Cu1—O1—C1	−171.41 (19)
Cu1—O1—C1—C2	178.07 (16)	O9—Cu1—O3—C9	−172.86 (19)
Cu1^i—Cu1—O3—C9	0.64 (18)	O10—Cu2—O5—C20	176.54 (18)
Cu1^i—Cu1—O1—C1	0.91 (19)	O10—Cu2—O7—C28	−172.37 (18)
Cu1^i—Cu1—O9—C19	9.2 (4)	C1—C2—C3—C4	−99.5 (3)
Cu1—O3—C9—O4	−1.3 (3)	C1—C2—C3—C8	80.4 (3)
Cu1—O3—C9—C10	−179.57 (16)	C2—C3—C4—C5	179.6 (3)
Cu1^i—O4—C9—O3	1.3 (3)	C2—C3—C8—C7	−178.6 (3)
Cu1^i—O4—C9—C10	179.52 (15)	C3—C4—C5—C6	−0.8 (5)
Cu1—O9—C19—N1	−179.0 (2)	C4—C5—C6—C7	1.0 (5)
Cu2^ii—Cu2—O5—C20	1.11 (18)	C4—C3—C8—C7	1.3 (4)
Cu2^ii—Cu2—O7—C28	0.82 (17)	C5—C6—C7—C8	0.0 (5)
Cu2^ii—O6—C20—O5	4.7 (4)	C6—C7—C8—C3	−1.2 (5)
Cu2^ii—O6—C20—C21	−177.42 (17)	C8—C3—C4—C5	−0.3 (4)
Cu2—O5—C20—O6	−3.6 (4)	C9—C10—C11—C16	145.4 (2)
Cu2—O5—C20—C21	178.41 (17)	C9—C10—C11—C12	−38.0 (4)
Cu2^ii—O8—C28—O7	0.9 (4)	C10—C11—C12—C13	−175.8 (3)
Cu2^ii—O8—C28—C29	−177.38 (16)	C10—C11—C16—C15	175.7 (3)
Cu2—O7—C28—O8	−1.3 (3)	C11—C12—C13—C14	0.0 (6)
Cu2—O7—C28—C29	177.06 (15)	C12—C13—C14—C15	−0.6 (7)
Cu2—O10—C38—N2	−176.1 (2)	C12—C11—C16—C15	−1.0 (4)
O1—Cu1—O3—C9	85.85 (19)	C13—C14—C15—C16	0.4 (6)
O1—C1—C2—C3	151.5 (2)	C16—C11—C12—C13	0.8 (5)
O2^i—Cu1—O3—C9	−82.28 (19)	C17—N1—C19—O9	−179.2 (3)
O2^i—Cu1—O1—C1	5.6 (5)	C18—N1—C19—O9	2.6 (4)
O2^i—Cu1—O9—C19	−39.9 (2)	C20—C21—C22—C27	−136.0 (3)
O2—C1—C2—C3	−30.1 (4)	C20—C21—C22—C23	44.9 (3)
O3—Cu1—O1—C1	−80.54 (19)	C21—C22—C23—C24	179.9 (3)
O1—Cu1—O9—C19	139.51 (19)	C21—C22—C27—C26	−179.6 (3)
O3—Cu1—O9—C19	49.0 (2)	C22—C23—C24—C25	0.0 (5)
O3—C9—C10—C11	−43.1 (3)	C23—C24—C25—C26	−1.0 (5)
O4—C9—C10—C11	138.5 (2)	C23—C22—C27—C26	−0.5 (4)
O4^i—Cu1—O1—C1	87.43 (19)	C24—C25—C26—C27	1.3 (5)
O4^i—Cu1—O3—C9	0.7 (5)	C25—C26—C27—C22	−0.5 (5)
O4^i—Cu1—O9—C19	−129.63 (19)	C27—C22—C23—C24	0.8 (4)
O5—Cu2—O7—C28	86.63 (18)	C28—C29—C30—C31	−95.3 (3)
O5—Cu2—O10—C38	−130.5 (2)	C28—C29—C30—C35	86.1 (3)
O5—C20—C21—C22	−147.4 (2)	C29—C30—C31—C32	−177.5 (2)
O6^ii—Cu2—O10—C38	49.2 (2)	C29—C30—C35—C34	178.4 (2)
O6^ii—Cu2—O7—C28	−81.75 (18)	C30—C31—C32—C33	−0.8 (5)
O6^ii—Cu2—O5—C20	−2.0 (5)	C31—C32—C33—C34	−0.6 (5)
O6—C20—C21—C22	34.5 (3)	C31—C30—C35—C34	−0.2 (4)
O7—Cu2—O10—C38	138.87 (19)	C32—C33—C34—C35	1.5 (5)
O7—Cu2—O5—C20	−84.75 (19)	C33—C34—C35—C30	−1.1 (5)
O7—C28—C29—C30	144.8 (2)	C35—C30—C31—C32	1.2 (4)
O8—C28—C29—C30	−36.7 (3)	C36—N2—C38—O10	−179.5 (3)
O8^ii—Cu2—O5—C20	83.81 (19)	C37—N2—C38—O10	1.6 (5)
O8^ii—Cu2—O7—C28	2.2 (5)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+1, −z+1.