trans-Carbonyl­chloro­bis­(tri-m-tolyl­phosphino)­rhodium(I) di­chloro­methane solvate

The title compound, [RhCl{P(C₇H₇)₃}₂(CO)]·CH₂Cl₂, where P(C₇H₇)₃ is tri-m-tolyl­phosphine, crystallizes with a dichloromethane molecule in the asymmetric unit. Important geometrical parameters are Rh—P = 2.3229 (15) and 2.3269 (15) Å, Rh—Cl = 2.3659 (15) Å, Rh—C = 1.793 (6) Å, C—Rh—Cl = 174.6 (2)°, P—Rh—C = 90.33 (17)° and 92.68 (17)°, and Rh—C[triple bond]O = 176.2 (5)°. The effective cone angles for the phosphine ligands were calculated to be 160 and 155°.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.010 Å
• Disorder in solvent or counterion
• R factor = 0.062
• wR factor = 0.151
• Data-to-parameter ratio = 19.1

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature        293 K
PLAT202_ALERT_3_C Isotropic non-H Atoms in Anion/Solvent .........          3
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.75 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.18 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C65
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C13
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C1A
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         10
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          4

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART-NT (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus and XPREP (Bruker, 1999); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Berndt, 2001); software used to prepare material for publication: WinGX (Farrugia, 1999).

trans-Carbonylchlorobis(tri-m-tolylphosphino)rhodium(I) dichloromethane solvate

Crystal data

[RhCl(C21H21P)2(CO)]·CH2Cl2	Z = 2
Mr = 859.99	F(000) = 884
Triclinic, P1	Dx = 1.386 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.061 (2) Å	Cell parameters from 814 reflections
b = 11.763 (2) Å	θ = 2.6–22.6°
c = 19.337 (4) Å	µ = 0.72 mm^−1
α = 100.87 (3)°	T = 293 K
β = 100.71 (3)°	Rectangle, yellow
γ = 108.14 (3)°	0.60 × 0.22 × 0.12 mm
V = 2061.0 (9) Å^3

Data collection

Bruker SMART CCD 1K diffractometer	5105 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.047
ω scans	θmax = 27.0°, θmin = 1.1°
Absorption correction: multi-scan SADABS (Bruker, 1998)	h = −12→12
Tmin = 0.672, Tmax = 0.919	k = −14→15
