Concomitance of octamolybdate isomers in metastable crystal structures isolated using homoleptic Co^II/Co^III complexes as structure-directing templates

Exploiting the kinetic domain provided by hydro­thermal conditions, it was possible to isolate three transient metastable crystal structures, each bearing concomitant pairs of octamolybdate isomers, namely, α–β, γ–β or β_cs–β_gp stabilized by distinctive homoleptic [Co(bpy)₃]ⁿ⁺ (bpy = 2,2′-bi­pyridine; n = 2 or 3) cations generated in situ: [Co(bpy)₃]₄[(α-Mo₈O₂₆)(β-Mo₈O₂₆)]·5H₂O (1), [NH₄][Co(bpy)₃][(γ-Mo₈O₂₆)_0.5(β-Mo₈O₂₆)_0.5]·4H₂O (2) and [Co(bpy)₃]₂[(β_cs-Mo₈O₂₆)_0.5(β_gp-Mo₈O₂₆)]·12H₂O (3). Solid 1 with the space group P2₁/n and unit-cell parameters a = 22.160 (6), b = 14.209 (3), c = 24.641 (4) Å, β = 99.10 (2)° and V = 7661 (3) ų resulted in the same crystal structure as that synthesized previously under different conditions by Sun et al. [J. Mol. Struct. (2005), 741, 149–153]. Factors directing the reaction, such as product com­position and phase stability, were monitored by analysis of the PXRD patterns of the bulk solids obtained under different experimental conditions. The relative proportions of the mixed phases 1–3 or their stabilization are highly dependent on the initial Co:Mo molar ratio and the reaction temperature. In particular, an increase in temperature induces the transformation of 1–3 into more thermodynamically stable phases formed by one-dimensional coordination polymers [Co(bpy)₂(β-Mo₈O₂₆)_0.5]_n (4) and [(MoO₃)(bpy)]_n (5). The crystal structures of 1–3 correspond to molecular salts self-assembled by C—H...O—Mo, C...H and H...H intermolecular contacts. A Hirshfeld surface analysis for 1 showed that the C...H and H...H interactions represent an average of 51.8% of the total cation–cation intermolecular contacts. In contrast, these interactions are vastly reduced in 2 (23.0%) and 3 (average 28.5% for both isomers). EPR experiments indicated that the crystal structures of 1 and 3 are paramagnetic, and that for 2 is diamagnetic. The paramagnetism of 3 stems from the in situ formation of [Co(bpy)₃]³⁺ in a high-spin configuration. The structure-directing properties of the [Co(bpy)₃]ⁿ⁺ cations in the isolation and self-assembly of concomitant octamolybdate isomers are also described from the viewpoint of crystal engineering.

Computing details

Data collection: CrystalClear (Rigaku, 2005) for (2), (3); MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1991) for (4). Cell refinement: CrystalClear (Rigaku, 2005) for (2), (3); MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1991) for (4). Data reduction: CrystalClear (Rigaku, 2005) for (2), (3); TEXSAN (Molecular Structure Corporation, 1999) for (4). For all structures, program(s) used to solve structure: SHELXS (Sheldrick, 2008); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2015); molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

Ammonium tris(2,2'-bipyridine)cobaltate(II) octamolybdate tetrahydrate (2)

Crystal data

(NH4)[Co(C10H8N2)3][Mo8O26]·4H2O	F(000) = 3472
Mr = 1801.11	Dx = 2.476 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71069 Å
a = 19.270 (3) Å	Cell parameters from 8270 reflections
b = 10.993 (2) Å	θ = 1.8–25.2°
c = 23.917 (3) Å	µ = 2.44 mm^−1
β = 107.517 (11)°	T = 298 K
V = 4831.5 (13) Å^3	Plate, light yellow
Z = 4	0.33 × 0.31 × 0.09 mm

Data collection

Rigaku AFC-7S/Mercury (2x2 bin mode) diffractometer	Rint = 0.070
Absorption correction: multi-scan (CrystalClear; Rigaku, 2005)	θmax = 25.0°, θmin = 1.8°
Tmin = 0.484, Tmax = 0.715	h = 0→20
8653 measured reflections	k = 0→13
8270 independent reflections	l = −28→27
6849 reflections with I > 2σ(I)

