The Al61.49Mn11.35Ni4 phase in the Al–Mn–Ni system

Hu, Q.; Wen, B.; Fan, C.

doi:10.1107/S2414314622000384

inorganic compounds

IUCrDATA

ISSN: 2414-3146

Volume 7| Part 1| January 2022| x220038

https://doi.org/10.1107/S2414314622000384

Open

access

The Al_61.49Mn_11.35Ni₄ phase in the Al–Mn–Ni system

Qifa Hu,^a Bin Wen ^a and Changzeng Fan ^a ^*

^aState Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, People's Republic of China
^*Correspondence e-mail: chzfan@ysu.edu.cn

Edited by M. Weil, Vienna University of Technology, Austria (Received 29 November 2021; accepted 11 January 2022; online 14 January 2022)

An intermetallic phase in the Al–Mn–Ni system crystallizing in space group Cmcm (No. 63) and refined formula Al_61.49Mn_11.35Ni₄ (called the R′ phase) has been synthesized by high-temperature sintering of a mixture with initial chemical composition Al₆₀Mn₇Ni₃. In comparison with the structure model of the previously reported R phase with composition Al₆₀Mn₁₁Ni₄ [Robinson (1954 ). Acta Cryst. 7, 494–497], there are two mutually exchanged Mn and Ni sites together with one positionally disordered Al site [occupancy ratio 0.811 (8):0.121 (7)] and one partially occupied Mn site [s.o.f. 0.677 (5)] in the current structure model of the R′ phase.

Keywords: crystal structure; high-temperature sintering; R-phase; Al–Mn–Ni system..

CCDC reference: 2141311

Structure description

The ternary Al–Mn–Ni alloy system contains a variety of phases with complex or even quasicrystalline structures, most of which are not completely determined. Phase equilibria in the Al-rich region of the Al–Mn–Ni alloy system have been investigated previously. In this regard, a ternary phase with composition close to Al₆₀Mn₁₁Ni₄ was reported as thermodynamically stable, crystallizing in space group Bbmm (non-conventional setting of space group Cmcm) with unit-cell parameters of a = 23.8, b = 12.5, c = 7.55 Å (Raynor, 1944 ). Its chemical composition was determined to be Al_80.0Mn_14.7Ni_5.3 for the same sample. This phase was later denominated the R phase (Robinson, 1954). The derived crystal-structure model for the R phase had some ambiguities because at that time it was not possible to accurately model the deficiencies or the type of element for some of the atomic sites (Robinson, 1954). The R phase with similar composition/crystal structure has also been discovered in other systems, such as the T₃ phase in the Al–Mn–Zn system or the Al₂₀Mn₃Cu₂ phase (Damjanovic, 1961 ). It is interesting to note that the orthorhombic phase in the Al–Mn system is isostructural with the R phase and in coexistence with the decagonal quasicrystal in a rapidly solidified Al–Mn alloy, implying it is inseparable from the formation of quasicrystals (Li & Kuo, 1992 ).

In the present study, a slightly different crystal-structure model for the R phase in the Al–Mn–Ni system has been refined on basis of single-crystal X-ray diffraction data. This phase has similar unit-cell parameters to the previously reported R phase (Table 1, using the conventional setting Cmcm). Its chemical composition was refined to be Al_61.49Mn_11.35Ni₄, in accordance with complementary SEM/EDX results (see Fig. S1 and Table S1 of the supporting information).

Table 1
Experimental details

Crystal data
Chemical formula	Al_61.49Mn_11.35Ni₄
M_r	2517.49
Crystal system, space group	Orthorhombic, Cmcm
Temperature (K)	296
a, b, c (Å)	7.6135 (3), 23.9582 (11), 12.4828 (6)
V (Å³)	2276.93 (18)
Z	2
Radiation type	Mo Kα
μ (mm⁻¹)	5.85
Crystal size (mm)	0.10 × 0.10 × 0.05

Data collection
Diffractometer	Bruker D8 Venture Photon 100 CMOS
Absorption correction	Multi-scan (SADABS; Krause et al., 2015 )
T_min, T_max	0.648, 0.746
No. of measured, independent and observed [I > 2σ(I)] reflections	40442, 1584, 1269
R_int	0.090
(sin θ/λ)_max (Å⁻¹)	0.666

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.039, 0.095, 1.06
No. of reflections	1584
No. of parameters	114
Δρ_max, Δρ_min (e Å⁻³)	1.85, −1.03
Computer programs: APEX3 and SAINT (Bruker, 2015 ), SHELXT (Sheldrick, 2015a ), SHELXL (Sheldrick, 2015b ), DIAMOND (Brandenburg & Putz, 2017 ) and publCIF (Westrip, 2010 ).

In comparison with the R phase, the R′ phase has a slightly higher Al and Mn content. A detailed comparison of the atomic labelling and coordinates between these two structure models along with the transformation matrix that transforms the original non-conventional setting to the current standard setting can be found in Table S2 of the supporting information. The R′ phase has two reversed sites compared to the original R phase whereby Mn4 in the original model becomes Ni1 in the current model, and vice versa. In addition, the R′ phase shows positional disorder of one Al site (Al7), and one Mn site (Mn2) with partial occupancy. Fig. 1 shows the distribution of all atoms in the unit cell of Al_61.49Mn_11.35Ni₄ with four distorted icosahedra illustrated for simplicity. The environments of the Mn3 and Mn4 sites are shown in Fig. 2a and 2b, respectively. The icosahedron centered at Mn3 is surrounded solely by Al atoms (Al3, Al4, Al5, Al6, Al10, Al11, Al12 and Al13) while that centered at Mn4 atom is composed by eleven Al atoms (Al1, Al2, Al4, Al5, Al9, Al11 and Al12) and one Mn atom (Mn4); all of the corresponding atomic sites are fully occupied. The polyhedron centered at Al3 is composed of a pentagonal prism capped by two atoms at the base faces, as shown in Fig. 3a. The environments of Al3 are displayed in Fig. 3b, where ten Al atoms (Al6, Al12 and Al13) and two Mn atoms (Mn3) surround the central atom.

Figure 1
The crystal structure of Al_61.49Mn_11.35Ni₄ with two Mn3 atoms and two Mn4 atoms displayed with their coordination environments as polyhedra.

Figure 2
(a) The environment of the Mn3 atom at the 8f site; (b) the environment of the Mn4 atom at the 8g site with displacement ellipsoids given at the 90% probability level. [Symmetry codes: (iii) −x + 1/2, −y + $[{3\over 2}]$ , −z + 1; (iv) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + 1; (v) −x, y, z; (vi) x, y, z − 1; (viii) −x, y, z − 1; (xiii) x, y, −z + $[{3\over 2}]$ ; (xiv) −x, y, −z + $[{3\over 2}]$ ; (xvii) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z; (xviii) −x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z; (xix) −x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , z + $[{1\over 2}]$ .]

Figure 3
(a) The polyhedron formed around the Al3 atom at the 4c site; (b) the environment of the Al3 atom with displacement ellipsoids given at the 90% probability level. [Symmetry codes: (iii) −x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + 1; (iv) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + 1; (v) −x, y, z; (vii) −x, y, −z + $[{1\over 2}]$ ; (xx) x, y, −z + $[{1\over 2}]$ ; (xxi) −x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , z − $[{1\over 2}]$ ; (xxii) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , z − $[{1\over 2}]$ .]

Synthesis and crystallization

The high-purity elements Al (indicated purity 99.8%; 2.4285 g), Mn (indicated purity 99.96%; 0.5768 g) and Ni (indicated purity 99.9%; 0.2641 g) were mixed in the molar ratio 60:7:3 and ground in an agate mortar. The blended powders were placed into a cemented carbide grinding mound of 9.6 mm diameter and pressed at 4 MPa for about 5 min. The obtained cylindrical block was put into a silica glass tube and vacuum-sealed by a home-made sealing machine. The resulting ampoule then was placed in a furnace (SG-XQL1200) and heated up to 473 K for 10 min with a heating rate of 10 K min⁻¹ and then heated up to 1373 K for 30 min with the same heating rate. Finally, the sample was slowly cooled to room temperature by turning off the furnace power. Suitable pieces of single-crystal grains were broken and selected from the product for single-crystal X-ray diffraction.

Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1. Manganese site Mn2 is partially occupied, and its site occupation factor (s.o.f.) was refined to 0.677 (5). The aluminium site Al17 was found to be disordered over two positions with refined s.o.f.s of 0.811 (8) and 0.121 (7) for Al7A and Al7B, respectively. The same anisotropic displacement parameters were used for these two split Al sites. All Ni sites in the present model show full occupancy. The maximum and minimum residual electron densities in the final difference map are located 1.42 Å from site Al11 and 0.57 Å from site Al7A, respectively.

Structural data

CCDC reference: 2141311

Crystal structure: contains datablock I. DOI: https://doi.org/10.1107/S2414314622000384/wm4158sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2414314622000384/wm4158Isup2.hkl

supplementary materials. DOI: https://doi.org/10.1107/S2414314622000384/wm4158sup3.docx

reply. DOI: https://doi.org/10.1107/S2414314622000384/wm4158sup4.docx

checkCIF report

Computing details top

Data collection: APEX3 (Bruker, 2015); cell refinement: SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg & Putz, 2017); software used to prepare material for publication: publCIF (Westrip, 2010).

(I) top

Crystal data top

Al_61.49Mn_11.35Ni₄	D_x = 3.672 Mg m⁻³
M_r = 2517.49	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmcm	Cell parameters from 8707 reflections
a = 7.6135 (3) Å	θ = 2.4–30.6°
b = 23.9582 (11) Å	µ = 5.85 mm⁻¹
c = 12.4828 (6) Å	T = 296 K
V = 2276.93 (18) Å³	Fragment, metallic
Z = 2	0.10 × 0.10 × 0.05 mm
F(000) = 2390

Data collection top

Bruker D8 Venture Photon 100 CMOS diffractometer	1269 reflections with I > 2σ(I)
φ and ω scans	R_int = 0.090
Absorption correction: multi-scan (SADABS; Krause et al., 2015)	θ_max = 28.3°, θ_min = 2.4°
T_min = 0.648, T_max = 0.746	h = −10→10
40442 measured reflections	k = −31→31
1584 independent reflections	l = −16→16

Refinement top

Refinement on F²	114 parameters
Least-squares matrix: full	0 restraints
R[F² > 2σ(F²)] = 0.039	w = 1/[σ²(F_o²) + (0.0463P)² + 17.4467P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.095	(Δ/σ)_max = 0.001
S = 1.06	Δρ_max = 1.85 e Å⁻³
1584 reflections	Δρ_min = −1.03 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ni1	0.000000	0.91273 (3)	0.06707 (7)	0.0123 (2)
Mn1	0.000000	0.54113 (5)	0.750000	0.0070 (3)
Mn2	0.000000	0.92062 (7)	0.750000	0.0071 (6)	0.677 (5)
Mn3	0.000000	0.63847 (3)	0.05426 (6)	0.00525 (19)
Mn4	0.18574 (11)	0.71395 (3)	0.750000	0.00517 (19)
Al1	0.000000	0.81074 (10)	0.750000	0.0081 (5)
Al2	0.000000	0.79366 (10)	0.250000	0.0083 (5)
Al3	0.000000	0.63386 (10)	0.250000	0.0111 (5)
Al4	0.000000	0.63837 (6)	0.84947 (13)	0.0066 (3)
Al5	0.000000	0.73945 (7)	0.93387 (13)	0.0076 (3)
Al6	0.000000	0.53869 (7)	0.11718 (14)	0.0129 (4)
Al7A	0.000000	0.98517 (9)	0.9064 (2)	0.0170 (8)	0.811 (8)
Al7B	0.000000	0.000000	0.000000	0.0170 (8)	0.121 (7)
Al8	0.2272 (3)	0.01406 (8)	0.250000	0.0250 (5)
Al9	0.1846 (2)	0.89615 (7)	0.250000	0.0094 (4)
Al10	0.18981 (16)	0.55406 (5)	0.93399 (9)	0.0075 (3)
Al11	0.19159 (16)	0.82804 (5)	0.06539 (9)	0.0074 (3)
Al12	0.18747 (16)	0.71601 (5)	0.12610 (9)	0.0080 (3)
Al13	0.18943 (17)	0.89124 (5)	0.88587 (11)	0.0135 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ni1	0.0055 (4)	0.0074 (4)	0.0241 (5)	0.000	0.000	−0.0016 (3)
Mn1	0.0134 (6)	0.0033 (5)	0.0044 (5)	0.000	0.000	0.000
Mn2	0.0057 (10)	0.0112 (10)	0.0043 (9)	0.000	0.000	0.000
Mn3	0.0080 (4)	0.0039 (4)	0.0039 (4)	0.000	0.000	0.0003 (3)
Mn4	0.0049 (4)	0.0059 (4)	0.0046 (4)	0.0000 (3)	0.000	0.000
Al1	0.0099 (12)	0.0074 (11)	0.0071 (11)	0.000	0.000	0.000
Al2	0.0051 (12)	0.0117 (12)	0.0080 (11)	0.000	0.000	0.000
Al3	0.0182 (14)	0.0106 (12)	0.0045 (11)	0.000	0.000	0.000
Al4	0.0074 (8)	0.0060 (8)	0.0065 (8)	0.000	0.000	0.0008 (6)
Al5	0.0077 (8)	0.0072 (8)	0.0079 (8)	0.000	0.000	0.0011 (6)
Al6	0.0241 (11)	0.0051 (8)	0.0094 (8)	0.000	0.000	0.0021 (6)
Al7A	0.0102 (12)	0.0087 (12)	0.0320 (15)	0.000	0.000	−0.0034 (10)
Al7B	0.0102 (12)	0.0087 (12)	0.0320 (15)	0.000	0.000	−0.0034 (10)
Al8	0.0427 (14)	0.0160 (10)	0.0162 (10)	0.0111 (9)	0.000	0.000
Al9	0.0088 (9)	0.0125 (8)	0.0068 (8)	−0.0031 (7)	0.000	0.000
Al10	0.0073 (6)	0.0069 (5)	0.0082 (6)	−0.0003 (4)	−0.0009 (5)	−0.0003 (4)
Al11	0.0073 (6)	0.0074 (5)	0.0074 (6)	0.0009 (4)	0.0006 (5)	0.0013 (4)
Al12	0.0077 (6)	0.0067 (5)	0.0098 (6)	−0.0012 (5)	0.0003 (5)	−0.0028 (4)
Al13	0.0130 (7)	0.0101 (6)	0.0174 (7)	−0.0008 (5)	−0.0003 (5)	0.0021 (5)

