New RE microporous heteropolyhedral silicates containing 4¹5¹6¹8² tetrahedral sheets

Four heteropolyhedral microporous silicates, A₃RESi₆O₁₅·2.25H₂O, crystallizing in the Cmm2 space group and based on 4¹5¹6¹8² tetrahedral sheets [A₃ = Na_2.74K_0.26, RE = Ce, abbreviated as TR05; TR06: A₃ = Na_2.72K_0.28, RE = La; TR07: A₃ = Na₃, RE = La; TR08: A₃ = Na_2.74(H₃O)_0.26, RE = La_0.68Eu_0.32] have been hydrothermally synthesized in Teflon-lined autoclaves at 503 K and structurally characterized using X-ray diffraction single-crystal data. Except for TR05, diffraction data have been collected on {001} twins by merohedry. The four structures are isotypic and based on strongly corrugated 4¹5¹6¹8² silicate sheets interconnected along [010] by seven-coordinated RE polyhedra to form a microporous heteropolyhedral framework. The framework is crossed by three systems of ellipsoidal channels that host H₂O molecules and alkaline ions. The channels run either parallel or perpendicular to the silicate sheets; the largest effective channel width is 4.7 × 2 Å. In TR08 some (H₃O)⁺ replaces alkalis. Although the H atoms have not been localized, the configuration of the hydrogen bonding has been deduced from bond lengths and angles.

Computing details

Data collection: CrysAlis RED, oxford diffraction ltd., version 1.171.32.13 (release 29-11-2007 crysalis171 .net) (compiled nov 29 2007,17:23:28) empirical absorption correction using spherical harmonics, implemented in scale3 abspack scaling algorithm. for TR05; CrysAlis CCD, Oxford Diffraction Ltd., Version 1.171.32.27 (release 29-05-2008 CrysAlis171 .NET) (compiled May 29 2008,13:12:44) for TR06; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.13 (release 29-11-2007 CrysAlis171 .NET) (compiled Nov 29 2007,17:23:28) for TR07; CrysAlis CCD, Oxford Diffraction Ltd., Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) (compiled Jun 10 2008,16:49:55) for TR08. Cell refinement: CrysAlis RED, oxford diffraction ltd., version 1.171.32.13 (release 29-11-2007 crysalis171 .net) (compiled nov 29 2007,17:23:28) empirical absorption correction using spherical harmonics, implemented in scale3 abspack scaling algorithm. for TR05; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.27 (release 29-05-2008 CrysAlis171 .NET) (compiled May 29 2008,13:12:44) for TR06; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.13 (release 29-11-2007 CrysAlis171 .NET) (compiled Nov 29 2007,17:23:28) for TR07; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) (compiled Jun 10 2008,16:49:55) for TR08. Data reduction: CrysAlis RED, oxford diffraction ltd., version 1.171.32.13 (release 29-11-2007 crysalis171 .net) (compiled nov 29 2007,17:23:28) empirical absorption correction using spherical harmonics, implemented in scale3 abspack scaling algorithm. for TR05; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.27 (release 29-05-2008 CrysAlis171 .NET) (compiled May 29 2008,13:12:44) for TR06; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.13 (release 29-11-2007 CrysAlis171 .NET) (compiled Nov 29 2007,17:23:28) for TR07; CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) (compiled Jun 10 2008,16:49:55) for TR08. Program(s) used to solve structure: SHELXS97 (Sheldrick, 1997) for TR05, TR07, TR08; SHELXS86 (Sheldrick, 1986) for TR06. For all structures, program(s) used to refine structure: SHELXL97 (Sheldrick, 1997). Molecular graphics: ATOMS 6.2 for TR05, TR07, TR08; Atoms 6.2 for TR06. Software used to prepare material for publication: WinGX publication routines (Farrugia, 1999) for TR06.

Trisodium Cerium Phyllo-hexasilicate Dihydrate (TR05)

Crystal data

CeH4.5Na2.74K0.26O17.25Si6	Dx = 2.671 Mg m^−3
Mr = 662.35	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmm2	Cell parameters from 12761 reflections
a = 7.4128 (1) Å	θ = 3.1–32.6°
b = 30.9652 (6) Å	µ = 3.43 mm^−1
c = 7.1756 (1) Å	T = 293 K
V = 1647.08 (5) Å^3	Prismatic, colourless
Z = 4	0.18 × 0.05 × 0.04 mm
F(000) = 1278

Data collection

Oxford X'Calibur Gemini Ultra diffractometer	3182 independent reflections
Radiation source: fine-focus sealed tube	2987 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.047
Detector resolution: 10.289 pixels mm^-1	θmax = 32.7°, θmin = 3.1°
phi/ω scans	h = −11→10
Absorption correction: multi-scan crysalis red, oxford diffraction ltd., version 1.171.32.13 (release 29-11-2007 crysalis171 .net) (compiled nov 29 2007,17:23:28) empirical (using intensity measurements) absorption correction using spherical harmonics, implemented in scale3 abspack scaling algorithm.	k = −46→46
Tmin = 0.886, Tmax = 1	l = −10→10
26071 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.033	w = 1/[σ^2(Fo^2) + (0.1116P)^2 + 16.3552P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.093	(Δ/σ)max = 0.001
S = 0.64	Δρmax = 2.63 e Å^−3
3182 reflections	Δρmin = −0.75 e Å^−3
149 parameters	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
1 restraint	Absolute structure parameter: −0.008 (15)
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ce1	0.5000	0.369159 (7)	−0.67290 (5)	0.01030 (8)
Na1	0.0000	0.37498 (11)	−0.6905 (9)	0.0331 (10)
Na2	0.2197 (5)	0.26184 (15)	0.4745 (6)	0.022 (3)	0.374 (17)
K2	0.2197 (5)	0.26184 (15)	0.4745 (6)	0.071 (15)*	0.126 (17)
Na3	0.2414 (9)	0.4642 (2)	−0.8828 (9)	0.0475 (15)*	0.50
Si1	0.5000	0.31882 (5)	−0.2635 (2)	0.0105 (3)
Si2	0.5000	0.41640 (4)	−0.1650 (3)	0.0101 (2)
Si3	0.20809 (13)	0.45030 (3)	−0.42275 (15)	0.00922 (17)
Si4	0.20738 (14)	0.29819 (3)	−0.96149 (17)	0.01212 (19)
O1	0.3229 (5)	0.30375 (11)	−0.1533 (6)	0.0284 (8)
O2	0.0000	0.29905 (15)	−0.0353 (6)	0.0164 (8)
O3	0.2500	0.2500	−0.8783 (7)	0.0196 (10)
O4	0.2392 (6)	0.5000	−0.4901 (7)	0.0166 (8)
O5	0.2591 (4)	0.41797 (10)	−0.5844 (4)	0.0174 (6)
O6	0.5000	0.41090 (13)	−0.9458 (6)	0.0158 (8)
O7	0.0000	0.44529 (16)	−0.3545 (6)	0.0172 (8)
O8	0.3224 (4)	0.44326 (10)	−0.2313 (4)	0.0174 (6)
O9	0.5000	0.37151 (13)	−0.2866 (7)	0.0180 (9)
O10	0.5000	0.30167 (15)	−0.4718 (7)	0.0320 (13)
O11	0.2473 (5)	0.33258 (12)	−0.8046 (6)	0.0261 (8)
OW1	0.5000	0.5000	0.179 (2)	0.030 (3)*	0.50
OW2	0.0000	0.3114 (4)	−0.456 (2)	0.093 (4)*
OW3	0.0726 (15)	0.4441 (4)	−0.9067 (19)	0.058 (3)*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ce1	0.01030 (12)	0.01041 (12)	0.01019 (11)	0.000	0.000	−0.00138 (13)
Na1	0.0161 (11)	0.0389 (15)	0.044 (3)	0.000	0.000	−0.021 (2)
Na2	0.012 (3)	0.025 (4)	0.031 (5)	−0.0070 (19)	0.0040 (19)	−0.008 (2)
Si1	0.0099 (6)	0.0114 (6)	0.0103 (7)	0.000	0.000	0.0023 (5)
Si2	0.0094 (5)	0.0109 (5)	0.0100 (5)	0.000	0.000	0.0019 (7)
Si3	0.0086 (4)	0.0086 (4)	0.0105 (4)	0.0010 (3)	−0.0010 (3)	−0.0007 (3)
Si4	0.0084 (4)	0.0103 (4)	0.0176 (5)	−0.0006 (3)	−0.0009 (4)	0.0001 (4)
O1	0.0191 (13)	0.0297 (15)	0.037 (2)	0.0005 (12)	0.0157 (16)	0.0160 (17)
O2	0.0108 (16)	0.023 (2)	0.0153 (19)	0.000	0.000	−0.0047 (16)
O3	0.026 (2)	0.014 (2)	0.019 (2)	0.0010 (17)	0.000	0.000
O4	0.0176 (19)	0.0144 (18)	0.018 (2)	0.000	0.0010 (16)	0.000
O5	0.0180 (13)	0.0174 (14)	0.0167 (14)	0.0041 (11)	0.0004 (11)	−0.0039 (11)
O6	0.023 (2)	0.0157 (18)	0.0092 (18)	0.000	0.000	0.0041 (14)
O7	0.0074 (16)	0.024 (2)	0.020 (2)	0.000	0.000	0.0023 (17)
O8	0.0141 (13)	0.0211 (13)	0.0172 (12)	0.0043 (11)	−0.0039 (11)	−0.0032 (11)
O9	0.026 (2)	0.0114 (19)	0.017 (2)	0.000	0.000	−0.0005 (14)
O10	0.071 (4)	0.0145 (19)	0.0109 (19)	0.000	0.000	−0.0023 (16)
O11	0.0209 (15)	0.0197 (15)	0.038 (2)	−0.0007 (13)	−0.0120 (15)	−0.0131 (15)

Geometric parameters (Å, º)

