Eu6Sb6S17 is isotypic with Sr6Sb6S17 and can be regarded as consisting of two isolated [Sb3S7]5- anions and an S32- polysulfide anion that are joined together by Eu2+ cations. There are six crystallographically unique Eu2+ cations bound by sulfide and polysulfide anions in seven-, eight- and nine-coordinate environments. Each of the [Sb3S7]5- anions consists of a trinuclear assembly of corner-sharing SbS3 units. The [Sb3S7]5- anions are connected by long (3.1 Å) Sb-S interactions, forming one-dimensional ribbons running down the a axis and packed with opposing directions of polarity. The bent S32- anions stack in columns parallel to the a axis, oriented in opposing directions with respect to one another. The overall structure is three-dimensional and has channels running down the a axis to house the stereochemically active lone pair of electrons on the Sb3+ centers. The presence of Eu2+ is supported by both magnetic measurements and bond-valence calculations.
Supporting information
Key indicators
- Single-crystal X-ray study
- T = 193 K
- Mean (S-S) = 0.003 Å
- R factor = 0.031
- wR factor = 0.062
- Data-to-parameter ratio = 26.8
checkCIF/PLATON results
No syntax errors found
Alert level B
PLAT112_ALERT_2_B ADDSYM Detects Additional (Pseudo) Symm. Elem... m
PLAT112_ALERT_2_B ADDSYM Detects Additional (Pseudo) Symm. Elem... n
PLAT112_ALERT_2_B ADDSYM Detects Additional (Pseudo) Symm. Elem... b
Alert level C
STRVA01_ALERT_4_C Flack test results are ambiguous.
From the CIF: _refine_ls_abs_structure_Flack 0.699
From the CIF: _refine_ls_abs_structure_Flack_su 0.016
PLAT033_ALERT_2_C Flack Parameter Value Deviates from Zero ....... 0.70
PLAT113_ALERT_2_C ADDSYM Suggests Possible Pseudo/New Spacegroup . Pbca
Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
correct. If it is not, please give the correct count in the
_publ_section_exptl_refinement section of the submitted CIF.
From the CIF: _diffrn_reflns_theta_max 28.32
From the CIF: _reflns_number_total 7062
Count of symmetry unique reflns 3990
Completeness (_total/calc) 176.99%
TEST3: Check Friedels for noncentro structure
Estimate of Friedel pairs measured 3072
Fraction of Friedel pairs measured 0.770
Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem
3 ALERT level B = Potentially serious problem
3 ALERT level C = Check and explain
1 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
5 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
2 ALERT type 4 Improvement, methodology, query or suggestion
checkCIF publication errors
Alert level A
PUBL022_ALERT_1_A There is a mismatched ~ on line 242
chalcoantimonites and chalcobismuthites, <i>e.g.</i> K~2~(Ln~2-~<i>~x~</i>~
If you require a ~ then it should be escaped
with a \, i.e. \~
Otherwise there must be a matching closing ~, e.g. C~2~H~4~
PUBL022_ALERT_1_A There is a mismatched ~ on line 243
~)Sb~4+~<i>~x~</i>Sb~4~Se~12~ (Ln = La, Ce, Pr and Gd; Chen & Dorhout, 1997),
If you require a ~ then it should be escaped
with a \, i.e. \~
Otherwise there must be a matching closing ~, e.g. C~2~H~4~
2 ALERT level A = Data missing that is essential or data in wrong format
0 ALERT level G = General alerts. Data that may be required is missing
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: XP in SHELXTL; software used to prepare material for publication: SHELXTL.
