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The structure refined as [H3O]+·[[(C12H8N2)VIV(=O)O]2(H2AsO4)] by Zheng, Zhang & Yang [J. Chem. Crystallogr. (2005). 34, 267–273] is rerefined as [V2O4(HAsO4)(C12H8N2)2]·H2O, whose crystal structure features a disordered [HAsO4]2− group that links the dinuclear mol­ecules through O—H...O hydrogen bonds into a chain running along the a axis.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807010082/xu2216sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807010082/xu2216Isup2.hkl
Contains datablock I

CCDC reference: 643676

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.050
  • wR factor = 0.113
  • Data-to-parameter ratio = 15.2

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT432_ALERT_2_B Short Inter X...Y Contact O1W .. C13 .. 2.91 Ang.
Alert level C CRYSC01_ALERT_1_C The word below has not been recognised as a standard identifier. Yellowish PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 2
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: CrystalClear (Rigaku Corporation, 2000); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: atomic coordinates from published structure; program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2007).

µ-Hydrogenarsenato-κ2O:O'-di-µ-oxo-κ4O:O-bis[oxo(1,10- phenanthroline-κ2N,N')vanadium(V)] monohydrate top
Crystal data top
[V2O4(HAsO4)(C12H8N2)2]·H2OF(000) = 1368
Mr = 684.23Dx = 1.879 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 7834 reflections
a = 9.175 (2) Åθ = 2.5–27.5°
b = 18.638 (5) ŵ = 2.20 mm1
c = 14.482 (4) ÅT = 295 K
β = 102.333 (3)°Prism, yellow–green
V = 2419 (1) Å30.45 × 0.13 × 0.10 mm
Z = 4
Data collection top
Rigaku Mercury
diffractometer
5517 independent reflections
Radiation source: medium-focus sealed tube5151 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.031
ω scansθmax = 27.5°, θmin = 2.5°
Absorption correction: multi-scan
(Jacobson, 1998)
h = 1111
Tmin = 0.717, Tmax = 0.803k = 2424
18641 measured reflectionsl = 1818
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.050Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.113H-atom parameters constrained
S = 1.24 w = 1/[σ2(Fo2) + (0.0158P)2 + 13.118P]
where P = (Fo2 + 2Fc2)/3
5517 reflections(Δ/σ)max = 0.001
363 parametersΔρmax = 0.65 e Å3