Ce1—O6	2.346 (4)	O2—O3^vi	2.648 (4)
Ce1—O11	2.384 (3)	O2—O11^vi	2.680 (5)
Ce1—O11^i	2.384 (3)	O2—O11^xiii	2.680 (5)
Ce1—O5^i	2.424 (3)	O2—OW2	3.046 (15)
Ce1—O5	2.424 (3)	O2—Na1^vi	3.414 (7)
Ce1—O10	2.540 (5)	O2—K2^xiv	4.043 (6)
Ce1—O9	2.773 (5)	O2—K2^iv	4.043 (6)
Ce1—Si1	3.3254 (16)	O3—Si4^v	1.638 (2)
Ce1—Na1	3.7129 (3)	O3—K2^iv	2.568 (7)
Ce1—Na1^ii	3.7129 (3)	O3—Na2^iv	2.568 (7)
Ce1—Na3^i	3.821 (7)	O3—K2^x	2.568 (7)
Ce1—Na3	3.821 (7)	O3—Na2^x	2.568 (7)
Na1—O11^iii	2.399 (4)	O3—O11^v	2.611 (4)
Na1—O11	2.399 (4)	O3—O11	2.611 (4)
Na1—O5	2.458 (4)	O3—O1^x	2.637 (6)
Na1—O5^iii	2.458 (4)	O3—O1^iv	2.637 (6)
Na1—OW2	2.588 (14)	O3—O2^iv	2.648 (4)
Na1—OW3	2.698 (13)	O3—O2^x	2.648 (4)
Na1—OW3^iii	2.698 (13)	O4—Si3^viii	1.6295 (19)
Na1—O7	3.248 (7)	O4—O8^viii	2.630 (5)
Na1—Si3	3.393 (4)	O4—O8	2.630 (5)
Na1—Si3^iii	3.393 (4)	O4—O5	2.633 (3)
Na1—O2^iv	3.414 (7)	O4—O5^viii	2.633 (3)
Na1—Si4^iii	3.435 (4)	O4—O7	2.638 (5)
Na2—K2^v	0.860 (9)	O4—O7^xv	2.638 (5)
Na2—Na2^v	0.860 (9)	O4—Na3^viii	3.029 (8)
Na2—OW2^vi	2.291 (9)	O4—OW1^iv	3.062 (15)
Na2—O10^vi	2.447 (5)	O5—O7	2.669 (5)
Na2—O3^vi	2.568 (7)	O5—O8	2.693 (4)
Na2—O10^vii	2.582 (6)	O5—OW3	2.814 (13)
Na2—O11^vi	2.975 (6)	O5—O11	3.081 (5)
Na2—O1^vi	3.066 (7)	O5—O9	3.134 (5)
Na2—OW2^vii	3.115 (10)	O5—O6	3.156 (5)
Na2—K2^iii	3.257 (8)	O5—OW3^iii	3.471 (13)
Na2—Na2^iii	3.257 (8)	O6—Si2^iv	1.582 (5)
Na2—Si1^vi	3.311 (4)	O6—Na3^i	2.569 (7)
K2—K2^v	0.860 (9)	O6—O8^iv	2.633 (5)
K2—Na2^v	0.860 (9)	O6—O8^ix	2.633 (5)
K2—OW2^vi	2.291 (9)	O6—O9^iv	2.733 (7)
K2—O10^vi	2.447 (5)	O6—OW1^iv	2.901 (7)
K2—O3^vi	2.568 (7)	O6—O5^i	3.156 (5)
K2—O10^vii	2.582 (6)	O6—O11	3.227 (5)
K2—O11^vi	2.975 (6)	O6—O11^i	3.227 (5)
K2—O1^vi	3.066 (7)	O7—Si3^iii	1.6257 (18)
K2—OW2^vii	3.115 (10)	O7—O8	2.549 (3)
K2—Na2^iii	3.257 (8)	O7—O8^iii	2.549 (3)
K2—K2^iii	3.257 (8)	O7—O4^xv	2.638 (5)
K2—Si1^vi	3.311 (4)	O7—O5^iii	2.669 (5)
Na3—OW3	1.407 (13)	O7—OW3^vi	3.258 (15)
Na3—Na3^viii	2.220 (14)	O7—OW3^xiii	3.258 (15)
Na3—OW1^iv	2.259 (8)	O7—O7^xv	3.388 (10)
Na3—OW3^iii	2.415 (13)	O8—O9	2.613 (5)
Na3—O6	2.569 (7)	O8—O8^i	2.633 (6)
Na3—O5	2.578 (7)	O8—O6^vi	2.633 (5)
Na3—O8^iv	2.652 (7)	O8—Na3^vi	2.652 (7)
Na3—O4	3.029 (8)	O8—OW3^vi	2.976 (13)
Na3—OW3^viii	3.108 (14)	O8—Na3^xvi	3.851 (8)
Na3—Si2^iv	3.156 (7)	O9—O10	2.538 (6)
Na3—Si3	3.338 (7)	O9—O8^i	2.613 (5)
Si1—O10	1.586 (5)	O9—O1^i	2.654 (5)
Si1—O1^i	1.603 (3)	O9—O6^vi	2.733 (7)
Si1—O1	1.603 (3)	O9—O5^i	3.134 (5)
Si1—O9	1.640 (4)	O10—K2^iv	2.447 (5)
Si1—K2^iv	3.311 (4)	O10—Na2^iv	2.447 (5)
Si1—Na2^iv	3.311 (4)	O10—K2^ix	2.447 (5)
Si1—K2^ix	3.311 (4)	O10—Na2^ix	2.447 (5)
Si1—Na2^ix	3.311 (4)	O10—K2^x	2.582 (6)
Si1—Na2^x	3.525 (5)	O10—Na2^x	2.582 (6)
Si1—K2^x	3.525 (5)	O10—K2^xi	2.582 (6)
Si1—Na2^xi	3.525 (5)	O10—Na2^xi	2.582 (6)
Si2—O6^vi	1.582 (5)	O10—O1^i	2.636 (6)
Si2—O8	1.628 (3)	O11—O2^iv	2.680 (5)
Si2—O8^i	1.628 (3)	O11—O1^iv	2.715 (6)
Si2—O9	1.641 (5)	O11—K2^iv	2.975 (6)
Si2—Na3^xii	3.156 (7)	O11—Na2^iv	2.975 (6)
Si2—Na3^vi	3.156 (7)	O11—OW2	3.167 (13)
Si3—O5	1.578 (3)	OW1—Na3^xvii	2.259 (8)
Si3—O7	1.6257 (18)	OW1—Na3^vi	2.259 (8)
Si3—O8	1.629 (3)	OW1—Na3^xii	2.259 (8)
Si3—O4	1.6295 (19)	OW1—Na3^xvi	2.259 (8)
Si4—O11	1.578 (4)	OW1—O6^vi	2.901 (7)
Si4—O2^iv	1.6263 (18)	OW1—O6^xvii	2.901 (7)
Si4—O1^iv	1.630 (4)	OW1—O4^xvii	3.062 (14)
Si4—O3	1.638 (2)	OW1—O4^vi	3.062 (14)
Si4—Na2^iv	3.326 (5)	OW2—K2^xiv	2.291 (9)
Si4—K2^iv	3.326 (5)	OW2—Na2^xiv	2.291 (9)
Si4—K2^x	3.679 (4)	OW2—K2^iv	2.291 (9)
O1—Si4^vi	1.630 (4)	OW2—Na2^iv	2.291 (9)
O1—O2	2.543 (3)	OW2—K2^xviii	3.115 (10)
O1—O1^i	2.626 (7)	OW2—Na2^xviii	3.115 (10)
O1—O10	2.636 (6)	OW2—K2^x	3.115 (10)
O1—O3^vi	2.637 (5)	OW2—Na2^x	3.115 (10)
O1—O9	2.654 (5)	OW2—O11^iii	3.167 (13)
O1—O11^vi	2.715 (6)	OW3—OW3^iii	1.08 (2)
O1—K2^iv	3.066 (7)	OW3—Na3^iii	2.415 (13)
O1—Na2^iv	3.066 (7)	OW3—O8^iv	2.976 (13)
O1—OW2	3.243 (11)	OW3—Na3^viii	3.108 (14)
O1—K2^x	3.370 (7)	OW3—O7^iv	3.258 (15)
O2—Si4^vi	1.6263 (18)	OW3—OW3^viii	3.46 (2)
O2—Si4^xiii	1.6263 (18)	OW3—O5^iii	3.471 (13)
O2—O1^iii	2.543 (4)	OW3—Na3^xv	3.676 (13)
O2—O3^xiii	2.648 (4)
O6—Ce1—O11	86.04 (12)	Si3—O4—O8^viii	117.0 (2)
O6—Ce1—O11^i	86.04 (12)	Si3^viii—O4—O8	117.0 (2)
O11—Ce1—O11^i	103.56 (18)	Si3—O4—O8	36.17 (12)
O6—Ce1—O5^i	82.83 (10)	O8^viii—O4—O8	83.84 (19)
O11—Ce1—O5^i	168.17 (13)	Si3^viii—O4—O5	174.5 (3)
O11^i—Ce1—O5^i	79.70 (12)	Si3—O4—O5	34.21 (10)
O6—Ce1—O5	82.83 (11)	O8^viii—O4—O5	144.4 (2)
O11—Ce1—O5	79.70 (12)	O8—O4—O5	61.56 (10)
O11^i—Ce1—O5	168.17 (13)	Si3^viii—O4—O5^viii	34.21 (10)
O5^i—Ce1—O5	94.90 (15)	Si3—O4—O5^viii	174.5 (3)
O6—Ce1—O10	158.06 (15)	O8^viii—O4—O5^viii	61.56 (10)
O11—Ce1—O10	80.46 (12)	O8—O4—O5^viii	144.4 (2)
O11^i—Ce1—O10	80.46 (12)	O5—O4—O5^viii	149.5 (3)
O5^i—Ce1—O10	111.35 (10)	Si3^viii—O4—O7	113.7 (2)
O5—Ce1—O10	111.35 (10)	Si3—O4—O7	35.81 (13)
O6—Ce1—O9	145.06 (14)	O8^viii—O4—O7	109.0 (2)
O11—Ce1—O9	114.12 (12)	O8—O4—O7	57.88 (12)
O11^i—Ce1—O9	114.12 (12)	O5—O4—O7	60.85 (12)
O5^i—Ce1—O9	73.84 (10)	O5^viii—O4—O7	138.8 (2)
O5—Ce1—O9	73.84 (10)	Si3^viii—O4—O7^xv	35.81 (13)
O10—Ce1—O9	56.88 (14)	Si3—O4—O7^xv	113.7 (2)
O6—Ce1—Si1	174.52 (11)	O8^viii—O4—O7^xv	57.88 (12)
O11—Ce1—Si1	97.32 (11)	O8—O4—O7^xv	109.0 (2)
O11^i—Ce1—Si1	97.32 (11)	O5—O4—O7^xv	138.8 (2)
O5^i—Ce1—Si1	93.49 (8)	O5^viii—O4—O7^xv	60.85 (12)
O5—Ce1—Si1	93.49 (8)	O7—O4—O7^xv	79.9 (2)
O10—Ce1—Si1	27.42 (12)	Si3^viii—O4—Na3	128.5 (2)
O9—Ce1—Si1	29.46 (9)	Si3—O4—Na3	86.03 (18)
O6—Ce1—Na1	86.84 (9)	O8^viii—O4—Na3	154.2 (2)
O11—Ce1—Na1	39.23 (11)	O8—O4—Na3	114.26 (16)
O11^i—Ce1—Na1	142.55 (13)	O5—O4—Na3	53.64 (16)
O5^i—Ce1—Na1	135.56 (10)	O5^viii—O4—Na3	96.6 (2)
O5—Ce1—Na1	40.82 (9)	O7—O4—Na3	96.39 (19)
O10—Ce1—Na1	93.40 (8)	O7^xv—O4—Na3	125.6 (2)
O9—Ce1—Na1	91.87 (10)	Si3^viii—O4—Na3^viii	86.03 (18)
Si1—Ce1—Na1	93.02 (10)	Si3—O4—Na3^viii	128.5 (2)
O6—Ce1—Na1^ii	86.84 (9)	O8^viii—O4—Na3^viii	114.26 (16)
O11—Ce1—Na1^ii	142.55 (13)	O8—O4—Na3^viii	154.2 (2)
O11^i—Ce1—Na1^ii	39.23 (11)	O5—O4—Na3^viii	96.6 (2)
O5^i—Ce1—Na1^ii	40.82 (9)	O5^viii—O4—Na3^viii	53.64 (16)
O5—Ce1—Na1^ii	135.56 (10)	O7—O4—Na3^viii	125.6 (2)
O10—Ce1—Na1^ii	93.40 (8)	O7^xv—O4—Na3^viii	96.39 (19)
O9—Ce1—Na1^ii	91.87 (10)	Na3—O4—Na3^viii	43.0 (3)
Si1—Ce1—Na1^ii	93.02 (10)	Si3^viii—O4—OW1^iv	108.63 (16)
Na1—Ce1—Na1^ii	173.21 (15)	Si3—O4—OW1^iv	108.63 (16)
O6—Ce1—Na3^i	41.13 (12)	O8^viii—O4—OW1^iv	113.6 (2)
O11—Ce1—Na3^i	127.13 (14)	O8—O4—OW1^iv	113.6 (2)
O11^i—Ce1—Na3^i	79.36 (13)	O5—O4—OW1^iv	76.43 (13)
O5^i—Ce1—Na3^i	41.73 (12)	O5^viii—O4—OW1^iv	76.43 (13)
O5—Ce1—Na3^i	89.59 (13)	O7—O4—OW1^iv	135.26 (17)
O10—Ce1—Na3^i	149.05 (10)	O7^xv—O4—OW1^iv	135.26 (17)
O9—Ce1—Na3^i	111.95 (12)	Na3—O4—OW1^iv	43.5 (2)
Si1—Ce1—Na3^i	135.17 (10)	Na3^viii—O4—OW1^iv	43.5 (2)
Na1—Ce1—Na3^i	116.75 (12)	Si3—O5—Ce1	139.87 (18)
Na1^ii—Ce1—Na3^i	56.52 (12)	Si3—O5—Na1	112.58 (19)
O6—Ce1—Na3	41.13 (12)	Ce1—O5—Na1	99.03 (13)
O11—Ce1—Na3	79.36 (13)	Si3—O5—Na3	104.3 (2)
O11^i—Ce1—Na3	127.13 (14)	Ce1—O5—Na3	99.54 (18)
O5^i—Ce1—Na3	89.59 (13)	Na1—O5—Na3	90.2 (2)
O5—Ce1—Na3	41.73 (13)	Si3—O5—O4	35.48 (13)
O10—Ce1—Na3	149.05 (10)	Ce1—O5—O4	135.24 (17)
O9—Ce1—Na3	111.95 (12)	Na1—O5—O4	123.94 (17)
Si1—Ce1—Na3	135.17 (10)	Na3—O5—O4	71.1 (2)
Na1—Ce1—Na3	56.52 (12)	Si3—O5—O7	34.15 (11)
Na1^ii—Ce1—Na3	116.75 (12)	Ce1—O5—O7	152.82 (18)
Na3^i—Ce1—Na3	60.2 (2)	Na1—O5—O7	78.50 (16)
O11^iii—Na1—O11	99.7 (2)	Na3—O5—O7	107.5 (2)
O11^iii—Na1—O5	177.9 (3)	O4—O5—O7	59.68 (15)
O11—Na1—O5	78.75 (11)	Si3—O5—O8	33.48 (10)
O11^iii—Na1—O5^iii	78.75 (11)	Ce1—O5—O8	107.42 (13)
O11—Na1—O5^iii	177.9 (3)	Na1—O5—O8	125.8 (2)
O5—Na1—O5^iii	102.8 (2)	Na3—O5—O8	129.0 (2)
O11^iii—Na1—OW2	78.8 (2)	O4—O5—O8	59.17 (14)
O11—Na1—OW2	78.8 (2)	O7—O5—O8	56.77 (12)
O5—Na1—OW2	102.2 (3)	Si3—O5—OW3	107.7 (3)
O5^iii—Na1—OW2	102.2 (3)	Ce1—O5—OW3	109.0 (3)
O11^iii—Na1—OW3	113.0 (3)	Na1—O5—OW3	61.1 (3)
O11—Na1—OW3	94.9 (3)	Na3—O5—OW3	29.8 (3)
O5—Na1—OW3	66.0 (3)	O4—O5—OW3	84.6 (3)
O5^iii—Na1—OW3	84.5 (3)	O7—O5—OW3	93.6 (3)
OW2—Na1—OW3	167.7 (3)	O8—O5—OW3	140.8 (3)
O11^iii—Na1—OW3^iii	94.9 (3)	Si3—O5—O11	156.1 (2)
O11—Na1—OW3^iii	113.0 (3)	Ce1—O5—O11	49.58 (9)
O5—Na1—OW3^iii	84.5 (3)	Na1—O5—O11	49.78 (11)
O5^iii—Na1—OW3^iii	66.0 (3)	Na3—O5—O11	92.79 (19)
OW2—Na1—OW3^iii	167.7 (3)	O4—O5—O11	163.34 (18)
OW3—Na1—OW3^iii	23.0 (5)	O7—O5—O11	124.64 (17)
O11^iii—Na1—O7	128.33 (14)	O8—O5—O11	137.46 (15)
O11—Na1—O7	128.33 (14)	OW3—O5—O11	79.1 (3)
O5—Na1—O7	53.64 (11)	Si3—O5—O9	85.79 (15)
O5^iii—Na1—O7	53.64 (11)	Ce1—O5—O9	58.18 (10)
OW2—Na1—O7	91.6 (4)	Na1—O5—O9	114.07 (17)
OW3—Na1—O7	84.0 (3)	Na3—O5—O9	148.18 (19)
OW3^iii—Na1—O7	84.0 (3)	O4—O5—O9	107.43 (17)
O11^iii—Na1—Si3	156.49 (17)	O7—O5—O9	97.71 (15)
O11—Na1—Si3	102.83 (10)	O8—O5—O9	52.61 (12)
O5—Na1—Si3	25.44 (9)	OW3—O5—O9	166.5 (3)
O5^iii—Na1—Si3	78.91 (13)	O11—O5—O9	88.39 (14)
OW2—Na1—Si3	99.0 (3)	Si3—O5—O6	141.57 (19)
OW3—Na1—Si3	71.9 (3)	Ce1—O5—O6	47.52 (8)
OW3^iii—Na1—Si3	82.6 (3)	Na1—O5—O6	98.64 (17)
O7—Na1—Si3	28.23 (5)	Na3—O5—O6	52.04 (17)
O11^iii—Na1—Si3^iii	102.83 (10)	O4—O5—O6	108.04 (17)
O11—Na1—Si3^iii	156.49 (17)	O7—O5—O6	159.52 (17)
O5—Na1—Si3^iii	78.91 (13)	O8—O5—O6	133.99 (14)
O5^iii—Na1—Si3^iii	25.44 (9)	OW3—O5—O6	67.8 (3)
OW2—Na1—Si3^iii	99.0 (3)	O11—O5—O6	62.31 (12)
OW3—Na1—Si3^iii	82.6 (3)	O9—O5—O6	101.88 (12)
OW3^iii—Na1—Si3^iii	71.9 (3)	Si3—O5—OW3^iii	99.9 (2)
O7—Na1—Si3^iii	28.23 (5)	Ce1—O5—OW3^iii	119.5 (2)
Si3—Na1—Si3^iii	54.09 (8)	Na1—O5—OW3^iii	50.7 (2)
O11^iii—Na1—O2^iv	51.36 (12)	Na3—O5—OW3^iii	44.1 (2)
O11—Na1—O2^iv	51.36 (12)	O4—O5—OW3^iii	84.6 (2)
O5—Na1—O2^iv	126.69 (14)	O7—O5—OW3^iii	80.1 (2)
O5^iii—Na1—O2^iv	126.69 (14)	O8—O5—OW3^iii	133.0 (2)
OW2—Na1—O2^iv	86.9 (3)	OW3—O5—OW3^iii	15.7 (3)
OW3—Na1—O2^iv	97.4 (3)	O11—O5—OW3^iii	80.7 (2)
OW3^iii—Na1—O2^iv	97.4 (3)	O9—O5—OW3^iii	164.8 (2)
O7—Na1—O2^iv	178.6 (2)	O6—O5—OW3^iii	82.5 (2)
Si3—Na1—O2^iv	152.13 (8)	Si2^iv—O6—Ce1	152.8 (3)
Si3^iii—Na1—O2^iv	152.13 (8)	Si2^iv—O6—Na3^i	96.1 (2)
O11^iii—Na1—Si4^iii	23.92 (9)	Ce1—O6—Na3^i	101.94 (19)
O11—Na1—Si4^iii	76.70 (14)	Si2^iv—O6—Na3	96.1 (2)
O5—Na1—Si4^iii	154.16 (17)	Ce1—O6—Na3	101.94 (19)
O5^iii—Na1—Si4^iii	101.57 (9)	Na3^i—O6—Na3	96.5 (3)
OW2—Na1—Si4^iii	80.8 (3)	Si2^iv—O6—O8^iv	35.46 (10)
OW3—Na1—Si4^iii	108.2 (3)	Ce1—O6—O8^iv	149.20 (9)
OW3^iii—Na1—Si4^iii	97.7 (3)	Na3^i—O6—O8^iv	105.4 (2)
O7—Na1—Si4^iii	152.15 (9)	Na3—O6—O8^iv	61.28 (17)
Si3—Na1—Si4^iii	179.51 (7)	Si2^iv—O6—O8^ix	35.46 (10)
Si3^iii—Na1—Si4^iii	126.37 (2)	Ce1—O6—O8^ix	149.20 (9)
O2^iv—Na1—Si4^iii	27.47 (4)	Na3^i—O6—O8^ix	61.28 (17)
K2^v—Na2—Na2^v	0.0 (7)	Na3—O6—O8^ix	105.4 (2)
K2^v—Na2—OW2^vi	160.4 (6)	O8^iv—O6—O8^ix	59.98 (17)
Na2^v—Na2—OW2^vi	160.4 (6)	Si2^iv—O6—O9^iv	32.69 (14)
K2^v—Na2—O10^vi	89.2 (5)	Ce1—O6—O9^iv	120.07 (18)
Na2^v—Na2—O10^vi	89.2 (5)	Na3^i—O6—O9^iv	116.35 (19)
OW2^vi—Na2—O10^vi	103.4 (3)	Na3—O6—O9^iv	116.35 (19)
K2^v—Na2—O3^vi	80.36 (11)	O8^iv—O6—O9^iv	58.23 (13)
Na2^v—Na2—O3^vi	80.36 (11)	O8^ix—O6—O9^iv	58.23 (13)
OW2^vi—Na2—O3^vi	111.8 (4)	Si2^iv—O6—OW1^iv	101.8 (4)
O10^vi—Na2—O3^vi	98.80 (19)	Ce1—O6—OW1^iv	105.5 (4)
K2^v—Na2—O10^vii	71.3 (5)	Na3^i—O6—OW1^iv	48.32 (17)
Na2^v—Na2—O10^vii	71.3 (5)	Na3—O6—OW1^iv	48.32 (17)
OW2^vi—Na2—O10^vii	91.7 (3)	O8^iv—O6—OW1^iv	83.0 (3)
O10^vi—Na2—O10^vii	153.6 (3)	O8^ix—O6—OW1^iv	83.0 (3)
O3^vi—Na2—O10^vii	95.37 (18)	O9^iv—O6—OW1^iv	134.5 (4)
K2^v—Na2—O11^vi	126.3 (3)	Si2^iv—O6—O5^i	144.03 (9)
Na2^v—Na2—O11^vi	126.3 (3)	Ce1—O6—O5^i	49.65 (9)
OW2^vi—Na2—O11^vi	72.6 (4)	Na3^i—O6—O5^i	52.32 (17)
O10^vi—Na2—O11^vi	71.13 (17)	Na3—O6—O5^i	103.5 (2)
O3^vi—Na2—O11^vi	55.63 (12)	O8^iv—O6—O5^i	153.60 (19)
O10^vii—Na2—O11^vi	134.8 (2)	O8^ix—O6—O5^i	109.27 (11)
K2^v—Na2—O1^vi	103.3 (3)	O9^iv—O6—O5^i	140.02 (11)
Na2^v—Na2—O1^vi	103.3 (3)	OW1^iv—O6—O5^i	71.4 (3)
OW2^vi—Na2—O1^vi	72.9 (3)	Si2^iv—O6—O5	144.03 (9)
O10^vi—Na2—O1^vi	55.79 (15)	Ce1—O6—O5	49.65 (9)
O3^vi—Na2—O1^vi	153.82 (18)	Na3^i—O6—O5	103.5 (2)
O10^vii—Na2—O1^vi	110.5 (2)	Na3—O6—O5	52.32 (17)
O11^vi—Na2—O1^vi	104.93 (16)	O8^iv—O6—O5	109.27 (11)
K2^v—Na2—OW2^vii	14.3 (4)	O8^ix—O6—O5	153.60 (19)
Na2^v—Na2—OW2^vii	14.3 (4)	O9^iv—O6—O5	140.02 (11)
OW2^vi—Na2—OW2^vii	158.0 (7)	OW1^iv—O6—O5	71.4 (3)
O10^vi—Na2—OW2^vii	77.0 (2)	O5^i—O6—O5	68.92 (14)
O3^vi—Na2—OW2^vii	89.7 (3)	Si2^iv—O6—O11	113.15 (18)
O10^vii—Na2—OW2^vii	80.9 (2)	Ce1—O6—O11	47.47 (9)
O11^vi—Na2—OW2^vii	126.7 (3)	Na3^i—O6—O11	149.4 (2)
O1^vi—Na2—OW2^vii	90.2 (3)	Na3—O6—O11	89.66 (17)
K2^v—Na2—K2^iii	121.5 (5)	O8^iv—O6—O11	103.89 (12)
Na2^v—Na2—K2^iii	121.5 (5)	O8^ix—O6—O11	145.11 (19)
OW2^vi—Na2—K2^iii	44.7 (2)	O9^iv—O6—O11	86.88 (14)
O10^vi—Na2—K2^iii	148.12 (14)	OW1^iv—O6—O11	128.2 (3)
O3^vi—Na2—K2^iii	95.01 (9)	O5^i—O6—O11	97.04 (15)
O10^vii—Na2—K2^iii	50.90 (12)	O5—O6—O11	57.71 (11)
O11^vi—Na2—K2^iii	93.94 (10)	Si2^iv—O6—O11^i	113.15 (18)
O1^vi—Na2—K2^iii	104.44 (9)	Ce1—O6—O11^i	47.47 (9)
OW2^vii—Na2—K2^iii	131.84 (17)	Na3^i—O6—O11^i	89.66 (17)
K2^v—Na2—Na2^iii	121.5 (5)	Na3—O6—O11^i	149.4 (2)
Na2^v—Na2—Na2^iii	121.5 (5)	O8^iv—O6—O11^i	145.11 (19)
OW2^vi—Na2—Na2^iii	44.7 (2)	O8^ix—O6—O11^i	103.89 (12)
O10^vi—Na2—Na2^iii	148.12 (14)	O9^iv—O6—O11^i	86.88 (14)
O3^vi—Na2—Na2^iii	95.01 (9)	OW1^iv—O6—O11^i	128.2 (3)
O10^vii—Na2—Na2^iii	50.90 (12)	O5^i—O6—O11^i	57.71 (11)
O11^vi—Na2—Na2^iii	93.94 (10)	O5—O6—O11^i	97.04 (15)
O1^vi—Na2—Na2^iii	104.44 (9)	O11—O6—O11^i	70.96 (15)
OW2^vii—Na2—Na2^iii	131.84 (17)	Si3^iii—O7—Si3	143.2 (3)
K2^iii—Na2—Na2^iii	0.0 (2)	Si3^iii—O7—O8	175.1 (3)
K2^v—Na2—Si1^vi	97.3 (4)	Si3—O7—O8	38.48 (10)
Na2^v—Na2—Si1^vi	97.3 (4)	Si3^iii—O7—O8^iii	38.48 (10)
OW2^vi—Na2—Si1^vi	88.1 (3)	Si3—O7—O8^iii	175.1 (3)
O10^vi—Na2—Si1^vi	27.01 (13)	O8—O7—O8^iii	139.3 (2)
O3^vi—Na2—Si1^vi	125.52 (15)	Si3^iii—O7—O4	117.7 (3)
O10^vii—Na2—Si1^vi	135.8 (2)	Si3—O7—O4	35.90 (12)
O11^vi—Na2—Si1^vi	86.94 (13)	O8—O7—O4	60.90 (13)
O1^vi—Na2—Si1^vi	28.78 (7)	O8^iii—O7—O4	140.7 (2)
OW2^vii—Na2—Si1^vi	83.1 (2)	Si3^iii—O7—O4^xv	35.90 (12)
K2^iii—Na2—Si1^vi	128.87 (7)	Si3—O7—O4^xv	117.7 (2)
Na2^iii—Na2—Si1^vi	128.87 (7)	O8—O7—O4^xv	140.7 (2)
K2^v—K2—Na2^v	0.0 (7)	O8^iii—O7—O4^xv	60.90 (13)
K2^v—K2—OW2^vi	160.4 (6)	O4—O7—O4^xv	84.5 (2)
Na2^v—K2—OW2^vi	160.4 (6)	Si3^iii—O7—O5^iii	33.02 (12)
K2^v—K2—O10^vi	89.2 (5)	Si3—O7—O5^iii	121.8 (2)
Na2^v—K2—O10^vi	89.2 (5)	O8—O7—O5^iii	151.8 (2)
OW2^vi—K2—O10^vi	103.4 (3)	O8^iii—O7—O5^iii	62.09 (10)
K2^v—K2—O3^vi	80.36 (11)	O4—O7—O5^iii	117.3 (2)
Na2^v—K2—O3^vi	80.36 (11)	O4^xv—O7—O5^iii	59.47 (11)
OW2^vi—K2—O3^vi	111.8 (4)	Si3^iii—O7—O5	121.8 (2)
O10^vi—K2—O3^vi	98.80 (19)	Si3—O7—O5	33.02 (12)
K2^v—K2—O10^vii	71.3 (5)	O8—O7—O5	62.09 (10)
Na2^v—K2—O10^vii	71.3 (5)	O8^iii—O7—O5	151.8 (2)
OW2^vi—K2—O10^vii	91.7 (3)	O4—O7—O5	59.47 (11)
O10^vi—K2—O10^vii	153.6 (3)	O4^xv—O7—O5	117.3 (2)
O3^vi—K2—O10^vii	95.37 (18)	O5^iii—O7—O5	92.0 (2)
K2^v—K2—O11^vi	126.3 (3)	Si3^iii—O7—Na1	80.83 (18)
Na2^v—K2—O11^vi	126.3 (3)	Si3—O7—Na1	80.83 (18)
OW2^vi—K2—O11^vi	72.6 (4)	O8—O7—Na1	103.94 (13)
O10^vi—K2—O11^vi	71.13 (17)	O8^iii—O7—Na1	103.94 (13)
O3^vi—K2—O11^vi	55.63 (12)	O4—O7—Na1	99.02 (17)
O10^vii—K2—O11^vi	134.8 (2)	O4^xv—O7—Na1	99.02 (17)
K2^v—K2—O1^vi	103.3 (3)	O5^iii—O7—Na1	47.85 (11)
Na2^v—K2—O1^vi	103.3 (3)	O5—O7—Na1	47.85 (11)
OW2^vi—K2—O1^vi	72.9 (3)	Si3^iii—O7—OW3^vi	117.0 (3)
O10^vi—K2—O1^vi	55.79 (15)	Si3—O7—OW3^vi	98.1 (3)
O3^vi—K2—O1^vi	153.82 (18)	O8—O7—OW3^vi	60.2 (2)
O10^vii—K2—O1^vi	110.5 (2)	O8^iii—O7—OW3^vi	79.2 (2)
O11^vi—K2—O1^vi	104.93 (16)	O4—O7—OW3^vi	105.1 (3)
K2^v—K2—OW2^vii	14.3 (4)	O4^xv—O7—OW3^vi	118.8 (3)
Na2^v—K2—OW2^vii	14.3 (4)	O5^iii—O7—OW3^vi	136.4 (2)
OW2^vi—K2—OW2^vii	158.0 (7)	O5—O7—OW3^vi	119.1 (2)
O10^vi—K2—OW2^vii	77.0 (2)	Na1—O7—OW3^vi	136.4 (3)
O3^vi—K2—OW2^vii	89.7 (3)	Si3^iii—O7—OW3^xiii	98.1 (3)
O10^vii—K2—OW2^vii	80.9 (2)	Si3—O7—OW3^xiii	117.0 (3)
O11^vi—K2—OW2^vii	126.7 (3)	O8—O7—OW3^xiii	79.2 (2)
O1^vi—K2—OW2^vii	90.2 (3)	O8^iii—O7—OW3^xiii	60.2 (2)
K2^v—K2—Na2^iii	121.5 (5)	O4—O7—OW3^xiii	118.8 (3)
Na2^v—K2—Na2^iii	121.5 (5)	O4^xv—O7—OW3^xiii	105.1 (3)
OW2^vi—K2—Na2^iii	44.7 (2)	O5^iii—O7—OW3^xiii	119.1 (2)
O10^vi—K2—Na2^iii	148.12 (14)	O5—O7—OW3^xiii	136.4 (2)
O3^vi—K2—Na2^iii	95.01 (9)	Na1—O7—OW3^xiii	136.4 (3)
O10^vii—K2—Na2^iii	50.90 (12)	OW3^vi—O7—OW3^xiii	19.0 (4)
O11^vi—K2—Na2^iii	93.94 (10)	Si3^iii—O7—O7^xv	84.52 (18)
O1^vi—K2—Na2^iii	104.44 (9)	Si3—O7—O7^xv	84.52 (18)
OW2^vii—K2—Na2^iii	131.84 (17)	O8—O7—O7^xv	91.42 (13)
K2^v—K2—K2^iii	121.5 (5)	O8^iii—O7—O7^xv	91.42 (13)
Na2^v—K2—K2^iii	121.5 (5)	O4—O7—O7^xv	50.05 (11)
OW2^vi—K2—K2^iii	44.7 (2)	O4^xv—O7—O7^xv	50.05 (11)
O10^vi—K2—K2^iii	148.12 (14)	O5^iii—O7—O7^xv	108.48 (12)
O3^vi—K2—K2^iii	95.01 (9)	O5—O7—O7^xv	108.48 (12)
O10^vii—K2—K2^iii	50.90 (12)	Na1—O7—O7^xv	132.09 (13)
O11^vi—K2—K2^iii	93.94 (10)	OW3^vi—O7—O7^xv	90.6 (2)
O1^vi—K2—K2^iii	104.44 (9)	OW3^xiii—O7—O7^xv	90.6 (2)
OW2^vii—K2—K2^iii	131.84 (17)	Si2—O8—Si3	137.4 (2)
Na2^iii—K2—K2^iii	0.0 (2)	Si2—O8—O7	150.7 (2)
K2^v—K2—Si1^vi	97.3 (4)	Si3—O8—O7	38.39 (12)
Na2^v—K2—Si1^vi	97.3 (4)	Si2—O8—O9	37.14 (12)
OW2^vi—K2—Si1^vi	88.1 (3)	Si3—O8—O9	104.35 (18)
O10^vi—K2—Si1^vi	27.01 (13)	O7—O8—O9	116.15 (17)
O3^vi—K2—Si1^vi	125.52 (15)	Si2—O8—O4	137.5 (2)
O10^vii—K2—Si1^vi	135.8 (2)	Si3—O8—O4	36.19 (11)
O11^vi—K2—Si1^vi	86.94 (13)	O7—O8—O4	61.22 (16)
O1^vi—K2—Si1^vi	28.78 (7)	O9—O8—O4	125.37 (19)
OW2^vii—K2—Si1^vi	83.1 (2)	Si2—O8—O8^i	36.05 (13)
Na2^iii—K2—Si1^vi	128.87 (7)	Si3—O8—O8^i	121.35 (12)
K2^iii—K2—Si1^vi	128.87 (7)	O7—O8—O8^i	159.65 (12)
OW3—Na3—Na3^viii	116.2 (5)	O9—O8—O8^i	59.75 (8)
OW3—Na3—OW1^iv	174.4 (8)	O4—O8—O8^i	103.56 (12)
Na3^viii—Na3—OW1^iv	60.57 (19)	Si2—O8—O6^vi	34.31 (12)
OW3—Na3—OW3^iii	11.8 (3)	Si3—O8—O6^vi	165.3 (2)
Na3^viii—Na3—OW3^iii	104.9 (3)	O7—O8—O6^vi	138.42 (18)
OW1^iv—Na3—OW3^iii	163.3 (5)	O9—O8—O6^vi	62.80 (16)
OW3—Na3—O6	111.0 (6)	O4—O8—O6^vi	157.05 (17)
Na3^viii—Na3—O6	129.94 (17)	O8^i—O8—O6^vi	60.01 (8)
OW1^iv—Na3—O6	73.5 (2)	Si2—O8—Na3^vi	91.8 (2)
OW3^iii—Na3—O6	122.8 (4)	Si3—O8—Na3^vi	130.1 (2)
OW3—Na3—O5	84.4 (6)	O7—O8—Na3^vi	96.2 (2)
Na3^viii—Na3—O5	123.69 (17)	O9—O8—Na3^vi	117.7 (2)
OW1^iv—Na3—O5	93.8 (5)	O4—O8—Na3^vi	116.7 (2)
OW3^iii—Na3—O5	88.0 (4)	O8^i—O8—Na3^vi	103.09 (15)
O6—Na3—O5	75.6 (2)	O6^vi—O8—Na3^vi	58.16 (18)
OW3—Na3—O8^iv	88.8 (6)	Si2—O8—O5	105.51 (17)
Na3^viii—Na3—O8^iv	104.13 (17)	Si3—O8—O5	32.31 (10)
OW1^iv—Na3—O8^iv	96.5 (5)	O7—O8—O5	61.14 (14)
OW3^iii—Na3—O8^iv	95.1 (4)	O9—O8—O5	72.40 (15)
O6—Na3—O8^iv	60.56 (18)	O4—O8—O5	59.27 (12)
O5—Na3—O8^iv	129.5 (3)	O8^i—O8—O5	100.04 (9)
OW3—Na3—O4	105.7 (6)	O6^vi—O8—O5	135.11 (16)
Na3^viii—Na3—O4	68.50 (14)	Na3^vi—O8—O5	156.7 (2)
OW1^iv—Na3—O4	69.0 (5)	Si2—O8—OW3^vi	106.2 (3)
OW3^iii—Na3—O4	98.9 (4)	Si3—O8—OW3^vi	109.6 (3)
O6—Na3—O4	113.8 (3)	O7—O8—OW3^vi	71.8 (3)
O5—Na3—O4	55.31 (15)	O9—O8—OW3^vi	116.1 (3)
O8^iv—Na3—O4	165.5 (3)	O4—O8—OW3^vi	113.6 (3)
OW3—Na3—OW3^viii	92.2 (7)	O8^i—O8—OW3^vi	128.5 (2)
Na3^viii—Na3—OW3^viii	24.0 (2)	O6^vi—O8—OW3^vi	72.9 (3)
OW1^iv—Na3—OW3^viii	84.5 (3)	Na3^vi—O8—OW3^vi	28.2 (3)
OW3^iii—Na3—OW3^viii	81.0 (4)	O5—O8—OW3^vi	129.1 (3)
O6—Na3—OW3^viii	151.3 (4)	Si2—O8—Na3^xvi	108.45 (17)
O5—Na3—OW3^viii	125.0 (4)	Si3—O8—Na3^xvi	111.51 (16)
O8^iv—Na3—OW3^viii	105.2 (3)	O7—O8—Na3^xvi	93.48 (17)
O4—Na3—OW3^viii	73.4 (3)	O9—O8—Na3^xvi	144.12 (18)
OW3—Na3—Si2^iv	104.8 (6)	O4—O8—Na3^xvi	85.67 (15)
Na3^viii—Na3—Si2^iv	117.94 (13)	O8^i—O8—Na3^xvi	98.97 (11)
OW1^iv—Na3—Si2^iv	80.8 (4)	O6^vi—O8—Na3^xvi	81.73 (16)
OW3^iii—Na3—Si2^iv	114.8 (4)	Na3^vi—O8—Na3^xvi	34.0 (2)
O6—Na3—Si2^iv	29.90 (12)	O5—O8—Na3^xvi	143.14 (16)
O5—Na3—Si2^iv	104.0 (2)	OW3^vi—O8—Na3^xvi	52.3 (3)
O8^iv—Na3—Si2^iv	31.04 (10)	Si1—O9—Si2	142.1 (4)
O4—Na3—Si2^iv	140.5 (2)	Si1—O9—O10	37.36 (16)
OW3^viii—Na3—Si2^iv	129.6 (3)	Si2—O9—O10	179.4 (3)
OW3—Na3—Si3	89.9 (6)	Si1—O9—O8^i	146.16 (15)
Na3^viii—Na3—Si3	97.38 (12)	Si2—O9—O8^i	36.78 (10)
OW1^iv—Na3—Si3	86.1 (5)	O10—O9—O8^i	143.53 (16)
OW3^iii—Na3—Si3	88.0 (4)	Si1—O9—O8	146.16 (15)
O6—Na3—Si3	98.4 (2)	Si2—O9—O8	36.78 (10)
O5—Na3—Si3	27.27 (10)	O10—O9—O8	143.53 (16)
O8^iv—Na3—Si3	156.6 (3)	O8^i—O9—O8	60.51 (16)
O4—Na3—Si3	29.14 (7)	Si1—O9—O1	34.60 (10)
OW3^viii—Na3—Si3	98.2 (3)	Si2—O9—O1	118.5 (2)
Si2^iv—Na3—Si3	128.3 (2)	O10—O9—O1	60.98 (16)
OW3—Na3—Na1	42.3 (6)	O8^i—O9—O1	150.1 (3)
Na3^viii—Na3—Na1	140.70 (12)	O8—O9—O1	111.61 (13)
OW1^iv—Na3—Na1	136.9 (4)	Si1—O9—O1^i	34.60 (10)
OW3^iii—Na3—Na1	49.1 (3)	Si2—O9—O1^i	118.5 (2)
O6—Na3—Na1	86.9 (2)	O10—O9—O1^i	60.98 (16)
O5—Na3—Na1	43.53 (15)	O8^i—O9—O1^i	111.61 (13)
O8^iv—Na3—Na1	106.8 (2)	O8—O9—O1^i	150.1 (3)
O4—Na3—Na1	85.47 (18)	O1—O9—O1^i	59.31 (18)
OW3^viii—Na3—Na1	121.8 (3)	Si1—O9—O6^vi	110.7 (3)
Si2^iv—Na3—Na1	101.0 (2)	Si2—O9—O6^vi	31.36 (15)
Si3—Na3—Na1	58.73 (14)	O10—O9—O6^vi	148.1 (2)
O10—Si1—O1^i	111.6 (2)	O8^i—O9—O6^vi	58.97 (13)
O10—Si1—O1	111.6 (2)	O8—O9—O6^vi	58.97 (13)
O1^i—Si1—O1	110.1 (3)	O1—O9—O6^vi	91.73 (19)
O10—Si1—O9	103.8 (3)	O1^i—O9—O6^vi	91.73 (19)
O1^i—Si1—O9	109.86 (17)	Si1—O9—Ce1	94.3 (2)
O1—Si1—O9	109.86 (17)	Si2—O9—Ce1	123.6 (2)
O10—Si1—K2^iv	44.49 (11)	O10—O9—Ce1	56.93 (16)
O1^i—Si1—K2^iv	129.73 (17)	O8^i—O9—Ce1	100.04 (16)
O1—Si1—K2^iv	67.10 (19)	O8—O9—Ce1	100.04 (16)
O9—Si1—K2^iv	118.21 (16)	O1—O9—Ce1	109.86 (17)
O10—Si1—Na2^iv	44.49 (11)	O1^i—O9—Ce1	109.86 (17)
O1^i—Si1—Na2^iv	129.73 (17)	O6^vi—O9—Ce1	155.01 (19)
O1—Si1—Na2^iv	67.10 (19)	Si1—O9—O5^i	121.70 (19)
O9—Si1—Na2^iv	118.21 (16)	Si2—O9—O5^i	88.51 (17)
K2^iv—Si1—Na2^iv	0.0 (2)	O10—O9—O5^i	91.96 (17)
O10—Si1—K2^ix	44.49 (11)	O8^i—O9—O5^i	54.99 (11)
O1^i—Si1—K2^ix	67.10 (19)	O8—O9—O5^i	90.03 (16)
O1—Si1—K2^ix	129.73 (17)	O1—O9—O5^i	152.9 (2)
O9—Si1—K2^ix	118.21 (16)	O1^i—O9—O5^i	109.07 (12)
K2^iv—Si1—K2^ix	77.73 (14)	O6^vi—O9—O5^i	113.91 (14)
Na2^iv—Si1—K2^ix	77.73 (14)	Ce1—O9—O5^i	47.98 (9)
O10—Si1—Na2^ix	44.49 (11)	Si1—O9—O5	121.70 (19)
O1^i—Si1—Na2^ix	67.10 (19)	Si2—O9—O5	88.51 (17)
O1—Si1—Na2^ix	129.73 (17)	O10—O9—O5	91.96 (17)
O9—Si1—Na2^ix	118.21 (16)	O8^i—O9—O5	90.03 (16)
K2^iv—Si1—Na2^ix	77.73 (14)	O8—O9—O5	54.99 (11)
Na2^iv—Si1—Na2^ix	77.73 (14)	O1—O9—O5	109.07 (12)
K2^ix—Si1—Na2^ix	0.00 (18)	O1^i—O9—O5	152.9 (2)
O10—Si1—Ce1	47.52 (18)	O6^vi—O9—O5	113.91 (14)
O1^i—Si1—Ce1	124.93 (16)	Ce1—O9—O5	47.98 (9)
O1—Si1—Ce1	124.93 (16)	O5^i—O9—O5	69.47 (16)
O9—Si1—Ce1	56.25 (19)	Si1—O10—K2^iv	108.50 (19)
K2^iv—Si1—Ce1	75.42 (9)	Si1—O10—Na2^iv	108.50 (19)
Na2^iv—Si1—Ce1	75.42 (9)	K2^iv—O10—Na2^iv	0.0 (2)
K2^ix—Si1—Ce1	75.42 (9)	Si1—O10—K2^ix	108.50 (19)
Na2^ix—Si1—Ce1	75.42 (9)	K2^iv—O10—K2^ix	116.2 (3)
O10—Si1—Na2^x	42.29 (15)	Na2^iv—O10—K2^ix	116.2 (3)
O1^i—Si1—Na2^x	115.82 (17)	Si1—O10—Na2^ix	108.50 (19)
O1—Si1—Na2^x	71.23 (19)	K2^iv—O10—Na2^ix	116.2 (3)
O9—Si1—Na2^x	130.62 (17)	Na2^iv—O10—Na2^ix	116.2 (3)
K2^iv—Si1—Na2^x	14.00 (14)	K2^ix—O10—Na2^ix	0.0 (3)
Na2^iv—Si1—Na2^x	14.00 (14)	Si1—O10—O9	38.87 (17)
K2^ix—Si1—Na2^x	67.02 (6)	K2^iv—O10—O9	120.79 (14)
Na2^ix—Si1—Na2^x	67.02 (6)	Na2^iv—O10—O9	120.79 (14)
Ce1—Si1—Na2^x	82.02 (8)	K2^ix—O10—O9	120.79 (14)
O10—Si1—K2^x	42.29 (15)	Na2^ix—O10—O9	120.79 (14)
O1^i—Si1—K2^x	115.82 (17)	Si1—O10—Ce1	105.1 (2)
O1—Si1—K2^x	71.23 (19)	K2^iv—O10—Ce1	108.98 (17)
O9—Si1—K2^x	130.62 (17)	Na2^iv—O10—Ce1	108.98 (17)
K2^iv—Si1—K2^x	14.00 (14)	K2^ix—O10—Ce1	108.98 (17)
Na2^iv—Si1—K2^x	14.00 (14)	Na2^ix—O10—Ce1	108.98 (17)
K2^ix—Si1—K2^x	67.02 (6)	O9—O10—Ce1	66.19 (16)
Na2^ix—Si1—K2^x	67.02 (6)	Si1—O10—K2^x	113.3 (2)
Ce1—Si1—K2^x	82.02 (8)	K2^iv—O10—K2^x	19.4 (2)
Na2^x—Si1—K2^x	0.0 (2)	Na2^iv—O10—K2^x	19.4 (2)
O10—Si1—Na2^xi	42.29 (15)	K2^ix—O10—K2^x	97.37 (17)
O1^i—Si1—Na2^xi	71.23 (19)	Na2^ix—O10—K2^x	97.37 (17)
O1—Si1—Na2^xi	115.82 (17)	O9—O10—K2^x	136.64 (16)
O9—Si1—Na2^xi	130.62 (17)	Ce1—O10—K2^x	122.81 (18)
K2^iv—Si1—Na2^xi	67.02 (6)	Si1—O10—Na2^x	113.3 (2)
Na2^iv—Si1—Na2^xi	67.02 (6)	K2^iv—O10—Na2^x	19.4 (2)
K2^ix—Si1—Na2^xi	14.00 (14)	Na2^iv—O10—Na2^x	19.4 (2)
Na2^ix—Si1—Na2^xi	14.00 (14)	K2^ix—O10—Na2^x	97.37 (17)
Ce1—Si1—Na2^xi	82.02 (8)	Na2^ix—O10—Na2^x	97.37 (17)
Na2^x—Si1—Na2^xi	55.04 (13)	O9—O10—Na2^x	136.64 (16)
K2^x—Si1—Na2^xi	55.04 (13)	Ce1—O10—Na2^x	122.81 (18)
O6^vi—Si2—O8	110.22 (16)	K2^x—O10—Na2^x	0.0 (3)
O6^vi—Si2—O8^i	110.22 (16)	Si1—O10—K2^xi	113.3 (2)
O8—Si2—O8^i	107.9 (3)	K2^iv—O10—K2^xi	97.37 (17)
O6^vi—Si2—O9	115.9 (3)	Na2^iv—O10—K2^xi	97.37 (17)
O8—Si2—O9	106.08 (17)	K2^ix—O10—K2^xi	19.4 (2)
O8^i—Si2—O9	106.08 (17)	Na2^ix—O10—K2^xi	19.4 (2)
O6^vi—Si2—Na3^xii	54.04 (16)	O9—O10—K2^xi	136.64 (16)
O8—Si2—Na3^xii	116.06 (18)	Ce1—O10—K2^xi	122.81 (18)
O8^i—Si2—Na3^xii	57.12 (17)	K2^x—O10—K2^xi	78.2 (2)
O9—Si2—Na3^xii	137.56 (15)	Na2^x—O10—K2^xi	78.2 (2)
O6^vi—Si2—Na3^vi	54.04 (16)	Si1—O10—Na2^xi	113.3 (2)
O8—Si2—Na3^vi	57.12 (17)	K2^iv—O10—Na2^xi	97.37 (17)
O8^i—Si2—Na3^vi	116.06 (18)	Na2^iv—O10—Na2^xi	97.37 (17)
O9—Si2—Na3^vi	137.56 (15)	K2^ix—O10—Na2^xi	19.4 (2)
Na3^xii—Si2—Na3^vi	74.8 (2)	Na2^ix—O10—Na2^xi	19.4 (2)
O5—Si3—O7	112.8 (2)	O9—O10—Na2^xi	136.64 (16)
O5—Si3—O8	114.22 (17)	Ce1—O10—Na2^xi	122.81 (18)
O7—Si3—O8	103.1 (2)	K2^x—O10—Na2^xi	78.2 (2)
O5—Si3—O4	110.3 (2)	Na2^x—O10—Na2^xi	78.2 (2)
O7—Si3—O4	108.3 (2)	K2^xi—O10—Na2^xi	0.0 (3)
O8—Si3—O4	107.6 (2)	Si1—O10—O1^i	34.42 (12)
O5—Si3—Na3	48.47 (17)	K2^iv—O10—O1^i	124.9 (2)
O7—Si3—Na3	112.3 (2)	Na2^iv—O10—O1^i	124.9 (2)
O8—Si3—Na3	144.37 (16)	K2^ix—O10—O1^i	74.09 (16)
O4—Si3—Na3	64.8 (2)	Na2^ix—O10—O1^i	74.09 (16)
O5—Si3—Na1	41.98 (13)	O9—O10—O1^i	61.68 (16)
O7—Si3—Na1	70.94 (19)	Ce1—O10—O1^i	118.20 (17)
O8—Si3—Na1	128.47 (15)	K2^x—O10—O1^i	117.5 (2)
O4—Si3—Na1	123.1 (2)	Na2^x—O10—O1^i	117.5 (2)
Na3—Si3—Na1	64.02 (15)	K2^xi—O10—O1^i	80.43 (17)
O11—Si4—O2^iv	113.5 (2)	Na2^xi—O10—O1^i	80.43 (17)
O11—Si4—O1^iv	115.6 (2)	Si4—O11—Ce1	138.7 (2)
O2^iv—Si4—O1^iv	102.7 (2)	Si4—O11—Na1	118.0 (2)
O11—Si4—O3	108.6 (2)	Ce1—O11—Na1	101.84 (15)
O2^iv—Si4—O3	108.43 (18)	Si4—O11—O3	36.48 (14)
O1^iv—Si4—O3	107.62 (19)	Ce1—O11—O3	122.65 (15)
O11—Si4—Na2^iv	63.39 (18)	Na1—O11—O3	127.65 (17)
O2^iv—Si4—Na2^iv	109.76 (17)	Si4—O11—O2^iv	33.82 (11)
O1^iv—Si4—Na2^iv	144.64 (15)	Ce1—O11—O2^iv	165.1 (2)
O3—Si4—Na2^iv	48.97 (18)	Na1—O11—O2^iv	84.27 (16)
O11—Si4—K2^iv	63.39 (18)	O3—O11—O2^iv	60.05 (14)
O2^iv—Si4—K2^iv	109.76 (17)	Si4—O11—O1^iv	32.76 (12)
O1^iv—Si4—K2^iv	144.64 (15)	Ce1—O11—O1^iv	111.06 (17)
O3—Si4—K2^iv	48.97 (18)	Na1—O11—O1^iv	130.7 (2)
Na2^iv—Si4—K2^iv	0.00 (16)	O3—O11—O1^iv	59.32 (15)
O11—Si4—Na1	38.07 (15)	O2^iv—O11—O1^iv	56.24 (12)
O2^iv—Si4—Na1	75.53 (16)	Si4—O11—K2^iv	88.31 (19)
O1^iv—Si4—Na1	129.79 (16)	Ce1—O11—K2^iv	97.87 (15)
O3—Si4—Na1	120.7 (2)	Na1—O11—K2^iv	96.9 (2)
Na2^iv—Si4—Na1	73.38 (13)	O3—O11—K2^iv	54.26 (16)
K2^iv—Si4—Na1	73.38 (13)	O2^iv—O11—K2^iv	94.80 (17)
O11—Si4—K2^x	72.94 (18)	O1^iv—O11—K2^iv	113.10 (16)
O2^iv—Si4—K2^x	115.11 (17)	Si4—O11—Na2^iv	88.31 (19)
O1^iv—Si4—K2^x	133.97 (15)	Ce1—O11—Na2^iv	97.87 (15)
O3—Si4—K2^x	37.0 (2)	Na1—O11—Na2^iv	96.9 (2)
Na2^iv—Si4—K2^x	12.87 (13)	O3—O11—Na2^iv	54.26 (16)
K2^iv—Si4—K2^x	12.87 (13)	O2^iv—O11—Na2^iv	94.80 (17)
Na1—Si4—K2^x	86.22 (13)	O1^iv—O11—Na2^iv	113.10 (16)
Si1—O1—Si4^vi	151.4 (3)	K2^iv—O11—Na2^iv	0.0 (2)
Si1—O1—O2	162.2 (2)	Si4—O11—O5	161.9 (2)
Si4^vi—O1—O2	38.61 (12)	Ce1—O11—O5	50.72 (9)
Si1—O1—O1^i	34.97 (16)	Na1—O11—O5	51.47 (11)
Si4^vi—O1—O1^i	121.68 (15)	O3—O11—O5	160.7 (2)
O2—O1—O1^i	160.26 (14)	O2^iv—O11—O5	131.97 (17)
Si1—O1—O10	34.01 (13)	O1^iv—O11—O5	138.50 (18)
Si4^vi—O1—O10	172.3 (2)	K2^iv—O11—O5	106.77 (16)
O2—O1—O10	139.1 (2)	Na2^iv—O11—O5	106.77 (16)
O1^i—O1—O10	60.13 (10)	Si4—O11—OW2	108.3 (3)
Si1—O1—O3^vi	136.1 (2)	Ce1—O11—OW2	103.9 (2)
Si4^vi—O1—O3^vi	36.30 (9)	Na1—O11—OW2	53.3 (2)
O2—O1—O3^vi	61.46 (12)	O3—O11—OW2	87.8 (3)
O1^i—O1—O3^vi	101.82 (8)	O2^iv—O11—OW2	90.6 (2)
O10—O1—O3^vi	137.32 (18)	O1^iv—O11—OW2	141.1 (3)
Si1—O1—O9	35.54 (11)	K2^iv—O11—OW2	43.7 (2)
Si4^vi—O1—O9	130.4 (2)	Na2^iv—O11—OW2	43.7 (2)
O2—O1—O9	129.12 (18)	O5—O11—OW2	77.9 (2)
O1^i—O1—O9	60.35 (9)	Si4—O11—O10	116.3 (2)
O10—O1—O9	57.34 (16)	Ce1—O11—O10	51.91 (10)
O3^vi—O1—O9	150.5 (2)	Na1—O11—O10	111.0 (2)
Si1—O1—O11^vi	121.9 (2)	O3—O11—O10	81.54 (16)
Si4^vi—O1—O11^vi	31.60 (13)	O2^iv—O11—O10	138.58 (19)
O2—O1—O11^vi	61.18 (15)	O1^iv—O11—O10	118.11 (16)
O1^i—O1—O11^vi	101.90 (11)	K2^iv—O11—O10	46.67 (12)
O10—O1—O11^vi	155.45 (19)	Na2^iv—O11—O10	46.67 (12)
O3^vi—O1—O11^vi	58.38 (14)	O5—O11—O10	81.76 (13)
O9—O1—O11^vi	100.04 (19)	OW2—O11—O10	71.73 (18)
Si1—O1—K2^iv	84.1 (2)	Si4—O11—O6	113.1 (2)
Si4^vi—O1—K2^iv	124.05 (19)	Ce1—O11—O6	46.49 (9)
O2—O1—K2^iv	91.78 (17)	Na1—O11—O6	98.02 (15)
O1^i—O1—K2^iv	104.44 (9)	O3—O11—O6	131.90 (18)
O10—O1—K2^iv	50.12 (13)	O2^iv—O11—O6	119.62 (19)
O3^vi—O1—K2^iv	109.49 (17)	O1^iv—O11—O6	80.68 (16)
O9—O1—K2^iv	98.27 (19)	K2^iv—O11—O6	143.56 (16)
O11^vi—O1—K2^iv	152.93 (16)	Na2^iv—O11—O6	143.56 (16)
Si1—O1—Na2^iv	84.1 (2)	O5—O11—O6	59.98 (12)
Si4^vi—O1—Na2^iv	124.05 (19)	OW2—O11—O6	137.7 (3)
O2—O1—Na2^iv	91.78 (17)	O10—O11—O6	96.89 (13)
O1^i—O1—Na2^iv	104.44 (9)	Na3^xvii—OW1—Na3^vi	157.4 (10)
O10—O1—Na2^iv	50.12 (13)	Na3^xvii—OW1—Na3^xii	58.9 (4)
O3^vi—O1—Na2^iv	109.49 (17)	Na3^vi—OW1—Na3^xii	116.1 (4)
O9—O1—Na2^iv	98.27 (19)	Na3^xvii—OW1—Na3^xvi	116.1 (4)
O11^vi—O1—Na2^iv	152.93 (16)	Na3^vi—OW1—Na3^xvi	58.9 (4)
K2^iv—O1—Na2^iv	0.0 (2)	Na3^xii—OW1—Na3^xvi	157.4 (10)
Si1—O1—OW2	104.6 (3)	Na3^xvii—OW1—O6^vi	114.0 (4)
Si4^vi—O1—OW2	100.8 (2)	Na3^vi—OW1—O6^vi	58.1 (2)
O2—O1—OW2	62.1 (2)	Na3^xii—OW1—O6^vi	58.1 (2)
O1^i—O1—OW2	137.6 (2)	Na3^xvi—OW1—O6^vi	114.0 (4)
O10—O1—OW2	77.7 (2)	Na3^xvii—OW1—O6^xvii	58.1 (2)
O3^vi—O1—OW2	113.4 (2)	Na3^vi—OW1—O6^xvii	114.0 (4)
O9—O1—OW2	93.8 (3)	Na3^xii—OW1—O6^xvii	114.0 (4)
O11^vi—O1—OW2	116.2 (2)	Na3^xvi—OW1—O6^xvii	58.1 (2)
K2^iv—O1—OW2	42.5 (2)	O6^vi—OW1—O6^xvii	144.1 (7)
Na2^iv—O1—OW2	42.5 (2)	Na3^xvii—OW1—O4^xvii	67.4 (3)
Si1—O1—K2^x	82.01 (19)	Na3^vi—OW1—O4^xvii	133.5 (6)
Si4^vi—O1—K2^x	123.80 (18)	Na3^xii—OW1—O4^xvii	67.4 (3)
O2—O1—K2^x	98.12 (17)	Na3^xvi—OW1—O4^xvii	133.5 (6)
O1^i—O1—K2^x	95.37 (9)	O6^vi—OW1—O4^xvii	103.8 (2)
O10—O1—K2^x	49.08 (14)	O6^xvii—OW1—O4^xvii	103.8 (2)
O3^vi—O1—K2^x	101.16 (15)	Na3^xvii—OW1—O4^vi	133.5 (6)
O9—O1—K2^x	103.72 (19)	Na3^vi—OW1—O4^vi	67.4 (3)
O11^vi—O1—K2^x	155.40 (16)	Na3^xii—OW1—O4^vi	133.5 (6)
K2^iv—O1—K2^x	14.37 (15)	Na3^xvi—OW1—O4^vi	67.4 (3)
Na2^iv—O1—K2^x	14.37 (15)	O6^vi—OW1—O4^vi	103.8 (2)
OW2—O1—K2^x	56.2 (2)	O6^xvii—OW1—O4^vi	103.8 (2)
Si4^vi—O2—Si4^xiii	141.9 (3)	O4^xvii—OW1—O4^vi	78.3 (4)
Si4^vi—O2—O1^iii	177.6 (3)	K2^xiv—OW2—Na2^xiv	0.0 (3)
Si4^xiii—O2—O1^iii	38.71 (13)	K2^xiv—OW2—K2^iv	90.6 (5)
Si4^vi—O2—O1	38.71 (13)	Na2^xiv—OW2—K2^iv	90.6 (5)
Si4^xiii—O2—O1	177.6 (3)	K2^xiv—OW2—Na2^iv	90.6 (5)
O1^iii—O2—O1	140.5 (3)	Na2^xiv—OW2—Na2^iv	90.6 (5)
Si4^vi—O2—O3^xiii	120.9 (2)	K2^iv—OW2—Na2^iv	0.0 (3)
Si4^xiii—O2—O3^xiii	35.93 (10)	K2^xiv—OW2—Na1	111.7 (5)
O1^iii—O2—O3^xiii	61.03 (12)	Na2^xiv—OW2—Na1	111.7 (5)
O1—O2—O3^xiii	146.4 (2)	K2^iv—OW2—Na1	111.7 (5)
Si4^vi—O2—O3^vi	35.93 (10)	Na2^iv—OW2—Na1	111.7 (5)
Si4^xiii—O2—O3^vi	120.9 (2)	K2^xiv—OW2—O2	97.5 (4)
O1^iii—O2—O3^vi	146.4 (2)	Na2^xiv—OW2—O2	97.5 (4)
O1—O2—O3^vi	61.03 (12)	K2^iv—OW2—O2	97.5 (4)
O3^xiii—O2—O3^vi	88.83 (17)	Na2^iv—OW2—O2	97.5 (4)
Si4^vi—O2—O11^vi	32.68 (13)	Na1—OW2—O2	137.6 (5)
Si4^xiii—O2—O11^vi	116.9 (2)	K2^xiv—OW2—K2^xviii	5.32 (17)
O1^iii—O2—O11^vi	145.8 (2)	Na2^xiv—OW2—K2^xviii	5.32 (17)
O1—O2—O11^vi	62.59 (15)	K2^iv—OW2—K2^xviii	87.3 (4)
O3^xiii—O2—O11^vi	116.0 (2)	Na2^iv—OW2—K2^xviii	87.3 (4)
O3^vi—O2—O11^vi	58.70 (11)	Na1—OW2—K2^xviii	116.8 (4)
Si4^vi—O2—O11^xiii	116.9 (2)	O2—OW2—K2^xviii	93.8 (3)
Si4^xiii—O2—O11^xiii	32.68 (13)	K2^xiv—OW2—Na2^xviii	5.32 (17)
O1^iii—O2—O11^xiii	62.59 (15)	Na2^xiv—OW2—Na2^xviii	5.32 (17)
O1—O2—O11^xiii	145.8 (2)	K2^iv—OW2—Na2^xviii	87.3 (4)
O3^xiii—O2—O11^xiii	58.70 (11)	Na2^iv—OW2—Na2^xviii	87.3 (4)
O3^vi—O2—O11^xiii	116.0 (2)	Na1—OW2—Na2^xviii	116.8 (4)
O11^vi—O2—O11^xiii	86.3 (2)	O2—OW2—Na2^xviii	93.8 (3)
Si4^vi—O2—OW2	108.99 (15)	K2^xviii—OW2—Na2^xviii	0.0 (2)
Si4^xiii—O2—OW2	108.99 (15)	K2^xiv—OW2—K2^x	87.3 (4)
O1^iii—O2—OW2	70.28 (14)	Na2^xiv—OW2—K2^x	87.3 (4)
O1—O2—OW2	70.28 (14)	K2^iv—OW2—K2^x	5.32 (17)
O3^xiii—O2—OW2	119.6 (2)	Na2^iv—OW2—K2^x	5.32 (17)
O3^vi—O2—OW2	119.6 (2)	Na1—OW2—K2^x	116.8 (4)
O11^vi—O2—OW2	124.4 (2)	O2—OW2—K2^x	93.8 (3)
O11^xiii—O2—OW2	124.4 (2)	K2^xviii—OW2—K2^x	83.7 (3)
Si4^vi—O2—Na1^vi	77.00 (16)	Na2^xviii—OW2—K2^x	83.7 (3)
Si4^xiii—O2—Na1^vi	77.00 (16)	K2^xiv—OW2—Na2^x	87.3 (4)
O1^iii—O2—Na1^vi	101.65 (15)	Na2^xiv—OW2—Na2^x	87.3 (4)
O1—O2—Na1^vi	101.65 (15)	K2^iv—OW2—Na2^x	5.32 (17)
O3^xiii—O2—Na1^vi	94.96 (16)	Na2^iv—OW2—Na2^x	5.32 (17)
O3^vi—O2—Na1^vi	94.96 (16)	Na1—OW2—Na2^x	116.8 (4)
O11^vi—O2—Na1^vi	44.37 (11)	O2—OW2—Na2^x	93.8 (3)
O11^xiii—O2—Na1^vi	44.37 (11)	K2^xviii—OW2—Na2^x	83.7 (3)
OW2—O2—Na1^vi	129.3 (3)	Na2^xviii—OW2—Na2^x	83.7 (3)
Si4^vi—O2—K2^xiv	131.26 (19)	K2^x—OW2—Na2^x	0.0 (2)
Si4^xiii—O2—K2^xiv	84.14 (14)	K2^xiv—OW2—O11^iii	63.7 (3)
O1^iii—O2—K2^xiv	49.28 (14)	Na2^xiv—OW2—O11^iii	63.7 (3)
O1—O2—K2^xiv	96.08 (17)	K2^iv—OW2—O11^iii	112.3 (5)
O3^xiii—O2—K2^xiv	85.69 (16)	Na2^iv—OW2—O11^iii	112.3 (5)
O3^vi—O2—K2^xiv	119.25 (18)	Na1—OW2—O11^iii	48.0 (2)
O11^vi—O2—K2^xiv	157.44 (16)	O2—OW2—O11^iii	143.94 (19)
O11^xiii—O2—K2^xiv	111.86 (11)	K2^xviii—OW2—O11^iii	68.9 (2)
OW2—O2—K2^xiv	34.18 (17)	Na2^xviii—OW2—O11^iii	68.9 (2)
Na1^vi—O2—K2^xiv	145.78 (14)	K2^x—OW2—O11^iii	114.3 (4)
Si4^vi—O2—K2^iv	84.14 (14)	Na2^x—OW2—O11^iii	114.3 (4)
Si4^xiii—O2—K2^iv	131.26 (19)	K2^xiv—OW2—O11	112.3 (5)
O1^iii—O2—K2^iv	96.08 (17)	Na2^xiv—OW2—O11	112.3 (5)
O1—O2—K2^iv	49.28 (14)	K2^iv—OW2—O11	63.7 (3)
O3^xiii—O2—K2^iv	119.25 (18)	Na2^iv—OW2—O11	63.7 (3)
O3^vi—O2—K2^iv	85.69 (16)	Na1—OW2—O11	48.0 (2)
O11^vi—O2—K2^iv	111.86 (11)	O2—OW2—O11	143.94 (19)
O11^xiii—O2—K2^iv	157.44 (16)	K2^xviii—OW2—O11	114.3 (4)
OW2—O2—K2^iv	34.18 (17)	Na2^xviii—OW2—O11	114.3 (4)
Na1^vi—O2—K2^iv	145.78 (14)	K2^x—OW2—O11	68.9 (2)
K2^xiv—O2—K2^iv	47.51 (12)	Na2^x—OW2—O11	68.9 (2)
Si4^v—O3—Si4	137.2 (4)	O11^iii—OW2—O11	70.7 (3)
Si4^v—O3—K2^iv	120.4 (2)	OW3^iii—OW3—Na3	152.8 (5)
Si4—O3—K2^iv	102.27 (17)	OW3^iii—OW3—Na3^iii	15.5 (3)
Si4^v—O3—Na2^iv	120.4 (2)	Na3—OW3—Na3^iii	137.3 (8)
Si4—O3—Na2^iv	102.27 (17)	OW3^iii—OW3—Na1	78.5 (2)
K2^iv—O3—Na2^iv	0.0 (3)	Na3—OW3—Na1	117.2 (7)
Si4^v—O3—K2^x	102.27 (17)	Na3^iii—OW3—Na1	88.3 (4)
Si4—O3—K2^x	120.4 (2)	OW3^iii—OW3—O5	119.4 (2)
K2^iv—O3—K2^x	19.3 (2)	Na3—OW3—O5	65.8 (6)
Na2^iv—O3—K2^x	19.3 (2)	Na3^iii—OW3—O5	119.3 (5)
Si4^v—O3—Na2^x	102.27 (17)	Na1—OW3—O5	52.9 (3)
Si4—O3—Na2^x	120.4 (2)	OW3^iii—OW3—O8^iv	128.5 (2)
K2^iv—O3—Na2^x	19.3 (2)	Na3—OW3—O8^iv	63.0 (5)
Na2^iv—O3—Na2^x	19.3 (2)	Na3^iii—OW3—O8^iv	131.1 (6)
K2^x—O3—Na2^x	0.00 (3)	Na1—OW3—O8^iv	124.6 (4)
Si4^v—O3—O11^v	34.94 (11)	O5—OW3—O8^iv	109.6 (4)
Si4—O3—O11^v	165.3 (2)	OW3^iii—OW3—Na3^viii	113.7 (2)
K2^iv—O3—O11^v	86.6 (2)	Na3—OW3—Na3^viii	39.9 (4)
Na2^iv—O3—O11^v	86.6 (2)	Na3^iii—OW3—Na3^viii	98.6 (4)
K2^x—O3—O11^v	70.11 (15)	Na1—OW3—Na3^viii	140.7 (5)
Na2^x—O3—O11^v	70.11 (15)	O5—OW3—Na3^viii	91.1 (4)
Si4^v—O3—O11	165.3 (2)	O8^iv—OW3—Na3^viii	78.5 (3)
Si4—O3—O11	34.94 (11)	OW3^iii—OW3—O7^iv	80.49 (19)
K2^iv—O3—O11	70.11 (15)	Na3—OW3—O7^iv	105.2 (7)
Na2^iv—O3—O11	70.11 (15)	Na3^iii—OW3—O7^iv	84.7 (4)
K2^x—O3—O11	86.6 (2)	Na1—OW3—O7^iv	122.9 (4)
Na2^x—O3—O11	86.6 (2)	O5—OW3—O7^iv	153.5 (4)
O11^v—O3—O11	156.6 (3)	O8^iv—OW3—O7^iv	48.0 (2)
Si4^v—O3—O1^x	36.08 (13)	Na3^viii—OW3—O7^iv	96.4 (4)
Si4—O3—O1^x	105.2 (2)	OW3^iii—OW3—O6	161.4 (2)
K2^iv—O3—O1^x	144.08 (17)	Na3—OW3—O6	45.8 (4)
Na2^iv—O3—O1^x	144.08 (17)	Na3^iii—OW3—O6	176.9 (5)
K2^x—O3—O1^x	131.72 (14)	Na1—OW3—O6	89.6 (3)
Na2^x—O3—O1^x	131.72 (14)	O5—OW3—O6	61.0 (2)
O11^v—O3—O1^x	62.30 (14)	O8^iv—OW3—O6	48.84 (19)
O11—O3—O1^x	140.2 (2)	Na3^viii—OW3—O6	84.5 (3)
Si4^v—O3—O1^iv	105.2 (2)	O7^iv—OW3—O6	94.4 (3)
Si4—O3—O1^iv	36.08 (13)	OW3^iii—OW3—OW3^viii	90.000 (5)
K2^iv—O3—O1^iv	131.72 (14)	Na3—OW3—OW3^viii	63.8 (5)
Na2^iv—O3—O1^iv	131.72 (14)	Na3^iii—OW3—OW3^viii	75.1 (3)
K2^x—O3—O1^iv	144.08 (17)	Na1—OW3—OW3^viii	142.5 (3)
Na2^x—O3—O1^iv	144.08 (17)	O5—OW3—OW3^viii	106.7 (2)
O11^v—O3—O1^iv	140.2 (2)	O8^iv—OW3—OW3^viii	90.5 (2)
O11—O3—O1^iv	62.30 (14)	Na3^viii—OW3—OW3^viii	24.0 (2)
O1^x—O3—O1^iv	83.1 (2)	O7^iv—OW3—OW3^viii	89.4 (2)
Si4^v—O3—O2^iv	120.2 (2)	O6—OW3—OW3^viii	107.9 (2)
Si4—O3—O2^iv	35.64 (10)	OW3^iii—OW3—O5^iii	44.9 (2)
K2^iv—O3—O2^iv	106.05 (14)	Na3—OW3—O5^iii	130.7 (8)
Na2^iv—O3—O2^iv	106.05 (14)	Na3^iii—OW3—O5^iii	47.9 (3)
K2^x—O3—O2^iv	124.24 (19)	Na1—OW3—O5^iii	44.8 (2)
Na2^x—O3—O2^iv	124.24 (19)	O5—OW3—O5^iii	74.5 (3)
O11^v—O3—O2^iv	130.79 (13)	O8^iv—OW3—O5^iii	163.8 (4)
O11—O3—O2^iv	61.26 (12)	Na3^viii—OW3—O5^iii	117.5 (4)
O1^x—O3—O2^iv	84.27 (17)	O7^iv—OW3—O5^iii	122.9 (3)
O1^iv—O3—O2^iv	57.51 (12)	O6—OW3—O5^iii	131.0 (4)
Si4^v—O3—O2^x	35.64 (10)	OW3^viii—OW3—O5^iii	103.5 (2)
Si4—O3—O2^x	120.2 (2)	OW3^iii—OW3—Na3^xv	50.7 (2)
K2^iv—O3—O2^x	124.24 (19)	Na3—OW3—Na3^xv	102.5 (6)
Na2^iv—O3—O2^x	124.24 (19)	Na3^iii—OW3—Na3^xv	35.7 (3)
K2^x—O3—O2^x	106.05 (14)	Na1—OW3—Na3^xv	117.4 (4)
Na2^x—O3—O2^x	106.05 (14)	O5—OW3—Na3^xv	119.7 (4)
O11^v—O3—O2^x	61.26 (12)	O8^iv—OW3—Na3^xv	115.9 (4)
O11—O3—O2^x	130.79 (13)	Na3^viii—OW3—Na3^xv	63.0 (3)
O1^x—O3—O2^x	57.51 (12)	O7^iv—OW3—Na3^xv	86.1 (3)
O1^iv—O3—O2^x	84.27 (17)	O6—OW3—Na3^xv	147.3 (4)
O2^iv—O3—O2^x	129.6 (3)	OW3^viii—OW3—Na3^xv	39.4 (2)
Si3^viii—O4—Si3	141.6 (3)	O5^iii—OW3—Na3^xv	72.6 (2)
Si3^viii—O4—O8^viii	36.17 (12)

