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The CoII ion in the title compound, [Co(C24H20N3O)2], is chelated by two deprotonated monoanions through their amido N and carbonyl O atoms in a distorted tetra­hedral geometry.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806005186/xu2004sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806005186/xu2004Isup2.hkl
Contains datablock I

CCDC reference: 601271

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.005 Å
  • R factor = 0.058
  • wR factor = 0.155
  • Data-to-parameter ratio = 21.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT241_ALERT_2_B Check High Ueq as Compared to Neighbors for C5
Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.25 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.30 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for C20 - C24 .. 6.45 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C14 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C22 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C1 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C12 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C20
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 8 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis{5-methyl-2-phenyl-4-[(3-tolylamino-κN)phenylmethylene]-1H-pyrazol-3(4H)- onato-κO}cobalt(II) top
Crystal data top
[Co(C24H20N2O)2]Z = 2
Mr = 791.79F(000) = 826
Triclinic, P1Dx = 1.270 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.0829 (5) ÅCell parameters from 3856 reflections
b = 12.2184 (7) Åθ = 2.3–20.4°
c = 17.857 (1) ŵ = 0.46 mm1
α = 99.864 (1)°T = 295 K
β = 94.422 (1)°Block, red
γ = 105.554 (1)°0.30 × 0.20 × 0.12 mm
V = 2070.4 (2) Å3
Data collection top
Bruker APEX area-detector
diffractometer
9382 independent reflections
Radiation source: fine-focus sealed tube5098 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.075
φ and ω scansθmax = 27.5°, θmin = 1.2°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1313
Tmin = 0.874, Tmax = 0.947k = 1515
24322 measured reflectionsl = 2323
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.058Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.155H-atom parameters constrained
S = 0.88 w = 1/[σ2(Fo2) + (0.0724P)2]
where P = (Fo2 + 2Fc2)/3
9382 reflections(Δ/σ)max = 0.001
