[1,1′-Bis­(diphenyl­phosphino)ferrocene-κ²P,P′]bis­(2,3,4,5,6-penta­fluoro­benzene­thiol­ato)platinum(II)

The title compound, [PtFe(C₆F₆S)₂(C₁₇H₁₄P)₂], was obtained from the metathesis reaction of [Pt(dppf)Cl₂] and [Pb(SC₆F₅)₂] in CH₂Cl₂ [dppf is 1,1′-bis­(diphenyl­phosphino)ferrocene]. Two independent mol­ecules are found in the asymmetric unit. The Pt^II centers have a distorted square-planar environment with the P atoms of the dppf ligand coordinating to the metal centers in a bidentate fashion. The coordination of each Pt atom is completed by two –SC₆F₅ ligands in an anti conformation. The crystal packing exhibits inter­esting C—H...π stacking.

Key indicators

• Single-crystal X-ray study
• T = 291 K
• R factor = 0.037
• wR factor = 0.082
• Data-to-parameter ratio = 13.0

checkCIF/PLATON results

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Computing details

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

[1,1'-bis(diphenylphosphino)ferrocene-κ²P,P']bis(2,3,4,5,6- pentafluorobenzenethiolato)platinum(II)

Crystal data

[PtFe(C6F6S)2(C17H14P)2]	F(000) = 4480
Mr = 1147.68	Dx = 1.848 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 8741 reflections
a = 19.7466 (9) Å	θ = 2.3–30.9°
b = 22.0846 (10) Å	µ = 4.00 mm^−1
c = 19.7669 (9) Å	T = 291 K
β = 106.807 (1)°	Prism, yellow
V = 8252.0 (7) Å^3	0.20 × 0.16 × 0.08 mm
Z = 8

Data collection

Bruker SMART APEX CCD diffractometer	14535 independent reflections
Radiation source: fine-focus sealed tube	11545 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.066
Detector resolution: 0.84 pixels mm^-1	θmax = 25.0°, θmin = 1.4°
ω scans	h = −23→23
Absorption correction: multi-scan (SADABS; Sheldrick, 1998)	k = −26→26
Tmin = 0.502, Tmax = 0.740	l = −23→23
67222 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.037	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.082	H-atom parameters constrained
S = 1.01	w = 1/[σ^2(Fo^2) + (0.0356P)^2] where P = (Fo^2 + 2Fc^2)/3
14535 reflections	(Δ/σ)max = 0.003
1117 parameters	Δρmax = 1.07 e Å^−3
0 restraints	Δρmin = −0.45 e Å^−3

Special details

Experimental. 1H NMR (300 MHz, CDCl3): δ 7.95–7.25 (m, Ph, 20H), 4.43 (s, Cp, 4H), 4.27 (s, Cp, 4H); 31P{1H} NMR (121 MHz, CDCl3): δ 28.16 (s, P); 19F{1H} NMR (282 MHz, CDCl3): δ -135.08 (d, 3JFo-Fm = 22.01 Hz, o-F), -164.56 (t, 3JFm-Fp= 22.01 Hz, p-F), -166.87 (m, 4JFo-Fp= 4.79, m-F).