Geometric parameters (Å, º) top

Ni1—Al7Bⁱ	2.2523 (7)	Al2—Al9^vii	2.829 (3)
Ni1—Al7Aⁱⁱ	2.468 (2)	Al2—Al9	2.829 (3)
Ni1—Al10ⁱⁱⁱ	2.4921 (12)	Al2—Al11^xx	2.8490 (13)
Ni1—Al10^iv	2.4921 (12)	Al2—Al11^v	2.8490 (13)
Ni1—Al11	2.4989 (13)	Al2—Al11^vii	2.8490 (13)
Ni1—Al11^v	2.4989 (13)	Al2—Al11	2.8490 (13)
Ni1—Al7A^vi	2.652 (3)	Al3—Al6^xx	2.819 (3)
Ni1—Al9	2.7106 (12)	Al3—Al6	2.819 (3)
Ni1—Al9^vii	2.7107 (12)	Al3—Al12^xx	2.881 (2)
Ni1—Al13^viii	2.7315 (15)	Al3—Al12^vii	2.881 (2)
Ni1—Al13^vi	2.7315 (15)	Al3—Al12^v	2.881 (2)
Mn1—Al8^ix	2.462 (2)	Al3—Al12	2.881 (2)
Mn1—Al8^x	2.462 (2)	Al3—Al13^iv	2.9714 (14)
Mn1—Al6^xi	2.5310 (19)	Al3—Al13^xxi	2.9714 (14)
Mn1—Al6^xii	2.5310 (19)	Al3—Al13^xxii	2.9714 (14)
Mn1—Al4	2.6399 (19)	Al3—Al13ⁱⁱⁱ	2.9714 (14)
Mn1—Al4^xiii	2.6400 (19)	Al4—Al4^xiii	2.483 (3)
Mn1—Al10^xiv	2.7312 (12)	Al4—Al5	2.641 (2)
Mn1—Al10^v	2.7312 (12)	Al4—Al10	2.6985 (18)
Mn1—Al10^xiii	2.7312 (12)	Al4—Al10^v	2.6985 (18)
Mn1—Al10	2.7312 (12)	Al4—Al11ⁱⁱⁱ	2.7001 (15)
Mn1—Al9ⁱⁱⁱ	2.8328 (18)	Al4—Al11^iv	2.7001 (14)
Mn1—Al9^xv	2.8328 (18)	Al4—Al9^xv	2.8270 (18)
Mn2—Al8^xvi	2.333 (2)	Al4—Al9ⁱⁱⁱ	2.8270 (18)
Mn2—Al8^xii	2.333 (2)	Al5—Al12ⁱⁱⁱ	2.7131 (15)
Mn2—Al13^xiv	2.3349 (14)	Al5—Al12^iv	2.7131 (15)
Mn2—Al13^xiii	2.3349 (14)	Al5—Al12^xxiii	2.8480 (18)
Mn2—Al13^v	2.3349 (14)	Al5—Al12^xxiv	2.8480 (18)
Mn2—Al13	2.3349 (14)	Al5—Al11^iv	2.8510 (15)
Mn2—Al7A^xiii	2.491 (3)	Al5—Al11ⁱⁱⁱ	2.8510 (15)
Mn2—Al7A	2.491 (3)	Al6—Al8^xxv	2.722 (2)
Mn2—Al1	2.633 (3)	Al6—Al8^xxvi	2.722 (2)
Mn3—Al3	2.4459 (8)	Al6—Al10^xii	2.7266 (19)
Mn3—Al12^v	2.5085 (13)	Al6—Al10^xxvii	2.7266 (19)
Mn3—Al12	2.5086 (13)	Al6—Al10^viii	2.7300 (19)
Mn3—Al6	2.5162 (19)	Al6—Al10^vi	2.7300 (19)
Mn3—Al4^vi	2.5563 (18)	Al6—Al13ⁱⁱⁱ	2.9000 (16)
Mn3—Al13^iv	2.5800 (14)	Al6—Al13^iv	2.9000 (16)
Mn3—Al13ⁱⁱⁱ	2.5800 (14)	Al7A—Al7A^xxviii	2.442 (5)
Mn3—Al5^vi	2.8481 (18)	Al7A—Al8^xii	2.608 (3)
Mn3—Al11^xvii	2.8962 (13)	Al7A—Al8^xvi	2.608 (3)
Mn3—Al11^xviii	2.8962 (13)	Al7A—Al13^v	2.685 (2)
Mn3—Al10^viii	2.9039 (13)	Al7A—Al13	2.685 (2)
Mn3—Al10^vi	2.9039 (13)	Al7A—Al10^xxix	2.9016 (17)
Mn4—Al2ⁱⁱⁱ	2.3996 (9)	Al7A—Al10^xxvi	2.9016 (17)
Mn4—Al12ⁱⁱⁱ	2.4779 (13)	Al7B—Al10^xxx	2.8166 (12)
Mn4—Al12^xix	2.4779 (13)	Al7B—Al10^xxxi	2.8166 (12)
Mn4—Al4	2.6116 (15)	Al7B—Al10^xxxii	2.8166 (12)
Mn4—Al4^xiii	2.6116 (15)	Al7B—Al10^x	2.8166 (12)
Mn4—Al11^xix	2.6823 (12)	Al8—Al9^xxxiii	2.843 (3)
Mn4—Al11ⁱⁱⁱ	2.6823 (12)	Al8—Al13^xxxiv	2.847 (2)
Mn4—Al1	2.716 (2)	Al8—Al13^xxvii	2.847 (2)
Mn4—Al5	2.7642 (15)	Al8—Al10^x	2.8874 (16)
Mn4—Al5^xiii	2.7642 (15)	Al8—Al10^xxxv	2.8874 (16)
Mn4—Al9ⁱⁱⁱ	2.8163 (19)	Al9—Al10^xxi	2.7591 (15)
Mn4—Mn4^xiv	2.8282 (17)	Al9—Al10ⁱⁱⁱ	2.7591 (15)
Al1—Al5	2.861 (2)	Al9—Al9^vii	2.811 (4)
Al1—Al5^xiii	2.861 (2)	Al9—Al11	2.8242 (15)
Al1—Al12^xv	2.9093 (14)	Al9—Al11^xx	2.8242 (15)
Al1—Al12ⁱⁱⁱ	2.9093 (14)	Al10—Al13^xxxvi	2.7603 (17)
Al1—Al12^iv	2.9093 (14)	Al10—Al10^v	2.890 (2)
Al1—Al12^xix	2.9093 (14)	Al11—Al13^vi	2.7046 (17)
Al1—Al13	2.946 (2)	Al11—Al12^xviii	2.7705 (16)
Al1—Al13^v	2.946 (2)	Al11—Al12	2.7891 (16)
Al1—Al13^xiii	2.946 (2)	Al11—Al11^v	2.917 (2)
Al2—Al12	2.809 (2)	Al12—Al13ⁱⁱⁱ	2.7393 (17)
Al2—Al12^v	2.809 (2)	Al12—Al12^v	2.855 (3)
Al2—Al12^vii	2.809 (2)	Al13—Al13^v	2.884 (3)
Al2—Al12^xx	2.809 (2)