13219 measured reflections	l = −24→24
8864 independent reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.062	w = 1/[σ^2(Fo^2) + (0.0525P)^2 + 1.6693P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.151	(Δ/σ)max = 0.001
S = 1.02	Δρmax = 0.84 e Å^−3
8864 reflections	Δρmin = −0.73 e Å^−3
464 parameters

Special details

Experimental. The intensity data was collected on a Siemens SMART CCD 1 K diffractometer using an exposure time of 10 s/frame. A total of 1350 frames were collected with a frame width of 0.3° covering up to θ = 26.99° with 98.5% completeness accomplished. The first 50 frames were recollected at the end of each data collection to check for decay; none was found.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Rh	0.26170 (5)	0.20464 (4)	0.72527 (2)	0.02874 (14)
P1	0.26797 (16)	0.31120 (13)	0.63555 (7)	0.0317 (3)
P2	0.25787 (16)	0.10801 (13)	0.81974 (7)	0.0311 (3)
C	0.2755 (7)	0.0761 (6)	0.6644 (3)	0.0421 (15)
O	0.2763 (6)	−0.0096 (4)	0.6241 (3)	0.0698 (15)
Cl1	0.21963 (17)	0.36651 (13)	0.80029 (7)	0.0415 (4)
C11	0.2607 (6)	0.2221 (5)	0.5456 (3)	0.0357 (13)
C12	0.3839 (7)	0.2075 (6)	0.5296 (3)	0.0422 (15)
H12	0.4722	0.2488	0.5645	0.051*
C13	0.3818 (7)	0.1344 (6)	0.4642 (3)	0.0474 (16)
C14	0.2499 (8)	0.0717 (6)	0.4144 (3)	0.0566 (18)
H14	0.2455	0.0219	0.3699	0.068*
C15	0.1241 (7)	0.0807 (6)	0.4286 (3)	0.0542 (18)
H15	0.0356	0.0355	0.3945	0.065*
C16	0.1295 (7)	0.1570 (6)	0.4938 (3)	0.0438 (15)
H16	0.0447	0.1647	0.5029	0.053*
C17	0.5195 (9)	0.1249 (8)	0.4472 (4)	0.089 (3)
H17A	0.5728	0.104	0.4863	0.133*
H17B	0.5778	0.203	0.4418	0.133*
H17C	0.4954	0.0616	0.4027	0.133*
C21	0.1188 (6)	0.3677 (6)	0.6195 (3)	0.0372 (14)
C22	0.1344 (7)	0.4845 (6)	0.6097 (3)	0.0463 (16)
H22	0.2256	0.5374	0.6104	0.056*
C23	0.0182 (10)	0.5252 (8)	0.5988 (3)	0.066 (2)
C24	−0.1150 (10)	0.4444 (9)	0.5965 (4)	0.080 (3)
H24	−0.1941	0.4697	0.5887	0.096*
C25	−0.1367 (8)	0.3277 (8)	0.6052 (4)	0.071 (2)
H25	−0.2291	0.2747	0.6025	0.085*
C26	−0.0186 (7)	0.2893 (7)	0.6183 (3)	0.0535 (17)
H26	−0.0313	0.2115	0.6262	0.064*
C27	0.0409 (10)	0.6552 (8)	0.5920 (4)	0.089 (3)
H27A	0.1266	0.6856	0.5757	0.133*
H27B	0.052	0.7082	0.6387	0.133*
H27C	−0.0413	0.6546	0.5574	0.133*
C31	0.4310 (6)	0.4491 (5)	0.6561 (3)	0.0341 (13)
C32	0.5101 (6)	0.5047 (5)	0.7280 (3)	0.0385 (14)