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.727145 (10)	0.134195 (9)	0.480976 (11)	0.03303 (6)
Fe1	0.17062 (4)	0.45798 (3)	0.53480 (4)	0.03746 (18)
S1	0.82216 (8)	0.13869 (6)	0.58713 (8)	0.0459 (4)
S2	0.76364 (8)	0.21938 (7)	0.42946 (9)	0.0562 (4)
P1	0.70551 (7)	0.04332 (6)	0.52712 (7)	0.0351 (3)
P2	0.62987 (7)	0.13562 (6)	0.38442 (7)	0.0318 (3)
F1	0.95768 (17)	0.19786 (15)	0.64602 (19)	0.0641 (10)
F2	0.98644 (19)	0.31254 (17)	0.6858 (2)	0.0768 (11)
F3	0.8806 (2)	0.39180 (16)	0.6803 (2)	0.0762 (11)
F4	0.7450 (2)	0.35487 (18)	0.6313 (2)	0.0824 (12)
F5	0.71367 (18)	0.24037 (16)	0.5907 (2)	0.0724 (11)
F6	0.8906 (2)	0.13468 (16)	0.4465 (2)	0.0783 (12)
F7	1.0275 (2)	0.1649 (2)	0.4951 (3)	0.1034 (16)
F8	1.0667 (2)	0.2801 (2)	0.5350 (2)	0.1072 (16)
F9	0.9658 (2)	0.36527 (19)	0.5256 (2)	0.0929 (14)
F10	0.82986 (19)	0.33607 (15)	0.4825 (2)	0.0694 (10)
C1	0.6453 (3)	−0.0121 (2)	0.4743 (3)	0.0388 (13)
C2	0.5697 (3)	−0.0089 (3)	0.4527 (3)	0.0452 (14)
H2	0.5426	0.0227	0.4620	0.054*
C3	0.5435 (3)	−0.0621 (3)	0.4147 (3)	0.0540 (16)
H3	0.4960	−0.0715	0.3947	0.065*
C4	0.6004 (4)	−0.0981 (3)	0.4121 (3)	0.0569 (17)
H4	0.5973	−0.1355	0.3898	0.068*
C5	0.6637 (3)	−0.0683 (2)	0.4488 (3)	0.0487 (15)
H5	0.7094	−0.0828	0.4552	0.058*
C6	0.6155 (3)	0.0680 (2)	0.3313 (3)	0.0346 (12)
C7	0.6712 (3)	0.0305 (2)	0.3224 (3)	0.0432 (14)
H7	0.7194	0.0373	0.3419	0.052*
C8	0.6407 (3)	−0.0184 (3)	0.2792 (3)	0.0515 (16)
H8	0.6654	−0.0496	0.2653	0.062*
C9	0.5674 (3)	−0.0127 (3)	0.2602 (3)	0.0533 (16)
H9	0.5349	−0.0396	0.2323	0.064*
C10	0.5510 (3)	0.0409 (2)	0.2904 (3)	0.0402 (13)
H10	0.5058	0.0562	0.2848	0.048*
C11	0.7905 (3)	0.0040 (2)	0.5516 (3)	0.0372 (12)
C12	0.8186 (3)	−0.0249 (2)	0.6149 (3)	0.0506 (15)
H12	0.7922	−0.0277	0.6468	0.061*
C13	0.8855 (3)	−0.0500 (3)	0.6319 (3)	0.0603 (18)
H13	0.9038	−0.0686	0.6756	0.072*
C14	0.9250 (3)	−0.0480 (3)	0.5857 (3)	0.0542 (16)
H14	0.9696	−0.0656	0.5971	0.065*
C15	0.8977 (3)	−0.0196 (3)	0.5223 (3)	0.0507 (15)
H15	0.9241	−0.0178	0.4902	0.061*
C16	0.8312 (3)	0.0065 (3)	0.5053 (3)	0.0479 (15)
H16	0.8137	0.0261	0.4621	0.057*
C17	0.6757 (3)	0.0412 (2)	0.6065 (3)	0.0414 (13)
C18	0.6745 (3)	0.0918 (3)	0.6460 (3)	0.0515 (15)
H18	0.6870	0.1293	0.6319	0.062*
C19	0.6541 (3)	0.0863 (4)	0.7087 (3)	0.0648 (18)
H19	0.6528	0.1205	0.7358	0.078*
C20	0.6365 (3)	0.0318 (4)	0.7293 (3)	0.0650 (19)
H20	0.6229	0.0288	0.7705	0.078*
C21	0.6381 (3)	−0.0191 (3)	0.6908 (4)	0.0668 (19)
H21	0.6275	−0.0568	0.7062	0.080*
C22	0.6560 (3)	−0.0137 (3)	0.6282 (3)	0.0577 (17)
H22	0.6546	−0.0478	0.6003	0.069*
C23	0.5504 (3)	0.1524 (2)	0.4103 (3)	0.0348 (12)
C24	0.5558 (3)	0.1655 (2)	0.4791 (3)	0.0463 (14)
H24	0.5993	0.1619	0.5132	0.056*
C25	0.4969 (4)	0.1842 (3)	0.4987 (4)	0.0628 (18)
H25	0.5012	0.1932	0.5457	0.075*
C26	0.4324 (4)	0.1895 (3)	0.4484 (4)	0.0671 (19)
H26	0.3927	0.2015	0.4612	0.080*
C27	0.4273 (3)	0.1767 (3)	0.3794 (4)	0.0649 (18)
H27	0.3836	0.1801	0.3454	0.078*
C28	0.4849 (3)	0.1592 (3)	0.3596 (3)	0.0511 (15)
H28	0.4805	0.1517	0.3122	0.061*
C29	0.6270 (3)	0.1936 (2)	0.3185 (3)	0.0382 (13)
C30	0.6488 (3)	0.1809 (3)	0.2598 (3)	0.0445 (14)
H30	0.6646	0.1421	0.2539	0.053*
C31	0.6475 (3)	0.2245 (3)	0.2097 (3)	0.0561 (17)
H31	0.6624	0.2152	0.1704	0.067*
C32	0.6238 (3)	0.2824 (3)	0.2182 (4)	0.0620 (18)
H32	0.6225	0.3121	0.1844	0.074*
C33	0.6024 (3)	0.2957 (3)	0.2762 (4)	0.0588 (18)
H33	0.5872	0.3347	0.2819	0.071*
C34	0.6031 (3)	0.2520 (2)	0.3271 (3)	0.0471 (15)
H34	0.5878	0.2614	0.3662	0.056*
C35	0.8349 (3)	0.2138 (2)	0.6154 (3)	0.0420 (13)
C36	0.9030 (3)	0.2347 (3)	0.6428 (3)	0.0468 (14)
C37	0.9195 (3)	0.2935 (3)	0.6645 (3)	0.0502 (15)
C38	0.8659 (4)	0.3338 (3)	0.6601 (3)	0.0527 (16)
C39	0.7967 (3)	0.3147 (3)	0.6354 (3)	0.0563 (16)
C40	0.7826 (3)	0.2565 (3)	0.6142 (3)	0.0513 (15)
C41	0.8544 (3)	0.2333 (2)	0.4645 (3)	0.0412 (13)
C42	0.9070 (3)	0.1916 (3)	0.4672 (3)	0.0516 (15)
C43	0.9781 (3)	0.2071 (3)	0.4921 (4)	0.0612 (18)
C44	0.9976 (3)	0.2645 (4)	0.5115 (4)	0.0639 (19)
C45	0.9474 (4)	0.3077 (3)	0.5066 (3)	0.0635 (19)
C46	0.8774 (3)	0.2920 (3)	0.4846 (3)	0.0453 (14)
Pt2	0.372198 (10)	0.386613 (9)	0.626326 (10)	0.03166 (6)
Fe2	0.60739 (4)	−0.01482 (3)	0.36821 (4)	0.03734 (18)
S3	0.43158 (8)	0.29486 (6)	0.61708 (8)	0.0477 (4)
S4	0.42426 (8)	0.38830 (6)	0.75055 (7)	0.0454 (4)
P3	0.33145 (7)	0.48088 (6)	0.63851 (7)	0.0312 (3)
P4	0.30609 (7)	0.37185 (6)	0.51091 (7)	0.0351 (3)
F11	0.51871 (18)	0.41557 (17)	0.6348 (2)	0.0701 (10)
F12	0.6527 (2)	0.4312 (2)	0.7056 (2)	0.0908 (13)
F13	0.7336 (2)	0.3366 (2)	0.7709 (2)	0.1076 (16)
F14	0.6760 (3)	0.2251 (2)	0.7611 (3)	0.140 (2)
F15	0.5391 (2)	0.20736 (18)	0.6918 (2)	0.0968 (15)
F16	0.54859 (19)	0.31576 (17)	0.83277 (19)	0.0707 (10)
F17	0.5510 (2)	0.20056 (19)	0.8729 (3)	0.1062 (16)
F18	0.4303 (3)	0.13497 (17)	0.8452 (2)	0.1042 (16)
F19	0.3063 (2)	0.1864 (2)	0.7745 (3)	0.1036 (15)
F20	0.30232 (19)	0.30206 (18)	0.7328 (2)	0.0773 (12)
C47	0.2378 (3)	0.4822 (2)	0.6272 (3)	0.0333 (12)
C48	0.1862 (3)	0.5290 (2)	0.6027 (3)	0.0446 (14)
H48	0.1954	0.5689	0.5929	0.054*
C49	0.1191 (3)	0.5037 (3)	0.5960 (3)	0.0503 (15)
H49	0.0762	0.5241	0.5804	0.060*
C50	0.1275 (3)	0.4422 (3)	0.6170 (3)	0.0484 (15)
H50	0.0914	0.4155	0.6179	0.058*
C51	0.2003 (3)	0.4288 (2)	0.6361 (3)	0.0390 (13)
H51	0.2206	0.3915	0.6520	0.047*
C52	0.2240 (3)	0.4138 (2)	0.4766 (3)	0.0370 (12)
C53	0.2132 (3)	0.4755 (3)	0.4548 (3)	0.0438 (14)
H53	0.2487	0.5034	0.4557	0.053*
C54	0.1398 (3)	0.4871 (3)	0.4316 (3)	0.0537 (16)
H54	0.1187	0.5239	0.4147	0.064*
C55	0.1040 (3)	0.4333 (3)	0.4386 (3)	0.0535 (16)
H55	0.0553	0.4286	0.4275	0.064*
C56	0.1549 (3)	0.3878 (3)	0.4652 (3)	0.0437 (14)
H56	0.1453	0.3478	0.4739	0.052*
C57	0.3525 (3)	0.5353 (2)	0.5789 (3)	0.0344 (12)
C58	0.3309 (3)	0.5952 (2)	0.5775 (3)	0.0419 (13)
H58	0.3055	0.6080	0.6078	0.050*
C59	0.3469 (3)	0.6363 (3)	0.5313 (3)	0.0520 (16)
H59	0.3311	0.6761	0.5298	0.062*
C60	0.3859 (3)	0.6180 (3)	0.4881 (3)	0.0609 (18)
H60	0.3972	0.6457	0.4576	0.073*
C61	0.4087 (3)	0.5589 (3)	0.4892 (3)	0.0600 (17)
H61	0.4345	0.5466	0.4590	0.072*
C62	0.3931 (3)	0.5178 (3)	0.5355 (3)	0.0452 (14)
H62	0.4098	0.4783	0.5374	0.054*
C63	0.3723 (3)	0.5174 (2)	0.7231 (3)	0.0359 (12)
C64	0.3355 (3)	0.5285 (3)	0.7711 (3)	0.0532 (16)
H64	0.2879	0.5181	0.7603	0.064*
C65	0.3688 (4)	0.5550 (3)	0.8352 (3)	0.068 (2)
H65	0.3435	0.5629	0.8672	0.082*
C66	0.4384 (4)	0.5696 (3)	0.8519 (3)	0.068 (2)
H66	0.4605	0.5865	0.8959	0.081*
C67	0.4763 (4)	0.5599 (2)	0.8053 (3)	0.0573 (17)
H67	0.5237	0.5710	0.8169	0.069*
C68	0.4440 (3)	0.5332 (2)	0.7401 (3)	0.0430 (14)
H68	0.4697	0.5259	0.7082	0.052*
C69	0.2716 (3)	0.2947 (2)	0.5038 (3)	0.0396 (13)
C70	0.2529 (3)	0.2624 (3)	0.4418 (3)	0.0570 (17)
H70	0.2634	0.2783	0.4024	0.068*
C71	0.2190 (4)	0.2070 (3)	0.4363 (4)	0.072 (2)
H71	0.2061	0.1865	0.3934	0.086*
C72	0.2046 (3)	0.1825 (3)	0.4938 (4)	0.067 (2)
H72	0.1825	0.1450	0.4905	0.080*
C73	0.2226 (3)	0.2135 (3)	0.5566 (4)	0.0641 (18)
H73	0.2115	0.1975	0.5956	0.077*
C74	0.2574 (3)	0.2688 (3)	0.5622 (3)	0.0538 (16)
H74	0.2712	0.2887	0.6055	0.065*
C75	0.3463 (3)	0.3776 (2)	0.4390 (3)	0.0428 (14)
C76	0.4149 (3)	0.3611 (3)	0.4478 (3)	0.0655 (19)
H76	0.4428	0.3501	0.4926	0.079*
C77	0.4440 (4)	0.3602 (4)	0.3925 (4)	0.087 (3)
H77	0.4905	0.3474	0.4000	0.105*
C78	0.4053 (4)	0.3780 (4)	0.3268 (4)	0.086 (3)
H78	0.4252	0.3773	0.2895	0.103*
C79	0.3374 (5)	0.3967 (4)	0.3159 (4)	0.105 (3)
H79	0.3108	0.4096	0.2714	0.126*
C80	0.3080 (4)	0.3965 (4)	0.3721 (4)	0.089 (3)
H80	0.2615	0.4093	0.3645	0.107*
C81	0.5210 (3)	0.3104 (3)	0.6611 (3)	0.0522 (16)
C82	0.5548 (3)	0.3660 (3)	0.6671 (3)	0.0581 (17)
C83	0.6243 (4)	0.3752 (4)	0.7023 (4)	0.0647 (19)
C84	0.6647 (4)	0.3278 (4)	0.7349 (4)	0.077 (2)
C85	0.6359 (4)	0.2720 (4)	0.7300 (4)	0.083 (2)
C86	0.5651 (4)	0.2639 (3)	0.6940 (4)	0.071 (2)
C87	0.4257 (3)	0.3122 (2)	0.7783 (3)	0.0405 (13)
C88	0.4871 (3)	0.2845 (3)	0.8161 (3)	0.0486 (15)
C89	0.4894 (4)	0.2248 (3)	0.8372 (3)	0.0645 (19)
C90	0.4286 (5)	0.1923 (3)	0.8236 (4)	0.067 (2)
C91	0.3672 (4)	0.2187 (3)	0.7882 (3)	0.0642 (19)
C92	0.3653 (3)	0.2775 (3)	0.7672 (3)	0.0509 (15)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.03010 (12)	0.03124 (12)	0.03399 (12)	−0.00058 (8)	0.00332 (9)	0.00300 (9)