Refinement

Refinement on F^2	Hydrogen site location: mixed
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.028	w = 1/[σ^2(Fo^2) + (0.0312P)^2 + 6.2337P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.070	(Δ/σ)max = 0.002
S = 1.05	Δρmax = 0.79 e Å^−3
8270 reflections	Δρmin = −0.59 e Å^−3
724 parameters	Extinction correction: SHELXL2013 (Sheldrick, 2015), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
279 restraints	Extinction coefficient: 0.00080 (3)
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Co1	0.74851 (3)	0.01392 (6)	0.24076 (3)	0.03090 (15)
N11	0.7073 (2)	−0.1221 (3)	0.27064 (16)	0.0344 (9)
N21	0.8165 (2)	−0.1073 (3)	0.22986 (15)	0.0347 (9)
C11	0.6531 (3)	−0.1176 (5)	0.2951 (2)	0.0449 (12)
H11	0.6324	−0.0428	0.2988	0.054*
C21	0.6275 (3)	−0.2207 (6)	0.3148 (3)	0.0572 (15)
H21	0.5907	−0.2158	0.3325	0.069*
C31	0.6574 (3)	−0.3315 (6)	0.3078 (2)	0.0601 (15)
H31	0.6397	−0.4025	0.3196	0.072*
C41	0.7135 (3)	−0.3369 (5)	0.2834 (2)	0.0486 (13)
H41	0.7341	−0.4112	0.2785	0.058*
C51	0.7387 (3)	−0.2303 (4)	0.26629 (18)	0.0372 (10)
C61	0.7998 (3)	−0.2228 (4)	0.24177 (18)	0.0384 (11)
C71	0.8396 (3)	−0.3201 (5)	0.2320 (2)	0.0502 (13)
H71	0.8275	−0.3989	0.2397	0.060*
C81	0.8973 (3)	−0.2999 (6)	0.2107 (2)	0.0569 (14)
H81	0.9245	−0.3651	0.2040	0.068*
C91	0.9149 (3)	−0.1819 (5)	0.1992 (2)	0.0528 (14)
H91	0.9541	−0.1665	0.1851	0.063*
C101	0.8727 (3)	−0.0883 (5)	0.2092 (2)	0.0446 (12)
H101	0.8838	−0.0090	0.2013	0.053*
N31	0.8023 (2)	0.0511 (3)	0.32113 (15)	0.0312 (8)
N41	0.6807 (2)	0.1327 (3)	0.25345 (17)	0.0360 (9)
C111	0.8627 (3)	−0.0035 (5)	0.3540 (2)	0.0434 (12)
H111	0.8859	−0.0593	0.3364	0.052*
C121	0.8921 (3)	0.0202 (5)	0.4132 (2)	0.0491 (13)
H121	0.9342	−0.0192	0.4350	0.059*
C131	0.8582 (3)	0.1026 (5)	0.4394 (2)	0.0467 (12)
H131	0.8769	0.1193	0.4793	0.056*
C141	0.7964 (3)	0.1600 (4)	0.4059 (2)	0.0407 (11)
H141	0.7729	0.2165	0.4229	0.049*
C151	0.7691 (2)	0.1336 (4)	0.3468 (2)	0.0322 (10)
C161	0.7031 (3)	0.1864 (4)	0.3072 (2)	0.0358 (10)
C171	0.6650 (3)	0.2822 (5)	0.3211 (3)	0.0496 (13)
H171	0.6813	0.3188	0.3578	0.059*
C181	0.6026 (3)	0.3229 (5)	0.2802 (3)	0.0542 (14)
H181	0.5763	0.3874	0.2888	0.065*
C191	0.5799 (3)	0.2674 (5)	0.2270 (3)	0.0515 (13)
H191	0.5376	0.2932	0.1991	0.062*
C201	0.6198 (3)	0.1728 (5)	0.2144 (2)	0.0465 (12)
H201	0.6038	0.1359	0.1778	0.056*
N51	0.7890 (2)	0.1442 (3)	0.20660 (15)	0.0313 (8)
N61	0.6910 (2)	−0.0150 (3)	0.16047 (16)	0.0360 (9)
C211	0.8391 (3)	0.2260 (4)	0.2345 (2)	0.0399 (11)
H211	0.8596	0.2189	0.2749	0.048*
C221	0.8614 (3)	0.3198 (4)	0.2060 (2)	0.0411 (11)
H221	0.8967	0.3743	0.2267	0.049*
C231	0.8306 (3)	0.3318 (5)	0.1465 (2)	0.0430 (12)
H231	0.8442	0.3955	0.1264	0.052*
C241	0.7793 (3)	0.2480 (4)	0.1168 (2)	0.0374 (11)
H241	0.7583	0.2544	0.0764	0.045*
C251	0.7595 (3)	0.1557 (4)	0.14722 (19)	0.0315 (10)
C261	0.7045 (2)	0.0633 (4)	0.12145 (19)	0.0314 (10)
C271	0.6661 (3)	0.0571 (5)	0.0625 (2)	0.0429 (12)
H271	0.6757	0.1114	0.0359	0.051*
C281	0.6129 (3)	−0.0321 (5)	0.0438 (2)	0.0471 (13)
H281	0.5862	−0.0378	0.0044	0.057*
C291	0.6002 (3)	−0.1108 (5)	0.0832 (2)	0.0503 (14)
H291	0.5647	−0.1706	0.0709	0.060*
C301	0.6396 (3)	−0.1022 (5)	0.1414 (2)	0.0477 (13)
H301	0.6308	−0.1570	0.1682	0.057*
Mo11	1.00264 (2)	−0.31281 (4)	0.37675 (2)	0.03569 (11)
Mo21	1.11043 (2)	−0.47839 (4)	0.61095 (2)	0.03785 (11)
Mo31	1.13414 (2)	−0.44775 (4)	0.47548 (2)	0.03163 (10)
Mo41	1.01947 (2)	−0.65353 (3)	0.48606 (2)	0.02919 (10)
O11	1.0222 (2)	−0.4000 (3)	0.32503 (15)	0.0502 (9)
O21	0.99318 (19)	−0.1690 (3)	0.34815 (15)	0.0475 (9)
O31	1.09829 (17)	−0.3054 (3)	0.43315 (14)	0.0376 (8)
O41	1.09642 (18)	−0.6394 (3)	0.63519 (13)	0.0415 (8)
O51	1.2024 (2)	−0.4688 (4)	0.63128 (16)	0.0594 (11)
O61	1.08534 (16)	−0.3613 (3)	0.54446 (13)	0.0324 (7)
O71	1.0848 (2)	−0.3924 (4)	0.66014 (15)	0.0593 (11)
O81	1.21808 (18)	−0.4023 (3)	0.51724 (15)	0.0435 (8)
O91	1.11385 (16)	−0.5815 (3)	0.52435 (13)	0.0332 (7)
O101	1.15039 (19)	−0.5386 (3)	0.42296 (15)	0.0435 (8)
O111	1.0384 (2)	−0.7337 (3)	0.43207 (15)	0.0454 (9)
O121	1.00795 (16)	−0.4767 (3)	0.44529 (12)	0.0286 (7)
O131	1.02082 (17)	−0.7607 (3)	0.53994 (14)	0.0366 (7)
Mo12	0.34625 (2)	0.48897 (4)	−0.12965 (2)	0.03419 (11)
Mo22	0.50075 (2)	0.39679 (4)	−0.14515 (2)	0.03434 (11)
Mo32	0.63677 (2)	0.42880 (4)	−0.02408 (2)	0.03372 (11)
Mo42	0.50852 (2)	0.36849 (4)	0.04103 (2)	0.03179 (10)
O12	0.30665 (19)	0.5812 (3)	−0.18704 (14)	0.0481 (9)
O22	0.2767 (2)	0.4069 (4)	−0.11802 (17)	0.0615 (11)
O32	0.39721 (18)	0.3672 (3)	−0.15271 (16)	0.0448 (9)
O42	0.37498 (17)	0.5763 (3)	−0.05689 (13)	0.0380 (8)
O52	0.46137 (17)	0.5620 (3)	−0.11706 (13)	0.0338 (7)
O62	0.4967 (2)	0.4325 (3)	−0.21466 (15)	0.0509 (9)
O72	0.5207 (2)	0.2453 (3)	−0.13682 (16)	0.0469 (9)
O82	0.6569 (2)	0.2796 (3)	−0.02701 (14)	0.0476 (9)
O92	0.59502 (17)	0.4605 (3)	−0.10528 (13)	0.0352 (7)
O102	0.71866 (19)	0.4991 (4)	−0.00642 (16)	0.0531 (10)
O112	0.5264 (2)	0.2183 (3)	0.05296 (15)	0.0478 (9)
O122	0.51919 (17)	0.4047 (3)	−0.03279 (13)	0.0335 (7)
O132	0.58586 (18)	0.6229 (3)	−0.02349 (14)	0.0399 (8)
N1A	0.1998 (3)	0.2935 (5)	−0.0471 (3)	0.0827 (18)
H1AA	0.2311	0.3325	−0.0703	0.124*
H1AB	0.1611	0.3545	−0.0431	0.124*
H1AC	0.1746	0.2169	−0.0686	0.124*
H1AD	0.2326	0.2697	−0.0059	0.124*
O1	0.6242 (4)	0.0357 (6)	−0.0882 (3)	0.072 (3)	0.695 (11)
H1A	0.5814	0.0250	−0.0860	0.108*	0.695 (11)
H1B	0.6434	0.0860	−0.0610	0.108*	0.695 (11)
O3	0.2065 (4)	0.2988 (7)	0.0810 (3)	0.133 (2)
H3A	0.2362	0.2492	0.0733	0.199*
H3B	0.1700	0.2992	0.0505	0.199*
O2	0.3196 (5)	0.1983 (8)	0.0437 (3)	0.076 (3)	0.71 (2)
H2A	0.3445	0.2311	0.0239	0.114*	0.71 (2)
H2B	0.3494	0.1512	0.0673	0.114*	0.71 (2)
O1A	0.5506 (11)	−0.0212 (16)	−0.1113 (7)	0.078 (6)	0.305 (11)
H1AE	0.5584	−0.0746	−0.0844	0.118*	0.305 (11)
H1AF	0.5212	−0.0493	−0.1426	0.118*	0.305 (11)
O2A	0.3008 (14)	0.116 (3)	0.0589 (12)	0.127 (10)	0.29 (2)
H2AA	0.3071	0.1441	0.0277	0.191*	0.29 (2)
H2AB	0.3366	0.0684	0.0726	0.191*	0.29 (2)
O4	0.0744 (4)	0.4662 (8)	−0.0929 (5)	0.142 (3)
H4A	0.0700	0.4922	−0.0607	0.213*
H4B	0.0312	0.4510	−0.1138	0.213*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Co1	0.0366 (4)	0.0278 (3)	0.0263 (3)	−0.0008 (3)	0.0065 (3)	0.0024 (2)
N11	0.038 (2)	0.034 (2)	0.0268 (19)	−0.0046 (16)	0.0034 (16)	0.0040 (16)
N21	0.046 (2)	0.031 (2)	0.0244 (19)	0.0014 (17)	0.0068 (17)	0.0016 (15)
C11	0.039 (3)	0.048 (3)	0.045 (3)	−0.005 (2)	0.010 (2)	0.010 (2)
C21	0.052 (3)	0.062 (3)	0.058 (3)	−0.014 (3)	0.016 (3)	0.015 (3)
C31	0.068 (4)	0.051 (3)	0.051 (3)	−0.021 (3)	0.004 (3)	0.011 (3)
C41	0.068 (3)	0.037 (3)	0.031 (3)	−0.009 (2)	0.001 (2)	0.006 (2)
C51	0.052 (3)	0.032 (2)	0.019 (2)	−0.0025 (19)	−0.0037 (18)	0.0028 (17)
C61	0.053 (3)	0.035 (2)	0.020 (2)	0.001 (2)	0.0004 (19)	−0.0020 (18)
C71	0.071 (3)	0.038 (3)	0.033 (3)	0.012 (2)	0.001 (2)	−0.001 (2)
C81	0.071 (4)	0.057 (3)	0.038 (3)	0.023 (3)	0.009 (3)	−0.002 (2)
C91	0.057 (3)	0.063 (3)	0.039 (3)	0.014 (3)	0.015 (2)	−0.001 (2)
C101	0.054 (3)	0.045 (3)	0.036 (3)	0.005 (2)	0.016 (2)	0.003 (2)
N31	0.036 (2)	0.0280 (19)	0.0275 (18)	−0.0005 (16)	0.0071 (15)	−0.0002 (15)
N41	0.034 (2)	0.033 (2)	0.041 (2)	0.0025 (17)	0.0116 (16)	0.0104 (16)
C111	0.046 (3)	0.043 (3)	0.036 (2)	0.011 (2)	0.005 (2)	−0.001 (2)
C121	0.059 (3)	0.042 (3)	0.035 (2)	0.002 (2)	−0.003 (2)	−0.001 (2)
C131	0.056 (3)	0.044 (3)	0.034 (2)	−0.009 (2)	0.004 (2)	−0.003 (2)
C141	0.052 (3)	0.033 (3)	0.038 (2)	−0.007 (2)	0.016 (2)	−0.007 (2)
C151	0.034 (2)	0.029 (2)	0.036 (2)	−0.0030 (18)	0.0134 (18)	−0.0004 (18)
C161	0.036 (2)	0.030 (2)	0.042 (2)	−0.0035 (19)	0.0133 (19)	0.0035 (19)
C171	0.050 (3)	0.038 (3)	0.064 (3)	0.003 (2)	0.022 (2)	0.000 (2)
C181	0.049 (3)	0.040 (3)	0.080 (4)	0.011 (2)	0.030 (3)	0.019 (3)
C191	0.040 (3)	0.051 (3)	0.066 (3)	0.010 (2)	0.019 (2)	0.027 (3)
C201	0.040 (3)	0.052 (3)	0.044 (3)	0.004 (2)	0.008 (2)	0.014 (2)
N51	0.038 (2)	0.0272 (19)	0.0278 (18)	0.0005 (16)	0.0093 (15)	0.0008 (15)
N61	0.042 (2)	0.032 (2)	0.0303 (19)	−0.0009 (17)	0.0047 (17)	0.0027 (16)
C211	0.045 (3)	0.038 (3)	0.036 (2)	−0.005 (2)	0.012 (2)	−0.001 (2)
C221	0.041 (3)	0.031 (2)	0.054 (3)	−0.006 (2)	0.018 (2)	−0.003 (2)
C231	0.049 (3)	0.031 (2)	0.054 (3)	0.001 (2)	0.024 (2)	0.003 (2)
C241	0.047 (3)	0.030 (2)	0.040 (2)	0.007 (2)	0.020 (2)	0.0064 (19)
C251	0.037 (2)	0.028 (2)	0.031 (2)	0.0060 (18)	0.0122 (18)	0.0012 (17)
C261	0.036 (2)	0.031 (2)	0.028 (2)	0.0051 (18)	0.0102 (18)	0.0010 (17)
C271	0.050 (3)	0.043 (3)	0.033 (2)	0.001 (2)	0.010 (2)	0.004 (2)
C281	0.055 (3)	0.052 (3)	0.028 (2)	−0.007 (2)	0.002 (2)	−0.003 (2)
C291	0.064 (4)	0.040 (3)	0.038 (3)	−0.013 (3)	0.002 (2)	−0.005 (2)
C301	0.066 (3)	0.036 (3)	0.035 (2)	−0.017 (2)	0.005 (2)	0.002 (2)
Mo11	0.0390 (2)	0.0348 (2)	0.0333 (2)	0.00422 (18)	0.01103 (18)	0.00643 (17)
Mo21	0.0406 (3)	0.0397 (2)	0.0266 (2)	−0.00563 (19)	0.00003 (17)	0.00111 (18)
Mo31	0.0312 (2)	0.0303 (2)	0.0340 (2)	0.00100 (17)	0.01072 (17)	0.00174 (17)
Mo41	0.0339 (2)	0.0226 (2)	0.0308 (2)	0.00112 (16)	0.00932 (16)	−0.00204 (16)
O11	0.058 (2)	0.054 (2)	0.042 (2)	0.0107 (19)	0.0197 (18)	0.0022 (17)
O21	0.051 (2)	0.045 (2)	0.048 (2)	0.0083 (17)	0.0175 (17)	0.0137 (17)
O31	0.0380 (19)	0.0343 (18)	0.0431 (19)	0.0013 (15)	0.0161 (15)	0.0079 (15)
O41	0.042 (2)	0.046 (2)	0.0319 (17)	0.0045 (16)	0.0040 (15)	0.0112 (15)
O51	0.049 (2)	0.065 (3)	0.051 (2)	−0.014 (2)	−0.0055 (18)	0.018 (2)
O61	0.0350 (18)	0.0267 (16)	0.0323 (17)	−0.0038 (13)	0.0053 (14)	−0.0030 (13)
O71	0.082 (3)	0.057 (2)	0.0328 (19)	−0.009 (2)	0.0088 (19)	−0.0115 (18)
O81	0.0353 (19)	0.046 (2)	0.047 (2)	−0.0066 (16)	0.0099 (16)	0.0012 (17)
O91	0.0323 (18)	0.0295 (17)	0.0350 (17)	0.0030 (13)	0.0059 (14)	0.0041 (14)
O101	0.047 (2)	0.044 (2)	0.043 (2)	0.0049 (16)	0.0180 (16)	−0.0002 (16)
O111	0.058 (2)	0.0341 (19)	0.049 (2)	−0.0018 (17)	0.0240 (18)	−0.0105 (16)
O121	0.0335 (17)	0.0253 (16)	0.0266 (15)	−0.0006 (13)	0.0084 (13)	−0.0013 (12)
O131	0.0408 (19)	0.0278 (17)	0.0424 (18)	0.0033 (14)	0.0145 (15)	0.0032 (14)
Mo12	0.0346 (2)	0.0379 (2)	0.0276 (2)	−0.00091 (18)	0.00571 (17)	−0.00219 (17)
Mo22	0.0394 (2)	0.0294 (2)	0.0339 (2)	0.00375 (18)	0.01050 (18)	−0.00261 (17)
Mo32	0.0334 (2)	0.0371 (2)	0.0301 (2)	0.00698 (18)	0.00872 (17)	−0.00198 (17)
Mo42	0.0344 (2)	0.0275 (2)	0.0316 (2)	0.00267 (17)	0.00729 (17)	−0.00409 (16)
O12	0.046 (2)	0.060 (2)	0.0340 (19)	0.0102 (18)	0.0044 (16)	0.0044 (17)
O22	0.059 (3)	0.081 (3)	0.048 (2)	−0.024 (2)	0.0202 (19)	−0.016 (2)
O32	0.040 (2)	0.0340 (19)	0.058 (2)	−0.0033 (15)	0.0100 (17)	−0.0079 (16)
O42	0.0338 (18)	0.047 (2)	0.0319 (17)	−0.0002 (15)	0.0079 (14)	−0.0056 (15)
O52	0.0374 (18)	0.0326 (17)	0.0306 (16)	0.0060 (14)	0.0088 (14)	0.0010 (14)
O62	0.062 (2)	0.053 (2)	0.0354 (19)	0.0068 (19)	0.0108 (17)	−0.0020 (17)
O72	0.055 (2)	0.0296 (18)	0.058 (2)	0.0052 (16)	0.0198 (18)	−0.0044 (16)
O82	0.059 (2)	0.046 (2)	0.0376 (19)	0.0190 (18)	0.0133 (17)	0.0039 (16)
O92	0.0392 (19)	0.0346 (18)	0.0343 (17)	0.0042 (15)	0.0148 (14)	0.0028 (14)
O102	0.040 (2)	0.069 (3)	0.051 (2)	0.0003 (19)	0.0138 (17)	−0.0066 (19)
O112	0.057 (2)	0.0333 (19)	0.053 (2)	0.0067 (17)	0.0168 (18)	−0.0005 (16)
O122	0.0342 (18)	0.0310 (17)	0.0308 (16)	0.0021 (14)	0.0031 (14)	−0.0015 (13)
O132	0.046 (2)	0.0316 (18)	0.0423 (19)	−0.0017 (15)	0.0140 (16)	−0.0077 (15)
N1A	0.088 (4)	0.077 (4)	0.088 (4)	−0.039 (3)	0.033 (3)	−0.006 (3)
O1	0.116 (7)	0.050 (4)	0.049 (4)	−0.011 (4)	0.022 (4)	0.002 (3)
O3	0.121 (6)	0.127 (6)	0.131 (6)	−0.010 (5)	0.009 (4)	0.004 (5)
O2	0.093 (6)	0.057 (5)	0.086 (6)	−0.001 (4)	0.042 (4)	0.008 (4)
O1A	0.100 (15)	0.081 (12)	0.057 (10)	−0.002 (10)	0.028 (10)	0.013 (9)
O2A	0.128 (18)	0.14 (2)	0.115 (17)	−0.067 (16)	0.044 (14)	−0.038 (17)
O4	0.123 (5)	0.106 (5)	0.212 (7)	0.001 (4)	0.073 (5)	0.037 (5)