Symmetry codes: (i) −x+1, y, z; (ii) x+1, y, z; (iii) −x, y, z; (iv) x, y, z−1; (v) −x+1/2, −y+1/2, z; (vi) x, y, z+1; (vii) −x+1/2, −y+1/2, z+1; (viii) x, −y+1, z; (ix) −x+1, y, z−1; (x) −x+1/2, −y+1/2, z−1; (xi) x+1/2, −y+1/2, z−1; (xii) −x+1, y, z+1; (xiii) −x, y, z+1; (xiv) −x, y, z−1; (xv) −x, −y+1, z; (xvi) x, −y+1, z+1; (xvii) −x+1, −y+1, z+1; (xviii) x−1/2, −y+1/2, z−1.

'Trisodium Lanthanum Phyllo-hexasilicate Dihydrate' (TR06)

Crystal data

H18K1.12La4Na10.88O70Si24	Dx = 2.652 Mg m^−3 Dm = 2.66 Mg m^−3 Dm measured by not measured
Mr = 660.16	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmm2	Cell parameters from 16947 reflections
a = 7.4217 (2) Å	θ = 3.0–32.7°
b = 31.0393 (7) Å	µ = 3.25 mm^−1
c = 7.1962 (1) Å	T = 293 K
V = 1657.75 (6) Å^3	Prism, colourless
Z = 4	0.18 × 0.06 × 0.03 mm
F(000) = 1276

Data collection

Oxford X'Calibur Gemini Ultra diffractometer	3158 independent reflections
Radiation source: fine-focus sealed tube	3022 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.082
Detector resolution: 10.2890 pixels mm^-1	θmax = 32.8°, θmin = 3.1°
phi/ω scans	h = −11→11
Absorption correction: multi scan CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.27 (release 29-05-2008 CrysAlis171 .NET) (compiled May 29 2008,13:12:44) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.	k = −45→46
Tmin = 0.743, Tmax = 1.000	l = −10→10
22843 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.074	w = 1/[σ^2(Fo^2) + (0.1P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.172	(Δ/σ)max = 3.531
S = 1.38	Δρmax = 6.61 e Å^−3
3158 reflections	Δρmin = −2.07 e Å^−3
135 parameters	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
1 restraint	Absolute structure parameter: 0.45 (3)
Primary atom site location: structure-invariant direct methods

Special details

Experimental. CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.27 (release 29–05-2008 CrysAlis171. NET) (compiled May 29 2008,13:12:44) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
La1	0.5000	0.369136 (15)	−0.67191 (9)	0.00853 (15)
K1	0.0000	0.37346 (10)	−0.6918 (7)	0.010 (3)*	0.27 (5)
Na1	0.0000	0.37346 (10)	−0.6918 (7)	0.018 (8)*	0.73 (5)
Na2	0.2216 (10)	0.2616 (3)	0.4701 (12)	0.0219 (17)	0.50
Na3	0.2447 (14)	0.4631 (4)	−0.8800 (19)	0.044 (3)*	0.50
Si1	0.5000	0.31895 (10)	−0.2609 (4)	0.0083 (5)
Si2	0.5000	0.41648 (8)	−0.1668 (7)	0.0101 (4)
Si3	0.2077 (3)	0.45055 (7)	−0.4220 (3)	0.0073 (3)
Si4	0.2065 (3)	0.29818 (7)	−0.9607 (3)	0.0105 (4)
O1	0.3206 (8)	0.30324 (19)	−0.1503 (13)	0.0249 (13)*
O2	0.0000	0.2985 (3)	−0.0373 (13)	0.0165 (16)
O3	0.2500	0.2500	−0.8795 (15)	0.0150 (18)
O4	0.2411 (11)	0.5000	−0.4881 (13)	0.0137 (15)
O5	0.2552 (7)	0.41801 (18)	−0.5824 (9)	0.0127 (10)*
O6	0.5000	0.4110 (3)	−0.9481 (12)	0.0138 (15)
O7	0.0000	0.4461 (3)	−0.3532 (13)	0.0145 (16)
O8	0.3237 (7)	0.44301 (19)	−0.2315 (9)	0.0157 (11)
O9	0.5000	0.3718 (3)	−0.2867 (14)	0.0169 (17)
O10	0.5000	0.3008 (3)	−0.4725 (17)	0.035 (3)
O11	0.2454 (9)	0.3325 (2)	−0.8089 (12)	0.0239 (15)
OW1	0.5000	0.5000	0.177 (5)	0.037 (8)	0.50
OW2	0.041 (3)	0.3114 (6)	−0.457 (4)	0.057 (6)*	0.50
OW3	0.076 (3)	0.4446 (7)	−0.909 (5)	0.066 (6)*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
La1	0.0081 (2)	0.0113 (2)	0.0062 (2)	0.000	0.000	−0.0008 (3)
Na2	0.020 (4)	0.027 (4)	0.018 (4)	−0.005 (3)	−0.004 (3)	−0.003 (3)
Si1	0.0053 (11)	0.0151 (12)	0.0046 (14)	0.000	0.000	0.0025 (10)
Si2	0.0084 (9)	0.0148 (10)	0.0072 (11)	0.000	0.000	0.0055 (16)
Si3	0.0086 (8)	0.0088 (8)	0.0045 (9)	0.0011 (6)	−0.0007 (7)	−0.0004 (7)
Si4	0.0092 (8)	0.0100 (8)	0.0122 (10)	−0.0006 (7)	−0.0003 (8)	0.0012 (7)
O2	0.008 (3)	0.030 (4)	0.012 (4)	0.000	0.000	0.001 (3)
O3	0.023 (4)	0.013 (4)	0.009 (4)	−0.003 (3)	0.000	0.000
O4	0.017 (4)	0.021 (4)	0.003 (4)	0.000	0.002 (3)	0.000
O6	0.022 (4)	0.017 (4)	0.002 (4)	0.000	0.000	0.002 (3)
O7	0.007 (3)	0.025 (4)	0.012 (4)	0.000	0.000	0.003 (3)
O8	0.014 (2)	0.023 (3)	0.011 (3)	0.007 (2)	−0.006 (2)	−0.002 (2)
O9	0.022 (4)	0.015 (4)	0.013 (4)	0.000	0.000	−0.002 (3)
O10	0.074 (8)	0.013 (4)	0.018 (5)	0.000	0.000	0.002 (4)
O11	0.015 (3)	0.022 (3)	0.035 (4)	−0.001 (2)	−0.013 (3)	−0.017 (3)
OW1	0.050 (19)	0.06 (2)	0.003 (12)	0.000	0.000	0.000

Geometric parameters (Å, º)