europium antimony sulfide
top
Crystal data top
Eu6Sb6S17 | F(000) = 3824 |
Mr = 2187.28 | Dx = 5.095 Mg m−3 |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 7062 reflections |
a = 8.236 (2) Å | θ = 1.6–28.3° |
b = 15.237 (3) Å | µ = 19.80 mm−1 |
c = 22.724 (5) Å | T = 193 K |
V = 2851.7 (11) Å3 | Prism, black |
Z = 4 | 0.11 × 0.08 × 0.05 mm |
Data collection top
Bruker SMART APEX diffractometer | 7062 independent reflections |
Radiation source: fine-focus sealed tube | 6058 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.055 |
ω scans | θmax = 28.3°, θmin = 1.6° |
Absorption correction: numerical (SHELXTL; Sheldrick, 1997) | h = −10→10 |
Tmin = 0.102, Tmax = 0.383 | k = −20→19 |
29271 measured reflections | l = −30→30 |
Refinement top
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | w = 1/[σ2(Fo2) + (0.0189P)2] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.031 | (Δ/σ)max = 0.002 |
wR(F2) = 0.062 | Δρmax = 1.41 e Å−3 |
S = 1.00 | Δρmin = −1.23 e Å−3 |
7062 reflections | Extinction correction: SHELXTL, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
264 parameters | Extinction coefficient: 0.000081 (7) |
0 restraints | Absolute structure: Flack (1983), 3084 Friedel pairs |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: 0.699 (16) |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Eu1 | −0.24890 (7) | −0.44990 (4) | 0.21293 (3) | 0.01187 (13) | |
Eu2 | 0.25359 (6) | −0.44487 (4) | 0.21124 (2) | 0.01138 (13) | |
Eu3 | 0.25743 (6) | −0.55805 (4) | 0.04396 (2) | 0.01101 (13) | |
Eu4 | 0.75051 (6) | −0.56076 (4) | 0.04524 (2) | 0.01075 (12) | |
Eu5 | 0.75622 (6) | −0.66597 (4) | −0.12281 (2) | 0.01029 (13) | |
Eu6 | 1.24942 (6) | −0.66659 (4) | −0.12393 (2) | 0.01054 (13) | |
Sb1 | −0.02334 (8) | −0.20669 (4) | 0.23203 (2) | 0.01337 (14) | |
Sb2 | 0.01222 (9) | −0.31758 (4) | 0.08537 (2) | 0.01276 (12) | |
Sb3 | 0.49364 (9) | −0.32492 (4) | 0.05958 (2) | 0.01261 (12) | |
Sb4 | 0.53432 (7) | −0.42215 (4) | −0.09216 (3) | 0.01265 (14) | |
Sb5 | 1.01938 (8) | −0.42766 (4) | −0.10816 (2) | 0.01144 (13) | |
Sb6 | 0.99997 (9) | −0.80859 (3) | −0.25011 (2) | 0.01199 (12) | |
S1 | 0.0001 (4) | −0.34890 (13) | 0.28152 (9) | 0.0120 (4) | |
S2 | −0.2157 (3) | −0.26825 (19) | 0.15715 (13) | 0.0126 (6) | |
S3 | 0.2297 (3) | −0.2702 (2) | 0.14998 (14) | 0.0139 (6) | |
S4 | 0.0029 (3) | −0.47102 (14) | 0.11941 (8) | 0.0114 (4) | |
S5 | 0.5040 (3) | −0.46228 (14) | 0.11727 (8) | 0.0110 (4) | |
S6 | 0.2759 (3) | −0.3737 (2) | −0.00482 (13) | 0.0140 (6) | |
S7 | 0.7240 (3) | −0.37670 (19) | −0.00959 (13) | 0.0122 (6) | |
S8 | 0.5070 (3) | −0.56906 (13) | −0.05339 (8) | 0.0099 (4) | |
S9 | 1.0089 (3) | −0.56270 (14) | −0.05055 (8) | 0.0117 (4) | |
S10 | 0.7675 (3) | −0.4741 (2) | −0.16414 (14) | 0.0131 (6) | |
S11 | 1.2424 (3) | −0.4778 (2) | −0.17007 (13) | 0.0133 (6) | |
S12 | 0.7490 (3) | −0.84651 (18) | −0.19195 (12) | 0.0109 (5) | |
S13 | 1.2119 (3) | −0.85439 (19) | −0.18205 (13) | 0.0139 (6) | |
S14 | 0.9982 (4) | −0.65447 (13) | −0.22023 (8) | 0.0104 (4) | |
S15 | 0.5012 (3) | −0.79586 (13) | −0.07184 (8) | 0.0116 (4) | |
S16 | 0.3593 (3) | −0.75150 (16) | −0.00157 (10) | 0.0113 (5) | |