Geometric parameters (Å, º)

Co1—N11	1.928 (4)	Mo11—O31	1.931 (3)
Co1—N21	1.941 (4)	Mo11—O41^i	1.917 (3)
Co1—N31	1.933 (4)	Mo11—O121	2.417 (3)
Co1—N41	1.934 (4)	Mo11—O131^i	2.317 (3)
Co1—N51	1.926 (4)	Mo21—Mo41^i	3.2026 (7)
Co1—N61	1.933 (4)	Mo21—O41	1.907 (3)
N11—C11	1.342 (6)	Mo21—O51	1.694 (4)
N11—C51	1.353 (6)	Mo21—O61	1.989 (3)
N21—C61	1.361 (6)	Mo21—O71	1.695 (4)
N21—C101	1.336 (6)	Mo21—O91	2.380 (3)
C11—H11	0.9300	Mo21—O121^i	2.326 (3)
C11—C21	1.375 (7)	Mo31—O31	1.879 (3)
C21—H21	0.9300	Mo31—O61	2.333 (3)
C21—C31	1.379 (9)	Mo31—O81	1.700 (3)
C31—H31	0.9300	Mo31—O91	1.989 (3)
C31—C41	1.376 (8)	Mo31—O101	1.706 (3)
C41—H41	0.9300	Mo31—O121	2.340 (3)
C41—C51	1.377 (7)	Mo41—Mo21^i	3.2025 (7)
C51—C61	1.467 (7)	Mo41—O61^i	1.937 (3)
C61—C71	1.377 (7)	Mo41—O91	1.942 (3)
C71—H71	0.9300	Mo41—O111	1.691 (3)
C71—C81	1.373 (8)	Mo41—O121	2.157 (3)
C81—H81	0.9300	Mo41—O121^i	2.355 (3)
C81—C91	1.390 (8)	Mo41—O131	1.740 (3)
C91—H91	0.9300	O41—Mo11^i	1.916 (3)
C91—C101	1.375 (7)	O61—Mo41^i	1.937 (3)
C101—H101	0.9300	O121—Mo21^i	2.326 (3)
N31—C111	1.336 (6)	O121—Mo41^i	2.355 (3)
N31—C151	1.358 (6)	O131—Mo11^i	2.317 (3)
N41—C161	1.362 (6)	Mo12—O12	1.692 (3)
N41—C201	1.336 (6)	Mo12—O22	1.707 (4)
C111—H111	0.9300	Mo12—O32	1.840 (3)
C111—C121	1.382 (7)	Mo12—O42	1.918 (3)
C121—H121	0.9300	Mo12—O52	2.292 (3)
C121—C131	1.373 (8)	Mo22—O32	1.975 (3)
C131—H131	0.9300	Mo22—O52	2.152 (3)
C131—C141	1.374 (7)	Mo22—O62	1.687 (3)
C141—H141	0.9300	Mo22—O72	1.707 (3)
C141—C151	1.381 (6)	Mo22—O92	1.912 (3)
C151—C161	1.459 (6)	Mo22—O122	2.604 (3)
C161—C171	1.380 (7)	Mo32—O42^ii	2.017 (3)
C171—H171	0.9300	Mo32—O82	1.692 (3)
C171—C181	1.377 (8)	Mo32—O92	1.897 (3)
C181—H181	0.9300	Mo32—O102	1.693 (4)
C181—C191	1.359 (8)	Mo32—O122	2.228 (3)
C191—H191	0.9300	Mo32—O132	2.351 (3)
C191—C201	1.378 (8)	Mo42—O42^ii	2.245 (3)
C201—H201	0.9300	Mo42—O52^ii	1.896 (3)
N51—C211	1.341 (6)	Mo42—O112	1.694 (3)
N51—C251	1.367 (5)	Mo42—O122	1.881 (3)
N61—C261	1.351 (6)	Mo42—O132^ii	1.742 (3)
N61—C301	1.355 (6)	O42—Mo32^ii	2.017 (3)
C211—H211	0.9300	O42—Mo42^ii	2.245 (3)
C211—C221	1.375 (7)	O52—Mo42^ii	1.895 (3)
C221—H221	0.9300	O132—Mo42^ii	1.742 (3)
C221—C231	1.375 (7)	N1A—H1AA	1.0298
C231—H231	0.9300	N1A—H1AB	1.0287
C231—C241	1.381 (7)	N1A—H1AC	1.0293
C241—H241	0.9300	N1A—H1AD	1.0313
C241—C251	1.368 (6)	O1—H1A	0.8497
C251—C261	1.463 (6)	O1—H1B	0.8498
C261—C271	1.383 (6)	O3—H3A	0.8499
C271—H271	0.9300	O3—H3B	0.8477
C271—C281	1.392 (7)	O2—H2A	0.8499
C281—H281	0.9300	O2—H2B	0.8493
C281—C291	1.355 (7)	O1A—H1AE	0.8503
C291—H291	0.9300	O1A—H1AF	0.8497
C291—C301	1.373 (7)	O2A—H2AA	0.8502
C301—H301	0.9300	O2A—H2AB	0.8501
Mo11—O11	1.694 (4)	O4—H4A	0.8499
Mo11—O21	1.710 (3)	O4—H4B	0.8500
N11—Co1—N21	83.54 (17)	O51—Mo21—O61	99.82 (15)
N11—Co1—N31	87.27 (16)	O51—Mo21—O71	105.3 (2)
N11—Co1—N41	95.29 (17)	O51—Mo21—O91	88.78 (16)
N11—Co1—N61	93.67 (16)	O51—Mo21—O121^i	159.79 (16)
N31—Co1—N21	95.58 (16)	O61—Mo21—Mo41^i	34.80 (9)
N31—Co1—N41	83.47 (16)	O61—Mo21—O91	71.10 (11)
N41—Co1—N21	178.53 (16)	O61—Mo21—O121^i	73.44 (11)
N51—Co1—N11	176.53 (16)	O71—Mo21—Mo41^i	85.56 (13)
N51—Co1—N21	94.46 (16)	O71—Mo21—O41	102.08 (17)
N51—Co1—N31	95.76 (16)	O71—Mo21—O61	98.20 (16)
N51—Co1—N41	86.75 (16)	O71—Mo21—O91	163.80 (15)
N51—Co1—N61	83.39 (16)	O71—Mo21—O121^i	94.57 (15)
N61—Co1—N21	87.81 (16)	O91—Mo21—Mo41^i	78.79 (7)
N61—Co1—N31	176.56 (16)	O121^i—Mo21—Mo41^i	42.32 (7)
N61—Co1—N41	93.15 (17)	O121^i—Mo21—O91	71.02 (10)
C11—N11—Co1	126.5 (4)	O31—Mo31—O61	83.15 (12)
C11—N11—C51	119.3 (4)	O31—Mo31—O91	145.79 (13)
C51—N11—Co1	114.2 (3)	O31—Mo31—O121	76.56 (12)
C61—N21—Co1	113.6 (3)	O61—Mo31—O121	70.79 (10)
C101—N21—Co1	126.8 (3)	O81—Mo31—O31	101.66 (15)
C101—N21—C61	119.5 (4)	O81—Mo31—O61	88.83 (14)
N11—C11—H11	119.1	O81—Mo31—O91	101.10 (14)
N11—C11—C21	121.8 (5)	O81—Mo31—O101	104.56 (17)
C21—C11—H11	119.1	O81—Mo31—O121	159.62 (14)
C11—C21—H21	120.7	O91—Mo31—O61	72.13 (12)
C11—C21—C31	118.6 (6)	O91—Mo31—O121	73.22 (11)
C31—C21—H21	120.7	O101—Mo31—O31	102.13 (15)
C21—C31—H31	120.0	O101—Mo31—O61	164.06 (14)
C41—C31—C21	120.1 (5)	O101—Mo31—O91	96.43 (15)
C41—C31—H31	120.0	O101—Mo31—O121	95.59 (14)
C31—C41—H41	120.6	O61^i—Mo41—Mo21^i	35.88 (9)
C31—C41—C51	118.8 (6)	O61^i—Mo41—O91	149.98 (13)
C51—C41—H41	120.6	O61^i—Mo41—O121^i	77.53 (11)
N11—C51—C41	121.3 (5)	O61^i—Mo41—O121	78.45 (12)
N11—C51—C61	114.4 (4)	O91—Mo41—Mo21^i	125.03 (9)
C41—C51—C61	124.3 (5)	O91—Mo41—O121	78.47 (12)
N21—C61—C51	113.9 (4)	O91—Mo41—O121^i	78.37 (12)
N21—C61—C71	120.7 (5)	O111—Mo41—Mo21^i	89.07 (12)
C71—C61—C51	125.4 (5)	O111—Mo41—O61^i	101.31 (15)
C61—C71—H71	120.3	O111—Mo41—O91	100.71 (15)
C81—C71—C61	119.5 (5)	O111—Mo41—O121^i	173.81 (14)
C81—C71—H71	120.3	O111—Mo41—O121	98.10 (14)
C71—C81—H81	120.1	O111—Mo41—O131	104.73 (16)
C71—C81—C91	119.8 (5)	O121^i—Mo41—Mo21^i	86.53 (7)
C91—C81—H81	120.1	O121—Mo41—Mo21^i	46.56 (8)
C81—C91—H91	120.9	O121—Mo41—O121^i	75.71 (11)
C101—C91—C81	118.1 (6)	O131—Mo41—Mo21^i	132.63 (11)
C101—C91—H91	120.9	O131—Mo41—O61^i	96.76 (14)
N21—C101—C91	122.4 (5)	O131—Mo41—O91	97.09 (14)
N21—C101—H101	118.8	O131—Mo41—O121^i	81.45 (13)
C91—C101—H101	118.8	O131—Mo41—O121	157.17 (13)
C111—N31—Co1	127.0 (3)	Mo31—O31—Mo11	117.40 (17)
C111—N31—C151	118.7 (4)	Mo21—O41—Mo11^i	115.78 (16)
C151—N31—Co1	114.0 (3)	Mo21—O61—Mo31	104.44 (13)
C161—N41—Co1	113.8 (3)	Mo41^i—O61—Mo21	109.32 (15)
C201—N41—Co1	127.3 (4)	Mo41^i—O61—Mo31	111.37 (13)
C201—N41—C161	118.6 (4)	Mo31—O91—Mo21	102.77 (13)
N31—C111—H111	118.9	Mo41—O91—Mo21	109.71 (14)
N31—C111—C121	122.2 (5)	Mo41—O91—Mo31	110.25 (14)
C121—C111—H111	118.9	Mo21^i—O121—Mo11	86.11 (9)
C111—C121—H121	120.4	Mo21^i—O121—Mo31	162.60 (14)
C131—C121—C111	119.2 (5)	Mo21^i—O121—Mo41^i	98.36 (11)
C131—C121—H121	120.4	Mo31—O121—Mo11	86.33 (10)
C121—C131—H131	120.5	Mo31—O121—Mo41^i	97.63 (10)
C121—C131—C141	119.0 (5)	Mo41—O121—Mo11	162.99 (14)
C141—C131—H131	120.5	Mo41^i—O121—Mo11	92.72 (10)
C131—C141—H141	120.1	Mo41—O121—Mo21^i	91.12 (11)
C131—C141—C151	119.8 (5)	Mo41—O121—Mo31	91.54 (11)
C151—C141—H141	120.1	Mo41—O121—Mo41^i	104.29 (11)
N31—C151—C141	121.1 (4)	Mo41—O131—Mo11^i	115.95 (15)
N31—C151—C161	114.1 (4)	O12—Mo12—O22	105.33 (19)
C141—C151—C161	124.7 (4)	O12—Mo12—O32	110.09 (17)
N41—C161—C151	114.1 (4)	O12—Mo12—O42	111.89 (16)
N41—C161—C171	121.2 (5)	O12—Mo12—O52	94.54 (15)
C171—C161—C151	124.8 (5)	O22—Mo12—O32	100.39 (18)
C161—C171—H171	120.3	O22—Mo12—O42	98.24 (16)