Al7Aⁱⁱ—Ni1—Al10ⁱⁱⁱ	71.59 (3)	Al11^iv—Al4—Al9ⁱⁱⁱ	177.12 (7)
Al7Aⁱⁱ—Ni1—Al10^iv	71.59 (3)	Al9^xv—Al4—Al9ⁱⁱⁱ	116.30 (7)
Al10ⁱⁱⁱ—Ni1—Al10^iv	142.75 (6)	Al4—Al5—Al12ⁱⁱⁱ	104.51 (5)
Al7Bⁱ—Ni1—Al11	138.65 (3)	Al4—Al5—Al12^iv	104.51 (5)
Al7Aⁱⁱ—Ni1—Al11	143.68 (3)	Al12ⁱⁱⁱ—Al5—Al12^iv	122.57 (8)
Al10ⁱⁱⁱ—Ni1—Al11	72.91 (4)	Al4—Al5—Mn4	57.73 (5)
Al10^iv—Ni1—Al11	144.33 (5)	Al12ⁱⁱⁱ—Al5—Mn4	53.78 (4)
Al7Aⁱⁱ—Ni1—Al11^v	143.68 (3)	Al12^iv—Al5—Mn4	107.85 (6)
Al10ⁱⁱⁱ—Ni1—Al11^v	144.33 (5)	Al4—Al5—Mn4^xiv	57.73 (5)
Al10^iv—Ni1—Al11^v	72.91 (4)	Al12ⁱⁱⁱ—Al5—Mn4^xiv	107.85 (6)
Al11—Ni1—Al11^v	71.42 (6)	Al12^iv—Al5—Mn4^xiv	53.78 (4)
Al7Aⁱⁱ—Ni1—Al7A^vi	56.83 (10)	Mn4—Al5—Mn4^xiv	61.54 (5)
Al10ⁱⁱⁱ—Ni1—Al7A^vi	77.70 (3)	Al4—Al5—Al12^xxiii	98.93 (6)
Al10^iv—Ni1—Al7A^vi	77.70 (3)	Al12ⁱⁱⁱ—Al5—Al12^xxiii	82.56 (4)
Al11—Ni1—Al7A^vi	121.67 (5)	Al12^iv—Al5—Al12^xxiii	138.55 (6)
Al11^v—Ni1—Al7A^vi	121.67 (5)	Mn4—Al5—Al12^xxiii	113.56 (4)
Al7Bⁱ—Ni1—Al9	116.69 (4)	Mn4^xiv—Al5—Al12^xxiii	155.84 (7)
Al7Aⁱⁱ—Ni1—Al9	91.85 (7)	Al4—Al5—Al12^xxiv	98.93 (6)
Al10ⁱⁱⁱ—Ni1—Al9	63.89 (4)	Al12ⁱⁱⁱ—Al5—Al12^xxiv	138.55 (6)
Al10^iv—Ni1—Al9	122.86 (5)	Al12^iv—Al5—Al12^xxiv	82.56 (4)
Al11—Ni1—Al9	65.51 (4)	Mn4—Al5—Al12^xxiv	155.84 (7)
Al11^v—Ni1—Al9	101.00 (5)	Mn4^xiv—Al5—Al12^xxiv	113.56 (4)
Al7A^vi—Ni1—Al9	137.13 (5)	Al12^xxiii—Al5—Al12^xxiv	60.15 (6)
Al7Aⁱⁱ—Ni1—Al9^vii	91.85 (7)	Al4—Al5—Mn3^xxiii	55.36 (5)
Al10ⁱⁱⁱ—Ni1—Al9^vii	122.86 (5)	Al12ⁱⁱⁱ—Al5—Mn3^xxiii	118.66 (4)
Al10^iv—Ni1—Al9^vii	63.89 (4)	Al12^iv—Al5—Mn3^xxiii	118.66 (4)
Al11—Ni1—Al9^vii	100.99 (5)	Mn4—Al5—Mn3^xxiii	104.50 (5)
Al11^v—Ni1—Al9^vii	65.51 (4)	Mn4^xiv—Al5—Mn3^xxiii	104.50 (5)
Al7A^vi—Ni1—Al9^vii	137.13 (5)	Al12^xxiii—Al5—Mn3^xxiii	52.26 (4)
Al9—Ni1—Al9^vii	62.46 (7)	Al12^xxiv—Al5—Mn3^xxiii	52.26 (4)
Al7Aⁱⁱ—Ni1—Al13^viii	107.32 (6)	Al4—Al5—Al11^iv	58.75 (4)
Al10ⁱⁱⁱ—Ni1—Al13^viii	123.79 (5)	Al12ⁱⁱⁱ—Al5—Al11^iv	161.14 (7)
Al10^iv—Ni1—Al13^viii	63.61 (4)	Al12^iv—Al5—Al11^iv	60.11 (4)
Al11—Ni1—Al13^viii	98.53 (4)	Mn4—Al5—Al11^iv	107.38 (6)
Al11^v—Ni1—Al13^viii	62.09 (4)	Mn4^xiv—Al5—Al11^iv	57.04 (3)
Al7A^vi—Ni1—Al13^viii	59.81 (5)	Al12^xxiii—Al5—Al11^iv	107.35 (6)
Al9—Ni1—Al13^viii	160.69 (5)	Al12^xxiv—Al5—Al11^iv	58.17 (4)
Al9^vii—Ni1—Al13^viii	113.34 (4)	Mn3^xxiii—Al5—Al11^iv	61.09 (4)
Al7Aⁱⁱ—Ni1—Al13^vi	107.32 (6)	Al4—Al5—Al11ⁱⁱⁱ	58.75 (4)
Al10ⁱⁱⁱ—Ni1—Al13^vi	63.61 (4)	Al12ⁱⁱⁱ—Al5—Al11ⁱⁱⁱ	60.11 (4)
Al10^iv—Ni1—Al13^vi	123.79 (5)	Al12^iv—Al5—Al11ⁱⁱⁱ	161.14 (7)
Al11—Ni1—Al13^vi	62.09 (4)	Mn4—Al5—Al11ⁱⁱⁱ	57.04 (3)
Al11^v—Ni1—Al13^vi	98.53 (4)	Mn4^xiv—Al5—Al11ⁱⁱⁱ	107.38 (6)
Al7A^vi—Ni1—Al13^vi	59.81 (5)	Al12^xxiii—Al5—Al11ⁱⁱⁱ	58.17 (4)
Al9—Ni1—Al13^vi	113.34 (4)	Al12^xxiv—Al5—Al11ⁱⁱⁱ	107.35 (6)
Al9^vii—Ni1—Al13^vi	160.69 (5)	Mn3^xxiii—Al5—Al11ⁱⁱⁱ	61.09 (4)
Al13^viii—Ni1—Al13^vi	63.74 (6)	Al11^iv—Al5—Al11ⁱⁱⁱ	110.89 (7)
Al8^ix—Mn1—Al8^x	115.05 (12)	Al4—Al5—Al1	103.14 (8)
Al8^ix—Mn1—Al6^xi	66.07 (5)	Al12ⁱⁱⁱ—Al5—Al1	62.86 (4)
Al8^x—Mn1—Al6^xi	66.07 (5)	Al12^iv—Al5—Al1	62.86 (4)
Al8^ix—Mn1—Al6^xii	66.07 (5)	Mn4—Al5—Al1	57.71 (5)
Al8^x—Mn1—Al6^xii	66.07 (5)	Mn4^xiv—Al5—Al1	57.71 (5)
Al6^xi—Mn1—Al6^xii	81.85 (9)	Al12^xxiii—Al5—Al1	142.53 (5)
Al8^ix—Mn1—Al4	118.28 (5)	Al12^xxiv—Al5—Al1	142.53 (5)
Al8^x—Mn1—Al4	118.28 (5)	Mn3^xxiii—Al5—Al1	158.50 (8)
Al6^xi—Mn1—Al4	167.13 (6)	Al11^iv—Al5—Al1	109.95 (5)
Al6^xii—Mn1—Al4	111.02 (5)	Al11ⁱⁱⁱ—Al5—Al1	109.95 (5)
Al8^ix—Mn1—Al4^xiii	118.28 (5)	Mn3—Al6—Mn1^xii	157.26 (8)
Al8^x—Mn1—Al4^xiii	118.28 (5)	Mn3—Al6—Al8^xxv	113.33 (6)
Al6^xi—Mn1—Al4^xiii	111.02 (5)	Mn1^xii—Al6—Al8^xxv	55.75 (5)
Al6^xii—Mn1—Al4^xiii	167.13 (6)	Mn3—Al6—Al8^xxvi	113.33 (6)
Al4—Mn1—Al4^xiii	56.11 (7)	Mn1^xii—Al6—Al8^xxvi	55.75 (5)
Al8^ix—Mn1—Al10^xiv	67.33 (3)	Al8^xxv—Al6—Al8^xxvi	99.45 (9)
Al8^x—Mn1—Al10^xiv	120.48 (3)	Mn3—Al6—Al10^xii	134.52 (6)
Al6^xi—Mn1—Al10^xiv	62.28 (4)	Mn1^xii—Al6—Al10^xii	62.46 (4)
Al6^xii—Mn1—Al10^xiv	129.53 (5)	Al8^xxv—Al6—Al10^xii	111.74 (7)
Al4—Mn1—Al10^xiv	107.18 (5)	Al8^xxvi—Al6—Al10^xii	64.00 (5)
Al4^xiii—Mn1—Al10^xiv	60.29 (4)	Mn3—Al6—Al10^xxvii	134.52 (6)
Al8^ix—Mn1—Al10^v	67.33 (3)	Mn1^xii—Al6—Al10^xxvii	62.46 (4)
Al8^x—Mn1—Al10^v	120.48 (3)	Al8^xxv—Al6—Al10^xxvii	64.00 (5)
Al6^xi—Mn1—Al10^v	129.53 (5)	Al8^xxvi—Al6—Al10^xxvii	111.74 (7)
Al6^xii—Mn1—Al10^v	62.28 (4)	Al10^xii—Al6—Al10^xxvii	64.01 (6)
Al4—Mn1—Al10^v	60.29 (4)	Mn3—Al6—Al10^viii	67.07 (5)
Al4^xiii—Mn1—Al10^v	107.18 (5)	Mn1^xii—Al6—Al10^viii	130.58 (6)
Al10^xiv—Mn1—Al10^v	114.48 (5)	Al8^xxv—Al6—Al10^viii	160.60 (7)
Al8^ix—Mn1—Al10^xiii	120.48 (3)	Al8^xxvi—Al6—Al10^viii	97.78 (4)
Al8^x—Mn1—Al10^xiii	67.33 (3)	Al10^xii—Al6—Al10^viii	68.47 (6)
Al6^xi—Mn1—Al10^xiii	62.28 (4)	Al10^xxvii—Al6—Al10^viii	101.20 (7)
Al6^xii—Mn1—Al10^xiii	129.53 (5)	Mn3—Al6—Al10^vi	67.07 (5)
Al4—Mn1—Al10^xiii	107.18 (5)	Mn1^xii—Al6—Al10^vi	130.58 (6)
Al4^xiii—Mn1—Al10^xiii	60.29 (4)	Al8^xxv—Al6—Al10^vi	97.78 (4)
Al10^xiv—Mn1—Al10^xiii	63.89 (5)	Al8^xxvi—Al6—Al10^vi	160.60 (7)
Al10^v—Mn1—Al10^xiii	166.98 (7)	Al10^xii—Al6—Al10^vi	101.20 (7)
Al8^ix—Mn1—Al10	120.48 (3)	Al10^xxvii—Al6—Al10^vi	68.47 (6)
Al8^x—Mn1—Al10	67.33 (3)	Al10^viii—Al6—Al10^vi	63.92 (6)
Al6^xi—Mn1—Al10	129.54 (5)	Mn3—Al6—Al3	54.21 (5)
Al6^xii—Mn1—Al10	62.28 (4)	Mn1^xii—Al6—Al3	103.05 (7)
Al4—Mn1—Al10	60.29 (4)	Al8^xxv—Al6—Al3	79.47 (6)
Al4^xiii—Mn1—Al10	107.18 (5)	Al8^xxvi—Al6—Al3	79.47 (6)
Al10^xiv—Mn1—Al10	166.98 (7)	Al10^xii—Al6—Al3	142.84 (5)
Al10^v—Mn1—Al10	63.89 (5)	Al10^xxvii—Al6—Al3	142.84 (5)
Al10^xiii—Mn1—Al10	114.48 (5)	Al10^viii—Al6—Al3	112.56 (6)
Al8^ix—Mn1—Al9ⁱⁱⁱ	179.56 (8)	Al10^vi—Al6—Al3	112.56 (6)
Al8^x—Mn1—Al9ⁱⁱⁱ	64.51 (6)	Mn3—Al6—Al13ⁱⁱⁱ	56.36 (4)
Al6^xi—Mn1—Al9ⁱⁱⁱ	113.63 (3)	Mn1^xii—Al6—Al13ⁱⁱⁱ	116.48 (5)
Al6^xii—Mn1—Al9ⁱⁱⁱ	113.63 (3)	Al8^xxv—Al6—Al13ⁱⁱⁱ	60.75 (5)
Al4—Mn1—Al9ⁱⁱⁱ	62.08 (4)	Al8^xxvi—Al6—Al13ⁱⁱⁱ	139.08 (8)
Al4^xiii—Mn1—Al9ⁱⁱⁱ	62.09 (4)	Al10^xii—Al6—Al13ⁱⁱⁱ	154.26 (6)
Al10^xiv—Mn1—Al9ⁱⁱⁱ	112.85 (4)	Al10^xxvii—Al6—Al13ⁱⁱⁱ	92.09 (4)
Al10^v—Mn1—Al9ⁱⁱⁱ	112.85 (4)	Al10^viii—Al6—Al13ⁱⁱⁱ	110.04 (7)
Al10^xiii—Mn1—Al9ⁱⁱⁱ	59.42 (3)	Al10^vi—Al6—Al13ⁱⁱⁱ	58.63 (4)
Al10—Mn1—Al9ⁱⁱⁱ	59.42 (3)	Al3—Al6—Al13ⁱⁱⁱ	62.59 (4)
Al8^ix—Mn1—Al9^xv	64.51 (6)	Mn3—Al6—Al13^iv	56.36 (4)
Al8^x—Mn1—Al9^xv	179.56 (8)	Mn1^xii—Al6—Al13^iv	116.48 (5)
Al6^xi—Mn1—Al9^xv	113.63 (3)	Al8^xxv—Al6—Al13^iv	139.08 (8)
Al6^xii—Mn1—Al9^xv	113.63 (3)	Al8^xxvi—Al6—Al13^iv	60.75 (5)
Al4—Mn1—Al9^xv	62.09 (4)	Al10^xii—Al6—Al13^iv	92.09 (4)
Al4^xiii—Mn1—Al9^xv	62.09 (4)	Al10^xxvii—Al6—Al13^iv	154.26 (6)
Al10^xiv—Mn1—Al9^xv	59.42 (3)	Al10^viii—Al6—Al13^iv	58.63 (4)
Al10^v—Mn1—Al9^xv	59.42 (3)	Al10^vi—Al6—Al13^iv	110.04 (7)
Al10^xiii—Mn1—Al9^xv	112.85 (4)	Al3—Al6—Al13^iv	62.59 (4)
Al10—Mn1—Al9^xv	112.85 (4)	Al13ⁱⁱⁱ—Al6—Al13^iv	109.24 (7)
Al9ⁱⁱⁱ—Mn1—Al9^xv	115.92 (8)	Al7A^xxviii—Al7A—Ni1ⁱⁱ	65.38 (9)
Al8^xvi—Mn2—Al8^xii	95.71 (13)	Al7A^xxviii—Al7A—Mn2	158.53 (16)
Al8^xvi—Mn2—Al13^xiv	131.32 (5)	Ni1ⁱⁱ—Al7A—Mn2	136.09 (12)
Al8^xii—Mn2—Al13^xiv	75.18 (5)	Al7A^xxviii—Al7A—Al8^xii	135.57 (7)
Al8^xvi—Mn2—Al13^xiii	75.18 (5)	Ni1ⁱⁱ—Al7A—Al8^xii	95.36 (8)
Al8^xii—Mn2—Al13^xiii	131.32 (5)	Mn2—Al7A—Al8^xii	54.39 (7)
Al13^xiv—Mn2—Al13^xiii	76.30 (7)	Al7A^xxviii—Al7A—Al8^xvi	135.57 (7)
Al8^xvi—Mn2—Al13^v	131.32 (5)	Ni1ⁱⁱ—Al7A—Al8^xvi	95.36 (8)
Al8^xii—Mn2—Al13^v	75.18 (5)	Mn2—Al7A—Al8^xvi	54.39 (7)
Al13^xiv—Mn2—Al13^v	93.17 (7)	Al8^xii—Al7A—Al8^xvi	83.07 (11)
Al13^xiii—Mn2—Al13^v	144.92 (10)	Al7A^xxviii—Al7A—Ni1^xxiii	57.79 (10)
Al8^xvi—Mn2—Al13	75.18 (5)	Ni1ⁱⁱ—Al7A—Ni1^xxiii	123.17 (10)
Al8^xii—Mn2—Al13	131.32 (5)	Mn2—Al7A—Ni1^xxiii	100.74 (8)
Al13^xiv—Mn2—Al13	144.91 (10)	Al8^xii—Al7A—Ni1^xxiii	124.80 (8)
Al13^xiii—Mn2—Al13	93.16 (7)	Al8^xvi—Al7A—Ni1^xxiii	124.80 (8)
Al13^v—Mn2—Al13	76.30 (7)	Al7A^xxviii—Al7A—Al13^v	109.59 (12)
Al8^xvi—Mn2—Al7A^xiii	65.38 (5)	Ni1ⁱⁱ—Al7A—Al13^v	147.49 (4)
Al8^xii—Mn2—Al7A^xiii	65.38 (5)	Mn2—Al7A—Al13^v	53.47 (6)
Al13^xiv—Mn2—Al7A^xiii	67.53 (5)	Al8^xii—Al7A—Al13^v	65.06 (7)
Al13^xiii—Mn2—Al7A^xiii	67.53 (5)	Al8^xvi—Al7A—Al13^v	106.89 (10)
Al13^v—Mn2—Al7A^xiii	139.16 (5)	Ni1^xxiii—Al7A—Al13^v	61.56 (6)
Al13—Mn2—Al7A^xiii	139.16 (5)	Al7A^xxviii—Al7A—Al13	109.59 (12)
Al8^xvi—Mn2—Al7A	65.38 (6)	Ni1ⁱⁱ—Al7A—Al13	147.49 (4)