S17 | 0.4964 (3) | −0.70617 (13) | 0.06972 (8) | 0.0120 (4) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Eu1 | 0.0112 (3) | 0.0133 (3) | 0.0110 (3) | −0.0005 (2) | 0.0004 (2) | −0.0009 (2) |
Eu2 | 0.0106 (3) | 0.0131 (3) | 0.0105 (3) | 0.0000 (2) | 0.0000 (2) | −0.0006 (2) |
Eu3 | 0.0088 (2) | 0.0118 (3) | 0.0124 (3) | 0.0002 (2) | 0.0001 (2) | −0.0013 (2) |
Eu4 | 0.0094 (2) | 0.0114 (3) | 0.0115 (3) | 0.0003 (2) | −0.0004 (2) | −0.0013 (2) |
Eu5 | 0.0094 (2) | 0.0111 (3) | 0.0103 (3) | 0.0006 (2) | 0.0000 (2) | 0.0005 (2) |
Eu6 | 0.0090 (2) | 0.0116 (3) | 0.0110 (3) | 0.0006 (2) | −0.0001 (2) | 0.0003 (2) |
Sb1 | 0.0159 (4) | 0.0116 (3) | 0.0126 (3) | −0.0018 (3) | −0.0005 (3) | 0.0003 (2) |
Sb2 | 0.0130 (3) | 0.0118 (3) | 0.0134 (3) | −0.0001 (3) | −0.0021 (3) | 0.0009 (2) |
Sb3 | 0.0124 (3) | 0.0111 (3) | 0.0142 (3) | −0.0006 (3) | −0.0019 (3) | −0.0005 (2) |
Sb4 | 0.0165 (4) | 0.0094 (3) | 0.0121 (3) | 0.0002 (3) | −0.0021 (3) | 0.0016 (2) |
Sb5 | 0.0115 (3) | 0.0098 (3) | 0.0130 (3) | 0.0000 (3) | 0.0009 (3) | −0.0003 (2) |
Sb6 | 0.0117 (3) | 0.0113 (3) | 0.0130 (2) | 0.0004 (4) | −0.0009 (3) | −0.0019 (2) |
S1 | 0.0113 (10) | 0.0120 (10) | 0.0126 (9) | 0.0018 (13) | −0.0018 (13) | −0.0001 (8) |
S2 | 0.0117 (12) | 0.0147 (16) | 0.0115 (14) | 0.0011 (10) | 0.0018 (10) | −0.0004 (12) |
S3 | 0.0130 (12) | 0.0133 (15) | 0.0153 (14) | 0.0001 (11) | 0.0001 (11) | −0.0012 (11) |
S4 | 0.0116 (10) | 0.0117 (10) | 0.0109 (9) | −0.0006 (13) | −0.0006 (12) | −0.0013 (8) |
S5 | 0.0085 (10) | 0.0134 (10) | 0.0112 (9) | 0.0012 (12) | 0.0013 (12) | −0.0013 (8) |
S6 | 0.0136 (13) | 0.0139 (15) | 0.0144 (15) | 0.0020 (11) | −0.0035 (11) | −0.0006 (12) |
S7 | 0.0101 (12) | 0.0123 (15) | 0.0142 (15) | 0.0004 (11) | 0.0003 (11) | −0.0005 (12) |
S8 | 0.0104 (10) | 0.0087 (9) | 0.0105 (9) | 0.0003 (13) | 0.0005 (11) | 0.0001 (7) |
S9 | 0.0116 (10) | 0.0139 (11) | 0.0096 (9) | −0.0003 (12) | 0.0008 (11) | 0.0016 (8) |
S10 | 0.0131 (12) | 0.0137 (15) | 0.0126 (13) | 0.0013 (12) | 0.0001 (11) | −0.0004 (12) |
S11 | 0.0135 (12) | 0.0137 (15) | 0.0128 (14) | 0.0000 (12) | 0.0014 (11) | −0.0001 (12) |
S12 | 0.0110 (12) | 0.0108 (13) | 0.0110 (13) | −0.0007 (11) | −0.0026 (11) | −0.0001 (10) |
S13 | 0.0149 (13) | 0.0117 (14) | 0.0150 (14) | 0.0004 (11) | −0.0029 (10) | −0.0008 (11) |
S14 | 0.0113 (10) | 0.0089 (10) | 0.0111 (9) | 0.0017 (12) | −0.0001 (12) | 0.0006 (7) |
S15 | 0.0127 (10) | 0.0129 (10) | 0.0093 (9) | −0.0007 (14) | −0.0006 (11) | −0.0004 (8) |
S16 | 0.0114 (10) | 0.0107 (11) | 0.0119 (11) | 0.0011 (10) | 0.0020 (10) | 0.0010 (9) |
S17 | 0.0127 (10) | 0.0106 (10) | 0.0128 (9) | 0.0003 (13) | 0.0005 (12) | −0.0005 (8) |
Geometric parameters (Å, º) top
Eu1—S5i | 2.984 (3) | Eu6—S1ix | 2.988 (3) |
Eu1—S4 | 2.987 (3) | Eu6—S14 | 3.017 (3) |
Eu1—S1 | 3.000 (3) | Eu6—S9 | 3.035 (2) |
Eu1—S14ii | 3.009 (3) | Eu6—S8vi | 3.046 (2) |
Eu1—S10ii | 3.028 (3) | Eu6—S11 | 3.063 (3) |
Eu1—S2 | 3.056 (3) | Eu6—S15vi | 3.095 (2) |
Eu1—S13iii | 3.081 (3) | Eu6—S17vii | 3.101 (3) |
Eu1—Eu2i | 4.0983 (12) | Eu6—S13 | 3.167 (3) |
Eu1—Eu5ii | 4.1297 (11) | Eu6—S16vi | 3.197 (3) |
Eu1—Eu2 | 4.1394 (12) | Eu6—Eu2ix | 4.1127 (11) |
Eu1—Eu4i | 4.1683 (11) | Eu6—Eu3vi | 4.1587 (11) |
Eu2—S11iv | 2.944 (3) | Sb1—S1 | 2.449 (2) |
Eu2—S4 | 2.962 (3) | Sb1—S2 | 2.507 (3) |
