Iodo­tris(triphenyl­phosphine)nickel(I) diethyl ether hemisolvate

A comparison of the title compound, [NiI(C₁₈H₁₅P)₃]·0.5C₄H₁₀O, with the previously reported chloro- and bromo-analogues suggests that bond-angle distortion may not always be required for steric relief. The asymmetric unit contains two complex molecules and one disordered diethyl ether molecule.

Key indicators

• Single-crystal X-ray study
• T = 120 K
• Mean [sigma](C-C) = 0.004 Å
• Disorder in solvent or counterion
• R factor = 0.035
• wR factor = 0.084
• Data-to-parameter ratio = 18.4

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT223_ALERT_4_B Large Solvent/Anion  H     Ueq(max)/Ueq(min) ...       4.44 Ratio

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.86
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.57 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.77 Ratio
PLAT221_ALERT_4_C Large Solvent/Anion  C     Ueq(max)/Ueq(min) ...       3.61 Ratio
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         O1
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C113
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C115
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  11 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2001); software used to prepare material for publication: SHELXTL.

Iodotris(triphenylphosphine)nickel(I) diethyl ether hemisolvate

Crystal data

[NiI(C18H15P)3]·0.5C4H10O	Z = 4
Mr = 1009.48	F(000) = 2064
Triclinic, P1	Dx = 1.415 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 13.072 (4) Å	Cell parameters from 958 reflections
b = 20.035 (5) Å	θ = 2.7–22.2°
c = 21.364 (6) Å	µ = 1.20 mm^−1
α = 113.354 (4)°	T = 120 K
β = 105.597 (4)°	Block, orange
γ = 98.451 (4)°	0.34 × 0.28 × 0.24 mm
V = 4740 (2) Å^3

Data collection

Bruker APEX diffractometer	21295 independent reflections
Radiation source: fine-focus sealed tube, Bruker APEX	17682 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.037
Detector resolution: 836.6 pixels mm^-1	θmax = 28.3°, θmin = 1.7°
ω scans	h = −16→17
Absorption correction: multi-scan (SADABS; Sheldrick, 2003)	k = −26→26
Tmin = 0.620, Tmax = 0.746	l = −28→27
53243 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.035	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.084	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0363P)^2 + 0.8632P] where P = (Fo^2 + 2Fc^2)/3
21295 reflections	(Δ/σ)max = 0.002
1158 parameters	Δρmax = 1.50 e Å^−3
7 restraints	Δρmin = −0.52 e Å^−3