La1—O6	2.374 (8)	O2—O1^iii	2.519 (7)
La1—O11	2.415 (6)	O2—O3^vii	2.645 (8)
La1—O11^i	2.415 (6)	O2—O3^vi	2.645 (8)
La1—O5^i	2.453 (6)	O2—O11^vi	2.671 (9)
La1—O5	2.453 (6)	O2—O11^vii	2.671 (9)
La1—O10	2.560 (10)	O2—OW2	3.06 (3)
La1—O9	2.773 (10)	O2—OW2^iii	3.06 (3)
La1—Si1	3.343 (3)	O2—K1^vi	3.405 (11)
La1—K1	3.7160 (3)	O2—Na1^vi	3.405 (11)
La1—Na1	3.7160 (3)	O3—Si4^v	1.638 (4)
La1—K1^ii	3.7160 (3)	O3—Na2^iv	2.551 (15)
La1—Na1^ii	3.7160 (3)	O3—Na2^xiii	2.551 (15)
K1—O11^iii	2.375 (7)	O3—O1^xiii	2.608 (11)
K1—O11	2.375 (7)	O3—O1^iv	2.608 (11)
K1—O5	2.474 (6)	O3—O11	2.612 (7)
K1—O5^iii	2.474 (6)	O3—O11^v	2.612 (7)
K1—OW2^iii	2.58 (2)	O3—O2^iv	2.645 (8)
K1—OW2	2.58 (2)	O3—O2^xiii	2.645 (8)
K1—OW3	2.76 (3)	O4—Si3^x	1.626 (4)
K1—OW3^iii	2.76 (3)	O4—O8^x	2.630 (9)
K1—O7	3.321 (10)	O4—O8	2.630 (9)
K1—Si4^iii	3.399 (4)	O4—O7	2.634 (9)
K1—Si4	3.399 (4)	O4—O7^xiv	2.634 (9)
K1—O2^iv	3.405 (11)	O4—O5	2.636 (6)
Na1—O11^iii	2.375 (7)	O4—O5^x	2.636 (6)
Na1—O11	2.375 (7)	O4—Na3^x	3.044 (17)
Na1—O5	2.474 (6)	O4—OW1^iv	3.08 (3)
Na1—O5^iii	2.474 (6)	O5—O7	2.659 (9)
Na1—OW2^iii	2.58 (2)	O5—O8	2.690 (9)
Na1—OW2	2.58 (2)	O5—OW3	2.83 (3)
Na1—OW3	2.76 (3)	O5—O11	3.115 (9)
Na1—OW3^iii	2.76 (3)	O5—O9	3.144 (10)
Na1—O7	3.321 (10)	O5—O6	3.206 (9)
Na1—Si4^iii	3.399 (4)	O6—Si2^iv	1.583 (9)
Na1—Si4	3.399 (4)	O6—Na3^i	2.540 (13)
Na1—O2^iv	3.405 (11)	O6—O8^iv	2.619 (9)
Na2—Na2^v	0.832 (16)	O6—O8^xi	2.619 (9)
Na2—OW2^vi	2.11 (2)	O6—O9^iv	2.722 (13)
Na2—O10^vi	2.434 (9)	O6—OW1^iv	2.907 (13)
Na2—OW2^vii	2.54 (2)	O6—O5^i	3.206 (9)
Na2—O3^vi	2.551 (15)	O6—O11	3.240 (10)
Na2—O10^viii	2.574 (11)	O6—O11^i	3.240 (10)
Na2—OW2^viii	2.92 (2)	O7—Si3^iii	1.625 (4)
Na2—O11^vi	2.986 (12)	O7—O8	2.559 (6)
Na2—O1^vi	3.110 (12)	O7—O8^iii	2.559 (6)
Na2—Na2^iii	3.289 (15)	O7—O4^xiv	2.634 (9)
Na2—Si4^vi	3.304 (9)	O7—O5^iii	2.659 (9)
Na2—OW2^ix	3.32 (2)	O7—OW3^vi	3.24 (3)
Na3—OW3	1.40 (2)	O7—OW3^vii	3.24 (3)
Na3—OW1^iv	2.252 (13)	O8—O9	2.598 (9)
Na3—Na3^x	2.29 (3)	O8—O8^i	2.617 (11)
Na3—OW3^iii	2.46 (2)	O8—O6^vi	2.619 (9)
Na3—O6	2.540 (13)	O8—Na3^vi	2.670 (15)
Na3—O5	2.560 (15)	O8—OW3^vi	2.96 (3)
Na3—O8^iv	2.670 (15)	O9—O10	2.578 (13)
Na3—O4	3.044 (17)	O9—O8^i	2.598 (9)
Na3—OW3^x	3.13 (3)	O9—O1^i	2.696 (10)
Na3—Si2^iv	3.153 (14)	O9—O6^vi	2.722 (13)
Na3—Si3	3.330 (14)	O9—O5^i	3.144 (10)
Si1—O10	1.623 (13)	O10—Na2^iv	2.434 (9)
Si1—O1^i	1.626 (7)	O10—Na2^xi	2.434 (9)
Si1—O1	1.626 (7)	O10—Na2^xiii	2.574 (11)
Si1—O9	1.652 (9)	O10—Na2^xv	2.574 (11)
Si1—Na2^iv	3.345 (8)	O10—O1^i	2.674 (14)
Si1—Na2^xi	3.345 (8)	O10—O11	3.225 (12)
Si2—O6^vi	1.583 (9)	O10—O11^i	3.225 (12)
Si2—O8^i	1.614 (6)	O10—OW2^i	3.43 (2)
Si2—O8	1.614 (6)	O11—O2^iv	2.671 (9)
Si2—O9	1.632 (9)	O11—O1^iv	2.679 (12)
Si2—Na3^xii	3.153 (14)	O11—Na2^iv	2.986 (12)
Si2—Na3^vi	3.153 (14)	O11—OW2	3.03 (2)
Si3—O5	1.574 (7)	OW1—Na3^vi	2.252 (13)
Si3—O7	1.625 (4)	OW1—Na3^xvi	2.252 (13)
Si3—O4	1.626 (4)	OW1—Na3^xvii	2.252 (13)
Si3—O8	1.636 (6)	OW1—Na3^xii	2.252 (13)
Si4—O11	1.554 (7)	OW1—O6^vi	2.907 (13)
Si4—O1^iv	1.614 (9)	OW1—O6^xvi	2.907 (13)
Si4—O2^iv	1.628 (4)	OW1—O4^xvi	3.08 (3)
Si4—O3	1.638 (4)	OW1—O4^vi	3.08 (3)
Si4—Na2^iv	3.304 (10)	OW2—OW2^iii	0.60 (4)
O1—Si4^vi	1.614 (9)	OW2—Na2^iv	2.11 (2)
O1—O2	2.519 (7)	OW2—Na2^xviii	2.54 (2)
O1—O3^vi	2.608 (11)	OW2—Na2^xiii	2.92 (2)
O1—O1^i	2.662 (13)	OW2—Na2^xix	3.32 (2)
O1—O10	2.674 (14)	OW2—O11^iii	3.37 (2)
O1—O11^vi	2.679 (12)	OW3—OW3^iii	1.12 (4)
O1—O9	2.696 (10)	OW3—Na3^iii	2.46 (2)
O1—OW2	3.04 (2)	OW3—O8^iv	2.96 (3)
O1—Na2^iv	3.110 (12)	OW3—Na3^x	3.13 (3)
O1—Na2^xiii	3.407 (13)	OW3—O7^iv	3.24 (3)
O1—O1^v	3.468 (12)	OW3—OW3^x	3.44 (5)
O2—Si4^vii	1.628 (4)	OW3—O5^iii	3.50 (3)
O2—Si4^vi	1.628 (4)
O6—La1—O11	85.1 (2)	O8^x—O4—Na3	154.4 (4)
O6—La1—O11^i	85.1 (2)	O8—O4—Na3	113.3 (3)
O11—La1—O11^i	103.0 (3)	O7—O4—Na3	96.2 (3)
O6—La1—O5^i	83.21 (19)	O7^xiv—O4—Na3	125.9 (4)
O11—La1—O5^i	167.8 (2)	O5—O4—Na3	53.0 (3)
O11^i—La1—O5^i	79.5 (2)	O5^x—O4—Na3	97.1 (4)
O6—La1—O5	83.21 (19)	Si3^x—O4—Na3^x	85.3 (3)
O11—La1—O5	79.5 (2)	Si3—O4—Na3^x	128.8 (5)
O11^i—La1—O5	167.8 (2)	O8^x—O4—Na3^x	113.3 (3)
O5^i—La1—O5	95.6 (3)	O8—O4—Na3^x	154.4 (4)
O6—La1—O10	157.2 (3)	O7—O4—Na3^x	125.9 (4)
O11—La1—O10	80.7 (3)	O7^xiv—O4—Na3^x	96.2 (3)
O11^i—La1—O10	80.7 (3)	O5—O4—Na3^x	97.1 (4)
O5^i—La1—O10	111.4 (2)	O5^x—O4—Na3^x	53.0 (3)
O5—La1—O10	111.4 (2)	Na3—O4—Na3^x	44.2 (5)
O6—La1—O9	145.1 (3)	Si3^x—O4—OW1^iv	108.9 (3)
O11—La1—O9	115.0 (2)	Si3—O4—OW1^iv	108.9 (3)
O11^i—La1—O9	115.0 (2)	O8^x—O4—OW1^iv	113.8 (4)
O5^i—La1—O9	73.67 (18)	O8—O4—OW1^iv	113.8 (4)
O5—La1—O9	73.67 (18)	O7—O4—OW1^iv	135.4 (3)
O10—La1—O9	57.6 (3)	O7^xiv—O4—OW1^iv	135.4 (3)
O6—La1—Si1	174.6 (2)	O5—O4—OW1^iv	76.9 (2)
O11—La1—Si1	98.2 (2)	O5^x—O4—OW1^iv	76.9 (2)
O11^i—La1—Si1	98.2 (2)	Na3—O4—OW1^iv	43.1 (4)
O5^i—La1—Si1	93.20 (15)	Na3^x—O4—OW1^iv	43.1 (4)
O5—La1—Si1	93.20 (15)	Si3—O5—La1	139.1 (3)
O10—La1—Si1	28.1 (3)	Si3—O5—K1	114.9 (3)
O9—La1—Si1	29.51 (17)	La1—O5—K1	97.9 (2)
O6—La1—K1	87.02 (7)	Si3—O5—Na1	114.9 (3)
O11—La1—K1	38.74 (18)	La1—O5—Na1	97.9 (2)
O11^i—La1—K1	141.49 (19)	K1—O5—Na1	0.00 (12)
O5^i—La1—K1	136.68 (14)	Si3—O5—Na3	104.8 (4)
O5—La1—K1	41.24 (14)	La1—O5—Na3	98.1 (3)
O10—La1—K1	92.95 (6)	K1—O5—Na3	90.9 (3)
O9—La1—K1	92.14 (8)	Na1—O5—Na3	90.9 (3)
Si1—La1—K1	92.92 (7)	Si3—O5—O4	35.2 (2)
O6—La1—Na1	87.02 (7)	La1—O5—O4	133.9 (3)
O11—La1—Na1	38.74 (18)	K1—O5—O4	126.3 (3)
O11^i—La1—Na1	141.49 (19)	Na1—O5—O4	126.3 (3)
O5^i—La1—Na1	136.68 (14)	Na3—O5—O4	71.7 (4)
O5—La1—Na1	41.24 (14)	Si3—O5—O7	34.4 (2)
O10—La1—Na1	92.95 (6)	La1—O5—O7	153.3 (3)
O9—La1—Na1	92.14 (8)	K1—O5—O7	80.5 (2)
Si1—La1—Na1	92.92 (7)	Na1—O5—O7	80.5 (2)
K1—La1—Na1	0.00 (18)	Na3—O5—O7	108.5 (4)
O6—La1—K1^ii	87.02 (7)	O4—O5—O7	59.7 (3)
O11—La1—K1^ii	141.49 (19)	Si3—O5—O8	33.79 (19)
O11^i—La1—K1^ii	38.74 (17)	La1—O5—O8	106.5 (2)
O5^i—La1—K1^ii	41.24 (14)	K1—O5—O8	127.2 (3)
O5—La1—K1^ii	136.68 (14)	Na1—O5—O8	127.2 (3)
O10—La1—K1^ii	92.95 (6)	Na3—O5—O8	129.3 (4)
O9—La1—K1^ii	92.14 (8)	O4—O5—O8	59.2 (3)
Si1—La1—K1^ii	92.92 (7)	O7—O5—O8	57.2 (2)
K1—La1—K1^ii	173.95 (13)	Si3—O5—OW3	108.5 (6)
Na1—La1—K1^ii	173.95 (13)	La1—O5—OW3	108.1 (6)
O6—La1—Na1^ii	87.02 (7)	K1—O5—OW3	62.4 (5)
O11—La1—Na1^ii	141.49 (19)	Na1—O5—OW3	62.4 (5)
O11^i—La1—Na1^ii	38.74 (17)	Na3—O5—OW3	29.5 (5)
O5^i—La1—Na1^ii	41.24 (14)	O4—O5—OW3	85.1 (6)
O5—La1—Na1^ii	136.68 (14)	O7—O5—OW3	94.9 (6)
O10—La1—Na1^ii	92.95 (6)	O8—O5—OW3	141.8 (6)
O9—La1—Na1^ii	92.14 (8)	Si3—O5—O11	157.7 (4)
Si1—La1—Na1^ii	92.92 (7)	La1—O5—O11	49.69 (16)
K1—La1—Na1^ii	173.95 (13)	K1—O5—O11	48.66 (17)
Na1—La1—Na1^ii	173.95 (13)	Na1—O5—O11	48.66 (17)
K1^ii—La1—Na1^ii	0.00 (18)	Na3—O5—O11	91.6 (4)
O11^iii—K1—O11	100.1 (3)	O4—O5—O11	163.0 (4)
O11^iii—K1—O5	177.5 (3)	O7—O5—O11	126.0 (3)
O11—K1—O5	79.91 (19)	O8—O5—O11	137.8 (3)
O11^iii—K1—O5^iii	79.91 (19)	OW3—O5—O11	78.6 (5)
O11—K1—O5^iii	177.5 (3)	Si3—O5—O9	85.7 (3)
O5—K1—O5^iii	99.9 (3)	La1—O5—O9	57.85 (19)
O11^iii—K1—OW2^iii	75.1 (5)	K1—O5—O9	113.8 (2)
O11—K1—OW2^iii	85.6 (5)	Na1—O5—O9	113.8 (2)
O5—K1—OW2^iii	107.4 (5)	Na3—O5—O9	146.4 (3)
O5^iii—K1—OW2^iii	96.8 (5)	O4—O5—O9	106.8 (3)
O11^iii—K1—OW2	85.6 (5)	O7—O5—O9	98.1 (3)
O11—K1—OW2	75.1 (5)	O8—O5—O9	52.2 (2)
O5—K1—OW2	96.8 (5)	OW3—O5—O9	165.6 (6)
O5^iii—K1—OW2	107.4 (5)	O11—O5—O9	88.8 (3)
OW2^iii—K1—OW2	13.4 (9)	Si3—O5—O6	140.6 (3)
O11^iii—K1—OW3	112.5 (6)	La1—O5—O6	47.34 (16)
O11—K1—OW3	94.0 (5)	K1—O5—O6	97.7 (2)
O5—K1—OW3	65.0 (6)	Na1—O5—O6	97.7 (2)
O5^iii—K1—OW3	83.7 (5)	Na3—O5—O6	50.8 (3)
OW2^iii—K1—OW3	172.3 (8)	O4—O5—O6	107.4 (3)
OW2—K1—OW3	160.6 (7)	O7—O5—O6	159.3 (3)
O11^iii—K1—OW3^iii	94.0 (5)	O8—O5—O6	133.1 (2)
O11—K1—OW3^iii	112.5 (6)	OW3—O5—O6	66.6 (5)
O5—K1—OW3^iii	83.7 (5)	O11—O5—O6	61.7 (2)
O5^iii—K1—OW3^iii	65.0 (6)	O9—O5—O6	101.4 (2)
OW2^iii—K1—OW3^iii	160.6 (7)	Si2^iv—O6—La1	153.1 (5)
OW2—K1—OW3^iii	172.3 (8)	Si2^iv—O6—Na3^i	97.1 (4)
OW3—K1—OW3^iii	23.5 (8)	La1—O6—Na3^i	100.8 (4)
O11^iii—K1—O7	128.59 (18)	Si2^iv—O6—Na3	97.1 (4)
O11—K1—O7	128.59 (18)	La1—O6—Na3	100.8 (4)
O5—K1—O7	52.17 (16)	Na3^i—O6—Na3	96.5 (6)
O5^iii—K1—O7	52.17 (16)	Si2^iv—O6—O8^iv	35.40 (19)
OW2^iii—K1—O7	91.5 (5)	La1—O6—O8^iv	149.27 (17)
OW2—K1—O7	91.5 (5)	Na3^i—O6—O8^iv	106.3 (4)
OW3—K1—O7	82.7 (6)	Na3—O6—O8^iv	62.3 (4)
OW3^iii—K1—O7	82.7 (6)	Si2^iv—O6—O8^xi	35.40 (19)
O11^iii—K1—Si4^iii	23.74 (16)	La1—O6—O8^xi	149.27 (17)
O11—K1—Si4^iii	77.06 (18)	Na3^i—O6—O8^xi	62.3 (4)
O5—K1—Si4^iii	155.60 (19)	Na3—O6—O8^xi	106.3 (4)
O5^iii—K1—Si4^iii	102.73 (14)	O8^iv—O6—O8^xi	59.9 (3)
OW2^iii—K1—Si4^iii	78.9 (5)	Si2^iv—O6—O9^iv	32.7 (3)
OW2—K1—Si4^iii	85.0 (5)	La1—O6—O9^iv	120.4 (3)
OW3—K1—Si4^iii	108.6 (6)	Na3^i—O6—O9^iv	117.2 (4)
OW3^iii—K1—Si4^iii	97.7 (6)	Na3—O6—O9^iv	117.2 (4)
O7—K1—Si4^iii	152.23 (8)	O8^iv—O6—O9^iv	58.2 (3)
O11^iii—K1—Si4	77.06 (18)	O8^xi—O6—O9^iv	58.2 (3)
O11—K1—Si4	23.74 (16)	Si2^iv—O6—OW1^iv	101.9 (7)
O5—K1—Si4	102.73 (14)	La1—O6—OW1^iv	105.1 (7)
O5^iii—K1—Si4	155.60 (19)	Na3^i—O6—OW1^iv	48.3 (3)
OW2^iii—K1—Si4	85.0 (5)	Na3—O6—OW1^iv	48.3 (3)
OW2—K1—Si4	78.9 (5)	O8^iv—O6—OW1^iv	83.1 (6)
OW3—K1—Si4	97.7 (6)	O8^xi—O6—OW1^iv	83.1 (6)
OW3^iii—K1—Si4	108.6 (6)	O9^iv—O6—OW1^iv	134.6 (7)
O7—K1—Si4	152.23 (8)	Si2^iv—O6—O5^i	143.98 (17)
Si4^iii—K1—Si4	53.59 (9)	La1—O6—O5^i	49.45 (17)
O11^iii—K1—O2^iv	51.36 (17)	Na3^i—O6—O5^i	51.3 (3)
O11—K1—O2^iv	51.36 (17)	Na3—O6—O5^i	102.8 (4)
O5—K1—O2^iv	127.90 (17)	O8^iv—O6—O5^i	153.7 (3)
O5^iii—K1—O2^iv	127.90 (17)	O8^xi—O6—O5^i	109.3 (2)
OW2^iii—K1—O2^iv	88.2 (5)	O9^iv—O6—O5^i	139.9 (2)
OW2—K1—O2^iv	88.2 (5)	OW1^iv—O6—O5^i	71.4 (5)
OW3—K1—O2^iv	97.6 (7)	Si2^iv—O6—O5	143.98 (17)
OW3^iii—K1—O2^iv	97.6 (7)	La1—O6—O5	49.45 (17)
O7—K1—O2^iv	179.7 (3)	Na3^i—O6—O5	102.8 (4)
Si4^iii—K1—O2^iv	27.69 (6)	Na3—O6—O5	51.3 (3)
Si4—K1—O2^iv	27.69 (6)	O8^iv—O6—O5	109.3 (2)
O11^iii—Na1—O11	100.1 (3)	O8^xi—O6—O5	153.7 (3)
O11^iii—Na1—O5	177.5 (3)	O9^iv—O6—O5	139.9 (2)
O11—Na1—O5	79.91 (19)	OW1^iv—O6—O5	71.4 (5)
O11^iii—Na1—O5^iii	79.91 (19)	O5^i—O6—O5	69.1 (3)
O11—Na1—O5^iii	177.5 (3)	Si2^iv—O6—O11	112.9 (3)
O5—Na1—O5^iii	99.9 (3)	La1—O6—O11	47.96 (18)
O11^iii—Na1—OW2^iii	75.1 (5)	Na3^i—O6—O11	148.7 (5)
O11—Na1—OW2^iii	85.6 (5)	Na3—O6—O11	89.1 (3)
O5—Na1—OW2^iii	107.4 (5)	O8^iv—O6—O11	103.6 (2)
O5^iii—Na1—OW2^iii	96.8 (5)	O8^xi—O6—O11	144.8 (4)
O11^iii—Na1—OW2	85.6 (5)	O9^iv—O6—O11	86.7 (3)
O11—Na1—OW2	75.1 (5)	OW1^iv—O6—O11	128.2 (5)
O5—Na1—OW2	96.8 (5)	O5^i—O6—O11	97.3 (3)
O5^iii—Na1—OW2	107.4 (5)	O5—O6—O11	57.8 (2)
OW2^iii—Na1—OW2	13.4 (9)	Si2^iv—O6—O11^i	112.9 (3)
O11^iii—Na1—OW3	112.5 (6)	La1—O6—O11^i	47.96 (18)
O11—Na1—OW3	94.0 (5)	Na3^i—O6—O11^i	89.1 (3)
O5—Na1—OW3	65.0 (6)	Na3—O6—O11^i	148.7 (5)
O5^iii—Na1—OW3	83.7 (5)	O8^iv—O6—O11^i	144.8 (4)
OW2^iii—Na1—OW3	172.3 (8)	O8^xi—O6—O11^i	103.6 (2)
OW2—Na1—OW3	160.6 (7)	O9^iv—O6—O11^i	86.7 (3)
O11^iii—Na1—OW3^iii	94.0 (5)	OW1^iv—O6—O11^i	128.2 (5)
O11—Na1—OW3^iii	112.5 (6)	O5^i—O6—O11^i	57.8 (2)
O5—Na1—OW3^iii	83.7 (5)	O5—O6—O11^i	97.3 (3)
O5^iii—Na1—OW3^iii	65.0 (6)	O11—O6—O11^i	71.3 (3)
OW2^iii—Na1—OW3^iii	160.6 (7)	Si3^iii—O7—Si3	143.1 (6)
OW2—Na1—OW3^iii	172.3 (8)	Si3^iii—O7—O8	176.5 (6)
OW3—Na1—OW3^iii	23.5 (8)	Si3—O7—O8	38.5 (2)
O11^iii—Na1—O7	128.59 (18)	Si3^iii—O7—O8^iii	38.5 (2)
O11—Na1—O7	128.59 (18)	Si3—O7—O8^iii	176.5 (6)
O5—Na1—O7	52.17 (16)	O8—O7—O8^iii	139.7 (5)
O5^iii—Na1—O7	52.17 (16)	Si3^iii—O7—O4	118.6 (5)
OW2^iii—Na1—O7	91.5 (5)	Si3—O7—O4	35.9 (2)
OW2—Na1—O7	91.5 (5)	O8—O7—O4	60.8 (2)
OW3—Na1—O7	82.7 (6)	O8^iii—O7—O4	142.0 (4)
OW3^iii—Na1—O7	82.7 (6)	Si3^iii—O7—O4^xiv	35.9 (2)
O11^iii—Na1—Si4^iii	23.74 (16)	Si3—O7—O4^xiv	118.6 (5)
O11—Na1—Si4^iii	77.06 (18)	O8—O7—O4^xiv	142.0 (4)
O5—Na1—Si4^iii	155.60 (19)	O8^iii—O7—O4^xiv	60.8 (2)
O5^iii—Na1—Si4^iii	102.73 (14)	O4—O7—O4^xiv	85.6 (4)
OW2^iii—Na1—Si4^iii	78.9 (5)	Si3^iii—O7—O5^iii	33.2 (2)
OW2—Na1—Si4^iii	85.0 (5)	Si3—O7—O5^iii	120.9 (5)
OW3—Na1—Si4^iii	108.6 (6)	O8—O7—O5^iii	150.3 (4)
OW3^iii—Na1—Si4^iii	97.7 (6)	O8^iii—O7—O5^iii	62.0 (2)
O7—Na1—Si4^iii	152.23 (8)	O4—O7—O5^iii	117.6 (4)
O11^iii—Na1—Si4	77.06 (18)	O4^xiv—O7—O5^iii	59.7 (2)
O11—Na1—Si4	23.74 (16)	Si3^iii—O7—O5	120.9 (5)
O5—Na1—Si4	102.73 (14)	Si3—O7—O5	33.2 (2)
O5^iii—Na1—Si4	155.60 (19)	O8—O7—O5	62.0 (2)
OW2^iii—Na1—Si4	85.0 (5)	O8^iii—O7—O5	150.3 (4)
OW2—Na1—Si4	78.9 (5)	O4—O7—O5	59.7 (2)
OW3—Na1—Si4	97.7 (6)	O4^xiv—O7—O5	117.6 (4)
OW3^iii—Na1—Si4	108.6 (6)	O5^iii—O7—O5	90.8 (4)
O7—Na1—Si4	152.23 (8)	Si3^iii—O7—OW3^vi	117.8 (5)
Si4^iii—Na1—Si4	53.59 (9)	Si3—O7—OW3^vi	97.9 (5)
O11^iii—Na1—O2^iv	51.36 (17)	O8—O7—OW3^vi	60.0 (4)
O11—Na1—O2^iv	51.36 (17)	O8^iii—O7—OW3^vi	79.9 (4)
O5—Na1—O2^iv	127.90 (17)	O4—O7—OW3^vi	104.8 (5)
O5^iii—Na1—O2^iv	127.90 (17)	O4^xiv—O7—OW3^vi	119.3 (5)
OW2^iii—Na1—O2^iv	88.2 (5)	O5^iii—O7—OW3^vi	136.8 (5)
OW2—Na1—O2^iv	88.2 (5)	O5—O7—OW3^vi	118.9 (4)
OW3—Na1—O2^iv	97.6 (7)	Si3^iii—O7—OW3^vii	97.9 (5)
OW3^iii—Na1—O2^iv	97.6 (7)	Si3—O7—OW3^vii	117.8 (5)
O7—Na1—O2^iv	179.7 (3)	O8—O7—OW3^vii	79.9 (4)
Si4^iii—Na1—O2^iv	27.69 (6)	O8^iii—O7—OW3^vii	60.0 (4)
Si4—Na1—O2^iv	27.69 (6)	O4—O7—OW3^vii	119.3 (5)
Na2^v—Na2—OW2^vi	162.2 (10)	O4^xiv—O7—OW3^vii	104.8 (5)
Na2^v—Na2—O10^vi	90.1 (11)	O5^iii—O7—OW3^vii	118.9 (4)
OW2^vi—Na2—O10^vi	97.5 (6)	O5—O7—OW3^vii	136.8 (5)
Na2^v—Na2—OW2^vii	155.9 (12)	OW3^vi—O7—OW3^vii	20.0 (7)
OW2^vi—Na2—OW2^vii	10.6 (7)	Si3^iii—O7—K1	80.4 (3)
O10^vi—Na2—OW2^vii	108.1 (6)	Si3—O7—K1	80.4 (3)
Na2^v—Na2—O3^vi	80.6 (2)	O8—O7—K1	103.0 (3)
OW2^vi—Na2—O3^vi	113.6 (8)	O8^iii—O7—K1	103.0 (3)
O10^vi—Na2—O3^vi	99.7 (4)	O4—O7—K1	99.2 (3)
OW2^vii—Na2—O3^vi	110.7 (7)	O4^xiv—O7—K1	99.2 (3)
Na2^v—Na2—O10^viii	71.0 (11)	O5^iii—O7—K1	47.29 (19)
OW2^vi—Na2—O10^viii	96.0 (6)	O5—O7—K1	47.29 (19)
O10^vi—Na2—O10^viii	153.1 (6)	OW3^vi—O7—K1	135.4 (5)
OW2^vii—Na2—O10^viii	86.3 (5)	OW3^vii—O7—K1	135.4 (5)
O3^vi—Na2—O10^viii	96.0 (4)	Si3^iii—O7—Na1	80.4 (3)
Na2^v—Na2—OW2^viii	12.8 (7)	Si3—O7—Na1	80.4 (3)
OW2^vi—Na2—OW2^viii	155.1 (12)	O8—O7—Na1	103.0 (3)
O10^vi—Na2—OW2^viii	81.1 (5)	O8^iii—O7—Na1	103.0 (3)
OW2^vii—Na2—OW2^viii	153.9 (10)	O4—O7—Na1	99.2 (3)
O3^vi—Na2—OW2^viii	91.1 (5)	O4^xiv—O7—Na1	99.2 (3)
O10^viii—Na2—OW2^viii	76.9 (5)	O5^iii—O7—Na1	47.29 (19)
Na2^v—Na2—O11^vi	127.3 (7)	O5—O7—Na1	47.29 (19)
OW2^vi—Na2—O11^vi	70.4 (7)	OW3^vi—O7—Na1	135.4 (5)
O10^vi—Na2—O11^vi	72.2 (4)	OW3^vii—O7—Na1	135.4 (5)
OW2^vii—Na2—O11^vi	74.7 (6)	K1—O7—Na1	0.00 (15)
O3^vi—Na2—O11^vi	55.6 (2)	Si2—O8—Si3	137.9 (4)
O10^viii—Na2—O11^vi	134.5 (4)	Si2—O8—O7	151.5 (4)
OW2^viii—Na2—O11^vi	131.1 (5)	Si3—O8—O7	38.1 (2)
Na2^v—Na2—O1^vi	103.8 (5)	Si2—O8—O9	37.1 (3)
OW2^vi—Na2—O1^vi	68.1 (7)	Si3—O8—O9	105.0 (4)
O10^vi—Na2—O1^vi	56.1 (3)	O7—O8—O9	116.9 (3)
OW2^vii—Na2—O1^vi	75.3 (6)	Si2—O8—O8^i	35.9 (2)
O3^vi—Na2—O1^vi	154.9 (4)	Si3—O8—O8^i	121.8 (2)
O10^viii—Na2—O1^vi	108.8 (4)	O7—O8—O8^i	159.9 (2)
OW2^viii—Na2—O1^vi	91.2 (5)	O9—O8—O8^i	59.76 (15)
O11^vi—Na2—O1^vi	105.6 (3)	Si2—O8—O6^vi	34.6 (2)
Na2^v—Na2—Na2^iii	120.4 (11)	Si3—O8—O6^vi	165.9 (4)
OW2^vi—Na2—Na2^iii	50.6 (6)	O7—O8—O6^vi	138.6 (3)
O10^vi—Na2—Na2^iii	148.1 (3)	O9—O8—O6^vi	62.9 (3)
OW2^vii—Na2—Na2^iii	40.0 (5)	O8^i—O8—O6^vi	60.03 (16)
O3^vi—Na2—Na2^iii	94.74 (17)	Si2—O8—O4	137.3 (4)
O10^viii—Na2—Na2^iii	50.3 (2)	Si3—O8—O4	36.1 (2)
OW2^viii—Na2—Na2^iii	127.2 (4)	O7—O8—O4	61.0 (3)
O11^vi—Na2—Na2^iii	93.39 (19)	O9—O8—O4	125.6 (4)
O1^vi—Na2—Na2^iii	103.67 (18)	O8^i—O8—O4	103.5 (2)
Na2^v—Na2—Si4^vi	108.3 (2)	O6^vi—O8—O4	156.7 (3)
OW2^vi—Na2—Si4^vi	87.7 (7)	Si2—O8—Na3^vi	91.4 (4)
O10^vi—Na2—Si4^vi	90.9 (4)	Si3—O8—Na3^vi	130.1 (4)
OW2^vii—Na2—Si4^vi	87.6 (6)	O7—O8—Na3^vi	96.3 (4)
O3^vi—Na2—Si4^vi	29.01 (13)	O9—O8—Na3^vi	117.0 (4)
O10^viii—Na2—Si4^vi	112.8 (4)	O8^i—O8—Na3^vi	102.7 (3)
OW2^viii—Na2—Si4^vi	117.2 (5)	O6^vi—O8—Na3^vi	57.4 (3)
O11^vi—Na2—Si4^vi	28.02 (16)	O4—O8—Na3^vi	117.2 (4)
O1^vi—Na2—Si4^vi	133.5 (3)	Si2—O8—O5	106.1 (3)
Na2^iii—Na2—Si4^vi	88.05 (13)	Si3—O8—O5	32.34 (19)
Na2^v—Na2—OW2^ix	18.2 (9)	O7—O8—O5	60.8 (3)
OW2^vi—Na2—OW2^ix	155.9 (12)	O9—O8—O5	72.9 (3)
O10^vi—Na2—OW2^ix	73.1 (4)	O8^i—O8—O5	100.90 (16)
OW2^vii—Na2—OW2^ix	158.3 (10)	O6^vi—O8—O5	135.7 (3)
O3^vi—Na2—OW2^ix	90.1 (5)	O4—O8—O5	59.4 (2)
O10^viii—Na2—OW2^ix	85.2 (4)	Na3^vi—O8—O5	156.2 (4)
OW2^viii—Na2—OW2^ix	8.3 (6)	Si2—O8—OW3^vi	106.6 (6)
O11^vi—Na2—OW2^ix	124.6 (5)	Si3—O8—OW3^vi	109.1 (6)
O1^vi—Na2—OW2^ix	88.6 (5)	O7—O8—OW3^vi	71.6 (6)
Na2^iii—Na2—OW2^ix	135.5 (4)	O9—O8—OW3^vi	116.5 (5)
Si4^vi—Na2—OW2^ix	114.1 (5)	O8^i—O8—OW3^vi	128.4 (5)
OW3—Na3—OW1^iv	173.4 (13)	O6^vi—O8—OW3^vi	73.0 (5)
OW3—Na3—Na3^x	114.4 (10)	O4—O8—OW3^vi	113.2 (5)
OW1^iv—Na3—Na3^x	59.4 (3)	Na3^vi—O8—OW3^vi	28.1 (5)
OW3—Na3—OW3^iii	11.6 (6)	O5—O8—OW3^vi	128.5 (6)
OW1^iv—Na3—OW3^iii	161.8 (9)	Si2—O9—Si1	141.6 (7)
Na3^x—Na3—OW3^iii	103.6 (6)	Si2—O9—O10	179.3 (6)
OW3—Na3—O6	112.2 (12)	Si1—O9—O10	37.7 (3)
OW1^iv—Na3—O6	74.4 (4)	Si2—O9—O8^i	36.6 (2)
Na3^x—Na3—O6	129.6 (3)	Si1—O9—O8^i	145.9 (3)
OW3^iii—Na3—O6	123.8 (8)	O10—O9—O8^i	143.7 (3)
OW3—Na3—O5	85.9 (14)	Si2—O9—O8	36.6 (2)
OW1^iv—Na3—O5	95.7 (9)	Si1—O9—O8	145.9 (3)
Na3^x—Na3—O5	123.2 (3)	O10—O9—O8	143.7 (3)
OW3^iii—Na3—O5	88.4 (8)	O8^i—O9—O8	60.5 (3)
O6—Na3—O5	77.9 (4)	Si2—O9—O1^i	118.6 (5)
OW3—Na3—O8^iv	87.6 (14)	Si1—O9—O1^i	34.3 (2)
OW1^iv—Na3—O8^iv	96.2 (9)	O10—O9—O1^i	60.9 (3)
Na3^x—Na3—O8^iv	103.5 (3)	O8^i—O9—O1^i	111.5 (3)
OW3^iii—Na3—O8^iv	94.4 (9)	O8—O9—O1^i	149.8 (5)
O6—Na3—O8^iv	60.3 (4)	Si2—O9—O1	118.6 (5)
O5—Na3—O8^iv	131.1 (5)	Si1—O9—O1	34.3 (2)
OW3—Na3—O4	106.7 (14)	O10—O9—O1	60.9 (3)
OW1^iv—Na3—O4	69.3 (9)	O8^i—O9—O1	149.8 (5)
Na3^x—Na3—O4	67.9 (3)	O8—O9—O1	111.5 (3)
OW3^iii—Na3—O4	99.2 (9)	O1^i—O9—O1	59.2 (3)
O6—Na3—O4	115.1 (5)	Si2—O9—O6^vi	31.6 (3)
O5—Na3—O4	55.3 (3)	Si1—O9—O6^vi	110.0 (5)
O8^iv—Na3—O4	165.3 (5)	O10—O9—O6^vi	147.7 (5)
OW3—Na3—OW3^x	90.4 (13)	O8^i—O9—O6^vi	58.9 (3)
OW1^iv—Na3—OW3^x	83.4 (6)	O8—O9—O6^vi	58.9 (3)
Na3^x—Na3—OW3^x	23.9 (4)	O1^i—O9—O6^vi	91.5 (4)
OW3^iii—Na3—OW3^x	79.7 (8)	O1—O9—O6^vi	91.5 (4)
O6—Na3—OW3^x	150.2 (7)	Si2—O9—La1	123.7 (5)
O5—Na3—OW3^x	124.6 (8)	Si1—O9—La1	94.7 (4)
O8^iv—Na3—OW3^x	103.8 (7)	O10—O9—La1	57.0 (3)
O4—Na3—OW3^x	73.4 (7)	O8^i—O9—La1	100.3 (3)
OW3—Na3—Si2^iv	104.6 (13)	O8—O9—La1	100.3 (3)
OW1^iv—Na3—Si2^iv	81.2 (7)	O1^i—O9—La1	109.9 (3)
Na3^x—Na3—Si2^iv	117.3 (2)	O1—O9—La1	109.9 (3)
OW3^iii—Na3—Si2^iv	114.7 (8)	O6^vi—O9—La1	155.2 (4)
O6—Na3—Si2^iv	29.9 (2)	Si2—O9—O5	88.3 (3)
O5—Na3—Si2^iv	106.1 (4)	Si1—O9—O5	121.9 (4)
O8^iv—Na3—Si2^iv	30.79 (19)	O10—O9—O5	92.2 (4)
O4—Na3—Si2^iv	141.6 (4)	O8^i—O9—O5	90.4 (3)
OW3^x—Na3—Si2^iv	128.0 (7)	O8—O9—O5	54.9 (2)
OW3—Na3—Si3	91.5 (15)	O1^i—O9—O5	153.1 (4)
OW1^iv—Na3—Si3	87.0 (9)	O1—O9—O5	108.7 (2)
Na3^x—Na3—Si3	96.7 (2)	O6^vi—O9—O5	113.7 (3)
OW3^iii—Na3—Si3	88.7 (9)	La1—O9—O5	48.49 (19)
O6—Na3—Si3	100.2 (4)	Si2—O9—O5^i	88.3 (3)
O5—Na3—Si3	27.2 (2)	Si1—O9—O5^i	121.9 (4)
O8^iv—Na3—Si3	158.1 (5)	O10—O9—O5^i	92.2 (4)
O4—Na3—Si3	29.11 (15)	O8^i—O9—O5^i	54.9 (2)
OW3^x—Na3—Si3	98.1 (7)	O8—O9—O5^i	90.4 (3)
Si2^iv—Na3—Si3	130.0 (4)	O1^i—O9—O5^i	108.7 (2)
OW3—Na3—Na1	44.1 (12)	O1—O9—O5^i	153.1 (4)
OW1^iv—Na3—Na1	138.7 (8)	O6^vi—O9—O5^i	113.7 (3)
Na3^x—Na3—Na1	140.9 (2)	La1—O9—O5^i	48.49 (19)
OW3^iii—Na3—Na1	50.2 (6)	O5—O9—O5^i	70.6 (3)
O6—Na3—Na1	87.5 (4)	Si1—O10—Na2^iv	109.4 (4)
O5—Na3—Na1	43.6 (2)	Si1—O10—Na2^xi	109.4 (4)
O8^iv—Na3—Na1	106.7 (4)	Na2^iv—O10—Na2^xi	116.2 (5)
O4—Na3—Na1	86.4 (3)	Si1—O10—La1	103.8 (4)
OW3^x—Na3—Na1	122.1 (5)	Na2^iv—O10—La1	108.6 (4)
Si2^iv—Na3—Na1	101.2 (4)	Na2^xi—O10—La1	108.6 (4)
Si3—Na3—Na1	59.6 (2)	Si1—O10—Na2^xiii	114.3 (5)
O10—Si1—O1^i	110.8 (4)	Na2^iv—O10—Na2^xiii	18.9 (4)
O10—Si1—O1	110.8 (4)	Na2^xi—O10—Na2^xiii	98.0 (3)
O1^i—Si1—O1	109.9 (6)	La1—O10—Na2^xiii	122.2 (4)
O10—Si1—O9	103.8 (5)	Si1—O10—Na2^xv	114.3 (5)
O1^i—Si1—O9	110.7 (3)	Na2^iv—O10—Na2^xv	98.0 (3)
O1—Si1—O9	110.7 (3)	Na2^xi—O10—Na2^xv	18.9 (4)
O10—Si1—La1	48.0 (4)	La1—O10—Na2^xv	122.2 (4)
O1^i—Si1—La1	124.9 (3)	Na2^xiii—O10—Na2^xv	79.4 (4)
O1—Si1—La1	124.9 (3)	Si1—O10—O9	38.5 (3)
O9—Si1—La1	55.8 (4)	Na2^iv—O10—O9	121.1 (3)
O10—Si1—Na2^iv	43.3 (2)	Na2^xi—O10—O9	121.1 (3)
O1^i—Si1—Na2^iv	129.0 (3)	La1—O10—O9	65.3 (3)
O1—Si1—Na2^iv	67.5 (3)	Na2^xiii—O10—O9	136.6 (3)
O9—Si1—Na2^iv	117.6 (3)	Na2^xv—O10—O9	136.6 (3)
La1—Si1—Na2^iv	74.70 (17)	Si1—O10—O1^i	34.6 (2)
O10—Si1—Na2^xi	43.3 (2)	Na2^iv—O10—O1^i	125.7 (5)
O1^i—Si1—Na2^xi	67.5 (3)	Na2^xi—O10—O1^i	74.8 (3)
O1—Si1—Na2^xi	129.0 (3)	La1—O10—O1^i	117.6 (3)
O9—Si1—Na2^xi	117.6 (3)	Na2^xiii—O10—O1^i	118.6 (5)
La1—Si1—Na2^xi	74.70 (17)	Na2^xv—O10—O1^i	80.9 (3)
Na2^iv—Si1—Na2^xi	76.3 (3)	O9—O10—O1^i	61.7 (3)
O6^vi—Si2—O8^i	110.0 (3)	Si1—O10—O1	34.6 (2)
O6^vi—Si2—O8	110.0 (3)	Na2^iv—O10—O1	74.8 (3)
O8^i—Si2—O8	108.3 (5)	Na2^xi—O10—O1	125.7 (5)
O6^vi—Si2—O9	115.7 (5)	La1—O10—O1	117.6 (3)
O8^i—Si2—O9	106.3 (4)	Na2^xiii—O10—O1	80.9 (3)
O8—Si2—O9	106.3 (4)	Na2^xv—O10—O1	118.6 (5)
O6^vi—Si2—Na3^xii	53.1 (3)	O9—O10—O1	61.7 (3)
O8^i—Si2—Na3^xii	57.8 (3)	O1^i—O10—O1	59.7 (4)
O8—Si2—Na3^xii	116.2 (4)	Si1—O10—O11	126.8 (4)
O9—Si2—Na3^xii	137.4 (3)	Na2^iv—O10—O11	61.8 (3)
O6^vi—Si2—Na3^vi	53.1 (3)	Na2^xi—O10—O11	121.5 (5)
O8^i—Si2—Na3^vi	116.2 (4)	La1—O10—O11	47.7 (2)
O8—Si2—Na3^vi	57.8 (3)	Na2^xiii—O10—O11	74.6 (3)
O9—Si2—Na3^vi	137.4 (3)	Na2^xv—O10—O11	118.9 (5)
Na3^xii—Si2—Na3^vi	73.9 (5)	O9—O10—O11	97.4 (3)
O5—Si3—O7	112.5 (4)	O1^i—O10—O11	159.0 (4)
O5—Si3—O4	110.9 (4)	O1—O10—O11	110.5 (2)
O7—Si3—O4	108.3 (4)	Si1—O10—O11^i	126.8 (4)
O5—Si3—O8	113.9 (3)	Na2^iv—O10—O11^i	121.5 (5)
O7—Si3—O8	103.4 (4)	Na2^xi—O10—O11^i	61.8 (3)
O4—Si3—O8	107.4 (4)	La1—O10—O11^i	47.7 (2)
O5—Si3—Na3	48.0 (3)	Na2^xiii—O10—O11^i	118.9 (5)
O7—Si3—Na3	113.0 (4)	Na2^xv—O10—O11^i	74.6 (3)
O4—Si3—Na3	65.6 (4)	O9—O10—O11^i	97.4 (3)
O8—Si3—Na3	143.4 (3)	O1^i—O10—O11^i	110.5 (2)
O5—Si3—K1	40.6 (2)	O1—O10—O11^i	159.0 (4)
O7—Si3—K1	71.9 (3)	O11—O10—O11^i	71.7 (4)
O4—Si3—K1	124.0 (3)	Si1—O10—OW2^i	86.3 (5)
O8—Si3—K1	127.5 (2)	Na2^iv—O10—OW2^i	153.9 (5)
Na3—Si3—K1	63.9 (2)	Na2^xi—O10—OW2^i	37.7 (4)
O5—Si3—Na1	40.6 (2)	La1—O10—OW2^i	86.5 (4)
O7—Si3—Na1	71.9 (3)	Na2^xiii—O10—OW2^i	135.5 (4)
O4—Si3—Na1	124.0 (3)	Na2^xv—O10—OW2^i	56.1 (4)
O8—Si3—Na1	127.5 (2)	O9—O10—OW2^i	84.3 (4)
Na3—Si3—Na1	63.9 (2)	O1^i—O10—OW2^i	58.2 (5)
K1—Si3—Na1	0.00 (16)	O1—O10—OW2^i	117.6 (6)
O11—Si4—O1^iv	115.5 (4)	O11—O10—OW2^i	125.3 (5)
O11—Si4—O2^iv	114.1 (4)	O11^i—O10—OW2^i	54.0 (4)
O1^iv—Si4—O2^iv	102.0 (4)	Si4—O11—Na1	118.3 (3)
O11—Si4—O3	109.8 (5)	Si4—O11—K1	118.3 (3)
O1^iv—Si4—O3	106.7 (4)	Na1—O11—K1	0.00 (13)
O2^iv—Si4—O3	108.2 (4)	Si4—O11—La1	139.1 (4)
O11—Si4—Na2^iv	64.5 (4)	Na1—O11—La1	101.7 (3)
O1^iv—Si4—Na2^iv	144.0 (3)	K1—O11—La1	101.7 (3)
O2^iv—Si4—Na2^iv	110.6 (4)	Si4—O11—O3	36.2 (3)
O3—Si4—Na2^iv	49.0 (4)	Na1—O11—O3	127.1 (3)
O11—Si4—K1	38.0 (2)	K1—O11—O3	127.1 (3)
O1^iv—Si4—K1	130.6 (2)	La1—O11—O3	122.0 (3)
O2^iv—Si4—K1	76.3 (3)	Si4—O11—O2^iv	33.8 (2)
O3—Si4—K1	120.9 (3)	Na1—O11—O2^iv	84.7 (3)
Na2^iv—Si4—K1	73.59 (17)	K1—O11—O2^iv	84.7 (3)
O11—Si4—Na1	38.0 (2)	La1—O11—O2^iv	166.1 (4)
O1^iv—Si4—Na1	130.6 (2)	O3—O11—O2^iv	60.1 (3)
O2^iv—Si4—Na1	76.3 (3)	Si4—O11—O1^iv	32.9 (2)
O3—Si4—Na1	120.9 (3)	Na1—O11—O1^iv	131.8 (3)
Na2^iv—Si4—Na1	73.59 (17)	K1—O11—O1^iv	131.8 (3)
K1—Si4—Na1	0.00 (8)	La1—O11—O1^iv	111.8 (3)
Si4^vi—O1—Si1	150.8 (5)	O3—O11—O1^iv	59.1 (3)
Si4^vi—O1—O2	39.2 (3)	O2^iv—O11—O1^iv	56.2 (2)
Si1—O1—O2	161.6 (5)	Si4—O11—Na2^iv	87.5 (4)
Si4^vi—O1—O3^vi	36.98 (19)	Na1—O11—Na2^iv	96.3 (3)
Si1—O1—O3^vi	136.1 (4)	K1—O11—Na2^iv	96.3 (3)
O2—O1—O3^vi	62.1 (3)	La1—O11—Na2^iv	96.8 (3)
Si4^vi—O1—O1^i	121.7 (3)	O3—O11—Na2^iv	53.7 (3)
Si1—O1—O1^i	35.0 (3)	O2^iv—O11—Na2^iv	94.7 (3)
O2—O1—O1^i	160.8 (3)	O1^iv—O11—Na2^iv	112.3 (3)
O3^vi—O1—O1^i	101.60 (14)	Si4—O11—OW2	110.3 (5)
Si4^vi—O1—O10	172.5 (4)	Na1—O11—OW2	55.5 (4)
Si1—O1—O10	34.6 (3)	K1—O11—OW2	55.5 (4)
O2—O1—O10	138.5 (4)	La1—O11—OW2	98.8 (5)
O3^vi—O1—O10	136.9 (3)	O3—O11—OW2	87.5 (5)
O1^i—O1—O10	60.2 (2)	O2^iv—O11—OW2	95.0 (5)
Si4^vi—O1—O11^vi	31.6 (2)	O1^iv—O11—OW2	143.0 (5)
Si1—O1—O11^vi	121.2 (4)	Na2^iv—O11—OW2	41.2 (4)
O2—O1—O11^vi	61.7 (3)	Si4—O11—O5	163.1 (4)
O3^vi—O1—O11^vi	59.2 (3)	Na1—O11—O5	51.43 (17)
O1^i—O1—O11^vi	102.03 (19)	K1—O11—O5	51.43 (17)
O10—O1—O11^vi	155.3 (3)	La1—O11—O5	50.76 (15)
Si4^vi—O1—O9	130.1 (4)	O3—O11—O5	159.6 (4)
Si1—O1—O9	35.0 (2)	O2^iv—O11—O5	132.4 (3)
O2—O1—O9	129.0 (3)	O1^iv—O11—O5	139.8 (4)
O3^vi—O1—O9	150.6 (4)	Na2^iv—O11—O5	106.1 (3)
O1^i—O1—O9	60.42 (16)	OW2—O11—O5	76.0 (4)
O10—O1—O9	57.4 (3)	Si4—O11—O10	115.3 (4)
O11^vi—O1—O9	99.7 (3)	Na1—O11—O10	110.2 (3)
Si4^vi—O1—OW2	105.2 (5)	K1—O11—O10	110.2 (3)
Si1—O1—OW2	100.3 (6)	La1—O11—O10	51.6 (2)
O2—O1—OW2	66.0 (5)	O3—O11—O10	80.7 (3)
O3^vi—O1—OW2	117.2 (4)	O2^iv—O11—O10	137.8 (4)
O1^i—O1—OW2	133.1 (4)	O1^iv—O11—O10	117.6 (3)
O10—O1—OW2	73.4 (5)	Na2^iv—O11—O10	45.9 (2)
O11^vi—O1—OW2	119.6 (5)	OW2—O11—O10	66.4 (5)
O9—O1—OW2	90.4 (5)	O5—O11—O10	81.6 (3)
Si4^vi—O1—Na2^iv	125.3 (3)	Si4—O11—O6	114.0 (5)
Si1—O1—Na2^iv	83.6 (4)	Na1—O11—O6	98.9 (3)
O2—O1—Na2^iv	92.1 (3)	K1—O11—O6	98.9 (3)
O3^vi—O1—Na2^iv	110.2 (3)	La1—O11—O6	46.89 (17)
O1^i—O1—Na2^iv	103.67 (18)	O3—O11—O6	132.0 (3)
O10—O1—Na2^iv	49.1 (3)	O2^iv—O11—O6	120.3 (4)
O11^vi—O1—Na2^iv	153.8 (3)	O1^iv—O11—O6	81.4 (3)
O9—O1—Na2^iv	97.2 (4)	Na2^iv—O11—O6	142.8 (3)
OW2—O1—Na2^iv	40.2 (4)	OW2—O11—O6	135.6 (5)
Si4^vi—O1—Na2^xiii	124.9 (3)	O5—O11—O6	60.6 (2)
Si1—O1—Na2^xiii	82.0 (4)	O10—O11—O6	96.9 (2)
O2—O1—Na2^xiii	97.9 (3)	Na3^vi—OW1—Na3^xvi	158.9 (18)
O3^vi—O1—Na2^xiii	101.9 (3)	Na3^vi—OW1—Na3^xvii	61.1 (7)
O1^i—O1—Na2^xiii	95.28 (16)	Na3^xvi—OW1—Na3^xvii	114.6 (8)
O10—O1—Na2^xiii	48.3 (3)	Na3^vi—OW1—Na3^xii	114.6 (8)
O11^vi—O1—Na2^xiii	156.4 (3)	Na3^xvi—OW1—Na3^xii	61.1 (7)
O9—O1—Na2^xiii	102.7 (4)	Na3^xvii—OW1—Na3^xii	158.9 (18)
OW2—O1—Na2^xiii	53.5 (4)	Na3^vi—OW1—O6^vi	57.3 (4)
Na2^iv—O1—Na2^xiii	13.7 (3)	Na3^xvi—OW1—O6^vi	115.2 (7)
Si4^vi—O1—O1^v	75.4 (2)	Na3^xvii—OW1—O6^vi	115.2 (7)
Si1—O1—O1^v	122.2 (3)	Na3^xii—OW1—O6^vi	57.3 (4)
O2—O1—O1^v	70.1 (3)	Na3^vi—OW1—O6^xvi	115.2 (7)
O3^vi—O1—O1^v	48.3 (2)	Na3^xvi—OW1—O6^xvi	57.3 (4)
O1^i—O1—O1^v	107.6 (2)	Na3^xvii—OW1—O6^xvi	57.3 (4)
O10—O1—O1^v	97.1 (3)	Na3^xii—OW1—O6^xvi	115.2 (7)
O11^vi—O1—O1^v	105.1 (2)	O6^vi—OW1—O6^xvi	143.8 (13)
O9—O1—O1^v	154.4 (3)	Na3^vi—OW1—O4^xvi	131.9 (11)
OW2—O1—O1^v	82.7 (4)	Na3^xvi—OW1—O4^xvi	67.6 (6)
Na2^iv—O1—O1^v	62.1 (2)	Na3^xvii—OW1—O4^xvi	131.9 (11)
Na2^xiii—O1—O1^v	53.80 (19)	Na3^xii—OW1—O4^xvi	67.6 (6)
Si4^vii—O2—Si4^vi	140.5 (7)	O6^vi—OW1—O4^xvi	104.0 (4)
Si4^vii—O2—O1^iii	38.8 (2)	O6^xvi—OW1—O4^xvi	104.0 (4)
Si4^vi—O2—O1^iii	176.9 (6)	Na3^vi—OW1—O4^vi	67.6 (6)
Si4^vii—O2—O1	176.9 (6)	Na3^xvi—OW1—O4^vi	131.9 (11)
Si4^vi—O2—O1	38.8 (2)	Na3^xvii—OW1—O4^vi	67.6 (6)
O1^iii—O2—O1	141.7 (6)	Na3^xii—OW1—O4^vi	131.9 (11)
Si4^vii—O2—O3^vii	36.03 (19)	O6^vi—OW1—O4^vi	104.0 (4)
Si4^vi—O2—O3^vii	120.8 (5)	O6^xvi—OW1—O4^vi	104.0 (4)
O1^iii—O2—O3^vii	60.6 (2)	O4^xvi—OW1—O4^vi	77.2 (8)
O1—O2—O3^vii	146.5 (4)	OW2^iii—OW2—Na2^iv	129.4 (6)
Si4^vii—O2—O3^vi	120.8 (5)	OW2^iii—OW2—Na2^xviii	40.0 (5)
Si4^vi—O2—O3^vi	36.03 (19)	Na2^iv—OW2—Na2^xviii	89.4 (8)
O1^iii—O2—O3^vi	146.5 (4)	OW2^iii—OW2—K1	83.3 (4)
O1—O2—O3^vi	60.6 (2)	Na2^iv—OW2—K1	117.2 (10)
O3^vii—O2—O3^vi	89.1 (3)	Na2^xviii—OW2—K1	103.3 (8)
Si4^vii—O2—O11^vi	115.9 (5)	OW2^iii—OW2—Na1	83.3 (4)
Si4^vi—O2—O11^vi	32.1 (3)	Na2^iv—OW2—Na1	117.2 (10)
O1^iii—O2—O11^vi	145.1 (4)	Na2^xviii—OW2—Na1	103.3 (8)
O1—O2—O11^vi	62.1 (3)	K1—OW2—Na1	0.00 (9)
O3^vii—O2—O11^vi	116.1 (4)	OW2^iii—OW2—Na2^xiii	127.2 (4)
O3^vi—O2—O11^vi	58.9 (2)	Na2^iv—OW2—Na2^xiii	5.0 (3)
Si4^vii—O2—O11^vii	32.1 (3)	Na2^xviii—OW2—Na2^xiii	87.3 (5)
Si4^vi—O2—O11^vii	115.9 (5)	K1—OW2—Na2^xiii	122.1 (9)
O1^iii—O2—O11^vii	62.1 (3)	Na1—OW2—Na2^xiii	122.1 (9)
O1—O2—O11^vii	145.1 (4)	OW2^iii—OW2—O11	120.1 (4)
O3^vii—O2—O11^vii	58.9 (2)	Na2^iv—OW2—O11	68.4 (7)
O3^vi—O2—O11^vii	116.1 (4)	Na2^xviii—OW2—O11	110.1 (9)
O11^vi—O2—O11^vii	86.0 (4)	K1—OW2—O11	49.3 (4)
Si4^vii—O2—OW2	115.3 (5)	Na1—OW2—O11	49.3 (4)
Si4^vi—O2—OW2	104.0 (5)	Na2^xiii—OW2—O11	73.4 (5)
O1^iii—O2—OW2	76.5 (5)	OW2^iii—OW2—O1	133.1 (4)
O1—O2—OW2	65.2 (5)	Na2^iv—OW2—O1	71.7 (6)
O3^vii—O2—OW2	124.5 (5)	Na2^xviii—OW2—O1	128.5 (8)
O3^vi—O2—OW2	115.4 (5)	K1—OW2—O1	128.1 (7)
O11^vi—O2—OW2	119.2 (5)	Na1—OW2—O1	128.1 (7)
O11^vii—O2—OW2	128.5 (5)	Na2^xiii—OW2—O1	69.7 (5)
Si4^vii—O2—OW2^iii	104.0 (5)	O11—OW2—O1	106.4 (6)
Si4^vi—O2—OW2^iii	115.3 (5)	OW2^iii—OW2—O2	84.3 (4)
O1^iii—O2—OW2^iii	65.2 (5)	Na2^iv—OW2—O2	102.3 (8)
O1—O2—OW2^iii	76.5 (5)	Na2^xviii—OW2—O2	92.8 (7)
O3^vii—O2—OW2^iii	115.4 (5)	K1—OW2—O2	137.1 (8)
O3^vi—O2—OW2^iii	124.5 (5)	Na1—OW2—O2	137.1 (8)
O11^vi—O2—OW2^iii	128.5 (5)	Na2^xiii—OW2—O2	97.8 (7)
O11^vii—O2—OW2^iii	119.2 (5)	O11—OW2—O2	154.6 (8)
OW2—O2—OW2^iii	11.3 (8)	O1—OW2—O2	48.8 (4)
Si4^vii—O2—K1^vi	76.0 (3)	OW2^iii—OW2—Na2^xix	44.5 (4)
Si4^vi—O2—K1^vi	76.0 (3)	Na2^iv—OW2—Na2^xix	85.1 (6)
O1^iii—O2—K1^vi	101.3 (3)	Na2^xviii—OW2—Na2^xix	5.9 (3)
O1—O2—K1^vi	101.3 (3)	K1—OW2—Na2^xix	108.8 (7)
O3^vii—O2—K1^vi	94.3 (3)	Na1—OW2—Na2^xix	108.8 (7)
O3^vi—O2—K1^vi	94.3 (3)	Na2^xiii—OW2—Na2^xix	82.7 (5)
O11^vi—O2—K1^vi	44.0 (2)	O11—OW2—Na2^xix	111.9 (7)
O11^vii—O2—K1^vi	44.0 (2)	O1—OW2—Na2^xix	123.1 (7)
OW2—O2—K1^vi	129.1 (5)	O2—OW2—Na2^xix	89.8 (6)
OW2^iii—O2—K1^vi	129.1 (5)	OW2^iii—OW2—O11^iii	50.9 (4)
Si4^vii—O2—Na1^vi	76.0 (3)	Na2^iv—OW2—O11^iii	110.8 (9)
Si4^vi—O2—Na1^vi	76.0 (3)	Na2^xviii—OW2—O11^iii	58.7 (5)
O1^iii—O2—Na1^vi	101.3 (3)	K1—OW2—O11^iii	44.6 (4)
O1—O2—Na1^vi	101.3 (3)	Na1—OW2—O11^iii	44.6 (4)
O3^vii—O2—Na1^vi	94.3 (3)	Na2^xiii—OW2—O11^iii	113.4 (7)
O3^vi—O2—Na1^vi	94.3 (3)	O11—OW2—O11^iii	69.2 (6)
O11^vi—O2—Na1^vi	44.0 (2)	O1—OW2—O11^iii	172.8 (7)
O11^vii—O2—Na1^vi	44.0 (2)	O2—OW2—O11^iii	134.8 (7)
OW2—O2—Na1^vi	129.1 (5)	Na2^xix—OW2—O11^iii	64.2 (4)
OW2^iii—O2—Na1^vi	129.1 (5)	OW2^iii—OW2—O10	174.2 (3)
K1^vi—O2—Na1^vi	0.00 (15)	Na2^iv—OW2—O10	44.8 (5)
Si4—O3—Si4^v	138.2 (7)	Na2^xviii—OW2—O10	134.2 (7)
Si4—O3—Na2^iv	102.0 (3)	K1—OW2—O10	99.6 (6)
Si4^v—O3—Na2^iv	119.8 (5)	Na1—OW2—O10	99.6 (6)
Si4—O3—Na2^xiii	119.8 (5)	Na2^xiii—OW2—O10	47.0 (4)
Si4^v—O3—Na2^xiii	102.0 (3)	O11—OW2—O10	59.6 (4)
Na2^iv—O3—Na2^xiii	18.8 (4)	O1—OW2—O10	48.4 (4)
Si4—O3—O1^xiii	105.8 (5)	O2—OW2—O10	96.8 (6)
Si4^v—O3—O1^xiii	36.3 (2)	Na2^xix—OW2—O10	129.7 (6)
Na2^iv—O3—O1^xiii	144.1 (3)	O11^iii—OW2—O10	128.4 (8)
Na2^xiii—O3—O1^xiii	131.6 (3)	OW3^iii—OW3—Na3	153.9 (11)
Si4—O3—O1^iv	36.3 (2)	OW3^iii—OW3—Na3^iii	14.5 (6)
Si4^v—O3—O1^iv	105.8 (5)	Na3—OW3—Na3^iii	139.5 (17)
Na2^iv—O3—O1^iv	131.6 (3)	OW3^iii—OW3—K1	78.3 (4)
Na2^xiii—O3—O1^iv	144.1 (3)	Na3—OW3—K1	115.3 (16)
O1^xiii—O3—O1^iv	83.3 (4)	Na3^iii—OW3—K1	86.7 (8)
Si4—O3—O11	34.0 (2)	OW3^iii—OW3—Na1	78.3 (4)
Si4^v—O3—O11	165.4 (4)	Na3—OW3—Na1	115.3 (16)
Na2^iv—O3—O11	70.7 (3)	Na3^iii—OW3—Na1	86.7 (8)
Na2^xiii—O3—O11	87.0 (4)	K1—OW3—Na1	0.00 (19)
O1^xiii—O3—O11	139.8 (4)	OW3^iii—OW3—O5	118.1 (5)
O1^iv—O3—O11	61.7 (3)	Na3—OW3—O5	64.6 (12)
Si4—O3—O11^v	165.4 (4)	Na3^iii—OW3—O5	117.0 (12)
Si4^v—O3—O11^v	34.0 (2)	K1—OW3—O5	52.5 (5)
Na2^iv—O3—O11^v	87.0 (4)	Na1—OW3—O5	52.5 (5)
Na2^xiii—O3—O11^v	70.7 (3)	OW3^iii—OW3—O8^iv	128.4 (5)
O1^xiii—O3—O11^v	61.7 (3)	Na3—OW3—O8^iv	64.3 (12)
O1^iv—O3—O11^v	139.8 (4)	Na3^iii—OW3—O8^iv	132.3 (13)
O11—O3—O11^v	157.6 (6)	K1—OW3—O8^iv	123.8 (8)
Si4—O3—O2^iv	35.79 (19)	Na1—OW3—O8^iv	123.8 (8)
Si4^v—O3—O2^iv	120.3 (5)	O5—OW3—O8^iv	110.7 (7)
Na2^iv—O3—O2^iv	106.6 (3)	OW3^iii—OW3—Na3^x	113.6 (4)
Na2^xiii—O3—O2^iv	124.1 (4)	Na3—OW3—Na3^x	41.7 (9)
O1^xiii—O3—O2^iv	84.2 (4)	Na3^iii—OW3—Na3^x	99.6 (8)
O1^iv—O3—O2^iv	57.3 (2)	K1—OW3—Na3^x	140.7 (12)
O11—O3—O2^iv	61.1 (2)	Na1—OW3—Na3^x	140.7 (12)
O11^v—O3—O2^iv	130.6 (3)	O5—OW3—Na3^x	91.3 (8)
Si4—O3—O2^xiii	120.3 (5)	O8^iv—OW3—Na3^x	79.6 (6)
Si4^v—O3—O2^xiii	35.79 (19)	OW3^iii—OW3—O7^iv	80.0 (4)
Na2^iv—O3—O2^xiii	124.1 (4)	Na3—OW3—O7^iv	107.3 (16)
Na2^xiii—O3—O2^xiii	106.6 (3)	Na3^iii—OW3—O7^iv	85.0 (8)
O1^xiii—O3—O2^xiii	57.3 (2)	K1—OW3—O7^iv	122.3 (9)
O1^iv—O3—O2^xiii	84.2 (4)	Na1—OW3—O7^iv	122.3 (9)
O11—O3—O2^xiii	130.6 (3)	O5—OW3—O7^iv	154.9 (9)
O11^v—O3—O2^xiii	61.1 (2)	O8^iv—OW3—O7^iv	48.5 (5)
O2^iv—O3—O2^xiii	129.2 (6)	Na3^x—OW3—O7^iv	97.0 (8)
Si3^x—O4—Si3	141.5 (6)	OW3^iii—OW3—O6	161.1 (4)
Si3^x—O4—O8^x	36.4 (2)	Na3—OW3—O6	44.9 (8)
Si3—O4—O8^x	117.7 (5)	Na3^iii—OW3—O6	175.3 (10)
Si3^x—O4—O8	117.7 (5)	K1—OW3—O6	89.4 (6)
Si3—O4—O8	36.4 (2)	Na1—OW3—O6	89.4 (6)
O8^x—O4—O8	84.6 (4)	O5—OW3—O6	62.1 (5)
Si3^x—O4—O7	112.8 (4)	O8^iv—OW3—O6	48.8 (4)
Si3—O4—O7	35.8 (2)	Na3^x—OW3—O6	85.1 (5)
O8^x—O4—O7	109.1 (4)	O7^iv—OW3—O6	94.9 (8)
O8—O4—O7	58.2 (2)	OW3^iii—OW3—OW3^x	90.000 (11)
Si3^x—O4—O7^xiv	35.8 (2)	Na3—OW3—OW3^x	65.6 (10)
Si3—O4—O7^xiv	112.8 (4)	Na3^iii—OW3—OW3^x	76.4 (6)
O8^x—O4—O7^xiv	58.2 (2)	K1—OW3—OW3^x	143.0 (6)
O8—O4—O7^xiv	109.1 (4)	Na1—OW3—OW3^x	143.0 (6)
O7—O4—O7^xiv	78.8 (4)	O5—OW3—OW3^x	107.0 (5)
Si3^x—O4—O5	173.1 (5)	O8^iv—OW3—OW3^x	90.9 (5)
Si3—O4—O5	33.89 (18)	Na3^x—OW3—OW3^x	23.9 (4)
O8^x—O4—O5	145.2 (4)	O7^iv—OW3—OW3^x	89.1 (5)
O8—O4—O5	61.4 (2)	O6—OW3—OW3^x	108.3 (4)
O7—O4—O5	60.6 (2)	OW3^iii—OW3—O5^iii	45.4 (4)
O7^xiv—O4—O5	137.3 (4)	Na3—OW3—O5^iii	128.8 (18)
Si3^x—O4—O5^x	33.89 (18)	Na3^iii—OW3—O5^iii	47.0 (6)
Si3—O4—O5^x	173.1 (5)	K1—OW3—O5^iii	44.6 (4)
O8^x—O4—O5^x	61.4 (2)	Na1—OW3—O5^iii	44.6 (4)
O8—O4—O5^x	145.2 (4)	O5—OW3—O5^iii	72.7 (7)
O7—O4—O5^x	137.3 (4)	O8^iv—OW3—O5^iii	163.5 (9)
O7^xiv—O4—O5^x	60.6 (2)	Na3^x—OW3—O5^iii	116.8 (9)
O5—O4—O5^x	149.8 (5)	O7^iv—OW3—O5^iii	123.0 (7)
Si3^x—O4—Na3	128.8 (5)	O6—OW3—O5^iii	130.3 (9)
Si3—O4—Na3	85.3 (3)	OW3^x—OW3—O5^iii	103.6 (4)

Symmetry codes: (i) −x+1, y, z; (ii) x+1, y, z; (iii) −x, y, z; (iv) x, y, z−1; (v) −x+1/2, −y+1/2, z; (vi) x, y, z+1; (vii) −x, y, z+1; (viii) −x+1/2, −y+1/2, z+1; (ix) x+1/2, −y+1/2, z+1; (x) x, −y+1, z; (xi) −x+1, y, z−1; (xii) −x+1, y, z+1; (xiii) −x+1/2, −y+1/2, z−1; (xiv) −x, −y+1, z; (xv) x+1/2, −y+1/2, z−1; (xvi) −x+1, −y+1, z+1; (xvii) x, −y+1, z+1; (xviii) −x, y, z−1; (xix) x−1/2, −y+1/2, z−1.