C181—C171—C161	119.4 (5)	O22—Mo12—O52	160.09 (16)
C181—C171—H171	120.3	O32—Mo12—O42	127.01 (15)
C171—C181—H181	120.5	O32—Mo12—O52	73.22 (13)
C191—C181—C171	119.0 (5)	O42—Mo12—O52	72.65 (12)
C191—C181—H181	120.5	O32—Mo22—O52	74.09 (13)
C181—C191—H191	120.0	O32—Mo22—O122	85.43 (13)
C181—C191—C201	120.0 (5)	O52—Mo22—O122	66.48 (10)
C201—C191—H191	120.0	O62—Mo22—O32	101.66 (17)
N41—C201—C191	121.8 (5)	O62—Mo22—O52	101.24 (15)
N41—C201—H201	119.1	O62—Mo22—O72	106.52 (18)
C191—C201—H201	119.1	O62—Mo22—O92	99.29 (16)
C211—N51—Co1	127.6 (3)	O62—Mo22—O122	163.87 (15)
C211—N51—C251	117.9 (4)	O72—Mo22—O32	92.06 (16)
C251—N51—Co1	114.5 (3)	O72—Mo22—O52	151.01 (15)
C261—N61—Co1	114.2 (3)	O72—Mo22—O92	98.76 (15)
C261—N61—C301	119.5 (4)	O72—Mo22—O122	87.49 (14)
C301—N61—Co1	126.4 (3)	O92—Mo22—O32	152.57 (14)
N51—C211—H211	118.6	O92—Mo22—O52	84.65 (12)
N51—C211—C221	122.8 (5)	O92—Mo22—O122	70.07 (11)
C221—C211—H211	118.6	O42^ii—Mo32—O122	71.43 (12)
C211—C221—H221	120.5	O42^ii—Mo32—O132	81.49 (13)
C211—C221—C231	118.9 (5)	O82—Mo32—O42^ii	96.09 (15)
C231—C221—H221	120.5	O82—Mo32—O92	99.65 (15)
C221—C231—H231	120.4	O82—Mo32—O102	104.16 (19)
C221—C231—C241	119.2 (5)	O82—Mo32—O122	96.94 (15)
C241—C231—H231	120.4	O82—Mo32—O132	169.07 (15)
C231—C241—H241	120.3	O92—Mo32—O42^ii	148.47 (13)
C251—C241—C231	119.5 (5)	O92—Mo32—O122	79.64 (12)
C251—C241—H241	120.3	O92—Mo32—O132	77.89 (12)
N51—C251—C241	121.7 (4)	O102—Mo32—O42^ii	97.98 (15)
N51—C251—C261	113.3 (4)	O102—Mo32—O92	104.34 (16)
C241—C251—C261	124.9 (4)	O102—Mo32—O122	157.38 (15)
N61—C261—C251	114.6 (4)	O102—Mo32—O132	86.74 (16)
N61—C261—C271	121.2 (4)	O122—Mo32—O132	72.17 (11)
C271—C261—C251	124.1 (4)	O52^ii—Mo42—O42^ii	74.16 (12)
C261—C271—H271	120.7	O112—Mo42—O42^ii	95.29 (15)
C261—C271—C281	118.5 (5)	O112—Mo42—O52^ii	104.09 (15)
C281—C271—H271	120.7	O112—Mo42—O122	106.89 (16)
C271—C281—H281	120.1	O112—Mo42—O132^ii	103.79 (17)
C291—C281—C271	119.9 (5)	O122—Mo42—O42^ii	73.45 (12)
C291—C281—H281	120.1	O122—Mo42—O52^ii	136.62 (14)
C281—C291—H291	120.0	O132^ii—Mo42—O42^ii	160.88 (14)
C281—C291—C301	120.0 (5)	O132^ii—Mo42—O52^ii	101.84 (14)
C301—C291—H291	120.0	O132^ii—Mo42—O122	99.43 (14)
N61—C301—C291	121.0 (5)	Mo12—O32—Mo22	117.93 (17)
N61—C301—H301	119.5	Mo12—O42—Mo32^ii	140.54 (18)
C291—C301—H301	119.5	Mo12—O42—Mo42^ii	106.83 (14)
O11—Mo11—O21	104.56 (17)	Mo32^ii—O42—Mo42^ii	103.94 (13)
O11—Mo11—O31	99.14 (16)	Mo22—O52—Mo12	94.70 (12)
O11—Mo11—O41^i	99.59 (17)	Mo42^ii—O52—Mo12	105.78 (14)
O11—Mo11—O121	95.76 (14)	Mo42^ii—O52—Mo22	127.22 (15)
O11—Mo11—O131^i	165.63 (15)	Mo32—O92—Mo22	119.32 (16)
O21—Mo11—O31	101.82 (15)	Mo32—O122—Mo22	85.38 (10)
O21—Mo11—O41^i	102.25 (15)	Mo42—O122—Mo22	160.43 (16)
O21—Mo11—O121	159.67 (14)	Mo42—O122—Mo32	109.44 (13)
O21—Mo11—O131^i	89.81 (14)	Mo42^ii—O132—Mo32	117.07 (16)
O31—Mo11—O121	73.79 (11)	H1AA—N1A—H1AB	109.7
O31—Mo11—O131^i	77.10 (12)	H1AA—N1A—H1AC	109.5
O41^i—Mo11—O31	144.52 (13)	H1AA—N1A—H1AD	109.3
O41^i—Mo11—O121	74.56 (12)	H1AB—N1A—H1AC	109.5
O41^i—Mo11—O131^i	77.30 (13)	H1AB—N1A—H1AD	109.4
O131^i—Mo11—O121	69.87 (10)	H1AC—N1A—H1AD	109.4
O41—Mo21—Mo41^i	119.29 (10)	H1A—O1—H1B	104.5
O41—Mo21—O61	145.19 (13)	H3A—O3—H3B	104.7
O41—Mo21—O91	82.29 (12)	H2A—O2—H2B	104.3
O41—Mo21—O121^i	76.97 (12)	H1AE—O1A—H1AF	109.6
O51—Mo21—Mo41^i	134.56 (13)	H2AA—O2A—H2AB	104.3
O51—Mo21—O41	101.67 (17)	H4A—O4—H4B	104.6
Co1—N11—C11—C21	179.7 (4)	C161—C171—C181—C191	0.2 (8)
Co1—N11—C51—C41	−177.2 (3)	C171—C181—C191—C201	−0.8 (8)
Co1—N11—C51—C61	2.2 (5)	C181—C191—C201—N41	0.4 (8)
Co1—N21—C61—C51	−6.2 (5)	C201—N41—C161—C151	178.5 (4)
Co1—N21—C61—C71	175.1 (3)	C201—N41—C161—C171	−1.5 (7)
Co1—N21—C101—C91	−175.3 (4)	N51—C211—C221—C231	0.8 (8)
Co1—N31—C111—C121	−172.1 (4)	N51—C251—C261—N61	1.5 (6)
Co1—N31—C151—C141	172.8 (4)	N51—C251—C261—C271	178.8 (4)
Co1—N31—C151—C161	−5.5 (5)	N61—C261—C271—C281	−0.1 (7)
Co1—N41—C161—C151	−7.0 (5)	C211—N51—C251—C241	−0.9 (7)
Co1—N41—C161—C171	173.0 (4)	C211—N51—C251—C261	−178.9 (4)
Co1—N41—C201—C191	−172.9 (4)	C211—C221—C231—C241	−1.2 (8)
Co1—N51—C211—C221	−176.4 (4)	C221—C231—C241—C251	0.6 (7)
Co1—N51—C251—C241	176.2 (3)	C231—C241—C251—N51	0.5 (7)
Co1—N51—C251—C261	−1.8 (5)	C231—C241—C251—C261	178.2 (4)
Co1—N61—C261—C251	−0.5 (5)	C241—C251—C261—N61	−176.4 (4)
Co1—N61—C261—C271	−177.9 (4)	C241—C251—C261—C271	0.9 (7)
Co1—N61—C301—C291	177.4 (4)	C251—N51—C211—C221	0.3 (7)
N11—C11—C21—C31	−1.6 (8)	C251—C261—C271—C281	−177.2 (5)
N11—C51—C61—N21	2.7 (5)	C261—N61—C301—C291	−1.1 (8)
N11—C51—C61—C71	−178.7 (4)	C261—C271—C281—C291	−0.4 (8)
N21—C61—C71—C81	0.9 (7)	C271—C281—C291—C301	0.2 (9)
C11—N11—C51—C41	3.7 (7)	C281—C291—C301—N61	0.6 (9)
C11—N11—C51—C61	−176.9 (4)	C301—N61—C261—C251	178.2 (4)
C11—C21—C31—C41	2.2 (8)	C301—N61—C261—C271	0.8 (7)
C21—C31—C41—C51	0.0 (8)	Mo21^i—Mo41—O131—Mo11^i	−77.48 (19)
C31—C41—C51—N11	−3.0 (7)	O61—Mo31—O31—Mo11	−94.10 (18)
C31—C41—C51—C61	177.6 (5)	O61^i—Mo41—O131—Mo11^i	−76.53 (17)
C41—C51—C61—N21	−177.9 (4)	O81—Mo31—O31—Mo11	178.52 (18)
C41—C51—C61—C71	0.7 (7)	O91—Mo31—O31—Mo11	−50.7 (3)
C51—N11—C11—C21	−1.4 (7)	O91—Mo41—O131—Mo11^i	76.77 (17)
C51—C61—C71—C81	−177.6 (5)	O101—Mo31—O31—Mo11	70.6 (2)
C61—N21—C101—C91	0.1 (7)	O111—Mo41—O131—Mo11^i	179.86 (17)
C61—C71—C81—C91	−0.1 (8)	O121—Mo31—O31—Mo11	−22.28 (16)
C71—C81—C91—C101	−0.6 (8)	O121^i—Mo41—O131—Mo11^i	−0.27 (14)
C81—C91—C101—N21	0.6 (8)	O121—Mo41—O131—Mo11^i	−0.3 (4)
C101—N21—C61—C51	177.8 (4)	O12—Mo12—O32—Mo22	90.8 (2)
C101—N21—C61—C71	−0.9 (7)	O22—Mo12—O32—Mo22	−158.5 (2)
N31—C111—C121—C131	0.0 (9)	O42—Mo12—O32—Mo22	−49.8 (3)
N31—C151—C161—N41	8.2 (6)	O42^ii—Mo32—O92—Mo22	−46.6 (3)
N31—C151—C161—C171	−171.8 (5)	O42^ii—Mo42—O122—Mo22	147.5 (5)
N41—C161—C171—C181	1.0 (8)	O42^ii—Mo42—O122—Mo32	9.94 (13)
C111—N31—C151—C141	−0.9 (7)	O52—Mo12—O32—Mo22	2.05 (16)
C111—N31—C151—C161	−179.2 (4)	O52^ii—Mo42—O122—Mo22	−169.3 (4)
C111—C121—C131—C141	−0.6 (8)	O52^ii—Mo42—O122—Mo32	53.1 (2)
C121—C131—C141—C151	0.4 (8)	O82—Mo32—O92—Mo22	72.2 (2)
C131—C141—C151—N31	0.3 (7)	O102—Mo32—O92—Mo22	179.68 (19)
C131—C141—C151—C161	178.4 (5)	O112—Mo42—O122—Mo22	56.9 (5)
C141—C151—C161—N41	−170.0 (4)	O112—Mo42—O122—Mo32	−80.65 (18)
C141—C151—C161—C171	9.9 (8)	O122—Mo32—O92—Mo22	−23.12 (16)
C151—N31—C111—C121	0.8 (8)	O132—Mo32—O92—Mo22	−96.91 (18)
C151—C161—C171—C181	−179.0 (5)	O132^ii—Mo42—O122—Mo22	−50.7 (5)
C161—N41—C201—C191	0.8 (7)	O132^ii—Mo42—O122—Mo32	171.72 (15)