Special details

Experimental. Data collection was performed with four batch runs at φ = 0.00 ° (600 frames), at φ = 90.00 ° (600 frames), at φ = 180 ° (600 frames) and at φ = 270 ° (600 frames). Frame width = 0.30 ° in ω. Data were merged, corrected for decay, and treated with multi-scan absorption corrections.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
I1	0.372509 (13)	0.373162 (9)	0.243646 (8)	0.02092 (5)
I2	0.912599 (14)	0.852277 (9)	0.249793 (9)	0.02458 (5)
Ni1	0.33916 (2)	0.248594 (16)	0.256373 (16)	0.01510 (7)
Ni2	0.89928 (2)	0.717203 (17)	0.239753 (16)	0.01713 (7)
P1	0.32324 (5)	0.26524 (3)	0.36612 (3)	0.01647 (13)
P2	0.20207 (5)	0.15849 (4)	0.14746 (3)	0.01959 (13)
P3	0.50429 (5)	0.22494 (3)	0.26193 (3)	0.01728 (13)
P4	0.92219 (5)	0.74653 (4)	0.35818 (3)	0.01893 (13)
P5	0.73264 (5)	0.63041 (4)	0.15092 (3)	0.01953 (13)
P6	1.05247 (5)	0.68454 (4)	0.22113 (3)	0.01973 (13)
C1	0.5315 (2)	0.29453 (15)	0.47024 (13)	0.0223 (5)
H1A	0.5266	0.2431	0.4414	0.027*
C2	0.6246 (2)	0.34042 (16)	0.53225 (14)	0.0271 (6)
H2A	0.6830	0.3199	0.5458	0.032*
C3	0.6339 (2)	0.41527 (16)	0.57446 (14)	0.0300 (6)
H3A	0.6981	0.4460	0.6170	0.036*
C4	0.5500 (2)	0.44549 (15)	0.55494 (14)	0.0280 (6)
H4A	0.5565	0.4973	0.5837	0.034*
C5	0.4556 (2)	0.40014 (14)	0.49311 (13)	0.0218 (5)
H5A	0.3978	0.4212	0.4799	0.026*
C6	0.44505 (19)	0.32392 (13)	0.45022 (12)	0.0175 (5)
C7	0.2051 (2)	0.37034 (14)	0.36474 (13)	0.0228 (5)
H7A	0.2429	0.3785	0.3350	0.027*
C8	0.1334 (2)	0.41236 (15)	0.38364 (14)	0.0271 (6)
H8A	0.1206	0.4480	0.3657	0.033*
C9	0.0804 (2)	0.40254 (16)	0.42872 (15)	0.0317 (6)
H9A	0.0315	0.4315	0.4420	0.038*
C10	0.0991 (2)	0.35091 (18)	0.45410 (17)	0.0397 (7)
H10A	0.0639	0.3447	0.4858	0.048*
C11	0.1690 (2)	0.30746 (17)	0.43389 (15)	0.0319 (6)
H11A	0.1804	0.2712	0.4513	0.038*
C12	0.22254 (19)	0.31638 (14)	0.38859 (13)	0.0196 (5)
C13	0.3149 (2)	0.17485 (14)	0.44138 (13)	0.0230 (5)
H13A	0.3693	0.2165	0.4838	0.028*
C14	0.2750 (2)	0.10862 (15)	0.44409 (14)	0.0272 (6)
H14A	0.3024	0.1052	0.4883	0.033*
C15	0.1956 (2)	0.04721 (15)	0.38301 (15)	0.0301 (6)
H15A	0.1697	0.0013	0.3847	0.036*
C16	0.1543 (2)	0.05375 (15)	0.31927 (15)	0.0312 (6)
H16A	0.0982	0.0126	0.2774	0.037*
C17	0.1943 (2)	0.11979 (14)	0.31645 (14)	0.0250 (6)
H17A	0.1654	0.1235	0.2725	0.030*
C18	0.27621 (19)	0.18119 (13)	0.37706 (13)	0.0180 (5)
C19	0.0540 (2)	0.23585 (16)	0.19018 (15)	0.0331 (7)
H19A	0.1147	0.2644	0.2352	0.040*
C20	−0.0452 (2)	0.25488 (18)	0.18233 (17)	0.0423 (8)
H20A	−0.0520	0.2959	0.2217	0.051*
C21	−0.1330 (2)	0.21414 (18)	0.11755 (17)	0.0415 (8)
H21A	−0.2010	0.2269	0.1118	0.050*
C22	−0.1228 (2)	0.15445 (19)	0.06055 (16)	0.0426 (8)
H22A	−0.1840	0.1260	0.0158	0.051*
C23	−0.0237 (2)	0.13601 (17)	0.06837 (15)	0.0355 (7)
H23A	−0.0170	0.0954	0.0287	0.043*
C24	0.0664 (2)	0.17662 (14)	0.13418 (13)	0.0229 (5)
C25	0.0767 (2)	0.01744 (15)	0.12801 (14)	0.0306 (6)
H25A	0.0132	0.0354	0.1226	0.037*
C26	0.0691 (3)	−0.05227 (16)	0.12779 (15)	0.0405 (8)
H26A	0.0003	−0.0818	0.1222	0.049*
C27	0.1605 (3)	−0.07915 (16)	0.13567 (16)	0.0448 (9)
H27A	0.1550	−0.1265	0.1367	0.054*
C28	0.2598 (3)	−0.03745 (16)	0.14207 (16)	0.0408 (8)
H28A	0.3225	−0.0564	0.1465	0.049*
C29	0.2680 (2)	0.03240 (15)	0.14203 (14)	0.0299 (6)
H29A	0.3365	0.0608	0.1461	0.036*
C30	0.1772 (2)	0.06158 (14)	0.13607 (13)	0.0243 (6)
C31	0.2256 (2)	0.08183 (15)	0.00974 (13)	0.0255 (6)
H31A	0.2242	0.0389	0.0186	0.031*
C32	0.2369 (2)	0.07809 (16)	−0.05414 (14)	0.0308 (6)
H32A	0.2447	0.0331	−0.0884	0.037*
C33	0.2370 (2)	0.13969 (17)	−0.06799 (14)	0.0316 (6)
H33A	0.2445	0.1371	−0.1119	0.038*
C34	0.2262 (2)	0.20538 (16)	−0.01799 (14)	0.0297 (6)
H34A	0.2253	0.2476	−0.0279	0.036*
C35	0.2165 (2)	0.20980 (14)	0.04642 (13)	0.0245 (6)
H35A	0.2102	0.2553	0.0809	0.029*
C36	0.21608 (19)	0.14763 (14)	0.06093 (13)	0.0207 (5)
C37	0.4590 (2)	0.11690 (14)	0.30790 (14)	0.0239 (6)
H37A	0.3841	0.1124	0.2833	0.029*
C38	0.4819 (2)	0.07447 (15)	0.34514 (15)	0.0310 (6)
H38A	0.4230	0.0410	0.3457	0.037*
C39	0.5902 (3)	0.08102 (16)	0.38115 (14)	0.0336 (7)
H39A	0.6062	0.0528	0.4075	0.040*
C40	0.6755 (2)	0.12854 (16)	0.37898 (15)	0.0321 (7)
H40A	0.7502	0.1323	0.4031	0.039*
C41	0.6527 (2)	0.17083 (15)	0.34188 (14)	0.0265 (6)
H41A	0.7119	0.2036	0.3408	0.032*
C42	0.5437 (2)	0.16576 (13)	0.30616 (13)	0.0196 (5)
C43	0.5650 (2)	0.11893 (14)	0.15382 (14)	0.0257 (6)
H43A	0.5846	0.0971	0.1859	0.031*
C44	0.5799 (2)	0.08934 (16)	0.08686 (15)	0.0335 (7)
H44A	0.6091	0.0472	0.0733	0.040*
C45	0.5522 (2)	0.12126 (16)	0.04034 (14)	0.0324 (7)
H45A	0.5625	0.1011	−0.0052	0.039*
C46	0.5098 (2)	0.18231 (15)	0.05996 (14)	0.0272 (6)
H46A	0.4917	0.2046	0.0281	0.033*
C47	0.4934 (2)	0.21150 (14)	0.12607 (13)	0.0232 (5)
H47A	0.4628	0.2530	0.1389	0.028*
C48	0.52156 (19)	0.17994 (13)	0.17378 (13)	0.0193 (5)
C49	0.7167 (2)	0.31411 (15)	0.29019 (14)	0.0242 (6)
H49A	0.7195	0.2718	0.2502	0.029*
C50	0.8042 (2)	0.37984 (15)	0.32763 (14)	0.0279 (6)
H50A	0.8667	0.3823	0.3131	0.033*
C51	0.8015 (2)	0.44190 (15)	0.38588 (14)	0.0253 (6)
H51A	0.8617	0.4870	0.4113	0.030*
C52	0.7104 (2)	0.43798 (14)	0.40694 (13)	0.0236 (5)
H52A	0.7085	0.4803	0.4473	0.028*
C53	0.6221 (2)	0.37263 (13)	0.36942 (13)	0.0201 (5)
H53A	0.5593	0.3707	0.3837	0.024*
C54	0.62460 (19)	0.30961 (14)	0.31071 (13)	0.0186 (5)
C55	1.0919 (2)	0.88253 (14)	0.43217 (14)	0.0237 (5)
H55A	1.1126	0.8632	0.3905	0.028*
C56	1.1577 (2)	0.95049 (15)	0.49235 (14)	0.0278 (6)
H56A	1.2245	0.9765	0.4923	0.033*
C57	1.1271 (2)	0.98070 (15)	0.55246 (14)	0.0299 (6)