Trisodium Lanthanum Phyllo-hexasilicate Dihydrate (TR07)

Crystal data

LaH4.5Na3.0O17.25Si6	Dx = 2.654 Mg m^−3
Mr = 656.96	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmm2	Cell parameters from 6924 reflections
a = 7.4153 (3) Å	θ = 3.0–29.1°
b = 31.0018 (14) Å	µ = 3.20 mm^−1
c = 7.1532 (3) Å	T = 293 K
V = 1644.43 (12) Å^3	Prismatic, colurless
Z = 4	0.17 × 0.05 × 0.04 mm
F(000) = 1266

Data collection

Oxford X'Calibur Gemini Ultra diffractometer	1952 independent reflections
Radiation source: fine-focus sealed tube	1896 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.053
Detector resolution: 10.2890 pixels mm^-1	θmax = 29.1°, θmin = 3.1°
phi/ω scans	h = −9→8
Absorption correction: multi scan CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.13 (release 29-11-2007 CrysAlis171 .NET) (compiled Nov 29 2007,17:23:28) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.	k = −41→41
Tmin = 0.688, Tmax = 1.000	l = −9→8
7624 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.053	w = 1/[σ^2(Fo^2) + (0.1P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.150	(Δ/σ)max = 0.001
S = 1.29	Δρmax = 5.00 e Å^−3
1952 reflections	Δρmin = −0.99 e Å^−3
140 parameters	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
1 restraint	Absolute structure parameter: 0.07 (3)
Primary atom site location: structure-invariant direct methods

Special details

Experimental. CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.13 (release 29–11-2007 CrysAlis171. NET) (compiled Nov 29 2007,17:23:28) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
La1	0.5000	0.631250 (17)	1.67208 (12)	0.0100 (2)
Na1	1.0000	0.62651 (12)	1.6891 (10)	0.0073 (9)*
Na2	0.7820 (14)	0.7381 (3)	0.5423 (16)	0.036 (2)	0.50
Na3	0.7527 (14)	0.5376 (4)	1.8858 (15)	0.036 (3)	0.50
Si1	0.5000	0.68219 (11)	1.2637 (6)	0.0106 (7)
Si2	0.5000	0.58395 (9)	1.1687 (8)	0.0107 (6)
Si3	0.7915 (3)	0.54938 (9)	1.4243 (4)	0.0101 (5)
Si4	0.7944 (3)	0.70201 (8)	1.9609 (4)	0.0130 (5)
O1	0.6801 (10)	0.6969 (2)	1.1531 (15)	0.0305 (16)*
O2	1.0000	0.7021 (3)	1.0411 (14)	0.017 (2)
O3	0.7500	0.7500	1.8737 (15)	0.012 (2)
O4	0.7568 (14)	0.5000	1.4909 (15)	0.016 (2)
O5	0.7454 (8)	0.5815 (2)	1.5864 (10)	0.0146 (13)
O6	0.5000	0.5898 (3)	1.9476 (15)	0.018 (2)
O7	1.0000	0.5541 (3)	1.3548 (14)	0.017 (2)
O8	0.6751 (9)	0.5576 (2)	1.2323 (10)	0.0195 (15)
O9	0.5000	0.6295 (3)	1.2886 (15)	0.016 (2)
O10	0.5000	0.7008 (3)	1.4757 (15)	0.024 (2)
O11	0.7577 (9)	0.6679 (2)	1.8049 (13)	0.0251 (18)
OW1	0.5000	0.5000	0.826 (4)	0.018 (6)*	0.50
OW2	1.0000	0.6894 (6)	1.467 (3)	0.078 (5)*
OW3	0.921 (3)	0.5530 (7)	1.905 (4)	0.060 (6)*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
La1	0.0093 (3)	0.0118 (3)	0.0088 (3)	0.000	0.000	0.0003 (4)
Na2	0.041 (6)	0.037 (6)	0.029 (6)	0.003 (5)	−0.014 (5)	0.006 (4)
Na3	0.042 (6)	0.047 (7)	0.018 (6)	0.001 (4)	0.001 (5)	0.018 (5)
Si1	0.0070 (15)	0.0155 (15)	0.0093 (18)	0.000	0.000	0.0042 (13)
Si2	0.0090 (12)	0.0135 (12)	0.0097 (14)	0.000	0.000	0.003 (2)
Si3	0.0099 (10)	0.0107 (11)	0.0097 (13)	0.0009 (9)	−0.0011 (10)	−0.0008 (9)
Si4	0.0105 (11)	0.0114 (10)	0.0169 (14)	0.0008 (9)	0.0006 (11)	−0.0005 (9)
O2	0.012 (4)	0.026 (5)	0.012 (5)	0.000	0.000	−0.005 (4)
O3	0.010 (4)	0.013 (5)	0.013 (6)	0.007 (3)	0.000	0.000
O4	0.025 (5)	0.013 (4)	0.010 (5)	0.000	0.000 (4)	0.000
O5	0.019 (3)	0.014 (3)	0.011 (3)	0.001 (2)	0.004 (3)	−0.005 (3)
O6	0.030 (5)	0.009 (4)	0.016 (5)	0.000	0.000	0.004 (4)
O7	0.018 (5)	0.021 (5)	0.013 (5)	0.000	0.000	0.008 (4)
O8	0.018 (3)	0.021 (3)	0.019 (4)	0.009 (3)	−0.004 (3)	−0.003 (3)
O9	0.022 (5)	0.016 (5)	0.009 (5)	0.000	0.000	0.004 (3)
O10	0.048 (6)	0.015 (4)	0.010 (5)	0.000	0.000	0.000 (4)
O11	0.011 (3)	0.025 (4)	0.038 (5)	−0.002 (3)	−0.006 (3)	−0.014 (4)

Geometric parameters (Å, º)