H32	0.4813	0.4686	0.7642	0.046*
C33	0.6308 (7)	0.6124 (6)	0.7476 (3)	0.0463 (15)
C34	0.6753 (7)	0.6645 (6)	0.6934 (4)	0.0542 (17)
H34	0.7566	0.7366	0.7057	0.065*
C35	0.6002 (8)	0.6104 (6)	0.6221 (4)	0.0550 (18)
H35	0.6319	0.6454	0.5861	0.066*
C36	0.4771 (7)	0.5036 (6)	0.6024 (3)	0.0485 (16)
H36	0.4256	0.4686	0.5537	0.058*
C37	0.7120 (8)	0.6734 (7)	0.8274 (3)	0.071 (2)
H37A	0.6442	0.6797	0.8556	0.107*
H37B	0.7791	0.7547	0.8322	0.107*
H37C	0.764	0.6241	0.8449	0.107*
C41	0.2706 (6)	−0.0471 (5)	0.8020 (3)	0.0345 (13)
C42	0.1661 (6)	−0.1507 (5)	0.8071 (3)	0.0366 (13)
H42	0.0841	−0.1434	0.8201	0.044*
C43	0.1803 (7)	−0.2671 (5)	0.7930 (3)	0.0402 (14)
C44	0.3018 (7)	−0.2763 (6)	0.7747 (3)	0.0436 (15)
H44	0.3131	−0.3528	0.7654	0.052*
C45	0.4088 (7)	−0.1719 (6)	0.7698 (3)	0.0527 (17)
H45	0.4922	−0.1786	0.7581	0.063*
C46	0.3917 (7)	−0.0588 (6)	0.7822 (3)	0.0480 (16)
H46	0.4621	0.0101	0.7773	0.058*
C47	0.0628 (7)	−0.3786 (6)	0.7979 (4)	0.0587 (18)
H47A	−0.0252	−0.3934	0.7622	0.088*
H47B	0.0473	−0.3641	0.8458	0.088*
H47C	0.091	−0.4497	0.7888	0.088*
C51	0.0875 (6)	0.0859 (5)	0.8458 (3)	0.0343 (13)
C52	0.0792 (7)	0.1327 (6)	0.9149 (3)	0.0427 (15)
H52	0.1644	0.1774	0.9514	0.051*
C53	−0.0525 (8)	0.1151 (6)	0.9316 (3)	0.0534 (17)
C54	−0.1772 (7)	0.0510 (7)	0.8771 (4)	0.0580 (18)
H54	−0.2665	0.0399	0.8872	0.07*
C55	−0.1721 (7)	0.0031 (7)	0.8079 (4)	0.0595 (19)
H55	−0.2579	−0.0419	0.7718	0.071*
C56	−0.0408 (7)	0.0209 (6)	0.7910 (3)	0.0470 (16)
H56	−0.038	−0.0101	0.7436	0.056*
C57	−0.0563 (9)	0.1705 (9)	1.0086 (4)	0.093 (3)
H57A	−0.0386	0.2575	1.0156	0.14*
H57B	0.0171	0.1593	1.0432	0.14*
H57C	−0.1497	0.1298	1.0155	0.14*
C61	0.4005 (6)	0.1886 (5)	0.9046 (3)	0.0361 (13)
C62	0.4921 (6)	0.3099 (5)	0.9164 (3)	0.0401 (14)
H62	0.4824	0.3497	0.8795	0.048*
C63	0.5989 (7)	0.3746 (6)	0.9819 (3)	0.0482 (16)
C64	0.6101 (8)	0.3128 (7)	1.0354 (3)	0.0587 (19)
H64	0.6786	0.3543	1.0799	0.07*
C65	0.5227 (9)	0.1913 (8)	1.0247 (4)	0.070 (2)
H65	0.5344	0.1515	1.0614	0.083*
C66	0.4173 (7)	0.1279 (6)	0.9596 (3)	0.0501 (16)
H66	0.3582	0.0459	0.9526	0.06*
C67	0.6948 (8)	0.5057 (6)	0.9941 (4)	0.071 (2)
H67A	0.7278	0.5457	1.0454	0.107*
H67B	0.6417	0.5484	0.9697	0.107*
H67C	0.7767	0.5076	0.9749	0.107*
C1A	0.836 (2)	0.307 (2)	0.7749 (11)	0.064 (6)*	0.426 (11)