446 parametersΔρmax = 0.33 e Å3
288 restraintsΔρmin = 0.37 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.60088 (4)0.60520 (4)0.25139 (2)0.04938 (16)
O10.7430 (2)0.7038 (2)0.2063 (1)0.0567 (6)
O20.6194 (2)0.4571 (2)0.2669 (1)0.0557 (6)
N10.8055 (3)0.8025 (2)0.1088 (2)0.0606 (7)
N20.7451 (4)0.8213 (3)0.0418 (2)0.0769 (9)
N30.4437 (3)0.5916 (2)0.1743 (1)0.0514 (7)
N40.7190 (3)0.3619 (2)0.3467 (1)0.0504 (6)
N50.7800 (3)0.3815 (3)0.4223 (2)0.0603 (7)
N60.6021 (3)0.6729 (2)0.3606 (1)0.0474 (6)
C10.9474 (2)0.8598 (2)0.1327 (2)0.067 (1)
C21.0209 (3)0.8371 (2)0.1945 (2)0.082 (1)
C31.1610 (3)0.8957 (3)0.2155 (2)0.096 (1)
C41.2276 (2)0.9769 (3)0.1747 (2)0.111 (2)
C51.1541 (4)0.9996 (3)0.1129 (2)0.143 (2)
C61.0141 (3)0.9410 (3)0.0919 (2)0.113 (2)
C70.7096 (3)0.7339 (3)0.1438 (2)0.051 (1)
C80.5810 (4)0.7077 (3)0.0982 (2)0.053 (1)
C90.6128 (5)0.7657 (4)0.0358 (2)0.072 (1)
C100.5201 (5)0.7704 (5)0.0333 (2)0.119 (2)
C110.4518 (3)0.6383 (3)0.1133 (2)0.051 (1)
C120.3265 (2)0.6182 (2)0.0576 (1)0.057 (1)
C130.2891 (3)0.5213 (2)0.0016 (2)0.092 (1)
C140.1773 (3)0.5055 (3)0.0570 (2)0.127 (2)
C150.1030 (3)0.5866 (3)0.0532 (2)0.128 (2)
C160.1403 (3)0.6835 (3)0.0061 (2)0.110 (2)
C170.2521 (3)0.6993 (2)0.0615 (1)0.082 (1)
C180.3135 (2)0.5270 (2)0.1911 (1)0.062 (1)
C190.2304 (3)0.5834 (2)0.2316 (1)0.071 (1)
C200.1084 (3)0.5194 (3)0.2532 (2)0.096 (2)
C210.0695 (3)0.3990 (3)0.2342 (2)0.129 (2)
C220.1526 (4)0.3426 (2)0.1937 (2)0.142 (2)
C230.2746 (3)0.4066 (2)0.1721 (2)0.101 (2)
C240.0167 (5)0.5805 (6)0.2936 (3)0.147 (2)
C250.7219 (2)0.2611 (2)0.2957 (1)0.052 (1)
C260.6349 (2)0.2211 (2)0.2265 (1)0.074 (1)
C270.6434 (3)0.1236 (2)0.1763 (1)0.089 (1)
C280.7389 (3)0.0659 (2)0.1953 (1)0.084 (1)
C290.8258 (2)0.1059 (2)0.2645 (2)0.075 (1)
C300.8174 (2)0.2034 (2)0.3147 (1)0.065 (1)
C310.6723 (3)0.4528 (3)0.3334 (2)0.046 (1)
C320.6996 (3)0.5331 (3)0.4039 (2)0.046 (1)
C330.7689 (3)0.4820 (3)0.4555 (2)0.055 (1)
C340.8309 (5)0.5256 (4)0.5382 (2)0.085 (1)
C350.6602 (3)0.6378 (3)0.4170 (2)0.045 (1)
C360.6948 (2)0.7103 (2)0.4959 (1)0.052 (1)
C370.8149 (2)0.8031 (2)0.5109 (2)0.076 (1)
C380.8594 (3)0.8667 (2)0.5852 (2)0.102 (2)
C390.7838 (4)0.8375 (3)0.6444 (1)0.104 (2)
C400.6638 (3)0.7447 (3)0.6293 (1)0.102 (2)
C410.6193 (2)0.6811 (2)0.5551 (1)0.079 (1)
C420.5453 (2)0.7689 (2)0.3750 (1)0.048 (1)
C430.4358 (2)0.7657 (2)0.4181 (1)0.056 (1)