La1—O6	2.352 (10)	O2—O1^iv	3.496 (11)
La1—O11	2.417 (7)	O3—Si4^iv	1.647 (5)
La1—O11^i	2.417 (7)	O3—Na2^vii	2.411 (16)
La1—O5^i	2.462 (6)	O3—Na2^xi	2.411 (16)
La1—O5	2.462 (6)	O3—O11^iv	2.594 (8)
La1—O10	2.575 (10)	O3—O11	2.594 (8)
La1—O9	2.744 (11)	O3—O1^xi	2.641 (12)
La1—Si1	3.321 (4)	O3—O1^vii	2.641 (12)
La1—Na1	3.7126 (4)	O3—O2^vii	2.660 (9)
La1—Na1^ii	3.7126 (4)	O3—O2^xi	2.660 (9)
La1—Na3^i	3.779 (11)	O4—Si3^viii	1.624 (4)
La1—Na3	3.779 (11)	O4—O5	2.619 (7)
Na1—O11^iii	2.358 (8)	O4—O5^viii	2.619 (7)
Na1—O11	2.358 (8)	O4—O8^viii	2.642 (11)
Na1—O5	2.460 (7)	O4—O8	2.642 (11)
Na1—O5^iii	2.460 (7)	O4—O7^xiv	2.648 (10)
Na1—OW2	2.51 (2)	O4—O7	2.648 (10)
Na1—OW3	2.81 (2)	O4—Na3^viii	3.056 (16)
Na1—OW3^iii	2.81 (2)	O4—OW1^vii	3.06 (3)
Na1—O7	3.280 (12)	O5—O7	2.652 (10)
Na1—Si4^iii	3.403 (5)	O5—O8	2.690 (10)
Na1—Si4	3.403 (5)	O5—OW3	2.77 (3)
Na1—Si3	3.420 (5)	O5—O11	3.101 (10)
Na1—Si3^iii	3.420 (5)	O5—O6	3.171 (11)
Na2—Na2^iv	0.879 (19)	O5—O9	3.171 (11)
Na2—OW2^v	2.276 (16)	O5—OW3^iii	3.48 (2)
Na2—O3^v	2.411 (16)	O6—Si2^vii	1.593 (12)
Na2—O10^v	2.435 (12)	O6—Na3^i	2.516 (13)
Na2—O10^vi	2.535 (14)	O6—O8^vii	2.614 (11)
Na2—O11^v	2.881 (13)	O6—O8^ix	2.614 (11)
Na2—OW2^vi	3.118 (17)	O6—O9^vii	2.731 (15)
Na2—O1^v	3.154 (16)	O6—OW1^vii	2.918 (13)
Na2—Si4^v	3.198 (11)	O6—O5^i	3.171 (11)
Na2—Na2^iii	3.23 (2)	O6—O11	3.246 (11)
Na2—Si1^v	3.368 (11)	O6—O11^i	3.246 (11)
Na2—O1^vi	3.448 (15)	O7—Si3^iii	1.630 (4)
Na3—OW3	1.34 (2)	O7—O8	2.566 (7)
Na3—OW1^vii	2.247 (13)	O7—O8^iii	2.566 (7)
Na3—Na3^viii	2.33 (3)	O7—O4^xiv	2.648 (10)
Na3—OW3^iii	2.47 (2)	O7—O5^iii	2.652 (10)
Na3—O6	2.516 (13)	O7—OW3^v	3.27 (3)
Na3—O5	2.539 (12)	O7—OW3^xii	3.27 (3)
Na3—O8^vii	2.620 (14)	O7—O7^xiv	3.353 (19)
Na3—O4	3.056 (16)	O8—O8^i	2.596 (13)
Na3—OW3^viii	3.07 (2)	O8—O9	2.610 (9)
Na3—Si2^vii	3.110 (13)	O8—O6^v	2.614 (11)
Na3—Si3	3.333 (11)	O8—Na3^v	2.620 (14)
Si1—O1^i	1.618 (9)	O8—OW3^v	2.97 (3)
Si1—O1	1.618 (9)	O9—O10	2.586 (13)
Si1—O10	1.623 (12)	O9—O8^i	2.610 (9)
Si1—O9	1.644 (9)	O9—O1^i	2.663 (11)
Si1—Na2^vii	3.368 (11)	O9—O6^v	2.731 (15)
Si1—Na2^ix	3.368 (11)	O9—O5^i	3.171 (11)
Si2—O6^v	1.593 (12)	O10—Na2^vii	2.435 (12)
Si2—O8^i	1.600 (7)	O10—Na2^ix	2.435 (12)
Si2—O8	1.600 (7)	O10—Na2^xi	2.535 (14)
Si2—O9	1.651 (10)	O10—Na2^xv	2.535 (14)
Si2—Na3^x	3.110 (13)	O10—O1^i	2.669 (14)
Si2—Na3^v	3.110 (13)	O10—O11	3.200 (12)
Si3—O5	1.566 (7)	O10—O11^i	3.200 (12)
Si3—O4	1.624 (4)	O10—OW2^iv	3.40 (2)
Si3—O7	1.630 (4)	O11—O2^vii	2.686 (11)
Si3—O8	1.642 (7)	O11—O1^vii	2.710 (14)
Si4—O11	1.562 (8)	O11—Na2^vii	2.881 (13)
Si4—O1^vii	1.623 (11)	O11—OW2	3.08 (2)
Si4—O2^vii	1.629 (4)	O11—Na2^xi	3.482 (14)
Si4—O3	1.647 (5)	OW1—Na3^v	2.247 (13)
Si4—Na2^vii	3.198 (11)	OW1—Na3^xvi	2.247 (13)
O1—Si4^v	1.623 (10)	OW1—Na3^xvii	2.247 (13)
O1—O2	2.509 (8)	OW1—Na3^x	2.247 (13)
O1—O3^v	2.641 (12)	OW1—O6^v	2.918 (13)
O1—O9	2.663 (11)	OW1—O6^xvi	2.918 (13)
O1—O10	2.669 (14)	OW1—O4^xvi	3.06 (3)
O1—O1^i	2.671 (15)	OW1—O4^v	3.06 (3)
O1—O11^v	2.710 (14)	OW2—Na2^xviii	2.276 (16)
O1—Na2^vii	3.154 (16)	OW2—Na2^vii	2.276 (16)
O1—OW2	3.28 (2)	OW2—O11^iii	3.08 (2)
O1—Na2^xi	3.448 (15)	OW2—Na2^xix	3.118 (17)
O1—O1^iv	3.451 (13)	OW2—Na2^xi	3.118 (17)
O2—Si4^v	1.629 (4)	OW2—O1^iii	3.28 (2)
O2—Si4^xii	1.629 (4)	OW2—O10^iv	3.40 (2)
O2—O1^iii	2.509 (8)	OW3—OW3^iii	1.18 (4)
O2—O3^xii	2.660 (9)	OW3—Na3^iii	2.47 (2)
O2—O3^v	2.660 (9)	OW3—O8^vii	2.97 (3)
O2—O11^v	2.686 (11)	OW3—Na3^viii	3.07 (2)
O2—O11^xii	2.686 (11)	OW3—O7^vii	3.27 (3)
O2—OW2	3.07 (3)	OW3—OW3^viii	3.28 (4)
O2—Na1^v	3.441 (11)	OW3—O5^iii	3.48 (2)
O2—O1^xiii	3.496 (11)	OW3—OW3^xiv	3.49 (4)
O6—La1—O11	85.8 (3)	Na3—O5—O4	72.6 (4)
O6—La1—O11^i	85.8 (3)	Si3—O5—O7	34.7 (2)
O11—La1—O11^i	104.5 (4)	Na1—O5—O7	79.7 (3)
O6—La1—O5^i	82.4 (2)	La1—O5—O7	152.0 (4)
O11—La1—O5^i	167.4 (3)	Na3—O5—O7	109.8 (4)
O11^i—La1—O5^i	78.9 (2)	O4—O5—O7	60.3 (3)
O6—La1—O5	82.4 (2)	Si3—O5—O8	33.9 (2)
O11—La1—O5	78.9 (2)	Na1—O5—O8	125.9 (3)
O11^i—La1—O5	167.4 (3)	La1—O5—O8	105.3 (3)
O5^i—La1—O5	95.3 (3)	Na3—O5—O8	130.6 (4)
O6—La1—O10	156.1 (3)	O4—O5—O8	59.7 (3)
O11—La1—O10	79.7 (3)	O7—O5—O8	57.4 (3)
O11^i—La1—O10	79.7 (3)	Si3—O5—OW3	107.6 (6)
O5^i—La1—O10	112.9 (2)	Na1—O5—OW3	64.8 (5)
O5—La1—O10	112.9 (2)	La1—O5—OW3	110.0 (6)
O6—La1—O9	145.8 (3)	Na3—O5—OW3	28.9 (5)
O11—La1—O9	113.7 (2)	O4—O5—OW3	83.7 (6)
O11^i—La1—O9	113.7 (2)	O7—O5—OW3	94.4 (6)
O5^i—La1—O9	74.8 (2)	O8—O5—OW3	141.0 (6)
O5—La1—O9	74.8 (2)	Si3—O5—O11	156.3 (4)
O10—La1—O9	58.1 (3)	Na1—O5—O11	48.51 (19)
O6—La1—Si1	175.3 (2)	La1—O5—O11	49.89 (17)
O11—La1—Si1	97.0 (2)	Na3—O5—O11	92.1 (4)
O11^i—La1—Si1	97.0 (2)	O4—O5—O11	164.4 (4)
O5^i—La1—Si1	94.51 (18)	O7—O5—O11	124.8 (3)
O5—La1—Si1	94.51 (18)	O8—O5—O11	135.9 (3)
O10—La1—Si1	28.5 (2)	OW3—O5—O11	81.2 (5)
O9—La1—Si1	29.55 (18)	Si3—O5—O6	141.3 (4)
O6—La1—Na1	87.19 (10)	Na1—O5—O6	98.7 (3)
O11—La1—Na1	38.4 (2)	La1—O5—O6	47.32 (17)
O11^i—La1—Na1	142.7 (2)	Na3—O5—O6	50.8 (3)
O5^i—La1—Na1	136.16 (16)	O4—O5—O6	108.0 (4)
O5—La1—Na1	41.01 (16)	O7—O5—O6	160.7 (4)
O10—La1—Na1	92.93 (8)	O8—O5—O6	132.7 (3)
O9—La1—Na1	91.83 (11)	OW3—O5—O6	68.0 (5)
Si1—La1—Na1	92.73 (10)	O11—O5—O6	62.3 (2)
O6—La1—Na1^ii	87.19 (10)	Si3—O5—O9	85.8 (3)
O11—La1—Na1^ii	142.7 (2)	Na1—O5—O9	112.0 (3)
O11^i—La1—Na1^ii	38.4 (2)	La1—O5—O9	56.6 (2)
O5^i—La1—Na1^ii	41.01 (16)	Na3—O5—O9	146.1 (3)
O5—La1—Na1^ii	136.16 (16)	O4—O5—O9	107.2 (4)
O10—La1—Na1^ii	92.93 (7)	O7—O5—O9	98.0 (3)
O9—La1—Na1^ii	91.83 (11)	O8—O5—O9	52.1 (2)
Si1—La1—Na1^ii	92.73 (10)	OW3—O5—O9	166.4 (6)
Na1—La1—Na1^ii	174.11 (16)	O11—O5—O9	87.2 (3)
O6—La1—Na3^i	40.7 (2)	O6—O5—O9	100.4 (3)
O11—La1—Na3^i	126.4 (3)	Si3—O5—OW3^iii	99.6 (5)
O11^i—La1—Na3^i	79.0 (3)	Na1—O5—OW3^iii	53.3 (4)
O5^i—La1—Na3^i	41.7 (2)	La1—O5—OW3^iii	121.5 (5)
O5—La1—Na3^i	89.2 (2)	Na3—O5—OW3^iii	45.2 (5)
O10—La1—Na3^i	149.85 (16)	O4—O5—OW3^iii	84.4 (5)
O9—La1—Na3^i	112.9 (2)	O7—O5—OW3^iii	79.7 (5)
Si1—La1—Na3^i	136.16 (18)	O8—O5—OW3^iii	133.2 (5)
Na1—La1—Na3^i	116.84 (17)	OW3—O5—OW3^iii	17.4 (6)
Na1^ii—La1—Na3^i	57.39 (17)	O11—O5—OW3^iii	82.4 (4)
O6—La1—Na3	40.7 (2)	O6—O5—OW3^iii	84.0 (4)
O11—La1—Na3	79.0 (3)	O9—O5—OW3^iii	165.3 (4)
O11^i—La1—Na3	126.4 (3)	Si2^vii—O6—La1	153.5 (5)
O5^i—La1—Na3	89.2 (2)	Si2^vii—O6—Na3^i	95.8 (4)
O5—La1—Na3	41.7 (2)	La1—O6—Na3^i	101.8 (4)
O10—La1—Na3	149.85 (16)	Si2^vii—O6—Na3	95.8 (4)
O9—La1—Na3	112.9 (2)	La1—O6—Na3	101.8 (4)
Si1—La1—Na3	136.16 (17)	Na3^i—O6—Na3	96.3 (6)
Na1—La1—Na3	57.39 (17)	Si2^vii—O6—O8^vii	35.1 (2)
Na1^ii—La1—Na3	116.84 (18)	La1—O6—O8^vii	149.5 (2)
Na3^i—La1—Na3	59.5 (3)	Na3^i—O6—O8^vii	105.1 (4)
O11^iii—Na1—O11	99.3 (4)	Na3—O6—O8^vii	61.4 (3)
O11^iii—Na1—O5	176.7 (4)	Si2^vii—O6—O8^ix	35.1 (2)
O11—Na1—O5	80.1 (2)	La1—O6—O8^ix	149.50 (19)
O11^iii—Na1—O5^iii	80.1 (2)	Na3^i—O6—O8^ix	61.4 (3)
O11—Na1—O5^iii	176.7 (4)	Na3—O6—O8^ix	105.1 (4)
O5—Na1—O5^iii	100.3 (3)	O8^vii—O6—O8^ix	59.5 (4)
O11^iii—Na1—OW2	78.5 (4)	Si2^vii—O6—O9^vii	33.3 (3)
O11—Na1—OW2	78.5 (4)	La1—O6—O9^vii	120.2 (4)
O5—Na1—OW2	104.5 (4)	Na3^i—O6—O9^vii	116.5 (4)
O5^iii—Na1—OW2	104.5 (4)	Na3—O6—O9^vii	116.5 (4)
O11^iii—Na1—OW3	114.0 (6)	O8^vii—O6—O9^vii	58.4 (3)
O11—Na1—OW3	95.1 (5)	O8^ix—O6—O9^vii	58.4 (3)
O5—Na1—OW3	62.9 (5)	Si2^vii—O6—OW1^vii	100.7 (7)
O5^iii—Na1—OW3	82.2 (5)	La1—O6—OW1^vii	105.8 (7)
OW2—Na1—OW3	166.9 (5)	Na3^i—O6—OW1^vii	48.2 (3)
O11^iii—Na1—OW3^iii	95.1 (5)	Na3—O6—OW1^vii	48.2 (3)
O11—Na1—OW3^iii	114.0 (6)	O8^vii—O6—OW1^vii	82.3 (6)
O5—Na1—OW3^iii	82.2 (5)	O8^ix—O6—OW1^vii	82.3 (6)
O5^iii—Na1—OW3^iii	62.9 (5)	O9^vii—O6—OW1^vii	134.0 (7)
OW2—Na1—OW3^iii	166.9 (5)	Si2^vii—O6—O5^i	143.1 (2)
OW3—Na1—OW3^iii	24.1 (8)	La1—O6—O5^i	50.3 (2)
O11^iii—Na1—O7	128.9 (2)	Na3^i—O6—O5^i	51.5 (3)
O11—Na1—O7	128.9 (2)	Na3—O6—O5^i	103.4 (4)
O5—Na1—O7	52.71 (19)	O8^vii—O6—O5^i	152.7 (4)
O5^iii—Na1—O7	52.71 (19)	O8^ix—O6—O5^i	108.6 (2)
OW2—Na1—O7	94.0 (6)	O9^vii—O6—O5^i	139.9 (2)
OW3—Na1—O7	81.1 (6)	OW1^vii—O6—O5^i	71.3 (5)
OW3^iii—Na1—O7	81.1 (6)	Si2^vii—O6—O5	143.1 (2)
O11^iii—Na1—Si4^iii	23.64 (19)	La1—O6—O5	50.3 (2)
O11—Na1—Si4^iii	76.5 (2)	Na3^i—O6—O5	103.4 (4)
O5—Na1—Si4^iii	154.8 (2)	Na3—O6—O5	51.5 (3)
O5^iii—Na1—Si4^iii	102.51 (17)	O8^vii—O6—O5	108.6 (2)
OW2—Na1—Si4^iii	80.1 (5)	O8^ix—O6—O5	152.7 (4)
OW3—Na1—Si4^iii	109.7 (5)	O9^vii—O6—O5	139.9 (2)
OW3^iii—Na1—Si4^iii	98.6 (5)	OW1^vii—O6—O5	71.3 (5)
O7—Na1—Si4^iii	152.53 (10)	O5^i—O6—O5	70.0 (3)
O11^iii—Na1—Si4	76.5 (2)	Si2^vii—O6—O11	113.4 (4)
O11—Na1—Si4	23.6 (2)	La1—O6—O11	47.9 (2)
O5—Na1—Si4	102.51 (16)	Na3^i—O6—O11	149.6 (5)
O5^iii—Na1—Si4	154.8 (2)	Na3—O6—O11	89.2 (3)
OW2—Na1—Si4	80.1 (5)	O8^vii—O6—O11	103.7 (3)
OW3—Na1—Si4	98.6 (5)	O8^ix—O6—O11	145.3 (4)
OW3^iii—Na1—Si4	109.7 (5)	O9^vii—O6—O11	86.9 (3)
O7—Na1—Si4	152.53 (10)	OW1^vii—O6—O11	128.2 (5)
Si4^iii—Na1—Si4	53.23 (12)	O5^i—O6—O11	98.2 (3)
O11^iii—Na1—Si3	156.8 (2)	O5—O6—O11	57.8 (2)
O11—Na1—Si3	103.31 (19)	Si2^vii—O6—O11^i	113.4 (4)
O5—Na1—Si3	24.64 (16)	La1—O6—O11^i	47.9 (2)
O5^iii—Na1—Si3	77.6 (2)	Na3^i—O6—O11^i	89.2 (3)
OW2—Na1—Si3	101.1 (5)	Na3—O6—O11^i	149.6 (5)
OW3—Na1—Si3	69.1 (5)	O8^vii—O6—O11^i	145.3 (4)
OW3^iii—Na1—Si3	80.3 (5)	O8^ix—O6—O11^i	103.7 (3)
O7—Na1—Si3	28.07 (8)	O9^vii—O6—O11^i	86.9 (3)
Si4^iii—Na1—Si3	178.8 (2)	OW1^vii—O6—O11^i	128.2 (5)
Si4—Na1—Si3	126.49 (6)	O5^i—O6—O11^i	57.8 (2)
O11^iii—Na1—Si3^iii	103.31 (19)	O5—O6—O11^i	98.2 (3)
O11—Na1—Si3^iii	156.8 (2)	O11—O6—O11^i	72.1 (3)
O5—Na1—Si3^iii	77.6 (2)	Si3—O7—Si3^iii	142.9 (7)
O5^iii—Na1—Si3^iii	24.64 (17)	Si3—O7—O8	38.5 (2)
OW2—Na1—Si3^iii	101.1 (5)	Si3^iii—O7—O8	176.6 (6)
OW3—Na1—Si3^iii	80.3 (5)	Si3—O7—O8^iii	176.6 (6)
OW3^iii—Na1—Si3^iii	69.1 (5)	Si3^iii—O7—O8^iii	38.5 (2)
O7—Na1—Si3^iii	28.07 (7)	O8—O7—O8^iii	139.7 (5)
Si4^iii—Na1—Si3^iii	126.49 (6)	Si3—O7—O4	35.5 (3)
Si4—Na1—Si3^iii	178.8 (2)	Si3^iii—O7—O4	118.5 (5)
Si3—Na1—Si3^iii	53.76 (12)	O8—O7—O4	60.9 (3)
Na2^iv—Na2—OW2^v	160.3 (14)	O8^iii—O7—O4	142.4 (4)
Na2^iv—Na2—O3^v	79.5 (2)	Si3—O7—O4^xiv	118.5 (5)
OW2^v—Na2—O3^v	113.8 (7)	Si3^iii—O7—O4^xiv	35.5 (2)
Na2^iv—Na2—O10^v	86.3 (14)	O8—O7—O4^xiv	142.4 (4)
OW2^v—Na2—O10^v	104.5 (6)	O8^iii—O7—O4^xiv	60.9 (3)
O3^v—Na2—O10^v	100.4 (5)	O4—O7—O4^xiv	85.9 (5)
Na2^iv—Na2—O10^vi	73.5 (14)	Si3—O7—O5^iii	120.9 (5)
OW2^v—Na2—O10^vi	89.9 (5)	Si3^iii—O7—O5^iii	33.2 (3)
O3^v—Na2—O10^vi	97.6 (5)	O8—O7—O5^iii	150.2 (4)
O10^v—Na2—O10^vi	149.9 (6)	O8^iii—O7—O5^iii	62.0 (2)
Na2^iv—Na2—O11^v	127.0 (10)	O4—O7—O5^iii	117.3 (4)
OW2^v—Na2—O11^v	72.4 (6)	O4^xiv—O7—O5^iii	59.2 (2)
O3^v—Na2—O11^v	57.9 (3)	Si3—O7—O5	33.2 (3)
O10^v—Na2—O11^v	73.5 (4)	Si3^iii—O7—O5	120.9 (5)
O10^vi—Na2—O11^v	136.6 (5)	O8—O7—O5	62.0 (2)
Na2^iv—Na2—OW2^vi	14.2 (10)	O8^iii—O7—O5	150.2 (4)
OW2^v—Na2—OW2^vi	156.1 (11)	O4—O7—O5	59.2 (2)
O3^v—Na2—OW2^vi	89.6 (5)	O4^xiv—O7—O5	117.3 (4)
O10^v—Na2—OW2^vi	74.5 (4)	O5^iii—O7—O5	90.8 (4)
O10^vi—Na2—OW2^vi	81.7 (4)	Si3—O7—OW3^v	97.4 (5)
O11^v—Na2—OW2^vi	128.0 (5)	Si3^iii—O7—OW3^v	118.0 (5)
Na2^iv—Na2—O1^v	102.2 (7)	O8—O7—OW3^v	59.7 (4)
OW2^v—Na2—O1^v	72.1 (6)	O8^iii—O7—OW3^v	80.4 (4)
O3^v—Na2—O1^v	155.0 (5)	O4—O7—OW3^v	103.5 (5)
O10^v—Na2—O1^v	55.3 (4)	O4^xiv—O7—OW3^v	118.5 (5)
O10^vi—Na2—O1^v	106.8 (5)	O5^iii—O7—OW3^v	138.2 (5)
O11^v—Na2—O1^v	104.8 (4)	O5—O7—OW3^v	119.3 (4)
OW2^vi—Na2—O1^v	88.8 (5)	Si3—O7—OW3^xii	118.0 (5)
Na2^iv—Na2—Si4^v	108.0 (3)	Si3^iii—O7—OW3^xii	97.4 (5)
OW2^v—Na2—Si4^v	88.2 (7)	O8—O7—OW3^xii	80.4 (4)
O3^v—Na2—Si4^v	30.20 (16)	O8^iii—O7—OW3^xii	59.7 (4)
O10^v—Na2—Si4^v	92.4 (4)	O4—O7—OW3^xii	118.5 (5)
O10^vi—Na2—Si4^v	114.8 (4)	O4^xiv—O7—OW3^xii	103.5 (5)
O11^v—Na2—Si4^v	29.2 (2)	O5^iii—O7—OW3^xii	119.3 (4)
OW2^vi—Na2—Si4^v	115.7 (6)	O5—O7—OW3^xii	138.2 (5)
O1^v—Na2—Si4^v	133.8 (4)	OW3^v—O7—OW3^xii	20.7 (7)
Na2^iv—Na2—Na2^iii	122.7 (15)	Si3—O7—Na1	80.7 (4)
OW2^v—Na2—Na2^iii	44.7 (4)	Si3^iii—O7—Na1	80.7 (4)
O3^v—Na2—Na2^iii	95.7 (3)	O8—O7—Na1	102.7 (3)
O10^v—Na2—Na2^iii	149.2 (3)	O8^iii—O7—Na1	102.7 (3)
O10^vi—Na2—Na2^iii	50.4 (3)	O4—O7—Na1	99.5 (3)
O11^v—Na2—Na2^iii	93.6 (3)	O4^xiv—O7—Na1	99.5 (3)
OW2^vi—Na2—Na2^iii	132.1 (3)	O5^iii—O7—Na1	47.6 (2)
O1^v—Na2—Na2^iii	103.9 (2)	O5—O7—Na1	47.6 (2)
Si4^v—Na2—Na2^iii	88.36 (19)	OW3^v—O7—Na1	136.4 (5)
Na2^iv—Na2—Si1^v	95.6 (12)	OW3^xii—O7—Na1	136.4 (5)
OW2^v—Na2—Si1^v	87.7 (5)	Si3—O7—O7^xiv	84.9 (4)
O3^v—Na2—Si1^v	126.8 (4)	Si3^iii—O7—O7^xiv	84.9 (4)
O10^v—Na2—Si1^v	26.8 (3)	O8—O7—O7^xiv	92.4 (3)
O10^vi—Na2—Si1^v	132.0 (5)	O8^iii—O7—O7^xiv	92.4 (3)
O11^v—Na2—Si1^v	87.6 (3)	O4—O7—O7^xiv	50.7 (2)
OW2^vi—Na2—Si1^v	81.5 (4)	O4^xiv—O7—O7^xiv	50.7 (2)
O1^v—Na2—Si1^v	28.48 (18)	O5^iii—O7—O7^xiv	108.7 (2)
Si4^v—Na2—Si1^v	113.1 (3)	O5—O7—O7^xiv	108.7 (2)
Na2^iii—Na2—Si1^v	128.38 (18)	OW3^v—O7—O7^xiv	89.4 (4)
Na2^iv—Na2—O1^vi	63.4 (6)	OW3^xii—O7—O7^xiv	89.4 (4)
OW2^v—Na2—O1^vi	98.0 (7)	Na1—O7—O7^xiv	133.21 (19)
O3^v—Na2—O1^vi	135.4 (4)	Si2—O8—Si3	138.0 (5)
O10^v—Na2—O1^vi	100.9 (4)	Si2—O8—O7	151.7 (4)
O10^vi—Na2—O1^vi	50.2 (3)	Si3—O8—O7	38.2 (3)
O11^v—Na2—O1^vi	166.7 (5)	Si2—O8—O8^i	35.8 (3)
OW2^vi—Na2—O1^vi	59.6 (4)	Si3—O8—O8^i	121.7 (3)
O1^v—Na2—O1^vi	62.8 (4)	O7—O8—O8^i	159.9 (3)
Si4^v—Na2—O1^vi	163.3 (4)	Si2—O8—O9	37.3 (3)
Na2^iii—Na2—O1^vi	85.3 (2)	Si3—O8—O9	105.4 (4)
Si1^v—Na2—O1^vi	82.7 (3)	O7—O8—O9	116.8 (4)
OW3—Na3—OW1^vii	168.1 (13)	O8^i—O8—O9	60.17 (17)
OW3—Na3—Na3^viii	110.8 (10)	Si2—O8—O6^v	34.9 (3)
OW1^vii—Na3—Na3^viii	58.8 (3)	Si3—O8—O6^v	166.4 (4)
OW3—Na3—OW3^iii	10.1 (6)	O7—O8—O6^v	138.5 (4)
OW1^vii—Na3—OW3^iii	158.0 (8)	O8^i—O8—O6^v	60.23 (19)
Na3^viii—Na3—OW3^iii	101.1 (6)	O9—O8—O6^v	63.0 (3)
OW3—Na3—O6	116.4 (12)	Si2—O8—Na3^v	91.7 (4)
OW1^vii—Na3—O6	75.3 (4)	Si3—O8—Na3^v	129.7 (4)
Na3^viii—Na3—O6	130.1 (3)	O7—O8—Na3^v	96.1 (4)
OW3^iii—Na3—O6	126.5 (7)	O8^i—O8—Na3^v	102.7 (3)
OW3—Na3—O5	85.1 (12)	O9—O8—Na3^v	117.2 (4)
OW1^vii—Na3—O5	95.8 (8)	O6^v—O8—Na3^v	57.5 (3)
Na3^viii—Na3—O5	122.5 (3)	Si2—O8—O4	136.9 (5)
OW3^iii—Na3—O5	87.9 (7)	Si3—O8—O4	35.8 (2)
O6—Na3—O5	77.7 (4)	O7—O8—O4	61.1 (3)
OW3—Na3—O8^vii	91.4 (13)	O8^i—O8—O4	103.3 (3)
OW1^vii—Na3—O8^vii	96.8 (8)	O9—O8—O4	125.7 (4)
Na3^viii—Na3—O8^vii	103.7 (3)	O6^v—O8—O4	156.7 (4)
OW3^iii—Na3—O8^vii	96.7 (7)	Na3^v—O8—O4	116.9 (4)
O6—Na3—O8^vii	61.2 (4)	Si2—O8—O5	106.5 (4)
O5—Na3—O8^vii	131.8 (5)	Si3—O8—O5	32.2 (2)
OW3—Na3—O4	102.7 (13)	O7—O8—O5	60.5 (3)
OW1^vii—Na3—O4	68.6 (8)	O8^i—O8—O5	101.17 (19)
Na3^viii—Na3—O4	67.6 (2)	O9—O8—O5	73.5 (3)
OW3^iii—Na3—O4	96.6 (7)	O6^v—O8—O5	136.4 (3)
O6—Na3—O4	114.5 (5)	Na3^v—O8—O5	156.0 (4)
O5—Na3—O4	54.9 (3)	O4—O8—O5	58.8 (3)
O8^vii—Na3—O4	165.3 (5)	Si2—O8—OW3^v	107.3 (6)
OW3—Na3—OW3^viii	86.8 (13)	Si3—O8—OW3^v	109.2 (5)
OW1^vii—Na3—OW3^viii	82.7 (5)	O7—O8—OW3^v	72.0 (5)
Na3^viii—Na3—OW3^viii	24.1 (4)	O8^i—O8—OW3^v	127.8 (5)
OW3^iii—Na3—OW3^viii	77.1 (8)	O9—O8—OW3^v	117.9 (5)
O6—Na3—OW3^viii	151.9 (6)	O6^v—O8—OW3^v	73.1 (5)
O5—Na3—OW3^viii	122.4 (7)	Na3^v—O8—OW3^v	26.8 (5)
O8^vii—Na3—OW3^viii	105.3 (6)	O4—O8—OW3^v	112.3 (5)
O4—Na3—OW3^viii	71.9 (6)	O5—O8—OW3^v	129.6 (5)
OW3—Na3—Si2^vii	109.2 (12)	Si1—O9—Si2	142.5 (8)
OW1^vii—Na3—Si2^vii	82.0 (6)	Si1—O9—O10	37.4 (4)
Na3^viii—Na3—Si2^vii	117.5 (2)	Si2—O9—O10	179.9 (7)
OW3^iii—Na3—Si2^vii	117.7 (7)	Si1—O9—O8^i	146.3 (3)
O6—Na3—Si2^vii	30.6 (3)	Si2—O9—O8^i	35.9 (2)
O5—Na3—Si2^vii	106.7 (4)	O10—O9—O8^i	144.1 (3)
O8^vii—Na3—Si2^vii	30.9 (2)	Si1—O9—O8	146.3 (3)
O4—Na3—Si2^vii	141.6 (4)	Si2—O9—O8	35.9 (2)
OW3^viii—Na3—Si2^vii	129.6 (6)	O10—O9—O8	144.1 (3)
OW3—Na3—Si3	88.9 (13)	O8^i—O9—O8	59.7 (3)
OW1^vii—Na3—Si3	86.6 (8)	Si1—O9—O1^i	34.9 (2)
Na3^viii—Na3—Si3	96.3 (2)	Si2—O9—O1^i	118.8 (5)
OW3^iii—Na3—Si3	87.1 (7)	O10—O9—O1^i	61.1 (3)
O6—Na3—Si3	99.6 (4)	O8^i—O9—O1^i	111.4 (3)
O5—Na3—Si3	26.83 (19)	O8—O9—O1^i	149.7 (5)
O8^vii—Na3—Si3	158.4 (5)	Si1—O9—O1	34.9 (2)
O4—Na3—Si3	29.03 (14)	Si2—O9—O1	118.8 (5)
OW3^viii—Na3—Si3	96.3 (6)	O10—O9—O1	61.1 (3)
Si2^vii—Na3—Si3	130.2 (4)	O8^i—O9—O1	149.7 (5)
OW3—Na3—Na1	45.0 (11)	O8—O9—O1	111.4 (3)
OW1^vii—Na3—Na1	138.4 (8)	O1^i—O9—O1	60.2 (4)
Na3^viii—Na3—Na1	140.0 (2)	Si1—O9—O6^v	110.5 (5)
OW3^iii—Na3—Na1	51.3 (6)	Si2—O9—O6^v	32.0 (3)
O6—Na3—Na1	87.4 (4)	O10—O9—O6^v	147.9 (5)
O5—Na3—Na1	43.1 (2)	O8^i—O9—O6^v	58.6 (3)
O8^vii—Na3—Na1	107.5 (4)	O8—O9—O6^v	58.6 (3)
O4—Na3—Na1	85.7 (3)	O1^i—O9—O6^v	91.6 (4)
OW3^viii—Na3—Na1	120.7 (5)	O1—O9—O6^v	91.6 (4)
Si2^vii—Na3—Na1	102.0 (4)	Si1—O9—La1	95.1 (5)
Si3—Na3—Na1	59.0 (2)	Si2—O9—La1	122.4 (5)
O1^i—Si1—O1	111.3 (7)	O10—O9—La1	57.7 (3)
O1^i—Si1—O10	110.9 (4)	O8^i—O9—La1	99.9 (3)
O1—Si1—O10	110.9 (4)	O8—O9—La1	99.9 (3)
O1^i—Si1—O9	109.5 (3)	O1^i—O9—La1	110.4 (4)
O1—Si1—O9	109.5 (3)	O1—O9—La1	110.4 (4)
O10—Si1—O9	104.7 (5)	O6^v—O9—La1	154.4 (4)
O1^i—Si1—La1	124.3 (4)	Si1—O9—O5	122.6 (4)
O1—Si1—La1	124.3 (4)	Si2—O9—O5	87.0 (3)
O10—Si1—La1	49.3 (3)	O10—O9—O5	93.1 (4)
O9—Si1—La1	55.4 (4)	O8^i—O9—O5	89.4 (3)
O1^i—Si1—Na2^vii	131.0 (3)	O8—O9—O5	54.4 (2)
O1—Si1—Na2^vii	68.4 (4)	O1^i—O9—O5	154.2 (4)
O10—Si1—Na2^vii	42.6 (2)	O1—O9—O5	108.9 (3)
O9—Si1—Na2^vii	116.6 (3)	O6^v—O9—O5	112.9 (3)
La1—Si1—Na2^vii	74.0 (2)	La1—O9—O5	48.5 (2)
O1^i—Si1—Na2^ix	68.4 (4)	Si1—O9—O5^i	122.6 (4)
O1—Si1—Na2^ix	131.0 (3)	Si2—O9—O5^i	87.0 (3)
O10—Si1—Na2^ix	42.6 (2)	O10—O9—O5^i	93.1 (4)
O9—Si1—Na2^ix	116.6 (3)	O8^i—O9—O5^i	54.4 (2)
La1—Si1—Na2^ix	74.0 (2)	O8—O9—O5^i	89.4 (3)
Na2^vii—Si1—Na2^ix	76.8 (4)	O1^i—O9—O5^i	108.9 (3)
O6^v—Si2—O8^i	109.9 (4)	O1—O9—O5^i	154.2 (4)
O6^v—Si2—O8	109.9 (4)	O6^v—O9—O5^i	112.9 (3)
O8^i—Si2—O8	108.5 (6)	La1—O9—O5^i	48.5 (2)
O6^v—Si2—O9	114.7 (5)	O5—O9—O5^i	70.0 (3)
O8^i—Si2—O9	106.8 (4)	Si1—O10—Na2^vii	110.6 (4)
O8—Si2—O9	106.8 (4)	Si1—O10—Na2^ix	110.6 (4)
O6^v—Si2—Na3^x	53.6 (3)	Na2^vii—O10—Na2^ix	118.3 (6)
O8^i—Si2—Na3^x	57.3 (3)	Si1—O10—Na2^xi	116.2 (5)
O8—Si2—Na3^x	116.0 (4)	Na2^vii—O10—Na2^xi	20.2 (4)
O9—Si2—Na3^x	137.1 (3)	Na2^ix—O10—Na2^xi	99.0 (4)
O6^v—Si2—Na3^v	53.6 (3)	Si1—O10—Na2^xv	116.2 (5)
O8^i—Si2—Na3^v	116.0 (4)	Na2^vii—O10—Na2^xv	99.0 (4)
O8—Si2—Na3^v	57.3 (3)	Na2^ix—O10—Na2^xv	20.2 (4)
O9—Si2—Na3^v	137.1 (3)	Na2^xi—O10—Na2^xv	79.2 (5)
Na3^x—Si2—Na3^v	74.1 (4)	Si1—O10—La1	102.2 (4)
O5—Si3—O4	110.4 (5)	Na2^vii—O10—La1	106.9 (4)
O5—Si3—O7	112.1 (4)	Na2^ix—O10—La1	106.9 (4)
O4—Si3—O7	108.9 (5)	Na2^xi—O10—La1	121.6 (4)
O5—Si3—O8	113.9 (4)	Na2^xv—O10—La1	121.6 (4)
O4—Si3—O8	108.0 (5)	Si1—O10—O9	38.0 (3)
O7—Si3—O8	103.3 (4)	Na2^vii—O10—O9	120.4 (3)
O5—Si3—Na3	47.0 (3)	Na2^ix—O10—O9	120.4 (3)
O4—Si3—Na3	65.9 (4)	Na2^xi—O10—O9	137.4 (3)
O7—Si3—Na3	113.2 (4)	Na2^xv—O10—O9	137.4 (3)
O8—Si3—Na3	143.1 (3)	La1—O10—O9	64.2 (3)
O5—Si3—Na1	40.9 (2)	Si1—O10—O1^i	34.5 (2)
O4—Si3—Na1	124.6 (4)	Na2^vii—O10—O1^i	128.3 (5)
O7—Si3—Na1	71.2 (4)	Na2^ix—O10—O1^i	76.2 (4)
O8—Si3—Na1	126.3 (3)	Na2^xi—O10—O1^i	121.0 (5)
Na3—Si3—Na1	64.4 (2)	Na2^xv—O10—O1^i	83.0 (4)
O11—Si4—O1^vii	116.6 (4)	La1—O10—O1^i	115.7 (3)
O11—Si4—O2^vii	114.6 (4)	O9—O10—O1^i	60.9 (3)
O1^vii—Si4—O2^vii	101.0 (5)	Si1—O10—O1	34.5 (2)
O11—Si4—O3	107.9 (5)	Na2^vii—O10—O1	76.2 (4)
O1^vii—Si4—O3	107.7 (4)	Na2^ix—O10—O1	128.3 (5)
O2^vii—Si4—O3	108.6 (4)	Na2^xi—O10—O1	83.0 (4)
O11—Si4—Na2^vii	64.1 (4)	Na2^xv—O10—O1	121.0 (5)
O1^vii—Si4—Na2^vii	144.3 (3)	La1—O10—O1	115.7 (3)
O2^vii—Si4—Na2^vii	110.9 (4)	O9—O10—O1	60.9 (3)
O3—Si4—Na2^vii	47.4 (4)	O1^i—O10—O1	60.0 (4)
O11—Si4—Na1	37.2 (3)	Si1—O10—O11	125.0 (4)
O1^vii—Si4—Na1	130.6 (3)	Na2^vii—O10—O11	59.7 (3)
O2^vii—Si4—Na1	77.5 (3)	Na2^ix—O10—O11	121.3 (5)
O3—Si4—Na1	119.6 (4)	Na2^xi—O10—O11	73.7 (3)
Na2^vii—Si4—Na1	73.6 (2)	Na2^xv—O10—O11	118.8 (5)
Si1—O1—Si4^v	150.8 (6)	La1—O10—O11	48.0 (2)
Si1—O1—O2	162.7 (5)	O9—O10—O11	96.2 (3)
Si4^v—O1—O2	39.6 (3)	O1^i—O10—O11	157.0 (4)
Si1—O1—O3^v	135.1 (4)	O1—O10—O11	108.8 (3)
Si4^v—O1—O3^v	36.4 (2)	Si1—O10—O11^i	125.0 (4)
O2—O1—O3^v	62.1 (3)	Na2^vii—O10—O11^i	121.3 (5)
Si1—O1—O9	35.6 (2)	Na2^ix—O10—O11^i	59.7 (3)
Si4^v—O1—O9	130.3 (5)	Na2^xi—O10—O11^i	118.8 (5)
O2—O1—O9	129.9 (4)	Na2^xv—O10—O11^i	73.7 (3)
O3^v—O1—O9	149.7 (5)	La1—O10—O11^i	48.0 (2)
Si1—O1—O10	34.6 (3)	O9—O10—O11^i	96.2 (3)
Si4^v—O1—O10	171.6 (4)	O1^i—O10—O11^i	108.8 (3)
O2—O1—O10	138.3 (5)	O1—O10—O11^i	157.0 (4)
O3^v—O1—O10	136.4 (4)	O11—O10—O11^i	73.3 (4)
O9—O1—O10	58.0 (3)	Si1—O10—OW2^iv	109.8 (6)
Si1—O1—O1^i	34.4 (3)	Na2^vii—O10—OW2^iv	62.0 (3)
Si4^v—O1—O1^i	121.5 (3)	Na2^ix—O10—OW2^iv	62.0 (3)
O2—O1—O1^i	161.0 (3)	Na2^xi—O10—OW2^iv	42.0 (3)
O3^v—O1—O1^i	101.32 (16)	Na2^xv—O10—OW2^iv	42.0 (3)
O9—O1—O1^i	59.91 (19)	La1—O10—OW2^iv	148.0 (6)
O10—O1—O1^i	60.0 (2)	O9—O10—OW2^iv	147.8 (6)
Si1—O1—O11^v	122.0 (5)	O1^i—O10—OW2^iv	91.7 (5)
Si4^v—O1—O11^v	31.0 (3)	O1—O10—OW2^iv	91.7 (5)
O2—O1—O11^v	61.8 (3)	O11—O10—OW2^iv	109.4 (4)
O3^v—O1—O11^v	58.0 (3)	O11^i—O10—OW2^iv	109.4 (4)
O9—O1—O11^v	100.4 (4)	Si4—O11—Na1	119.1 (4)
O10—O1—O11^v	156.3 (4)	Si4—O11—La1	137.5 (4)
O1^i—O1—O11^v	102.3 (2)	Na1—O11—La1	102.1 (3)
Si1—O1—Na2^vii	83.1 (5)	Si4—O11—O3	37.2 (3)
Si4^v—O1—Na2^vii	125.7 (4)	Na1—O11—O3	128.1 (3)
O2—O1—Na2^vii	91.7 (4)	La1—O11—O3	121.2 (3)
O3^v—O1—Na2^vii	111.6 (4)	Si4—O11—O2^vii	33.5 (2)
O9—O1—Na2^vii	96.7 (5)	Na1—O11—O2^vii	85.8 (3)
O10—O1—Na2^vii	48.6 (3)	La1—O11—O2^vii	164.2 (4)
O1^i—O1—Na2^vii	103.9 (2)	O3—O11—O2^vii	60.5 (3)
O11^v—O1—Na2^vii	153.5 (4)	Si4—O11—O1^vii	32.4 (3)
Si1—O1—OW2	104.0 (6)	Na1—O11—O1^vii	131.7 (4)
Si4^v—O1—OW2	102.1 (5)	La1—O11—O1^vii	110.5 (3)
O2—O1—OW2	62.5 (4)	O3—O11—O1^vii	59.7 (3)
O3^v—O1—OW2	114.9 (4)	O2^vii—O11—O1^vii	55.4 (3)
O9—O1—OW2	93.3 (5)	Si4—O11—Na2^vii	86.7 (4)
O10—O1—OW2	76.9 (4)	Na1—O11—Na2^vii	97.7 (4)
O1^i—O1—OW2	136.4 (4)	La1—O11—Na2^vii	98.5 (4)
O11^v—O1—OW2	116.9 (4)	O3—O11—Na2^vii	51.9 (4)
Na2^vii—O1—OW2	41.4 (4)	O2^vii—O11—Na2^vii	94.0 (4)
Si1—O1—Na2^xi	80.7 (4)	O1^vii—O11—Na2^vii	111.2 (4)
Si4^v—O1—Na2^xi	125.8 (4)	Si4—O11—OW2	108.1 (5)
O2—O1—Na2^xi	98.2 (4)	Na1—O11—OW2	53.0 (4)
O3^v—O1—Na2^xi	103.3 (3)	La1—O11—OW2	104.7 (4)
O9—O1—Na2^xi	101.9 (4)	O3—O11—OW2	87.1 (4)
O10—O1—Na2^xi	46.8 (3)	O2^vii—O11—OW2	91.0 (4)
O1^i—O1—Na2^xi	94.7 (2)	O1^vii—O11—OW2	140.5 (5)
O11^v—O1—Na2^xi	156.8 (4)	Na2^vii—O11—OW2	44.7 (4)
Na2^vii—O1—Na2^xi	14.4 (3)	Si4—O11—O5	161.9 (5)
OW2—O1—Na2^xi	55.2 (4)	Na1—O11—O5	51.4 (2)
Si1—O1—O1^iv	121.1 (4)	La1—O11—O5	51.19 (18)
Si4^v—O1—O1^iv	75.5 (3)	O3—O11—O5	160.4 (5)
O2—O1—O1^iv	69.8 (3)	O2^vii—O11—O5	132.7 (3)
O3^v—O1—O1^iv	49.2 (2)	O1^vii—O11—O5	138.1 (4)
O9—O1—O1^iv	154.1 (4)	Na2^vii—O11—O5	109.0 (4)
O10—O1—O1^iv	96.1 (3)	OW2—O11—O5	79.0 (4)
O1^i—O1—O1^iv	107.5 (2)	Si4—O11—O10	114.4 (4)
O11^v—O1—O1^iv	104.7 (2)	Na1—O11—O10	111.7 (4)
Na2^vii—O1—O1^iv	62.8 (2)	La1—O11—O10	52.3 (2)
OW2—O1—O1^iv	81.4 (4)	O3—O11—O10	79.2 (3)
Na2^xi—O1—O1^iv	54.4 (2)	O2^vii—O11—O10	137.4 (4)
Si4^v—O2—Si4^xii	138.7 (7)	O1^vii—O11—O10	116.3 (3)
Si4^v—O2—O1^iii	175.7 (6)	Na2^vii—O11—O10	46.9 (3)
Si4^xii—O2—O1^iii	39.4 (3)	OW2—O11—O10	72.7 (3)
Si4^v—O2—O1	39.4 (3)	O5—O11—O10	83.5 (3)
Si4^xii—O2—O1	175.7 (6)	Si4—O11—O6	112.5 (5)
O1^iii—O2—O1	142.0 (6)	Na1—O11—O6	98.9 (3)
Si4^v—O2—O3^xii	119.7 (5)	La1—O11—O6	46.3 (2)
Si4^xii—O2—O3^xii	35.9 (2)	O3—O11—O6	131.2 (4)
O1^iii—O2—O3^xii	61.4 (3)	O2^vii—O11—O6	119.4 (4)
O1—O2—O3^xii	147.0 (4)	O1^vii—O11—O6	80.4 (3)
Si4^v—O2—O3^v	35.9 (2)	Na2^vii—O11—O6	143.6 (4)
Si4^xii—O2—O3^v	119.7 (5)	OW2—O11—O6	138.6 (5)
O1^iii—O2—O3^v	147.0 (4)	O5—O11—O6	59.9 (3)
O1—O2—O3^v	61.4 (3)	O10—O11—O6	96.8 (3)
O3^xii—O2—O3^v	88.4 (4)	Si4—O11—Na2^xi	80.3 (4)
Si4^v—O2—O11^v	31.9 (3)	Na1—O11—Na2^xi	109.3 (4)
Si4^xii—O2—O11^v	113.8 (5)	La1—O11—Na2^xi	96.6 (3)
O1^iii—O2—O11^v	143.9 (4)	O3—O11—Na2^xi	43.8 (4)
O1—O2—O11^v	62.8 (3)	O2^vii—O11—Na2^xi	93.7 (4)
O3^xii—O2—O11^v	113.8 (5)	O1^vii—O11—Na2^xi	101.5 (3)
O3^v—O2—O11^v	58.1 (2)	Na2^vii—O11—Na2^xi	11.6 (3)
Si4^v—O2—O11^xii	113.8 (5)	OW2—O11—Na2^xi	56.3 (4)
Si4^xii—O2—O11^xii	31.9 (3)	O5—O11—Na2^xi	116.6 (4)
O1^iii—O2—O11^xii	62.8 (3)	O10—O11—Na2^xi	44.3 (3)
O1—O2—O11^xii	143.9 (4)	O6—O11—Na2^xi	138.1 (3)
O3^xii—O2—O11^xii	58.1 (2)	Na3^v—OW1—Na3^xvi	158.2 (16)
O3^v—O2—O11^xii	113.8 (5)	Na3^v—OW1—Na3^xvii	62.5 (6)
O11^v—O2—O11^xii	84.0 (4)	Na3^xvi—OW1—Na3^xvii	113.0 (8)
Si4^v—O2—OW2	110.4 (4)	Na3^v—OW1—Na3^x	113.0 (8)
Si4^xii—O2—OW2	110.4 (4)	Na3^xvi—OW1—Na3^x	62.5 (6)
O1^iii—O2—OW2	71.0 (3)	Na3^xvii—OW1—Na3^x	158.2 (16)
O1—O2—OW2	71.0 (3)	Na3^v—OW1—O6^v	56.5 (4)
O3^xii—O2—OW2	121.2 (4)	Na3^xvi—OW1—O6^v	116.0 (6)
O3^v—O2—OW2	121.2 (4)	Na3^xvii—OW1—O6^v	116.0 (6)
O11^v—O2—OW2	125.0 (4)	Na3^x—OW1—O6^v	56.5 (4)
O11^xii—O2—OW2	125.0 (4)	Na3^v—OW1—O6^xvi	116.0 (6)
Si4^v—O2—Na1^v	75.0 (3)	Na3^xvi—OW1—O6^xvi	56.5 (4)
Si4^xii—O2—Na1^v	75.0 (3)	Na3^xvii—OW1—O6^xvi	56.5 (4)
O1^iii—O2—Na1^v	100.9 (3)	Na3^x—OW1—O6^xvi	116.0 (6)
O1—O2—Na1^v	100.9 (3)	O6^v—OW1—O6^xvi	145.4 (12)
O3^xii—O2—Na1^v	92.9 (3)	Na3^v—OW1—O4^xvi	131.8 (10)
O3^v—O2—Na1^v	92.9 (3)	Na3^xvi—OW1—O4^xvi	68.3 (5)
O11^v—O2—Na1^v	43.1 (2)	Na3^xvii—OW1—O4^xvi	131.8 (10)
O11^xii—O2—Na1^v	43.1 (2)	Na3^x—OW1—O4^xvi	68.3 (5)
OW2—O2—Na1^v	129.7 (5)	O6^v—OW1—O4^xvi	103.5 (4)
Si4^v—O2—O1^xiii	116.1 (4)	O6^xvi—OW1—O4^xvi	103.5 (4)
Si4^xii—O2—O1^xiii	74.1 (3)	Na3^v—OW1—O4^v	68.3 (5)
O1^iii—O2—O1^xiii	67.9 (3)	Na3^xvi—OW1—O4^v	131.8 (10)
O1—O2—O1^xiii	110.2 (4)	Na3^xvii—OW1—O4^v	68.3 (5)
O3^xii—O2—O1^xiii	48.5 (3)	Na3^x—OW1—O4^v	131.8 (10)
O3^v—O2—O1^xiii	82.5 (3)	O6^v—OW1—O4^v	103.5 (4)
O11^v—O2—O1^xiii	138.9 (4)	O6^xvi—OW1—O4^v	103.5 (4)
O11^xii—O2—O1^xiii	104.0 (3)	O4^xvi—OW1—O4^v	76.9 (8)
OW2—O2—O1^xiii	83.6 (4)	Na2^xviii—OW2—Na2^vii	90.5 (9)
Na1^v—O2—O1^xiii	141.1 (3)	Na2^xviii—OW2—Na1	111.4 (8)
Si4^v—O2—O1^iv	74.1 (3)	Na2^vii—OW2—Na1	111.4 (8)
Si4^xii—O2—O1^iv	116.1 (4)	Na2^xviii—OW2—O2	98.6 (7)
O1^iii—O2—O1^iv	110.2 (4)	Na2^vii—OW2—O2	98.6 (7)
O1—O2—O1^iv	67.9 (3)	Na1—OW2—O2	136.5 (8)
O3^xii—O2—O1^iv	82.5 (3)	Na2^xviii—OW2—O11^iii	62.9 (5)
O3^v—O2—O1^iv	48.5 (3)	Na2^vii—OW2—O11^iii	111.9 (9)
O11^v—O2—O1^iv	104.0 (3)	Na1—OW2—O11^iii	48.5 (4)
O11^xii—O2—O1^iv	138.9 (4)	O2—OW2—O11^iii	143.6 (3)
OW2—O2—O1^iv	83.6 (4)	Na2^xviii—OW2—O11	111.9 (9)
Na1^v—O2—O1^iv	141.1 (3)	Na2^vii—OW2—O11	62.9 (5)
O1^xiii—O2—O1^iv	44.9 (3)	Na1—OW2—O11	48.5 (4)
Si4^iv—O3—Si4	135.5 (7)	O2—OW2—O11	143.6 (3)
Si4^iv—O3—Na2^vii	122.1 (5)	O11^iii—OW2—O11	71.3 (6)
Si4—O3—Na2^vii	102.4 (3)	Na2^xviii—OW2—Na2^xix	5.4 (4)
Si4^iv—O3—Na2^xi	102.4 (3)	Na2^vii—OW2—Na2^xix	87.6 (6)
Si4—O3—Na2^xi	122.1 (5)	Na1—OW2—Na2^xix	116.8 (7)
Na2^vii—O3—Na2^xi	21.0 (5)	O2—OW2—Na2^xix	94.5 (6)
Si4^iv—O3—O11^iv	35.0 (2)	O11^iii—OW2—Na2^xix	68.3 (4)
Si4—O3—O11^iv	164.4 (5)	O11—OW2—Na2^xix	114.3 (8)
Na2^vii—O3—O11^iv	88.1 (5)	Na2^xviii—OW2—Na2^xi	87.6 (6)
Na2^xi—O3—O11^iv	70.2 (3)	Na2^vii—OW2—Na2^xi	5.4 (4)
Si4^iv—O3—O11	164.4 (5)	Na1—OW2—Na2^xi	116.8 (7)
Si4—O3—O11	35.0 (2)	O2—OW2—Na2^xi	94.5 (6)
Na2^vii—O3—O11	70.2 (3)	O11^iii—OW2—Na2^xi	114.3 (8)
Na2^xi—O3—O11	88.1 (5)	O11—OW2—Na2^xi	68.3 (4)
O11^iv—O3—O11	158.1 (6)	Na2^xix—OW2—Na2^xi	84.3 (6)
Si4^iv—O3—O1^xi	35.8 (3)	Na2^xviii—OW2—O1	129.0 (8)
Si4—O3—O1^xi	103.7 (5)	Na2^vii—OW2—O1	66.4 (4)
Na2^vii—O3—O1^xi	145.1 (4)	Na1—OW2—O1	119.2 (4)
Na2^xi—O3—O1^xi	131.9 (3)	O2—OW2—O1	46.4 (4)
O11^iv—O3—O1^xi	62.4 (3)	O11^iii—OW2—O1	167.1 (6)
O11—O3—O1^xi	138.7 (5)	O11—OW2—O1	97.5 (2)
Si4^iv—O3—O1^vii	103.7 (5)	Na2^xix—OW2—O1	123.6 (7)
Si4—O3—O1^vii	35.8 (3)	Na2^xi—OW2—O1	65.2 (3)
Na2^vii—O3—O1^vii	131.9 (3)	Na2^xviii—OW2—O1^iii	66.4 (4)
Na2^xi—O3—O1^vii	145.1 (4)	Na2^vii—OW2—O1^iii	129.0 (8)
O11^iv—O3—O1^vii	138.7 (5)	Na1—OW2—O1^iii	119.2 (4)
O11—O3—O1^vii	62.4 (3)	O2—OW2—O1^iii	46.4 (4)
O1^xi—O3—O1^vii	81.6 (5)	O11^iii—OW2—O1^iii	97.5 (2)
Si4^iv—O3—O2^vii	118.2 (5)	O11—OW2—O1^iii	167.1 (6)
Si4—O3—O2^vii	35.5 (2)	Na2^xix—OW2—O1^iii	65.2 (3)
Na2^vii—O3—O2^vii	106.8 (3)	Na2^xi—OW2—O1^iii	123.6 (7)
Na2^xi—O3—O2^vii	126.7 (4)	O1—OW2—O1^iii	92.8 (7)
O11^iv—O3—O2^vii	130.4 (3)	Na2^xviii—OW2—O10^iv	48.1 (4)
O11—O3—O2^vii	61.5 (3)	Na2^vii—OW2—O10^iv	48.1 (4)
O1^xi—O3—O2^vii	82.5 (4)	Na1—OW2—O10^iv	139.8 (9)
O1^vii—O3—O2^vii	56.5 (3)	O2—OW2—O10^iv	83.7 (5)
Si4^iv—O3—O2^xi	35.5 (2)	O11^iii—OW2—O10^iv	101.7 (6)
Si4—O3—O2^xi	118.2 (5)	O11—OW2—O10^iv	101.7 (6)
Na2^vii—O3—O2^xi	126.7 (4)	Na2^xix—OW2—O10^iv	43.6 (3)
Na2^xi—O3—O2^xi	106.8 (3)	Na2^xi—OW2—O10^iv	43.6 (3)
O11^iv—O3—O2^xi	61.5 (3)	O1—OW2—O10^iv	86.6 (4)
O11—O3—O2^xi	130.4 (3)	O1^iii—OW2—O10^iv	86.6 (4)
O1^xi—O3—O2^xi	56.5 (3)	OW3^iii—OW3—Na3	158.3 (11)
O1^vii—O3—O2^xi	82.5 (4)	OW3^iii—OW3—Na3^iii	11.6 (6)
O2^vii—O3—O2^xi	126.5 (6)	Na3—OW3—Na3^iii	146.7 (16)
Si3^viii—O4—Si3	141.1 (7)	OW3^iii—OW3—O5	118.0 (5)
Si3^viii—O4—O5	172.4 (6)	Na3—OW3—O5	66.0 (11)
Si3—O4—O5	34.1 (2)	Na3^iii—OW3—O5	118.5 (10)
Si3^viii—O4—O5^viii	34.1 (2)	OW3^iii—OW3—Na1	77.9 (4)
Si3—O4—O5^viii	172.4 (6)	Na3—OW3—Na1	115.3 (14)
O5—O4—O5^viii	149.5 (6)	Na3^iii—OW3—Na1	85.5 (7)
Si3^viii—O4—O8^viii	36.3 (3)	O5—OW3—Na1	52.3 (5)
Si3—O4—O8^viii	117.9 (6)	OW3^iii—OW3—O8^vii	127.8 (5)
O5—O4—O8^viii	145.8 (5)	Na3—OW3—O8^vii	61.8 (11)
O5^viii—O4—O8^viii	61.5 (2)	Na3^iii—OW3—O8^vii	130.8 (10)
Si3^viii—O4—O8	117.9 (6)	O5—OW3—O8^vii	110.2 (7)
Si3—O4—O8	36.3 (3)	Na1—OW3—O8^vii	121.4 (8)
O5—O4—O8	61.5 (2)	OW3^iii—OW3—Na3^viii	113.9 (4)
O5^viii—O4—O8	145.8 (5)	Na3—OW3—Na3^viii	45.1 (9)
O8^viii—O4—O8	85.1 (4)	Na3^iii—OW3—Na3^viii	102.6 (8)
Si3^viii—O4—O7^xiv	35.6 (3)	O5—OW3—Na3^viii	93.7 (7)
Si3—O4—O7^xiv	112.4 (5)	Na1—OW3—Na3^viii	143.1 (10)
O5—O4—O7^xiv	136.8 (4)	O8^vii—OW3—Na3^viii	80.2 (6)
O5^viii—O4—O7^xiv	60.5 (3)	OW3^iii—OW3—O7^vii	79.7 (4)
O8^viii—O4—O7^xiv	58.0 (2)	Na3—OW3—O7^vii	105.7 (14)
O8—O4—O7^xiv	109.1 (5)	Na3^iii—OW3—O7^vii	83.1 (7)
Si3^viii—O4—O7	112.4 (5)	O5—OW3—O7^vii	152.9 (9)
Si3—O4—O7	35.6 (3)	Na1—OW3—O7^vii	119.6 (8)
O5—O4—O7	60.5 (3)	O8^vii—OW3—O7^vii	48.2 (4)
O5^viii—O4—O7	136.8 (4)	Na3^viii—OW3—O7^vii	97.2 (7)
O8^viii—O4—O7	109.1 (5)	OW3^iii—OW3—OW3^viii	90.000 (12)
O8—O4—O7	58.0 (3)	Na3—OW3—OW3^viii	69.2 (11)
O7^xiv—O4—O7	78.6 (5)	Na3^iii—OW3—OW3^viii	78.9 (6)
Si3^viii—O4—Na3	129.2 (5)	O5—OW3—OW3^viii	108.6 (5)
Si3—O4—Na3	85.0 (4)	Na1—OW3—OW3^viii	144.1 (5)
O5—O4—Na3	52.5 (3)	O8^vii—OW3—OW3^viii	92.8 (4)
O5^viii—O4—Na3	97.3 (4)	Na3^viii—OW3—OW3^viii	24.1 (4)
O8^viii—O4—Na3	154.5 (4)	O7^vii—OW3—OW3^viii	90.6 (4)
O8—O4—Na3	112.8 (3)	OW3^iii—OW3—O6	159.2 (4)
O7^xiv—O4—Na3	126.0 (4)	Na3—OW3—O6	42.5 (9)
O7—O4—Na3	96.0 (4)	Na3^iii—OW3—O6	170.8 (9)
Si3^viii—O4—Na3^viii	85.0 (4)	O5—OW3—O6	61.8 (5)
Si3—O4—Na3^viii	129.2 (5)	Na1—OW3—O6	88.2 (6)
O5—O4—Na3^viii	97.3 (4)	O8^vii—OW3—O6	48.5 (4)
O5^viii—O4—Na3^viii	52.5 (3)	Na3^viii—OW3—O6	86.4 (5)
O8^viii—O4—Na3^viii	112.8 (3)	O7^vii—OW3—O6	94.3 (7)
O8—O4—Na3^viii	154.5 (4)	OW3^viii—OW3—O6	110.0 (4)
O7^xiv—O4—Na3^viii	96.0 (4)	OW3^iii—OW3—O5^iii	44.6 (4)
O7—O4—Na3^viii	126.0 (4)	Na3—OW3—O5^iii	133.3 (16)
Na3—O4—Na3^viii	44.8 (5)	Na3^iii—OW3—O5^iii	46.8 (5)
Si3^viii—O4—OW1^vii	109.2 (4)	O5—OW3—O5^iii	73.4 (6)
Si3—O4—OW1^vii	109.2 (4)	Na1—OW3—O5^iii	44.5 (4)
O5—O4—OW1^vii	77.0 (3)	O8^vii—OW3—O5^iii	160.1 (8)
O5^viii—O4—OW1^vii	77.0 (3)	Na3^viii—OW3—O5^iii	119.5 (8)
O8^viii—O4—OW1^vii	113.9 (4)	O7^vii—OW3—O5^iii	120.9 (6)
O8—O4—OW1^vii	113.9 (4)	OW3^viii—OW3—O5^iii	104.7 (4)
O7^xiv—O4—OW1^vii	135.4 (3)	O6—OW3—O5^iii	129.7 (7)
O7—O4—OW1^vii	135.4 (3)	OW3^iii—OW3—OW3^xiv	70.3 (7)
Na3—O4—OW1^vii	43.1 (4)	Na3—OW3—OW3^xiv	88.7 (13)
Na3^viii—O4—OW1^vii	43.1 (4)	Na3^iii—OW3—OW3^xiv	59.2 (7)
Si3—O5—Na1	114.5 (3)	O5—OW3—OW3^xiv	117.3 (6)
Si3—O5—La1	138.1 (4)	Na1—OW3—OW3^xiv	133.8 (7)
Na1—O5—La1	97.9 (2)	O8^vii—OW3—OW3^xiv	104.6 (6)
Si3—O5—Na3	106.1 (4)	Na3^viii—OW3—OW3^xiv	43.7 (5)
Na1—O5—Na3	92.1 (4)	O7^vii—OW3—OW3^xiv	87.1 (4)
La1—O5—Na3	98.1 (4)	OW3^viii—OW3—OW3^xiv	19.7 (7)
Si3—O5—O4	35.5 (3)	O6—OW3—OW3^xiv	129.6 (10)
Na1—O5—O4	126.9 (3)	O5^iii—OW3—OW3^xiv	90.0 (6)
La1—O5—O4	133.9 (3)

Symmetry codes: (i) −x+1, y, z; (ii) x−1, y, z; (iii) −x+2, y, z; (iv) −x+3/2, −y+3/2, z; (v) x, y, z−1; (vi) −x+3/2, −y+3/2, z−1; (vii) x, y, z+1; (viii) x, −y+1, z; (ix) −x+1, y, z+1; (x) −x+1, y, z−1; (xi) −x+3/2, −y+3/2, z+1; (xii) −x+2, y, z−1; (xiii) x+1/2, −y+3/2, z; (xiv) −x+2, −y+1, z; (xv) x−1/2, −y+3/2, z+1; (xvi) −x+1, −y+1, z−1; (xvii) x, −y+1, z−1; (xviii) −x+2, y, z+1; (xix) x+1/2, −y+3/2, z+1.