Al8^xii—Mn2—Al7A	65.38 (5)	Mn2—Al7A—Al13	53.47 (6)
Al13^xiv—Mn2—Al7A	139.16 (5)	Al8^xii—Al7A—Al13	106.89 (10)
Al13^xiii—Mn2—Al7A	139.16 (5)	Al8^xvi—Al7A—Al13	65.06 (7)
Al13^v—Mn2—Al7A	67.53 (5)	Ni1^xxiii—Al7A—Al13	61.56 (6)
Al13—Mn2—Al7A	67.53 (5)	Al13^v—Al7A—Al13	64.98 (7)
Al7A^xiii—Mn2—Al7A	103.23 (13)	Al7A^xxviii—Al7A—Al10^xxix	73.80 (7)
Al8^xvi—Mn2—Al1	132.14 (7)	Ni1ⁱⁱ—Al7A—Al10^xxix	54.58 (4)
Al8^xii—Mn2—Al1	132.14 (7)	Mn2—Al7A—Al10^xxix	116.50 (6)
Al13^xiv—Mn2—Al1	72.46 (5)	Al8^xii—Al7A—Al10^xxix	128.64 (11)
Al13^xiii—Mn2—Al1	72.46 (5)	Al8^xvi—Al7A—Al10^xxix	62.94 (5)
Al13^v—Mn2—Al1	72.46 (5)	Ni1^xxiii—Al7A—Al10^xxix	106.41 (7)
Al13—Mn2—Al1	72.46 (5)	Al13^v—Al7A—Al10^xxix	157.69 (7)
Al7A^xiii—Mn2—Al1	128.38 (6)	Al13—Al7A—Al10^xxix	92.91 (4)
Al7A—Mn2—Al1	128.38 (6)	Al7A^xxviii—Al7A—Al10^xxvi	73.80 (7)
Al3—Mn3—Al12^v	71.11 (6)	Ni1ⁱⁱ—Al7A—Al10^xxvi	54.58 (4)
Al3—Mn3—Al12	71.11 (6)	Mn2—Al7A—Al10^xxvi	116.50 (6)
Al12^v—Mn3—Al12	69.36 (6)	Al8^xii—Al7A—Al10^xxvi	62.94 (5)
Al3—Mn3—Al6	69.22 (7)	Al8^xvi—Al7A—Al10^xxvi	128.64 (11)
Al12^v—Mn3—Al6	126.30 (5)	Ni1^xxiii—Al7A—Al10^xxvi	106.41 (7)
Al12—Mn3—Al6	126.30 (5)	Al13^v—Al7A—Al10^xxvi	92.91 (4)
Al3—Mn3—Al4^vi	177.36 (8)	Al13—Al7A—Al10^xxvi	157.69 (7)
Al12^v—Mn3—Al4^vi	110.99 (5)	Al10^xxix—Al7A—Al10^xxvi	108.96 (8)
Al12—Mn3—Al4^vi	110.99 (5)	Ni1^xxxvii—Al7B—Ni1^xxxiii	180.00 (4)
Al6—Mn3—Al4^vi	108.13 (6)	Ni1^xxxvii—Al7B—Al10^xxx	57.62 (2)
Al3—Mn3—Al13^iv	72.43 (4)	Ni1^xxxiii—Al7B—Al10^xxx	122.38 (2)
Al12^v—Mn3—Al13^iv	65.12 (4)	Ni1^xxxvii—Al7B—Al10^xxxi	122.38 (2)
Al12—Mn3—Al13^iv	128.48 (5)	Ni1^xxxiii—Al7B—Al10^xxxi	57.62 (2)
Al6—Mn3—Al13^iv	69.36 (3)	Al10^xxx—Al7B—Al10^xxxi	180.00 (6)
Al4^vi—Mn3—Al13^iv	106.82 (4)	Ni1^xxxvii—Al7B—Al10^xxxii	57.62 (2)
Al3—Mn3—Al13ⁱⁱⁱ	72.43 (4)	Ni1^xxxiii—Al7B—Al10^xxxii	122.38 (2)
Al12^v—Mn3—Al13ⁱⁱⁱ	128.48 (5)	Al10^xxx—Al7B—Al10^xxxii	113.96 (5)
Al12—Mn3—Al13ⁱⁱⁱ	65.12 (4)	Al10^xxxi—Al7B—Al10^xxxii	66.04 (5)
Al6—Mn3—Al13ⁱⁱⁱ	69.36 (3)	Ni1^xxxvii—Al7B—Al10^x	122.38 (2)
Al4^vi—Mn3—Al13ⁱⁱⁱ	106.82 (4)	Ni1^xxxiii—Al7B—Al10^x	57.62 (2)
Al13^iv—Mn3—Al13ⁱⁱⁱ	132.84 (7)	Al10^xxx—Al7B—Al10^x	66.04 (5)
Al3—Mn3—Al5^vi	124.43 (8)	Al10^xxxi—Al7B—Al10^x	113.96 (5)
Al12^v—Mn3—Al5^vi	63.87 (4)	Al10^xxxii—Al7B—Al10^x	180.00 (6)
Al12—Mn3—Al5^vi	63.87 (4)	Mn2^xii—Al8—Mn1^x	170.33 (12)
Al6—Mn3—Al5^vi	166.34 (6)	Mn2^xii—Al8—Al7A^xii	60.24 (7)
Al4^vi—Mn3—Al5^vi	58.21 (5)	Mn1^x—Al8—Al7A^xii	124.28 (6)
Al13^iv—Mn3—Al5^vi	112.78 (3)	Mn2^xii—Al8—Al7A^xxxviii	60.24 (7)
Al13ⁱⁱⁱ—Mn3—Al5^vi	112.78 (3)	Mn1^x—Al8—Al7A^xxxviii	124.28 (6)
Al3—Mn3—Al11^xvii	121.85 (3)	Al7A^xii—Al8—Al7A^xxxviii	96.93 (11)
Al12^v—Mn3—Al11^xvii	61.18 (4)	Mn2^xii—Al8—Al6^xxxix	114.85 (7)
Al12—Mn3—Al11^xvii	116.13 (5)	Mn1^x—Al8—Al6^xxxix	58.18 (6)
Al6—Mn3—Al11^xvii	115.10 (3)	Al7A^xii—Al8—Al6^xxxix	163.78 (10)
Al4^vi—Mn3—Al11^xvii	58.97 (3)	Al7A^xxxviii—Al8—Al6^xxxix	92.78 (5)
Al13^iv—Mn3—Al11^xvii	58.86 (4)	Mn2^xii—Al8—Al6^xl	114.85 (7)
Al13ⁱⁱⁱ—Mn3—Al11^xvii	165.67 (5)	Mn1^x—Al8—Al6^xl	58.18 (6)
Al5^vi—Mn3—Al11^xvii	59.51 (3)	Al7A^xii—Al8—Al6^xl	92.78 (5)
Al3—Mn3—Al11^xviii	121.85 (3)	Al7A^xxxviii—Al8—Al6^xl	163.78 (10)
Al12^v—Mn3—Al11^xviii	116.14 (5)	Al6^xxxix—Al8—Al6^xl	75.03 (9)
Al12—Mn3—Al11^xviii	61.18 (4)	Mn2^xii—Al8—Al9^xxxiii	125.60 (11)
Al6—Mn3—Al11^xviii	115.10 (3)	Mn1^x—Al8—Al9^xxxiii	64.07 (6)
Al4^vi—Mn3—Al11^xviii	58.97 (3)	Al7A^xii—Al8—Al9^xxxiii	86.07 (8)
Al13^iv—Mn3—Al11^xviii	165.67 (5)	Al7A^xxxviii—Al8—Al9^xxxiii	86.07 (8)
Al13ⁱⁱⁱ—Mn3—Al11^xviii	58.86 (4)	Al6^xxxix—Al8—Al9^xxxiii	107.60 (7)
Al5^vi—Mn3—Al11^xviii	59.51 (3)	Al6^xl—Al8—Al9^xxxiii	107.60 (7)
Al11^xvii—Mn3—Al11^xviii	108.34 (5)	Mn2^xii—Al8—Al13^xxxiv	52.45 (5)
Al3—Mn3—Al10^viii	119.02 (6)	Mn1^x—Al8—Al13^xxxiv	120.86 (8)
Al12^v—Mn3—Al10^viii	114.67 (4)	Al7A^xii—Al8—Al13^xxxiv	111.92 (9)
Al12—Mn3—Al10^viii	169.66 (5)	Al7A^xxxviii—Al8—Al13^xxxiv	58.77 (6)
Al6—Mn3—Al10^viii	59.98 (4)	Al6^xxxix—Al8—Al13^xxxiv	62.71 (5)
Al4^vi—Mn3—Al10^viii	58.82 (4)	Al6^xl—Al8—Al13^xxxiv	105.48 (9)
Al13^iv—Mn3—Al10^viii	60.10 (4)	Al9^xxxiii—Al8—Al13^xxxiv	141.28 (5)
Al13ⁱⁱⁱ—Mn3—Al10^viii	114.44 (5)	Mn2^xii—Al8—Al13^xxvii	52.45 (5)
Al5^vi—Mn3—Al10^viii	108.59 (4)	Mn1^x—Al8—Al13^xxvii	120.86 (8)
Al11^xvii—Mn3—Al10^viii	61.50 (3)	Al7A^xii—Al8—Al13^xxvii	58.77 (6)
Al11^xviii—Mn3—Al10^viii	109.26 (4)	Al7A^xxxviii—Al8—Al13^xxvii	111.92 (9)
Al3—Mn3—Al10^vi	119.02 (6)	Al6^xxxix—Al8—Al13^xxvii	105.48 (9)
Al12^v—Mn3—Al10^vi	169.66 (5)	Al6^xl—Al8—Al13^xxvii	62.71 (5)
Al12—Mn3—Al10^vi	114.67 (4)	Al9^xxxiii—Al8—Al13^xxvii	141.28 (5)
Al6—Mn3—Al10^vi	59.98 (4)	Al13^xxxiv—Al8—Al13^xxvii	73.12 (7)
Al4^vi—Mn3—Al10^vi	58.82 (4)	Mn2^xii—Al8—Al10^x	122.79 (6)
Al13^iv—Mn3—Al10^vi	114.44 (5)	Mn1^x—Al8—Al10^x	60.78 (5)
Al13ⁱⁱⁱ—Mn3—Al10^vi	60.10 (4)	Al7A^xii—Al8—Al10^x	63.50 (5)
Al5^vi—Mn3—Al10^vi	108.59 (4)	Al7A^xxxviii—Al8—Al10^x	138.12 (11)
Al11^xvii—Mn3—Al10^vi	109.26 (4)	Al6^xxxix—Al8—Al10^x	116.10 (9)
Al11^xviii—Mn3—Al10^vi	61.50 (3)	Al6^xl—Al8—Al10^x	58.07 (5)
Al10^viii—Mn3—Al10^vi	59.69 (5)	Al9^xxxiii—Al8—Al10^x	57.55 (4)
Al2ⁱⁱⁱ—Mn4—Al12ⁱⁱⁱ	70.30 (6)	Al13^xxxiv—Al8—Al10^x	161.13 (8)
Al2ⁱⁱⁱ—Mn4—Al12^xix	70.30 (6)	Al13^xxvii—Al8—Al10^x	89.92 (4)
Al12ⁱⁱⁱ—Mn4—Al12^xix	77.24 (6)	Mn2^xii—Al8—Al10^xxxv	122.79 (6)
Al2ⁱⁱⁱ—Mn4—Al4	119.16 (6)	Mn1^x—Al8—Al10^xxxv	60.78 (5)
Al12ⁱⁱⁱ—Mn4—Al4	112.57 (5)	Al7A^xii—Al8—Al10^xxxv	138.12 (11)
Al12^xix—Mn4—Al4	167.76 (5)	Al7A^xxxviii—Al8—Al10^xxxv	63.50 (5)
Al2ⁱⁱⁱ—Mn4—Al4^xiii	119.16 (6)	Al6^xxxix—Al8—Al10^xxxv	58.07 (5)
Al12ⁱⁱⁱ—Mn4—Al4^xiii	167.76 (5)	Al6^xl—Al8—Al10^xxxv	116.10 (9)
Al12^xix—Mn4—Al4^xiii	112.57 (5)	Al9^xxxiii—Al8—Al10^xxxv	57.55 (4)
Al4—Mn4—Al4^xiii	56.78 (7)	Al13^xxxiv—Al8—Al10^xxxv	89.92 (4)
Al2ⁱⁱⁱ—Mn4—Al11^xix	67.93 (4)	Al13^xxvii—Al8—Al10^xxxv	161.13 (8)
Al12ⁱⁱⁱ—Mn4—Al11^xix	130.89 (5)	Al10^x—Al8—Al10^xxxv	105.39 (8)
Al12^xix—Mn4—Al11^xix	65.30 (4)	Ni1—Al9—Ni1^xx	114.80 (7)
Al4—Mn4—Al11^xix	109.69 (5)	Ni1—Al9—Al10^xxi	144.85 (7)
Al4^xiii—Mn4—Al11^xix	61.32 (4)	Ni1^xx—Al9—Al10^xxi	54.20 (3)
Al2ⁱⁱⁱ—Mn4—Al11ⁱⁱⁱ	67.93 (4)	Ni1—Al9—Al10ⁱⁱⁱ	54.20 (3)
Al12ⁱⁱⁱ—Mn4—Al11ⁱⁱⁱ	65.30 (4)	Ni1^xx—Al9—Al10ⁱⁱⁱ	144.85 (7)
Al12^xix—Mn4—Al11ⁱⁱⁱ	130.89 (5)	Al10^xxi—Al9—Al10ⁱⁱⁱ	112.70 (8)
Al4—Mn4—Al11ⁱⁱⁱ	61.32 (4)	Ni1—Al9—Al9^vii	58.77 (3)
Al4^xiii—Mn4—Al11ⁱⁱⁱ	109.69 (5)	Ni1^xx—Al9—Al9^vii	58.77 (3)
Al11^xix—Mn4—Al11ⁱⁱⁱ	118.44 (6)	Al10^xxi—Al9—Al9^vii	110.28 (4)
Al2ⁱⁱⁱ—Mn4—Al1	125.73 (7)	Al10ⁱⁱⁱ—Al9—Al9^vii	110.28 (4)
Al12ⁱⁱⁱ—Mn4—Al1	67.95 (4)	Ni1—Al9—Mn4ⁱⁱⁱ	108.60 (4)
Al12^xix—Mn4—Al1	67.95 (4)	Ni1^xx—Al9—Mn4ⁱⁱⁱ	108.60 (4)
Al4—Mn4—Al1	108.06 (4)	Al10^xxi—Al9—Mn4ⁱⁱⁱ	106.47 (5)
Al4^xiii—Mn4—Al1	108.06 (4)	Al10ⁱⁱⁱ—Al9—Mn4ⁱⁱⁱ	106.47 (5)
Al11^xix—Mn4—Al1	120.10 (3)	Al9^vii—Al9—Mn4ⁱⁱⁱ	110.52 (4)
Al11ⁱⁱⁱ—Mn4—Al1	120.10 (3)	Ni1—Al9—Al11	53.63 (3)
Al2ⁱⁱⁱ—Mn4—Al5	121.80 (3)	Ni1^xx—Al9—Al11	141.43 (7)
Al12ⁱⁱⁱ—Mn4—Al5	62.05 (4)	Al10^xxi—Al9—Al11	157.30 (8)
Al12^xix—Mn4—Al5	124.60 (5)	Al10ⁱⁱⁱ—Al9—Al11	64.15 (3)
Al4—Mn4—Al5	58.77 (5)	Al9^vii—Al9—Al11	91.08 (4)
Al4^xiii—Mn4—Al5	105.73 (4)	Mn4ⁱⁱⁱ—Al9—Al11	56.79 (4)
Al11^xix—Mn4—Al5	167.00 (5)	Ni1—Al9—Al11^xx	141.43 (7)
Al11ⁱⁱⁱ—Mn4—Al5	63.11 (4)	Ni1^xx—Al9—Al11^xx	53.63 (3)
Al1—Mn4—Al5	62.93 (4)	Al10^xxi—Al9—Al11^xx	64.16 (3)
Al2ⁱⁱⁱ—Mn4—Al5^xiii	121.80 (3)	Al10ⁱⁱⁱ—Al9—Al11^xx	157.30 (8)
Al12ⁱⁱⁱ—Mn4—Al5^xiii	124.60 (5)	Al9^vii—Al9—Al11^xx	91.08 (4)
Al12^xix—Mn4—Al5^xiii	62.05 (4)	Mn4ⁱⁱⁱ—Al9—Al11^xx	56.79 (4)
Al4—Mn4—Al5^xiii	105.73 (4)	Al11—Al9—Al11^xx	109.37 (7)
Al4^xiii—Mn4—Al5^xiii	58.77 (5)	Ni1—Al9—Al4^xxi	148.57 (6)
Al11^xix—Mn4—Al5^xiii	63.11 (4)	Ni1^xx—Al9—Al4^xxi	96.50 (4)
Al11ⁱⁱⁱ—Mn4—Al5^xiii	167.00 (5)	Al10^xxi—Al9—Al4^xxi	57.76 (5)
Al1—Mn4—Al5^xiii	62.93 (4)	Al10ⁱⁱⁱ—Al9—Al4^xxi	101.40 (7)
Al5—Mn4—Al5^xiii	112.26 (5)	Al9^vii—Al9—Al4^xxi	148.15 (4)
Al2ⁱⁱⁱ—Mn4—Al9ⁱⁱⁱ	65.12 (7)	Mn4ⁱⁱⁱ—Al9—Al4^xxi	55.13 (5)
Al12ⁱⁱⁱ—Mn4—Al9ⁱⁱⁱ	119.85 (5)	Al11—Al9—Al4^xxi	99.98 (7)
Al12^xix—Mn4—Al9ⁱⁱⁱ	119.85 (5)	Al11^xx—Al9—Al4^xxi	57.08 (4)
Al4—Mn4—Al9ⁱⁱⁱ	62.64 (4)	Ni1—Al9—Al4ⁱⁱⁱ	96.50 (4)
Al4^xiii—Mn4—Al9ⁱⁱⁱ	62.64 (4)	Ni1^xx—Al9—Al4ⁱⁱⁱ	148.57 (6)
Al11^xix—Mn4—Al9ⁱⁱⁱ	61.75 (3)	Al10^xxi—Al9—Al4ⁱⁱⁱ	101.40 (7)