H57A	1.1723	1.0276	0.5933	0.036*
C58	1.0308 (2)	0.94258 (15)	0.55303 (14)	0.0307 (6)
H58A	1.0090	0.9635	0.5940	0.037*
C59	0.9654 (2)	0.87318 (15)	0.49334 (14)	0.0266 (6)
H59A	0.8997	0.8467	0.4943	0.032*
C60	0.9955 (2)	0.84245 (14)	0.43249 (13)	0.0215 (5)
C61	1.0724 (2)	0.72178 (14)	0.46551 (14)	0.0247 (6)
H61A	1.0926	0.7748	0.4966	0.030*
C62	1.1248 (2)	0.67629 (15)	0.48899 (14)	0.0254 (6)
H62A	1.1811	0.6984	0.5361	0.030*
C63	1.0961 (2)	0.59903 (14)	0.44471 (14)	0.0239 (5)
H63A	1.1321	0.5680	0.4613	0.029*
C64	1.0146 (2)	0.56727 (14)	0.37603 (14)	0.0239 (5)
H64A	0.9944	0.5142	0.3453	0.029*
C65	0.9626 (2)	0.61254 (14)	0.35198 (13)	0.0219 (5)
H65A	0.9073	0.5902	0.3045	0.026*
C66	0.9899 (2)	0.69015 (13)	0.39620 (13)	0.0193 (5)
C67	0.7424 (2)	0.67626 (16)	0.38347 (14)	0.0311 (6)
H67A	0.7878	0.6482	0.3980	0.037*
C68	0.6330 (2)	0.66257 (19)	0.38053 (15)	0.0406 (8)
H68A	0.6040	0.6244	0.3920	0.049*
C69	0.5669 (3)	0.7038 (2)	0.36117 (16)	0.0466 (9)
H69A	0.4926	0.6944	0.3596	0.056*
C70	0.6087 (2)	0.7588 (2)	0.34400 (16)	0.0436 (8)
H70A	0.5636	0.7879	0.3312	0.052*
C71	0.7168 (2)	0.77174 (17)	0.34548 (15)	0.0344 (7)
H71A	0.7448	0.8091	0.3328	0.041*
C72	0.7849 (2)	0.73048 (15)	0.36538 (13)	0.0246 (6)
C73	0.6925 (2)	0.53025 (15)	0.20746 (14)	0.0279 (6)
H73A	0.7001	0.5748	0.2494	0.033*
C74	0.6742 (2)	0.46085 (17)	0.20863 (16)	0.0340 (7)
H74A	0.6689	0.4582	0.2511	0.041*
C75	0.6638 (2)	0.39591 (17)	0.14840 (17)	0.0363 (7)
H75A	0.6536	0.3486	0.1498	0.044*
C76	0.6681 (2)	0.39965 (15)	0.08599 (16)	0.0327 (7)
H76A	0.6599	0.3547	0.0442	0.039*
C77	0.6845 (2)	0.46867 (14)	0.08407 (15)	0.0263 (6)
H77A	0.6851	0.4704	0.0404	0.032*
C78	0.6999 (2)	0.53547 (14)	0.14548 (14)	0.0223 (5)
C79	0.5100 (2)	0.60836 (16)	0.14447 (16)	0.0330 (7)
H79A	0.5094	0.5583	0.1371	0.040*
C80	0.4142 (2)	0.63143 (17)	0.14470 (18)	0.0420 (8)
H80A	0.3491	0.5973	0.1384	0.050*
C81	0.4139 (3)	0.70374 (18)	0.1541 (2)	0.0508 (9)
H81A	0.3489	0.7195	0.1542	0.061*
C82	0.5084 (3)	0.75262 (18)	0.1631 (2)	0.0508 (9)
H82A	0.5077	0.8019	0.1683	0.061*
C83	0.6044 (2)	0.73100 (16)	0.16485 (17)	0.0364 (7)
H83A	0.6697	0.7661	0.1728	0.044*
C84	0.6061 (2)	0.65827 (14)	0.15503 (14)	0.0245 (6)
C85	0.6302 (2)	0.61399 (15)	0.00801 (14)	0.0275 (6)
H85A	0.5718	0.6295	0.0228	0.033*
C86	0.6272 (2)	0.59749 (16)	−0.06231 (15)	0.0328 (7)
H86A	0.5670	0.6024	−0.0951	0.039*
C87	0.7102 (2)	0.57419 (15)	−0.08483 (15)	0.0325 (7)
H87A	0.7076	0.5635	−0.1328	0.039*
C88	0.7981 (2)	0.56615 (15)	−0.03761 (14)	0.0295 (6)
H88A	0.8551	0.5491	−0.0534	0.035*
C89	0.8025 (2)	0.58310 (14)	0.03269 (14)	0.0247 (6)
H89A	0.8630	0.5779	0.0650	0.030*
C90	0.7194 (2)	0.60769 (13)	0.05663 (13)	0.0203 (5)
C91	1.0265 (2)	0.72711 (15)	0.10907 (14)	0.0278 (6)
H91A	0.9937	0.7623	0.1353	0.033*
C92	1.0353 (2)	0.72433 (15)	0.04488 (14)	0.0308 (6)
H92A	1.0095	0.7582	0.0279	0.037*
C93	1.0812 (2)	0.67262 (16)	0.00563 (15)	0.0338 (7)
H93A	1.0875	0.6711	−0.0382	0.041*
C94	1.1180 (2)	0.62299 (17)	0.03019 (15)	0.0351 (7)
H94A	1.1484	0.5867	0.0028	0.042*
C95	1.1105 (2)	0.62610 (16)	0.09464 (14)	0.0287 (6)
H95A	1.1363	0.5920	0.1112	0.034*
C96	1.0657 (2)	0.67846 (14)	0.13547 (13)	0.0215 (5)
C97	1.2323 (3)	0.81478 (16)	0.27985 (17)	0.0397 (7)
H97A	1.2013	0.8171	0.2354	0.048*
C98	1.3268 (3)	0.87046 (18)	0.33422 (19)	0.0533 (10)
H98A	1.3598	0.9109	0.3269	0.064*
C99	1.3734 (3)	0.86781 (17)	0.39905 (18)	0.0467 (8)
H99A	1.4391	0.9056	0.4358	0.056*
C100	1.3241 (2)	0.81035 (16)	0.41002 (15)	0.0347 (7)
H10B	1.3554	0.8087	0.4548	0.042*
C101	1.2292 (2)	0.75460 (15)	0.35634 (14)	0.0267 (6)
H10C	1.1953	0.7153	0.3648	0.032*
C102	1.1826 (2)	0.75573 (14)	0.28980 (13)	0.0233 (5)
C103	1.1830 (2)	0.58598 (15)	0.23836 (13)	0.0256 (6)
H10D	1.2469	0.6271	0.2559	0.031*
C104	1.1949 (2)	0.51665 (15)	0.23305 (14)	0.0277 (6)
H10E	1.2671	0.5108	0.2476	0.033*
C105	1.1036 (2)	0.45621 (16)	0.20696 (14)	0.0308 (6)
H10F	1.1126	0.4087	0.2032	0.037*
C106	0.9981 (2)	0.46452 (15)	0.18610 (15)	0.0300 (6)
H10G	0.9347	0.4229	0.1682	0.036*
C107	0.9857 (2)	0.53386 (14)	0.19152 (13)	0.0246 (6)
H10H	0.9133	0.5392	0.1768	0.030*
C108	1.0771 (2)	0.59588 (13)	0.21802 (13)	0.0194 (5)
O1	0.7659 (3)	0.0598 (2)	0.2164 (2)	0.0334 (8)	0.66
C109	0.8717 (9)	0.1066 (7)	0.2313 (6)	0.051 (2)	0.66
H10I	0.8628	0.1290	0.1970	0.061*	0.66
H10J	0.9213	0.0740	0.2212	0.061*	0.66
C110	0.9261 (6)	0.1685 (4)	0.3065 (3)	0.069 (2)	0.66
H11B	0.9968	0.1984	0.3112	0.103*	0.66
H11C	0.9397	0.1471	0.3409	0.103*	0.66
H11D	0.8780	0.2013	0.3173	0.103*	0.66
C111	0.7688 (6)	0.0107 (3)	0.2478 (3)	0.0526 (16)	0.66
H11E	0.7963	0.0399	0.3017	0.063*	0.66
H11F	0.8186	−0.0206	0.2340	0.063*	0.66
C112	0.6482 (11)	−0.0406 (7)	0.2185 (8)	0.082 (5)	0.66
H11G	0.6469	−0.0770	0.2386	0.122*	0.66
H11H	0.6214	−0.0682	0.1651	0.122*	0.66
H11I	0.6002	−0.0091	0.2335	0.122*	0.66
O2	0.7284 (6)	0.0281 (4)	0.2190 (4)	0.0353 (16)	0.34
C113	0.8474 (7)	0.0570 (5)	0.2610 (5)	0.038 (2)	0.34
H11J	0.8839	0.0170	0.2434	0.046*	0.34
H11K	0.8609	0.0725	0.3134	0.046*	0.34
C114	0.8930 (18)	0.1233 (13)	0.2515 (15)	0.101 (12)	0.34
H11L	0.9715	0.1464	0.2827	0.151*	0.34
H11M	0.8521	0.1607	0.2651	0.151*	0.34
H11N	0.8854	0.1065	0.2002	0.151*	0.34
C115	0.6734 (13)	−0.0311 (9)	0.2296 (11)	0.028 (3)	0.34
H11O	0.6880	−0.0139	0.2823	0.034*	0.34
H11P	0.7009	−0.0759	0.2112	0.034*	0.34
C116	0.5484 (9)	−0.0521 (7)	0.1876 (9)	0.086 (5)	0.34
H11Q	0.5073	−0.0812	0.2052	0.129*	0.34
H11R	0.5320	−0.0828	0.1353	0.129*	0.34
H11S	0.5261	−0.0056	0.1955	0.129*	0.34