Trisodium Europium Lanthanum Phyllo-hexasilicate Dihydrate (TR08)

Crystal data

Eu0.32H5.28La0.68Na2.74O17.51Si6	F(000) = 1271
Mr = 660.09	Dx = 2.693 Mg m^−3
Orthorhombic, Cmm2	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: C 2 -2	Cell parameters from 12720 reflections
a = 7.3907 (1) Å	θ = 3.1–32.7°
b = 30.8726 (6) Å	µ = 3.63 mm^−1
c = 7.1271 (1) Å	T = 293 K
V = 1626.19 (4) Å^3	Prismatic, colourless
Z = 4	0.15 × 0.05 × 0.04 mm

Data collection

Oxford X'Calibur Gemini Ultra diffractometer	3105 independent reflections
Radiation source: fine-focus sealed tube	2877 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.071
Detector resolution: 10.2890 pixels mm^-1	θmax = 32.7°, θmin = 3.2°
phi/ω scans	h = −11→11
Absorption correction: multi-scan CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) (compiled Jun 10 2008,16:49:55) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.	k = −46→46
Tmin = 0.914, Tmax = 1.000	l = −10→10
22263 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.051	w = 1/[σ^2(Fo^2) + (0.1P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.136	(Δ/σ)max = 0.970
S = 1.04	Δρmax = 3.42 e Å^−3
3105 reflections	Δρmin = −1.84 e Å^−3
141 parameters	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
1 restraint	Absolute structure parameter: 0.11 (2)
Primary atom site location: structure-invariant direct methods

Special details

Experimental. CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.32.29 (release 10–06-2008 CrysAlis171. NET) (compiled Jun 10 2008,16:49:55) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
La1	0.5000	0.631135 (12)	1.67144 (8)	0.0009 (8)*	0.68 (4)
Eu1	0.5000	0.631135 (12)	1.67144 (8)	0.032 (2)*	0.32 (4)
Na1	1.0000	0.62541 (11)	1.6939 (7)	0.0150 (8)*
Na2	0.7826 (10)	0.7374 (3)	0.5363 (11)	0.0322 (18)	0.50
Na3	0.7547 (11)	0.5376 (3)	1.8831 (12)	0.032 (10)*	0.35 (12)
OW4	0.7547 (11)	0.5376 (3)	1.8831 (12)	0.0 (2)*	0.15 (12)
Si1	0.5000	0.68210 (8)	1.2652 (4)	0.0091 (5)
Si2	0.5000	0.58399 (7)	1.1631 (6)	0.0103 (4)
Si3	0.7910 (2)	0.54966 (6)	1.4237 (3)	0.0089 (4)
Si4	0.7930 (2)	0.70203 (6)	1.9596 (3)	0.0118 (4)
O1	0.6799 (8)	0.69709 (18)	1.1520 (11)	0.0274 (13)
O2	1.0000	0.7016 (3)	1.0362 (11)	0.0172 (15)
O3	0.7500	0.7500	1.8699 (11)	0.0147 (15)
O4	0.7572 (11)	0.5000	1.4909 (12)	0.0171 (15)
O5	0.7412 (7)	0.58227 (17)	1.5840 (7)	0.0161 (10)
O6	0.5000	0.5904 (2)	1.9443 (11)	0.0187 (15)
O7	1.0000	0.5543 (3)	1.3543 (11)	0.0180 (15)
O8	0.6760 (7)	0.55703 (17)	1.2286 (8)	0.0190 (11)
O9	0.5000	0.6289 (2)	1.2873 (12)	0.0185 (15)
O10	0.5000	0.7003 (3)	1.4764 (12)	0.0251 (17)
O11	0.7532 (7)	0.66723 (19)	1.8052 (9)	0.0225 (13)
OW1	0.5000	0.5000	0.826 (3)	0.018 (4)*	0.50
OW2	1.0000	0.6900 (5)	1.466 (3)	0.080 (5)*
OW3	0.924 (2)	0.5543 (5)	1.901 (3)	0.050 (4)*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Na2	0.033 (4)	0.038 (5)	0.025 (4)	0.002 (3)	−0.014 (3)	−0.001 (3)
Si1	0.0083 (11)	0.0125 (11)	0.0064 (12)	0.000	0.000	0.0010 (9)
Si2	0.0104 (9)	0.0125 (9)	0.0079 (10)	0.000	0.000	0.0032 (15)
Si3	0.0091 (7)	0.0101 (8)	0.0075 (8)	0.0012 (6)	−0.0011 (6)	−0.0002 (6)
Si4	0.0098 (8)	0.0113 (8)	0.0144 (9)	0.0003 (6)	0.0006 (7)	0.0005 (6)
O1	0.022 (2)	0.031 (3)	0.030 (3)	0.002 (2)	0.016 (3)	0.011 (3)
O2	0.010 (3)	0.025 (4)	0.017 (4)	0.000	0.000	0.004 (3)
O3	0.011 (3)	0.023 (4)	0.010 (4)	0.008 (3)	0.000	0.000
O4	0.023 (4)	0.014 (3)	0.015 (4)	0.000	0.005 (3)	0.000
O5	0.021 (2)	0.017 (2)	0.010 (2)	0.0016 (19)	0.0064 (19)	−0.0040 (18)
O6	0.027 (4)	0.019 (3)	0.010 (4)	0.000	0.000	0.005 (3)
O7	0.011 (3)	0.028 (4)	0.015 (4)	0.000	0.000	0.004 (3)
O8	0.021 (3)	0.021 (2)	0.014 (2)	0.008 (2)	−0.007 (2)	−0.0045 (18)
O9	0.020 (4)	0.017 (3)	0.018 (4)	0.000	0.000	0.005 (3)
O10	0.048 (5)	0.017 (3)	0.010 (3)	0.000	0.000	−0.003 (3)
O11	0.011 (2)	0.023 (3)	0.034 (3)	0.002 (2)	−0.007 (2)	−0.011 (2)

Geometric parameters (Å, º)

La1—O6	2.315 (7)	O1—OW2	3.263 (16)
La1—O11	2.377 (6)	O1—Na2^xi	3.416 (12)
La1—O11^i	2.377 (6)	O1—O1^v	3.427 (11)
La1—O5^i	2.417 (5)	O2—Si4^vi	1.624 (3)
La1—O5	2.417 (5)	O2—Si4^xii	1.624 (3)
La1—O10	2.548 (8)	O2—O1^iii	2.509 (6)
La1—O9	2.738 (9)	O2—O3^xii	2.656 (7)
La1—Si1	3.295 (3)	O2—O3^vi	2.656 (6)
La1—Na1^ii	3.7030 (3)	O2—O11^vi	2.676 (8)
La1—Na1	3.7030 (3)	O2—O11^xii	2.676 (8)
La1—OW4^i	3.764 (9)	O2—OW2	3.08 (2)
La1—Na3^i	3.764 (9)	O2—Na1^vi	3.388 (9)
Eu1—O6	2.315 (7)	O2—O1^xiii	3.498 (9)
Eu1—O11	2.377 (6)	O2—O1^v	3.498 (9)
Eu1—O11^i	2.377 (6)	O3—Si4^v	1.644 (4)
Eu1—O5^i	2.417 (5)	O3—Na2^iv	2.422 (12)
Eu1—O5	2.417 (5)	O3—Na2^xi	2.422 (12)
Eu1—O10	2.548 (8)	O3—O11^v	2.597 (6)
Eu1—O9	2.738 (9)	O3—O11	2.597 (6)
Eu1—Si1	3.295 (3)	O3—O1^xi	2.642 (9)
Eu1—Na1^ii	3.7030 (3)	O3—O1^iv	2.642 (9)
Eu1—Na1	3.7030 (3)	O3—O2^iv	2.656 (7)
Eu1—OW4^i	3.764 (9)	O3—O2^xi	2.656 (6)
Eu1—Na3^i	3.764 (9)	O4—Si3^viii	1.625 (3)
Na1—O11^iii	2.371 (6)	O4—O5	2.628 (6)
Na1—O11	2.371 (6)	O4—O5^viii	2.628 (6)
Na1—O5	2.459 (6)	O4—O8^viii	2.637 (8)
Na1—O5^iii	2.459 (6)	O4—O8	2.637 (8)
Na1—OW2	2.574 (18)	O4—O7	2.641 (8)
Na1—OW3	2.705 (18)	O4—O7^xiv	2.641 (8)
Na1—OW3^iii	2.705 (17)	O4—Na3^viii	3.026 (12)
Na1—O7	3.268 (10)	O4—OW4^viii	3.026 (12)
Na1—O2^iv	3.388 (9)	O5—O7	2.661 (8)
Na1—Si4^iii	3.394 (4)	O5—O8	2.693 (8)
Na1—Si4	3.394 (4)	O5—OW3	2.768 (19)
Na1—Si3	3.401 (4)	O5—O11	3.062 (8)
Na2—Na2^v	0.916 (16)	O5—O9	3.118 (9)
Na2—OW2^vi	2.229 (14)	O6—Si2^iv	1.572 (8)
Na2—O10^vi	2.419 (9)	O6—OW4^i	2.530 (10)
Na2—O3^vi	2.422 (12)	O6—Na3^i	2.530 (10)
Na2—O10^vii	2.543 (11)	O6—O8^iv	2.620 (8)
Na2—O11^vi	2.900 (11)	O6—O8^ix	2.620 (8)
Na2—O1^vi	3.102 (11)	O6—O9^iv	2.718 (12)
Na2—OW2^vii	3.104 (15)	O6—OW1^iv	2.917 (10)
Na2—Si4^vi	3.210 (9)	O6—O5^i	3.136 (8)
Na2—Na2^iii	3.214 (15)	O7—Si3^iii	1.629 (3)
Na2—Si1^vi	3.317 (8)	O7—O8	2.558 (6)
Na2—O1^vii	3.416 (12)	O7—O8^iii	2.558 (6)
Na3—OW3	1.357 (17)	O7—O4^xiv	2.641 (8)
Na3—OW1^iv	2.248 (9)	O7—O5^iii	2.661 (8)
Na3—OW4^viii	2.319 (18)	O7—OW3^vi	3.28 (2)
Na3—Na3^viii	2.319 (18)	O7—OW3^xii	3.28 (2)
Na3—OW3^iii	2.436 (18)	O7—O7^xiv	3.352 (17)
Na3—O6	2.530 (10)	O8—OW4^vi	2.601 (10)
Na3—O5	2.542 (10)	O8—Na3^vi	2.601 (10)
Na3—O8^iv	2.601 (10)	O8—O8^i	2.602 (11)
Na3—O4	3.026 (12)	O8—O9	2.606 (8)
Na3—Si2^iv	3.095 (9)	O8—O6^vi	2.620 (8)
Na3—OW3^viii	3.100 (19)	O8—OW3^vi	2.970 (19)
Na3—Si3	3.306 (9)	O9—O10	2.584 (11)
OW4—OW3	1.357 (17)	O9—O8^i	2.606 (8)
OW4—OW1^iv	2.248 (9)	O9—O1^i	2.670 (8)
OW4—OW4^viii	2.319 (18)	O9—O6^vi	2.718 (12)
OW4—Na3^viii	2.319 (18)	O9—O5^i	3.118 (9)
OW4—OW3^iii	2.436 (18)	O10—Na2^iv	2.419 (9)
OW4—O6	2.530 (10)	O10—Na2^ix	2.419 (9)
OW4—O5	2.542 (10)	O10—Na2^xi	2.543 (11)
OW4—O8^iv	2.601 (10)	O10—Na2^xv	2.543 (11)
OW4—O4	3.026 (12)	O10—O1^i	2.669 (10)
OW4—Si2^iv	3.095 (9)	O10—O11	3.168 (9)
OW4—OW3^viii	3.100 (19)	O10—O11^i	3.168 (9)
Si1—O10	1.607 (9)	O11—O2^iv	2.676 (8)
Si1—O1^i	1.623 (6)	O11—O1^iv	2.693 (10)
Si1—O1	1.623 (6)	O11—Na2^iv	2.900 (11)
Si1—O9	1.650 (8)	O11—OW2	3.111 (17)
Si1—Na2^iv	3.317 (8)	OW1—OW4^vi	2.248 (9)
Si1—Na2^ix	3.317 (8)	OW1—Na3^vi	2.248 (9)
Si2—O6^vi	1.572 (8)	OW1—OW4^xvi	2.248 (9)
Si2—O8^i	1.614 (5)	OW1—Na3^xvi	2.248 (9)
Si2—O8	1.614 (5)	OW1—OW4^xvii	2.248 (9)
Si2—O9	1.645 (8)	OW1—Na3^xvii	2.248 (9)
Si2—Na3^x	3.095 (9)	OW1—Na3^x	2.248 (9)
Si2—OW4^x	3.095 (9)	OW1—OW4^x	2.248 (9)
Si2—OW4^vi	3.095 (9)	OW1—O6^vi	2.917 (10)
Si2—Na3^vi	3.095 (9)	OW1—O6^xvi	2.917 (10)
Si3—O5	1.567 (5)	OW1—O4^xvi	3.05 (2)
Si3—O4	1.625 (3)	OW1—O4^vi	3.05 (2)
Si3—O7	1.629 (3)	OW2—Na2^xviii	2.229 (14)
Si3—O8	1.645 (6)	OW2—Na2^iv	2.229 (14)
Si4—O11	1.566 (6)	OW2—Na2^xix	3.104 (15)
Si4—O1^iv	1.613 (7)	OW2—Na2^xi	3.104 (15)
Si4—O2^iv	1.624 (3)	OW2—O11^iii	3.111 (17)
Si4—O3	1.644 (4)	OW2—O1^iii	3.263 (16)
Si4—Na2^iv	3.210 (9)	OW2—O10^v	3.386 (18)
O1—Si4^vi	1.613 (7)	OW3—OW3^iii	1.13 (3)
O1—O2	2.509 (6)	OW3—OW4^iii	2.436 (17)
O1—O3^vi	2.642 (9)	OW3—Na3^iii	2.436 (17)
O1—O1^i	2.659 (11)	OW3—O8^iv	2.970 (19)
O1—O10	2.669 (10)	OW3—Na3^viii	3.100 (19)
O1—O9	2.670 (8)	OW3—OW4^viii	3.100 (19)
O1—O11^vi	2.693 (10)	OW3—O7^iv	3.28 (2)
O1—Na2^iv	3.102 (11)
O6—La1—O11	85.3 (2)	O5—O4—O7^xiv	137.5 (3)
O6—La1—O11^i	85.3 (2)	O5^viii—O4—O7^xiv	60.7 (2)
O11—La1—O11^i	103.8 (3)	O8^viii—O4—O7^xiv	58.0 (2)
O6—La1—O5^i	82.99 (18)	O8—O4—O7^xiv	108.5 (3)
O11—La1—O5^i	167.5 (2)	O7—O4—O7^xiv	78.8 (4)
O11^i—La1—O5^i	79.36 (19)	Si3^viii—O4—OW4	129.4 (4)
O6—La1—O5	82.99 (18)	Si3—O4—OW4	84.9 (3)
O11—La1—O5	79.36 (18)	O5—O4—OW4	52.9 (2)
O11^i—La1—O5	167.5 (2)	O5^viii—O4—OW4	97.9 (3)
O5^i—La1—O5	95.1 (3)	O8^viii—O4—OW4	155.4 (3)
O6—La1—O10	155.9 (3)	O8—O4—OW4	113.4 (2)
O11—La1—O10	80.0 (2)	O7—O4—OW4	95.8 (3)
O11^i—La1—O10	79.97 (19)	O7^xiv—O4—OW4	126.0 (4)
O5^i—La1—O10	112.48 (17)	Si3^viii—O4—Na3	129.4 (4)
O5—La1—O10	112.48 (17)	Si3—O4—Na3	84.9 (3)
O6—La1—O9	145.7 (3)	O5—O4—Na3	52.9 (2)
O11—La1—O9	114.37 (18)	O5^viii—O4—Na3	97.9 (3)
O11^i—La1—O9	114.37 (18)	O8^viii—O4—Na3	155.4 (3)
O5^i—La1—O9	74.13 (17)	O8—O4—Na3	113.4 (2)
O5—La1—O9	74.13 (17)	O7—O4—Na3	95.8 (3)
O10—La1—O9	58.4 (2)	O7^xiv—O4—Na3	126.0 (4)
O6—La1—Si1	175.7 (2)	OW4—O4—Na3	0.0 (3)
O11—La1—Si1	97.38 (17)	Si3^viii—O4—Na3^viii	84.9 (3)
O11^i—La1—Si1	97.38 (17)	Si3—O4—Na3^viii	129.4 (4)
O5^i—La1—Si1	94.10 (13)	O5—O4—Na3^viii	97.9 (3)
O5—La1—Si1	94.10 (13)	O5^viii—O4—Na3^viii	52.9 (2)
O10—La1—Si1	28.41 (19)	O8^viii—O4—Na3^viii	113.4 (2)
O9—La1—Si1	29.97 (16)	O8—O4—Na3^viii	155.4 (3)
O6—La1—Na1^ii	86.43 (7)	O7—O4—Na3^viii	126.0 (4)
O11—La1—Na1^ii	142.23 (16)	O7^xiv—O4—Na3^viii	95.8 (3)
O11^i—La1—Na1^ii	38.70 (15)	OW4—O4—Na3^viii	45.1 (4)
O5^i—La1—Na1^ii	41.00 (14)	Na3—O4—Na3^viii	45.1 (4)
O5—La1—Na1^ii	135.84 (14)	Si3^viii—O4—OW4^viii	84.9 (3)
O10—La1—Na1^ii	93.65 (6)	Si3—O4—OW4^viii	129.4 (4)
O9—La1—Na1^ii	92.41 (8)	O5—O4—OW4^viii	97.9 (3)
Si1—La1—Na1^ii	93.49 (7)	O5^viii—O4—OW4^viii	52.9 (2)
O6—La1—Na1	86.43 (7)	O8^viii—O4—OW4^viii	113.4 (2)
O11—La1—Na1	38.70 (15)	O8—O4—OW4^viii	155.4 (3)
O11^i—La1—Na1	142.23 (16)	O7—O4—OW4^viii	126.0 (4)
O5^i—La1—Na1	135.84 (14)	O7^xiv—O4—OW4^viii	95.8 (3)
O5—La1—Na1	41.00 (14)	OW4—O4—OW4^viii	45.1 (4)
O10—La1—Na1	93.65 (6)	Na3—O4—OW4^viii	45.1 (4)
O9—La1—Na1	92.41 (8)	Na3^viii—O4—OW4^viii	0.0 (4)
Si1—La1—Na1	93.49 (7)	Si3—O5—La1	139.7 (3)
Na1^ii—La1—Na1	172.61 (13)	Si3—O5—Eu1	139.7 (3)
O6—La1—OW4^i	41.13 (18)	La1—O5—Eu1	0.0
O11—La1—OW4^i	126.4 (2)	Si3—O5—Na1	113.5 (3)
O11^i—La1—OW4^i	78.79 (19)	La1—O5—Na1	98.8 (2)
O5^i—La1—OW4^i	41.87 (18)	Eu1—O5—Na1	98.8 (2)
O5—La1—OW4^i	89.61 (19)	Si3—O5—Na3	104.7 (3)
O10—La1—OW4^i	149.54 (13)	La1—O5—Na3	98.7 (3)
O9—La1—OW4^i	112.41 (19)	Eu1—O5—Na3	98.7 (3)
Si1—La1—OW4^i	135.94 (14)	Na1—O5—Na3	89.8 (3)
Na1^ii—La1—OW4^i	56.42 (14)	Si3—O5—OW4	104.7 (3)
Na1—La1—OW4^i	116.43 (14)	La1—O5—OW4	98.7 (3)
O6—La1—Na3^i	41.13 (18)	Eu1—O5—OW4	98.7 (3)
O11—La1—Na3^i	126.4 (2)	Na1—O5—OW4	89.8 (3)
O11^i—La1—Na3^i	78.79 (19)	Na3—O5—OW4	0.0 (3)
O5^i—La1—Na3^i	41.87 (18)	Si3—O5—O4	35.3 (2)
O5—La1—Na3^i	89.61 (19)	La1—O5—O4	134.5 (3)
O10—La1—Na3^i	149.54 (13)	Eu1—O5—O4	134.5 (3)
O9—La1—Na3^i	112.41 (19)	Na1—O5—O4	124.7 (3)
Si1—La1—Na3^i	135.94 (14)	Na3—O5—O4	71.6 (3)
Na1^ii—La1—Na3^i	56.42 (14)	OW4—O5—O4	71.6 (3)
Na1—La1—Na3^i	116.43 (14)	Si3—O5—O7	34.34 (19)
OW4^i—La1—Na3^i	0.0 (2)	La1—O5—O7	153.0 (3)
O6—Eu1—O11	85.3 (2)	Eu1—O5—O7	153.0 (3)
O6—Eu1—O11^i	85.3 (2)	Na1—O5—O7	79.2 (2)
O11—Eu1—O11^i	103.8 (3)	Na3—O5—O7	108.2 (3)
O6—Eu1—O5^i	82.99 (18)	OW4—O5—O7	108.2 (3)
O11—Eu1—O5^i	167.5 (2)	O4—O5—O7	59.9 (3)
O11^i—Eu1—O5^i	79.36 (19)	Si3—O5—O8	33.92 (17)
O6—Eu1—O5	82.99 (18)	La1—O5—O8	106.9 (2)
O11—Eu1—O5	79.36 (18)	Eu1—O5—O8	106.9 (2)
O11^i—Eu1—O5	167.5 (2)	Na1—O5—O8	126.6 (3)
O5^i—Eu1—O5	95.1 (3)	Na3—O5—O8	129.7 (3)
O6—Eu1—O10	155.9 (3)	OW4—O5—O8	129.7 (3)
O11—Eu1—O10	80.0 (2)	O4—O5—O8	59.4 (2)
O11^i—Eu1—O10	79.97 (19)	O7—O5—O8	57.1 (2)
O5^i—Eu1—O10	112.48 (17)	Si3—O5—OW3	106.2 (5)
O5—Eu1—O10	112.48 (17)	La1—O5—OW3	110.1 (4)
O6—Eu1—O9	145.7 (3)	Eu1—O5—OW3	110.1 (4)
O11—Eu1—O9	114.37 (18)	Na1—O5—OW3	62.0 (4)
O11^i—Eu1—O9	114.37 (18)	Na3—O5—OW3	29.2 (4)
O5^i—Eu1—O9	74.13 (17)	OW4—O5—OW3	29.2 (4)
O5—Eu1—O9	74.13 (17)	O4—O5—OW3	83.2 (4)
O10—Eu1—O9	58.4 (2)	O7—O5—OW3	92.9 (4)
O6—Eu1—Si1	175.7 (2)	O8—O5—OW3	139.8 (4)
O11—Eu1—Si1	97.38 (17)	Si3—O5—O11	156.8 (3)
O11^i—Eu1—Si1	97.38 (17)	La1—O5—O11	49.74 (14)
O5^i—Eu1—Si1	94.10 (13)	Eu1—O5—O11	49.74 (14)
O5—Eu1—Si1	94.10 (13)	Na1—O5—O11	49.41 (16)
O10—Eu1—Si1	28.41 (19)	Na3—O5—O11	91.9 (3)
O9—Eu1—Si1	29.97 (16)	OW4—O5—O11	91.9 (3)
O6—Eu1—Na1^ii	86.43 (7)	O4—O5—O11	163.1 (3)
O11—Eu1—Na1^ii	142.23 (16)	O7—O5—O11	125.0 (3)
O11^i—Eu1—Na1^ii	38.70 (15)	O8—O5—O11	137.5 (3)
O5^i—Eu1—Na1^ii	41.00 (14)	OW3—O5—O11	80.4 (4)
O5—Eu1—Na1^ii	135.84 (14)	Si3—O5—O9	86.3 (3)
O10—Eu1—Na1^ii	93.65 (6)	La1—O5—O9	57.65 (18)
O9—Eu1—Na1^ii	92.41 (8)	Eu1—O5—O9	57.65 (18)
Si1—Eu1—Na1^ii	93.49 (7)	Na1—O5—O9	114.3 (2)
O6—Eu1—Na1	86.43 (7)	Na3—O5—O9	147.3 (3)
O11—Eu1—Na1	38.70 (15)	OW4—O5—O9	147.3 (3)
O11^i—Eu1—Na1	142.23 (16)	O4—O5—O9	107.5 (3)
O5^i—Eu1—Na1	135.84 (14)	O7—O5—O9	98.3 (2)
O5—Eu1—Na1	41.00 (14)	O8—O5—O9	52.7 (2)
O10—Eu1—Na1	93.65 (6)	OW3—O5—O9	167.4 (4)
O9—Eu1—Na1	92.41 (8)	O11—O5—O9	88.3 (2)
Si1—Eu1—Na1	93.49 (7)	Si2^iv—O6—La1	154.4 (5)
Na1^ii—Eu1—Na1	172.61 (13)	Si2^iv—O6—Eu1	154.4 (5)
O6—Eu1—OW4^i	41.13 (18)	La1—O6—Eu1	0.00 (2)
O11—Eu1—OW4^i	126.4 (2)	Si2^iv—O6—OW4^i	95.1 (3)
O11^i—Eu1—OW4^i	78.79 (19)	La1—O6—OW4^i	101.9 (3)
O5^i—Eu1—OW4^i	41.87 (18)	Eu1—O6—OW4^i	101.9 (3)
O5—Eu1—OW4^i	89.61 (19)	Si2^iv—O6—Na3^i	95.1 (3)
O10—Eu1—OW4^i	149.54 (13)	La1—O6—Na3^i	101.9 (3)
O9—Eu1—OW4^i	112.41 (19)	Eu1—O6—Na3^i	101.9 (3)
Si1—Eu1—OW4^i	135.94 (14)	OW4^i—O6—Na3^i	0.0 (5)
Na1^ii—Eu1—OW4^i	56.42 (14)	Si2^iv—O6—Na3	95.1 (3)
Na1—Eu1—OW4^i	116.43 (14)	La1—O6—Na3	101.9 (3)
O6—Eu1—Na3^i	41.13 (18)	Eu1—O6—Na3	101.9 (3)
O11—Eu1—Na3^i	126.4 (2)	OW4^i—O6—Na3	96.2 (5)
O11^i—Eu1—Na3^i	78.79 (19)	Na3^i—O6—Na3	96.2 (5)
O5^i—Eu1—Na3^i	41.87 (18)	Si2^iv—O6—OW4	95.1 (3)
O5—Eu1—Na3^i	89.61 (19)	La1—O6—OW4	101.9 (3)
O10—Eu1—Na3^i	149.54 (13)	Eu1—O6—OW4	101.9 (3)
O9—Eu1—Na3^i	112.41 (19)	OW4^i—O6—OW4	96.2 (5)
Si1—Eu1—Na3^i	135.94 (14)	Na3^i—O6—OW4	96.2 (5)
Na1^ii—Eu1—Na3^i	56.42 (14)	Na3—O6—OW4	0.0 (3)
Na1—Eu1—Na3^i	116.43 (14)	Si2^iv—O6—O8^iv	35.19 (17)
OW4^i—Eu1—Na3^i	0.0 (2)	La1—O6—O8^iv	149.70 (16)
O11^iii—Na1—O11	100.6 (3)	Eu1—O6—O8^iv	149.70 (16)
O11^iii—Na1—O5	179.0 (3)	OW4^i—O6—O8^iv	104.4 (3)
O11—Na1—O5	78.65 (18)	Na3^i—O6—O8^iv	104.4 (3)
O11^iii—Na1—O5^iii	78.65 (18)	Na3—O6—O8^iv	60.6 (3)
O11—Na1—O5^iii	179.0 (3)	OW4—O6—O8^iv	60.6 (3)
O5—Na1—O5^iii	102.1 (3)	Si2^iv—O6—O8^ix	35.19 (17)
O11^iii—Na1—OW2	77.8 (3)	La1—O6—O8^ix	149.70 (16)
O11—Na1—OW2	77.8 (3)	Eu1—O6—O8^ix	149.70 (16)
O5—Na1—OW2	102.6 (3)	OW4^i—O6—O8^ix	60.6 (3)
O5^iii—Na1—OW2	102.6 (3)	Na3^i—O6—O8^ix	60.6 (3)
O11^iii—Na1—OW3	114.9 (4)	Na3—O6—O8^ix	104.4 (3)
O11—Na1—OW3	95.7 (4)	OW4—O6—O8^ix	104.4 (3)
O5—Na1—OW3	64.6 (4)	O8^iv—O6—O8^ix	59.5 (3)
O5^iii—Na1—OW3	84.0 (4)	Si2^iv—O6—O9^iv	33.2 (3)
OW2—Na1—OW3	166.9 (4)	La1—O6—O9^iv	121.2 (3)
O11^iii—Na1—OW3^iii	95.7 (4)	Eu1—O6—O9^iv	121.2 (3)
O11—Na1—OW3^iii	114.9 (4)	OW4^i—O6—O9^iv	115.9 (3)
O5—Na1—OW3^iii	84.0 (4)	Na3^i—O6—O9^iv	115.9 (3)
O5^iii—Na1—OW3^iii	64.6 (4)	Na3—O6—O9^iv	115.9 (3)
OW2—Na1—OW3^iii	166.9 (4)	OW4—O6—O9^iv	115.9 (3)
OW3—Na1—OW3^iii	24.1 (7)	O8^iv—O6—O9^iv	58.4 (2)
O11^iii—Na1—O7	127.84 (17)	O8^ix—O6—O9^iv	58.4 (2)
O11—Na1—O7	127.84 (17)	Si2^iv—O6—OW1^iv	99.5 (6)
O5—Na1—O7	53.13 (14)	La1—O6—OW1^iv	106.0 (5)
O5^iii—Na1—O7	53.13 (14)	Eu1—O6—OW1^iv	106.0 (5)
OW2—Na1—O7	93.0 (5)	OW4^i—O6—OW1^iv	48.1 (2)
OW3—Na1—O7	81.8 (4)	Na3^i—O6—OW1^iv	48.1 (2)
OW3^iii—Na1—O7	81.8 (4)	Na3—O6—OW1^iv	48.1 (2)
O11^iii—Na1—O2^iv	51.79 (16)	OW4—O6—OW1^iv	48.1 (2)
O11—Na1—O2^iv	51.79 (16)	O8^iv—O6—OW1^iv	81.2 (4)
O5—Na1—O2^iv	127.26 (15)	O8^ix—O6—OW1^iv	81.2 (4)
O5^iii—Na1—O2^iv	127.26 (15)	O9^iv—O6—OW1^iv	132.7 (5)
OW2—Na1—O2^iv	85.2 (4)	Si2^iv—O6—O5^i	143.32 (18)
OW3—Na1—O2^iv	99.9 (4)	La1—O6—O5^i	49.90 (16)
OW3^iii—Na1—O2^iv	99.9 (4)	Eu1—O6—O5^i	49.90 (16)
O7—Na1—O2^iv	178.3 (2)	OW4^i—O6—O5^i	52.0 (2)
O11^iii—Na1—Si4^iii	24.12 (15)	Na3^i—O6—O5^i	52.0 (2)
O11—Na1—Si4^iii	77.33 (18)	Na3—O6—O5^i	103.3 (3)
O5—Na1—Si4^iii	154.94 (17)	OW4—O6—O5^i	103.3 (3)
O5^iii—Na1—Si4^iii	101.82 (13)	O8^iv—O6—O5^i	152.1 (3)
OW2—Na1—Si4^iii	79.2 (4)	O8^ix—O6—O5^i	108.63 (19)
OW3—Na1—Si4^iii	110.9 (4)	O9^iv—O6—O5^i	140.50 (19)
OW3^iii—Na1—Si4^iii	99.7 (4)	OW1^iv—O6—O5^i	71.7 (4)
O7—Na1—Si4^iii	151.81 (8)	Si3^iii—O7—Si3	143.2 (5)
O2^iv—Na1—Si4^iii	27.71 (6)	Si3^iii—O7—O8	175.8 (5)
O11^iii—Na1—Si4	77.33 (18)	Si3—O7—O8	38.84 (18)
O11—Na1—Si4	24.12 (15)	Si3^iii—O7—O8^iii	38.84 (18)
O5—Na1—Si4	101.82 (13)	Si3—O7—O8^iii	175.8 (5)
O5^iii—Na1—Si4	154.94 (17)	O8—O7—O8^iii	138.8 (4)
OW2—Na1—Si4	79.2 (4)	Si3^iii—O7—O4	118.5 (4)
OW3—Na1—Si4	99.7 (4)	Si3—O7—O4	35.7 (2)
OW3^iii—Na1—Si4	110.9 (4)	O8—O7—O4	60.9 (2)
O7—Na1—Si4	151.81 (8)	O8^iii—O7—O4	141.8 (4)
O2^iv—Na1—Si4	27.71 (6)	Si3^iii—O7—O4^xiv	35.7 (2)
Si4^iii—Na1—Si4	53.58 (9)	Si3—O7—O4^xiv	118.5 (4)
O11^iii—Na1—Si3	155.96 (19)	O8—O7—O4^xiv	141.8 (4)
O11—Na1—Si3	102.38 (15)	O8^iii—O7—O4^xiv	60.9 (2)
O5—Na1—Si3	24.99 (13)	O4—O7—O4^xiv	85.6 (4)
O5^iii—Na1—Si3	78.48 (16)	Si3^iii—O7—O5^iii	32.9 (2)
OW2—Na1—Si3	100.1 (4)	Si3—O7—O5^iii	121.6 (4)
OW3—Na1—Si3	69.8 (4)	O8—O7—O5^iii	151.3 (4)
OW3^iii—Na1—Si3	81.1 (4)	O8^iii—O7—O5^iii	62.09 (18)
O7—Na1—Si3	28.18 (6)	O4—O7—O5^iii	117.9 (4)
O2^iv—Na1—Si3	152.25 (7)	O4^xiv—O7—O5^iii	59.41 (19)
Si4^iii—Na1—Si3	179.25 (14)	Si3^iii—O7—O5	121.6 (4)
Si4—Na1—Si3	126.19 (4)	Si3—O7—O5	32.9 (2)
Na2^v—Na2—OW2^vi	159.4 (11)	O8—O7—O5	62.09 (18)
Na2^v—Na2—O10^vi	87.1 (10)	O8^iii—O7—O5	151.3 (4)
OW2^vi—Na2—O10^vi	105.8 (5)	O4—O7—O5	59.41 (19)
Na2^v—Na2—O3^vi	79.1 (2)	O4^xiv—O7—O5	117.9 (4)
OW2^vi—Na2—O3^vi	113.5 (6)	O5^iii—O7—O5	91.9 (3)
O10^vi—Na2—O3^vi	99.4 (4)	Si3^iii—O7—Na1	80.5 (3)
Na2^v—Na2—O10^vii	71.8 (10)	Si3—O7—Na1	80.5 (3)
OW2^vi—Na2—O10^vii	90.1 (5)	O8—O7—Na1	103.7 (2)
O10^vi—Na2—O10^vii	150.9 (4)	O8^iii—O7—Na1	103.7 (2)
O3^vi—Na2—O10^vii	96.1 (3)	O4—O7—Na1	98.8 (3)
Na2^v—Na2—O11^vi	126.6 (7)	O4^xiv—O7—Na1	98.8 (3)
OW2^vi—Na2—O11^vi	73.4 (5)	O5^iii—O7—Na1	47.65 (17)
O10^vi—Na2—O11^vi	72.5 (3)	O5—O7—Na1	47.65 (17)
O3^vi—Na2—O11^vi	57.6 (2)	Si3^iii—O7—OW3^vi	117.5 (4)
O10^vii—Na2—O11^vi	136.3 (3)	Si3—O7—OW3^vi	97.8 (4)
Na2^v—Na2—O1^vi	102.3 (5)	O8—O7—OW3^vi	59.6 (3)
OW2^vi—Na2—O1^vi	73.4 (5)	O8^iii—O7—OW3^vi	79.4 (3)
O10^vi—Na2—O1^vi	56.2 (3)	O4—O7—OW3^vi	104.2 (4)
O3^vi—Na2—O1^vi	155.1 (4)	O4^xiv—O7—OW3^vi	118.7 (4)
O10^vii—Na2—O1^vi	108.0 (4)	O5^iii—O7—OW3^vi	136.9 (4)
O11^vi—Na2—O1^vi	105.4 (3)	O5—O7—OW3^vi	118.9 (3)
Na2^v—Na2—OW2^vii	14.6 (8)	Na1—O7—OW3^vi	136.9 (4)
OW2^vi—Na2—OW2^vii	157.2 (9)	Si3^iii—O7—OW3^xii	97.8 (4)
O10^vi—Na2—OW2^vii	74.5 (3)	Si3—O7—OW3^xii	117.5 (4)
O3^vi—Na2—OW2^vii	88.6 (4)	O8—O7—OW3^xii	79.4 (3)
O10^vii—Na2—OW2^vii	81.5 (3)	O8^iii—O7—OW3^xii	59.6 (3)
O11^vi—Na2—OW2^vii	126.6 (4)	O4—O7—OW3^xii	118.7 (4)
O1^vi—Na2—OW2^vii	89.0 (4)	O4^xiv—O7—OW3^xii	104.2 (4)
Na2^v—Na2—Si4^vi	107.6 (2)	O5^iii—O7—OW3^xii	118.9 (3)
OW2^vi—Na2—Si4^vi	88.4 (6)	O5—O7—OW3^xii	136.9 (4)
O10^vi—Na2—Si4^vi	91.5 (3)	Na1—O7—OW3^xii	136.9 (4)
O3^vi—Na2—Si4^vi	30.00 (12)	OW3^vi—O7—OW3^xii	19.8 (5)
O10^vii—Na2—Si4^vi	113.6 (3)	Si3^iii—O7—O7^xiv	85.0 (3)
O11^vi—Na2—Si4^vi	29.14 (15)	Si3—O7—O7^xiv	85.0 (3)
O1^vi—Na2—Si4^vi	134.4 (3)	O8—O7—O7^xiv	91.9 (2)
OW2^vii—Na2—Si4^vi	114.4 (4)	O8^iii—O7—O7^xiv	91.9 (2)
Na2^v—Na2—Na2^iii	121.7 (11)	O4—O7—O7^xiv	50.61 (19)
OW2^vi—Na2—Na2^iii	43.9 (4)	O4^xiv—O7—O7^xiv	50.61 (19)
O10^vi—Na2—Na2^iii	149.7 (2)	O5^iii—O7—O7^xiv	108.9 (2)
O3^vi—Na2—Na2^iii	95.70 (18)	O5—O7—O7^xiv	108.9 (2)
O10^vii—Na2—Na2^iii	50.8 (2)	Na1—O7—O7^xiv	132.21 (16)
O11^vi—Na2—Na2^iii	94.29 (18)	OW3^vi—O7—O7^xiv	90.0 (3)
O1^vi—Na2—Na2^iii	104.16 (18)	OW3^xii—O7—O7^xiv	90.0 (3)
OW2^vii—Na2—Na2^iii	132.3 (3)	Si2—O8—Si3	137.1 (4)
Si4^vi—Na2—Na2^iii	88.62 (14)	Si2—O8—O7	150.8 (4)
Na2^v—Na2—Si1^vi	96.1 (9)	Si3—O8—O7	38.4 (2)
OW2^vi—Na2—Si1^vi	89.2 (4)	Si2—O8—OW4^vi	91.4 (3)
O10^vi—Na2—Si1^vi	27.2 (2)	Si3—O8—OW4^vi	130.8 (3)
O3^vi—Na2—Si1^vi	126.3 (3)	O7—O8—OW4^vi	96.6 (3)
O10^vii—Na2—Si1^vi	133.6 (4)	Si2—O8—Na3^vi	91.4 (3)
O11^vi—Na2—Si1^vi	87.3 (3)	Si3—O8—Na3^vi	130.8 (3)
O1^vi—Na2—Si1^vi	29.03 (13)	O7—O8—Na3^vi	96.6 (3)
OW2^vii—Na2—Si1^vi	81.6 (3)	OW4^vi—O8—Na3^vi	0.0 (4)
Si4^vi—Na2—Si1^vi	112.8 (3)	Si2—O8—O8^i	36.3 (2)
Na2^iii—Na2—Si1^vi	129.01 (14)	Si3—O8—O8^i	121.1 (2)
Na2^v—Na2—O1^vii	62.5 (5)	O7—O8—O8^i	159.4 (2)
OW2^vi—Na2—O1^vii	98.6 (6)	OW4^vi—O8—O8^i	102.9 (2)
O10^vi—Na2—O1^vii	102.1 (3)	Na3^vi—O8—O8^i	102.9 (2)
O3^vi—Na2—O1^vii	134.4 (3)	Si2—O8—O9	37.3 (2)
O10^vii—Na2—O1^vii	50.7 (3)	Si3—O8—O9	103.9 (3)
O11^vi—Na2—O1^vii	168.0 (3)	O7—O8—O9	116.1 (3)
O1^vi—Na2—O1^vii	63.2 (3)	OW4^vi—O8—O9	117.4 (3)
OW2^vii—Na2—O1^vii	59.8 (4)	Na3^vi—O8—O9	117.4 (3)
Si4^vi—Na2—O1^vii	162.4 (3)	O8^i—O8—O9	60.05 (14)
Na2^iii—Na2—O1^vii	85.34 (16)	Si2—O8—O6^vi	34.2 (2)
Si1^vi—Na2—O1^vii	83.6 (2)	Si3—O8—O6^vi	164.7 (3)
OW3—Na3—OW1^iv	169.5 (10)	O7—O8—O6^vi	138.5 (3)
OW3—Na3—OW4^viii	112.3 (8)	OW4^vi—O8—O6^vi	58.0 (3)