H1A1	0.9057	0.2664	0.7796	0.077*	0.426 (11)
H1A2	0.8688	0.3719	0.7507	0.077*	0.426 (11)
Cl2A	0.8275 (11)	0.3715 (7)	0.8576 (5)	0.110 (3)*	0.426 (11)
Cl3A	0.6616 (7)	0.1950 (8)	0.7187 (5)	0.104 (3)*	0.426 (11)
C1B	0.862 (2)	0.300 (2)	0.8000 (11)	0.104 (7)*	0.574 (11)
H1B1	0.8865	0.2272	0.801	0.125*	0.574 (11)
H1B2	0.9188	0.3473	0.7727	0.125*	0.574 (11)
Cl2B	0.8990 (8)	0.3896 (5)	0.8876 (4)	0.110 (2)*	0.574 (11)
Cl3B	0.6654 (6)	0.2538 (7)	0.7557 (4)	0.126 (2)*	0.574 (11)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Rh	0.0329 (3)	0.0265 (2)	0.0284 (2)	0.01179 (19)	0.00847 (18)	0.00841 (18)
P1	0.0381 (9)	0.0309 (8)	0.0275 (8)	0.0145 (7)	0.0082 (6)	0.0074 (6)
P2	0.0340 (9)	0.0277 (8)	0.0302 (8)	0.0089 (7)	0.0079 (6)	0.0083 (6)
C	0.061 (4)	0.037 (4)	0.039 (3)	0.024 (3)	0.018 (3)	0.016 (3)
O	0.112 (4)	0.054 (3)	0.061 (3)	0.048 (3)	0.035 (3)	0.012 (3)
Cl1	0.0579 (10)	0.0357 (8)	0.0372 (8)	0.0238 (8)	0.0179 (7)	0.0069 (6)
C11	0.048 (4)	0.034 (3)	0.030 (3)	0.017 (3)	0.010 (3)	0.014 (3)
C12	0.044 (4)	0.048 (4)	0.037 (3)	0.020 (3)	0.010 (3)	0.012 (3)
C13	0.056 (4)	0.054 (4)	0.040 (4)	0.027 (4)	0.019 (3)	0.012 (3)
C14	0.073 (5)	0.056 (4)	0.034 (4)	0.025 (4)	0.009 (3)	−0.002 (3)
C15	0.049 (4)	0.060 (5)	0.042 (4)	0.018 (4)	0.004 (3)	−0.003 (3)
C16	0.046 (4)	0.045 (4)	0.039 (3)	0.018 (3)	0.011 (3)	0.007 (3)
C17	0.080 (6)	0.119 (8)	0.068 (5)	0.049 (6)	0.030 (4)	−0.006 (5)
C21	0.043 (4)	0.046 (4)	0.027 (3)	0.024 (3)	0.006 (3)	0.007 (3)
C22	0.062 (4)	0.048 (4)	0.032 (3)	0.029 (4)	0.008 (3)	0.007 (3)
C23	0.089 (6)	0.083 (6)	0.040 (4)	0.060 (6)	0.006 (4)	0.011 (4)
C24	0.089 (7)	0.115 (8)	0.058 (5)	0.080 (7)	0.005 (5)	0.013 (5)
C25	0.045 (5)	0.096 (7)	0.073 (5)	0.034 (5)	0.012 (4)	0.012 (5)
C26	0.053 (5)	0.057 (4)	0.054 (4)	0.024 (4)	0.014 (3)	0.015 (3)
C27	0.148 (9)	0.092 (6)	0.062 (5)	0.089 (7)	0.020 (5)	0.030 (5)
C31	0.043 (4)	0.032 (3)	0.033 (3)	0.018 (3)	0.012 (3)	0.014 (3)
C32	0.036 (4)	0.036 (3)	0.041 (3)	0.010 (3)	0.009 (3)	0.011 (3)
C33	0.045 (4)	0.044 (4)	0.043 (4)	0.012 (3)	0.006 (3)	0.009 (3)
C34	0.057 (5)	0.040 (4)	0.056 (4)	0.005 (3)	0.017 (4)	0.008 (3)
C35	0.072 (5)	0.038 (4)	0.060 (4)	0.011 (4)	0.036 (4)	0.020 (3)
C36	0.061 (5)	0.042 (4)	0.040 (4)	0.014 (3)	0.015 (3)	0.011 (3)
C37	0.065 (5)	0.061 (5)	0.059 (5)	0.000 (4)	−0.007 (4)	0.012 (4)