6 restraintsΔρmin = 0.91 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
As10.71488 (5)0.49891 (2)0.41755 (3)0.0124 (1)
V10.71507 (8)0.48151 (4)0.19344 (5)0.0146 (2)
V20.68297 (8)0.34485 (4)0.30780 (5)0.0136 (2)
O10.8636 (3)0.5141 (2)0.5051 (2)0.0218 (7)
O20.5651 (3)0.5401 (2)0.4433 (2)0.0189 (6)
O30.6744 (3)0.4102 (2)0.4076 (2)0.0171 (6)
O40.7488 (4)0.5293 (2)0.3142 (2)0.0182 (6)
O50.7396 (4)0.2733 (2)0.3684 (2)0.0223 (7)
O60.8279 (3)0.3767 (2)0.2689 (2)0.0166 (6)
O70.5698 (3)0.4295 (2)0.1992 (2)0.0178 (6)
O80.6495 (4)0.5477 (2)0.1255 (2)0.0213 (7)
O1w0.9109 (6)0.1756 (3)0.2749 (5)0.077 (2)
N10.7692 (4)0.4237 (2)0.0762 (2)0.0177 (7)
N20.9576 (4)0.4974 (2)0.2056 (2)0.0151 (7)
N30.6018 (4)0.2786 (2)0.1874 (3)0.0169 (7)
N40.4401 (4)0.3327 (2)0.3012 (2)0.0140 (7)
C10.6709 (5)0.3903 (3)0.0096 (3)0.0220 (9)
C20.7128 (6)0.3516 (3)0.0632 (3)0.027 (1)
C30.8603 (6)0.3465 (3)0.0666 (3)0.026 (1)
C40.9675 (5)0.3830 (2)0.0008 (3)0.020 (1)
C50.9162 (5)0.4217 (2)0.0711 (3)0.015 (1)
C61.0183 (5)0.4618 (2)0.1404 (3)0.015 (1)
C71.1250 (6)0.3849 (2)0.0011 (3)0.024 (1)
C81.2204 (5)0.4239 (3)0.0662 (3)0.023 (1)
C91.1698 (5)0.4636 (2)0.1385 (3)0.019 (1)
C101.2640 (5)0.5040 (2)0.2087 (3)0.021 (1)
C111.2044 (5)0.5385 (2)0.2758 (3)0.022 (1)
C121.0506 (5)0.5342 (2)0.2725 (3)0.020 (1)
C130.6879 (5)0.2497 (2)0.1346 (3)0.021 (1)
C140.6348 (5)0.1994 (3)0.0637 (3)0.023 (1)
C150.4863 (5)0.1806 (2)0.0443 (3)0.021 (1)
C160.3914 (5)0.2114 (2)0.0980 (3)0.017 (1)
C170.4551 (5)0.2589 (2)0.1700 (3)0.014 (1)
C180.2342 (5)0.1954 (2)0.0845 (3)0.020 (1)
C190.1507 (5)0.2248 (2)0.1413 (3)0.019 (1)
C200.3676 (5)0.2891 (2)0.2305 (3)0.013 (1)
C210.2136 (5)0.2735 (2)0.2156 (3)0.015 (1)
C220.1320 (5)0.3083 (2)0.2750 (3)0.016 (1)
C230.2056 (5)0.3546 (2)0.3438 (3)0.017 (1)
C240.3594 (5)0.3640 (2)0.3562 (3)0.017 (1)
H1o0.94170.51600.48250.026*0.50
H2o0.53050.51480.48250.023*0.50
H1w10.86270.20710.29970.092*
H1w20.89740.13520.30190.092*
H10.57030.39280.01130.026*
H20.64070.32920.10910.033*
H30.88940.31920.11320.032*
H71.16130.35910.04410.028*
H81.32100.42500.06420.028*
H101.36540.50730.20970.025*
H111.26580.56470.32340.027*
H121.01210.55790.31850.023*
H130.78750.26340.14510.025*
H140.69950.17870.02980.028*
H150.44920.14800.00360.025*
H180.18980.16450.03620.024*
H190.05000.21310.13180.023*
H220.03020.30010.26780.019*
H230.15290.37940.38170.020*