Fe1	0.0321 (4)	0.0388 (4)	0.0403 (5)	0.0021 (3)	0.0086 (4)	−0.0013 (3)
S1	0.0418 (9)	0.0395 (8)	0.0452 (9)	−0.0017 (6)	−0.0053 (7)	0.0016 (6)
S2	0.0408 (9)	0.0515 (9)	0.0626 (11)	−0.0106 (7)	−0.0068 (8)	0.0232 (8)
P1	0.0374 (8)	0.0344 (8)	0.0320 (8)	−0.0001 (6)	0.0077 (6)	0.0039 (6)
P2	0.0314 (7)	0.0309 (7)	0.0309 (7)	0.0021 (6)	0.0054 (6)	0.0009 (6)
F1	0.041 (2)	0.064 (2)	0.076 (3)	0.0068 (17)	−0.0013 (18)	−0.0134 (19)
F2	0.050 (2)	0.076 (3)	0.089 (3)	−0.0130 (19)	−0.004 (2)	−0.020 (2)
F3	0.094 (3)	0.052 (2)	0.072 (3)	−0.001 (2)	0.009 (2)	−0.0172 (19)
F4	0.075 (3)	0.081 (3)	0.087 (3)	0.030 (2)	0.017 (2)	−0.012 (2)
F5	0.039 (2)	0.074 (3)	0.098 (3)	0.0009 (18)	0.011 (2)	−0.006 (2)
F6	0.102 (3)	0.046 (2)	0.096 (3)	0.000 (2)	0.044 (3)	−0.002 (2)
F7	0.075 (3)	0.121 (4)	0.129 (4)	0.039 (3)	0.052 (3)	0.043 (3)
F8	0.045 (3)	0.169 (5)	0.096 (3)	−0.027 (3)	0.002 (2)	0.032 (3)
F9	0.094 (3)	0.081 (3)	0.094 (3)	−0.046 (2)	0.012 (3)	−0.011 (2)
F10	0.070 (3)	0.045 (2)	0.091 (3)	0.0004 (18)	0.020 (2)	0.0072 (19)
C1	0.040 (3)	0.036 (3)	0.040 (3)	−0.002 (2)	0.011 (3)	0.001 (2)
C2	0.041 (3)	0.051 (4)	0.046 (4)	−0.007 (3)	0.017 (3)	0.009 (3)
C3	0.052 (4)	0.053 (4)	0.051 (4)	−0.020 (3)	0.005 (3)	0.008 (3)
C4	0.079 (5)	0.034 (3)	0.053 (4)	−0.013 (3)	0.012 (4)	0.003 (3)
C5	0.053 (4)	0.034 (3)	0.059 (4)	0.002 (3)	0.016 (3)	0.008 (3)
C6	0.036 (3)	0.032 (3)	0.036 (3)	0.003 (2)	0.010 (2)	0.004 (2)
C7	0.047 (4)	0.044 (3)	0.044 (3)	−0.003 (3)	0.020 (3)	0.000 (3)
C8	0.066 (5)	0.046 (4)	0.050 (4)	0.000 (3)	0.030 (3)	−0.009 (3)
C9	0.065 (4)	0.053 (4)	0.039 (4)	−0.013 (3)	0.009 (3)	−0.011 (3)
C10	0.039 (3)	0.045 (3)	0.031 (3)	−0.004 (2)	0.002 (2)	−0.001 (2)
C11	0.035 (3)	0.034 (3)	0.038 (3)	−0.001 (2)	0.004 (3)	0.003 (2)
C12	0.050 (4)	0.049 (4)	0.054 (4)	0.006 (3)	0.016 (3)	0.013 (3)
C13	0.052 (4)	0.058 (4)	0.059 (4)	0.016 (3)	−0.002 (3)	0.014 (3)
C14	0.042 (4)	0.049 (4)	0.063 (4)	0.012 (3)	0.001 (3)	−0.005 (3)
C15	0.041 (4)	0.053 (4)	0.059 (4)	0.005 (3)	0.015 (3)	−0.008 (3)
C16	0.045 (4)	0.052 (4)	0.040 (3)	0.004 (3)	0.002 (3)	0.002 (3)
C17	0.038 (3)	0.049 (4)	0.035 (3)	−0.002 (3)	0.008 (3)	0.004 (3)
C18	0.048 (4)	0.059 (4)	0.043 (4)	0.006 (3)	0.006 (3)	0.002 (3)
C19	0.061 (4)	0.089 (5)	0.044 (4)	0.001 (4)	0.015 (3)	−0.013 (4)
C20	0.060 (5)	0.094 (6)	0.047 (4)	−0.002 (4)	0.026 (3)	0.007 (4)
C21	0.065 (5)	0.077 (5)	0.065 (5)	−0.007 (4)	0.029 (4)	0.019 (4)
C22	0.066 (4)	0.059 (4)	0.051 (4)	−0.007 (3)	0.020 (3)	0.010 (3)
C23	0.033 (3)	0.037 (3)	0.035 (3)	0.003 (2)	0.011 (2)	−0.002 (2)
C24	0.048 (4)	0.046 (3)	0.045 (4)	0.009 (3)	0.013 (3)	−0.002 (3)
C25	0.073 (5)	0.073 (5)	0.055 (4)	0.013 (4)	0.040 (4)	0.004 (3)
C26	0.054 (5)	0.064 (5)	0.091 (6)	0.017 (3)	0.034 (4)	0.001 (4)
C27	0.041 (4)	0.079 (5)	0.070 (5)	0.008 (3)	0.010 (3)	−0.008 (4)
C28	0.042 (4)	0.057 (4)	0.051 (4)	0.005 (3)	0.008 (3)	−0.007 (3)
C29	0.031 (3)	0.036 (3)	0.042 (3)	−0.004 (2)	0.002 (3)	0.007 (2)
C30	0.041 (3)	0.049 (3)	0.045 (4)	0.009 (3)	0.015 (3)	0.011 (3)
C31	0.049 (4)	0.073 (5)	0.049 (4)	0.012 (3)	0.018 (3)	0.023 (3)
C32	0.063 (4)	0.058 (4)	0.063 (5)	0.004 (3)	0.015 (4)	0.030 (3)
C33	0.058 (4)	0.034 (3)	0.071 (5)	0.003 (3)	−0.004 (4)	0.009 (3)
C34	0.054 (4)	0.041 (3)	0.040 (3)	0.006 (3)	0.002 (3)	0.002 (3)
C35	0.043 (4)	0.044 (3)	0.034 (3)	0.002 (3)	0.004 (3)	0.004 (2)
C36	0.042 (4)	0.052 (4)	0.042 (3)	0.006 (3)	0.005 (3)	−0.003 (3)
C37	0.042 (4)	0.059 (4)	0.038 (3)	−0.006 (3)	−0.005 (3)	−0.012 (3)
C38	0.066 (5)	0.043 (4)	0.044 (4)	−0.002 (3)	0.008 (3)	−0.007 (3)
C39	0.057 (4)	0.058 (4)	0.052 (4)	0.016 (3)	0.013 (3)	0.000 (3)
C40	0.036 (4)	0.060 (4)	0.051 (4)	0.000 (3)	0.000 (3)	0.002 (3)
C41	0.036 (3)	0.045 (3)	0.039 (3)	−0.007 (3)	0.006 (3)	0.010 (3)
C42	0.061 (4)	0.049 (4)	0.048 (4)	−0.001 (3)	0.022 (3)	0.006 (3)
C43	0.048 (4)	0.072 (5)	0.070 (5)	0.019 (4)	0.028 (4)	0.020 (4)
C44	0.036 (4)	0.090 (6)	0.060 (4)	−0.015 (4)	0.005 (3)	0.016 (4)
C45	0.066 (5)	0.060 (4)	0.058 (4)	−0.029 (4)	0.009 (4)	0.003 (3)
C46	0.041 (4)	0.044 (4)	0.051 (4)	−0.004 (3)	0.013 (3)	0.010 (3)
Pt2	0.03272 (12)	0.03065 (11)	0.02959 (12)	0.00211 (8)	0.00581 (9)	−0.00047 (8)
Fe2	0.0384 (5)	0.0340 (4)	0.0393 (5)	−0.0037 (3)	0.0108 (4)	−0.0007 (3)
S3	0.0498 (9)	0.0456 (9)	0.0431 (9)	0.0155 (7)	0.0061 (7)	−0.0049 (7)
S4	0.0623 (10)	0.0345 (8)	0.0332 (8)	0.0027 (7)	0.0041 (7)	0.0010 (6)
P3	0.0327 (8)	0.0292 (7)	0.0310 (7)	−0.0012 (5)	0.0079 (6)	0.0003 (5)
P4	0.0326 (8)	0.0397 (8)	0.0316 (8)	0.0002 (6)	0.0072 (6)	−0.0038 (6)
F11	0.055 (2)	0.079 (3)	0.080 (3)	0.002 (2)	0.025 (2)	0.023 (2)
F12	0.066 (3)	0.123 (4)	0.087 (3)	−0.021 (3)	0.028 (2)	−0.005 (3)
F13	0.058 (3)	0.175 (5)	0.074 (3)	0.013 (3)	−0.007 (2)	−0.019 (3)
F14	0.117 (4)	0.124 (4)	0.126 (4)	0.072 (3)	−0.050 (3)	−0.020 (3)
F15	0.109 (4)	0.062 (3)	0.092 (3)	0.034 (2)	−0.014 (3)	−0.011 (2)
F16	0.055 (2)	0.077 (3)	0.065 (2)	−0.005 (2)	−0.0085 (19)	0.010 (2)
F17	0.099 (4)	0.079 (3)	0.116 (4)	0.038 (3)	−0.009 (3)	0.034 (3)
F18	0.169 (5)	0.041 (2)	0.099 (3)	0.003 (3)	0.035 (3)	0.017 (2)
F19	0.099 (4)	0.089 (3)	0.116 (4)	−0.043 (3)	0.021 (3)	0.018 (3)
F20	0.046 (2)	0.095 (3)	0.088 (3)	0.001 (2)	0.015 (2)	0.029 (2)
C47	0.034 (3)	0.033 (3)	0.034 (3)	−0.001 (2)	0.011 (2)	−0.002 (2)
C48	0.049 (4)	0.041 (3)	0.043 (3)	0.004 (3)	0.013 (3)	−0.003 (3)
C49	0.034 (3)	0.063 (4)	0.057 (4)	0.009 (3)	0.018 (3)	−0.012 (3)
C50	0.042 (4)	0.057 (4)	0.052 (4)	−0.007 (3)	0.023 (3)	−0.005 (3)
C51	0.040 (3)	0.040 (3)	0.038 (3)	−0.003 (2)	0.014 (3)	−0.001 (2)
C52	0.033 (3)	0.043 (3)	0.031 (3)	0.004 (2)	0.003 (2)	−0.002 (2)
C53	0.044 (4)	0.052 (4)	0.034 (3)	−0.001 (3)	0.009 (3)	0.006 (3)
C54	0.057 (4)	0.063 (4)	0.033 (3)	0.016 (3)	−0.001 (3)	0.011 (3)
C55	0.041 (4)	0.065 (4)	0.048 (4)	0.004 (3)	0.001 (3)	−0.002 (3)
C56	0.037 (3)	0.045 (3)	0.044 (3)	0.001 (3)	0.003 (3)	−0.009 (3)
C57	0.035 (3)	0.036 (3)	0.030 (3)	−0.001 (2)	0.005 (2)	−0.002 (2)
C58	0.038 (3)	0.042 (3)	0.045 (3)	0.003 (2)	0.010 (3)	0.001 (3)
C59	0.056 (4)	0.041 (3)	0.053 (4)	−0.002 (3)	0.006 (3)	0.013 (3)
C60	0.062 (4)	0.068 (5)	0.056 (4)	−0.011 (3)	0.022 (4)	0.024 (3)
C61	0.066 (5)	0.068 (5)	0.058 (4)	−0.008 (4)	0.035 (4)	0.000 (3)
C62	0.037 (3)	0.047 (4)	0.050 (4)	−0.005 (3)	0.010 (3)	0.002 (3)
C63	0.044 (3)	0.024 (3)	0.035 (3)	0.002 (2)	0.003 (3)	0.007 (2)
C64	0.066 (4)	0.054 (4)	0.041 (4)	0.002 (3)	0.019 (3)	−0.003 (3)
C65	0.094 (6)	0.066 (5)	0.042 (4)	0.004 (4)	0.015 (4)	−0.009 (3)
C66	0.102 (6)	0.041 (4)	0.042 (4)	−0.002 (4)	−0.007 (4)	−0.004 (3)
C67	0.071 (5)	0.032 (3)	0.059 (4)	−0.002 (3)	0.003 (4)	0.001 (3)
C68	0.052 (4)	0.032 (3)	0.042 (3)	−0.006 (3)	0.010 (3)	0.003 (2)
C69	0.030 (3)	0.038 (3)	0.048 (4)	0.004 (2)	0.007 (3)	−0.008 (3)
C70	0.058 (4)	0.054 (4)	0.050 (4)	−0.005 (3)	0.002 (3)	−0.018 (3)
C71	0.056 (5)	0.070 (5)	0.076 (5)	0.001 (4)	−0.004 (4)	−0.033 (4)
C72	0.044 (4)	0.040 (4)	0.108 (6)	0.003 (3)	0.010 (4)	−0.012 (4)
C73	0.068 (5)	0.038 (4)	0.086 (5)	−0.001 (3)	0.023 (4)	0.001 (3)
C74	0.058 (4)	0.042 (4)	0.059 (4)	−0.009 (3)	0.014 (3)	−0.005 (3)
C75	0.037 (3)	0.053 (4)	0.038 (3)	−0.006 (3)	0.009 (3)	−0.007 (3)
C76	0.038 (4)	0.117 (6)	0.041 (4)	0.012 (4)	0.010 (3)	0.005 (4)
C77	0.042 (4)	0.162 (8)	0.066 (5)	0.003 (5)	0.027 (4)	0.001 (5)
C78	0.064 (5)	0.152 (8)	0.050 (5)	−0.012 (5)	0.030 (4)	−0.013 (5)
C79	0.086 (6)	0.188 (10)	0.047 (5)	0.033 (6)	0.031 (4)	0.020 (5)
C80	0.054 (5)	0.164 (8)	0.051 (5)	0.027 (5)	0.017 (4)	0.013 (5)
C81	0.054 (4)	0.060 (4)	0.040 (4)	0.020 (3)	0.010 (3)	−0.005 (3)
C82	0.053 (4)	0.073 (5)	0.052 (4)	0.014 (4)	0.022 (3)	0.003 (3)
C83	0.052 (4)	0.092 (6)	0.053 (4)	0.006 (4)	0.021 (4)	0.001 (4)
C84	0.042 (4)	0.123 (7)	0.054 (5)	0.018 (5)	−0.004 (3)	−0.019 (5)
C85	0.071 (6)	0.090 (6)	0.069 (5)	0.039 (5)	−0.010 (4)	−0.010 (4)
C86	0.081 (5)	0.053 (4)	0.065 (5)	0.024 (4)	0.001 (4)	−0.016 (4)
C87	0.051 (4)	0.037 (3)	0.032 (3)	0.005 (3)	0.009 (3)	0.001 (2)
C88	0.054 (4)	0.047 (4)	0.037 (3)	0.003 (3)	0.002 (3)	0.005 (3)
C89	0.069 (5)	0.055 (4)	0.054 (4)	0.019 (4)	−0.006 (4)	0.015 (3)
C90	0.108 (7)	0.035 (4)	0.053 (4)	0.004 (4)	0.016 (4)	0.010 (3)
C91	0.087 (6)	0.049 (4)	0.054 (4)	−0.022 (4)	0.016 (4)	−0.001 (3)
C92	0.056 (4)	0.055 (4)	0.041 (4)	0.001 (3)	0.012 (3)	0.006 (3)