Symmetry codes: (i) −x+2, −y−1, −z+1; (ii) −x+1, −y+1, −z.

Bis[tris(2,2'-bipyridine)cobaltate(II)] sesqui(octamolydate) dodecahydrate (3)

Crystal data

[Co(C10H8N2)3]2[{Mo8O26}0.5{Mo8O26}]·12H2O	F(000) = 5928
Mr = 3046.43	Dx = 2.216 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71069 Å
a = 11.151 (4) Å	Cell parameters from 17236 reflections
b = 21.972 (6) Å	θ = 1.9–25.2°
c = 37.570 (3) Å	µ = 2.04 mm^−1
β = 97.218 (16)°	T = 298 K
V = 9132 (4) Å^3	Needle, light orange
Z = 4	0.55 × 0.09 × 0.01 mm

Data collection

Rigaku AFC-7S/Mercury (2x2 bin mode) diffractometer	Rint = 0.138
Absorption correction: multi-scan (CrystalClear; Rigaku, 2005)	θmax = 25.2°, θmin = 1.9°
Tmin = 0.820, Tmax = 0.950	h = 0→13
17236 measured reflections	k = 0→26
16166 independent reflections	l = −44→44
7572 reflections with I > 2σ(I)

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.067	H-atom parameters constrained
wR(F^2) = 0.158	w = 1/[σ^2(Fo^2) + (0.0565P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.96	(Δ/σ)max = 0.001
16166 reflections	Δρmax = 0.84 e Å^−3
1126 parameters	Δρmin = −0.82 e Å^−3
522 restraints