Eu2—S5 | 2.981 (2) | Sb1—S12ii | 2.664 (3) |
Eu2—S14iv | 2.982 (3) | Sb2—S3 | 2.426 (3) |
Eu2—S1 | 3.008 (3) | Sb2—S4 | 2.464 (2) |
Eu2—S3 | 3.010 (3) | Sb2—S2 | 2.598 (3) |
Eu2—S12v | 3.209 (3) | Sb3—S6 | 2.431 (3) |
Eu2—Eu1vi | 4.0983 (12) | Sb3—S5 | 2.471 (2) |
Eu2—Eu6iv | 4.1127 (11) | Sb3—S7 | 2.587 (3) |
Eu2—Eu3 | 4.1743 (11) | Sb4—S8 | 2.416 (2) |
Eu3—S9i | 2.968 (2) | Sb4—S7 | 2.537 (3) |
Eu3—S5 | 3.005 (3) | Sb4—S10 | 2.644 (3) |
Eu3—S4 | 3.015 (3) | Sb5—S11 | 2.436 (3) |
Eu3—S6 | 3.023 (3) | Sb5—S9 | 2.440 (2) |
Eu3—S8 | 3.024 (2) | Sb5—S10 | 2.534 (3) |
Eu3—S17 | 3.051 (3) | Sb6—S13 | 2.434 (3) |
Eu3—S15v | 3.132 (3) | Sb6—S14 | 2.445 (2) |
Eu3—S16 | 3.235 (3) | Sb6—S12 | 2.520 (3) |
Eu3—Eu4 | 4.0614 (12) | S1—Eu6iv | 2.988 (3) |
Eu3—Eu6i | 4.1587 (11) | S1—Eu5ii | 3.039 (3) |
Eu3—Eu4i | 4.1753 (12) | S4—Eu4i | 3.005 (3) |
Eu4—S4vi | 3.005 (3) | S5—Eu1vi | 2.984 (3) |
Eu4—S5 | 3.009 (2) | S8—Eu6i | 3.046 (2) |
Eu4—S8 | 3.010 (2) | S9—Eu3vi | 2.968 (2) |
Eu4—S9 | 3.044 (2) | S10—Eu1viii | 3.028 (3) |
Eu4—S15vii | 3.066 (3) | S11—Eu2ix | 2.944 (3) |
Eu4—S7 | 3.077 (3) | S12—Sb1viii | 2.664 (3) |
Eu4—S17 | 3.098 (3) | S12—Eu2vii | 3.209 (3) |
Eu4—S16vii | 3.157 (3) | S13—Eu1x | 3.081 (3) |
Eu4—S13v | 3.382 (3) | S13—Eu4vii | 3.382 (3) |
Eu4—Eu5 | 4.1417 (11) | S14—Eu2ix | 2.982 (3) |
Eu4—Eu1vi | 4.1683 (11) | S14—Eu1viii | 3.009 (3) |
Eu5—S8 | 2.980 (2) | S15—S16 | 2.091 (3) |
Eu5—S14 | 2.984 (3) | S15—Eu4v | 3.066 (3) |
Eu5—S17vii | 3.027 (2) | S15—Eu6i | 3.095 (2) |
Eu5—S1viii | 3.039 (3) | S15—Eu3vii | 3.132 (3) |
Eu5—S10 | 3.073 (3) | S16—S17 | 2.092 (3) |
Eu5—S9 | 3.082 (2) | S16—Eu4v | 3.157 (3) |
Eu5—S15 | 3.110 (3) | S16—Eu6i | 3.197 (3) |
Eu5—S12 | 3.168 (3) | S16—Eu5v | 3.208 (2) |
Eu5—S16vii | 3.208 (2) | S17—Eu5v | 3.027 (2) |
Eu5—Eu6 | 4.0621 (12) | S17—Eu6v | 3.101 (3) |
Eu5—Eu1viii | 4.1296 (11) | | |
| | | |
S5i—Eu1—S4 | 87.04 (7) | S14—Eu5—S15 | 139.89 (6) |
S5i—Eu1—S1 | 151.29 (6) | S17vii—Eu5—S15 | 83.30 (7) |
S4—Eu1—S1 | 87.15 (7) | S1viii—Eu5—S15 | 81.07 (7) |
S5i—Eu1—S14ii | 86.32 (7) | S10—Eu5—S15 | 137.74 (7) |
S4—Eu1—S14ii | 152.88 (6) | S9—Eu5—S15 | 125.62 (6) |
S1—Eu1—S14ii | 86.16 (7) | S8—Eu5—S12 | 132.82 (7) |
S5i—Eu1—S10ii | 127.83 (7) | S14—Eu5—S12 | 72.28 (6) |
S4—Eu1—S10ii | 130.57 (7) | S17vii—Eu5—S12 | 69.58 (6) |
S1—Eu1—S10ii | 75.62 (7) | S1viii—Eu5—S12 | 72.36 (6) |
S14ii—Eu1—S10ii | 72.66 (7) | S10—Eu5—S12 | 132.47 (9) |
S5i—Eu1—S2 | 79.41 (7) | S9—Eu5—S12 | 136.05 (7) |
S4—Eu1—S2 | 74.95 (7) | S15—Eu5—S12 | 67.63 (6) |
S1—Eu1—S2 | 71.93 (7) | S8—Eu5—S16vii | 84.84 (6) |
S14ii—Eu1—S2 | 77.99 (6) | S14—Eu5—S16vii | 120.00 (7) |
S10ii—Eu1—S2 | 137.19 (8) | S17vii—Eu5—S16vii | 39.08 (6) |
S5i—Eu1—S13iii | 72.62 (7) | S1viii—Eu5—S16vii | 147.50 (6) |
S4—Eu1—S13iii | 78.84 (7) | S10—Eu5—S16vii | 129.37 (8) |
S1—Eu1—S13iii | 133.35 (7) | S9—Eu5—S16vii | 63.40 (6) |
S14ii—Eu1—S13iii | 123.72 (7) | S15—Eu5—S16vii | 66.48 (6) |
S10ii—Eu1—S13iii | 80.47 (8) | S12—Eu5—S16vii | 95.83 (7) |
S2—Eu1—S13iii | 142.33 (8) | S8—Eu5—Eu6 | 133.88 (5) |
S5i—Eu1—Eu2i | 46.57 (5) | S14—Eu5—Eu6 | 47.75 (5) |
S4—Eu1—Eu2i | 133.59 (5) | S17vii—Eu5—Eu6 | 49.27 (5) |
S1—Eu1—Eu2i | 132.73 (5) | S1viii—Eu5—Eu6 | 133.66 (5) |
S14ii—Eu1—Eu2i | 46.57 (5) | S10—Eu5—Eu6 | 88.28 (5) |