Geometric parameters (Å, º)

Pt1—P2	2.2833 (13)	C36—C37	1.377 (8)
Pt1—P1	2.2951 (13)	C37—C38	1.366 (8)
Pt1—S2	2.3495 (14)	C38—C39	1.378 (8)
Pt1—S1	2.3783 (14)	C39—C40	1.354 (8)
Fe1—C47	1.995 (5)	C41—C42	1.378 (8)
Fe1—C52	2.021 (5)	C41—C46	1.392 (7)
Fe1—C51	2.023 (5)	C42—C43	1.391 (9)
Fe1—C48	2.029 (5)	C43—C44	1.348 (9)
Fe1—C53	2.031 (5)	C44—C45	1.359 (9)
Fe1—C56	2.035 (5)	C45—C46	1.367 (8)
Fe1—C55	2.048 (6)	Pt2—P3	2.2696 (13)
Fe1—C54	2.055 (5)	Pt2—P4	2.3006 (14)
Fe1—C49	2.057 (5)	Pt2—S4	2.3724 (14)
Fe1—C50	2.070 (5)	Pt2—S3	2.3744 (14)
S1—C35	1.744 (5)	S3—C81	1.762 (6)
S2—C41	1.752 (5)	S4—C87	1.766 (5)
P1—C1	1.812 (5)	P3—C47	1.798 (5)
P1—C11	1.826 (5)	P3—C57	1.814 (5)
P1—C17	1.830 (5)	P3—C63	1.822 (5)
P2—C6	1.800 (5)	P4—C52	1.819 (5)
P2—C29	1.816 (5)	P4—C75	1.823 (6)
P2—C23	1.823 (5)	P4—C69	1.826 (5)
F1—C36	1.338 (6)	F11—C82	1.361 (7)
F2—C37	1.334 (6)	F12—C83	1.352 (8)
F3—C38	1.348 (6)	F13—C84	1.355 (7)
F4—C39	1.338 (6)	F14—C85	1.339 (8)
F5—C40	1.352 (6)	F15—C86	1.346 (8)
F6—C42	1.332 (6)	F16—C88	1.351 (6)
F7—C43	1.338 (7)	F17—C89	1.330 (7)
F8—C44	1.352 (7)	F18—C90	1.333 (7)
F9—C45	1.345 (7)	F19—C91	1.356 (7)
F10—C46	1.345 (6)	F20—C92	1.347 (7)
C1—C5	1.426 (7)	C47—C51	1.429 (7)
C1—C2	1.430 (7)	C47—C48	1.434 (7)
C1—Fe2	2.014 (5)	C48—C49	1.409 (7)
C2—C3	1.408 (8)	C48—H48	0.9300
C2—Fe2	2.019 (5)	C49—C50	1.414 (8)
C2—H2	0.9300	C49—H49	0.9300
C3—C4	1.389 (8)	C50—C51	1.409 (7)
C3—Fe2	2.048 (6)	C50—H50	0.9300
C3—H3	0.9300	C51—H51	0.9300
C4—C5	1.414 (8)	C52—C53	1.426 (7)
C4—Fe2	2.054 (6)	C52—C56	1.437 (7)
C4—H4	0.9300	C53—C54	1.412 (7)
C5—Fe2	2.036 (6)	C53—H53	0.9300
C5—H5	0.9300	C54—C55	1.409 (8)
C6—C7	1.428 (7)	C54—H54	0.9300
C6—C10	1.428 (7)	C55—C56	1.410 (7)
C6—Fe2	1.993 (5)	C55—H55	0.9300
C7—C8	1.400 (7)	C56—H56	0.9300
C7—Fe2	2.017 (5)	C57—C58	1.387 (7)
C7—H7	0.9300	C57—C62	1.388 (7)
C8—C9	1.392 (8)	C58—C59	1.385 (7)
C8—Fe2	2.051 (6)	C58—H58	0.9300
C8—H8	0.9300	C59—C60	1.366 (8)
C9—C10	1.406 (7)	C59—H59	0.9300
C9—Fe2	2.052 (6)	C60—C61	1.379 (8)
C9—H9	0.9300	C60—H60	0.9300
C10—Fe2	2.032 (5)	C61—C62	1.385 (8)
C10—H10	0.9300	C61—H61	0.9300
C11—C12	1.371 (7)	C62—H62	0.9300
C11—C16	1.383 (7)	C63—C64	1.374 (7)
C12—C13	1.381 (8)	C63—C68	1.400 (7)
C12—H12	0.9300	C64—C65	1.378 (8)
C13—C14	1.364 (8)	C64—H64	0.9300
C13—H13	0.9300	C65—C66	1.355 (9)
C14—C15	1.364 (8)	C65—H65	0.9300
C14—H14	0.9300	C66—C67	1.363 (9)
C15—C16	1.383 (7)	C66—H66	0.9300
C15—H15	0.9300	C67—C68	1.393 (8)
C16—H16	0.9300	C67—H67	0.9300
C17—C18	1.367 (7)	C68—H68	0.9300
C17—C22	1.378 (7)	C69—C70	1.373 (7)
C18—C19	1.415 (8)	C69—C74	1.386 (8)
C18—H18	0.9300	C70—C71	1.385 (9)
C19—C20	1.349 (9)	C70—H70	0.9300
C19—H19	0.9300	C71—C72	1.361 (10)
C20—C21	1.364 (9)	C71—H71	0.9300
C20—H20	0.9300	C72—C73	1.372 (9)
C21—C22	1.386 (8)	C72—H72	0.9300
C21—H21	0.9300	C73—C74	1.389 (8)
C22—H22	0.9300	C73—H73	0.9300
C23—C24	1.364 (7)	C74—H74	0.9300
C23—C28	1.397 (7)	C75—C76	1.365 (8)
C24—C25	1.390 (8)	C75—C80	1.383 (8)
C24—H24	0.9300	C76—C77	1.374 (8)
C25—C26	1.376 (9)	C76—H76	0.9300
C25—H25	0.9300	C77—C78	1.360 (10)
C26—C27	1.367 (9)	C77—H77	0.9300
C26—H26	0.9300	C78—C79	1.361 (10)
C27—C28	1.362 (8)	C78—H78	0.9300
C27—H27	0.9300	C79—C80	1.394 (9)
C28—H28	0.9300	C79—H79	0.9300
C29—C30	1.379 (7)	C80—H80	0.9300
C29—C34	1.400 (7)	C81—C86	1.381 (8)
C30—C31	1.376 (7)	C81—C82	1.386 (9)
C30—H30	0.9300	C82—C83	1.362 (9)
C31—C32	1.389 (8)	C83—C84	1.360 (10)
C31—H31	0.9300	C84—C85	1.348 (11)
C32—C33	1.363 (9)	C85—C86	1.386 (10)
C32—H32	0.9300	C87—C88	1.372 (7)
C33—C34	1.391 (8)	C87—C92	1.380 (8)
C33—H33	0.9300	C88—C89	1.380 (8)
C34—H34	0.9300	C89—C90	1.356 (9)
C35—C36	1.376 (8)	C90—C91	1.345 (9)
C35—C40	1.396 (8)	C91—C92	1.360 (8)
P2—Pt1—P1	97.82 (5)	P3—Pt2—P4	96.79 (5)
P2—Pt1—S2	85.18 (5)	P3—Pt2—S4	86.36 (5)
P1—Pt1—S2	171.16 (6)	P4—Pt2—S4	168.65 (5)
P2—Pt1—S1	174.45 (5)	P3—Pt2—S3	171.50 (5)
P1—Pt1—S1	82.87 (5)	P4—Pt2—S3	87.36 (5)
S2—Pt1—S1	94.95 (5)	S4—Pt2—S3	90.99 (5)
C47—Fe1—C52	109.4 (2)	C6—Fe2—C1	108.0 (2)
C47—Fe1—C51	41.65 (19)	C6—Fe2—C7	41.7 (2)
C52—Fe1—C51	111.1 (2)	C1—Fe2—C7	111.1 (2)
C47—Fe1—C48	41.7 (2)	C6—Fe2—C2	109.3 (2)
C52—Fe1—C48	138.2 (2)	C1—Fe2—C2	41.5 (2)
C51—Fe1—C48	69.3 (2)	C7—Fe2—C2	140.0 (2)
C47—Fe1—C53	110.3 (2)	C6—Fe2—C10	41.55 (19)
C52—Fe1—C53	41.2 (2)	C1—Fe2—C10	136.6 (2)
C51—Fe1—C53	139.9 (2)	C7—Fe2—C10	68.7 (2)
C48—Fe1—C53	110.5 (2)	C2—Fe2—C10	109.5 (2)
C47—Fe1—C56	138.9 (2)	C6—Fe2—C5	137.3 (2)
C52—Fe1—C56	41.5 (2)	C1—Fe2—C5	41.2 (2)
C51—Fe1—C56	111.8 (2)	C7—Fe2—C5	111.6 (2)
C48—Fe1—C56	178.9 (2)	C2—Fe2—C5	68.8 (2)
C53—Fe1—C56	68.6 (2)	C10—Fe2—C5	177.9 (2)
C47—Fe1—C55	178.3 (2)	C6—Fe2—C3	139.2 (2)
C52—Fe1—C55	69.1 (2)	C1—Fe2—C3	68.9 (2)
C51—Fe1—C55	139.4 (2)	C7—Fe2—C3	179.1 (2)
C48—Fe1—C55	138.9 (2)	C2—Fe2—C3	40.5 (2)
C53—Fe1—C55	68.1 (2)	C10—Fe2—C3	112.0 (2)
C56—Fe1—C55	40.4 (2)	C5—Fe2—C3	67.7 (2)
C47—Fe1—C54	138.8 (2)	C6—Fe2—C8	69.0 (2)
C52—Fe1—C54	68.9 (2)	C1—Fe2—C8	141.3 (2)
C51—Fe1—C54	179.6 (3)	C7—Fe2—C8	40.3 (2)
C48—Fe1—C54	111.0 (2)	C2—Fe2—C8	176.8 (2)
C53—Fe1—C54	40.4 (2)	C10—Fe2—C8	67.4 (2)
C56—Fe1—C54	67.9 (2)	C5—Fe2—C8	114.3 (2)
C55—Fe1—C54	40.2 (2)	C3—Fe2—C8	139.2 (2)
C47—Fe1—C49	68.9 (2)	C6—Fe2—C9	69.2 (2)
C52—Fe1—C49	178.3 (2)	C1—Fe2—C9	176.8 (2)
C51—Fe1—C49	67.9 (2)	C7—Fe2—C9	67.9 (2)
C48—Fe1—C49	40.3 (2)	C2—Fe2—C9	137.4 (2)
C53—Fe1—C49	138.7 (2)	C10—Fe2—C9	40.3 (2)
C56—Fe1—C49	140.0 (2)	C5—Fe2—C9	141.9 (2)
C55—Fe1—C49	112.5 (2)	C3—Fe2—C9	112.2 (2)
C54—Fe1—C49	112.1 (2)	C8—Fe2—C9	39.7 (2)
C47—Fe1—C50	69.0 (2)	C6—Fe2—C4	176.6 (2)
C52—Fe1—C50	140.0 (2)	C1—Fe2—C4	68.7 (2)
C51—Fe1—C50	40.2 (2)	C7—Fe2—C4	139.5 (3)
C48—Fe1—C50	68.2 (2)	C2—Fe2—C4	67.8 (2)
C53—Fe1—C50	178.7 (2)	C10—Fe2—C4	140.6 (2)
C56—Fe1—C50	112.7 (2)	C5—Fe2—C4	40.4 (2)
C55—Fe1—C50	112.6 (2)	C3—Fe2—C4	39.6 (2)
C54—Fe1—C50	139.5 (2)	C8—Fe2—C4	113.9 (2)
C49—Fe1—C50	40.1 (2)	C9—Fe2—C4	114.0 (2)
C35—S1—Pt1	109.06 (19)	C81—S3—Pt2	104.0 (2)
C41—S2—Pt1	112.09 (18)	C87—S4—Pt2	105.65 (18)
C1—P1—C11	103.4 (2)	C47—P3—C57	109.3 (2)
C1—P1—C17	99.0 (2)	C47—P3—C63	105.9 (2)
C11—P1—C17	105.0 (2)	C57—P3—C63	100.3 (2)
C1—P1—Pt1	121.89 (17)	C47—P3—Pt2	112.64 (16)
C11—P1—Pt1	104.99 (17)	C57—P3—Pt2	112.61 (17)
C17—P1—Pt1	120.44 (18)	C63—P3—Pt2	115.30 (16)