Al11ⁱⁱⁱ—Mn4—Al9ⁱⁱⁱ	61.75 (3)	Al10ⁱⁱⁱ—Al9—Al4ⁱⁱⁱ	57.76 (5)
Al1—Mn4—Al9ⁱⁱⁱ	169.14 (6)	Al9^vii—Al9—Al4ⁱⁱⁱ	148.15 (4)
Al5—Mn4—Al9ⁱⁱⁱ	112.73 (4)	Mn4ⁱⁱⁱ—Al9—Al4ⁱⁱⁱ	55.13 (5)
Al5^xiii—Mn4—Al9ⁱⁱⁱ	112.73 (4)	Al11—Al9—Al4ⁱⁱⁱ	57.08 (4)
Al2ⁱⁱⁱ—Mn4—Mn4^xiv	175.64 (6)	Al11^xx—Al9—Al4ⁱⁱⁱ	99.98 (7)
Al12ⁱⁱⁱ—Mn4—Mn4^xiv	112.93 (3)	Al4^xxi—Al9—Al4ⁱⁱⁱ	52.11 (7)
Al12^xix—Mn4—Mn4^xiv	112.93 (3)	Ni1—Al9—Al2	82.51 (4)
Al4—Mn4—Mn4^xiv	57.21 (3)	Ni1^xx—Al9—Al2	82.51 (4)
Al4^xiii—Mn4—Mn4^xiv	57.21 (3)	Al10^xxi—Al9—Al2	123.19 (4)
Al11^xix—Mn4—Mn4^xiv	110.38 (3)	Al10ⁱⁱⁱ—Al9—Al2	123.19 (4)
Al11ⁱⁱⁱ—Mn4—Mn4^xiv	110.38 (3)	Al9^vii—Al9—Al2	60.21 (4)
Al1—Mn4—Mn4^xiv	58.63 (3)	Mn4ⁱⁱⁱ—Al9—Al2	50.30 (4)
Al5—Mn4—Mn4^xiv	59.23 (2)	Al11—Al9—Al2	60.52 (4)
Al5^xiii—Mn4—Mn4^xiv	59.23 (2)	Al11^xx—Al9—Al2	60.52 (4)
Al9ⁱⁱⁱ—Mn4—Mn4^xiv	110.52 (4)	Al4^xxi—Al9—Al2	99.67 (6)
Mn2—Al1—Mn4	148.62 (3)	Al4ⁱⁱⁱ—Al9—Al2	99.67 (6)
Mn2—Al1—Mn4^xiv	148.63 (3)	Ni1—Al9—Mn1ⁱⁱⁱ	111.21 (4)
Mn4—Al1—Mn4^xiv	62.75 (6)	Ni1^xx—Al9—Mn1ⁱⁱⁱ	111.21 (4)
Mn2—Al1—Al5	126.65 (5)	Al10^xxi—Al9—Mn1ⁱⁱⁱ	58.46 (4)
Mn4—Al1—Al5	59.36 (5)	Al10ⁱⁱⁱ—Al9—Mn1ⁱⁱⁱ	58.46 (4)
Mn4^xiv—Al1—Al5	59.36 (5)	Al9^vii—Al9—Mn1ⁱⁱⁱ	147.96 (4)
Mn2—Al1—Al5^xiii	126.65 (5)	Mn4ⁱⁱⁱ—Al9—Mn1ⁱⁱⁱ	101.52 (6)
Mn4—Al1—Al5^xiii	59.36 (5)	Al11—Al9—Mn1ⁱⁱⁱ	106.89 (5)
Mn4^xiv—Al1—Al5^xiii	59.36 (5)	Al11^xx—Al9—Mn1ⁱⁱⁱ	106.89 (5)
Al5—Al1—Al5^xiii	106.69 (10)	Al4^xxi—Al9—Mn1ⁱⁱⁱ	55.61 (5)
Mn2—Al1—Al12^xv	102.72 (5)	Al4ⁱⁱⁱ—Al9—Mn1ⁱⁱⁱ	55.61 (5)
Mn4—Al1—Al12^xv	103.75 (7)	Al2—Al9—Mn1ⁱⁱⁱ	151.82 (8)
Mn4^xiv—Al1—Al12^xv	52.13 (3)	Ni1ⁱⁱⁱ—Al10—Al4	105.45 (5)
Al5—Al1—Al12^xv	107.16 (6)	Ni1ⁱⁱⁱ—Al10—Al6^xii	139.58 (5)
Al5^xiii—Al1—Al12^xv	56.09 (3)	Al4—Al10—Al6^xii	103.57 (5)
Mn2—Al1—Al12ⁱⁱⁱ	102.72 (5)	Ni1ⁱⁱⁱ—Al10—Al6^xxiii	123.31 (5)
Mn4—Al1—Al12ⁱⁱⁱ	52.13 (3)	Al4—Al10—Al6^xxiii	98.33 (5)
Mn4^xiv—Al1—Al12ⁱⁱⁱ	103.75 (7)	Al6^xii—Al10—Al6^xxiii	78.80 (7)
Al5—Al1—Al12ⁱⁱⁱ	56.09 (3)	Ni1ⁱⁱⁱ—Al10—Mn1	122.22 (5)
Al5^xiii—Al1—Al12ⁱⁱⁱ	107.16 (6)	Al4—Al10—Mn1	58.18 (5)
Al12^xv—Al1—Al12ⁱⁱⁱ	154.55 (10)	Al6^xii—Al10—Mn1	55.26 (5)
Mn2—Al1—Al12^iv	102.72 (5)	Al6^xxiii—Al10—Mn1	114.14 (5)
Mn4—Al1—Al12^iv	103.75 (7)	Ni1ⁱⁱⁱ—Al10—Al9ⁱⁱⁱ	61.91 (5)
Mn4^xiv—Al1—Al12^iv	52.13 (3)	Al4—Al10—Al9ⁱⁱⁱ	62.38 (5)
Al5—Al1—Al12^iv	56.09 (3)	Al6^xii—Al10—Al9ⁱⁱⁱ	109.94 (6)
Al5^xiii—Al1—Al12^iv	107.16 (6)	Al6^xxiii—Al10—Al9ⁱⁱⁱ	159.88 (7)
Al12^xv—Al1—Al12^iv	64.22 (5)	Mn1—Al10—Al9ⁱⁱⁱ	62.12 (4)
Al12ⁱⁱⁱ—Al1—Al12^iv	109.74 (6)	Ni1ⁱⁱⁱ—Al10—Al13^xxxvi	62.42 (4)
Mn2—Al1—Al12^xix	102.72 (5)	Al4—Al10—Al13^xxxvi	98.14 (6)
Mn4—Al1—Al12^xix	52.13 (3)	Al6^xii—Al10—Al13^xxxvi	138.97 (6)
Mn4^xiv—Al1—Al12^xix	103.75 (7)	Al6^xxiii—Al10—Al13^xxxvi	63.76 (5)
Al5—Al1—Al12^xix	107.16 (6)	Mn1—Al10—Al13^xxxvi	156.23 (6)
Al5^xiii—Al1—Al12^xix	56.09 (3)	Al9ⁱⁱⁱ—Al10—Al13^xxxvi	110.94 (6)
Al12^xv—Al1—Al12^xix	109.74 (6)	Ni1ⁱⁱⁱ—Al10—Al7B^xli	49.75 (3)
Al12ⁱⁱⁱ—Al1—Al12^xix	64.22 (5)	Al4—Al10—Al7B^xli	155.17 (5)
Al12^iv—Al1—Al12^xix	154.55 (10)	Al6^xii—Al10—Al7B^xli	97.94 (4)
Mn2—Al1—Al13	49.10 (4)	Al6^xxiii—Al10—Al7B^xli	97.86 (4)
Mn4—Al1—Al13	107.71 (3)	Mn1—Al10—Al7B^xli	129.61 (5)
Mn4^xiv—Al1—Al13	144.48 (4)	Al9ⁱⁱⁱ—Al10—Al7B^xli	98.73 (5)
Al5—Al1—Al13	85.93 (4)	Al13^xxxvi—Al10—Al7B^xli	72.59 (4)
Al5^xiii—Al1—Al13	148.52 (3)	Ni1ⁱⁱⁱ—Al10—Al8^x	88.21 (6)
Al12^xv—Al1—Al13	148.29 (8)	Al4—Al10—Al8^x	103.25 (6)
Al12ⁱⁱⁱ—Al1—Al13	55.78 (3)	Al6^xii—Al10—Al8^x	57.93 (6)
Al12^iv—Al1—Al13	103.80 (4)	Al6^xxiii—Al10—Al8^x	134.91 (7)
Al12^xix—Al1—Al13	92.86 (4)	Mn1—Al10—Al8^x	51.89 (5)
Mn2—Al1—Al13^v	49.10 (4)	Al9ⁱⁱⁱ—Al10—Al8^x	60.42 (5)
Mn4—Al1—Al13^v	144.49 (4)	Al13^xxxvi—Al10—Al8^x	147.50 (8)
Mn4^xiv—Al1—Al13^v	107.71 (3)	Ni1ⁱⁱⁱ—Al10—Al10^v	161.38 (3)
Al5—Al1—Al13^v	85.93 (4)	Al4—Al10—Al10^v	57.62 (3)
Al5^xiii—Al1—Al13^v	148.52 (3)	Al6^xii—Al10—Al10^v	57.99 (3)
Al12^xv—Al1—Al13^v	92.86 (4)	Al6^xxiii—Al10—Al10^v	58.04 (3)
Al12ⁱⁱⁱ—Al1—Al13^v	103.80 (4)	Mn1—Al10—Al10^v	58.05 (3)
Al12^iv—Al1—Al13^v	55.79 (3)	Al9ⁱⁱⁱ—Al10—Al10^v	110.28 (4)
Al12^xix—Al1—Al13^v	148.29 (8)	Al13^xxxvi—Al10—Al10^v	109.46 (4)
Al13—Al1—Al13^v	58.63 (6)	Al8^x—Al10—Al10^v	102.64 (6)
Mn2—Al1—Al13^xiii	49.10 (4)	Ni1ⁱⁱⁱ—Al10—Al7A^xl	53.82 (5)
Mn4—Al1—Al13^xiii	107.71 (3)	Al4—Al10—Al7A^xl	144.61 (7)
Mn4^xiv—Al1—Al13^xiii	144.49 (4)	Al6^xii—Al10—Al7A^xl	86.56 (5)
Al5—Al1—Al13^xiii	148.52 (3)	Al6^xxiii—Al10—Al7A^xl	116.97 (7)
Al5^xiii—Al1—Al13^xiii	85.93 (4)	Mn1—Al10—Al7A^xl	105.45 (6)
Al12^xv—Al1—Al13^xiii	103.80 (4)	Al9ⁱⁱⁱ—Al10—Al7A^xl	82.25 (7)
Al12ⁱⁱⁱ—Al1—Al13^xiii	92.86 (4)	Al13^xxxvi—Al10—Al7A^xl	95.49 (6)
Al12^iv—Al1—Al13^xiii	148.29 (8)	Al8^x—Al10—Al7A^xl	53.56 (7)
Al12^xix—Al1—Al13^xiii	55.79 (3)	Al10^v—Al10—Al7A^xl	144.48 (4)
Al13—Al1—Al13^xiii	70.31 (7)	Ni1ⁱⁱⁱ—Al10—Mn3^xxiii	104.59 (4)
Al13^v—Al1—Al13^xiii	98.19 (9)	Al4—Al10—Mn3^xxiii	54.15 (4)
Mn4^xxii—Al2—Mn4ⁱⁱⁱ	171.29 (12)	Al6^xii—Al10—Mn3^xxiii	115.15 (5)
Mn4^xxii—Al2—Al12	117.15 (7)	Al6^xxiii—Al10—Mn3^xxiii	52.94 (4)
Mn4ⁱⁱⁱ—Al2—Al12	56.15 (4)	Mn1—Al10—Mn3^xxiii	104.50 (4)
Mn4^xxii—Al2—Al12^v	56.15 (4)	Al9ⁱⁱⁱ—Al10—Mn3^xxiii	107.56 (5)
Mn4ⁱⁱⁱ—Al2—Al12^v	117.15 (7)	Al13^xxxvi—Al10—Mn3^xxiii	54.12 (4)
Al12—Al2—Al12^v	61.08 (6)	Al8^x—Al10—Mn3^xxiii	156.03 (6)
Mn4^xxii—Al2—Al12^vii	56.15 (4)	Al10^v—Al10—Mn3^xxiii	60.16 (2)
Mn4ⁱⁱⁱ—Al2—Al12^vii	117.15 (7)	Al7A^xl—Al10—Mn3^xxiii	149.60 (6)
Al12—Al2—Al12^vii	97.05 (9)	Ni1—Al11—Mn4ⁱⁱⁱ	120.04 (5)
Al12^v—Al2—Al12^vii	66.82 (7)	Ni1—Al11—Al4ⁱⁱⁱ	105.21 (5)
Mn4^xxii—Al2—Al12^xx	117.15 (7)	Mn4ⁱⁱⁱ—Al11—Al4ⁱⁱⁱ	58.05 (5)
Mn4ⁱⁱⁱ—Al2—Al12^xx	56.15 (4)	Ni1—Al11—Al13^vi	63.18 (4)
Al12—Al2—Al12^xx	66.82 (7)	Mn4ⁱⁱⁱ—Al11—Al13^vi	157.51 (6)
Al12^v—Al2—Al12^xx	97.05 (9)	Al4ⁱⁱⁱ—Al11—Al13^vi	99.47 (6)
Al12^vii—Al2—Al12^xx	61.08 (6)	Ni1—Al11—Al12^xviii	120.70 (5)
Mn4^xxii—Al2—Al9^vii	64.57 (5)	Mn4ⁱⁱⁱ—Al11—Al12^xviii	118.86 (5)
Mn4ⁱⁱⁱ—Al2—Al9^vii	124.14 (9)	Al4ⁱⁱⁱ—Al11—Al12^xviii	99.45 (6)
Al12—Al2—Al9^vii	145.81 (4)	Al13^vi—Al11—Al12^xviii	60.03 (4)
Al12^v—Al2—Al9^vii	108.81 (4)	Ni1—Al11—Al12	140.58 (6)
Al12^vii—Al2—Al9^vii	108.81 (4)	Mn4ⁱⁱⁱ—Al11—Al12	53.81 (4)
Al12^xx—Al2—Al9^vii	145.82 (4)	Al4ⁱⁱⁱ—Al11—Al12	100.93 (6)
Mn4^xxii—Al2—Al9	124.14 (9)	Al13^vi—Al11—Al12	139.80 (6)
Mn4ⁱⁱⁱ—Al2—Al9	64.57 (5)	Al12^xviii—Al11—Al12	82.62 (5)
Al12—Al2—Al9	108.81 (4)	Ni1—Al11—Al9	60.86 (4)
Al12^v—Al2—Al9	145.81 (4)	Mn4ⁱⁱⁱ—Al11—Al9	61.46 (4)
Al12^vii—Al2—Al9	145.81 (4)	Al4ⁱⁱⁱ—Al11—Al9	61.51 (5)
Al12^xx—Al2—Al9	108.81 (4)	Al13^vi—Al11—Al9	110.64 (6)
Al9^vii—Al2—Al9	59.57 (9)	Al12^xviii—Al11—Al9	158.50 (6)
Mn4^xxii—Al2—Al11^xx	122.17 (3)	Al12—Al11—Al9	109.52 (5)
Mn4ⁱⁱⁱ—Al2—Al11^xx	60.75 (3)	Ni1—Al11—Al2	85.94 (6)
Al12—Al2—Al11^xx	112.13 (4)	Mn4ⁱⁱⁱ—Al11—Al2	51.31 (3)
Al12^v—Al2—Al11^xx	153.77 (8)	Al4ⁱⁱⁱ—Al11—Al2	102.30 (5)
Al12^vii—Al2—Al11^xx	90.36 (4)	Al13^vi—Al11—Al2	145.99 (6)
Al12^xx—Al2—Al11^xx	59.07 (3)	Al12^xviii—Al11—Al2	139.28 (7)
Al9^vii—Al2—Al11^xx	90.20 (6)	Al12—Al11—Al2	59.75 (6)
Al9—Al2—Al11^xx	59.65 (4)	Al9—Al11—Al2	59.83 (6)
Mn4^xxii—Al2—Al11^v	60.75 (3)	Ni1—Al11—Al5ⁱⁱⁱ	160.26 (6)
Mn4ⁱⁱⁱ—Al2—Al11^v	122.17 (3)	Mn4ⁱⁱⁱ—Al11—Al5ⁱⁱⁱ	59.85 (4)
Al12—Al2—Al11^v	90.36 (4)	Al4ⁱⁱⁱ—Al11—Al5ⁱⁱⁱ	56.74 (5)
Al12^v—Al2—Al11^v	59.07 (3)	Al13^vi—Al11—Al5ⁱⁱⁱ	108.98 (6)
Al12^vii—Al2—Al11^v	112.13 (4)	Al12^xviii—Al11—Al5ⁱⁱⁱ	60.86 (5)
Al12^xx—Al2—Al11^v	153.77 (8)	Al12—Al11—Al5ⁱⁱⁱ	57.49 (4)
Al9^vii—Al2—Al11^v	59.65 (4)	Al9—Al11—Al5ⁱⁱⁱ	109.91 (6)
Al9—Al2—Al11^v	90.19 (6)	Al2—Al11—Al5ⁱⁱⁱ	104.78 (6)
Al11^xx—Al2—Al11^v	146.39 (10)	Ni1—Al11—Mn3^xviii	104.64 (4)
Mn4^xxii—Al2—Al11^vii	60.75 (3)	Mn4ⁱⁱⁱ—Al11—Mn3^xviii	105.35 (5)
Mn4ⁱⁱⁱ—Al2—Al11^vii	122.17 (3)	Al4ⁱⁱⁱ—Al11—Mn3^xviii	54.22 (4)
Al12—Al2—Al11^vii	153.77 (8)	Al13^vi—Al11—Mn3^xviii	54.73 (4)
Al12^v—Al2—Al11^vii	112.13 (4)	Al12^xviii—Al11—Mn3^xviii	52.49 (4)
Al12^vii—Al2—Al11^vii	59.07 (3)	Al12—Al11—Mn3^xviii	114.57 (5)
Al12^xx—Al2—Al11^vii	90.36 (4)	Al9—Al11—Mn3^xviii	106.02 (5)
Al9^vii—Al2—Al11^vii	59.65 (4)	Al2—Al11—Mn3^xviii	155.83 (5)
Al9—Al2—Al11^vii	90.19 (6)	Al5ⁱⁱⁱ—Al11—Mn3^xviii	59.41 (4)
Al11^xx—Al2—Al11^vii	61.59 (5)	Ni1—Al11—Al11^v	54.29 (3)
Al11^v—Al2—Al11^vii	107.97 (6)	Mn4ⁱⁱⁱ—Al11—Al11^v	110.38 (3)
Mn4^xxii—Al2—Al11	122.17 (3)	Al4ⁱⁱⁱ—Al11—Al11^v	150.42 (4)
Mn4ⁱⁱⁱ—Al2—Al11	60.75 (3)	Al13^vi—Al11—Al11^v	89.65 (4)