C41	0.038 (4)	0.033 (3)	0.030 (3)	0.013 (3)	0.001 (2)	0.009 (2)
C42	0.044 (4)	0.031 (3)	0.034 (3)	0.012 (3)	0.011 (3)	0.011 (3)
C43	0.046 (4)	0.029 (3)	0.041 (3)	0.012 (3)	0.009 (3)	0.007 (3)
C44	0.055 (4)	0.035 (4)	0.044 (4)	0.022 (3)	0.009 (3)	0.012 (3)
C45	0.048 (4)	0.062 (5)	0.063 (4)	0.034 (4)	0.022 (3)	0.021 (4)
C46	0.051 (4)	0.041 (4)	0.059 (4)	0.020 (3)	0.017 (3)	0.020 (3)
C47	0.062 (5)	0.036 (4)	0.084 (5)	0.018 (4)	0.022 (4)	0.025 (4)
C51	0.038 (3)	0.035 (3)	0.030 (3)	0.011 (3)	0.009 (3)	0.011 (3)
C52	0.042 (4)	0.046 (4)	0.036 (3)	0.012 (3)	0.011 (3)	0.007 (3)
C53	0.055 (5)	0.061 (5)	0.046 (4)	0.017 (4)	0.025 (3)	0.012 (3)
C54	0.046 (4)	0.064 (5)	0.064 (5)	0.015 (4)	0.024 (4)	0.016 (4)
C55	0.036 (4)	0.063 (5)	0.065 (5)	0.007 (4)	0.005 (3)	0.009 (4)
C56	0.044 (4)	0.045 (4)	0.043 (4)	0.010 (3)	0.009 (3)	0.004 (3)
C57	0.084 (6)	0.126 (8)	0.066 (5)	0.030 (6)	0.043 (5)	0.007 (5)
C61	0.042 (4)	0.038 (3)	0.030 (3)	0.017 (3)	0.007 (3)	0.009 (3)
C62	0.036 (4)	0.044 (4)	0.033 (3)	0.008 (3)	0.006 (3)	0.006 (3)
C63	0.038 (4)	0.055 (4)	0.037 (4)	0.008 (3)	0.004 (3)	−0.001 (3)
C64	0.060 (5)	0.065 (5)	0.037 (4)	0.018 (4)	−0.003 (3)	0.002 (4)
C65	0.086 (6)	0.079 (6)	0.040 (4)	0.033 (5)	−0.002 (4)	0.019 (4)
C66	0.057 (4)	0.039 (4)	0.048 (4)	0.012 (3)	0.003 (3)	0.015 (3)
C67	0.065 (5)	0.059 (5)	0.058 (5)	−0.003 (4)	0.009 (4)	−0.006 (4)

Geometric parameters (Å, º)

Rh—C	1.792 (6)	C37—H37C	0.96
Rh—P1	2.3231 (16)	C41—C42	1.373 (8)
Rh—P2	2.3266 (16)	C41—C46	1.381 (8)
Rh—Cl1	2.3659 (15)	C42—C43	1.403 (7)
P1—C21	1.821 (6)	C42—H42	0.93
P1—C31	1.827 (6)	C43—C44	1.363 (8)
P1—C11	1.829 (5)	C43—C47	1.500 (8)
P2—C61	1.828 (6)	C44—C45	1.391 (9)
P2—C51	1.831 (6)	C44—H44	0.93
P2—C41	1.841 (5)	C45—C46	1.377 (8)
C—O	1.156 (6)	C45—H45	0.93
C11—C12	1.385 (7)	C46—H46	0.93
C11—C16	1.386 (8)	C47—H47A	0.96
C12—C13	1.380 (7)	C47—H47B	0.96
C12—H12	0.93	C47—H47C	0.96
C13—C14	1.371 (9)	C51—C52	1.373 (7)
C13—C17	1.514 (9)	C51—C56	1.395 (8)
C14—C15	1.374 (8)	C52—C53	1.384 (8)
C14—H14	0.93	C52—H52	0.93
C15—C16	1.385 (7)	C53—C54	1.369 (9)
C15—H15	0.93	C53—C57	1.520 (8)
C16—H16	0.93	C54—C55	1.367 (8)
C17—H17A	0.96	C54—H54	0.93
C17—H17B	0.96	C55—C56	1.382 (8)
C17—H17C	0.96	C55—H55	0.93
C21—C22	1.387 (8)	C56—H56	0.93
C21—C26	1.395 (8)	C57—H57A	0.96
C22—C23	1.392 (9)	C57—H57B	0.96