C440.3759 (2)0.8564 (2)0.4266 (1)0.063 (1)
C450.4255 (3)0.9503 (2)0.3920 (1)0.075 (1)
C460.5350 (3)0.9535 (2)0.3488 (1)0.084 (1)
C470.5949 (2)0.8628 (2)0.3403 (1)0.066 (1)
C480.2551 (4)0.8530 (4)0.4725 (2)0.097 (1)
H20.97630.78270.22170.098*
H31.21010.88050.25690.115*
H41.32131.01620.18880.133*
H51.19871.05400.08560.172*
H60.96490.95620.05050.136*
H10a0.57540.81090.06690.179*
H10b0.45400.81030.01700.179*
H10c0.47170.69300.05990.179*
H130.33890.46700.00420.110*
H140.15230.44070.09670.152*
H150.02820.57610.09030.154*
H160.09060.73770.00860.132*
H170.27710.76410.10110.099*
H190.25640.66400.24430.086*
H210.01210.35620.24860.155*
H220.12660.26210.18100.171*
H230.33010.36880.14500.122*
H24a0.06930.65860.31650.221*
H24b0.01980.54070.33280.221*
H24c0.05860.58150.25760.221*
H260.57110.25970.21370.089*
H270.58520.09680.12990.106*
H280.74450.00070.16170.101*
H290.88970.06730.27730.090*
H300.87550.23020.36100.078*
H34a0.88100.47470.55350.128*
H34b0.75810.52760.56950.128*
H34c0.89310.60220.54430.128*
H370.86540.82260.47130.091*
H380.93970.92870.59530.123*
H390.81360.88000.69410.125*
H400.61320.72520.66890.123*
H410.53890.61910.54500.095*
H430.40260.70290.44130.067*
H450.38541.01100.39760.090*
H460.56821.01630.32570.101*
H470.66820.86490.31150.080*
H48a0.26610.92880.50250.145*
H48b0.25260.79900.50590.145*
H48c0.16990.82920.43820.145*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0563 (3)0.0572 (3)0.0410 (3)0.0198 (2)0.00660 (19)0.0209 (2)
O10.060 (1)0.066 (1)0.048 (1)0.016 (1)0.007 (1)0.024 (1)
O20.074 (2)0.057 (1)0.043 (1)0.028 (1)0.001 (1)0.016 (1)
N10.075 (2)0.058 (2)0.057 (2)0.021 (2)0.025 (2)0.023 (1)
N20.098 (3)0.088 (2)0.062 (2)0.034 (2)0.030 (2)0.039 (2)
N30.054 (2)0.056 (2)0.047 (2)0.013 (1)0.005 (1)0.020 (1)
N40.058 (2)0.052 (2)0.047 (2)0.024 (1)0.002 (1)0.016 (1)
N50.070 (2)0.066 (2)0.052 (2)0.028 (2)0.003 (1)0.020 (2)
N60.056 (2)0.050 (2)0.042 (1)0.020 (1)0.006 (1)0.017 (1)
C10.077 (3)0.053 (2)0.073 (2)0.016 (2)0.034 (2)0.009 (2)
C20.068 (3)0.074 (3)0.096 (3)0.006 (2)0.019 (2)0.014 (2)
C30.079 (3)0.086 (3)0.107 (3)0.011 (2)0.018 (3)0.006 (3)
C40.090 (3)0.087 (3)0.127 (4)0.011 (3)0.052 (3)0.015 (3)
C50.131 (5)0.138 (5)0.139 (5)0.016 (4)0.061 (4)0.038 (4)
C60.110 (4)0.115 (4)0.108 (4)0.002 (3)0.048 (3)0.045 (3)
C70.068 (2)0.049 (2)0.044 (2)0.023 (2)0.021 (2)0.013 (2)