C6—P2—C29	101.5 (2)	C52—P4—C75	102.5 (2)
C6—P2—C23	109.2 (2)	C52—P4—C69	100.0 (2)
C29—P2—C23	101.9 (2)	C75—P4—C69	104.1 (2)
C6—P2—Pt1	115.39 (17)	C52—P4—Pt2	119.09 (17)
C29—P2—Pt1	116.98 (17)	C75—P4—Pt2	120.89 (18)
C23—P2—Pt1	110.64 (17)	C69—P4—Pt2	107.48 (19)
C5—C1—C2	106.7 (5)	C51—C47—C48	107.1 (5)
C5—C1—P1	126.8 (4)	C51—C47—P3	121.5 (4)
C2—C1—P1	126.5 (4)	C48—C47—P3	131.1 (4)
C5—C1—Fe2	70.2 (3)	C51—C47—Fe1	70.2 (3)
C2—C1—Fe2	69.4 (3)	C48—C47—Fe1	70.4 (3)
P1—C1—Fe2	127.2 (3)	P3—C47—Fe1	119.8 (3)
C3—C2—C1	108.1 (5)	C49—C48—C47	107.5 (5)
C3—C2—Fe2	70.9 (3)	C49—C48—Fe1	70.9 (3)
C1—C2—Fe2	69.1 (3)	C47—C48—Fe1	67.9 (3)
C3—C2—H2	126.0	C49—C48—H48	126.2
C1—C2—H2	126.0	C47—C48—H48	126.2
Fe2—C2—H2	125.7	Fe1—C48—H48	126.6
C4—C3—C2	108.7 (5)	C48—C49—C50	109.1 (5)
C4—C3—Fe2	70.5 (3)	C48—C49—Fe1	68.8 (3)
C2—C3—Fe2	68.6 (3)	C50—C49—Fe1	70.4 (3)
C4—C3—H3	125.6	C48—C49—H49	125.5
C2—C3—H3	125.6	C50—C49—H49	125.5
Fe2—C3—H3	126.8	Fe1—C49—H49	126.9
C3—C4—C5	108.6 (5)	C51—C50—C49	107.7 (5)
C3—C4—Fe2	70.0 (3)	C51—C50—Fe1	68.1 (3)
C5—C4—Fe2	69.1 (3)	C49—C50—Fe1	69.5 (3)
C3—C4—H4	125.7	C51—C50—H50	126.1
C5—C4—H4	125.7	C49—C50—H50	126.1
Fe2—C4—H4	126.8	Fe1—C50—H50	127.9
C4—C5—C1	108.0 (5)	C50—C51—C47	108.5 (5)
C4—C5—Fe2	70.5 (3)	C50—C51—Fe1	71.7 (3)
C1—C5—Fe2	68.6 (3)	C47—C51—Fe1	68.1 (3)
C4—C5—H5	126.0	C50—C51—H51	125.7
C1—C5—H5	126.0	C47—C51—H51	125.7
Fe2—C5—H5	126.5	Fe1—C51—H51	126.0
C7—C6—C10	106.3 (5)	C53—C52—C56	106.4 (5)
C7—C6—P2	123.8 (4)	C53—C52—P4	129.6 (4)
C10—C6—P2	130.0 (4)	C56—C52—P4	124.0 (4)
C7—C6—Fe2	70.1 (3)	C53—C52—Fe1	69.8 (3)
C10—C6—Fe2	70.7 (3)	C56—C52—Fe1	69.8 (3)
P2—C6—Fe2	124.3 (3)	P4—C52—Fe1	126.1 (3)
C8—C7—C6	108.2 (5)	C54—C53—C52	108.7 (5)
C8—C7—Fe2	71.2 (3)	C54—C53—Fe1	70.7 (3)
C6—C7—Fe2	68.2 (3)	C52—C53—Fe1	69.0 (3)
C8—C7—H7	125.9	C54—C53—H53	125.6
C6—C7—H7	125.9	C52—C53—H53	125.6
Fe2—C7—H7	126.3	Fe1—C53—H53	126.2
C9—C8—C7	109.0 (5)	C55—C54—C53	108.1 (5)
C9—C8—Fe2	70.2 (3)	C55—C54—Fe1	69.7 (3)
C7—C8—Fe2	68.6 (3)	C53—C54—Fe1	68.9 (3)
C9—C8—H8	125.5	C55—C54—H54	125.9
C7—C8—H8	125.5	C53—C54—H54	125.9
Fe2—C8—H8	127.3	Fe1—C54—H54	127.1
C8—C9—C10	108.1 (5)	C54—C55—C56	108.3 (5)
C8—C9—Fe2	70.1 (3)	C54—C55—Fe1	70.2 (3)
C10—C9—Fe2	69.1 (3)	C56—C55—Fe1	69.3 (3)
C8—C9—H9	125.9	C54—C55—H55	125.8
C10—C9—H9	125.9	C56—C55—H55	125.8
Fe2—C9—H9	126.4	Fe1—C55—H55	126.2
C9—C10—C6	108.4 (5)	C55—C56—C52	108.4 (5)
C9—C10—Fe2	70.6 (3)	C55—C56—Fe1	70.3 (3)
C6—C10—Fe2	67.7 (3)	C52—C56—Fe1	68.7 (3)
C9—C10—H10	125.8	C55—C56—H56	125.8
C6—C10—H10	125.8	C52—C56—H56	125.8
Fe2—C10—H10	127.4	Fe1—C56—H56	126.7
C12—C11—C16	117.6 (5)	C58—C57—C62	118.8 (5)
C12—C11—P1	124.2 (4)	C58—C57—P3	121.3 (4)
C16—C11—P1	118.1 (4)	C62—C57—P3	119.9 (4)
C11—C12—C13	121.1 (6)	C59—C58—C57	120.7 (5)
C11—C12—H12	119.5	C59—C58—H58	119.7
C13—C12—H12	119.5	C57—C58—H58	119.7
C14—C13—C12	121.0 (6)	C60—C59—C58	119.7 (6)
C14—C13—H13	119.5	C60—C59—H59	120.2
C12—C13—H13	119.5	C58—C59—H59	120.2
C13—C14—C15	118.7 (6)	C59—C60—C61	120.7 (6)
C13—C14—H14	120.6	C59—C60—H60	119.7
C15—C14—H14	120.6	C61—C60—H60	119.7
C14—C15—C16	120.6 (6)	C60—C61—C62	119.8 (6)
C14—C15—H15	119.7	C60—C61—H61	120.1
C16—C15—H15	119.7	C62—C61—H61	120.1
C15—C16—C11	121.0 (5)	C61—C62—C57	120.3 (5)
C15—C16—H16	119.5	C61—C62—H62	119.8
C11—C16—H16	119.5	C57—C62—H62	119.8
C18—C17—C22	119.2 (5)	C64—C63—C68	119.3 (5)
C18—C17—P1	122.1 (4)	C64—C63—P3	122.1 (4)
C22—C17—P1	118.6 (4)	C68—C63—P3	118.6 (4)
C17—C18—C19	119.1 (6)	C63—C64—C65	120.2 (6)
C17—C18—H18	120.4	C63—C64—H64	119.9
C19—C18—H18	120.4	C65—C64—H64	119.9
C20—C19—C18	120.3 (6)	C66—C65—C64	120.4 (7)
C20—C19—H19	119.9	C66—C65—H65	119.8
C18—C19—H19	119.9	C64—C65—H65	119.8
C19—C20—C21	121.1 (6)	C65—C66—C67	121.0 (6)
C19—C20—H20	119.4	C65—C66—H66	119.5
C21—C20—H20	119.4	C67—C66—H66	119.5
C20—C21—C22	118.7 (6)	C66—C67—C68	119.9 (6)
C20—C21—H21	120.6	C66—C67—H67	120.1
C22—C21—H21	120.6	C68—C67—H67	120.1
C17—C22—C21	121.4 (6)	C67—C68—C63	119.2 (6)
C17—C22—H22	119.3	C67—C68—H68	120.4
C21—C22—H22	119.3	C63—C68—H68	120.4
C24—C23—C28	118.7 (5)	C70—C69—C74	117.6 (5)
C24—C23—P2	119.9 (4)	C70—C69—P4	123.4 (5)
C28—C23—P2	121.0 (4)	C74—C69—P4	118.8 (4)
C23—C24—C25	120.8 (6)	C69—C70—C71	121.8 (6)
C23—C24—H24	119.6	C69—C70—H70	119.1
C25—C24—H24	119.6	C71—C70—H70	119.1
C26—C25—C24	119.8 (6)	C72—C71—C70	119.9 (6)
C26—C25—H25	120.1	C72—C71—H71	120.0
C24—C25—H25	120.1	C70—C71—H71	120.0
C27—C26—C25	119.3 (6)	C71—C72—C73	119.7 (6)
C27—C26—H26	120.4	C71—C72—H72	120.2
C25—C26—H26	120.4	C73—C72—H72	120.2
C28—C27—C26	121.3 (6)	C72—C73—C74	120.2 (7)
C28—C27—H27	119.4	C72—C73—H73	119.9
C26—C27—H27	119.4	C74—C73—H73	119.9
C27—C28—C23	120.1 (6)	C69—C74—C73	120.7 (6)
C27—C28—H28	120.0	C69—C74—H74	119.6
C23—C28—H28	120.0	C73—C74—H74	119.6
C30—C29—C34	119.2 (5)	C76—C75—C80	116.9 (6)
C30—C29—P2	120.5 (4)	C76—C75—P4	121.4 (5)
C34—C29—P2	120.3 (4)	C80—C75—P4	121.7 (5)
C31—C30—C29	121.2 (5)	C75—C76—C77	122.0 (6)
C31—C30—H30	119.4	C75—C76—H76	119.0
C29—C30—H30	119.4	C77—C76—H76	119.0
C30—C31—C32	119.6 (6)	C78—C77—C76	120.4 (7)
C30—C31—H31	120.2	C78—C77—H77	119.8
C32—C31—H31	120.2	C76—C77—H77	119.8
C33—C32—C31	119.9 (6)	C77—C78—C79	119.7 (7)
C33—C32—H32	120.1	C77—C78—H78	120.2
C31—C32—H32	120.1	C79—C78—H78	120.2
C32—C33—C34	121.2 (6)	C78—C79—C80	119.4 (7)
C32—C33—H33	119.4	C78—C79—H79	120.3
C34—C33—H33	119.4	C80—C79—H79	120.3
C33—C34—C29	119.0 (6)	C75—C80—C79	121.6 (7)
C33—C34—H34	120.5	C75—C80—H80	119.2
C29—C34—H34	120.5	C79—C80—H80	119.2
C36—C35—C40	114.4 (5)	C86—C81—C82	113.3 (6)
C36—C35—S1	118.7 (4)	C86—C81—S3	119.5 (6)
C40—C35—S1	126.9 (5)	C82—C81—S3	127.2 (5)
F1—C36—C35	119.8 (5)	F11—C82—C83	115.7 (6)
F1—C36—C37	116.4 (5)	F11—C82—C81	119.9 (6)
C35—C36—C37	123.7 (5)	C83—C82—C81	124.4 (6)
F2—C37—C38	119.6 (5)	F12—C83—C84	120.3 (7)
F2—C37—C36	121.2 (5)	F12—C83—C82	120.2 (7)
C38—C37—C36	119.0 (6)	C84—C83—C82	119.5 (7)
F3—C38—C37	120.2 (6)	C85—C84—F13	120.5 (8)
F3—C38—C39	120.2 (6)	C85—C84—C83	119.6 (7)
C37—C38—C39	119.6 (6)	F13—C84—C83	119.9 (8)
F4—C39—C40	121.7 (6)	F14—C85—C84	119.5 (8)
F4—C39—C38	118.7 (6)	F14—C85—C86	120.8 (8)
C40—C39—C38	119.6 (6)	C84—C85—C86	119.7 (7)
F5—C40—C39	116.9 (5)	F15—C86—C81	119.5 (7)
F5—C40—C35	119.6 (5)	F15—C86—C85	117.0 (6)