H240.40770.39340.40510.020*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
As10.0129 (2)0.0140 (2)0.0107 (2)0.0022 (2)0.0037 (2)0.0022 (2)
V10.0133 (4)0.0186 (4)0.0129 (3)0.0021 (3)0.0051 (3)0.0015 (3)
V20.0135 (3)0.0147 (3)0.0124 (3)0.0008 (3)0.0022 (3)0.0021 (3)
O10.015 (2)0.030 (2)0.019 (2)0.003 (1)0.000 (1)0.006 (13)
O20.017 (2)0.020 (2)0.022 (2)0.0041 (2)0.010 (1)0.001 (1)
O30.022 (2)0.016 (1)0.01 (1)0.003 (1)0.005 (12)0.001 (11)
O40.026 (2)0.017 (2)0.015 (2)0.003 (1)0.011 (1)0.001 (1)
O50.029 (2)0.017 (2)0.020 (2)0.001 (1)0.003 (1)0.001 (1)
O60.014 (2)0.019 (2)0.016 (1)0.000 (1)0.002 (1)0.002 (1)
O70.014 (2)0.022 (2)0.017 (2)0.002 (1)0.00 (1)0.001 (1)
O80.021 (2)0.026 (2)0.019 (2)0.006 (1)0.008 (1)0.006 (1)
O1w0.060 (3)0.061 (3)0.108 (4)0.001 (3)0.016 (3)0.029 (3)
N10.018 (2)0.022 (2)0.013 (2)0.001 (2)0.003 (1)0.002 (1)
N20.017 (2)0.017 (2)0.013 (2)0.002 (1)0.007 (2)0.001 (1)
N30.016 (2)0.018 (2)0.017 (2)0.001 (1)0.005 (2)0.004 (1)
N40.014 (2)0.013 (2)0.016 (2)0.002 (1)0.005 (1)0.001 (1)
C10.019 (2)0.028 (2)0.018 (2)0.001 (2)0.000 (2)0.002 (2)
C20.034 (3)0.030 (3)0.017 (2)0.005 (2)0.003 (2)0.004 (2)
C30.043 (3)0.023 (2)0.015 (2)0.005 (2)0.010 (2)0.001 (2)
C40.031 (3)0.017 (2)0.015 (2)0.006 (2)0.009 (2)0.004 (2)
C50.016 (2)0.016 (2)0.016 (2)0.002 (2)0.006 (2)0.004 (2)
C60.016 (2)0.017 (2)0.013 (2)0.003 (2)0.005 (2)0.004 (2)
C70.032 (3)0.022 (2)0.021 (2)0.012 (2)0.016 (2)0.006 (2)
C80.023 (2)0.027 (2)0.025 (2)0.010 (2)0.014 (2)0.008 (2)
C90.020 (2)0.019 (2)0.019 (2)0.005 (2)0.008 (2)0.009 (2)
C100.011 (2)0.021 (2)0.031 (2)0.000 (2)0.005 (2)0.009 (2)
C110.021 (2)0.019 (2)0.026 (2)0.005 (2)0.006 (2)0.000 (2)
C120.023 (2)0.019 (2)0.018 (2)0.004 (2)0.006 (2)0.003 (2)
C130.018 (2)0.025 (2)0.021 (2)0.001 (2)0.005 (2)0.008 (2)
C140.026 (2)0.025 (2)0.021 (2)0.002 (2)0.010 (2)0.009 (2)
C150.024 (2)0.019 (2)0.017 (2)0.002 (2)0.000 (2)0.004 (2)
C160.018 (2)0.0152 (19)0.015 (2)0.002 (2)0.000 (2)0.000 (2)
C170.015 (2)0.0120 (19)0.014 (2)0.000 (2)0.002 (2)0.001 (2)
C180.020 (2)0.019 (2)0.018 (2)0.002 (2)0.002 (2)0.005 (2)
C190.015 (2)0.021 (2)0.021 (2)0.002 (2)0.001 (2)0.002 (2)
C200.014 (2)0.0193 (2)0.012 (2)0.003 (2)0.001 (2)0.000 (1)
C210.015 (2)0.013 (2)0.016 (2)0.000 (2)0.002 (2)0.001 (2)
C220.011 (2)0.018 (2)0.019 (2)0.001 (2)0.004 (2)0.004 (2)