S10ii—Eu1—Eu2i | 88.00 (5) | S9—Eu5—Eu6 | 47.90 (5) |
S2—Eu1—Eu2i | 93.94 (5) | S15—Eu5—Eu6 | 132.55 (5) |
S13iii—Eu1—Eu2i | 84.90 (5) | S12—Eu5—Eu6 | 90.78 (5) |
S5i—Eu1—Eu5ii | 132.50 (5) | S16vii—Eu5—Eu6 | 74.93 (4) |
S4—Eu1—Eu5ii | 134.37 (5) | S8—Eu5—Eu1viii | 104.87 (4) |
S1—Eu1—Eu5ii | 47.25 (5) | S14—Eu5—Eu1viii | 46.69 (5) |
S14ii—Eu1—Eu5ii | 46.19 (5) | S17vii—Eu5—Eu1viii | 130.16 (4) |
S10ii—Eu1—Eu5ii | 47.86 (6) | S1viii—Eu5—Eu1viii | 46.47 (5) |
S2—Eu1—Eu5ii | 89.37 (6) | S10—Eu5—Eu1viii | 46.94 (6) |
S13iii—Eu1—Eu5ii | 128.19 (6) | S9—Eu5—Eu1viii | 105.85 (4) |
Eu2i—Eu1—Eu5ii | 89.191 (17) | S15—Eu5—Eu1viii | 126.79 (4) |
S5i—Eu1—Eu2 | 132.56 (5) | S12—Eu5—Eu1viii | 85.56 (5) |
S4—Eu1—Eu2 | 45.67 (5) | S16vii—Eu5—Eu1viii | 165.44 (4) |
S1—Eu1—Eu2 | 46.53 (5) | Eu6—Eu5—Eu1viii | 90.568 (17) |
S14ii—Eu1—Eu2 | 132.63 (5) | S8—Eu5—Eu4 | 46.56 (4) |
S10ii—Eu1—Eu2 | 93.80 (5) | S14—Eu5—Eu4 | 131.98 (5) |
S2—Eu1—Eu2 | 83.68 (5) | S17vii—Eu5—Eu4 | 83.63 (4) |
S13iii—Eu1—Eu2 | 96.93 (5) | S1viii—Eu5—Eu4 | 128.53 (5) |
Eu2i—Eu1—Eu2 | 177.62 (3) | S10—Eu5—Eu4 | 85.06 (6) |
Eu5ii—Eu1—Eu2 | 90.863 (17) | S9—Eu5—Eu4 | 47.07 (4) |
S5i—Eu1—Eu4i | 46.17 (5) | S15—Eu5—Eu4 | 83.99 (4) |
S4—Eu1—Eu4i | 46.10 (5) | S12—Eu5—Eu4 | 142.47 (5) |
S1—Eu1—Eu4i | 133.12 (5) | S16vii—Eu5—Eu4 | 48.88 (5) |
S14ii—Eu1—Eu4i | 132.45 (5) | Eu6—Eu5—Eu4 | 91.034 (17) |
S10ii—Eu1—Eu4i | 133.49 (6) | Eu1viii—Eu5—Eu4 | 131.89 (2) |
S2—Eu1—Eu4i | 89.31 (6) | S1ix—Eu6—S14 | 86.97 (7) |
S13iii—Eu1—Eu4i | 53.08 (6) | S1ix—Eu6—S9 | 143.57 (6) |
Eu2i—Eu1—Eu4i | 89.877 (16) | S14—Eu6—S9 | 85.35 (7) |
Eu5ii—Eu1—Eu4i | 178.329 (19) | S1ix—Eu6—S8vi | 81.89 (7) |
Eu2—Eu1—Eu4i | 90.010 (16) | S14—Eu6—S8vi | 146.04 (6) |
S11iv—Eu2—S4 | 126.82 (7) | S9—Eu6—S8vi | 84.90 (7) |
S11iv—Eu2—S5 | 127.81 (7) | S1ix—Eu6—S11 | 72.10 (7) |
S4—Eu2—S5 | 88.03 (7) | S14—Eu6—S11 | 71.41 (7) |
S11iv—Eu2—S14iv | 73.56 (7) | S9—Eu6—S11 | 71.69 (7) |
S4—Eu2—S14iv | 156.03 (6) | S8vi—Eu6—S11 | 74.64 (7) |
S5—Eu2—S14iv | 86.85 (7) | S1ix—Eu6—S15vi | 82.11 (7) |
S11iv—Eu2—S1 | 73.50 (7) | S14—Eu6—S15vi | 140.87 (6) |
S4—Eu2—S1 | 87.46 (7) | S9—Eu6—S15vi | 124.00 (6) |
S5—Eu2—S1 | 154.68 (6) | S8vi—Eu6—S15vi | 69.06 (6) |
S14iv—Eu2—S1 | 87.24 (7) | S11—Eu6—S15vi | 137.85 (7) |
S11iv—Eu2—S3 | 141.13 (8) | S1ix—Eu6—S17vii | 143.02 (6) |
S4—Eu2—S3 | 75.38 (7) | S14—Eu6—S17vii | 82.28 (7) |
S5—Eu2—S3 | 78.03 (7) | S9—Eu6—S17vii | 70.68 (6) |
S14iv—Eu2—S3 | 80.65 (7) | S8vi—Eu6—S17vii | 124.33 (6) |
S1—Eu2—S3 | 76.72 (7) | S11—Eu6—S17vii | 135.28 (7) |
S11iv—Eu2—S12v | 74.26 (8) | S15vi—Eu6—S17vii | 84.29 (7) |
S4—Eu2—S12v | 76.25 (7) | S1ix—Eu6—S13 | 80.73 (7) |
S5—Eu2—S12v | 79.75 (6) | S14—Eu6—S13 | 71.69 (6) |
S14iv—Eu2—S12v | 125.60 (7) | S9—Eu6—S13 | 129.54 (7) |
S1—Eu2—S12v | 123.09 (7) | S8vi—Eu6—S13 | 136.75 (7) |
S3—Eu2—S12v | 144.28 (8) | S11—Eu6—S13 | 134.76 (9) |
S11iv—Eu2—Eu1vi | 88.43 (5) | S15vi—Eu6—S13 | 69.51 (6) |
S4—Eu2—Eu1vi | 134.50 (5) | S17vii—Eu6—S13 | 62.30 (6) |
S5—Eu2—Eu1vi | 46.62 (5) | S1ix—Eu6—S16vi | 117.51 (7) |
S14iv—Eu2—Eu1vi | 47.10 (5) | S14—Eu6—S16vi | 148.16 (6) |
S1—Eu2—Eu1vi | 134.27 (5) | S9—Eu6—S16vi | 85.30 (6) |
S3—Eu2—Eu1vi | 94.95 (5) | S8vi—Eu6—S16vi | 62.79 (6) |
S12v—Eu2—Eu1vi | 89.68 (5) | S11—Eu6—S16vi | 133.09 (8) |