C80.069 (2)0.061 (2)0.040 (2)0.028 (2)0.015 (2)0.019 (2)
C90.091 (3)0.088 (3)0.052 (2)0.038 (2)0.018 (2)0.034 (2)
C100.124 (4)0.183 (5)0.077 (3)0.050 (3)0.017 (3)0.084 (3)
C110.066 (2)0.051 (2)0.040 (2)0.026 (2)0.003 (2)0.008 (2)
C120.067 (2)0.069 (2)0.041 (2)0.032 (2)0.002 (2)0.008 (2)
C130.106 (3)0.094 (3)0.075 (3)0.056 (3)0.017 (2)0.016 (2)
C140.137 (4)0.144 (4)0.088 (3)0.072 (4)0.039 (3)0.031 (3)
C150.125 (4)0.179 (5)0.083 (3)0.084 (4)0.033 (3)0.008 (3)
C160.122 (4)0.150 (4)0.082 (3)0.092 (3)0.010 (3)0.009 (3)
C170.106 (3)0.095 (3)0.058 (2)0.061 (3)0.003 (2)0.001 (2)
C180.055 (2)0.068 (2)0.060 (2)0.009 (2)0.007 (2)0.029 (2)
C190.054 (2)0.102 (3)0.063 (2)0.016 (2)0.009 (2)0.038 (2)
C200.058 (3)0.157 (4)0.086 (3)0.030 (3)0.007 (2)0.064 (3)
C210.087 (4)0.148 (5)0.150 (5)0.006 (3)0.002 (3)0.093 (4)
C220.115 (4)0.110 (4)0.192 (6)0.004 (4)0.003 (4)0.073 (4)
C230.081 (3)0.084 (3)0.134 (4)0.009 (2)0.005 (3)0.037 (3)
C240.093 (3)0.253 (6)0.129 (4)0.058 (4)0.042 (3)0.101 (4)
C250.057 (2)0.049 (2)0.054 (2)0.017 (2)0.010 (2)0.021 (2)
C260.097 (3)0.071 (2)0.062 (2)0.044 (2)0.003 (2)0.011 (2)
C270.131 (4)0.077 (3)0.063 (2)0.050 (3)0.007 (2)0.006 (2)
C280.116 (3)0.069 (3)0.082 (3)0.049 (2)0.024 (2)0.017 (2)
C290.076 (3)0.063 (2)0.099 (3)0.034 (2)0.015 (2)0.025 (2)
C300.062 (2)0.058 (2)0.078 (2)0.020 (2)0.004 (2)0.022 (2)
C310.046 (2)0.050 (2)0.044 (2)0.013 (1)0.004 (1)0.018 (2)
C320.048 (2)0.052 (2)0.042 (2)0.017 (2)0.005 (1)0.017 (1)
C330.061 (2)0.059 (2)0.048 (2)0.021 (2)0.001 (2)0.017 (2)
C340.114 (3)0.090 (3)0.058 (2)0.049 (3)0.019 (2)0.015 (2)
C350.044 (2)0.052 (2)0.040 (2)0.011 (1)0.007 (1)0.014 (1)
C360.055 (2)0.057 (2)0.048 (2)0.024 (2)0.003 (2)0.013 (2)
C370.081 (3)0.068 (2)0.068 (2)0.013 (2)0.015 (2)0.015 (2)
C380.115 (4)0.073 (3)0.102 (3)0.022 (3)0.034 (3)0.001 (3)
C390.136 (4)0.109 (4)0.071 (3)0.073 (3)0.021 (3)0.017 (3)
C400.101 (3)0.158 (4)0.058 (3)0.062 (3)0.013 (2)0.007 (3)
C410.073 (2)0.118 (3)0.046 (2)0.029 (2)0.010 (2)0.012 (2)
C420.055 (2)0.052 (2)0.041 (2)0.018 (2)0.000 (1)0.013 (1)
C430.061 (2)0.061 (2)0.056 (2)0.027 (2)0.009 (2)0.023 (2)
C440.064 (2)0.072 (2)0.059 (2)0.031 (2)0.007 (2)0.015 (2)
C450.087 (3)0.069 (2)0.083 (3)0.040 (2)0.007 (2)0.024 (2)
C460.095 (3)0.065 (3)0.107 (3)0.030 (2)0.026 (3)0.041 (2)
C470.075 (2)0.061 (2)0.076 (2)0.027 (2)0.021 (2)0.029 (2)