C230.021 (2)0.017 (2)0.015 (2)0.005 (2)0.008 (2)0.003 (2)
C240.020 (2)0.017 (2)0.013 (2)0.003 (2)0.003 (2)0.002 (2)
Geometric parameters (Å, º) top
As1—O11.676 (3)C10—C111.374 (6)
As1—O21.684 (3)C11—C121.403 (6)
As1—O31.694 (3)C13—C141.400 (6)
As1—O41.690 (3)C14—C151.376 (7)
V1—O41.928 (3)C15—C161.408 (6)
V1—O62.367 (3)C16—C171.397 (6)
V1—O71.664 (3)C16—C181.444 (6)
V1—O81.612 (3)C17—C201.425 (6)
V1—N12.156 (4)C18—C191.354 (6)
V1—N22.214 (4)C19—C211.431 (6)
V2—O31.904 (3)C20—C211.413 (6)
V2—O51.620 (3)C21—C221.413 (6)
V2—O61.661 (3)C22—C231.381 (6)
V2—N32.137 (4)C23—C241.394 (6)
V2—N42.222 (4)O1—H1o0.85
V2—O72.312 (3)O2—H2o0.85
N1—C11.327 (6)O1w—H1w10.86
N1—C51.367 (6)O1w—H1w20.87
N2—C121.336 (6)C1—H10.93
N2—C61.367 (5)C2—H20.93
N3—C131.324 (6)C3—H30.93
N3—C171.366 (5)C7—H70.93
N4—C241.332 (5)C8—H80.93
N4—C201.364 (5)C10—H100.93
C1—C21.397 (7)C11—H110.93
C2—C31.368 (7)C12—H120.93
C3—C41.404 (7)C13—H130.93
C4—C51.408 (6)C14—H140.93
C4—C71.445 (7)C15—H150.93
C5—C61.429 (6)C18—H180.93
C6—C91.397 (6)C19—H190.93
C7—C81.353 (7)C22—H220.93
C8—C91.437 (6)C23—H230.93
C9—C101.404 (7)C24—H240.93
O1—As1—O2109.0 (2)C8—C7—C4120.9 (4)
O1—As1—O3111.0 (2)C7—C8—C9121.5 (4)
O1—As1—O4109.8 (2)C6—C9—C10117.3 (4)
O2—As1—O3106.8 (2)C6—C9—C8118.7 (4)
O2—As1—O4110.9 (2)C10—C9—C8124.0 (4)
O3—As1—O4109.3 (1)C11—C10—C9119.2 (4)
O4—V1—O689.6 (1)C10—C11—C12119.9 (4)
O4—V1—O7101.5 (1)N2—C12—C11122.5 (4)
O4—V1—O899.6 (2)N3—C13—C14122.6 (4)
O4—V1—N1157.8 (1)C15—C14—C13119.6 (4)
O4—V1—N284.4 (1)C14—C15—C16119.1 (4)
O6—V1—O776.8 (1)C17—C16—C15117.4 (4)
O6—V1—O8169.4 (1)C17—C16—C18118.6 (4)
O6—V1—N178.5 (1)C15—C16—C18124.0 (4)
O6—V1—N275.0 (1)N3—C17—C16123.1 (4)
O7—V1—O8106.1 (2)N3—C17—C20116.3 (4)
O7—V1—N194.0 (2)C16—C17—C20120.6 (4)
O7—V1—N2151.2 (1)C19—C18—C16120.9 (4)
O8—V1—N191.1 (2)C18—C19—C21121.5 (4)
O8—V1—N2100.6 (2)N4—C20—C21123.3 (4)
N1—V1—N274.5 (1)N4—C20—C17116.7 (4)
O3—V2—O5100.2 (2)C21—C20—C17120.0 (4)
O3—V2—O6101.2 (1)C22—C21—C20117.0 (4)
O3—V2—O789.7 (1)C22—C21—C19124.6 (4)
O3—V2—N3157.7 (1)C20—C21—C19118.4 (4)
O3—V2—N483.9 (1)C23—C22—C21119.0 (4)
O5—V2—O6106.9 (2)C22—C23—C24119.9 (4)
O5—V2—O7167.4 (1)N4—C24—C23122.9 (4)
O5—V2—N388.9 (2)As1—O1—H1o109.5
O5—V2—N498.2 (2)As1—O2—H2o109.5
O6—V2—O778.5 (1)H1w1—O1w—H1w2105.6
O6—V2—N395.4 (1)N1—C1—H1118.8
O6—V2—N4152.9 (1)C2—C1—H1118.8
O7—V2—N379.1 (1)C3—C2—H2120.1