C39—C40—C35	123.5 (6)	C81—C86—C85	123.5 (7)
C42—C41—C46	115.6 (5)	C88—C87—C92	115.2 (5)
C42—C41—S2	124.8 (5)	C88—C87—S4	121.7 (5)
C46—C41—S2	119.2 (4)	C92—C87—S4	123.0 (4)
F6—C42—C41	120.4 (6)	F16—C88—C87	119.7 (5)
F6—C42—C43	118.3 (6)	F16—C88—C89	117.8 (6)
C41—C42—C43	121.4 (6)	C87—C88—C89	122.5 (6)
F7—C43—C44	120.0 (7)	F17—C89—C90	120.8 (6)
F7—C43—C42	119.4 (7)	F17—C89—C88	119.3 (7)
C44—C43—C42	120.7 (6)	C90—C89—C88	119.8 (6)
C43—C44—F8	121.0 (7)	F18—C90—C91	120.9 (7)
C43—C44—C45	119.8 (6)	F18—C90—C89	120.0 (7)
F8—C44—C45	119.2 (7)	C91—C90—C89	119.1 (6)
F9—C45—C44	120.7 (6)	C90—C91—F19	119.3 (6)
F9—C45—C46	119.7 (7)	C90—C91—C92	120.9 (6)
C44—C45—C46	119.6 (6)	F19—C91—C92	119.8 (7)
F10—C46—C45	117.3 (5)	F20—C92—C91	118.6 (6)
F10—C46—C41	119.8 (5)	F20—C92—C87	119.0 (5)
C45—C46—C41	122.9 (6)	C91—C92—C87	122.4 (6)
P1—Pt1—S1—C35	−145.2 (2)	P3—Pt2—S4—C87	149.9 (2)
S2—Pt1—S1—C35	43.4 (2)	P4—Pt2—S4—C87	43.3 (3)
P2—Pt1—S2—C41	−161.8 (2)	S3—Pt2—S4—C87	−38.2 (2)
S1—Pt1—S2—C41	23.8 (2)	P4—Pt2—P3—C47	61.68 (18)
P2—Pt1—P1—C1	18.5 (2)	S4—Pt2—P3—C47	−107.37 (18)
S1—Pt1—P1—C1	−167.0 (2)	P4—Pt2—P3—C57	−62.44 (18)
P2—Pt1—P1—C11	135.23 (18)	S4—Pt2—P3—C57	128.51 (18)
S1—Pt1—P1—C11	−50.33 (18)	P4—Pt2—P3—C63	−176.66 (19)
P2—Pt1—P1—C17	−106.8 (2)	S4—Pt2—P3—C63	14.3 (2)
S1—Pt1—P1—C17	67.6 (2)	P3—Pt2—P4—C52	−24.4 (2)
P1—Pt1—P2—C6	−50.60 (19)	S4—Pt2—P4—C52	81.2 (3)
S2—Pt1—P2—C6	121.03 (19)	S3—Pt2—P4—C52	163.0 (2)
P1—Pt1—P2—C29	−169.9 (2)	P3—Pt2—P4—C75	103.9 (2)
S2—Pt1—P2—C29	1.7 (2)	S4—Pt2—P4—C75	−150.5 (3)
P1—Pt1—P2—C23	74.00 (18)	S3—Pt2—P4—C75	−68.6 (2)
S2—Pt1—P2—C23	−114.37 (18)	P3—Pt2—P4—C69	−137.03 (18)
C11—P1—C1—C5	−9.7 (5)	S4—Pt2—P4—C69	−31.4 (3)
C17—P1—C1—C5	−117.6 (5)	S3—Pt2—P4—C69	50.42 (18)
Pt1—P1—C1—C5	107.8 (5)	C57—P3—C47—C51	147.5 (4)
C11—P1—C1—C2	167.6 (5)	C63—P3—C47—C51	−105.3 (4)
C17—P1—C1—C2	59.7 (5)	Pt2—P3—C47—C51	21.5 (5)
Pt1—P1—C1—C2	−74.9 (5)	C57—P3—C47—C48	−25.6 (6)
C11—P1—C1—Fe2	−101.7 (4)	C63—P3—C47—C48	81.6 (5)
C17—P1—C1—Fe2	150.4 (3)	Pt2—P3—C47—C48	−151.6 (4)
Pt1—P1—C1—Fe2	15.8 (4)	C57—P3—C47—Fe1	63.6 (3)
C5—C1—C2—C3	−0.2 (6)	C63—P3—C47—Fe1	170.8 (3)
P1—C1—C2—C3	−177.9 (4)	Pt2—P3—C47—Fe1	−62.3 (3)
Fe2—C1—C2—C3	60.4 (4)	C52—Fe1—C47—C51	−100.2 (3)
C5—C1—C2—Fe2	−60.6 (4)	C48—Fe1—C47—C51	117.4 (4)
P1—C1—C2—Fe2	121.7 (4)	C53—Fe1—C47—C51	−144.2 (3)
C1—C2—C3—C4	−0.1 (6)	C56—Fe1—C47—C51	−63.8 (4)
Fe2—C2—C3—C4	59.2 (4)	C54—Fe1—C47—C51	179.9 (3)
C1—C2—C3—Fe2	−59.3 (4)	C49—Fe1—C47—C51	80.1 (3)
C2—C3—C4—C5	0.3 (7)	C50—Fe1—C47—C51	37.0 (3)
Fe2—C3—C4—C5	58.4 (4)	C52—Fe1—C47—C48	142.4 (3)
C2—C3—C4—Fe2	−58.1 (4)	C51—Fe1—C47—C48	−117.4 (4)
C3—C4—C5—C1	−0.4 (7)	C53—Fe1—C47—C48	98.4 (3)
Fe2—C4—C5—C1	58.5 (4)	C56—Fe1—C47—C48	178.8 (3)
C3—C4—C5—Fe2	−59.0 (4)	C54—Fe1—C47—C48	62.5 (4)
C2—C1—C5—C4	0.4 (6)	C49—Fe1—C47—C48	−37.3 (3)
P1—C1—C5—C4	178.1 (4)	C50—Fe1—C47—C48	−80.4 (3)
Fe2—C1—C5—C4	−59.7 (4)	C52—Fe1—C47—P3	15.4 (3)
C2—C1—C5—Fe2	60.1 (4)	C51—Fe1—C47—P3	115.7 (4)
P1—C1—C5—Fe2	−122.2 (4)	C48—Fe1—C47—P3	−126.9 (4)
C29—P2—C6—C7	95.3 (5)	C53—Fe1—C47—P3	−28.5 (3)
C23—P2—C6—C7	−157.6 (4)	C56—Fe1—C47—P3	51.8 (5)
Pt1—P2—C6—C7	−32.3 (5)	C54—Fe1—C47—P3	−64.4 (4)
C29—P2—C6—C10	−84.1 (5)	C49—Fe1—C47—P3	−164.3 (4)
C23—P2—C6—C10	23.0 (5)	C50—Fe1—C47—P3	152.7 (4)
Pt1—P2—C6—C10	148.3 (4)	C51—C47—C48—C49	−0.9 (6)
C29—P2—C6—Fe2	−177.0 (3)	P3—C47—C48—C49	172.9 (4)
C23—P2—C6—Fe2	−69.9 (4)	Fe1—C47—C48—C49	60.0 (4)
Pt1—P2—C6—Fe2	55.4 (3)	C51—C47—C48—Fe1	−61.0 (3)
C10—C6—C7—C8	−1.6 (6)	P3—C47—C48—Fe1	112.9 (5)
P2—C6—C7—C8	178.8 (4)	C47—Fe1—C48—C49	−119.0 (5)
Fe2—C6—C7—C8	60.2 (4)	C52—Fe1—C48—C49	−178.8 (3)
C10—C6—C7—Fe2	−61.8 (3)	C51—Fe1—C48—C49	−79.9 (4)
P2—C6—C7—Fe2	118.6 (4)	C53—Fe1—C48—C49	143.1 (4)
C6—C7—C8—C9	0.3 (6)	C55—Fe1—C48—C49	63.3 (5)
Fe2—C7—C8—C9	58.7 (4)	C54—Fe1—C48—C49	99.7 (4)
C6—C7—C8—Fe2	−58.4 (4)	C50—Fe1—C48—C49	−36.6 (3)
C7—C8—C9—C10	1.1 (7)	C52—Fe1—C48—C47	−59.8 (4)
Fe2—C8—C9—C10	58.8 (4)	C51—Fe1—C48—C47	39.1 (3)
C7—C8—C9—Fe2	−57.7 (4)	C53—Fe1—C48—C47	−97.9 (3)
C8—C9—C10—C6	−2.2 (6)	C55—Fe1—C48—C47	−177.7 (3)
Fe2—C9—C10—C6	57.3 (4)	C54—Fe1—C48—C47	−141.2 (3)
C8—C9—C10—Fe2	−59.5 (4)	C49—Fe1—C48—C47	119.0 (5)
C7—C6—C10—C9	2.3 (6)	C50—Fe1—C48—C47	82.4 (3)
P2—C6—C10—C9	−178.2 (4)	C47—C48—C49—C50	0.9 (6)
Fe2—C6—C10—C9	−59.1 (4)	Fe1—C48—C49—C50	59.1 (4)
C7—C6—C10—Fe2	61.4 (3)	C47—C48—C49—Fe1	−58.1 (4)
P2—C6—C10—Fe2	−119.1 (4)	C47—Fe1—C49—C48	38.6 (3)
C1—P1—C11—C12	−97.5 (5)	C51—Fe1—C49—C48	83.5 (4)
C17—P1—C11—C12	5.8 (5)	C53—Fe1—C49—C48	−58.5 (5)
Pt1—P1—C11—C12	133.7 (5)	C56—Fe1—C49—C48	−178.4 (4)
C1—P1—C11—C16	86.5 (5)	C55—Fe1—C49—C48	−140.5 (3)
C17—P1—C11—C16	−170.2 (4)	C54—Fe1—C49—C48	−96.9 (4)
Pt1—P1—C11—C16	−42.3 (4)	C50—Fe1—C49—C48	120.6 (5)
C16—C11—C12—C13	0.7 (9)	C47—Fe1—C49—C50	−82.0 (4)
P1—C11—C12—C13	−175.3 (5)	C51—Fe1—C49—C50	−37.1 (3)
C11—C12—C13—C14	−1.5 (10)	C48—Fe1—C49—C50	−120.6 (5)
C12—C13—C14—C15	1.1 (10)	C53—Fe1—C49—C50	−179.2 (4)
C13—C14—C15—C16	−0.1 (9)	C56—Fe1—C49—C50	60.9 (5)
C14—C15—C16—C11	−0.7 (9)	C55—Fe1—C49—C50	98.8 (4)
C12—C11—C16—C15	0.3 (8)	C54—Fe1—C49—C50	142.4 (4)
P1—C11—C16—C15	176.6 (4)	C48—C49—C50—C51	−0.6 (6)
C1—P1—C17—C18	−144.5 (5)	Fe1—C49—C50—C51	57.5 (4)
C11—P1—C17—C18	108.9 (5)	C48—C49—C50—Fe1	−58.1 (4)
Pt1—P1—C17—C18	−9.0 (5)	C47—Fe1—C50—C51	−38.2 (3)
C1—P1—C17—C22	37.6 (5)	C52—Fe1—C50—C51	57.3 (5)
C11—P1—C17—C22	−69.0 (5)	C48—Fe1—C50—C51	−83.2 (3)
Pt1—P1—C17—C22	173.1 (4)	C56—Fe1—C50—C51	97.4 (3)
C22—C17—C18—C19	0.9 (8)	C55—Fe1—C50—C51	141.3 (3)
P1—C17—C18—C19	−177.0 (4)	C54—Fe1—C50—C51	179.5 (4)
C17—C18—C19—C20	0.4 (9)	C49—Fe1—C50—C51	−120.1 (5)
C18—C19—C20—C21	0.3 (10)	C47—Fe1—C50—C49	81.8 (3)
C19—C20—C21—C22	−2.2 (10)	C52—Fe1—C50—C49	177.4 (3)
C18—C17—C22—C21	−3.0 (9)	C51—Fe1—C50—C49	120.1 (5)
P1—C17—C22—C21	175.0 (5)	C48—Fe1—C50—C49	36.8 (3)
C20—C21—C22—C17	3.6 (10)	C56—Fe1—C50—C49	−142.5 (3)
C6—P2—C23—C24	131.9 (4)	C55—Fe1—C50—C49	−98.6 (4)
C29—P2—C23—C24	−121.2 (4)	C54—Fe1—C50—C49	−60.5 (5)
Pt1—P2—C23—C24	3.9 (5)	C49—C50—C51—C47	0.0 (6)
C6—P2—C23—C28	−55.7 (5)	Fe1—C50—C51—C47	58.3 (4)
C29—P2—C23—C28	51.1 (5)	C49—C50—C51—Fe1	−58.3 (4)
Pt1—P2—C23—C28	176.2 (4)	C48—C47—C51—C50	0.6 (6)
C28—C23—C24—C25	1.1 (8)	P3—C47—C51—C50	−174.0 (4)
P2—C23—C24—C25	173.7 (5)	Fe1—C47—C51—C50	−60.5 (4)