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
I1	0.02617 (9)	0.01667 (8)	0.02157 (9)	0.00652 (7)	0.00780 (7)	0.01069 (7)
I2	0.03065 (10)	0.01779 (9)	0.02470 (9)	0.00770 (7)	0.00580 (7)	0.01157 (7)
Ni1	0.01546 (15)	0.01458 (15)	0.01441 (15)	0.00394 (12)	0.00446 (12)	0.00655 (12)
Ni2	0.01837 (16)	0.01562 (15)	0.01658 (15)	0.00488 (12)	0.00465 (13)	0.00764 (13)
P1	0.0163 (3)	0.0171 (3)	0.0152 (3)	0.0041 (2)	0.0049 (2)	0.0073 (2)
P2	0.0208 (3)	0.0176 (3)	0.0152 (3)	0.0001 (3)	0.0040 (3)	0.0060 (3)
P3	0.0169 (3)	0.0169 (3)	0.0173 (3)	0.0046 (2)	0.0058 (3)	0.0074 (3)
P4	0.0215 (3)	0.0173 (3)	0.0185 (3)	0.0056 (3)	0.0077 (3)	0.0084 (3)
P5	0.0190 (3)	0.0175 (3)	0.0181 (3)	0.0024 (3)	0.0041 (3)	0.0070 (3)
P6	0.0215 (3)	0.0188 (3)	0.0188 (3)	0.0071 (3)	0.0069 (3)	0.0084 (3)
C1	0.0206 (13)	0.0273 (14)	0.0214 (13)	0.0057 (11)	0.0074 (11)	0.0139 (11)
C2	0.0199 (13)	0.0392 (16)	0.0255 (14)	0.0055 (12)	0.0045 (11)	0.0215 (13)
C3	0.0244 (14)	0.0343 (16)	0.0212 (13)	−0.0066 (12)	−0.0012 (11)	0.0141 (12)
C4	0.0325 (15)	0.0224 (14)	0.0209 (13)	−0.0030 (12)	0.0067 (12)	0.0077 (11)
C5	0.0229 (13)	0.0232 (13)	0.0185 (12)	0.0035 (11)	0.0065 (11)	0.0104 (11)
C6	0.0189 (12)	0.0191 (12)	0.0142 (11)	0.0019 (10)	0.0063 (10)	0.0084 (10)
C7	0.0228 (13)	0.0216 (13)	0.0193 (12)	0.0046 (11)	0.0065 (11)	0.0063 (11)
C8	0.0322 (15)	0.0245 (14)	0.0225 (13)	0.0119 (12)	0.0073 (12)	0.0091 (11)
C9	0.0279 (15)	0.0373 (16)	0.0293 (15)	0.0171 (13)	0.0106 (12)	0.0117 (13)
C10	0.0413 (18)	0.054 (2)	0.0462 (19)	0.0275 (16)	0.0310 (16)	0.0300 (17)
C11	0.0385 (17)	0.0429 (17)	0.0373 (16)	0.0235 (14)	0.0237 (14)	0.0296 (14)
C12	0.0183 (12)	0.0198 (13)	0.0156 (12)	0.0047 (10)	0.0041 (10)	0.0049 (10)
C13	0.0272 (14)	0.0200 (13)	0.0198 (13)	0.0035 (11)	0.0086 (11)	0.0082 (11)
C14	0.0357 (16)	0.0274 (14)	0.0239 (14)	0.0087 (12)	0.0125 (12)	0.0158 (12)
C15	0.0383 (16)	0.0208 (14)	0.0337 (15)	0.0046 (12)	0.0165 (13)	0.0139 (12)
C16	0.0354 (16)	0.0250 (15)	0.0238 (14)	−0.0037 (12)	0.0114 (12)	0.0061 (12)
C17	0.0264 (14)	0.0271 (14)	0.0190 (13)	0.0004 (11)	0.0079 (11)	0.0107 (11)
C18	0.0181 (12)	0.0173 (12)	0.0176 (12)	0.0034 (10)	0.0080 (10)	0.0065 (10)
C19	0.0243 (15)	0.0327 (16)	0.0257 (14)	0.0029 (12)	0.0037 (12)	0.0028 (12)
C20	0.0325 (17)	0.0375 (18)	0.0428 (18)	0.0099 (14)	0.0121 (15)	0.0059 (15)
C21	0.0247 (16)	0.048 (2)	0.049 (2)	0.0125 (14)	0.0101 (14)	0.0211 (16)
C22	0.0255 (16)	0.059 (2)	0.0288 (16)	0.0075 (15)	−0.0005 (13)	0.0146 (15)
C23	0.0290 (16)	0.0427 (18)	0.0207 (14)	0.0072 (13)	0.0034 (12)	0.0057 (13)
C24	0.0196 (13)	0.0245 (14)	0.0207 (13)	0.0022 (11)	0.0061 (11)	0.0086 (11)
C25	0.0341 (16)	0.0268 (15)	0.0180 (13)	−0.0059 (12)	0.0045 (12)	0.0061 (11)
C26	0.048 (2)	0.0289 (16)	0.0253 (15)	−0.0161 (14)	0.0048 (14)	0.0095 (13)
C27	0.064 (2)	0.0189 (15)	0.0294 (16)	−0.0105 (15)	−0.0032 (16)	0.0103 (13)
C28	0.051 (2)	0.0209 (15)	0.0336 (16)	0.0033 (14)	−0.0014 (15)	0.0096 (13)
C29	0.0338 (16)	0.0208 (14)	0.0255 (14)	0.0007 (12)	0.0039 (12)	0.0084 (11)
C30	0.0328 (15)	0.0160 (12)	0.0145 (12)	−0.0040 (11)	0.0036 (11)	0.0047 (10)
C31	0.0258 (14)	0.0244 (14)	0.0208 (13)	0.0053 (11)	0.0050 (11)	0.0081 (11)
C32	0.0312 (15)	0.0354 (16)	0.0203 (13)	0.0109 (13)	0.0096 (12)	0.0067 (12)
C33	0.0293 (15)	0.0457 (18)	0.0177 (13)	0.0067 (13)	0.0074 (12)	0.0147 (13)
C34	0.0281 (15)	0.0324 (16)	0.0223 (14)	0.0000 (12)	0.0004 (12)	0.0151 (12)
C35	0.0254 (14)	0.0220 (13)	0.0186 (13)	0.0014 (11)	0.0024 (11)	0.0075 (11)
C36	0.0171 (12)	0.0227 (13)	0.0147 (12)	−0.0007 (10)	0.0007 (10)	0.0068 (10)
C37	0.0264 (14)	0.0209 (13)	0.0249 (13)	0.0086 (11)	0.0101 (11)	0.0099 (11)
C38	0.0431 (17)	0.0219 (14)	0.0325 (15)	0.0092 (13)	0.0172 (14)	0.0143 (12)
C39	0.0528 (19)	0.0278 (15)	0.0225 (14)	0.0167 (14)	0.0096 (14)	0.0145 (12)
C40	0.0306 (16)	0.0305 (15)	0.0277 (15)	0.0129 (13)	−0.0014 (12)	0.0123 (13)
C41	0.0262 (14)	0.0229 (14)	0.0255 (14)	0.0085 (11)	0.0065 (11)	0.0078 (11)
C42	0.0237 (13)	0.0180 (12)	0.0160 (12)	0.0083 (10)	0.0059 (10)	0.0067 (10)
C43	0.0277 (14)	0.0230 (14)	0.0235 (13)	0.0076 (11)	0.0084 (11)	0.0084 (11)
C44	0.0338 (16)	0.0309 (16)	0.0294 (15)	0.0120 (13)	0.0131 (13)	0.0057 (13)
C45	0.0296 (15)	0.0391 (17)	0.0180 (13)	0.0038 (13)	0.0103 (12)	0.0039 (12)
C46	0.0247 (14)	0.0347 (16)	0.0195 (13)	0.0033 (12)	0.0066 (11)	0.0125 (12)
C47	0.0193 (13)	0.0240 (14)	0.0235 (13)	0.0039 (11)	0.0063 (11)	0.0098 (11)
C48	0.0170 (12)	0.0189 (12)	0.0175 (12)	0.0018 (10)	0.0051 (10)	0.0058 (10)
C49	0.0203 (13)	0.0251 (14)	0.0221 (13)	0.0051 (11)	0.0073 (11)	0.0065 (11)
C50	0.0193 (13)	0.0339 (15)	0.0256 (14)	0.0027 (11)	0.0096 (11)	0.0097 (12)
C51	0.0212 (13)	0.0240 (14)	0.0236 (13)	−0.0006 (11)	0.0036 (11)	0.0094 (11)
C52	0.0257 (14)	0.0209 (13)	0.0202 (13)	0.0052 (11)	0.0066 (11)	0.0072 (11)
C53	0.0199 (13)	0.0217 (13)	0.0213 (13)	0.0062 (10)	0.0080 (10)	0.0119 (11)
C54	0.0168 (12)	0.0199 (12)	0.0188 (12)	0.0041 (10)	0.0039 (10)	0.0107 (10)
C55	0.0285 (14)	0.0223 (13)	0.0227 (13)	0.0091 (11)	0.0080 (11)	0.0128 (11)
C56	0.0301 (15)	0.0227 (14)	0.0281 (14)	0.0036 (11)	0.0044 (12)	0.0146 (12)
C57	0.0383 (16)	0.0173 (13)	0.0234 (14)	0.0066 (12)	0.0005 (12)	0.0063 (11)
C58	0.0383 (17)	0.0286 (15)	0.0228 (14)	0.0144 (13)	0.0095 (12)	0.0089 (12)
C59	0.0270 (14)	0.0286 (15)	0.0255 (14)	0.0105 (12)	0.0109 (12)	0.0117 (12)
C60	0.0272 (14)	0.0175 (12)	0.0198 (12)	0.0093 (11)	0.0058 (11)	0.0093 (10)
C61	0.0277 (14)	0.0195 (13)	0.0213 (13)	0.0035 (11)	0.0058 (11)	0.0070 (11)
C62	0.0223 (13)	0.0285 (14)	0.0211 (13)	0.0055 (11)	0.0032 (11)	0.0108 (11)
C63	0.0233 (13)	0.0249 (14)	0.0288 (14)	0.0087 (11)	0.0094 (11)	0.0165 (12)
C64	0.0234 (13)	0.0188 (13)	0.0272 (14)	0.0042 (11)	0.0084 (11)	0.0095 (11)
C65	0.0208 (13)	0.0233 (13)	0.0187 (12)	0.0041 (10)	0.0056 (10)	0.0085 (11)
C66	0.0208 (13)	0.0196 (12)	0.0202 (12)	0.0039 (10)	0.0090 (10)	0.0114 (10)
C67	0.0318 (16)	0.0390 (17)	0.0211 (14)	0.0061 (13)	0.0133 (12)	0.0111 (12)
C68	0.0350 (17)	0.051 (2)	0.0255 (15)	−0.0053 (15)	0.0154 (14)	0.0103 (14)
C69	0.0221 (16)	0.072 (2)	0.0277 (16)	0.0036 (16)	0.0099 (13)	0.0089 (16)
C70	0.0291 (16)	0.061 (2)	0.0338 (17)	0.0195 (16)	0.0108 (14)	0.0134 (16)
C71	0.0301 (16)	0.0403 (17)	0.0313 (16)	0.0113 (13)	0.0110 (13)	0.0144 (14)
C72	0.0235 (14)	0.0259 (14)	0.0176 (12)	0.0040 (11)	0.0073 (11)	0.0046 (11)
C73	0.0256 (14)	0.0289 (15)	0.0218 (13)	0.0005 (11)	0.0026 (11)	0.0109 (12)
C74	0.0306 (16)	0.0397 (17)	0.0302 (15)	0.0016 (13)	0.0021 (13)	0.0234 (14)
C75	0.0314 (16)	0.0286 (16)	0.0497 (19)	0.0026 (13)	0.0059 (14)	0.0264 (15)
C76	0.0324 (16)	0.0189 (14)	0.0411 (17)	0.0021 (12)	0.0134 (14)	0.0101 (13)
C77	0.0267 (14)	0.0233 (14)	0.0281 (14)	0.0044 (11)	0.0109 (12)	0.0113 (12)
C78	0.0178 (13)	0.0206 (13)	0.0231 (13)	0.0010 (10)	0.0024 (10)	0.0097 (11)
C79	0.0290 (15)	0.0253 (15)	0.0412 (17)	0.0076 (12)	0.0132 (13)	0.0116 (13)
C80	0.0245 (15)	0.0340 (17)	0.059 (2)	0.0059 (13)	0.0150 (15)	0.0140 (16)
C81	0.0254 (16)	0.0377 (19)	0.070 (2)	0.0107 (14)	0.0116 (16)	0.0091 (17)
C82	0.0321 (18)	0.0288 (17)	0.077 (3)	0.0093 (14)	0.0086 (17)	0.0176 (17)
C83	0.0232 (15)	0.0299 (16)	0.0500 (19)	0.0052 (12)	0.0095 (14)	0.0155 (14)
C84	0.0193 (13)	0.0231 (14)	0.0241 (13)	0.0050 (11)	0.0055 (11)	0.0060 (11)
C85	0.0246 (14)	0.0263 (14)	0.0251 (14)	0.0040 (11)	0.0028 (11)	0.0108 (12)
C86	0.0359 (16)	0.0328 (16)	0.0243 (14)	0.0060 (13)	0.0013 (13)	0.0156 (13)
C87	0.0425 (17)	0.0283 (15)	0.0201 (14)	0.0005 (13)	0.0074 (13)	0.0106 (12)
C88	0.0323 (16)	0.0263 (15)	0.0238 (14)	0.0012 (12)	0.0111 (12)	0.0075 (12)
C89	0.0216 (13)	0.0229 (13)	0.0240 (13)	−0.0011 (11)	0.0038 (11)	0.0108 (11)
C90	0.0207 (13)	0.0166 (12)	0.0187 (12)	−0.0014 (10)	0.0030 (10)	0.0086 (10)
C91	0.0346 (16)	0.0210 (14)	0.0236 (14)	0.0043 (12)	0.0091 (12)	0.0083 (11)
C92	0.0406 (17)	0.0253 (15)	0.0229 (14)	0.0023 (12)	0.0071 (13)	0.0130 (12)
C93	0.0398 (17)	0.0351 (16)	0.0217 (14)	0.0010 (13)	0.0122 (13)	0.0111 (13)
C94	0.0358 (17)	0.0406 (17)	0.0274 (15)	0.0134 (14)	0.0160 (13)	0.0103 (13)
C95	0.0290 (15)	0.0326 (15)	0.0270 (14)	0.0122 (12)	0.0112 (12)	0.0140 (12)
C96	0.0197 (13)	0.0209 (13)	0.0202 (12)	0.0014 (10)	0.0068 (10)	0.0076 (10)
C97	0.0441 (19)	0.0284 (16)	0.0339 (16)	−0.0032 (14)	0.0025 (14)	0.0145 (14)
C98	0.054 (2)	0.0330 (18)	0.053 (2)	−0.0104 (16)	−0.0005 (18)	0.0210 (17)
C99	0.0387 (19)	0.0292 (17)	0.0416 (19)	−0.0045 (14)	−0.0066 (15)	0.0055 (14)
C100	0.0342 (16)	0.0304 (16)	0.0264 (15)	0.0098 (13)	0.0013 (13)	0.0065 (12)
C101	0.0272 (14)	0.0265 (14)	0.0236 (14)	0.0084 (12)	0.0077 (12)	0.0095 (11)
C102	0.0238 (14)	0.0204 (13)	0.0213 (13)	0.0072 (11)	0.0070 (11)	0.0056 (11)
C103	0.0265 (14)	0.0276 (14)	0.0194 (13)	0.0089 (11)	0.0063 (11)	0.0086 (11)
C104	0.0344 (16)	0.0307 (15)	0.0199 (13)	0.0191 (13)	0.0092 (12)	0.0104 (12)
C105	0.0466 (18)	0.0246 (15)	0.0240 (14)	0.0167 (13)	0.0124 (13)	0.0117 (12)
C106	0.0373 (16)	0.0217 (14)	0.0282 (15)	0.0047 (12)	0.0128 (13)	0.0096 (12)
C107	0.0255 (14)	0.0260 (14)	0.0205 (13)	0.0082 (11)	0.0074 (11)	0.0093 (11)
C108	0.0243 (13)	0.0192 (12)	0.0162 (12)	0.0091 (10)	0.0081 (10)	0.0080 (10)
O1	0.027 (2)	0.037 (2)	0.0372 (19)	0.0094 (16)	0.0085 (16)	0.0203 (18)
C109	0.042 (4)	0.049 (4)	0.051 (4)	−0.002 (3)	0.025 (4)	0.012 (3)
C110	0.038 (3)	0.054 (4)	0.059 (4)	−0.003 (3)	0.014 (3)	−0.017 (3)
C111	0.071 (5)	0.047 (4)	0.042 (3)	0.037 (4)	0.015 (3)	0.020 (3)
C112	0.127 (12)	0.033 (4)	0.065 (7)	−0.014 (5)	0.039 (7)	0.014 (4)
O2	0.036 (5)	0.038 (5)	0.039 (4)	0.017 (4)	0.019 (4)	0.018 (4)
C113	0.020 (5)	0.033 (5)	0.049 (6)	0.005 (4)	0.002 (4)	0.014 (4)
C114	0.054 (14)	0.13 (3)	0.18 (3)	0.069 (18)	0.047 (18)	0.11 (3)
C115	0.029 (6)	0.032 (8)	0.041 (7)	0.027 (7)	0.023 (6)	0.020 (7)
C116	0.041 (7)	0.062 (9)	0.175 (16)	0.023 (6)	0.039 (9)	0.072 (10)