S11iv—Eu2—Eu6iv | 48.01 (6) | S15vi—Eu6—S16vi | 38.78 (6) |
S4—Eu2—Eu6iv | 133.86 (5) | S17vii—Eu6—S16vi | 65.91 (6) |
S5—Eu2—Eu6iv | 133.90 (5) | S13—Eu6—S16vi | 91.41 (7) |
S14iv—Eu2—Eu6iv | 47.08 (5) | S1ix—Eu6—Eu5 | 134.01 (5) |
S1—Eu2—Eu6iv | 46.49 (5) | S14—Eu6—Eu5 | 47.05 (5) |
S3—Eu2—Eu6iv | 93.20 (6) | S9—Eu6—Eu5 | 48.89 (5) |
S12v—Eu2—Eu6iv | 122.23 (5) | S8vi—Eu6—Eu5 | 133.79 (5) |
Eu1vi—Eu2—Eu6iv | 90.299 (17) | S11—Eu6—Eu5 | 88.91 (5) |
S11iv—Eu2—Eu1 | 89.73 (5) | S15vi—Eu6—Eu5 | 131.99 (5) |
S4—Eu2—Eu1 | 46.15 (5) | S17vii—Eu6—Eu5 | 47.71 (5) |
S5—Eu2—Eu1 | 134.17 (5) | S13—Eu6—Eu5 | 84.67 (5) |
S14iv—Eu2—Eu1 | 133.62 (5) | S16vi—Eu6—Eu5 | 106.17 (4) |
S1—Eu2—Eu1 | 46.38 (5) | S1ix—Eu6—Eu2ix | 46.90 (5) |
S3—Eu2—Eu1 | 87.44 (5) | S14—Eu6—Eu2ix | 46.37 (5) |
S12v—Eu2—Eu1 | 88.35 (5) | S9—Eu6—Eu2ix | 106.32 (4) |
Eu1vi—Eu2—Eu1 | 177.62 (3) | S8vi—Eu6—Eu2ix | 106.38 (4) |
Eu6iv—Eu2—Eu1 | 89.609 (17) | S11—Eu6—Eu2ix | 45.59 (6) |
S11iv—Eu2—Eu3 | 131.98 (6) | S15vi—Eu6—Eu2ix | 127.96 (4) |
S4—Eu2—Eu3 | 46.23 (5) | S17vii—Eu6—Eu2ix | 128.01 (4) |
S5—Eu2—Eu3 | 46.02 (5) | S13—Eu6—Eu2ix | 89.58 (6) |
S14iv—Eu2—Eu3 | 132.84 (5) | S16vi—Eu6—Eu2ix | 163.90 (4) |
S1—Eu2—Eu3 | 133.60 (5) | Eu5—Eu6—Eu2ix | 89.927 (17) |
S3—Eu2—Eu3 | 86.82 (6) | S1ix—Eu6—Eu3vi | 128.12 (5) |
S12v—Eu2—Eu3 | 57.75 (5) | S14—Eu6—Eu3vi | 130.68 (5) |
Eu1vi—Eu2—Eu3 | 89.613 (17) | S9—Eu6—Eu3vi | 45.49 (5) |
Eu6iv—Eu2—Eu3 | 179.911 (18) | S8vi—Eu6—Eu3vi | 46.54 (4) |
Eu1—Eu2—Eu3 | 90.479 (16) | S11—Eu6—Eu3vi | 86.61 (6) |
S9i—Eu3—S5 | 151.52 (6) | S15vi—Eu6—Eu3vi | 83.78 (4) |
S9i—Eu3—S4 | 86.70 (7) | S17vii—Eu6—Eu3vi | 83.97 (4) |
S5—Eu3—S4 | 86.62 (7) | S13—Eu6—Eu3vi | 138.03 (6) |
S9i—Eu3—S6 | 77.96 (7) | S16vi—Eu6—Eu3vi | 50.11 (5) |
S5—Eu3—S6 | 73.63 (7) | Eu5—Eu6—Eu3vi | 90.525 (17) |
S4—Eu3—S6 | 80.49 (7) | Eu2ix—Eu6—Eu3vi | 132.17 (2) |
S9i—Eu3—S8 | 86.46 (7) | S1—Sb1—S2 | 91.74 (9) |
S5—Eu3—S8 | 88.46 (7) | S1—Sb1—S12ii | 91.51 (9) |
S4—Eu3—S8 | 155.89 (6) | S2—Sb1—S12ii | 96.50 (9) |
S6—Eu3—S8 | 75.48 (7) | S3—Sb2—S4 | 96.62 (9) |
S9i—Eu3—S17 | 124.48 (6) | S3—Sb2—S2 | 93.86 (8) |
S5—Eu3—S17 | 79.45 (6) | S4—Sb2—S2 | 93.15 (9) |
S4—Eu3—S17 | 131.65 (6) | S6—Sb3—S5 | 94.92 (10) |
S6—Eu3—S17 | 136.48 (7) | S6—Sb3—S7 | 94.70 (7) |
S8—Eu3—S17 | 70.18 (6) | S5—Sb3—S7 | 92.21 (9) |
S9i—Eu3—S15v | 70.41 (6) | S8—Sb4—S7 | 92.32 (9) |
S5—Eu3—S15v | 133.50 (6) | S8—Sb4—S10 | 90.92 (9) |
S4—Eu3—S15v | 74.28 (6) | S7—Sb4—S10 | 95.27 (9) |
S6—Eu3—S15v | 140.20 (7) | S11—Sb5—S9 | 94.14 (9) |
S8—Eu3—S15v | 124.50 (6) | S11—Sb5—S10 | 103.87 (8) |
S17—Eu3—S15v | 82.54 (7) | S9—Sb5—S10 | 90.28 (10) |
S9i—Eu3—S16 | 85.74 (6) | S13—Sb6—S14 | 95.92 (9) |
S5—Eu3—S16 | 116.40 (6) | S13—Sb6—S12 | 100.90 (9) |
S4—Eu3—S16 | 139.72 (6) | S14—Sb6—S12 | 94.00 (9) |
S6—Eu3—S16 | 135.75 (7) | Sb1—S1—Eu6iv | 108.34 (8) |
S8—Eu3—S16 | 62.56 (6) | Sb1—S1—Eu1 | 99.29 (8) |
S17—Eu3—S16 | 38.75 (6) | Eu6iv—S1—Eu1 | 152.37 (8) |
S15v—Eu3—S16 | 65.90 (6) | Sb1—S1—Eu2 | 103.94 (8) |
S9i—Eu3—Eu4 | 134.00 (5) | Eu6iv—S1—Eu2 | 86.61 (8) |
S5—Eu3—Eu4 | 47.56 (5) | Eu1—S1—Eu2 | 87.09 (6) |
S4—Eu3—Eu4 | 134.07 (5) | Sb1—S1—Eu5ii | 102.00 (8) |
S6—Eu3—Eu4 | 87.81 (5) | Eu6iv—S1—Eu5ii | 87.67 (6) |
S8—Eu3—Eu4 | 47.55 (5) | Eu1—S1—Eu5ii | 86.28 (8) |