C480.099 (3)0.111 (3)0.104 (3)0.057 (3)0.035 (3)0.034 (3)
Geometric parameters (Å, º) top
Co1—O11.933 (2)C36—C371.39
Co1—O21.932 (2)C36—C411.39
Co1—N31.969 (2)C37—C381.39
Co1—N61.982 (2)C38—C391.39
O2—C311.278 (3)C39—C401.39
O1—C71.283 (3)C40—C411.39
N1—C71.366 (4)C42—C431.39
N1—N21.384 (4)C42—C471.39
N1—C11.409 (3)C43—C441.39
N2—C91.311 (5)C44—C451.39
N3—C111.311 (4)C44—C481.515 (4)
N3—C181.423 (3)C45—C461.39
N4—C311.366 (4)C46—C471.39
N4—N51.392 (3)C2—H20.93
N4—C251.410 (3)C3—H30.93
N5—C331.306 (4)C4—H40.93
N6—C351.317 (3)C5—H50.93
N6—C421.431 (3)C6—H60.93
C1—C21.39C10—H10a0.96
C1—C61.39C10—H10b0.96
C2—C31.39C10—H10c0.96
C3—C41.39C13—H130.93
C4—C51.39C14—H140.93
C5—C61.39C15—H150.93
C7—C81.405 (4)C16—H160.93
C8—C111.424 (4)C17—H170.93
C8—C91.432 (4)C19—H190.93
C9—C101.507 (5)C21—H210.93
C11—C121.484 (3)C22—H220.93
C12—C131.39C23—H230.93
C12—C171.39C24—H24a0.96
C13—C141.39C24—H24b0.96
C14—C151.39C24—H24c0.96
C15—C161.39C26—H260.93
C16—C171.39C27—H270.93
C18—C191.39C28—H280.93
C18—C231.39C29—H290.93
C19—C201.39C30—H300.93
C20—C211.39C34—H34a0.96
C20—C241.491 (6)C34—H34b0.96
C21—C221.39C34—H34c0.96
C22—C231.39C37—H370.93
C25—C261.39C38—H380.93
C25—C301.39C39—H390.93
C26—C271.39C40—H400.93
C27—C281.39C41—H410.93
C28—C291.39C43—H430.93
C29—C301.39C45—H450.93
C31—C321.415 (4)C46—H460.93
C32—C351.426 (4)C47—H470.93
C32—C331.434 (4)C48—H48a0.96
C33—C341.505 (4)C48—H48b0.96
C35—C361.490 (3)C48—H48c0.96
O1—Co1—O2119.3 (1)C43—C42—N6121.1 (2)
O1—Co1—N397.1 (1)C47—C42—N6118.7 (2)
O1—Co1—N6111.1 (1)C42—C43—C44120.0
O2—Co1—N3113.3 (1)C45—C44—C43120.0
O2—Co1—N696.8 (1)C45—C44—C48119.6 (2)
N3—Co1—N6120.8 (1)C43—C44—C48120.4 (2)
C31—O2—Co1117.1 (2)C44—C45—C46120.0
C7—O1—Co1119.2 (2)C47—C46—C45120.0
C7—N1—N2111.2 (3)C46—C47—C42120.0
C7—N1—C1130.6 (3)C3—C2—H2120.0
N2—N1—C1118.0 (3)C1—C2—H2120.0
C9—N2—N1105.8 (3)C2—C3—H3120.0
C11—N3—C18120.8 (3)C4—C3—H3120.0
C11—N3—Co1125.5 (2)C3—C4—H4120.0
C18—N3—Co1113.7 (2)C5—C4—H4120.0
C31—N4—N5111.1 (3)C6—C5—H5120.0
C31—N4—C25130.0 (2)C4—C5—H5120.0
N5—N4—C25118.7 (2)C5—C6—H6120.0
C33—N5—N4106.1 (2)C1—C6—H6120.0
C35—N6—C42121.4 (2)C9—C10—H10a109.5
C35—N6—Co1122.4 (2)C9—C10—H10b109.5
C42—N6—Co1116.0 (2)H10a—C10—H10b109.5
C2—C1—C6120.0C9—C10—H10c109.5
C2—C1—N1122.3 (2)H10a—C10—H10c109.5
C6—C1—N1117.7 (2)H10b—C10—H10c109.5
C3—C2—C1120.0C12—C13—H13120.0
C2—C3—C4120.0C14—C13—H13120.0