Geometric parameters (Å, º)

I1—Ni1	2.6028 (7)	C55—C60	1.394 (3)
I2—Ni2	2.6041 (8)	C55—H55A	0.9500
Ni1—P3	2.2596 (9)	C56—C57	1.380 (4)
Ni1—P1	2.3054 (9)	C56—H56A	0.9500
Ni1—P2	2.3153 (8)	C57—C58	1.379 (4)
Ni2—P4	2.2800 (9)	C57—H57A	0.9500
Ni2—P6	2.2812 (9)	C58—C59	1.396 (4)
Ni2—P5	2.3276 (8)	C58—H58A	0.9500
P1—C18	1.831 (2)	C59—C60	1.392 (3)
P1—C12	1.833 (2)	C59—H59A	0.9500
P1—C6	1.839 (2)	C61—C62	1.383 (4)
P2—C30	1.825 (3)	C61—C66	1.398 (3)
P2—C24	1.833 (3)	C61—H61A	0.9500
P2—C36	1.837 (2)	C62—C63	1.382 (3)
P3—C48	1.831 (2)	C62—H62A	0.9500
P3—C42	1.836 (2)	C63—C64	1.383 (3)
P3—C54	1.836 (2)	C63—H63A	0.9500
P4—C66	1.831 (2)	C64—C65	1.383 (3)
P4—C60	1.831 (3)	C64—H64A	0.9500
P4—C72	1.835 (3)	C65—C66	1.389 (3)
P5—C90	1.832 (3)	C65—H65A	0.9500
P5—C84	1.835 (3)	C67—C72	1.382 (4)
P5—C78	1.837 (3)	C67—C68	1.394 (4)
P6—C108	1.830 (2)	C67—H67A	0.9500
P6—C102	1.835 (3)	C68—C69	1.375 (5)
P6—C96	1.842 (3)	C68—H68A	0.9500
C1—C2	1.386 (3)	C69—C70	1.378 (5)
C1—C6	1.393 (3)	C69—H69A	0.9500
C1—H1A	0.9500	C70—C71	1.389 (4)
C2—C3	1.376 (4)	C70—H70A	0.9500
C2—H2A	0.9500	C71—C72	1.395 (4)
C3—C4	1.376 (4)	C71—H71A	0.9500
C3—H3A	0.9500	C73—C74	1.387 (4)
C4—C5	1.391 (3)	C73—C78	1.396 (4)
C4—H4A	0.9500	C73—H73A	0.9500
C5—C6	1.397 (3)	C74—C75	1.376 (4)
C5—H5A	0.9500	C74—H74A	0.9500
C7—C8	1.384 (3)	C75—C76	1.380 (4)
C7—C12	1.388 (3)	C75—H75A	0.9500
C7—H7A	0.9500	C76—C77	1.387 (4)
C8—C9	1.384 (4)	C76—H76A	0.9500
C8—H8A	0.9500	C77—C78	1.393 (3)
C9—C10	1.368 (4)	C77—H77A	0.9500
C9—H9A	0.9500	C79—C84	1.388 (4)
C10—C11	1.389 (4)	C79—C80	1.398 (4)
C10—H10A	0.9500	C79—H79A	0.9500
C11—C12	1.386 (3)	C80—C81	1.382 (4)
C11—H11A	0.9500	C80—H80A	0.9500
C13—C14	1.382 (3)	C81—C82	1.374 (4)
C13—C18	1.394 (3)	C81—H81A	0.9500
C13—H13A	0.9500	C82—C83	1.383 (4)
C14—C15	1.385 (4)	C82—H82A	0.9500
C14—H14A	0.9500	C83—C84	1.392 (4)
C15—C16	1.389 (4)	C83—H83A	0.9500
C15—H15A	0.9500	C85—C86	1.392 (4)
C16—C17	1.380 (4)	C85—C90	1.396 (3)
C16—H16A	0.9500	C85—H85A	0.9500
C17—C18	1.393 (3)	C86—C87	1.370 (4)
C17—H17A	0.9500	C86—H86A	0.9500
C19—C24	1.378 (4)	C87—C88	1.387 (4)
C19—C20	1.391 (4)	C87—H87A	0.9500
C19—H19A	0.9500	C88—C89	1.385 (4)
C20—C21	1.369 (4)	C88—H88A	0.9500
C20—H20A	0.9500	C89—C90	1.394 (3)
C21—C22	1.382 (4)	C89—H89A	0.9500
C21—H21A	0.9500	C91—C92	1.386 (4)
C22—C23	1.383 (4)	C91—C96	1.399 (4)
C22—H22A	0.9500	C91—H91A	0.9500
C23—C24	1.395 (4)	C92—C93	1.379 (4)
C23—H23A	0.9500	C92—H92A	0.9500
C25—C26	1.384 (4)	C93—C94	1.383 (4)
C25—C30	1.398 (4)	C93—H93A	0.9500
C25—H25A	0.9500	C94—C95	1.384 (4)
C26—C27	1.378 (5)	C94—H94A	0.9500
C26—H26A	0.9500	C95—C96	1.391 (3)
C27—C28	1.378 (4)	C95—H95A	0.9500
C27—H27A	0.9500	C97—C102	1.383 (4)
C28—C29	1.388 (4)	C97—C98	1.384 (4)
C28—H28A	0.9500	C97—H97A	0.9500
C29—C30	1.396 (4)	C98—C99	1.381 (4)
C29—H29A	0.9500	C98—H98A	0.9500
C31—C32	1.386 (4)	C99—C100	1.368 (4)
C31—C36	1.388 (3)	C99—H99A	0.9500
C31—H31A	0.9500	C100—C101	1.384 (4)
C32—C33	1.378 (4)	C100—H10B	0.9500
C32—H32A	0.9500	C101—C102	1.398 (3)
C33—C34	1.384 (4)	C101—H10C	0.9500
C33—H33A	0.9500	C103—C104	1.384 (4)
C34—C35	1.385 (4)	C103—C108	1.403 (3)
C34—H34A	0.9500	C103—H10D	0.9500
C35—C36	1.397 (3)	C104—C105	1.373 (4)
C35—H35A	0.9500	C104—H10E	0.9500
C37—C42	1.385 (3)	C105—C106	1.387 (4)
C37—C38	1.389 (3)	C105—H10F	0.9500
C37—H37A	0.9500	C106—C107	1.385 (4)
C38—C39	1.375 (4)	C106—H10G	0.9500
C38—H38A	0.9500	C107—C108	1.391 (3)
C39—C40	1.379 (4)	C107—H10H	0.9500
C39—H39A	0.9500	O1—C111	1.394 (7)
C40—C41	1.384 (4)	O1—C109	1.427 (10)
C40—H40A	0.9500	C109—C110	1.474 (12)
C41—C42	1.391 (3)	C109—H10I	0.9900
C41—H41A	0.9500	C109—H10J	0.9900
C43—C48	1.385 (3)	C110—H11B	0.9800
C43—C44	1.396 (4)	C110—H11C	0.9800
C43—H43A	0.9500	C110—H11D	0.9800
C44—C45	1.381 (4)	C111—C112	1.556 (13)
C44—H44A	0.9500	C111—H11E	0.9900
C45—C46	1.377 (4)	C111—H11F	0.9900
C45—H45A	0.9500	C112—H11G	0.9800
C46—C47	1.389 (3)	C112—H11H	0.9800
C46—H46A	0.9500	C112—H11I	0.9800
C47—C48	1.397 (3)	O2—C115	1.423 (15)
C47—H47A	0.9500	O2—C113	1.461 (10)
C49—C50	1.383 (4)	C113—C114	1.486 (18)
C49—C54	1.390 (3)	C113—H11J	0.9900
C49—H49A	0.9500	C113—H11K	0.9900
C50—C51	1.380 (4)	C114—H11L	0.9800
C50—H50A	0.9500	C114—H11M	0.9800
C51—C52	1.384 (3)	C114—H11N	0.9800
C51—H51A	0.9500	C115—C116	1.537 (18)
C52—C53	1.384 (3)	C115—H11O	0.9900
C52—H52A	0.9500	C115—H11P	0.9900
C53—C54	1.395 (3)	C116—H11Q	0.9800
C53—H53A	0.9500	C116—H11R	0.9800
C55—C56	1.386 (3)	C116—H11S	0.9800
P3—Ni1—P1	105.34 (2)	C52—C53—H53A	119.8
P3—Ni1—P2	109.96 (3)	C54—C53—H53A	119.8
P1—Ni1—P2	119.97 (3)	C49—C54—C53	118.8 (2)
P3—Ni1—I1	100.38 (2)	C49—C54—P3	122.58 (19)
P1—Ni1—I1	113.73 (2)	C53—C54—P3	118.62 (18)
P2—Ni1—I1	105.72 (3)	C56—C55—C60	120.3 (2)
P4—Ni2—P6	106.95 (3)	C56—C55—H55A	119.9
P4—Ni2—P5	116.77 (3)	C60—C55—H55A	119.9
P6—Ni2—P5	113.82 (3)	C57—C56—C55	120.6 (3)
P4—Ni2—I2	98.22 (2)	C57—C56—H56A	119.7
P6—Ni2—I2	108.67 (2)	C55—C56—H56A	119.7
P5—Ni2—I2	111.11 (2)	C58—C57—C56	119.8 (2)
C18—P1—C12	101.16 (11)	C58—C57—H57A	120.1
C18—P1—C6	102.89 (11)	C56—C57—H57A	120.1
C12—P1—C6	99.64 (11)	C57—C58—C59	120.0 (3)
C18—P1—Ni1	118.71 (8)	C57—C58—H58A	120.0
C12—P1—Ni1	113.40 (8)	C59—C58—H58A	120.0
C6—P1—Ni1	118.11 (8)	C60—C59—C58	120.6 (3)
C30—P2—C24	105.12 (12)	C60—C59—H59A	119.7