Al12—Al2—Al11	59.07 (3)	Al12^xviii—Al11—Al11^v	109.41 (4)
Al12^v—Al2—Al11	90.36 (4)	Al12—Al11—Al11^v	89.35 (4)
Al12^vii—Al2—Al11	153.77 (8)	Al9—Al11—Al11^v	88.92 (4)
Al12^xx—Al2—Al11	112.13 (4)	Al2—Al11—Al11^v	59.20 (3)
Al9^vii—Al2—Al11	90.19 (6)	Al5ⁱⁱⁱ—Al11—Al11^v	145.45 (4)
Al9—Al2—Al11	59.65 (4)	Mn3^xviii—Al11—Al11^v	144.17 (3)
Al11^xx—Al2—Al11	107.97 (6)	Ni1—Al11—Al10ⁱⁱⁱ	53.44 (3)
Al11^v—Al2—Al11	61.59 (5)	Mn4ⁱⁱⁱ—Al11—Al10ⁱⁱⁱ	104.42 (5)
Al11^vii—Al2—Al11	146.39 (10)	Al4ⁱⁱⁱ—Al11—Al10ⁱⁱⁱ	56.65 (5)
Mn3—Al3—Mn3^xx	174.83 (12)	Al13^vi—Al11—Al10ⁱⁱⁱ	58.05 (4)
Mn3—Al3—Al6^xx	128.61 (10)	Al12^xviii—Al11—Al10ⁱⁱⁱ	105.30 (5)
Mn3^xx—Al3—Al6^xx	56.56 (5)	Al12—Al11—Al10ⁱⁱⁱ	156.83 (6)
Mn3—Al3—Al6	56.56 (5)	Al9—Al11—Al10ⁱⁱⁱ	56.86 (4)
Mn3^xx—Al3—Al6	128.61 (10)	Al2—Al11—Al10ⁱⁱⁱ	115.42 (6)
Al6^xx—Al3—Al6	72.05 (9)	Al5ⁱⁱⁱ—Al11—Al10ⁱⁱⁱ	106.83 (5)
Mn3—Al3—Al12^xx	120.36 (8)	Mn3^xviii—Al11—Al10ⁱⁱⁱ	59.38 (4)
Mn3^xx—Al3—Al12^xx	55.46 (4)	Al11^v—Al11—Al10ⁱⁱⁱ	107.73 (3)
Al6^xx—Al3—Al12^xx	103.70 (4)	Mn4ⁱⁱⁱ—Al12—Mn3	161.15 (6)
Al6—Al3—Al12^xx	150.24 (3)	Mn4ⁱⁱⁱ—Al12—Al5ⁱⁱⁱ	64.16 (5)
Mn3—Al3—Al12^vii	120.36 (8)	Mn3—Al12—Al5ⁱⁱⁱ	133.76 (6)
Mn3^xx—Al3—Al12^vii	55.46 (4)	Mn4ⁱⁱⁱ—Al12—Al13ⁱⁱⁱ	122.41 (6)
Al6^xx—Al3—Al12^vii	103.70 (4)	Mn3—Al12—Al13ⁱⁱⁱ	58.70 (4)
Al6—Al3—Al12^vii	150.24 (3)	Al5ⁱⁱⁱ—Al12—Al13ⁱⁱⁱ	93.09 (6)
Al12^xx—Al3—Al12^vii	59.39 (6)	Mn4ⁱⁱⁱ—Al12—Al11^xviii	131.84 (6)
Mn3—Al3—Al12^v	55.46 (4)	Mn3—Al12—Al11^xviii	66.33 (4)
Mn3^xx—Al3—Al12^v	120.35 (8)	Al5ⁱⁱⁱ—Al12—Al11^xviii	67.68 (5)
Al6^xx—Al3—Al12^v	150.24 (3)	Al13ⁱⁱⁱ—Al12—Al11^xviii	58.79 (4)
Al6—Al3—Al12^v	103.70 (4)	Mn4ⁱⁱⁱ—Al12—Al11	60.89 (4)
Al12^xx—Al3—Al12^v	93.84 (8)	Mn3—Al12—Al11	128.46 (6)
Al12^vii—Al3—Al12^v	64.92 (6)	Al5ⁱⁱⁱ—Al12—Al11	62.40 (5)
Mn3—Al3—Al12	55.46 (4)	Al13ⁱⁱⁱ—Al12—Al11	152.13 (6)
Mn3^xx—Al3—Al12	120.35 (8)	Al11^xviii—Al12—Al11	97.38 (5)
Al6^xx—Al3—Al12	150.24 (3)	Mn4ⁱⁱⁱ—Al12—Al2	53.54 (3)
Al6—Al3—Al12	103.70 (4)	Mn3—Al12—Al2	113.47 (5)
Al12^xx—Al3—Al12	64.92 (6)	Al5ⁱⁱⁱ—Al12—Al2	109.70 (6)
Al12^vii—Al3—Al12	93.84 (8)	Al13ⁱⁱⁱ—Al12—Al2	145.60 (6)
Al12^v—Al3—Al12	59.38 (6)	Al11^xviii—Al12—Al2	153.67 (6)
Mn3—Al3—Al13^iv	55.87 (3)	Al11—Al12—Al2	61.18 (5)
Mn3^xx—Al3—Al13^iv	125.40 (3)	Mn4ⁱⁱⁱ—Al12—Al5^vi	125.99 (6)
Al6^xx—Al3—Al13^iv	99.90 (7)	Mn3—Al12—Al5^vi	63.87 (4)
Al6—Al3—Al13^iv	60.04 (4)	Al5ⁱⁱⁱ—Al12—Al5^vi	97.44 (4)
Al12^xx—Al3—Al13^iv	147.01 (8)	Al13ⁱⁱⁱ—Al12—Al5^vi	108.09 (6)
Al12^vii—Al3—Al13^iv	92.89 (4)	Al11^xviii—Al12—Al5^vi	60.97 (4)
Al12^v—Al3—Al13^iv	55.79 (3)	Al11—Al12—Al5^vi	65.61 (5)
Al12—Al3—Al13^iv	103.07 (5)	Al2—Al12—Al5^vi	94.51 (5)
Mn3—Al3—Al13^xxi	125.40 (3)	Mn4ⁱⁱⁱ—Al12—Al12^v	112.93 (3)
Mn3^xx—Al3—Al13^xxi	55.87 (3)	Mn3—Al12—Al12^v	55.32 (3)
Al6^xx—Al3—Al13^xxi	60.04 (4)	Al5ⁱⁱⁱ—Al12—Al12^v	151.29 (4)
Al6—Al3—Al13^xxi	99.90 (7)	Al13ⁱⁱⁱ—Al12—Al12^v	110.01 (4)
Al12^xx—Al3—Al13^xxi	55.79 (3)	Al11^xviii—Al12—Al12^v	109.41 (4)
Al12^vii—Al3—Al13^xxi	103.07 (5)	Al11—Al12—Al12^v	90.65 (4)
Al12^v—Al3—Al13^xxi	147.01 (8)	Al2—Al12—Al12^v	59.46 (3)
Al12—Al3—Al13^xxi	92.89 (4)	Al5^vi—Al12—Al12^v	59.92 (3)
Al13^iv—Al3—Al13^xxi	156.64 (10)	Mn4ⁱⁱⁱ—Al12—Al3	108.70 (5)
Mn3—Al3—Al13^xxii	125.40 (3)	Mn3—Al12—Al3	53.43 (4)
Mn3^xx—Al3—Al13^xxii	55.87 (3)	Al5ⁱⁱⁱ—Al12—Al3	148.34 (6)
Al6^xx—Al3—Al13^xxii	60.04 (4)	Al13ⁱⁱⁱ—Al12—Al3	63.77 (5)
Al6—Al3—Al13^xxii	99.90 (7)	Al11^xviii—Al12—Al3	111.56 (5)
Al12^xx—Al3—Al13^xxii	103.07 (5)	Al11—Al12—Al3	143.97 (6)
Al12^vii—Al3—Al13^xxii	55.79 (3)	Al2—Al12—Al3	84.56 (6)
Al12^v—Al3—Al13^xxii	92.89 (4)	Al5^vi—Al12—Al3	109.80 (5)
Al12—Al3—Al13^xxii	147.01 (8)	Al12^v—Al12—Al3	60.31 (3)
Al13^iv—Al3—Al13^xxii	69.61 (5)	Mn4ⁱⁱⁱ—Al12—Al1ⁱⁱⁱ	59.92 (5)
Al13^xxi—Al3—Al13^xxii	105.46 (6)	Mn3—Al12—Al1ⁱⁱⁱ	119.49 (6)
Mn3—Al3—Al13ⁱⁱⁱ	55.87 (3)	Al5ⁱⁱⁱ—Al12—Al1ⁱⁱⁱ	61.05 (5)
Mn3^xx—Al3—Al13ⁱⁱⁱ	125.40 (3)	Al13ⁱⁱⁱ—Al12—Al1ⁱⁱⁱ	62.78 (6)
Al6^xx—Al3—Al13ⁱⁱⁱ	99.90 (7)	Al11^xviii—Al12—Al1ⁱⁱⁱ	95.91 (5)
Al6—Al3—Al13ⁱⁱⁱ	60.04 (4)	Al11—Al12—Al1ⁱⁱⁱ	110.32 (6)
Al12^xx—Al3—Al13ⁱⁱⁱ	92.89 (4)	Al2—Al12—Al1ⁱⁱⁱ	105.59 (5)
Al12^vii—Al3—Al13ⁱⁱⁱ	147.01 (8)	Al5^vi—Al12—Al1ⁱⁱⁱ	154.32 (5)
Al12^v—Al3—Al13ⁱⁱⁱ	103.07 (5)	Al12^v—Al12—Al1ⁱⁱⁱ	144.87 (3)
Al12—Al3—Al13ⁱⁱⁱ	55.79 (3)	Al3—Al12—Al1ⁱⁱⁱ	88.24 (5)
Al13^iv—Al3—Al13ⁱⁱⁱ	105.46 (6)	Mn2—Al13—Mn3ⁱⁱⁱ	149.28 (6)
Al13^xxi—Al3—Al13ⁱⁱⁱ	69.61 (5)	Mn2—Al13—Al7A	59.00 (7)
Al13^xxii—Al3—Al13ⁱⁱⁱ	156.64 (10)	Mn3ⁱⁱⁱ—Al13—Al7A	134.09 (6)
Al4^xiii—Al4—Mn3^xxiii	179.94 (4)	Mn2—Al13—Al11^xxiii	140.75 (7)
Al4^xiii—Al4—Mn4^xiv	61.61 (4)	Mn3ⁱⁱⁱ—Al13—Al11^xxiii	66.42 (4)
Mn3^xxiii—Al4—Mn4^xiv	118.34 (5)	Al7A—Al13—Al11^xxiii	113.16 (8)
Al4^xiii—Al4—Mn4	61.61 (4)	Mn2—Al13—Ni1^xxiii	102.62 (5)
Mn3^xxiii—Al4—Mn4	118.34 (5)	Mn3ⁱⁱⁱ—Al13—Ni1^xxiii	107.22 (5)
Mn4^xiv—Al4—Mn4	65.57 (5)	Al7A—Al13—Ni1^xxiii	58.62 (6)
Al4^xiii—Al4—Mn1	61.94 (4)	Al11^xxiii—Al13—Ni1^xxiii	54.73 (4)
Mn3^xxiii—Al4—Mn1	118.11 (6)	Mn2—Al13—Al12ⁱⁱⁱ	117.03 (7)
Mn4^xiv—Al4—Mn1	112.85 (5)	Mn3ⁱⁱⁱ—Al13—Al12ⁱⁱⁱ	56.18 (4)
Mn4—Al4—Mn1	112.85 (5)	Al7A—Al13—Al12ⁱⁱⁱ	167.20 (7)
Al4^xiii—Al4—Al5	113.51 (5)	Al11^xxiii—Al13—Al12ⁱⁱⁱ	61.18 (4)
Mn3^xxiii—Al4—Al5	66.43 (6)	Ni1^xxiii—Al13—Al12ⁱⁱⁱ	113.74 (5)
Mn4^xiv—Al4—Al5	63.50 (5)	Mn2—Al13—Al10^xxxvi	130.87 (7)
Mn4—Al4—Al5	63.50 (5)	Mn3ⁱⁱⁱ—Al13—Al10^xxxvi	65.78 (4)
Mn1—Al4—Al5	175.45 (8)	Al7A—Al13—Al10^xxxvi	72.73 (6)
Al4^xiii—Al4—Al10	113.02 (4)	Al11^xxiii—Al13—Al10^xxxvi	65.72 (4)
Mn3^xxiii—Al4—Al10	67.03 (5)	Ni1^xxiii—Al13—Al10^xxxvi	53.97 (4)
Mn4^xiv—Al4—Al10	174.21 (8)	Al12ⁱⁱⁱ—Al13—Al10^xxxvi	112.08 (6)
Mn4—Al4—Al10	114.51 (3)	Mn2—Al13—Al8^xvi	52.37 (6)
Mn1—Al4—Al10	61.53 (4)	Mn3ⁱⁱⁱ—Al13—Al8^xvi	107.45 (7)
Al5—Al4—Al10	122.04 (7)	Al7A—Al13—Al8^xvi	56.17 (7)
Al4^xiii—Al4—Al10^v	113.02 (4)	Al11^xxiii—Al13—Al8^xvi	159.89 (6)
Mn3^xxiii—Al4—Al10^v	67.03 (5)	Ni1^xxiii—Al13—Al8^xvi	113.35 (6)
Mn4^xiv—Al4—Al10^v	114.51 (3)	Al12ⁱⁱⁱ—Al13—Al8^xvi	132.88 (7)
Mn4—Al4—Al10^v	174.21 (8)	Al10^xxxvi—Al13—Al8^xvi	94.20 (5)
Mn1—Al4—Al10^v	61.53 (4)	Mn2—Al13—Al13^v	51.85 (3)
Al5—Al4—Al10^v	122.04 (7)	Mn3ⁱⁱⁱ—Al13—Al13^v	156.42 (3)
Al10—Al4—Al10^v	64.76 (6)	Al7A—Al13—Al13^v	57.51 (4)
Al4^xiii—Al4—Al11ⁱⁱⁱ	113.18 (4)	Al11^xxiii—Al13—Al13^v	90.35 (4)
Mn3^xxiii—Al4—Al11ⁱⁱⁱ	66.80 (4)	Ni1^xxiii—Al13—Al13^v	58.13 (3)
Mn4^xiv—Al4—Al11ⁱⁱⁱ	116.83 (6)	Al12ⁱⁱⁱ—Al13—Al13^v	110.01 (4)
Mn4—Al4—Al11ⁱⁱⁱ	60.63 (3)	Al10^xxxvi—Al13—Al13^v	109.45 (4)
Mn1—Al4—Al11ⁱⁱⁱ	116.63 (4)	Al8^xvi—Al13—Al13^v	95.79 (6)
Al5—Al4—Al11ⁱⁱⁱ	64.51 (4)	Mn2—Al13—Al6ⁱⁱⁱ	108.64 (6)
Al10—Al4—Al11ⁱⁱⁱ	66.64 (4)	Mn3ⁱⁱⁱ—Al13—Al6ⁱⁱⁱ	54.29 (4)
Al10^v—Al4—Al11ⁱⁱⁱ	122.34 (7)	Al7A—Al13—Al6ⁱⁱⁱ	87.37 (5)
Al4^xiii—Al4—Al11^iv	113.18 (4)	Al11^xxiii—Al13—Al6ⁱⁱⁱ	109.27 (6)
Mn3^xxiii—Al4—Al11^iv	66.80 (4)	Ni1^xxiii—Al13—Al6ⁱⁱⁱ	109.41 (5)
Mn4^xiv—Al4—Al11^iv	60.63 (3)	Al12ⁱⁱⁱ—Al13—Al6ⁱⁱⁱ	105.27 (6)
Mn4—Al4—Al11^iv	116.83 (6)	Al10^xxxvi—Al13—Al6ⁱⁱⁱ	57.61 (5)
Mn1—Al4—Al11^iv	116.63 (4)	Al8^xvi—Al13—Al6ⁱⁱⁱ	56.54 (6)
Al5—Al4—Al11^iv	64.51 (4)	Al13^v—Al13—Al6ⁱⁱⁱ	144.62 (4)
Al10—Al4—Al11^iv	122.34 (7)	Mn2—Al13—Al1	58.45 (6)
Al10^v—Al4—Al11^iv	66.64 (4)	Mn3ⁱⁱⁱ—Al13—Al1	115.78 (6)
Al11ⁱⁱⁱ—Al4—Al11^iv	120.83 (8)	Al7A—Al13—Al1	109.92 (7)
Al4^xiii—Al4—Al9^xv	63.95 (3)	Al11^xxiii—Al13—Al1	96.52 (5)
Mn3^xxiii—Al4—Al9^xv	116.07 (4)	Ni1^xxiii—Al13—Al1	109.98 (4)
Mn4^xiv—Al4—Al9^xv	62.23 (4)	Al12ⁱⁱⁱ—Al13—Al1	61.44 (5)
Mn4—Al4—Al9^xv	117.00 (6)	Al10^xxxvi—Al13—Al1	160.56 (6)
Mn1—Al4—Al9^xv	62.31 (4)	Al8^xvi—Al13—Al1	103.19 (6)
Al5—Al4—Al9^xv	116.32 (5)	Al13^v—Al13—Al1	60.68 (3)
Al10—Al4—Al9^xv	114.06 (7)	Al6ⁱⁱⁱ—Al13—Al1	140.42 (6)
Al10^v—Al4—Al9^xv	59.86 (4)	Mn2—Al13—Al3ⁱⁱⁱ	97.93 (5)
Al11ⁱⁱⁱ—Al4—Al9^xv	177.12 (7)	Mn3ⁱⁱⁱ—Al13—Al3ⁱⁱⁱ	51.70 (3)
Al11^iv—Al4—Al9^xv	61.41 (4)	Al7A—Al13—Al3ⁱⁱⁱ	130.66 (8)
Al4^xiii—Al4—Al9ⁱⁱⁱ	63.95 (3)	Al11^xxiii—Al13—Al3ⁱⁱⁱ	110.78 (6)
Mn3^xxiii—Al4—Al9ⁱⁱⁱ	116.07 (4)	Ni1^xxiii—Al13—Al3ⁱⁱⁱ	158.58 (5)
Mn4^xiv—Al4—Al9ⁱⁱⁱ	117.00 (6)	Al12ⁱⁱⁱ—Al13—Al3ⁱⁱⁱ	60.44 (6)
Mn4—Al4—Al9ⁱⁱⁱ	62.23 (4)	Al10^xxxvi—Al13—Al3ⁱⁱⁱ	107.22 (5)
Mn1—Al4—Al9ⁱⁱⁱ	62.31 (4)	Al8^xvi—Al13—Al3ⁱⁱⁱ	74.99 (7)
Al5—Al4—Al9ⁱⁱⁱ	116.32 (5)	Al13^v—Al13—Al3ⁱⁱⁱ	142.73 (3)
Al10—Al4—Al9ⁱⁱⁱ	59.86 (4)	Al6ⁱⁱⁱ—Al13—Al3ⁱⁱⁱ	57.38 (6)
Al10^v—Al4—Al9ⁱⁱⁱ	114.06 (7)	Al1—Al13—Al3ⁱⁱⁱ	85.90 (5)
Al11ⁱⁱⁱ—Al4—Al9ⁱⁱⁱ	61.41 (4)