C3—C4—C5120.0C15—C14—H14120.0
C6—C5—C4120.0C13—C14—H14120.0
C5—C6—C1120.0C16—C15—H15120.0
O1—C7—N1122.0 (3)C14—C15—H15120.0
O1—C7—C8131.1 (3)C15—C16—H16120.0
N1—C7—C8106.9 (3)C17—C16—H16120.0
C7—C8—C11126.0 (3)C16—C17—H17120.0
C7—C8—C9104.0 (3)C12—C17—H17120.0
C11—C8—C9130.1 (3)C20—C19—H19120.0
N2—C9—C8112.1 (3)C18—C19—H19120.0
N2—C9—C10117.5 (3)C22—C21—H21120.0
C8—C9—C10130.4 (4)C20—C21—H21120.0
N3—C11—C8121.0 (3)C21—C22—H22120.0
N3—C11—C12120.6 (3)C23—C22—H22120.0
C8—C11—C12118.4 (3)C22—C23—H23120.0
C13—C12—C17120.0C18—C23—H23120.0
C13—C12—C11119.5 (2)C20—C24—H24a109.5
C17—C12—C11120.4 (2)C20—C24—H24b109.5
C12—C13—C14120.0H24a—C24—H24b109.5
C15—C14—C13120.0C20—C24—H24c109.5
C16—C15—C14120.0H24a—C24—H24c109.5
C15—C16—C17120.0H24b—C24—H24c109.5
C16—C17—C12120.0C25—C26—H26120.0
C19—C18—C23120.0C27—C26—H26120.0
C19—C18—N3120.1 (2)C28—C27—H27120.0
C23—C18—N3119.7 (2)C26—C27—H27120.0
C20—C19—C18120.0C27—C28—H28120.0
C19—C20—C21120.0C29—C28—H28120.0
C19—C20—C24119.7 (3)C30—C29—H29120.0
C21—C20—C24120.2 (3)C28—C29—H29120.0
C22—C21—C20120.0C29—C30—H30120.0
C21—C22—C23120.0C25—C30—H30120.0
C22—C23—C18120.0C33—C34—H34a109.5
C26—C25—C30120.0C33—C34—H34b109.5
C26—C25—N4121.4 (2)H34a—C34—H34b109.5
C30—C25—N4118.6 (2)C33—C34—H34c109.5
C25—C26—C27120.0H34a—C34—H34c109.5
C28—C27—C26120.0H34b—C34—H34c109.5
C27—C28—C29120.0C36—C37—H37120.0
C30—C29—C28120.0C38—C37—H37120.0
C29—C30—C25120.0C39—C38—H38120.0
O2—C31—N4122.3 (3)C37—C38—H38120.0
O2—C31—C32131.1 (3)C38—C39—H39120.0
N4—C31—C32106.6 (2)C40—C39—H39120.0
C31—C32—C35125.4 (3)C39—C40—H40120.0
C31—C32—C33104.1 (3)C41—C40—H40120.0
C35—C32—C33130.5 (3)C40—C41—H41120.0
N5—C33—C32112.0 (3)C36—C41—H41120.0
N5—C33—C34116.9 (3)C42—C43—H43120.0
C32—C33—C34131.1 (3)C44—C43—H43120.0
N6—C35—C32121.3 (3)C44—C45—H45120.0
N6—C35—C36120.8 (3)C46—C45—H45120.0
C32—C35—C36117.8 (2)C47—C46—H46120.0
C37—C36—C41120.0C45—C46—H46120.0
C37—C36—C35117.6 (2)C46—C47—H47120.0
C41—C36—C35122.1 (2)C42—C47—H47120.0
C36—C37—C38120.0C44—C48—H48a109.5
C39—C38—C37120.0C44—C48—H48b109.5
C38—C39—C40120.0H48a—C48—H48b109.5
C39—C40—C41120.0C44—C48—H48c109.5
C40—C41—C36120.0H48a—C48—H48c109.5
C43—C42—C47120.0H48b—C48—H48c109.5
O1—Co1—O2—C3196.1 (2)C8—C11—C12—C1783.9 (3)
N3—Co1—O2—C31150.6 (2)C11—C12—C13—C14175.8 (3)
N6—Co1—O2—C3122.8 (2)C11—C12—C17—C16175.7 (3)