C30—P2—C36	102.73 (11)	C58—C59—H59A	119.7
C24—P2—C36	99.78 (11)	C59—C60—C55	118.7 (2)
C30—P2—Ni1	114.77 (8)	C59—C60—P4	122.0 (2)
C24—P2—Ni1	113.52 (8)	C55—C60—P4	118.93 (19)
C36—P2—Ni1	118.93 (8)	C62—C61—C66	120.3 (2)
C48—P3—C42	104.30 (11)	C62—C61—H61A	119.8
C48—P3—C54	100.51 (11)	C66—C61—H61A	119.8
C42—P3—C54	103.04 (11)	C63—C62—C61	120.7 (2)
C48—P3—Ni1	115.28 (8)	C63—C62—H62A	119.6
C42—P3—Ni1	116.74 (8)	C61—C62—H62A	119.6
C54—P3—Ni1	114.91 (8)	C62—C63—C64	119.4 (2)
C66—P4—C60	100.63 (11)	C62—C63—H63A	120.3
C66—P4—C72	104.28 (12)	C64—C63—H63A	120.3
C60—P4—C72	102.56 (12)	C65—C64—C63	120.2 (2)
C66—P4—Ni2	117.16 (8)	C65—C64—H64A	119.9
C60—P4—Ni2	121.61 (8)	C63—C64—H64A	119.9
C72—P4—Ni2	108.49 (8)	C64—C65—C66	121.0 (2)
C90—P5—C84	101.51 (12)	C64—C65—H65A	119.5
C90—P5—C78	101.66 (11)	C66—C65—H65A	119.5
C84—P5—C78	102.71 (12)	C65—C66—C61	118.4 (2)
C90—P5—Ni2	115.01 (8)	C65—C66—P4	118.07 (18)
C84—P5—Ni2	116.57 (8)	C61—C66—P4	123.41 (19)
C78—P5—Ni2	117.04 (8)	C72—C67—C68	120.3 (3)
C108—P6—C102	102.58 (11)	C72—C67—H67A	119.9
C108—P6—C96	101.74 (11)	C68—C67—H67A	119.9
C102—P6—C96	101.88 (12)	C69—C68—C67	120.6 (3)
C108—P6—Ni2	121.16 (8)	C69—C68—H68A	119.7
C102—P6—Ni2	112.95 (8)	C67—C68—H68A	119.7
C96—P6—Ni2	114.10 (8)	C68—C69—C70	119.7 (3)
C2—C1—C6	120.0 (2)	C68—C69—H69A	120.1
C2—C1—H1A	120.0	C70—C69—H69A	120.1
C6—C1—H1A	120.0	C69—C70—C71	119.9 (3)
C3—C2—C1	121.0 (3)	C69—C70—H70A	120.0
C3—C2—H2A	119.5	C71—C70—H70A	120.0
C1—C2—H2A	119.5	C70—C71—C72	120.8 (3)
C4—C3—C2	119.8 (2)	C70—C71—H71A	119.6
C4—C3—H3A	120.1	C72—C71—H71A	119.6
C2—C3—H3A	120.1	C67—C72—C71	118.6 (3)
C3—C4—C5	120.0 (3)	C67—C72—P4	124.0 (2)
C3—C4—H4A	120.0	C71—C72—P4	117.1 (2)
C5—C4—H4A	120.0	C74—C73—C78	120.9 (3)
C4—C5—C6	120.6 (2)	C74—C73—H73A	119.5
C4—C5—H5A	119.7	C78—C73—H73A	119.5
C6—C5—H5A	119.7	C75—C74—C73	120.1 (3)
C1—C6—C5	118.6 (2)	C75—C74—H74A	119.9
C1—C6—P1	120.72 (19)	C73—C74—H74A	119.9
C5—C6—P1	120.58 (18)	C74—C75—C76	119.8 (3)
C8—C7—C12	121.0 (2)	C74—C75—H75A	120.1
C8—C7—H7A	119.5	C76—C75—H75A	120.1
C12—C7—H7A	119.5	C75—C76—C77	120.3 (3)
C9—C8—C7	120.0 (3)	C75—C76—H76A	119.8
C9—C8—H8A	120.0	C77—C76—H76A	119.8
C7—C8—H8A	120.0	C76—C77—C78	120.7 (3)
C10—C9—C8	119.6 (3)	C76—C77—H77A	119.6
C10—C9—H9A	120.2	C78—C77—H77A	119.6
C8—C9—H9A	120.2	C77—C78—C73	118.0 (2)
C9—C10—C11	120.5 (3)	C77—C78—P5	124.2 (2)
C9—C10—H10A	119.8	C73—C78—P5	117.8 (2)
C11—C10—H10A	119.8	C84—C79—C80	120.3 (3)
C12—C11—C10	120.7 (3)	C84—C79—H79A	119.8
C12—C11—H11A	119.6	C80—C79—H79A	119.8
C10—C11—H11A	119.6	C81—C80—C79	120.1 (3)
C11—C12—C7	118.2 (2)	C81—C80—H80A	119.9
C11—C12—P1	122.00 (19)	C79—C80—H80A	119.9
C7—C12—P1	119.61 (19)	C82—C81—C80	119.5 (3)
C14—C13—C18	120.7 (2)	C82—C81—H81A	120.2
C14—C13—H13A	119.7	C80—C81—H81A	120.2
C18—C13—H13A	119.7	C81—C82—C83	120.8 (3)
C13—C14—C15	120.7 (2)	C81—C82—H82A	119.6
C13—C14—H14A	119.7	C83—C82—H82A	119.6
C15—C14—H14A	119.7	C82—C83—C84	120.5 (3)
C14—C15—C16	119.0 (2)	C82—C83—H83A	119.7
C14—C15—H15A	120.5	C84—C83—H83A	119.7
C16—C15—H15A	120.5	C79—C84—C83	118.7 (2)
C17—C16—C15	120.3 (2)	C79—C84—P5	122.6 (2)
C17—C16—H16A	119.8	C83—C84—P5	118.6 (2)
C15—C16—H16A	119.8	C86—C85—C90	119.8 (3)
C16—C17—C18	121.1 (2)	C86—C85—H85A	120.1
C16—C17—H17A	119.5	C90—C85—H85A	120.1
C18—C17—H17A	119.5	C87—C86—C85	120.8 (3)
C17—C18—C13	118.2 (2)	C87—C86—H86A	119.6
C17—C18—P1	116.89 (18)	C85—C86—H86A	119.6
C13—C18—P1	124.94 (18)	C86—C87—C88	120.0 (3)
C24—C19—C20	121.6 (3)	C86—C87—H87A	120.0
C24—C19—H19A	119.2	C88—C87—H87A	120.0
C20—C19—H19A	119.2	C89—C88—C87	119.7 (3)
C21—C20—C19	119.5 (3)	C89—C88—H88A	120.2
C21—C20—H20A	120.2	C87—C88—H88A	120.2
C19—C20—H20A	120.2	C88—C89—C90	120.9 (2)
C20—C21—C22	120.0 (3)	C88—C89—H89A	119.5
C20—C21—H21A	120.0	C90—C89—H89A	119.5
C22—C21—H21A	120.0	C89—C90—C85	118.7 (2)
C21—C22—C23	120.3 (3)	C89—C90—P5	118.17 (19)
C21—C22—H22A	119.8	C85—C90—P5	123.1 (2)
C23—C22—H22A	119.8	C92—C91—C96	120.5 (3)
C22—C23—C24	120.4 (3)	C92—C91—H91A	119.7
C22—C23—H23A	119.8	C96—C91—H91A	119.7
C24—C23—H23A	119.8	C93—C92—C91	120.3 (3)
C19—C24—C23	118.1 (2)	C93—C92—H92A	119.9
C19—C24—P2	118.8 (2)	C91—C92—H92A	119.9
C23—C24—P2	123.0 (2)	C92—C93—C94	119.8 (3)
C26—C25—C30	120.5 (3)	C92—C93—H93A	120.1
C26—C25—H25A	119.8	C94—C93—H93A	120.1
C30—C25—H25A	119.8	C93—C94—C95	120.1 (3)
C27—C26—C25	120.5 (3)	C93—C94—H94A	120.0
C27—C26—H26A	119.7	C95—C94—H94A	120.0
C25—C26—H26A	119.7	C94—C95—C96	120.9 (3)
C26—C27—C28	120.1 (3)	C94—C95—H95A	119.5
C26—C27—H27A	120.0	C96—C95—H95A	119.5
C28—C27—H27A	120.0	C95—C96—C91	118.3 (2)
C27—C28—C29	119.7 (3)	C95—C96—P6	122.8 (2)
C27—C28—H28A	120.1	C91—C96—P6	118.89 (19)
C29—C28—H28A	120.1	C102—C97—C98	120.4 (3)
C28—C29—C30	121.1 (3)	C102—C97—H97A	119.8
C28—C29—H29A	119.5	C98—C97—H97A	119.8
C30—C29—H29A	119.5	C99—C98—C97	120.6 (3)
C29—C30—C25	118.1 (2)	C99—C98—H98A	119.7
C29—C30—P2	117.06 (19)	C97—C98—H98A	119.7
C25—C30—P2	124.6 (2)	C100—C99—C98	119.5 (3)
C32—C31—C36	120.7 (3)	C100—C99—H99A	120.3
C32—C31—H31A	119.6	C98—C99—H99A	120.3
C36—C31—H31A	119.6	C99—C100—C101	120.5 (3)
C33—C32—C31	120.0 (3)	C99—C100—H10B	119.8
C33—C32—H32A	120.0	C101—C100—H10B	119.8
C31—C32—H32A	120.0	C100—C101—C102	120.5 (3)
C32—C33—C34	120.0 (2)	C100—C101—H10C	119.7