OW1^iv—Na3—OW4^viii	59.0 (2)	Na3^vi—O8—O6^vi	58.0 (3)
OW3—Na3—Na3^viii	112.3 (8)	O8^i—O8—O6^vi	60.23 (15)
OW1^iv—Na3—Na3^viii	59.0 (2)	O9—O8—O6^vi	62.7 (3)
OW4^viii—Na3—Na3^viii	0.0 (6)	Si2—O8—O4	137.2 (4)
OW3—Na3—OW3^iii	10.4 (4)	Si3—O8—O4	36.0 (2)
OW1^iv—Na3—OW3^iii	159.4 (6)	O7—O8—O4	61.1 (3)
OW4^viii—Na3—OW3^iii	102.2 (4)	OW4^vi—O8—O4	117.8 (3)
Na3^viii—Na3—OW3^iii	102.2 (4)	Na3^vi—O8—O4	117.8 (3)
OW3—Na3—O6	115.1 (9)	O8^i—O8—O4	103.2 (2)
OW1^iv—Na3—O6	75.0 (3)	O9—O8—O4	124.6 (3)
OW4^viii—Na3—O6	130.2 (2)	O6^vi—O8—O4	157.5 (3)
Na3^viii—Na3—O6	130.2 (2)	Si2—O8—O5	105.5 (3)
OW3^iii—Na3—O6	125.5 (6)	Si3—O8—O5	32.11 (17)
OW3—Na3—O5	84.7 (9)	O7—O8—O5	60.8 (2)
OW1^iv—Na3—O5	95.5 (6)	OW4^vi—O8—O5	156.5 (3)
OW4^viii—Na3—O5	122.9 (2)	Na3^vi—O8—O5	156.5 (3)
Na3^viii—Na3—O5	122.9 (2)	O8^i—O8—O5	100.31 (16)
OW3^iii—Na3—O5	88.1 (5)	O9—O8—O5	72.1 (2)
O6—Na3—O5	76.4 (3)	O6^vi—O8—O5	134.6 (3)
OW3—Na3—O8^iv	91.7 (9)	O4—O8—O5	59.1 (2)
OW1^iv—Na3—O8^iv	96.0 (6)	Si2—O8—OW3^vi	106.5 (5)
OW4^viii—Na3—O8^iv	103.4 (2)	Si3—O8—OW3^vi	110.0 (4)
Na3^viii—Na3—O8^iv	103.4 (2)	O7—O8—OW3^vi	72.4 (4)
OW3^iii—Na3—O8^iv	96.9 (5)	OW4^vi—O8—OW3^vi	27.2 (4)
O6—Na3—O8^iv	61.4 (3)	Na3^vi—O8—OW3^vi	27.2 (4)
O5—Na3—O8^iv	131.3 (4)	O8^i—O8—OW3^vi	128.0 (4)
OW3—Na3—O4	103.0 (9)	O9—O8—OW3^vi	117.3 (4)
OW1^iv—Na3—O4	68.9 (6)	O6^vi—O8—OW3^vi	73.1 (4)
OW4^viii—Na3—O4	67.47 (18)	O4—O8—OW3^vi	113.5 (4)
Na3^viii—Na3—O4	67.47 (18)	O5—O8—OW3^vi	129.6 (4)
OW3^iii—Na3—O4	97.0 (5)	Si2—O9—Si1	141.9 (6)
O6—Na3—O4	114.3 (4)	Si2—O9—O10	178.9 (5)
O5—Na3—O4	55.5 (2)	Si1—O9—O10	36.9 (3)
O8^iv—Na3—O4	164.7 (4)	Si2—O9—O8^i	36.49 (18)
OW3—Na3—Si2^iv	108.9 (9)	Si1—O9—O8^i	146.3 (3)
OW1^iv—Na3—Si2^iv	81.2 (5)	O10—O9—O8^i	144.1 (3)
OW4^viii—Na3—Si2^iv	117.59 (17)	Si2—O9—O8	36.49 (18)
Na3^viii—Na3—Si2^iv	117.59 (17)	Si1—O9—O8	146.3 (3)
OW3^iii—Na3—Si2^iv	117.5 (5)	O10—O9—O8	144.1 (3)
O6—Na3—Si2^iv	30.4 (2)	O8^i—O9—O8	59.9 (3)
O5—Na3—Si2^iv	105.4 (3)	Si2—O9—O1	118.0 (4)
O8^iv—Na3—Si2^iv	31.41 (16)	Si1—O9—O1	34.98 (18)
O4—Na3—Si2^iv	141.0 (3)	O10—O9—O1	61.0 (3)
OW3—Na3—OW3^viii	88.4 (10)	O8^i—O9—O1	149.5 (4)
OW1^iv—Na3—OW3^viii	82.7 (4)	O8—O9—O1	111.4 (2)
OW4^viii—Na3—OW3^viii	23.9 (3)	Si2—O9—O1^i	118.0 (4)
Na3^viii—Na3—OW3^viii	23.9 (3)	Si1—O9—O1^i	34.98 (18)
OW3^iii—Na3—OW3^viii	78.4 (6)	O10—O9—O1^i	61.0 (3)
O6—Na3—OW3^viii	152.0 (5)	O8^i—O9—O1^i	111.4 (2)
O5—Na3—OW3^viii	123.1 (5)	O8—O9—O1^i	149.5 (4)
O8^iv—Na3—OW3^viii	105.2 (5)	O1—O9—O1^i	59.7 (3)
O4—Na3—OW3^viii	71.6 (4)	Si2—O9—O6^vi	31.5 (3)
Si2^iv—Na3—OW3^viii	130.0 (5)	Si1—O9—O6^vi	110.4 (4)
OW3—Na3—Si3	88.5 (9)	O10—O9—O6^vi	147.3 (4)
OW1^iv—Na3—Si3	86.9 (6)	O8^i—O9—O6^vi	58.9 (2)
OW4^viii—Na3—Si3	96.49 (16)	O8—O9—O6^vi	58.9 (2)
Na3^viii—Na3—Si3	96.49 (16)	O1—O9—O6^vi	91.1 (3)
OW3^iii—Na3—Si3	87.0 (5)	O1^i—O9—O6^vi	91.1 (3)
O6—Na3—Si3	99.1 (3)	Si2—O9—La1	124.0 (4)
O5—Na3—Si3	27.28 (15)	Si1—O9—La1	94.0 (4)
O8^iv—Na3—Si3	158.4 (4)	O10—O9—La1	57.1 (3)
O4—Na3—Si3	29.32 (11)	O8^i—O9—La1	100.5 (3)
Si2^iv—Na3—Si3	129.5 (3)	O8—O9—La1	100.5 (3)
OW3^viii—Na3—Si3	96.4 (4)	O1—O9—La1	110.0 (3)
OW3—OW4—OW1^iv	169.5 (10)	O1^i—O9—La1	110.0 (3)
OW3—OW4—OW4^viii	112.3 (8)	O6^vi—O9—La1	155.5 (3)
OW1^iv—OW4—OW4^viii	59.0 (2)	Si2—O9—Eu1	124.0 (4)
OW3—OW4—Na3^viii	112.3 (8)	Si1—O9—Eu1	94.0 (4)
OW1^iv—OW4—Na3^viii	59.0 (2)	O10—O9—Eu1	57.1 (3)
OW4^viii—OW4—Na3^viii	0.0 (6)	O8^i—O9—Eu1	100.5 (3)
OW3—OW4—OW3^iii	10.4 (4)	O8—O9—Eu1	100.5 (3)
OW1^iv—OW4—OW3^iii	159.4 (6)	O1—O9—Eu1	110.0 (3)
OW4^viii—OW4—OW3^iii	102.2 (4)	O1^i—O9—Eu1	110.0 (3)
Na3^viii—OW4—OW3^iii	102.2 (4)	O6^vi—O9—Eu1	155.5 (3)
OW3—OW4—O6	115.1 (9)	La1—O9—Eu1	0.000 (1)
OW1^iv—OW4—O6	75.0 (3)	Si2—O9—O5	88.6 (3)
OW4^viii—OW4—O6	130.2 (2)	Si1—O9—O5	121.6 (3)
Na3^viii—OW4—O6	130.2 (2)	O10—O9—O5	92.3 (3)
OW3^iii—OW4—O6	125.5 (6)	O8^i—O9—O5	90.1 (3)
OW3—OW4—O5	84.7 (9)	O8—O9—O5	55.27 (19)
OW1^iv—OW4—O5	95.5 (6)	O1—O9—O5	108.9 (2)
OW4^viii—OW4—O5	122.9 (2)	O1^i—O9—O5	153.3 (4)
Na3^viii—OW4—O5	122.9 (2)	O6^vi—O9—O5	114.1 (3)
OW3^iii—OW4—O5	88.1 (5)	La1—O9—O5	48.23 (16)
O6—OW4—O5	76.4 (3)	Eu1—O9—O5	48.23 (16)
OW3—OW4—O8^iv	91.7 (9)	Si2—O9—O5^i	88.6 (3)
OW1^iv—OW4—O8^iv	96.0 (6)	Si1—O9—O5^i	121.6 (3)
OW4^viii—OW4—O8^iv	103.4 (2)	O10—O9—O5^i	92.3 (3)
Na3^viii—OW4—O8^iv	103.4 (2)	O8^i—O9—O5^i	55.27 (19)
OW3^iii—OW4—O8^iv	96.9 (5)	O8—O9—O5^i	90.1 (3)
O6—OW4—O8^iv	61.4 (3)	O1—O9—O5^i	153.3 (4)
O5—OW4—O8^iv	131.3 (4)	O1^i—O9—O5^i	108.9 (2)
OW3—OW4—O4	103.0 (9)	O6^vi—O9—O5^i	114.1 (3)
OW1^iv—OW4—O4	68.9 (6)	La1—O9—O5^i	48.23 (16)
OW4^viii—OW4—O4	67.47 (18)	Eu1—O9—O5^i	48.23 (16)
Na3^viii—OW4—O4	67.47 (18)	O5—O9—O5^i	69.8 (3)
OW3^iii—OW4—O4	97.0 (5)	Si1—O10—Na2^iv	109.3 (3)
O6—OW4—O4	114.3 (4)	Si1—O10—Na2^ix	109.3 (3)
O5—OW4—O4	55.5 (2)	Na2^iv—O10—Na2^ix	119.4 (5)
O8^iv—OW4—O4	164.7 (4)	Si1—O10—Na2^xi	114.9 (4)
OW3—OW4—Si2^iv	108.9 (9)	Na2^iv—O10—Na2^xi	21.1 (4)
OW1^iv—OW4—Si2^iv	81.2 (5)	Na2^ix—O10—Na2^xi	99.1 (3)
OW4^viii—OW4—Si2^iv	117.59 (17)	Si1—O10—Na2^xv	114.9 (4)
Na3^viii—OW4—Si2^iv	117.59 (17)	Na2^iv—O10—Na2^xv	99.1 (3)
OW3^iii—OW4—Si2^iv	117.5 (5)	Na2^ix—O10—Na2^xv	21.1 (4)
O6—OW4—Si2^iv	30.4 (2)	Na2^xi—O10—Na2^xv	78.4 (4)
O5—OW4—Si2^iv	105.4 (3)	Si1—O10—La1	102.6 (4)
O8^iv—OW4—Si2^iv	31.41 (16)	Na2^iv—O10—La1	107.5 (3)
O4—OW4—Si2^iv	141.0 (3)	Na2^ix—O10—La1	107.5 (3)
OW3—OW4—OW3^viii	88.4 (10)	Na2^xi—O10—La1	122.9 (3)
OW1^iv—OW4—OW3^viii	82.7 (4)	Na2^xv—O10—La1	122.9 (3)
OW4^viii—OW4—OW3^viii	23.9 (3)	Si1—O10—Eu1	102.6 (4)
Na3^viii—OW4—OW3^viii	23.9 (3)	Na2^iv—O10—Eu1	107.5 (3)
OW3^iii—OW4—OW3^viii	78.4 (6)	Na2^ix—O10—Eu1	107.5 (3)
O6—OW4—OW3^viii	152.0 (5)	Na2^xi—O10—Eu1	122.9 (3)
O5—OW4—OW3^viii	123.1 (5)	Na2^xv—O10—Eu1	122.9 (3)
O8^iv—OW4—OW3^viii	105.2 (5)	La1—O10—Eu1	0.000 (9)
O4—OW4—OW3^viii	71.6 (4)	Si1—O10—O9	38.1 (3)
Si2^iv—OW4—OW3^viii	130.0 (5)	Na2^iv—O10—O9	119.7 (3)
OW3—OW4—Na1	43.2 (8)	Na2^ix—O10—O9	119.7 (3)
OW1^iv—OW4—Na1	139.2 (6)	Na2^xi—O10—O9	137.1 (3)
OW4^viii—OW4—Na1	140.21 (15)	Na2^xv—O10—O9	137.1 (3)
Na3^viii—OW4—Na1	140.21 (15)	La1—O10—O9	64.5 (3)
OW3^iii—OW4—Na1	49.9 (4)	Eu1—O10—O9	64.5 (3)
O6—OW4—Na1	87.3 (3)	Si1—O10—O1^i	34.5 (2)
O5—OW4—Na1	44.15 (19)	Na2^iv—O10—O1^i	126.9 (4)
O8^iv—OW4—Na1	107.4 (3)	Na2^ix—O10—O1^i	75.0 (3)
O4—OW4—Na1	86.5 (2)	Na2^xi—O10—O1^i	119.2 (4)
Si2^iv—OW4—Na1	101.7 (3)	Na2^xv—O10—O1^i	81.9 (3)
OW3^viii—OW4—Na1	120.7 (4)	La1—O10—O1^i	116.2 (3)
O10—Si1—O1^i	111.5 (3)	Eu1—O10—O1^i	116.2 (3)
O10—Si1—O1	111.5 (3)	O9—O10—O1^i	61.1 (3)
O1^i—Si1—O1	110.1 (5)	Si1—O10—O1	34.5 (2)
O10—Si1—O9	105.0 (4)	Na2^iv—O10—O1	75.0 (3)
O1^i—Si1—O9	109.4 (3)	Na2^ix—O10—O1	126.9 (4)
O1—Si1—O9	109.4 (3)	Na2^xi—O10—O1	81.9 (3)
O10—Si1—Eu1	49.0 (3)	Na2^xv—O10—O1	119.2 (4)
O1^i—Si1—Eu1	125.0 (3)	La1—O10—O1	116.2 (3)
O1—Si1—Eu1	125.0 (3)	Eu1—O10—O1	116.2 (3)
O9—Si1—Eu1	56.0 (3)	O9—O10—O1	61.1 (3)
O10—Si1—La1	49.0 (3)	O1^i—O10—O1	59.8 (3)
O1^i—Si1—La1	125.0 (3)	Si1—O10—O11	125.5 (3)
O1—Si1—La1	125.0 (3)	Na2^iv—O10—O11	60.8 (3)
O9—Si1—La1	56.0 (3)	Na2^ix—O10—O11	122.1 (4)
Eu1—Si1—La1	0.000 (12)	Na2^xi—O10—O11	75.3 (2)
O10—Si1—Na2^iv	43.49 (19)	Na2^xv—O10—O11	119.5 (4)
O1^i—Si1—Na2^iv	131.2 (3)	La1—O10—O11	47.65 (17)
O1—Si1—Na2^iv	68.1 (3)	Eu1—O10—O11	47.65 (17)
O9—Si1—Na2^iv	117.2 (3)	O9—O10—O11	96.4 (3)
Eu1—Si1—Na2^iv	74.57 (16)	O1^i—O10—O11	157.4 (3)
La1—Si1—Na2^iv	74.57 (16)	O1—O10—O11	109.5 (2)
O10—Si1—Na2^ix	43.49 (19)	Si1—O10—O11^i	125.5 (3)
O1^i—Si1—Na2^ix	68.1 (3)	Na2^iv—O10—O11^i	122.1 (4)
O1—Si1—Na2^ix	131.2 (3)	Na2^ix—O10—O11^i	60.8 (3)
O9—Si1—Na2^ix	117.2 (3)	Na2^xi—O10—O11^i	119.5 (4)
Eu1—Si1—Na2^ix	74.57 (16)	Na2^xv—O10—O11^i	75.3 (2)
La1—Si1—Na2^ix	74.57 (16)	La1—O10—O11^i	47.65 (17)
Na2^iv—Si1—Na2^ix	78.0 (3)	Eu1—O10—O11^i	47.65 (17)
O6^vi—Si2—O8^i	110.7 (3)	O9—O10—O11^i	96.4 (3)
O6^vi—Si2—O8	110.7 (3)	O1^i—O10—O11^i	109.5 (2)
O8^i—Si2—O8	107.5 (4)	O1—O10—O11^i	157.4 (3)
O6^vi—Si2—O9	115.3 (4)	O11—O10—O11^i	72.4 (3)
O8^i—Si2—O9	106.2 (3)	Si4—O11—Na1	117.6 (3)
O8—Si2—O9	106.2 (3)	Si4—O11—La1	138.7 (3)
O6^vi—Si2—Na3^x	54.5 (3)	Na1—O11—La1	102.5 (2)
O8^i—Si2—Na3^x	57.2 (3)	Si4—O11—Eu1	138.7 (3)
O8—Si2—Na3^x	116.0 (3)	Na1—O11—Eu1	102.5 (2)
O9—Si2—Na3^x	137.5 (2)	La1—O11—Eu1	0.000 (16)
O6^vi—Si2—OW4^x	54.5 (3)	Si4—O11—O3	37.0 (2)
O8^i—Si2—OW4^x	57.2 (3)	Na1—O11—O3	127.0 (3)
O8—Si2—OW4^x	116.0 (3)	La1—O11—O3	121.7 (2)
O9—Si2—OW4^x	137.5 (2)	Eu1—O11—O3	121.7 (2)
Na3^x—Si2—OW4^x	0.0 (4)	Si4—O11—O2^iv	33.67 (19)
O6^vi—Si2—OW4^vi	54.5 (3)	Na1—O11—O2^iv	84.1 (2)
O8^i—Si2—OW4^vi	116.0 (3)	La1—O11—O2^iv	165.7 (3)
O8—Si2—OW4^vi	57.2 (3)	Eu1—O11—O2^iv	165.7 (3)
O9—Si2—OW4^vi	137.5 (2)	O3—O11—O2^iv	60.5 (2)
Na3^x—Si2—OW4^vi	74.9 (3)	Si4—O11—O1^iv	32.64 (19)
OW4^x—Si2—OW4^vi	74.9 (3)	Na1—O11—O1^iv	130.4 (3)
O6^vi—Si2—Na3^vi	54.5 (3)	La1—O11—O1^iv	111.7 (3)
O8^i—Si2—Na3^vi	116.0 (3)	Eu1—O11—O1^iv	111.7 (3)
O8—Si2—Na3^vi	57.2 (3)	O3—O11—O1^iv	59.9 (2)
O9—Si2—Na3^vi	137.5 (2)	O2^iv—O11—O1^iv	55.7 (2)
Na3^x—Si2—Na3^vi	74.9 (3)	Si4—O11—Na2^iv	86.5 (3)
OW4^x—Si2—Na3^vi	74.9 (3)	Na1—O11—Na2^iv	97.4 (3)
OW4^vi—Si2—Na3^vi	0.0 (4)	La1—O11—Na2^iv	98.3 (3)
O5—Si3—O4	110.8 (4)	Eu1—O11—Na2^iv	98.3 (3)
O5—Si3—O7	112.8 (4)	O3—O11—Na2^iv	51.9 (3)
O4—Si3—O7	108.5 (4)	O2^iv—O11—Na2^iv	93.4 (3)
O5—Si3—O8	114.0 (3)	O1^iv—O11—Na2^iv	111.5 (3)
O4—Si3—O8	107.5 (4)	Si4—O11—O5	162.8 (4)
O7—Si3—O8	102.8 (3)	Na1—O11—O5	51.94 (16)
O5—Si3—Na3	48.0 (3)	La1—O11—O5	50.90 (15)
O4—Si3—Na3	65.7 (3)	Eu1—O11—O5	50.90 (15)
O7—Si3—Na3	112.8 (3)	O3—O11—O5	159.1 (3)
O8—Si3—Na3	144.2 (3)	O2^iv—O11—O5	132.5 (3)
O5—Si3—Na1	41.5 (2)	O1^iv—O11—O5	139.5 (3)
O4—Si3—Na1	123.5 (3)	Na2^iv—O11—O5	107.6 (3)
O7—Si3—Na1	71.4 (3)	Si4—O11—OW2	106.3 (4)
O8—Si3—Na1	128.2 (2)	Na1—O11—OW2	54.0 (3)
Na3—Si3—Na1	63.49 (17)	La1—O11—OW2	104.8 (3)
O11—Si4—O1^iv	115.8 (4)	Eu1—O11—OW2	104.8 (3)
O11—Si4—O2^iv	114.0 (4)	O3—O11—OW2	85.5 (4)
O1^iv—Si4—O2^iv	101.6 (4)	O2^iv—O11—OW2	89.4 (3)
O11—Si4—O3	108.0 (4)	O1^iv—O11—OW2	139.0 (4)
O1^iv—Si4—O3	108.4 (3)	Na2^iv—O11—OW2	43.4 (3)
O2^iv—Si4—O3	108.7 (3)	O5—O11—OW2	79.1 (3)
O11—Si4—Na2^iv	64.4 (3)	Si4—O11—O10	114.2 (3)
O1^iv—Si4—Na2^iv	145.0 (3)	Na1—O11—O10	112.5 (3)
O2^iv—Si4—Na2^iv	110.0 (3)	La1—O11—O10	52.38 (17)
O3—Si4—Na2^iv	47.4 (3)	Eu1—O11—O10	52.38 (17)
O11—Si4—Na1	38.2 (2)	O3—O11—O10	79.0 (3)
O1^iv—Si4—Na1	129.9 (2)	O2^iv—O11—O10	136.9 (3)
O2^iv—Si4—Na1	75.9 (3)	O1^iv—O11—O10	116.7 (3)
O3—Si4—Na1	119.9 (3)	Na2^iv—O11—O10	46.7 (2)
Na2^iv—Si4—Na1	73.93 (17)	O5—O11—O10	83.0 (2)
Si4^vi—O1—Si1	151.0 (5)	OW2—O11—O10	72.4 (3)
Si4^vi—O1—O2	39.4 (2)	Si4—O11—O6	113.8 (4)
Si1—O1—O2	162.1 (4)	Na1—O11—O6	98.7 (2)
Si4^vi—O1—O3^vi	36.19 (16)	La1—O11—O6	46.54 (16)
Si1—O1—O3^vi	135.7 (3)	Eu1—O11—O6	46.54 (16)
O2—O1—O3^vi	62.0 (2)	O3—O11—O6	132.3 (3)
Si4^vi—O1—O1^i	121.2 (2)	O2^iv—O11—O6	120.3 (3)
Si1—O1—O1^i	35.0 (3)	O1^iv—O11—O6	81.4 (3)
O2—O1—O1^i	160.5 (2)	Na2^iv—O11—O6	143.8 (3)
O3^vi—O1—O1^i	101.31 (13)	O5—O11—O6	60.3 (2)
Si4^vi—O1—O10	172.3 (4)	OW2—O11—O6	139.2 (4)
Si1—O1—O10	34.1 (2)	O10—O11—O6	97.1 (2)
O2—O1—O10	138.8 (4)	OW4^vi—OW1—Na3^vi	0.0 (6)
O3^vi—O1—O10	137.2 (3)	OW4^vi—OW1—OW4^xvi	159.1 (13)
O1^i—O1—O10	60.12 (17)	Na3^vi—OW1—OW4^xvi	159.1 (13)
Si4^vi—O1—O9	129.8 (4)	OW4^vi—OW1—Na3^xvi	159.1 (13)
Si1—O1—O9	35.67 (19)	Na3^vi—OW1—Na3^xvi	159.1 (13)
O2—O1—O9	129.2 (3)	OW4^xvi—OW1—Na3^xvi	0.0 (5)
O3^vi—O1—O9	149.3 (4)	OW4^vi—OW1—OW4^xvii	62.1 (5)
O1^i—O1—O9	60.14 (15)	Na3^vi—OW1—OW4^xvii	62.1 (5)
O10—O1—O9	57.9 (3)	OW4^xvi—OW1—OW4^xvii	113.7 (5)
Si4^vi—O1—O11^vi	31.6 (2)	Na3^xvi—OW1—OW4^xvii	113.7 (5)
Si1—O1—O11^vi	121.6 (4)	OW4^vi—OW1—Na3^xvii	62.1 (5)
O2—O1—O11^vi	61.8 (3)	Na3^vi—OW1—Na3^xvii	62.1 (5)
O3^vi—O1—O11^vi	58.2 (2)	OW4^xvi—OW1—Na3^xvii	113.7 (5)
O1^i—O1—O11^vi	101.60 (17)	Na3^xvi—OW1—Na3^xvii	113.7 (5)
O10—O1—O11^vi	155.2 (3)	OW4^xvii—OW1—Na3^xvii	0.0 (6)
O9—O1—O11^vi	99.3 (3)	OW4^vi—OW1—Na3^x	113.7 (5)
Si4^vi—O1—Na2^iv	125.9 (3)	Na3^vi—OW1—Na3^x	113.7 (5)
Si1—O1—Na2^iv	82.9 (4)	OW4^xvi—OW1—Na3^x	62.1 (5)
O2—O1—Na2^iv	92.2 (3)	Na3^xvi—OW1—Na3^x	62.1 (5)
O3^vi—O1—Na2^iv	112.1 (3)	OW4^xvii—OW1—Na3^x	159.1 (13)
O1^i—O1—Na2^iv	104.16 (18)	Na3^xvii—OW1—Na3^x	159.1 (13)
O10—O1—Na2^iv	48.9 (2)	OW4^vi—OW1—OW4^x	113.7 (5)
O9—O1—Na2^iv	96.8 (3)	Na3^vi—OW1—OW4^x	113.7 (5)
O11^vi—O1—Na2^iv	153.9 (3)	OW4^xvi—OW1—OW4^x	62.1 (5)
Si4^vi—O1—OW2	102.3 (4)	Na3^xvi—OW1—OW4^x	62.1 (5)
Si1—O1—OW2	103.6 (4)	OW4^xvii—OW1—OW4^x	159.1 (13)
O2—O1—OW2	63.0 (3)	Na3^xvii—OW1—OW4^x	159.1 (13)
O3^vi—O1—OW2	114.9 (3)	Na3^x—OW1—OW4^x	0.0 (2)
O1^i—O1—OW2	136.5 (3)	OW4^vi—OW1—O6^vi	56.9 (3)
O10—O1—OW2	76.7 (3)	Na3^vi—OW1—O6^vi	56.9 (3)
O9—O1—OW2	93.5 (4)	OW4^xvi—OW1—O6^vi	116.2 (5)
O11^vi—O1—OW2	117.4 (4)	Na3^xvi—OW1—O6^vi	116.2 (5)
Na2^iv—O1—OW2	40.9 (3)	OW4^xvii—OW1—O6^vi	116.2 (5)
Si4^vi—O1—Na2^xi	125.7 (3)	Na3^xvii—OW1—O6^vi	116.2 (5)
Si1—O1—Na2^xi	80.6 (3)	Na3^x—OW1—O6^vi	56.9 (3)
O2—O1—Na2^xi	98.9 (3)	OW4^x—OW1—O6^vi	56.9 (3)
O3^vi—O1—Na2^xi	103.2 (2)	OW4^vi—OW1—O6^xvi	116.2 (5)
O1^i—O1—Na2^xi	94.66 (16)	Na3^vi—OW1—O6^xvi	116.2 (5)
O10—O1—Na2^xi	47.5 (2)	OW4^xvi—OW1—O6^xvi	56.9 (3)
O9—O1—Na2^xi	102.6 (3)	Na3^xvi—OW1—O6^xvi	56.9 (3)
O11^vi—O1—Na2^xi	157.2 (3)	OW4^xvii—OW1—O6^xvi	56.9 (3)
Na2^iv—O1—Na2^xi	15.2 (3)	Na3^xvii—OW1—O6^xvi	56.9 (3)
OW2—O1—Na2^xi	55.3 (3)	Na3^x—OW1—O6^xvi	116.2 (5)
Si4^vi—O1—O1^v	75.7 (2)	OW4^x—OW1—O6^xvi	116.2 (5)
Si1—O1—O1^v	121.3 (3)	O6^vi—OW1—O6^xvi	146.4 (9)
O2—O1—O1^v	70.3 (3)	OW4^vi—OW1—O4^xvi	131.6 (8)
O3^vi—O1—O1^v	49.55 (19)	Na3^vi—OW1—O4^xvi	131.6 (8)
O1^i—O1—O1^v	107.60 (18)	OW4^xvi—OW1—O4^xvi	67.7 (4)
O10—O1—O1^v	96.6 (2)	Na3^xvi—OW1—O4^xvi	67.7 (4)
O9—O1—O1^v	154.4 (3)	OW4^xvii—OW1—O4^xvi	131.6 (8)
O11^vi—O1—O1^v	105.39 (19)	Na3^xvii—OW1—O4^xvi	131.6 (8)
Na2^iv—O1—O1^v	62.9 (2)	Na3^x—OW1—O4^xvi	67.7 (4)
OW2—O1—O1^v	81.0 (3)	OW4^x—OW1—O4^xvi	67.7 (4)
Na2^xi—O1—O1^v	53.91 (17)	O6^vi—OW1—O4^xvi	103.1 (3)
Si4^vi—O2—Si4^xii	140.7 (5)	O6^xvi—OW1—O4^xvi	103.1 (3)
Si4^vi—O2—O1^iii	177.3 (5)	OW4^vi—OW1—O4^vi	67.7 (4)
Si4^xii—O2—O1^iii	39.0 (2)	Na3^vi—OW1—O4^vi	67.7 (4)
Si4^vi—O2—O1	39.0 (2)	OW4^xvi—OW1—O4^vi	131.6 (8)
Si4^xii—O2—O1	177.3 (5)	Na3^xvi—OW1—O4^vi	131.6 (8)
O1^iii—O2—O1	141.1 (5)	OW4^xvii—OW1—O4^vi	67.7 (4)
Si4^vi—O2—O3^xii	120.0 (4)	Na3^xvii—OW1—O4^vi	67.7 (4)
Si4^xii—O2—O3^xii	35.89 (17)	Na3^x—OW1—O4^vi	131.6 (8)
O1^iii—O2—O3^xii	61.4 (2)	OW4^x—OW1—O4^vi	131.6 (8)
O1—O2—O3^xii	146.5 (3)	O6^vi—OW1—O4^vi	103.1 (3)
Si4^vi—O2—O3^vi	35.89 (17)	O6^xvi—OW1—O4^vi	103.1 (3)
Si4^xii—O2—O3^vi	120.0 (4)	O4^xvi—OW1—O4^vi	77.1 (6)
O1^iii—O2—O3^vi	146.5 (3)	Na2^xviii—OW2—Na2^iv	92.3 (7)
O1—O2—O3^vi	61.44 (19)	Na2^xviii—OW2—Na1	111.5 (7)
O3^xii—O2—O3^vi	88.2 (3)	Na2^iv—OW2—Na1	111.5 (7)
Si4^vi—O2—O11^vi	32.3 (2)	Na2^xviii—OW2—O2	98.5 (6)
Si4^xii—O2—O11^vi	116.0 (4)	Na2^iv—OW2—O2	98.5 (6)
O1^iii—O2—O11^vi	145.4 (4)	Na1—OW2—O2	135.8 (7)
O1—O2—O11^vi	62.5 (2)	Na2^xviii—OW2—Na2^xix	5.9 (3)
O3^xii—O2—O11^vi	115.0 (3)	Na2^iv—OW2—Na2^xix	88.6 (5)
O3^vi—O2—O11^vi	58.28 (18)	Na1—OW2—Na2^xix	117.2 (5)
Si4^vi—O2—O11^xii	116.0 (4)	O2—OW2—Na2^xix	94.4 (5)
Si4^xii—O2—O11^xii	32.3 (2)	Na2^xviii—OW2—Na2^xi	88.6 (5)
O1^iii—O2—O11^xii	62.5 (2)	Na2^iv—OW2—Na2^xi	5.9 (3)
O1—O2—O11^xii	145.4 (4)	Na1—OW2—Na2^xi	117.2 (5)
O3^xii—O2—O11^xii	58.28 (18)	O2—OW2—Na2^xi	94.4 (5)
O3^vi—O2—O11^xii	115.0 (3)	Na2^xix—OW2—Na2^xi	84.6 (5)
O11^vi—O2—O11^xii	85.9 (3)	Na2^xviii—OW2—O11^iii	63.3 (4)
Si4^vi—O2—OW2	109.6 (3)	Na2^iv—OW2—O11^iii	113.3 (8)
Si4^xii—O2—OW2	109.6 (3)	Na1—OW2—O11^iii	48.2 (3)
O1^iii—O2—OW2	70.6 (2)	O2—OW2—O11^iii	143.0 (3)
O1—O2—OW2	70.6 (2)	Na2^xix—OW2—O11^iii	69.1 (3)
O3^xii—O2—OW2	120.5 (3)	Na2^xi—OW2—O11^iii	115.6 (6)
O3^vi—O2—OW2	120.5 (3)	Na2^xviii—OW2—O11	113.3 (8)
O11^vi—O2—OW2	124.4 (3)	Na2^iv—OW2—O11	63.3 (4)
O11^xii—O2—OW2	124.4 (3)	Na1—OW2—O11	48.2 (3)
Si4^vi—O2—Na1^vi	76.4 (3)	O2—OW2—O11	143.0 (3)
Si4^xii—O2—Na1^vi	76.4 (3)	Na2^xix—OW2—O11	115.6 (6)
O1^iii—O2—Na1^vi	101.5 (2)	Na2^xi—OW2—O11	69.1 (3)
O1—O2—Na1^vi	101.5 (3)	O11^iii—OW2—O11	71.8 (5)
O3^xii—O2—Na1^vi	94.0 (2)	Na2^xviii—OW2—O1	129.3 (7)
O3^vi—O2—Na1^vi	94.0 (2)	Na2^iv—OW2—O1	65.7 (4)
O11^vi—O2—Na1^vi	44.12 (17)	Na1—OW2—O1	119.0 (4)
O11^xii—O2—Na1^vi	44.12 (17)	O2—OW2—O1	46.5 (3)
OW2—O2—Na1^vi	129.4 (4)	Na2^xix—OW2—O1	123.4 (6)
Si4^vi—O2—O1^xiii	115.4 (4)	Na2^xi—OW2—O1	64.8 (3)
Si4^xii—O2—O1^xiii	73.3 (3)	O11^iii—OW2—O1	166.7 (5)
O1^iii—O2—O1^xiii	67.3 (2)	O11—OW2—O1	97.06 (16)
O1—O2—O1^xiii	109.3 (3)	Na2^xviii—OW2—O1^iii	65.7 (4)
O3^xii—O2—O1^xiii	48.5 (2)	Na2^iv—OW2—O1^iii	129.3 (7)
O3^vi—O2—O1^xiii	82.3 (2)	Na1—OW2—O1^iii	119.0 (4)
O11^vi—O2—O1^xiii	139.3 (3)	O2—OW2—O1^iii	46.5 (3)
O11^xii—O2—O1^xiii	103.9 (2)	Na2^xix—OW2—O1^iii	64.8 (3)
OW2—O2—O1^xiii	82.5 (4)	Na2^xi—OW2—O1^iii	123.4 (6)
Na1^vi—O2—O1^xiii	142.2 (2)	O11^iii—OW2—O1^iii	97.06 (16)
Si4^vi—O2—O1^v	73.3 (3)	O11—OW2—O1^iii	166.7 (5)
Si4^xii—O2—O1^v	115.4 (4)	O1—OW2—O1^iii	93.0 (6)
O1^iii—O2—O1^v	109.3 (3)	Na2^xviii—OW2—O10^v	48.7 (4)
O1—O2—O1^v	67.3 (2)	Na2^iv—OW2—O10^v	48.7 (4)
O3^xii—O2—O1^v	82.3 (2)	Na1—OW2—O10^v	139.5 (7)
O3^vi—O2—O1^v	48.5 (2)	O2—OW2—O10^v	84.7 (5)
O11^vi—O2—O1^v	103.9 (2)	Na2^xix—OW2—O10^v	43.5 (3)
O11^xii—O2—O1^v	139.3 (3)	Na2^xi—OW2—O10^v	43.5 (3)
OW2—O2—O1^v	82.5 (4)	O11^iii—OW2—O10^v	102.1 (5)
Na1^vi—O2—O1^v	142.2 (2)	O11—OW2—O10^v	102.1 (5)
O1^xiii—O2—O1^v	44.7 (2)	O1—OW2—O10^v	87.1 (4)
Si4^v—O3—Si4	134.2 (5)	O1^iii—OW2—O10^v	87.1 (4)
Si4^v—O3—Na2^iv	123.1 (4)	OW3^iii—OW3—OW4	157.0 (8)
Si4—O3—Na2^iv	102.6 (3)	OW3^iii—OW3—Na3	157.0 (8)
Si4^v—O3—Na2^xi	102.6 (3)	OW4—OW3—Na3	0.0 (10)
Si4—O3—Na2^xi	123.1 (4)	OW3^iii—OW3—OW4^iii	12.6 (5)
Na2^iv—O3—Na2^xi	21.8 (4)	OW4—OW3—OW4^iii	144.4 (12)
Si4^v—O3—O11^v	35.01 (17)	Na3—OW3—OW4^iii	144.4 (12)
Si4—O3—O11^v	163.2 (4)	OW3^iii—OW3—Na3^iii	12.6 (5)
Na2^iv—O3—O11^v	89.1 (4)	OW4—OW3—Na3^iii	144.4 (12)
Na2^xi—O3—O11^v	70.5 (3)	Na3—OW3—Na3^iii	144.4 (12)
Si4^v—O3—O11	163.2 (4)	OW4^iii—OW3—Na3^iii	0.0 (4)
Si4—O3—O11	35.01 (17)	OW3^iii—OW3—Na1	78.0 (3)
Na2^iv—O3—O11	70.5 (3)	OW4—OW3—Na1	116.7 (10)
Na2^xi—O3—O11	89.1 (4)	Na3—OW3—Na1	116.7 (10)
O11^v—O3—O11	159.5 (5)	OW4^iii—OW3—Na1	86.6 (5)
Si4^v—O3—O1^xi	35.4 (2)	Na3^iii—OW3—Na1	86.6 (5)
Si4—O3—O1^xi	102.9 (4)	OW3^iii—OW3—O5	119.2 (4)
Na2^iv—O3—O1^xi	145.8 (3)	OW4—OW3—O5	66.1 (8)
Na2^xi—O3—O1^xi	131.9 (3)	Na3—OW3—O5	66.1 (8)
O11^v—O3—O1^xi	61.9 (2)	OW4^iii—OW3—O5	120.0 (7)
O11—O3—O1^xi	137.9 (3)	Na3^iii—OW3—O5	120.0 (7)
Si4^v—O3—O1^iv	102.9 (4)	Na1—OW3—O5	53.4 (4)
Si4—O3—O1^iv	35.4 (2)	OW3^iii—OW3—O8^iv	128.0 (4)
Na2^iv—O3—O1^iv	131.9 (3)	OW4—OW3—O8^iv	61.1 (8)
Na2^xi—O3—O1^iv	145.8 (3)	Na3—OW3—O8^iv	61.1 (8)
O11^v—O3—O1^iv	137.9 (3)	OW4^iii—OW3—O8^iv	130.4 (8)
O11—O3—O1^iv	61.9 (2)	Na3^iii—OW3—O8^iv	130.4 (8)
O1^xi—O3—O1^iv	80.9 (4)	Na1—OW3—O8^iv	122.3 (6)
Si4^v—O3—O2^iv	117.9 (4)	O5—OW3—O8^iv	109.4 (5)
Si4—O3—O2^iv	35.40 (16)	OW3^iii—OW3—Na3^viii	113.8 (3)
Na2^iv—O3—O2^iv	106.2 (3)	OW4—OW3—Na3^viii	43.8 (7)
Na2^xi—O3—O2^iv	126.7 (3)	Na3—OW3—Na3^viii	43.8 (7)
O11^v—O3—O2^iv	129.8 (2)	OW4^iii—OW3—Na3^viii	101.4 (6)
O11—O3—O2^iv	61.2 (2)	Na3^iii—OW3—Na3^viii	101.4 (6)
O1^xi—O3—O2^iv	82.7 (3)	Na1—OW3—Na3^viii	143.6 (7)
O1^iv—O3—O2^iv	56.5 (2)	O5—OW3—Na3^viii	93.2 (5)
Si4^v—O3—O2^xi	35.40 (16)	O8^iv—OW3—Na3^viii	79.0 (4)
Si4—O3—O2^xi	117.9 (4)	OW3^iii—OW3—OW4^viii	113.8 (3)
Na2^iv—O3—O2^xi	126.7 (3)	OW4—OW3—OW4^viii	43.8 (7)
Na2^xi—O3—O2^xi	106.2 (3)	Na3—OW3—OW4^viii	43.8 (7)
O11^v—O3—O2^xi	61.2 (2)	OW4^iii—OW3—OW4^viii	101.4 (6)
O11—O3—O2^xi	129.8 (2)	Na3^iii—OW3—OW4^viii	101.4 (6)
O1^xi—O3—O2^xi	56.5 (2)	Na1—OW3—OW4^viii	143.6 (7)
O1^iv—O3—O2^xi	82.7 (3)	O5—OW3—OW4^viii	93.2 (5)
O2^iv—O3—O2^xi	127.0 (5)	O8^iv—OW3—OW4^viii	79.0 (4)
Si3^viii—O4—Si3	141.2 (6)	Na3^viii—OW3—OW4^viii	0.0 (4)
Si3^viii—O4—O5	173.2 (5)	OW3^iii—OW3—O7^iv	80.1 (3)
Si3—O4—O5	33.87 (16)	OW4—OW3—O7^iv	104.5 (10)
Si3^viii—O4—O5^viii	33.87 (16)	Na3—OW3—O7^iv	104.5 (10)
Si3—O4—O5^viii	173.2 (5)	OW4^iii—OW3—O7^iv	83.3 (5)
O5—O4—O5^viii	150.3 (4)	Na3^iii—OW3—O7^iv	83.3 (5)
Si3^viii—O4—O8^viii	36.5 (2)	Na1—OW3—O7^iv	120.0 (6)
Si3—O4—O8^viii	117.1 (4)	O5—OW3—O7^iv	152.5 (6)
O5—O4—O8^viii	144.5 (4)	O8^iv—OW3—O7^iv	48.0 (3)
O5^viii—O4—O8^viii	61.54 (18)	Na3^viii—OW3—O7^iv	96.3 (5)
Si3^viii—O4—O8	117.1 (4)	OW4^viii—OW3—O7^iv	96.3 (5)
Si3—O4—O8	36.5 (2)	OW3^iii—OW3—O6	159.7 (3)
O5—O4—O8	61.54 (18)	OW4—OW3—O6	43.3 (6)
O5^viii—O4—O8	144.5 (4)	Na3—OW3—O6	43.3 (6)
O8^viii—O4—O8	83.8 (3)	OW4^iii—OW3—O6	172.2 (7)
Si3^viii—O4—O7	112.7 (4)	Na3^iii—OW3—O6	172.2 (7)
Si3—O4—O7	35.8 (2)	Na1—OW3—O6	88.5 (5)
O5—O4—O7	60.7 (2)	O5—OW3—O6	61.0 (4)
O5^viii—O4—O7	137.5 (3)	O8^iv—OW3—O6	48.6 (3)
O8^viii—O4—O7	108.5 (3)	Na3^viii—OW3—O6	86.1 (4)
O8—O4—O7	58.0 (2)	OW4^viii—OW3—O6	86.1 (4)
Si3^viii—O4—O7^xiv	35.8 (2)	O7^iv—OW3—O6	94.0 (5)
Si3—O4—O7^xiv	112.7 (4)

Symmetry codes: (i) −x+1, y, z; (ii) x−1, y, z; (iii) −x+2, y, z; (iv) x, y, z+1; (v) −x+3/2, −y+3/2, z; (vi) x, y, z−1; (vii) −x+3/2, −y+3/2, z−1; (viii) x, −y+1, z; (ix) −x+1, y, z+1; (x) −x+1, y, z−1; (xi) −x+3/2, −y+3/2, z+1; (xii) −x+2, y, z−1; (xiii) x+1/2, −y+3/2, z; (xiv) −x+2, −y+1, z; (xv) x−1/2, −y+3/2, z+1; (xvi) −x+1, −y+1, z−1; (xvii) x, −y+1, z−1; (xviii) −x+2, y, z+1; (xix) x+1/2, −y+3/2, z+1.