Symmetry codes: (i) x, y+1, z; (ii) −x, −y+2, −z+1; (iii) −x+1/2, −y+3/2, −z+1; (iv) x−1/2, −y+3/2, −z+1; (v) −x, y, z; (vi) x, y, z−1; (vii) −x, y, −z+1/2; (viii) −x, y, z−1; (ix) x−1/2, −y+1/2, z+1/2; (x) −x+1/2, −y+1/2, −z+1; (xi) −x, −y+1, z+1/2; (xii) −x, −y+1, −z+1; (xiii) x, y, −z+3/2; (xiv) −x, y, −z+3/2; (xv) x−1/2, −y+3/2, z+1/2; (xvi) x, −y+1, z+1/2; (xvii) x−1/2, −y+3/2, −z; (xviii) −x+1/2, −y+3/2, −z; (xix) −x+1/2, −y+3/2, z+1/2; (xx) x, y, −z+1/2; (xxi) −x+1/2, −y+3/2, z−1/2; (xxii) x−1/2, −y+3/2, z−1/2; (xxiii) x, y, z+1; (xxiv) −x, y, z+1; (xxv) −x+1/2, y+1/2, −z+1/2; (xxvi) x−1/2, y+1/2, z; (xxvii) x, −y+1, −z+1; (xxviii) −x, −y+2, −z+2; (xxix) −x+1/2, y+1/2, z; (xxx) −x+1/2, y−1/2, z−1; (xxxi) x−1/2, −y+1/2, −z+1; (xxxii) x−1/2, y−1/2, z−1; (xxxiii) x, y−1, z; (xxxiv) x, −y+1, z−1/2; (xxxv) −x+1/2, −y+1/2, z−1/2; (xxxvi) −x+1/2, −y+3/2, −z+2; (xxxvii) −x, −y+1, −z; (xxxviii) −x, −y+1, z−1/2; (xxxix) x+1/2, y−1/2, −z+1/2; (xl) x+1/2, y−1/2, z; (xli) x+1/2, y+1/2, z+1.