C32—C33—H33A	120.0	C102—C101—H10C	119.7
C34—C33—H33A	120.0	C97—C102—C101	118.4 (2)
C33—C34—C35	120.2 (3)	C97—C102—P6	121.4 (2)
C33—C34—H34A	119.9	C101—C102—P6	120.1 (2)
C35—C34—H34A	119.9	C104—C103—C108	120.5 (3)
C34—C35—C36	120.3 (2)	C104—C103—H10D	119.8
C34—C35—H35A	119.9	C108—C103—H10D	119.8
C36—C35—H35A	119.9	C105—C104—C103	120.6 (3)
C31—C36—C35	118.8 (2)	C105—C104—H10E	119.7
C31—C36—P2	124.0 (2)	C103—C104—H10E	119.7
C35—C36—P2	117.23 (19)	C104—C105—C106	119.9 (3)
C42—C37—C38	121.0 (2)	C104—C105—H10F	120.0
C42—C37—H37A	119.5	C106—C105—H10F	120.0
C38—C37—H37A	119.5	C107—C106—C105	119.6 (3)
C39—C38—C37	119.8 (3)	C107—C106—H10G	120.2
C39—C38—H38A	120.1	C105—C106—H10G	120.2
C37—C38—H38A	120.1	C106—C107—C108	121.4 (2)
C38—C39—C40	119.9 (3)	C106—C107—H10H	119.3
C38—C39—H39A	120.0	C108—C107—H10H	119.3
C40—C39—H39A	120.0	C107—C108—C103	118.0 (2)
C39—C40—C41	120.3 (3)	C107—C108—P6	118.21 (19)
C39—C40—H40A	119.8	C103—C108—P6	123.78 (19)
C41—C40—H40A	119.8	C111—O1—C109	115.0 (6)
C40—C41—C42	120.5 (3)	O1—C109—C110	115.2 (8)
C40—C41—H41A	119.8	O1—C109—H10I	108.5
C42—C41—H41A	119.8	C110—C109—H10I	108.5
C37—C42—C41	118.5 (2)	O1—C109—H10J	108.5
C37—C42—P3	117.32 (18)	C110—C109—H10J	108.5
C41—C42—P3	124.0 (2)	H10I—C109—H10J	107.5
C48—C43—C44	120.4 (3)	O1—C111—C112	107.0 (7)
C48—C43—H43A	119.8	O1—C111—H11E	110.3
C44—C43—H43A	119.8	C112—C111—H11E	110.3
C45—C44—C43	120.0 (3)	O1—C111—H11F	110.3
C45—C44—H44A	120.0	C112—C111—H11F	110.3
C43—C44—H44A	120.0	H11E—C111—H11F	108.6
C46—C45—C44	120.0 (2)	C115—O2—C113	113.3 (10)
C46—C45—H45A	120.0	O2—C113—C114	108.1 (11)
C44—C45—H45A	120.0	O2—C113—H11J	110.1
C45—C46—C47	120.3 (3)	C114—C113—H11J	110.1
C45—C46—H46A	119.8	O2—C113—H11K	110.1
C47—C46—H46A	119.8	C114—C113—H11K	110.1
C46—C47—C48	120.2 (2)	H11J—C113—H11K	108.4
C46—C47—H47A	119.9	C113—C114—H11L	109.5
C48—C47—H47A	119.9	C113—C114—H11M	109.5
C43—C48—C47	119.1 (2)	H11L—C114—H11M	109.5
C43—C48—P3	123.43 (19)	C113—C114—H11N	109.5
C47—C48—P3	117.45 (18)	H11L—C114—H11N	109.5
C50—C49—C54	120.4 (2)	H11M—C114—H11N	109.5
C50—C49—H49A	119.8	O2—C115—C116	108.2 (11)
C54—C49—H49A	119.8	O2—C115—H11O	110.1
C51—C50—C49	120.6 (2)	C116—C115—H11O	110.1
C51—C50—H50A	119.7	O2—C115—H11P	110.1
C49—C50—H50A	119.7	C116—C115—H11P	110.1
C50—C51—C52	119.5 (2)	H11O—C115—H11P	108.4
C50—C51—H51A	120.2	C115—C116—H11Q	109.5
C52—C51—H51A	120.2	C115—C116—H11R	109.5
C53—C52—C51	120.3 (2)	H11Q—C116—H11R	109.5
C53—C52—H52A	119.9	C115—C116—H11S	109.5
C51—C52—H52A	119.9	H11Q—C116—H11S	109.5
C52—C53—C54	120.4 (2)	H11R—C116—H11S	109.5
P3—Ni1—P1—C18	−81.40 (9)	C45—C46—C47—C48	1.1 (4)
P2—Ni1—P1—C18	43.13 (9)	C44—C43—C48—C47	−0.2 (4)
I1—Ni1—P1—C18	169.64 (9)	C44—C43—C48—P3	−177.4 (2)
P3—Ni1—P1—C12	160.08 (9)	C46—C47—C48—C43	−0.6 (4)
P2—Ni1—P1—C12	−75.39 (9)	C46—C47—C48—P3	176.77 (19)
I1—Ni1—P1—C12	51.13 (9)	C42—P3—C48—C43	−5.0 (2)
P3—Ni1—P1—C6	44.11 (9)	C54—P3—C48—C43	101.5 (2)
P2—Ni1—P1—C6	168.64 (9)	Ni1—P3—C48—C43	−134.35 (19)
I1—Ni1—P1—C6	−64.84 (9)	C42—P3—C48—C47	177.73 (19)
P3—Ni1—P2—C30	63.52 (10)	C54—P3—C48—C47	−75.8 (2)
P1—Ni1—P2—C30	−58.79 (10)	Ni1—P3—C48—C47	48.4 (2)
I1—Ni1—P2—C30	171.05 (10)	C54—C49—C50—C51	0.0 (4)
P3—Ni1—P2—C24	−175.54 (9)	C49—C50—C51—C52	0.2 (4)
P1—Ni1—P2—C24	62.16 (10)	C50—C51—C52—C53	−0.7 (4)
I1—Ni1—P2—C24	−68.00 (9)	C51—C52—C53—C54	1.0 (4)
P3—Ni1—P2—C36	−58.65 (10)	C50—C49—C54—C53	0.3 (4)
P1—Ni1—P2—C36	179.04 (9)	C50—C49—C54—P3	178.5 (2)
I1—Ni1—P2—C36	48.89 (10)	C52—C53—C54—C49	−0.8 (4)
P1—Ni1—P3—C48	161.25 (9)	C52—C53—C54—P3	−179.02 (18)
P2—Ni1—P3—C48	30.64 (9)	C48—P3—C54—C49	−21.0 (2)
I1—Ni1—P3—C48	−80.42 (9)	C42—P3—C54—C49	86.5 (2)
P1—Ni1—P3—C42	38.30 (9)	Ni1—P3—C54—C49	−145.39 (19)
P2—Ni1—P3—C42	−92.31 (9)	C48—P3—C54—C53	157.19 (19)
I1—Ni1—P3—C42	156.62 (9)	C42—P3—C54—C53	−95.3 (2)
P1—Ni1—P3—C54	−82.54 (9)	Ni1—P3—C54—C53	32.8 (2)
P2—Ni1—P3—C54	146.86 (9)	C60—C55—C56—C57	−2.1 (4)
I1—Ni1—P3—C54	35.79 (9)	C55—C56—C57—C58	0.7 (4)
P6—Ni2—P4—C66	−36.67 (9)	C56—C57—C58—C59	0.9 (4)
P5—Ni2—P4—C66	92.15 (9)	C57—C58—C59—C60	−1.0 (4)
I2—Ni2—P4—C66	−149.13 (9)	C58—C59—C60—C55	−0.4 (4)
P6—Ni2—P4—C60	87.33 (10)	C58—C59—C60—P4	172.2 (2)
P5—Ni2—P4—C60	−143.85 (10)	C56—C55—C60—C59	1.9 (4)
I2—Ni2—P4—C60	−25.13 (10)	C56—C55—C60—P4	−170.91 (19)
P6—Ni2—P4—C72	−154.31 (9)	C66—P4—C60—C59	−82.5 (2)
P5—Ni2—P4—C72	−25.49 (10)	C72—P4—C60—C59	24.8 (2)
I2—Ni2—P4—C72	93.22 (9)	Ni2—P4—C60—C59	146.09 (18)
P4—Ni2—P5—C90	−179.07 (9)	C66—P4—C60—C55	90.0 (2)
P6—Ni2—P5—C90	−53.63 (9)	C72—P4—C60—C55	−162.6 (2)
I2—Ni2—P5—C90	69.43 (9)	Ni2—P4—C60—C55	−41.4 (2)
P4—Ni2—P5—C84	62.28 (10)	C66—C61—C62—C63	−0.4 (4)
P6—Ni2—P5—C84	−172.28 (10)	C61—C62—C63—C64	0.5 (4)
I2—Ni2—P5—C84	−49.22 (10)	C62—C63—C64—C65	0.1 (4)
P4—Ni2—P5—C78	−59.82 (10)	C63—C64—C65—C66	−0.7 (4)
P6—Ni2—P5—C78	65.61 (10)	C64—C65—C66—C61	0.7 (4)
I2—Ni2—P5—C78	−171.33 (9)	C64—C65—C66—P4	176.79 (19)
P4—Ni2—P6—C108	70.35 (9)	C62—C61—C66—C65	−0.2 (4)
P5—Ni2—P6—C108	−60.14 (10)	C62—C61—C66—P4	−176.0 (2)
I2—Ni2—P6—C108	175.47 (9)	C60—P4—C66—C65	−174.49 (19)
P4—Ni2—P6—C102	−51.82 (10)	C72—P4—C66—C65	79.5 (2)
P5—Ni2—P6—C102	177.68 (9)	Ni2—P4—C66—C65	−40.4 (2)
I2—Ni2—P6—C102	53.30 (10)	C60—P4—C66—C61	1.4 (2)
P4—Ni2—P6—C96	−167.57 (9)	C72—P4—C66—C61	−104.7 (2)