C22—H22	0.93	C57—H57C	0.96
C23—C24	1.368 (11)	C61—C62	1.384 (8)
C23—C27	1.509 (10)	C61—C66	1.402 (8)
C24—C25	1.369 (11)	C62—C63	1.399 (8)
C24—H24	0.93	C62—H62	0.93
C25—C26	1.395 (9)	C63—C64	1.380 (9)
C25—H25	0.93	C63—C67	1.489 (9)
C26—H26	0.93	C64—C65	1.378 (10)
C27—H27A	0.96	C64—H64	0.93
C27—H27B	0.96	C65—C66	1.386 (9)
C27—H27C	0.96	C65—H65	0.93
C31—C32	1.385 (7)	C66—H66	0.93
C31—C36	1.395 (7)	C67—H67A	0.96
C32—C33	1.383 (8)	C67—H67B	0.96
C32—H32	0.93	C67—H67C	0.96
C33—C34	1.386 (8)	C1A—Cl2A	1.66 (2)
C33—C37	1.521 (8)	C1A—Cl3A	1.82 (2)
C34—C35	1.363 (9)	C1A—H1A1	0.97
C34—H34	0.93	C1A—H1A2	0.97
C35—C36	1.391 (9)	C1B—Cl2B	1.72 (2)
C35—H35	0.93	C1B—Cl3B	1.86 (2)
C36—H36	0.93	C1B—H1B1	0.97
C37—H37A	0.96	C1B—H1B2	0.97
C37—H37B	0.96
C—Rh—P1	90.40 (18)	C33—C37—H37C	109.5
C—Rh—P2	92.62 (18)	H37A—C37—H37C	109.5
P1—Rh—P2	176.88 (6)	H37B—C37—H37C	109.5
C—Rh—Cl1	174.6 (2)	C42—C41—C46	118.9 (5)
P1—Rh—Cl1	88.98 (5)	C42—C41—P2	123.4 (4)
P2—Rh—Cl1	88.08 (5)	C46—C41—P2	117.7 (4)
C21—P1—C31	104.6 (3)	C41—C42—C43	121.4 (5)
C21—P1—C11	104.8 (2)	C41—C42—H42	119.3
C31—P1—C11	103.7 (3)	C43—C42—H42	119.3
C21—P1—Rh	113.12 (19)	C44—C43—C42	118.8 (6)
C31—P1—Rh	114.15 (18)	C44—C43—C47	121.3 (5)
C11—P1—Rh	115.27 (18)	C42—C43—C47	119.9 (5)
C61—P2—C51	105.2 (2)	C43—C44—C45	120.4 (5)
C61—P2—C41	101.2 (2)	C43—C44—H44	119.8
C51—P2—C41	104.5 (3)	C45—C44—H44	119.8
C61—P2—Rh	117.1 (2)	C46—C45—C44	120.1 (6)
C51—P2—Rh	109.98 (17)	C46—C45—H45	119.9
C41—P2—Rh	117.47 (18)	C44—C45—H45	119.9
O—C—Rh	176.3 (6)	C45—C46—C41	120.4 (6)
C12—C11—C16	117.7 (5)	C45—C46—H46	119.8
C12—C11—P1	121.1 (4)	C41—C46—H46	119.8
C16—C11—P1	120.9 (4)	C43—C47—H47A	109.5
C13—C12—C11	123.0 (6)	C43—C47—H47B	109.5
C13—C12—H12	118.5	H47A—C47—H47B	109.5
C11—C12—H12	118.5	C43—C47—H47C	109.5
C14—C13—C12	117.4 (6)	H47A—C47—H47C	109.5
C14—C13—C17	120.9 (6)	H47B—C47—H47C	109.5
C12—C13—C17	121.7 (6)	C52—C51—C56	118.7 (5)
C13—C14—C15	121.7 (6)	C52—C51—P2	124.0 (4)
C13—C14—H14	119.2	C56—C51—P2	117.2 (4)
C15—C14—H14	119.2	C51—C52—C53	121.9 (6)
C14—C15—C16	119.8 (6)	C51—C52—H52	119.1
C14—C15—H15	120.1	C53—C52—H52	119.1
C16—C15—H15	120.1	C54—C53—C52	118.5 (6)
C15—C16—C11	120.3 (6)	C54—C53—C57	121.5 (6)
C15—C16—H16	119.8	C52—C53—C57	120.0 (6)
C11—C16—H16	119.8	C55—C54—C53	120.8 (6)
C13—C17—H17A	109.5	C55—C54—H54	119.6