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Co1	1.75256 (15)	0.76900 (8)	1.12418 (5)	0.0374 (4)
N11	1.6058 (10)	0.7952 (4)	1.1425 (3)	0.042 (3)
N21	1.6416 (9)	0.7353 (4)	1.0869 (3)	0.034 (2)
C11	1.5984 (15)	0.8254 (7)	1.1723 (4)	0.067 (4)
H11	1.6677	0.8314	1.1885	0.081*
C21	1.4894 (15)	0.8484 (7)	1.1801 (5)	0.066 (4)
H21	1.4876	0.8723	1.2004	0.079*
C31	1.3866 (15)	0.8369 (7)	1.1590 (5)	0.073 (5)
H31	1.3131	0.8513	1.1648	0.087*
C41	1.3923 (13)	0.8027 (6)	1.1282 (4)	0.057 (4)
H41	1.3223	0.7935	1.1130	0.069*
C51	1.5029 (12)	0.7827 (6)	1.1204 (4)	0.039 (3)
C61	1.5220 (11)	0.7466 (6)	1.0884 (4)	0.043 (3)
C71	1.4333 (12)	0.7250 (7)	1.0638 (4)	0.054 (4)
H71	1.3526	0.7312	1.0667	0.065*
C81	1.4633 (12)	0.6936 (6)	1.0343 (4)	0.053 (4)
H81	1.4030	0.6808	1.0165	0.064*
C91	1.5809 (11)	0.6815 (6)	1.0313 (4)	0.046 (3)
H91	1.6022	0.6596	1.0119	0.055*
C101	1.6690 (11)	0.7026 (6)	1.0580 (3)	0.043 (3)
H101	1.7496	0.6941	1.0561	0.051*
N31	1.7603 (9)	0.6898 (5)	1.1465 (3)	0.039 (2)
N41	1.8961 (9)	0.7411 (5)	1.1048 (3)	0.039 (2)
C111	1.6844 (13)	0.6693 (6)	1.1692 (4)	0.052 (4)
H111	1.6235	0.6948	1.1752	0.062*
C121	1.6948 (12)	0.6118 (6)	1.1836 (4)	0.051 (4)
H121	1.6406	0.5979	1.1987	0.061*
C131	1.7897 (12)	0.5746 (7)	1.1750 (4)	0.052 (3)
H131	1.8002	0.5359	1.1849	0.062*
C141	1.8668 (11)	0.5952 (6)	1.1518 (3)	0.040 (3)
H141	1.9270	0.5706	1.1445	0.049*
C151	1.8502 (11)	0.6552 (6)	1.1399 (3)	0.037 (3)
C161	1.9323 (11)	0.6823 (6)	1.1159 (4)	0.042 (3)
C171	2.0327 (11)	0.6577 (6)	1.1052 (4)	0.045 (3)
H171	2.0572	0.6190	1.1130	0.055*
C181	2.0988 (14)	0.6892 (7)	1.0829 (4)	0.065 (4)
H181	2.1663	0.6711	1.0751	0.078*
C191	2.0664 (13)	0.7472 (7)	1.0719 (4)	0.067 (4)
H191	2.1100	0.7696	1.0569	0.081*
C201	1.9639 (11)	0.7700 (6)	1.0848 (4)	0.047 (3)
H201	1.9418	0.8098	1.0785	0.056*
N51	1.8594 (9)	0.8074 (5)	1.1623 (3)	0.040 (3)
N61	1.7521 (9)	0.8495 (5)	1.1026 (3)	0.041 (3)
C211	1.6938 (12)	0.8641 (6)	1.0704 (4)	0.054 (4)
H211	1.6565	0.8338	1.0557	0.064*
C221	1.6886 (14)	0.9251 (7)	1.0588 (4)	0.067 (5)
H221	1.6494	0.9359	1.0364	0.080*
C231	1.7443 (14)	0.9685 (7)	1.0821 (5)	0.073 (5)
H231	1.7399	1.0093	1.0756	0.088*
C241	1.8041 (13)	0.9524 (6)	1.1138 (4)	0.062 (4)
H241	1.8445	0.9817	1.1286	0.074*
C251	1.8061 (11)	0.8916 (6)	1.1247 (4)	0.041 (3)
C261	1.8710 (13)	0.8692 (6)	1.1568 (4)	0.049 (3)
C271	1.9405 (14)	0.9027 (6)	1.1829 (4)	0.061 (4)
H271	1.9459	0.9447	1.1801	0.074*
C281	2.0005 (14)	0.8762 (6)	1.2121 (4)	0.063 (4)
H281	2.0443	0.8995	1.2299	0.076*
C291	1.9954 (14)	0.8119 (6)	1.2151 (4)	0.058 (4)
H291	2.0425	0.7919	1.2337	0.070*
C301	1.9210 (11)	0.7799 (6)	1.1905 (3)	0.043 (3)
H301	1.9129	0.7381	1.1934	0.051*
Co2	1.41575 (15)	0.64239 (8)	0.85112 (5)	0.0366 (4)
N12	1.5565 (9)	0.6117 (5)	0.8325 (3)	0.038 (3)
N22	1.4203 (8)	0.5657 (5)	0.8755 (3)	0.038 (2)
C12	1.3448 (12)	0.5453 (7)	0.8975 (4)	0.054 (4)
H12	1.2804	0.5699	0.9019	0.064*
C22	1.3575 (13)	0.4897 (7)	0.9138 (4)	0.063 (4)
H22	1.3081	0.4787	0.9310	0.076*
C32	1.4447 (12)	0.4503 (7)	0.9046 (4)	0.058 (4)
H32	1.4492	0.4107	0.9135	0.069*
C42	1.5251 (12)	0.4704 (6)	0.8822 (4)	0.050 (4)
H42	1.5877	0.4455	0.8767	0.060*
C52	1.5108 (10)	0.5279 (6)	0.8680 (3)	0.036 (3)
C62	1.5894 (10)	0.5527 (5)	0.8442 (3)	0.031 (3)
C72	1.6904 (10)	0.5254 (6)	0.8344 (3)	0.037 (3)
H72	1.7135	0.4869	0.8430	0.044*
C82	1.7596 (12)	0.5567 (6)	0.8111 (4)	0.045 (3)
H82	1.8286	0.5392	0.8039	0.054*
C92	1.7225 (11)	0.6128 (6)	0.7996 (3)	0.039 (3)
H92	1.7657	0.6334	0.7837	0.047*
C102	1.6234 (11)	0.6401 (6)	0.8106 (4)	0.046 (3)
H102	1.6022	0.6791	0.8026	0.055*
N32	1.2704 (9)	0.6721 (5)	0.8697 (3)	0.043 (3)
N42	1.3033 (9)	0.6070 (5)	0.8129 (3)	0.044 (3)
C112	1.3274 (13)	0.5730 (7)	0.7860 (4)	0.055 (4)
H112	1.4077	0.5628	0.7847	0.066*
C122	1.2425 (13)	0.5517 (6)	0.7600 (4)	0.054 (3)
H122	1.2637	0.5289	0.7409	0.064*
C132	1.1226 (14)	0.5652 (7)	0.7630 (5)	0.062 (4)
H132	1.0617	0.5516	0.7456	0.075*
C142	1.0943 (14)	0.5983 (7)	0.7914 (4)	0.062 (4)
H142	1.0139	0.6063	0.7939	0.075*
C152	1.1852 (12)	0.6199 (6)	0.8164 (4)	0.049 (3)
C162	1.1681 (12)	0.6563 (6)	0.8468 (4)	0.050 (3)
C172	1.0565 (13)	0.6791 (7)	0.8543 (5)	0.062 (4)
H172	0.9870	0.6698	0.8389	0.074*
C182	1.0476 (14)	0.7133 (7)	0.8825 (5)	0.068 (4)
H182	0.9727	0.7279	0.8870	0.081*
C192	1.1517 (13)	0.7276 (7)	0.9058 (5)	0.065 (4)
H192	1.1474	0.7513	0.9260	0.077*
C202	1.2621 (13)	0.7054 (6)	0.8977 (4)	0.056 (4)
H202	1.3320	0.7147	0.9129	0.067*
N52	1.5255 (9)	0.6829 (5)	0.8880 (3)	0.039 (2)
N62	1.4172 (9)	0.7222 (5)	0.8274 (3)	0.040 (2)
C212	1.3606 (11)	0.7379 (6)	0.7946 (4)	0.043 (3)
H212	1.3231	0.7077	0.7798	0.052*
C222	1.3573 (11)	0.7965 (6)	0.7829 (4)	0.050 (3)
H222	1.3158	0.8058	0.7606	0.060*
C232	1.4128 (12)	0.8407 (7)	0.8030 (4)	0.058 (4)
H232	1.4110	0.8806	0.7947	0.070*
C242	1.4727 (12)	0.8264 (6)	0.8363 (4)	0.049 (3)
H242	1.5095	0.8568	0.8510	0.058*
C252	1.4777 (11)	0.7640 (6)	0.8480 (4)	0.042 (3)
C262	1.5471 (12)	0.7416 (6)	0.8810 (4)	0.045 (3)
C272	1.6220 (14)	0.7779 (7)	0.9037 (4)	0.064 (4)
H272	1.6273	0.8197	0.9003	0.077*
C282	1.6905 (14)	0.7476 (8)	0.9326 (4)	0.069 (4)
H282	1.7447	0.7701	0.9482	0.083*
C292	1.6802 (13)	0.6866 (7)	0.9385 (4)	0.061 (4)
H292	1.7285	0.6671	0.9570	0.073*
C302	1.5925 (11)	0.6541 (6)	0.9150 (4)	0.043 (3)
H302	1.5816	0.6127	0.9185	0.052*
Mo11	2.08449 (10)	0.61474 (5)	0.97642 (3)	0.0359 (3)
Mo21	2.09333 (9)	0.45357 (5)	0.97588 (3)	0.0322 (3)
Mo31	1.77837 (10)	0.47473 (5)	0.95537 (3)	0.0371 (3)
Mo41	1.95681 (10)	0.54335 (5)	0.90550 (3)	0.0378 (3)
O11	1.9406 (7)	0.4099 (3)	0.9742 (2)	0.031 (2)
O21	2.1927 (6)	0.5232 (3)	0.9908 (2)	0.032 (2)
O31	1.9483 (7)	0.5343 (4)	0.9709 (2)	0.038 (2)
O41	2.0831 (7)	0.4668 (4)	0.9295 (2)	0.035 (2)
O51	1.8559 (7)	0.6004 (4)	0.8992 (2)	0.042 (2)
O61	2.1948 (7)	0.3957 (4)	0.9837 (2)	0.049 (3)
O71	1.8469 (7)	0.4791 (4)	0.9116 (2)	0.042 (2)
O81	2.0930 (7)	0.5886 (4)	0.9294 (2)	0.040 (2)
O91	1.6927 (8)	0.4114 (4)	0.9481 (2)	0.052 (3)
O101	1.9769 (8)	0.6695 (4)	0.9706 (3)	0.051 (3)
O111	1.6795 (8)	0.5326 (4)	0.9504 (2)	0.052 (3)
O121	1.9998 (8)	0.5301 (4)	0.8642 (2)	0.050 (3)
O131	2.2169 (8)	0.6546 (4)	0.9845 (3)	0.055 (3)
Mo12	1.80744 (11)	0.83389 (5)	0.68237 (3)	0.0425 (3)
Mo22	1.75942 (10)	0.82340 (5)	0.79815 (3)	0.0363 (3)
Mo32	1.92628 (10)	0.92835 (5)	0.75258 (3)	0.0393 (3)
Mo42	1.95616 (10)	0.76693 (5)	0.75208 (3)	0.0388 (3)
Mo52	2.06600 (10)	0.86137 (6)	0.82162 (3)	0.0420 (3)
Mo62	1.61683 (10)	0.89448 (5)	0.73052 (3)	0.0414 (3)
Mo72	1.72860 (12)	0.98142 (6)	0.80129 (4)	0.0482 (3)
Mo82	1.86658 (11)	0.91178 (6)	0.87151 (4)	0.0516 (4)
O12	1.6476 (7)	0.8899 (4)	0.7840 (2)	0.039 (2)
O22	1.9538 (7)	0.7950 (4)	0.7048 (2)	0.037 (2)
O32	1.9939 (7)	0.8566 (4)	0.8652 (2)	0.047 (2)
O42	1.8014 (6)	0.8423 (3)	0.7461 (2)	0.031 (2)
O52	2.0403 (7)	0.8644 (4)	0.7681 (2)	0.038 (2)
O62	1.7670 (7)	0.9655 (4)	0.7515 (2)	0.038 (2)
O72	1.9205 (7)	0.7871 (4)	0.8014 (2)	0.039 (2)
O82	1.8831 (7)	0.9102 (4)	0.8058 (2)	0.037 (2)
O92	1.9249 (8)	0.9159 (4)	0.7071 (2)	0.044 (2)
O102	1.6886 (7)	0.8953 (4)	0.6878 (2)	0.045 (2)
O112	1.7233 (8)	0.9507 (4)	0.8482 (2)	0.050 (3)
O122	1.6686 (7)	0.7626 (4)	0.7874 (2)	0.045 (2)
O132	1.7612 (7)	0.8336 (4)	0.8444 (2)	0.046 (2)
O142	2.0979 (7)	0.7364 (4)	0.7599 (3)	0.053 (3)
O152	2.1664 (7)	0.8046 (4)	0.8290 (3)	0.055 (3)
O162	2.0160 (8)	0.9897 (4)	0.7619 (2)	0.051 (3)
O172	1.8485 (9)	0.8483 (5)	0.6416 (2)	0.061 (3)
O182	1.5866 (9)	1.0113 (5)	0.7938 (3)	0.074 (3)
O192	1.8634 (8)	0.7062 (4)	0.7469 (2)	0.047 (2)
O202	2.1494 (8)	0.9265 (4)	0.8276 (2)	0.055 (3)
O212	1.8258 (9)	0.8914 (5)	0.9122 (3)	0.066 (3)
O222	1.8208 (9)	1.0409 (4)	0.8106 (3)	0.067 (3)
O232	1.5232 (8)	0.9535 (4)	0.7240 (3)	0.062 (3)
O242	1.5242 (8)	0.8325 (4)	0.7246 (3)	0.056 (3)
O252	1.7158 (8)	0.7719 (4)	0.6763 (3)	0.058 (3)
O262	1.9483 (9)	0.9763 (5)	0.8792 (3)	0.071 (3)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Co1	0.0381 (10)	0.0285 (10)	0.0450 (12)	−0.0025 (8)	0.0032 (9)	−0.0017 (9)
N11	0.054 (5)	0.026 (5)	0.045 (6)	0.007 (4)	0.006 (4)	0.002 (4)
N21	0.036 (4)	0.031 (5)	0.037 (5)	−0.009 (4)	0.009 (4)	−0.002 (4)
C11	0.072 (7)	0.071 (10)	0.060 (7)	0.009 (7)	0.012 (6)	−0.022 (7)