O7—V2—N474.9 (1)C1—C2—H2120.1
N3—V2—N474.6 (1)C2—C3—H3120.2
As1—O3—V2130.2 (2)C4—C3—H3120.2
As1—O4—V1128.6 (2)C8—C7—H7119.6
V2—O6—V198.5 (1)C4—C7—H7119.6
V1—O7—V2100.6 (1)C7—C8—H8119.3
C1—N1—C5118.2 (4)C9—C8—H8119.3
C1—N1—V1124.9 (3)C11—C10—H10120.4
C5—N1—V1116.9 (3)C9—C10—H10120.4
C12—N2—C6117.3 (4)C10—C11—H11120.1
C12—N2—V1127.0 (3)C12—C11—H11120.1
C6—N2—V1115.5 (3)N2—C12—H12118.8
C13—N3—C17118.0 (4)C11—C12—H12118.8
C13—N3—V2124.0 (3)N3—C13—H13118.7
C17—N3—V2117.6 (3)C14—C13—H13118.7
C24—N4—C20117.7 (4)C15—C14—H14120.2
C24—N4—V2127.6 (3)C13—C14—H14120.2
C20—N4—V2114.6 (3)C14—C15—H15120.5
N1—C1—C2122.5 (5)C16—C15—H15120.5
C3—C2—C1119.8 (5)C19—C18—H18119.6
C2—C3—C4119.6 (4)C16—C18—H18119.6
C3—C4—C5117.2 (4)C18—C19—H19119.2
C3—C4—C7124.5 (4)C21—C19—H19119.2
C5—C4—C7118.3 (4)C23—C22—H22120.5
N1—C5—C4122.7 (4)C21—C22—H22120.5
N1—C5—C6117.0 (4)C22—C23—H23120.1
C4—C5—C6120.4 (4)C24—C23—H23120.1
N2—C6—C9123.8 (4)N4—C24—H24118.5
N2—C6—C5115.9 (4)C23—C24—H24118.5
C9—C6—C5120.3 (4)
O1—As1—O3—V2114.2 (2)O5—V2—N4—C2083.9 (3)
O2—As1—O3—V2127.1 (2)O6—V2—N4—C2073.8 (4)
O4—As1—O3—V27.1 (3)O3—V2—N4—C20176.7 (3)
O5—V2—O3—As1143.5 (2)N3—V2—N4—C202.7 (3)
O6—V2—O3—As133.9 (3)O7—V2—N4—C2085.4 (3)
N3—V2—O3—As1103.7 (4)V1—V2—N4—C2094.2 (3)
N4—V2—O3—As1119.2 (2)C5—N1—C1—C22.1 (7)
O7—V2—O3—As144.4 (2)V1—N1—C1—C2177.7 (3)
V1—V2—O3—As112.8 (2)N1—C1—C2—C30.7 (7)
O1—As1—O4—V1132.8 (2)C1—C2—C3—C42.7 (7)
O2—As1—O4—V1106.6 (2)C2—C3—C4—C51.9 (7)
O3—As1—O4—V110.9 (3)C2—C3—C4—C7176.4 (4)
O8—V1—O4—As1138.6 (2)C1—N1—C5—C42.9 (6)
O7—V1—O4—As129.8 (3)V1—N1—C5—C4176.9 (3)
N1—V1—O4—As1103.6 (4)C1—N1—C5—C6176.2 (4)
N2—V1—O4—As1121.6 (2)V1—N1—C5—C64.0 (5)
O6—V1—O4—As146.7 (2)C3—C4—C5—N10.9 (6)
V2—V1—O4—As114.8 (2)C7—C4—C5—N1179.4 (4)
O5—V2—O6—V1176.9 (1)C3—C4—C5—C6178.2 (4)
O3—V2—O6—V172.5 (1)C7—C4—C5—C60.3 (6)
N3—V2—O6—V192.6 (1)C12—N2—C6—C91.8 (6)
N4—V2—O6—V126.2 (3)V1—N2—C6—C9178.0 (3)
O7—V2—O6—V114.9 (1)C12—N2—C6—C5178.6 (4)
O8—V1—O6—V2128.4 (8)V1—N2—C6—C52.4 (5)
O7—V1—O6—V221.0 (2)N1—C5—C6—N20.9 (5)
O4—V1—O6—V280.9 (2)C4—C5—C6—N2179.9 (4)
N1—V1—O6—V2118.0 (2)N1—C5—C6—C9178.6 (4)
N2—V1—O6—V2165.2 (2)C4—C5—C6—C90.5 (6)
O8—V1—O7—V2175.5 (1)C3—C4—C7—C8177.2 (4)
O4—V1—O7—V271.8 (1)C5—C4—C7—C81.1 (6)
N1—V1—O7—V292.2 (1)C4—C7—C8—C91.2 (7)
N2—V1—O7—V227.5 (3)N2—C6—C9—C100.6 (6)
O6—V1—O7—V215.0 (1)C5—C6—C9—C10179.9 (4)