C13—C17—H17B	109.5	C53—C54—H54	119.6
H17A—C17—H17B	109.5	C54—C55—C56	120.7 (6)
C13—C17—H17C	109.5	C54—C55—H55	119.6
H17A—C17—H17C	109.5	C56—C55—H55	119.6
H17B—C17—H17C	109.5	C55—C56—C51	119.3 (6)
C22—C21—C26	118.3 (6)	C55—C56—H56	120.3
C22—C21—P1	123.8 (5)	C51—C56—H56	120.3
C26—C21—P1	117.8 (5)	C53—C57—H57A	109.5
C21—C22—C23	122.2 (7)	C53—C57—H57B	109.5
C21—C22—H22	118.9	H57A—C57—H57B	109.5
C23—C22—H22	118.9	C53—C57—H57C	109.5
C24—C23—C22	117.5 (7)	H57A—C57—H57C	109.5
C24—C23—C27	121.9 (7)	H57B—C57—H57C	109.5
C22—C23—C27	120.6 (8)	C62—C61—C66	118.8 (5)
C23—C24—C25	122.7 (7)	C62—C61—P2	121.3 (4)
C23—C24—H24	118.6	C66—C61—P2	119.9 (5)
C25—C24—H24	118.6	C61—C62—C63	122.2 (6)
C24—C25—C26	119.3 (8)	C61—C62—H62	118.9
C24—C25—H25	120.4	C63—C62—H62	118.9
C26—C25—H25	120.4	C64—C63—C62	117.4 (6)
C25—C26—C21	120.0 (7)	C64—C63—C67	121.2 (6)
C25—C26—H26	120	C62—C63—C67	121.4 (6)
C21—C26—H26	120	C65—C64—C63	121.7 (6)
C23—C27—H27A	109.5	C65—C64—H64	119.1
C23—C27—H27B	109.5	C63—C64—H64	119.1
H27A—C27—H27B	109.5	C64—C65—C66	120.5 (6)
C23—C27—H27C	109.5	C64—C65—H65	119.8
H27A—C27—H27C	109.5	C66—C65—H65	119.8
H27B—C27—H27C	109.5	C65—C66—C61	119.3 (6)
C32—C31—C36	118.3 (6)	C65—C66—H66	120.3
C32—C31—P1	119.0 (4)	C61—C66—H66	120.3
C36—C31—P1	122.7 (5)	C63—C67—H67A	109.5
C33—C32—C31	121.9 (5)	C63—C67—H67B	109.5
C33—C32—H32	119.1	H67A—C67—H67B	109.5
C31—C32—H32	119.1	C63—C67—H67C	109.5
C32—C33—C34	118.9 (6)	H67A—C67—H67C	109.5
C32—C33—C37	120.4 (6)	H67B—C67—H67C	109.5
C34—C33—C37	120.7 (6)	Cl2A—C1A—Cl3A	112.5 (12)
C35—C34—C33	120.2 (6)	Cl2A—C1A—H1A1	109.1
C35—C34—H34	119.9	Cl3A—C1A—H1A1	109.1
C33—C34—H34	119.9	Cl2A—C1A—H1A2	109.1
C34—C35—C36	121.0 (6)	Cl3A—C1A—H1A2	109.1
C34—C35—H35	119.5	H1A1—C1A—H1A2	107.8
C36—C35—H35	119.5	Cl2B—C1B—Cl3B	108.8 (11)
C35—C36—C31	119.7 (6)	Cl2B—C1B—H1B1	109.9
C35—C36—H36	120.1	Cl3B—C1B—H1B1	109.9
C31—C36—H36	120.1	Cl2B—C1B—H1B2	109.9
C33—C37—H37A	109.5	Cl3B—C1B—H1B2	109.9
C33—C37—H37B	109.5	H1B1—C1B—H1B2	108.3
H37A—C37—H37B	109.5
C11—P2—Rh—C	−6.3 (3)	C41—P2—Rh—C	0.6 (3)
C21—P2—Rh—C	−132.7 (3)	C51—P2—Rh—C	−118.8 (3)
C31—P2—Rh—C	117.1 (3)	C61—P2—Rh—C	121.3 (3)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C32—H32···Cl1	0.93	2.81	3.543 (6)	137
C67—H67C···Cl2A	0.96	2.75	3.505 (10)	137
C67—H67C···Cl2B	0.96	2.69	3.547 (9)	149