P5—Ni2—P6—C96	61.93 (9)	Ni2—P4—C66—C61	135.43 (19)
I2—Ni2—P6—C96	−62.45 (9)	C72—C67—C68—C69	−1.4 (4)
C6—C1—C2—C3	−0.6 (4)	C67—C68—C69—C70	0.5 (5)
C1—C2—C3—C4	−0.3 (4)	C68—C69—C70—C71	0.8 (5)
C2—C3—C4—C5	0.7 (4)	C69—C70—C71—C72	−1.1 (4)
C3—C4—C5—C6	−0.2 (4)	C68—C67—C72—C71	1.1 (4)
C2—C1—C6—C5	1.0 (4)	C68—C67—C72—P4	−173.5 (2)
C2—C1—C6—P1	177.45 (18)	C70—C71—C72—C67	0.2 (4)
C4—C5—C6—C1	−0.7 (4)	C70—C71—C72—P4	175.1 (2)
C4—C5—C6—P1	−177.09 (19)	C66—P4—C72—C67	−10.3 (2)
C18—P1—C6—C1	54.1 (2)	C60—P4—C72—C67	−114.9 (2)
C12—P1—C6—C1	158.0 (2)	Ni2—P4—C72—C67	115.2 (2)
Ni1—P1—C6—C1	−78.8 (2)	C66—P4—C72—C71	175.0 (2)
C18—P1—C6—C5	−129.5 (2)	C60—P4—C72—C71	70.5 (2)
C12—P1—C6—C5	−25.6 (2)	Ni2—P4—C72—C71	−59.4 (2)
Ni1—P1—C6—C5	97.54 (19)	C78—C73—C74—C75	0.4 (4)
C12—C7—C8—C9	1.9 (4)	C73—C74—C75—C76	−2.0 (4)
C7—C8—C9—C10	−0.3 (4)	C74—C75—C76—C77	0.9 (4)
C8—C9—C10—C11	−1.2 (5)	C75—C76—C77—C78	1.9 (4)
C9—C10—C11—C12	1.0 (5)	C76—C77—C78—C73	−3.4 (4)
C10—C11—C12—C7	0.7 (4)	C76—C77—C78—P5	175.2 (2)
C10—C11—C12—P1	175.4 (2)	C74—C73—C78—C77	2.2 (4)
C8—C7—C12—C11	−2.1 (4)	C74—C73—C78—P5	−176.4 (2)
C8—C7—C12—P1	−177.01 (19)	C90—P5—C78—C77	6.9 (2)
C18—P1—C12—C11	26.2 (2)	C84—P5—C78—C77	111.7 (2)
C6—P1—C12—C11	−79.1 (2)	Ni2—P5—C78—C77	−119.2 (2)
Ni1—P1—C12—C11	154.5 (2)	C90—P5—C78—C73	−174.5 (2)
C18—P1—C12—C7	−159.1 (2)	C84—P5—C78—C73	−69.7 (2)
C6—P1—C12—C7	95.6 (2)	Ni2—P5—C78—C73	59.3 (2)
Ni1—P1—C12—C7	−30.8 (2)	C84—C79—C80—C81	1.2 (5)
C18—C13—C14—C15	−0.2 (4)	C79—C80—C81—C82	0.0 (5)
C13—C14—C15—C16	−1.6 (4)	C80—C81—C82—C83	−1.7 (6)
C14—C15—C16—C17	1.8 (4)	C81—C82—C83—C84	2.1 (5)
C15—C16—C17—C18	−0.2 (4)	C80—C79—C84—C83	−0.8 (4)
C16—C17—C18—C13	−1.6 (4)	C80—C79—C84—P5	−176.9 (2)
C16—C17—C18—P1	179.4 (2)	C82—C83—C84—C79	−0.8 (4)
C14—C13—C18—C17	1.8 (4)	C82—C83—C84—P5	175.4 (3)
C14—C13—C18—P1	−179.3 (2)	C90—P5—C84—C79	96.5 (2)
C12—P1—C18—C17	87.0 (2)	C78—P5—C84—C79	−8.4 (3)
C6—P1—C18—C17	−170.23 (19)	Ni2—P5—C84—C79	−137.7 (2)
Ni1—P1—C18—C17	−37.7 (2)	C90—P5—C84—C83	−79.6 (2)
C12—P1—C18—C13	−91.9 (2)	C78—P5—C84—C83	175.5 (2)
C6—P1—C18—C13	10.9 (2)	Ni2—P5—C84—C83	46.1 (2)
Ni1—P1—C18—C13	143.42 (19)	C90—C85—C86—C87	0.8 (4)
C24—C19—C20—C21	−0.1 (5)	C85—C86—C87—C88	0.6 (4)
C19—C20—C21—C22	0.1 (5)	C86—C87—C88—C89	−1.2 (4)
C20—C21—C22—C23	−0.6 (5)	C87—C88—C89—C90	0.4 (4)
C21—C22—C23—C24	1.0 (5)	C88—C89—C90—C85	0.9 (4)
C20—C19—C24—C23	0.5 (4)	C88—C89—C90—P5	−179.01 (19)
C20—C19—C24—P2	176.9 (2)	C86—C85—C90—C89	−1.5 (4)
C22—C23—C24—C19	−1.0 (4)	C86—C85—C90—P5	178.4 (2)
C22—C23—C24—P2	−177.2 (2)	C84—P5—C90—C89	−179.56 (19)
C30—P2—C24—C19	120.7 (2)	C78—P5—C90—C89	−73.8 (2)
C36—P2—C24—C19	−133.2 (2)	Ni2—P5—C90—C89	53.7 (2)
Ni1—P2—C24—C19	−5.5 (2)	C84—P5—C90—C85	0.5 (2)
C30—P2—C24—C23	−63.1 (3)	C78—P5—C90—C85	106.3 (2)
C36—P2—C24—C23	43.0 (3)	Ni2—P5—C90—C85	−126.25 (19)
Ni1—P2—C24—C23	170.6 (2)	C96—C91—C92—C93	1.1 (4)
C30—C25—C26—C27	0.1 (4)	C91—C92—C93—C94	0.4 (4)
C25—C26—C27—C28	−1.6 (4)	C92—C93—C94—C95	−1.1 (4)
C26—C27—C28—C29	1.3 (4)	C93—C94—C95—C96	0.4 (4)
C27—C28—C29—C30	0.4 (4)	C94—C95—C96—C91	1.1 (4)
C28—C29—C30—C25	−1.8 (4)	C94—C95—C96—P6	179.4 (2)
C28—C29—C30—P2	173.0 (2)	C92—C91—C96—C95	−1.8 (4)
C26—C25—C30—C29	1.5 (4)	C92—C91—C96—P6	179.8 (2)
C26—C25—C30—P2	−172.8 (2)	C108—P6—C96—C95	−13.5 (2)
C24—P2—C30—C29	178.7 (2)	C102—P6—C96—C95	92.3 (2)
C36—P2—C30—C29	74.7 (2)	Ni2—P6—C96—C95	−145.7 (2)
Ni1—P2—C30—C29	−55.8 (2)	C108—P6—C96—C91	164.9 (2)
C24—P2—C30—C25	−6.9 (2)	C102—P6—C96—C91	−89.4 (2)
C36—P2—C30—C25	−110.9 (2)	Ni2—P6—C96—C91	32.6 (2)
Ni1—P2—C30—C25	118.6 (2)	C102—C97—C98—C99	0.4 (5)
C36—C31—C32—C33	−1.1 (4)	C97—C98—C99—C100	−1.4 (6)
C31—C32—C33—C34	0.3 (4)	C98—C99—C100—C101	0.9 (5)
C32—C33—C34—C35	0.8 (4)	C99—C100—C101—C102	0.6 (4)
C33—C34—C35—C36	−0.9 (4)	C98—C97—C102—C101	1.1 (5)
C32—C31—C36—C35	1.0 (4)	C98—C97—C102—P6	176.0 (3)
C32—C31—C36—P2	−179.4 (2)	C100—C101—C102—C97	−1.6 (4)
C34—C35—C36—C31	0.1 (4)	C100—C101—C102—P6	−176.6 (2)
C34—C35—C36—P2	−179.6 (2)	C108—P6—C102—C97	137.9 (2)
C30—P2—C36—C31	−10.7 (2)	C96—P6—C102—C97	32.9 (3)
C24—P2—C36—C31	−118.8 (2)	Ni2—P6—C102—C97	−90.0 (2)
Ni1—P2—C36—C31	117.3 (2)	C108—P6—C102—C101	−47.2 (2)
C30—P2—C36—C35	169.00 (19)	C96—P6—C102—C101	−152.3 (2)
C24—P2—C36—C35	60.9 (2)	Ni2—P6—C102—C101	84.9 (2)
Ni1—P2—C36—C35	−63.0 (2)	C108—C103—C104—C105	0.8 (4)
C42—C37—C38—C39	0.2 (4)	C103—C104—C105—C106	−0.4 (4)
C37—C38—C39—C40	−1.2 (4)	C104—C105—C106—C107	0.2 (4)
C38—C39—C40—C41	1.2 (4)	C105—C106—C107—C108	−0.4 (4)
C39—C40—C41—C42	−0.2 (4)	C106—C107—C108—C103	0.8 (4)
C38—C37—C42—C41	0.8 (4)	C106—C107—C108—P6	178.6 (2)
C38—C37—C42—P3	−175.0 (2)	C104—C103—C108—C107	−1.0 (4)
C40—C41—C42—C37	−0.8 (4)	C104—C103—C108—P6	−178.62 (19)
C40—C41—C42—P3	174.7 (2)	C102—P6—C108—C107	158.25 (19)
C48—P3—C42—C37	−104.4 (2)	C96—P6—C108—C107	−96.6 (2)
C54—P3—C42—C37	150.95 (19)	Ni2—P6—C108—C107	31.2 (2)
Ni1—P3—C42—C37	24.0 (2)	C102—P6—C108—C103	−24.1 (2)
C48—P3—C42—C41	80.0 (2)	C96—P6—C108—C103	81.0 (2)
C54—P3—C42—C41	−24.6 (2)	Ni2—P6—C108—C103	−151.15 (18)
Ni1—P3—C42—C41	−151.50 (19)	C111—O1—C109—C110	−72.7 (11)
C48—C43—C44—C45	0.5 (4)	C109—O1—C111—C112	−174.0 (8)
C43—C44—C45—C46	0.0 (4)	C115—O2—C113—C114	−174.2 (14)
C44—C45—C46—C47	−0.8 (4)	C113—O2—C115—C116	175.6 (10)