S17—Eu3—Eu4 | 49.16 (5) | Eu2—S1—Eu5ii | 153.93 (8) |
S15v—Eu3—Eu4 | 131.69 (5) | Sb1—S2—Sb2 | 94.47 (9) |
S16—Eu3—Eu4 | 74.56 (4) | Sb1—S2—Eu1 | 96.54 (9) |
S9i—Eu3—Eu6i | 46.82 (5) | Sb2—S2—Eu1 | 93.62 (9) |
S5—Eu3—Eu6i | 135.43 (5) | Sb2—S3—Eu2 | 93.73 (9) |
S4—Eu3—Eu6i | 133.27 (5) | Sb2—S4—Eu2 | 94.12 (8) |
S6—Eu3—Eu6i | 91.94 (6) | Sb2—S4—Eu1 | 98.21 (8) |
S8—Eu3—Eu6i | 46.98 (5) | Eu2—S4—Eu1 | 88.18 (5) |
S17—Eu3—Eu6i | 83.81 (4) | Sb2—S4—Eu4i | 106.09 (8) |
S15v—Eu3—Eu6i | 83.81 (4) | Eu2—S4—Eu4i | 159.78 (8) |
S16—Eu3—Eu6i | 49.33 (4) | Eu1—S4—Eu4i | 88.16 (8) |
Eu4—Eu3—Eu6i | 91.052 (17) | Sb2—S4—Eu3 | 102.54 (8) |
S9i—Eu3—Eu2 | 131.58 (5) | Eu2—S4—Eu3 | 88.57 (8) |
S5—Eu3—Eu2 | 45.54 (5) | Eu1—S4—Eu3 | 159.18 (8) |
S4—Eu3—Eu2 | 45.19 (5) | Eu4i—S4—Eu3 | 87.81 (5) |
S6—Eu3—Eu2 | 87.16 (6) | Sb3—S5—Eu2 | 106.30 (8) |
S8—Eu3—Eu2 | 133.96 (5) | Sb3—S5—Eu1vi | 110.89 (9) |
S17—Eu3—Eu2 | 97.80 (4) | Eu2—S5—Eu1vi | 86.81 (5) |
S15v—Eu3—Eu2 | 95.99 (4) | Sb3—S5—Eu3 | 95.38 (7) |
S16—Eu3—Eu2 | 132.05 (5) | Eu2—S5—Eu3 | 88.44 (8) |
Eu4—Eu3—Eu2 | 90.302 (17) | Eu1vi—S5—Eu3 | 153.59 (8) |
Eu6i—Eu3—Eu2 | 178.347 (18) | Sb3—S5—Eu4 | 99.04 (7) |
S9i—Eu3—Eu4i | 46.77 (5) | Eu2—S5—Eu4 | 154.30 (8) |
S5—Eu3—Eu4i | 132.59 (5) | Eu1vi—S5—Eu4 | 88.15 (8) |
S4—Eu3—Eu4i | 45.99 (5) | Eu3—S5—Eu4 | 84.96 (5) |
S6—Eu3—Eu4i | 93.55 (5) | Sb3—S6—Eu3 | 95.77 (9) |
S8—Eu3—Eu4i | 133.17 (5) | Sb4—S7—Sb3 | 94.66 (9) |
S17—Eu3—Eu4i | 129.52 (5) | Sb4—S7—Eu4 | 95.42 (9) |
S15v—Eu3—Eu4i | 46.99 (5) | Sb3—S7—Eu4 | 94.82 (9) |
S16—Eu3—Eu4i | 104.63 (4) | Sb4—S8—Eu5 | 101.65 (8) |
Eu4—Eu3—Eu4i | 178.60 (3) | Sb4—S8—Eu4 | 99.82 (8) |
Eu6i—Eu3—Eu4i | 89.231 (17) | Eu5—S8—Eu4 | 87.48 (7) |
Eu2—Eu3—Eu4i | 89.438 (16) | Sb4—S8—Eu3 | 106.17 (8) |
S4vi—Eu4—S5 | 86.25 (7) | Eu5—S8—Eu3 | 151.97 (8) |
S4vi—Eu4—S8 | 153.84 (6) | Eu4—S8—Eu3 | 84.60 (5) |
S5—Eu4—S8 | 88.65 (7) | Sb4—S8—Eu6i | 108.96 (8) |
S4vi—Eu4—S9 | 85.53 (7) | Eu5—S8—Eu6i | 87.67 (5) |
S5—Eu4—S9 | 149.94 (6) | Eu4—S8—Eu6i | 151.20 (8) |
S8—Eu4—S9 | 86.15 (7) | Eu3—S8—Eu6i | 86.48 (7) |
S4vi—Eu4—S15vii | 75.39 (6) | Sb5—S9—Eu3vi | 110.09 (9) |
S5—Eu4—S15vii | 134.62 (6) | Sb5—S9—Eu6 | 97.00 (7) |
S8—Eu4—S15vii | 124.44 (6) | Eu3vi—S9—Eu6 | 87.69 (7) |
S9—Eu4—S15vii | 70.33 (6) | Sb5—S9—Eu4 | 113.59 (9) |
S4vi—Eu4—S7 | 82.04 (7) | Eu3vi—S9—Eu4 | 87.96 (5) |
S5—Eu4—S7 | 73.61 (7) | Eu6—S9—Eu4 | 148.67 (8) |
S8—Eu4—S7 | 71.91 (7) | Sb5—S9—Eu5 | 99.71 (7) |
S9—Eu4—S7 | 76.64 (7) | Eu3vi—S9—Eu5 | 149.68 (8) |
S15vii—Eu4—S7 | 141.00 (7) | Eu6—S9—Eu5 | 83.21 (5) |
S4vi—Eu4—S17 | 133.78 (6) | Eu4—S9—Eu5 | 85.07 (7) |
S5—Eu4—S17 | 78.65 (6) | Sb5—S10—Sb4 | 101.57 (11) |
S8—Eu4—S17 | 69.73 (6) | Sb5—S10—Eu1viii | 127.69 (10) |
S9—Eu4—S17 | 126.42 (6) | Sb4—S10—Eu1viii | 130.42 (10) |
S15vii—Eu4—S17 | 84.84 (7) | Sb5—S10—Eu5 | 97.87 (10) |
S7—Eu4—S17 | 132.58 (7) | Sb4—S10—Eu5 | 94.22 (9) |
S4vi—Eu4—S16vii | 113.09 (6) | Eu1viii—S10—Eu5 | 85.20 (8) |
S5—Eu4—S16vii | 144.51 (6) | Sb5—S11—Eu2ix | 131.54 (11) |
S8—Eu4—S16vii | 85.24 (6) | Sb5—S11—Eu6 | 96.37 (9) |
S9—Eu4—S16vii | 64.42 (6) | Eu2ix—S11—Eu6 | 86.41 (8) |
S15vii—Eu4—S16vii | 39.23 (6) | Sb6—S12—Sb1viii | 99.35 (10) |
S7—Eu4—S16vii | 135.95 (7) | Sb6—S12—Eu5 | 92.62 (8) |
S17—Eu4—S16vii | 66.43 (6) | Sb1viii—S12—Eu5 | 94.04 (8) |