C23—C24—C25—C26	0.2 (9)	C48—C47—C51—Fe1	61.1 (3)
C24—C25—C26—C27	−0.7 (10)	P3—C47—C51—Fe1	−113.5 (4)
C25—C26—C27—C28	−0.3 (11)	C47—Fe1—C51—C50	119.6 (4)
C26—C27—C28—C23	1.6 (10)	C52—Fe1—C51—C50	−144.5 (3)
C24—C23—C28—C27	−2.1 (9)	C48—Fe1—C51—C50	80.4 (3)
P2—C23—C28—C27	−174.5 (5)	C53—Fe1—C51—C50	178.0 (4)
C6—P2—C29—C30	−30.6 (5)	C56—Fe1—C51—C50	−99.8 (4)
C23—P2—C29—C30	−143.3 (4)	C55—Fe1—C51—C50	−62.4 (5)
Pt1—P2—C29—C30	95.9 (4)	C49—Fe1—C51—C50	37.0 (3)
C6—P2—C29—C34	149.9 (4)	C52—Fe1—C51—C47	95.9 (3)
C23—P2—C29—C34	37.2 (5)	C48—Fe1—C51—C47	−39.2 (3)
Pt1—P2—C29—C34	−83.6 (4)	C53—Fe1—C51—C47	58.4 (4)
C34—C29—C30—C31	0.1 (8)	C56—Fe1—C51—C47	140.6 (3)
P2—C29—C30—C31	−179.4 (4)	C55—Fe1—C51—C47	178.0 (3)
C29—C30—C31—C32	−0.1 (9)	C49—Fe1—C51—C47	−82.6 (3)
C30—C31—C32—C33	0.4 (10)	C50—Fe1—C51—C47	−119.6 (4)
C31—C32—C33—C34	−0.8 (10)	C75—P4—C52—C53	−59.6 (5)
C32—C33—C34—C29	0.8 (9)	C69—P4—C52—C53	−166.6 (5)
C30—C29—C34—C33	−0.5 (8)	Pt2—P4—C52—C53	76.8 (5)
P2—C29—C34—C33	179.1 (4)	C75—P4—C52—C56	119.0 (5)
Pt1—S1—C35—C36	−140.1 (4)	C69—P4—C52—C56	12.1 (5)
Pt1—S1—C35—C40	40.6 (6)	Pt2—P4—C52—C56	−104.5 (4)
C40—C35—C36—F1	−179.4 (5)	C75—P4—C52—Fe1	−152.3 (3)
S1—C35—C36—F1	1.2 (7)	C69—P4—C52—Fe1	100.7 (4)
C40—C35—C36—C37	−3.0 (9)	Pt2—P4—C52—Fe1	−15.9 (4)
S1—C35—C36—C37	177.7 (5)	C47—Fe1—C52—C53	−98.9 (3)
F1—C36—C37—F2	1.5 (8)	C51—Fe1—C52—C53	−143.4 (3)
C35—C36—C37—F2	−175.1 (5)	C48—Fe1—C52—C53	−61.3 (4)
F1—C36—C37—C38	177.8 (5)	C56—Fe1—C52—C53	117.1 (4)
C35—C36—C37—C38	1.2 (9)	C55—Fe1—C52—C53	80.2 (3)
F2—C37—C38—F3	−3.0 (9)	C54—Fe1—C52—C53	37.0 (3)
C36—C37—C38—F3	−179.3 (5)	C50—Fe1—C52—C53	−179.1 (4)
F2—C37—C38—C39	177.4 (5)	C47—Fe1—C52—C56	143.9 (3)
C36—C37—C38—C39	1.1 (9)	C51—Fe1—C52—C56	99.4 (3)
F3—C38—C39—F4	0.6 (9)	C48—Fe1—C52—C56	−178.5 (3)
C37—C38—C39—F4	−179.8 (5)	C53—Fe1—C52—C56	−117.1 (4)
F3—C38—C39—C40	179.0 (5)	C55—Fe1—C52—C56	−36.9 (3)
C37—C38—C39—C40	−1.4 (10)	C54—Fe1—C52—C56	−80.1 (3)
F4—C39—C40—F5	−1.8 (9)	C50—Fe1—C52—C56	63.8 (4)
C38—C39—C40—F5	179.8 (5)	C47—Fe1—C52—P4	26.0 (4)
F4—C39—C40—C35	177.8 (5)	C51—Fe1—C52—P4	−18.5 (4)
C38—C39—C40—C35	−0.6 (10)	C48—Fe1—C52—P4	63.5 (5)
C36—C35—C40—F5	−177.7 (5)	C53—Fe1—C52—P4	124.9 (5)
S1—C35—C40—F5	1.5 (8)	C56—Fe1—C52—P4	−118.0 (5)
C36—C35—C40—C39	2.7 (9)	C55—Fe1—C52—P4	−154.9 (4)
S1—C35—C40—C39	−178.1 (5)	C54—Fe1—C52—P4	161.9 (4)
Pt1—S2—C41—C42	54.2 (5)	C50—Fe1—C52—P4	−54.2 (5)
Pt1—S2—C41—C46	−133.2 (4)	C56—C52—C53—C54	0.8 (6)
C46—C41—C42—F6	−177.4 (5)	P4—C52—C53—C54	179.6 (4)
S2—C41—C42—F6	−4.6 (8)	Fe1—C52—C53—C54	−59.8 (4)
C46—C41—C42—C43	3.3 (8)	C56—C52—C53—Fe1	60.5 (4)
S2—C41—C42—C43	176.1 (5)	P4—C52—C53—Fe1	−120.7 (4)
F6—C42—C43—F7	−0.7 (9)	C47—Fe1—C53—C54	−143.4 (3)
C41—C42—C43—F7	178.6 (5)	C52—Fe1—C53—C54	119.9 (5)
F6—C42—C43—C44	177.8 (6)	C51—Fe1—C53—C54	179.5 (4)
C41—C42—C43—C44	−2.9 (10)	C48—Fe1—C53—C54	−98.8 (4)
F7—C43—C44—F8	−0.8 (10)	C56—Fe1—C53—C54	80.6 (4)
C42—C43—C44—F8	−179.2 (6)	C55—Fe1—C53—C54	37.0 (3)
F7—C43—C44—C45	178.3 (6)	C49—Fe1—C53—C54	−62.7 (5)
C42—C43—C44—C45	−0.2 (10)	C47—Fe1—C53—C52	96.7 (3)
C43—C44—C45—F9	−179.9 (6)	C51—Fe1—C53—C52	59.6 (5)
F8—C44—C45—F9	−0.8 (10)	C48—Fe1—C53—C52	141.3 (3)
C43—C44—C45—C46	2.6 (10)	C56—Fe1—C53—C52	−39.3 (3)
F8—C44—C45—C46	−178.3 (6)	C55—Fe1—C53—C52	−82.9 (3)
F9—C45—C46—F10	0.7 (9)	C54—Fe1—C53—C52	−119.9 (5)
C44—C45—C46—F10	178.2 (6)	C49—Fe1—C53—C52	177.4 (3)
F9—C45—C46—C41	−179.6 (5)	C52—C53—C54—C55	0.0 (6)
C44—C45—C46—C41	−2.1 (10)	Fe1—C53—C54—C55	−58.7 (4)
C42—C41—C46—F10	178.8 (5)	C52—C53—C54—Fe1	58.7 (4)
S2—C41—C46—F10	5.6 (7)	C47—Fe1—C54—C55	178.0 (3)
C42—C41—C46—C45	−0.9 (9)	C52—Fe1—C54—C55	82.2 (4)
S2—C41—C46—C45	−174.1 (5)	C48—Fe1—C54—C55	−142.7 (3)
C7—C6—Fe2—C1	101.9 (3)	C53—Fe1—C54—C55	120.0 (5)
C10—C6—Fe2—C1	−141.9 (3)	C56—Fe1—C54—C55	37.5 (3)
P2—C6—Fe2—C1	−16.0 (4)	C49—Fe1—C54—C55	−99.3 (4)
C10—C6—Fe2—C7	116.3 (4)	C50—Fe1—C54—C55	−62.0 (5)
P2—C6—Fe2—C7	−117.9 (5)	C47—Fe1—C54—C53	58.0 (5)
C7—C6—Fe2—C2	145.8 (3)	C52—Fe1—C54—C53	−37.7 (3)
C10—C6—Fe2—C2	−97.9 (3)	C48—Fe1—C54—C53	97.3 (4)
P2—C6—Fe2—C2	27.9 (4)	C56—Fe1—C54—C53	−82.5 (4)
C7—C6—Fe2—C10	−116.3 (4)	C55—Fe1—C54—C53	−120.0 (5)
P2—C6—Fe2—C10	125.8 (5)	C49—Fe1—C54—C53	140.8 (3)
C7—C6—Fe2—C5	66.4 (4)	C50—Fe1—C54—C53	178.0 (4)
C10—C6—Fe2—C5	−177.3 (3)	C53—C54—C55—C56	−0.7 (7)
P2—C6—Fe2—C5	−51.5 (5)	Fe1—C54—C55—C56	−59.0 (4)
C7—C6—Fe2—C3	−179.9 (4)	C53—C54—C55—Fe1	58.3 (4)
C10—C6—Fe2—C3	−63.7 (4)	C52—Fe1—C55—C54	−81.7 (4)
P2—C6—Fe2—C3	62.1 (5)	C51—Fe1—C55—C54	179.9 (3)
C7—C6—Fe2—C8	−37.1 (3)	C48—Fe1—C55—C54	59.2 (5)
C10—C6—Fe2—C8	79.2 (3)	C53—Fe1—C55—C54	−37.3 (3)
P2—C6—Fe2—C8	−155.0 (4)	C56—Fe1—C55—C54	−119.6 (5)
C7—C6—Fe2—C9	−79.7 (3)	C49—Fe1—C55—C54	98.0 (4)
C10—C6—Fe2—C9	36.6 (3)	C50—Fe1—C55—C54	141.6 (4)
P2—C6—Fe2—C9	162.4 (4)	C52—Fe1—C55—C56	37.9 (3)
C5—C1—Fe2—C6	−143.4 (3)	C51—Fe1—C55—C56	−60.6 (5)
C2—C1—Fe2—C6	99.1 (3)	C48—Fe1—C55—C56	178.8 (4)
P1—C1—Fe2—C6	−21.7 (4)	C53—Fe1—C55—C56	82.3 (4)
C5—C1—Fe2—C7	−99.1 (3)	C54—Fe1—C55—C56	119.6 (5)
C2—C1—Fe2—C7	143.4 (3)	C49—Fe1—C55—C56	−142.5 (4)
P1—C1—Fe2—C7	22.6 (4)	C50—Fe1—C55—C56	−98.9 (4)
C5—C1—Fe2—C2	117.5 (4)	C54—C55—C56—C52	1.2 (7)
P1—C1—Fe2—C2	−120.8 (5)	Fe1—C55—C56—C52	−58.3 (4)
C5—C1—Fe2—C10	−180.0 (3)	C54—C55—C56—Fe1	59.5 (4)
C2—C1—Fe2—C10	62.5 (4)	C53—C52—C56—C55	−1.2 (6)
P1—C1—Fe2—C10	−58.3 (5)	P4—C52—C56—C55	179.9 (4)
C2—C1—Fe2—C5	−117.5 (4)	Fe1—C52—C56—C55	59.3 (4)
P1—C1—Fe2—C5	121.7 (5)	C53—C52—C56—Fe1	−60.5 (4)
C5—C1—Fe2—C3	79.9 (4)	P4—C52—C56—Fe1	120.6 (4)
C2—C1—Fe2—C3	−37.6 (3)	C47—Fe1—C56—C55	−177.7 (3)
P1—C1—Fe2—C3	−158.4 (4)	C52—Fe1—C56—C55	−120.0 (5)
C5—C1—Fe2—C8	−64.8 (5)	C51—Fe1—C56—C55	142.4 (4)
C2—C1—Fe2—C8	177.7 (4)	C53—Fe1—C56—C55	−80.9 (4)
P1—C1—Fe2—C8	56.9 (5)	C54—Fe1—C56—C55	−37.3 (4)
C5—C1—Fe2—C4	37.3 (3)	C49—Fe1—C56—C55	61.2 (5)
C2—C1—Fe2—C4	−80.2 (4)	C50—Fe1—C56—C55	98.8 (4)
P1—C1—Fe2—C4	159.1 (4)	C47—Fe1—C56—C52	−57.7 (5)
C8—C7—Fe2—C6	−119.4 (5)	C51—Fe1—C56—C52	−97.7 (3)
C8—C7—Fe2—C1	147.0 (4)	C53—Fe1—C56—C52	39.0 (3)
C6—C7—Fe2—C1	−93.6 (3)	C55—Fe1—C56—C52	120.0 (5)
C8—C7—Fe2—C2	−175.1 (4)	C54—Fe1—C56—C52	82.7 (3)
C6—C7—Fe2—C2	−55.7 (5)	C49—Fe1—C56—C52	−178.9 (4)
C8—C7—Fe2—C10	−79.7 (4)	C50—Fe1—C56—C52	−141.3 (3)