O2—Co1—O1—C7120.8 (2)C11—N3—C18—C1985.7 (3)
N3—Co1—O1—C70.9 (2)Co1—N3—C18—C1992.7 (2)
N6—Co1—O1—C7127.9 (2)C11—N3—C18—C2399.4 (3)
C7—N1—N2—C90.6 (4)Co1—N3—C18—C2382.2 (2)
C1—N1—N2—C9175.5 (3)N3—C18—C19—C20174.9 (2)
O2—Co1—N3—C11124.7 (2)C18—C19—C20—C24177.4 (3)
O1—Co1—N3—C111.5 (3)C24—C20—C21—C22177.4 (3)
N6—Co1—N3—C11121.3 (2)N3—C18—C23—C22175.0 (2)
O2—Co1—N3—C1857.0 (2)C31—N4—C25—C2621.5 (4)
O1—Co1—N3—C18176.8 (2)N5—N4—C25—C26163.6 (2)
N6—Co1—N3—C1857.0 (2)C31—N4—C25—C30156.4 (3)
C31—N4—N5—C331.1 (3)N5—N4—C25—C3018.5 (3)
C25—N4—N5—C33177.0 (3)N4—C25—C26—C27177.9 (2)
O2—Co1—N6—C3524.7 (2)N4—C25—C30—C29178.0 (2)
O1—Co1—N6—C35100.4 (2)Co1—O2—C31—N4165.1 (2)
N3—Co1—N6—C35146.9 (2)Co1—O2—C31—C3212.7 (4)
O2—Co1—N6—C42160.0 (2)N5—N4—C31—O2176.1 (3)
O1—Co1—N6—C4274.9 (2)C25—N4—C31—O20.9 (5)
N3—Co1—N6—C4237.7 (2)N5—N4—C31—C322.2 (3)
C7—N1—C1—C211.7 (4)C25—N4—C31—C32177.4 (3)
N2—N1—C1—C2173.0 (2)O2—C31—C32—C355.8 (5)
C7—N1—C1—C6168.5 (3)N4—C31—C32—C35176.2 (3)
N2—N1—C1—C66.8 (3)O2—C31—C32—C33175.8 (3)
N1—C1—C2—C3179.8 (3)N4—C31—C32—C332.2 (3)
N1—C1—C6—C5179.8 (2)N4—N5—C33—C320.4 (4)
Co1—O1—C7—N1179.4 (2)N4—N5—C33—C34178.5 (3)
Co1—O1—C7—C80.2 (4)C31—C32—C33—N51.7 (4)
N2—N1—C7—O1179.0 (3)C35—C32—C33—N5176.6 (3)
C1—N1—C7—O15.5 (5)C31—C32—C33—C34177.0 (4)
N2—N1—C7—C80.6 (3)C35—C32—C33—C344.7 (6)
C1—N1—C7—C8174.9 (3)C42—N6—C35—C32171.3 (2)
O1—C7—C8—C110.5 (6)Co1—N6—C35—C3213.6 (4)
N1—C7—C8—C11179.9 (3)C42—N6—C35—C3612.5 (4)
O1—C7—C8—C9179.2 (3)Co1—N6—C35—C36162.6 (2)
N1—C7—C8—C90.4 (3)C31—C32—C35—N65.2 (5)
N1—N2—C9—C80.4 (4)C33—C32—C35—N6176.9 (3)
N1—N2—C9—C10179.6 (3)C31—C32—C35—C36178.5 (3)
C7—C8—C9—N20.0 (4)C33—C32—C35—C360.6 (5)
C11—C8—C9—N2179.7 (3)N6—C35—C36—C3779.3 (3)
C7—C8—C9—C10179.1 (4)C32—C35—C36—C3797.1 (3)
C11—C8—C9—C100.6 (7)N6—C35—C36—C41107.1 (3)
C18—N3—C11—C8177.0 (3)C32—C35—C36—C4176.5 (3)
Co1—N3—C11—C81.2 (4)C35—C36—C37—C38173.7 (2)
C18—N3—C11—C124.2 (4)C35—C36—C41—C40173.4 (2)
Co1—N3—C11—C12177.6 (2)C35—N6—C42—C4361.9 (3)
C7—C8—C11—N30.1 (5)Co1—N6—C42—C43122.8 (2)
C9—C8—C11—N3179.7 (3)C35—N6—C42—C47122.7 (2)
C7—C8—C11—C12178.8 (3)Co1—N6—C42—C4752.7 (2)
C9—C8—C11—C120.8 (5)N6—C42—C43—C44175.4 (2)
N3—C11—C12—C1387.1 (3)C42—C43—C44—C48179.1 (3)
C8—C11—C12—C1391.8 (3)C48—C44—C45—C46179.1 (3)
N3—C11—C12—C1797.2 (3)N6—C42—C47—C46175.5 (2)
 

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