S4vi—Eu4—S13v | 73.94 (6) | Sb6—S12—Eu2vii | 98.38 (9) |
S5—Eu4—S13v | 68.10 (6) | Sb1viii—S12—Eu2vii | 102.77 (8) |
S8—Eu4—S13v | 127.28 (6) | Eu5—S12—Eu2vii | 158.05 (10) |
S9—Eu4—S13v | 136.00 (6) | Sb6—S13—Eu1x | 102.00 (9) |
S15vii—Eu4—S13v | 67.03 (6) | Sb6—S13—Eu6 | 94.36 (9) |
S7—Eu4—S13v | 135.57 (8) | Eu1x—S13—Eu6 | 163.64 (10) |
S17—Eu4—S13v | 59.86 (6) | Sb6—S13—Eu4vii | 139.56 (11) |
S16vii—Eu4—S13v | 88.24 (7) | Eu1x—S13—Eu4vii | 80.18 (7) |
S4vi—Eu4—Eu3 | 133.71 (5) | Eu6—S13—Eu4vii | 87.30 (7) |
S5—Eu4—Eu3 | 47.48 (5) | Sb6—S14—Eu2ix | 109.78 (9) |
S8—Eu4—Eu3 | 47.85 (5) | Sb6—S14—Eu5 | 98.83 (8) |
S9—Eu4—Eu3 | 133.94 (5) | Eu2ix—S14—Eu5 | 151.05 (7) |
S15vii—Eu4—Eu3 | 133.00 (5) | Sb6—S14—Eu1viii | 111.81 (9) |
S7—Eu4—Eu3 | 85.23 (5) | Eu2ix—S14—Eu1viii | 86.33 (5) |
S17—Eu4—Eu3 | 48.17 (5) | Eu5—S14—Eu1viii | 87.12 (8) |
S16vii—Eu4—Eu3 | 106.89 (4) | Sb6—S14—Eu6 | 97.96 (8) |
S13v—Eu4—Eu3 | 85.20 (5) | Eu2ix—S14—Eu6 | 86.55 (8) |
S4vi—Eu4—Eu5 | 133.27 (5) | Eu5—S14—Eu6 | 85.20 (5) |
S5—Eu4—Eu5 | 134.61 (5) | Eu1viii—S14—Eu6 | 150.06 (7) |
S8—Eu4—Eu5 | 45.96 (4) | S16—S15—Eu4v | 72.74 (10) |
S9—Eu4—Eu5 | 47.86 (5) | S16—S15—Eu6i | 73.25 (10) |
S15vii—Eu4—Eu5 | 84.17 (4) | Eu4v—S15—Eu6i | 94.45 (8) |
S7—Eu4—Eu5 | 88.87 (6) | S16—S15—Eu5 | 117.15 (11) |
S17—Eu4—Eu5 | 84.06 (4) | Eu4v—S15—Eu5 | 169.03 (7) |
S16vii—Eu4—Eu5 | 49.94 (4) | Eu6i—S15—Eu5 | 84.55 (5) |
S13v—Eu4—Eu5 | 134.48 (5) | S16—S15—Eu3vii | 116.87 (10) |
Eu3—Eu4—Eu5 | 90.499 (17) | Eu4v—S15—Eu3vii | 84.69 (5) |
S4vi—Eu4—Eu1vi | 45.74 (5) | Eu6i—S15—Eu3vii | 168.81 (7) |
S5—Eu4—Eu1vi | 45.68 (5) | Eu5—S15—Eu3vii | 94.17 (8) |
S8—Eu4—Eu1vi | 134.30 (5) | S15—S16—S17 | 113.34 (15) |
S9—Eu4—Eu1vi | 131.06 (5) | S15—S16—Eu4v | 68.03 (9) |
S15vii—Eu4—Eu1vi | 96.18 (4) | S17—S16—Eu4v | 134.07 (12) |
S7—Eu4—Eu1vi | 90.05 (6) | S15—S16—Eu6i | 67.98 (9) |
S17—Eu4—Eu1vi | 97.26 (4) | S17—S16—Eu6i | 133.83 (12) |
S16vii—Eu4—Eu1vi | 130.85 (5) | Eu4v—S16—Eu6i | 90.75 (6) |
S13v—Eu4—Eu1vi | 46.74 (5) | S15—S16—Eu5v | 133.94 (12) |
Eu3—Eu4—Eu1vi | 90.204 (16) | S17—S16—Eu5v | 65.79 (9) |
Eu5—Eu4—Eu1vi | 178.659 (19) | Eu4v—S16—Eu5v | 81.18 (6) |
S8—Eu5—S14 | 145.45 (6) | Eu6i—S16—Eu5v | 148.21 (8) |
S8—Eu5—S17vii | 123.92 (6) | S15—S16—Eu3 | 133.14 (12) |
S14—Eu5—S17vii | 84.09 (7) | S17—S16—Eu3 | 65.88 (9) |
S8—Eu5—S1viii | 82.14 (6) | Eu4v—S16—Eu3 | 148.49 (8) |
S14—Eu5—S1viii | 85.92 (7) | Eu6i—S16—Eu3 | 80.56 (6) |
S17vii—Eu5—S1viii | 141.91 (6) | Eu5v—S16—Eu3 | 90.39 (6) |
S8—Eu5—S10 | 73.21 (7) | S16—S17—Eu5v | 75.13 (10) |
S14—Eu5—S10 | 72.36 (7) | S16—S17—Eu3 | 75.37 (10) |
S17vii—Eu5—S10 | 135.60 (7) | Eu5v—S17—Eu3 | 97.53 (8) |
S1viii—Eu5—S10 | 74.42 (7) | S16—S17—Eu4 | 117.50 (10) |
S8—Eu5—S9 | 85.99 (7) | Eu5v—S17—Eu4 | 166.72 (7) |
S14—Eu5—S9 | 85.09 (7) | Eu3—S17—Eu4 | 82.67 (5) |
S17vii—Eu5—S9 | 71.05 (6) | S16—S17—Eu6v | 117.64 (11) |
S1viii—Eu5—S9 | 144.29 (6) | Eu5v—S17—Eu6v | 83.02 (5) |
S10—Eu5—S9 | 69.91 (7) | Eu3—S17—Eu6v | 166.41 (7) |
S8—Eu5—S15 | 69.70 (6) | Eu4—S17—Eu6v | 93.70 (8) |
Symmetry codes: (i) x−1, y, z; (ii) −x+1/2, −y−1, z+1/2; (iii) x−3/2, −y−3/2, −z; (iv) −x+3/2, −y−1, z+1/2; (v) x−1/2, −y−3/2, −z; (vi) x+1, y, z; (vii) x+1/2, −y−3/2, −z; (viii) −x+1/2, −y−1, z−1/2; (ix) −x+3/2, −y−1, z−1/2; (x) x+3/2, −y−3/2, −z. |