O5—V2—O7—V1138.3 (6)N2—C6—C9—C8180.0 (4)
O6—V2—O7—V121.5 (2)C5—C6—C9—C80.5 (6)
O3—V2—O7—V180.0 (2)C7—C8—C9—C60.4 (6)
N3—V2—O7—V1119.4 (2)C7—C8—C9—C10179.0 (4)
N4—V2—O7—V1163.8 (2)C6—C9—C10—C111.0 (6)
O8—V1—N1—C175.6 (4)C8—C9—C10—C11178.4 (4)
O7—V1—N1—C130.6 (4)C9—C10—C11—C121.2 (7)
O4—V1—N1—C1165.0 (4)C6—N2—C12—C111.6 (6)
N2—V1—N1—C1176.3 (4)V1—N2—C12—C11177.3 (3)
O6—V1—N1—C1106.3 (4)C10—C11—C12—N20.1 (7)
V2—V1—N1—C178.1 (4)C17—N3—C13—C141.2 (7)
O8—V1—N1—C5104.5 (3)V2—N3—C13—C14171.7 (4)
O7—V1—N1—C5149.2 (3)N3—C13—C14—C152.7 (7)
O4—V1—N1—C514.8 (5)C13—C14—C15—C161.4 (7)
N2—V1—N1—C53.9 (3)C14—C15—C16—C171.2 (6)
O6—V1—N1—C573.6 (3)C14—C15—C16—C18179.5 (4)
V2—V1—N1—C5101.7 (3)C13—N3—C17—C161.6 (6)
O8—V1—N2—C1292.7 (4)V2—N3—C17—C16175.0 (3)
O7—V1—N2—C12109.7 (4)C13—N3—C17—C20177.7 (4)
O4—V1—N2—C126.1 (4)V2—N3—C17—C204.4 (5)
N1—V1—N2—C12179.1 (4)C15—C16—C17—N32.8 (6)
O6—V1—N2—C1297.2 (4)C18—C16—C17—N3178.8 (4)
V2—V1—N2—C1289.0 (4)C15—C16—C17—C20176.5 (4)
O8—V1—N2—C691.5 (3)C18—C16—C17—C201.9 (6)
O7—V1—N2—C666.0 (4)C17—C16—C18—C191.1 (6)
O4—V1—N2—C6169.7 (3)C15—C16—C18—C19177.2 (4)
N1—V1—N2—C63.3 (3)C16—C18—C19—C211.0 (7)
O6—V1—N2—C678.6 (3)C24—N4—C20—C212.5 (6)
V2—V1—N2—C686.7 (3)V2—N4—C20—C21178.9 (3)
O5—V2—N3—C1377.9 (4)C24—N4—C20—C17177.2 (4)
O6—V2—N3—C1328.9 (4)V2—N4—C20—C171.4 (5)
O3—V2—N3—C13167.3 (4)N3—C17—C20—N41.8 (5)
N4—V2—N3—C13176.7 (4)C16—C17—C20—N4177.5 (4)
O7—V2—N3—C13106.1 (4)N3—C17—C20—C21177.9 (4)
V1—V2—N3—C1378.5 (4)C16—C17—C20—C212.7 (6)
O5—V2—N3—C1795.0 (3)N4—C20—C21—C223.1 (6)
O6—V2—N3—C17158.2 (3)C17—C20—C21—C22176.6 (4)
O3—V2—N3—C1719.8 (6)N4—C20—C21—C19177.7 (4)
N4—V2—N3—C173.8 (3)C17—C20—C21—C192.6 (6)
O7—V2—N3—C1780.9 (3)C18—C19—C21—C22177.4 (4)
V1—V2—N3—C17108.6 (3)C18—C19—C21—C201.8 (6)
O5—V2—N4—C2497.6 (4)C20—C21—C22—C230.4 (6)
O6—V2—N4—C24104.6 (4)C19—C21—C22—C23179.6 (4)
O3—V2—N4—C241.8 (3)C21—C22—C23—C242.6 (6)
N3—V2—N4—C24175.8 (4)C20—N4—C24—C230.8 (6)
O7—V2—N4—C2493.1 (4)V2—N4—C24—C23177.7 (3)
V1—V2—N4—C2484.3 (3)C22—C23—C24—N43.4 (6)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1o···O1i0.851.842.593 (6)146
O2—H2o···O2ii0.851.842.683 (6)173
O1w—H1w1···O50.862.062.920 (7)173
O1w—H1w2···O8iii0.872.042.901 (6)173
Symmetry codes: (i) x+2, y+1, z+1; (ii) x+1, y+1, z+1; (iii) x+3/2, y1/2, z+1/2.
 

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