C21	0.080 (7)	0.050 (9)	0.071 (9)	0.008 (7)	0.026 (6)	−0.005 (7)
C31	0.073 (8)	0.075 (11)	0.075 (9)	0.017 (7)	0.030 (6)	−0.017 (8)
C41	0.057 (6)	0.055 (8)	0.064 (8)	0.016 (5)	0.023 (5)	0.001 (6)
C51	0.049 (5)	0.031 (6)	0.040 (6)	0.004 (4)	0.014 (4)	0.003 (5)
C61	0.036 (5)	0.045 (7)	0.049 (6)	−0.010 (4)	0.010 (4)	−0.007 (5)
C71	0.039 (6)	0.066 (9)	0.058 (7)	−0.014 (5)	0.009 (5)	−0.015 (6)
C81	0.043 (6)	0.062 (9)	0.055 (7)	−0.015 (5)	0.005 (5)	−0.015 (6)
C91	0.041 (5)	0.048 (8)	0.049 (7)	−0.013 (5)	0.006 (5)	−0.015 (6)
C101	0.036 (6)	0.047 (8)	0.046 (6)	−0.006 (5)	0.004 (5)	−0.015 (6)
N31	0.040 (5)	0.035 (5)	0.041 (6)	−0.007 (4)	0.003 (4)	0.000 (4)
N41	0.033 (5)	0.036 (5)	0.047 (6)	−0.002 (4)	0.006 (4)	−0.004 (4)
C111	0.061 (7)	0.041 (6)	0.057 (8)	0.000 (5)	0.021 (6)	0.006 (6)
C121	0.054 (7)	0.041 (6)	0.061 (9)	−0.003 (5)	0.016 (6)	0.007 (6)
C131	0.048 (7)	0.045 (6)	0.062 (8)	−0.002 (5)	0.002 (6)	0.002 (6)
C141	0.032 (6)	0.041 (5)	0.046 (7)	−0.006 (4)	−0.003 (5)	−0.013 (5)
C151	0.038 (5)	0.039 (5)	0.032 (6)	−0.011 (4)	−0.008 (4)	−0.017 (4)
C161	0.040 (5)	0.034 (5)	0.052 (7)	0.000 (4)	0.003 (5)	−0.005 (5)
C171	0.037 (6)	0.043 (6)	0.053 (8)	−0.007 (4)	−0.004 (5)	−0.026 (5)
C181	0.058 (8)	0.064 (7)	0.073 (10)	−0.008 (6)	0.016 (7)	−0.015 (6)
C191	0.053 (7)	0.072 (8)	0.081 (10)	−0.007 (6)	0.026 (7)	−0.007 (7)
C201	0.043 (6)	0.045 (6)	0.052 (8)	−0.016 (5)	0.009 (6)	−0.003 (6)
N51	0.050 (6)	0.031 (5)	0.035 (6)	−0.005 (4)	−0.010 (5)	−0.003 (4)
N61	0.044 (6)	0.031 (5)	0.046 (6)	0.000 (4)	−0.008 (4)	0.007 (4)
C211	0.061 (9)	0.039 (6)	0.056 (7)	−0.009 (6)	−0.013 (6)	0.016 (5)
C221	0.081 (11)	0.045 (6)	0.064 (8)	−0.011 (6)	−0.030 (7)	0.025 (5)
C231	0.079 (11)	0.051 (7)	0.084 (9)	−0.014 (6)	−0.018 (7)	0.013 (6)
C241	0.065 (9)	0.041 (6)	0.075 (8)	−0.008 (5)	−0.011 (7)	0.006 (5)
C251	0.039 (6)	0.031 (5)	0.051 (6)	−0.002 (4)	0.005 (5)	0.000 (4)
C261	0.062 (8)	0.027 (5)	0.054 (6)	−0.001 (5)	−0.005 (5)	−0.003 (4)
C271	0.095 (10)	0.028 (6)	0.054 (7)	−0.021 (6)	−0.014 (7)	0.008 (5)
C281	0.095 (10)	0.038 (6)	0.051 (7)	−0.014 (6)	−0.011 (7)	0.001 (5)
C291	0.081 (9)	0.045 (6)	0.042 (7)	−0.012 (6)	−0.022 (7)	0.008 (5)
C301	0.057 (8)	0.029 (6)	0.037 (6)	−0.002 (5)	−0.014 (5)	−0.002 (4)
Co2	0.0292 (9)	0.0346 (10)	0.0466 (12)	0.0022 (8)	0.0075 (8)	0.0078 (9)
N12	0.035 (5)	0.035 (5)	0.045 (6)	0.002 (4)	0.004 (4)	0.008 (4)
N22	0.030 (5)	0.034 (5)	0.050 (6)	0.001 (4)	0.004 (4)	0.012 (4)
C12	0.033 (6)	0.062 (7)	0.067 (9)	0.004 (5)	0.009 (6)	0.028 (6)
C22	0.056 (8)	0.064 (7)	0.071 (10)	−0.002 (6)	0.014 (7)	0.032 (7)
C32	0.045 (7)	0.052 (7)	0.074 (9)	−0.002 (5)	0.000 (6)	0.026 (6)
C42	0.046 (7)	0.037 (6)	0.066 (9)	−0.005 (5)	0.000 (6)	0.011 (5)
C52	0.025 (5)	0.034 (5)	0.046 (7)	−0.001 (4)	0.000 (5)	0.007 (5)
C62	0.028 (5)	0.027 (5)	0.037 (6)	−0.002 (4)	−0.002 (4)	0.000 (4)
C72	0.035 (5)	0.034 (6)	0.040 (7)	−0.002 (4)	−0.001 (5)	0.001 (5)
C82	0.039 (6)	0.042 (6)	0.057 (8)	−0.001 (5)	0.017 (6)	0.002 (5)
C92	0.039 (6)	0.040 (6)	0.038 (7)	−0.007 (5)	0.009 (5)	−0.004 (5)
C102	0.047 (6)	0.041 (6)	0.053 (8)	0.000 (5)	0.017 (6)	0.006 (5)
N32	0.035 (5)	0.036 (6)	0.059 (6)	0.005 (4)	0.016 (4)	0.012 (5)
N42	0.032 (5)	0.040 (6)	0.059 (7)	0.000 (4)	0.001 (4)	0.014 (5)
C112	0.047 (6)	0.055 (8)	0.062 (8)	0.001 (6)	−0.001 (5)	0.001 (6)
C122	0.058 (6)	0.045 (8)	0.054 (7)	−0.008 (6)	−0.008 (5)	0.024 (6)
C132	0.060 (7)	0.053 (8)	0.070 (8)	−0.014 (6)	−0.007 (6)	0.022 (6)
C142	0.049 (6)	0.056 (8)	0.079 (8)	−0.012 (6)	−0.005 (5)	0.020 (6)
C152	0.037 (5)	0.042 (7)	0.069 (7)	0.001 (5)	0.006 (4)	0.017 (5)
C162	0.034 (5)	0.049 (7)	0.069 (7)	−0.003 (5)	0.013 (4)	0.018 (5)
C172	0.042 (6)	0.059 (9)	0.086 (9)	0.007 (5)	0.018 (5)	0.021 (7)
C182	0.059 (7)	0.061 (9)	0.087 (9)	0.023 (6)	0.024 (6)	0.026 (7)
C192	0.063 (7)	0.060 (9)	0.077 (9)	0.017 (6)	0.030 (6)	0.015 (7)
C202	0.062 (7)	0.045 (8)	0.064 (8)	0.007 (6)	0.023 (5)	0.008 (6)
N52	0.034 (5)	0.032 (5)	0.053 (6)	0.005 (4)	0.010 (4)	0.000 (4)
N62	0.030 (5)	0.043 (5)	0.048 (5)	−0.001 (4)	0.010 (4)	0.004 (4)
C212	0.030 (6)	0.052 (6)	0.050 (6)	0.007 (5)	0.015 (5)	0.009 (5)
C222	0.035 (7)	0.054 (6)	0.063 (8)	0.004 (5)	0.011 (6)	0.017 (5)
C232	0.051 (8)	0.054 (7)	0.071 (8)	0.007 (5)	0.013 (6)	0.011 (5)
C242	0.046 (7)	0.034 (5)	0.068 (7)	0.001 (5)	0.015 (6)	0.001 (5)
C252	0.040 (6)	0.035 (5)	0.053 (6)	0.004 (4)	0.012 (5)	−0.001 (4)
C262	0.045 (6)	0.037 (5)	0.053 (6)	−0.002 (4)	0.011 (5)	−0.001 (4)
C272	0.076 (9)	0.049 (7)	0.065 (8)	−0.009 (6)	−0.003 (6)	−0.004 (5)
C282	0.063 (9)	0.075 (7)	0.065 (9)	−0.008 (6)	−0.009 (7)	−0.001 (6)
C292	0.056 (8)	0.073 (7)	0.051 (8)	0.002 (6)	0.000 (6)	0.004 (6)
C302	0.035 (6)	0.048 (6)	0.048 (7)	0.020 (5)	0.012 (5)	−0.003 (5)
Mo11	0.0369 (6)	0.0326 (6)	0.0372 (7)	−0.0061 (5)	0.0009 (5)	0.0035 (6)
Mo21	0.0284 (6)	0.0340 (6)	0.0349 (7)	0.0030 (5)	0.0069 (5)	−0.0002 (6)
Mo31	0.0296 (6)	0.0404 (7)	0.0397 (8)	−0.0035 (5)	−0.0017 (5)	0.0059 (6)
Mo41	0.0376 (7)	0.0401 (7)	0.0357 (7)	0.0010 (6)	0.0042 (6)	0.0035 (6)
O11	0.035 (5)	0.033 (5)	0.025 (5)	−0.007 (4)	0.003 (4)	−0.008 (4)
O21	0.023 (4)	0.025 (4)	0.051 (6)	−0.006 (4)	0.013 (4)	0.000 (4)
O31	0.030 (5)	0.051 (6)	0.033 (5)	0.002 (4)	0.001 (4)	0.002 (4)
O41	0.031 (5)	0.048 (5)	0.026 (5)	−0.004 (4)	0.003 (4)	0.007 (4)
O51	0.050 (5)	0.036 (5)	0.039 (6)	0.002 (4)	0.004 (5)	0.015 (4)
O61	0.032 (5)	0.055 (6)	0.058 (7)	0.016 (5)	−0.004 (5)	0.003 (5)
O71	0.051 (6)	0.051 (6)	0.024 (5)	−0.006 (5)	0.003 (4)	0.003 (4)
O81	0.039 (5)	0.043 (5)	0.040 (6)	−0.017 (4)	0.015 (4)	0.002 (4)
O91	0.060 (6)	0.043 (6)	0.051 (6)	−0.017 (5)	−0.006 (5)	0.013 (5)
O101	0.055 (6)	0.034 (5)	0.062 (7)	0.010 (5)	0.001 (5)	0.007 (5)
O111	0.048 (6)	0.066 (7)	0.039 (6)	−0.006 (5)	−0.005 (5)	0.002 (5)
O121	0.049 (6)	0.057 (6)	0.046 (6)	−0.006 (5)	0.011 (5)	−0.003 (5)
O131	0.045 (6)	0.055 (6)	0.060 (7)	−0.020 (5)	−0.009 (5)	0.016 (5)
Mo12	0.0484 (7)	0.0378 (7)	0.0411 (8)	−0.0036 (6)	0.0044 (6)	0.0017 (6)
Mo22	0.0322 (6)	0.0331 (7)	0.0445 (8)	−0.0024 (5)	0.0077 (6)	0.0021 (6)
Mo32	0.0424 (7)	0.0278 (6)	0.0473 (8)	−0.0051 (5)	0.0044 (6)	0.0037 (6)
Mo42	0.0394 (7)	0.0307 (7)	0.0473 (8)	0.0005 (5)	0.0092 (6)	0.0046 (6)
Mo52	0.0327 (6)	0.0450 (8)	0.0470 (8)	−0.0014 (6)	0.0002 (6)	0.0033 (6)
Mo62	0.0379 (7)	0.0372 (7)	0.0475 (8)	0.0008 (6)	−0.0007 (6)	0.0003 (6)
Mo72	0.0516 (8)	0.0375 (7)	0.0541 (9)	0.0089 (6)	0.0014 (7)	−0.0047 (6)
Mo82	0.0476 (8)	0.0579 (9)	0.0489 (9)	0.0025 (7)	0.0038 (7)	−0.0057 (7)
O12	0.030 (5)	0.055 (6)	0.032 (5)	0.012 (4)	0.002 (4)	−0.006 (5)
O22	0.044 (5)	0.033 (5)	0.037 (5)	0.000 (4)	0.018 (4)	0.013 (4)
O32	0.044 (5)	0.056 (6)	0.040 (6)	0.003 (5)	0.001 (5)	0.011 (5)
O42	0.031 (5)	0.024 (4)	0.038 (5)	−0.002 (4)	0.010 (4)	0.009 (4)
O52	0.030 (5)	0.035 (5)	0.050 (6)	−0.014 (4)	0.010 (4)	−0.006 (4)
O62	0.046 (5)	0.035 (5)	0.035 (5)	0.006 (4)	0.005 (4)	0.013 (4)
O72	0.049 (5)	0.035 (5)	0.034 (5)	−0.003 (4)	0.007 (4)	0.007 (4)
O82	0.034 (5)	0.031 (5)	0.046 (6)	0.000 (4)	0.003 (4)	−0.008 (4)
O92	0.052 (6)	0.043 (6)	0.037 (6)	0.000 (5)	0.011 (5)	0.008 (5)
O102	0.039 (5)	0.049 (6)	0.044 (6)	0.005 (4)	−0.006 (4)	0.012 (5)
O112	0.045 (5)	0.069 (7)	0.033 (6)	0.008 (5)	−0.001 (4)	−0.019 (5)
O122	0.045 (5)	0.044 (5)	0.048 (6)	−0.010 (4)	0.012 (5)	0.017 (5)
O132	0.041 (5)	0.046 (6)	0.052 (6)	−0.003 (4)	0.016 (5)	−0.002 (5)
O142	0.040 (5)	0.045 (6)	0.073 (7)	0.001 (5)	0.001 (5)	0.009 (5)
O152	0.032 (5)	0.065 (7)	0.065 (7)	−0.004 (5)	−0.002 (5)	0.005 (6)
O162	0.071 (7)	0.030 (5)	0.050 (7)	−0.016 (5)	−0.005 (5)	0.007 (5)
O172	0.085 (8)	0.068 (7)	0.034 (6)	−0.011 (6)	0.019 (5)	−0.005 (5)
O182	0.058 (7)	0.088 (8)	0.072 (8)	0.037 (6)	−0.008 (6)	−0.001 (7)
O192	0.050 (6)	0.035 (5)	0.059 (7)	−0.009 (4)	0.013 (5)	0.005 (5)
O202	0.053 (6)	0.054 (6)	0.052 (7)	−0.019 (5)	−0.010 (5)	−0.012 (5)
O212	0.066 (7)	0.090 (8)	0.043 (7)	0.004 (6)	0.002 (5)	−0.006 (6)
O222	0.084 (8)	0.045 (6)	0.067 (8)	0.001 (6)	−0.006 (6)	−0.014 (6)
O232	0.054 (6)	0.054 (6)	0.071 (8)	0.010 (5)	−0.016 (6)	−0.017 (6)
O242	0.045 (6)	0.051 (6)	0.069 (7)	−0.016 (5)	−0.001 (5)	0.008 (5)
O252	0.063 (6)	0.046 (6)	0.067 (7)	−0.003 (5)	0.014 (6)	0.000 (5)
O262	0.064 (7)	0.064 (7)	0.082 (8)	−0.008 (6)	0.001 (6)	−0.015 (6)