C6—C7—Fe2—C10	39.7 (3)	C47—P3—C57—C58	52.8 (5)
C8—C7—Fe2—C5	102.5 (4)	C63—P3—C57—C58	−58.2 (5)
C6—C7—Fe2—C5	−138.1 (3)	Pt2—P3—C57—C58	178.7 (4)
C6—C7—Fe2—C8	119.4 (5)	C47—P3—C57—C62	−129.4 (4)
C8—C7—Fe2—C9	−36.3 (3)	C63—P3—C57—C62	119.6 (4)
C6—C7—Fe2—C9	83.1 (3)	Pt2—P3—C57—C62	−3.5 (5)
C8—C7—Fe2—C4	65.4 (5)	C62—C57—C58—C59	2.7 (8)
C6—C7—Fe2—C4	−175.2 (4)	P3—C57—C58—C59	−179.5 (4)
C3—C2—Fe2—C6	145.5 (4)	C57—C58—C59—C60	−1.7 (9)
C1—C2—Fe2—C6	−95.6 (3)	C58—C59—C60—C61	0.9 (10)
C3—C2—Fe2—C1	−118.9 (5)	C59—C60—C61—C62	−1.2 (10)
C3—C2—Fe2—C7	−178.9 (4)	C60—C61—C62—C57	2.2 (9)
C1—C2—Fe2—C7	−59.9 (5)	C58—C57—C62—C61	−2.9 (8)
C3—C2—Fe2—C10	101.3 (4)	P3—C57—C62—C61	179.2 (4)
C1—C2—Fe2—C10	−139.7 (3)	C47—P3—C63—C64	13.4 (5)
C3—C2—Fe2—C5	−80.1 (4)	C57—P3—C63—C64	127.0 (4)
C1—C2—Fe2—C5	38.8 (3)	Pt2—P3—C63—C64	−111.8 (4)
C1—C2—Fe2—C3	118.9 (5)	C47—P3—C63—C68	−168.2 (4)
C3—C2—Fe2—C9	65.5 (5)	C57—P3—C63—C68	−54.7 (4)
C1—C2—Fe2—C9	−175.6 (3)	Pt2—P3—C63—C68	66.5 (4)
C3—C2—Fe2—C4	−36.4 (4)	C68—C63—C64—C65	0.2 (8)
C1—C2—Fe2—C4	82.5 (3)	P3—C63—C64—C65	178.5 (5)
C9—C10—Fe2—C6	120.4 (5)	C63—C64—C65—C66	−0.9 (10)
C9—C10—Fe2—C1	179.2 (4)	C64—C65—C66—C67	1.7 (10)
C6—C10—Fe2—C1	58.8 (4)	C65—C66—C67—C68	−1.7 (9)
C9—C10—Fe2—C7	80.5 (4)	C66—C67—C68—C63	0.9 (8)
C6—C10—Fe2—C7	−39.8 (3)	C64—C63—C68—C67	−0.2 (8)
C9—C10—Fe2—C2	−142.2 (4)	P3—C63—C68—C67	−178.5 (4)
C6—C10—Fe2—C2	97.4 (3)	C52—P4—C69—C70	79.9 (5)
C9—C10—Fe2—C3	−98.8 (4)	C75—P4—C69—C70	−25.8 (5)
C6—C10—Fe2—C3	140.8 (3)	Pt2—P4—C69—C70	−155.1 (4)
C9—C10—Fe2—C8	37.0 (3)	C52—P4—C69—C74	−94.2 (5)
C6—C10—Fe2—C8	−83.4 (3)	C75—P4—C69—C74	160.1 (4)
C6—C10—Fe2—C9	−120.4 (5)	Pt2—P4—C69—C74	30.8 (5)
C9—C10—Fe2—C4	−63.6 (5)	C74—C69—C70—C71	2.1 (9)
C6—C10—Fe2—C4	176.0 (4)	P4—C69—C70—C71	−172.0 (5)
C4—C5—Fe2—C6	176.2 (4)	C69—C70—C71—C72	−1.3 (10)
C1—C5—Fe2—C6	56.9 (4)	C70—C71—C72—C73	1.1 (10)
C4—C5—Fe2—C1	119.4 (5)	C71—C72—C73—C74	−1.9 (10)
C4—C5—Fe2—C7	−142.8 (4)	C70—C69—C74—C73	−2.8 (9)
C1—C5—Fe2—C7	97.9 (3)	P4—C69—C74—C73	171.6 (5)
C4—C5—Fe2—C2	80.3 (4)	C72—C73—C74—C69	2.8 (10)
C1—C5—Fe2—C2	−39.1 (3)	C52—P4—C75—C76	168.4 (5)
C4—C5—Fe2—C3	36.5 (4)	C69—P4—C75—C76	−87.7 (5)
C1—C5—Fe2—C3	−82.8 (3)	Pt2—P4—C75—C76	33.0 (6)
C4—C5—Fe2—C8	−99.0 (4)	C52—P4—C75—C80	−14.5 (6)
C1—C5—Fe2—C8	141.6 (3)	C69—P4—C75—C80	89.4 (6)
C4—C5—Fe2—C9	−61.5 (5)	Pt2—P4—C75—C80	−149.9 (5)
C1—C5—Fe2—C9	179.2 (4)	C80—C75—C76—C77	−3.1 (11)
C1—C5—Fe2—C4	−119.4 (5)	P4—C75—C76—C77	174.2 (6)
C4—C3—Fe2—C6	−175.2 (4)	C75—C76—C77—C78	2.2 (13)
C2—C3—Fe2—C6	−54.9 (5)	C76—C77—C78—C79	0.0 (14)
C4—C3—Fe2—C1	−81.8 (4)	C77—C78—C79—C80	−1.1 (14)
C2—C3—Fe2—C1	38.5 (3)	C76—C75—C80—C79	1.9 (12)
C4—C3—Fe2—C2	−120.3 (5)	P4—C75—C80—C79	−175.3 (7)
C4—C3—Fe2—C10	145.0 (4)	C78—C79—C80—C75	0.1 (14)
C2—C3—Fe2—C10	−94.7 (4)	Pt2—S3—C81—C86	150.8 (5)
C4—C3—Fe2—C5	−37.3 (4)	Pt2—S3—C81—C82	−29.6 (6)
C2—C3—Fe2—C5	83.0 (4)	C86—C81—C82—F11	177.3 (5)
C4—C3—Fe2—C8	64.6 (5)	S3—C81—C82—F11	−2.3 (9)
C2—C3—Fe2—C8	−175.1 (4)	C86—C81—C82—C83	−0.7 (9)
C4—C3—Fe2—C9	101.4 (4)	S3—C81—C82—C83	179.7 (5)
C2—C3—Fe2—C9	−138.3 (4)	F11—C82—C83—F12	2.2 (9)
C2—C3—Fe2—C4	120.3 (5)	C81—C82—C83—F12	−179.8 (6)
C9—C8—Fe2—C6	−82.4 (4)	F11—C82—C83—C84	−178.6 (6)
C7—C8—Fe2—C6	38.4 (3)	C81—C82—C83—C84	−0.5 (10)
C9—C8—Fe2—C1	−175.2 (4)	F12—C83—C84—C85	−178.8 (7)
C7—C8—Fe2—C1	−54.4 (5)	C82—C83—C84—C85	2.0 (11)
C9—C8—Fe2—C7	−120.8 (5)	F12—C83—C84—F13	0.2 (10)
C9—C8—Fe2—C10	−37.5 (3)	C82—C83—C84—F13	−179.0 (6)
C7—C8—Fe2—C10	83.3 (4)	F13—C84—C85—F14	−0.1 (12)
C9—C8—Fe2—C5	143.9 (3)	C83—C84—C85—F14	178.9 (7)
C7—C8—Fe2—C5	−95.3 (4)	F13—C84—C85—C86	178.9 (6)
C9—C8—Fe2—C3	60.4 (5)	C83—C84—C85—C86	−2.1 (12)
C7—C8—Fe2—C3	−178.8 (4)	C82—C81—C86—F15	−179.5 (6)
C7—C8—Fe2—C9	120.8 (5)	S3—C81—C86—F15	0.1 (9)
C9—C8—Fe2—C4	99.4 (4)	C82—C81—C86—C85	0.6 (10)
C7—C8—Fe2—C4	−139.8 (4)	S3—C81—C86—C85	−179.8 (6)
C8—C9—Fe2—C6	81.8 (4)	F14—C85—C86—F15	−0.1 (11)
C10—C9—Fe2—C6	−37.7 (3)	C84—C85—C86—F15	−179.1 (7)
C8—C9—Fe2—C7	36.8 (3)	F14—C85—C86—C81	179.8 (7)
C10—C9—Fe2—C7	−82.7 (3)	C84—C85—C86—C81	0.8 (12)
C8—C9—Fe2—C2	178.1 (4)	Pt2—S4—C87—C88	124.6 (4)
C10—C9—Fe2—C2	58.6 (5)	Pt2—S4—C87—C92	−59.0 (5)
C8—C9—Fe2—C10	119.5 (5)	C92—C87—C88—F16	−176.8 (5)
C8—C9—Fe2—C5	−60.4 (5)	S4—C87—C88—F16	−0.1 (8)
C10—C9—Fe2—C5	−179.9 (4)	C92—C87—C88—C89	4.5 (9)
C8—C9—Fe2—C3	−142.2 (4)	S4—C87—C88—C89	−178.9 (5)
C10—C9—Fe2—C3	98.3 (4)	F16—C88—C89—F17	0.4 (9)
C10—C9—Fe2—C8	−119.5 (5)	C87—C88—C89—F17	179.2 (6)
C8—C9—Fe2—C4	−99.1 (4)	F16—C88—C89—C90	177.8 (6)
C10—C9—Fe2—C4	141.5 (4)	C87—C88—C89—C90	−3.4 (10)
C3—C4—Fe2—C1	82.1 (4)	F17—C89—C90—F18	−1.2 (11)
C5—C4—Fe2—C1	−38.1 (3)	C88—C89—C90—F18	−178.5 (6)
C3—C4—Fe2—C7	−179.8 (4)	F17—C89—C90—C91	179.1 (6)
C5—C4—Fe2—C7	60.0 (5)	C88—C89—C90—C91	1.7 (11)
C3—C4—Fe2—C2	37.3 (4)	F18—C90—C91—F19	0.2 (10)
C5—C4—Fe2—C2	−82.9 (4)	C89—C90—C91—F19	180.0 (6)
C3—C4—Fe2—C10	−56.9 (5)	F18—C90—C91—C92	178.9 (6)
C5—C4—Fe2—C10	−177.1 (4)	C89—C90—C91—C92	−1.4 (11)
C3—C4—Fe2—C5	120.2 (5)	C90—C91—C92—F20	−178.9 (6)
C5—C4—Fe2—C3	−120.2 (5)	F19—C91—C92—F20	−0.3 (9)
C3—C4—Fe2—C8	−139.8 (4)	C90—C91—C92—C87	2.7 (10)
C5—C4—Fe2—C8	100.0 (4)	F19—C91—C92—C87	−178.6 (6)
C3—C4—Fe2—C9	−96.2 (4)	C88—C87—C92—F20	177.5 (5)
C5—C4—Fe2—C9	143.6 (4)	S4—C87—C92—F20	0.9 (8)
P4—Pt2—S3—C81	138.8 (2)	C88—C87—C92—C91	−4.1 (9)
S4—Pt2—S3—C81	−52.5 (2)	S4—C87—C92—C91	179.3 (5)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C18—H18···F5	0.93	2.69 (1)	3.61	176
C19—H19···F14	0.93	2.38 (1)	3.22	151
C25—H25···F15	0.93	2.78 (1)	3.70	169
C51—H51···F20	0.93	2.75 (1)	3.65	163
C74—H74···F20	0.93	2.43 (1)	3.31	158
C56—H56···F17^i	0.93	2.54 (1)	3.03	113
C71—H71···F13^i	0.93	2.68 (1)	3.50	148
C28—H28···F2^i	0.93	2.66 (1)	3.50	151
C21—H21···F3^ii	0.93	2.56 (1)	3.32	140
C13—H13···F16^ii	0.93	2.74 (1)	3.23	114
C31—H31···F20^iii	0.93	2.71 (1)	3.02	100
C54—H54···F3^iv	0.93	2.65 (1)	3.42	141
C61—H61···F11^iv	0.93	2.45 (1)	3.23	142
C48—H48···F10^iv	0.93	2.54 (1)	3.39	153
C56—H56···F8^v	0.93	2.68 (1)	3.46	142
C66—H66···F7^vi	0.93	2.72 (1)	3.58	155

Symmetry codes: (i) x−1/2, −y+1/2, z−1/2; (ii) −x+3/2, y−1/2, −z+3/2; (iii) x+1/2, −y+1/2, z−1/2; (iv) −x+1, −y+1, −z+1; (v) x−1, y, z; (vi) −x+3/2, y+1/2, −z+3/2.