Funding information

Funding for this research was provided by: The National Natural Science Foundation of China (grant No. 52173231 and 51771165).

References

Brandenburg, K. & Putz, H. (2017). DIAMOND. Crystal Impact GbR, Bonn, Germany. Google Scholar
Bruker (2015). APEX3 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Damjanovic, A. (1961). Acta Cryst. 14, 982–987. CrossRef ICSD CAS IUCr Journals Web of Science Google Scholar
Krause, L., Herbst-Irmer, R., Sheldrick, G. M. & Stalke, D. (2015). J. Appl. Cryst. 48, 3–10. Web of Science CSD CrossRef ICSD CAS IUCr Journals Google Scholar
Li, X. & Kuo, K. (1992). Philos. Mag. B, 65, 525–533. CrossRef CAS Web of Science Google Scholar
Raynor, G. V. (1944). J. Inst. Met. 70, 507. Google Scholar
Robinson, K. (1954). Acta Cryst. 7, 494–497. CrossRef ICSD CAS IUCr Journals Web of Science Google Scholar
Sheldrick, G. M. (2015a). Acta Cryst. A71, 3–8. Web of Science CrossRef IUCr Journals Google Scholar
Sheldrick, G. M. (2015b). Acta Cryst. C71, 3–8. Web of Science CrossRef IUCr Journals Google Scholar
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920–925. Web of Science CrossRef CAS IUCr Journals Google Scholar