Geometric parameters (Å, º)

Co1—N11	1.941 (11)	C172—H172	0.9300
Co1—N21	1.899 (10)	C172—C182	1.31 (2)
Co1—N31	1.930 (10)	C182—H182	0.9300
Co1—N41	1.939 (10)	C182—C192	1.40 (2)
Co1—N51	1.938 (10)	C192—H192	0.9300
Co1—N61	1.946 (10)	C192—C202	1.392 (18)
N11—C11	1.315 (16)	C202—H202	0.9300
N11—C51	1.357 (16)	N52—C262	1.346 (16)
N21—C61	1.365 (15)	N52—C302	1.341 (15)
N21—C101	1.369 (15)	N62—C212	1.355 (15)
C11—H11	0.9300	N62—C252	1.328 (16)
C11—C21	1.380 (19)	C212—H212	0.9300
C21—H21	0.9300	C212—C222	1.360 (17)
C21—C31	1.33 (2)	C222—H222	0.9300
C31—H31	0.9300	C222—C232	1.335 (19)
C31—C41	1.387 (19)	C232—H232	0.9300
C41—H41	0.9300	C232—C242	1.376 (19)
C41—C51	1.374 (17)	C242—H242	0.9300
C51—C61	1.476 (17)	C242—C252	1.439 (17)
C61—C71	1.352 (17)	C252—C262	1.462 (18)
C71—H71	0.9300	C262—C272	1.371 (18)
C71—C81	1.384 (18)	C272—H272	0.9300
C81—H81	0.9300	C272—C282	1.41 (2)
C81—C91	1.357 (17)	C282—H282	0.9300
C91—H91	0.9300	C282—C292	1.36 (2)
C91—C101	1.392 (16)	C292—H292	0.9300
C101—H101	0.9300	C292—C302	1.424 (19)
N31—C111	1.351 (15)	C302—H302	0.9300
N31—C151	1.307 (15)	Mo11—Mo21^i	3.2078 (17)
N41—C161	1.400 (15)	Mo11—O11^i	1.984 (8)
N41—C201	1.298 (15)	Mo11—O21	2.372 (8)
C111—H111	0.9300	Mo11—O31	2.323 (8)
C111—C121	1.374 (18)	Mo11—O81	1.873 (8)
C121—H121	0.9300	Mo11—O101	1.694 (8)
C121—C131	1.407 (18)	Mo11—O131	1.710 (8)
C131—H131	0.9300	Mo21—Mo11^i	3.2079 (17)
C131—C141	1.375 (17)	Mo21—Mo31^i	3.2050 (18)
C141—H141	0.9300	Mo21—O11	1.950 (8)
C141—C151	1.396 (17)	Mo21—O21	1.931 (7)
C151—C161	1.487 (17)	Mo21—O31	2.392 (8)
C161—C171	1.350 (17)	Mo21—O31^i	2.124 (8)
C171—H171	0.9300	Mo21—O41	1.755 (8)
C171—C181	1.371 (19)	Mo21—O61	1.703 (8)
C181—H181	0.9300	Mo31—Mo21^i	3.2049 (18)
C181—C191	1.37 (2)	Mo31—O11	2.342 (8)
C191—H191	0.9300	Mo31—O21^i	2.007 (8)
C191—C201	1.390 (18)	Mo31—O31	2.316 (8)
C201—H201	0.9300	Mo31—O71	1.902 (8)
N51—C261	1.384 (15)	Mo31—O91	1.690 (8)
N51—C301	1.332 (15)	Mo31—O111	1.677 (9)
N61—C211	1.337 (16)	Mo41—O31	2.480 (8)
N61—C251	1.335 (15)	Mo41—O41	2.304 (8)
C211—H211	0.9300	Mo41—O51	1.681 (8)
C211—C221	1.410 (18)	Mo41—O71	1.902 (9)
C221—H221	0.9300	Mo41—O81	1.938 (8)
C221—C231	1.39 (2)	Mo41—O121	1.705 (9)
C231—H231	0.9300	O11—Mo11^i	1.984 (8)
C231—C241	1.338 (19)	O21—Mo31^i	2.007 (8)
C241—H241	0.9300	O31—Mo21^i	2.124 (8)
C241—C251	1.396 (18)	Mo12—O22	1.938 (8)
C251—C261	1.414 (18)	Mo12—O42	2.410 (8)
C261—C271	1.382 (18)	Mo12—O92	2.350 (9)
C271—H271	0.9300	Mo12—O102	1.920 (8)
C271—C281	1.343 (19)	Mo12—O172	1.682 (9)
C281—H281	0.9300	Mo12—O252	1.701 (9)
C281—C291	1.420 (18)	Mo22—Mo42	3.2098 (18)
C291—H291	0.9300	Mo22—O12	1.950 (8)
C291—C301	1.357 (17)	Mo22—O42	2.109 (8)
C301—H301	0.9300	Mo22—O72	1.954 (8)
Co2—N12	1.919 (10)	Mo22—O82	2.349 (8)
Co2—N22	1.916 (10)	Mo22—O122	1.694 (9)
Co2—N32	1.956 (10)	Mo22—O132	1.749 (9)
Co2—N42	1.946 (11)	Mo32—Mo52	3.2102 (18)
Co2—N52	1.946 (11)	Mo32—O42	2.342 (7)
Co2—N62	1.969 (11)	Mo32—O52	1.936 (8)
N12—C62	1.403 (14)	Mo32—O62	1.951 (8)
N12—C102	1.333 (15)	Mo32—O82	2.151 (8)
N22—C12	1.328 (15)	Mo32—O92	1.730 (8)
N22—C52	1.364 (15)	Mo32—O162	1.689 (8)
C12—H12	0.9300	Mo42—O22	1.879 (8)
C12—C22	1.366 (18)	Mo42—O42	2.383 (7)
C22—H22	0.9300	Mo42—O52	2.384 (8)
C22—C32	1.378 (19)	Mo42—O72	1.995 (8)
C32—H32	0.9300	Mo42—O142	1.709 (8)
C32—C42	1.379 (18)	Mo42—O192	1.684 (8)
C42—H42	0.9300	Mo52—O32	1.917 (9)
C42—C52	1.371 (17)	Mo52—O52	1.995 (9)
C52—C62	1.437 (16)	Mo52—O72	2.358 (8)
C62—C72	1.365 (16)	Mo52—O82	2.315 (8)
C72—H72	0.9300	Mo52—O152	1.677 (9)
C72—C82	1.417 (17)	Mo52—O202	1.706 (9)
C82—H82	0.9300	Mo62—O12	1.996 (8)
C82—C92	1.355 (17)	Mo62—O42	2.363 (7)
C92—H92	0.9300	Mo62—O62	2.352 (9)
C92—C102	1.366 (16)	Mo62—O102	1.881 (9)
C102—H102	0.9300	Mo62—O232	1.665 (9)
N32—C162	1.386 (17)	Mo62—O242	1.707 (9)
N32—C202	1.293 (17)	Mo72—O12	2.267 (9)
N42—C112	1.311 (17)	Mo72—O62	2.000 (8)
N42—C152	1.369 (16)	Mo72—O82	2.318 (8)
C112—H112	0.9300	Mo72—O112	1.896 (9)
C112—C122	1.357 (18)	Mo72—O182	1.704 (9)
C122—H122	0.9300	Mo72—O222	1.672 (10)
C122—C132	1.39 (2)	Mo82—O32	1.905 (9)
C132—H132	0.9300	Mo82—O82	2.500 (8)
C132—C142	1.36 (2)	Mo82—O112	1.922 (9)
C142—H142	0.9300	Mo82—O132	2.251 (9)
C142—C152	1.377 (19)	Mo82—O212	1.709 (10)
C152—C162	1.43 (2)	Mo82—O262	1.691 (10)
C162—C172	1.403 (18)
N11—Co1—N61	85.4 (4)	O131—Mo11—O81	100.4 (4)
N21—Co1—N11	82.9 (5)	Mo31^i—Mo21—Mo11^i	91.40 (4)
N21—Co1—N31	87.6 (4)	O11—Mo21—Mo11^i	35.7 (2)
N21—Co1—N41	95.3 (4)	O11—Mo21—Mo31^i	124.6 (2)
N21—Co1—N51	176.6 (4)	O11—Mo21—O31^i	78.4 (3)
N21—Co1—N61	94.6 (4)	O11—Mo21—O31	77.5 (3)
N31—Co1—N11	96.2 (4)	O21—Mo21—Mo11^i	125.5 (2)
N31—Co1—N41	83.3 (4)	O21—Mo21—Mo31^i	36.3 (2)
N31—Co1—N51	94.7 (4)	O21—Mo21—O11	150.1 (3)
N31—Co1—N61	177.5 (5)	O21—Mo21—O31	78.0 (3)
N41—Co1—N11	178.1 (5)	O21—Mo21—O31^i	79.2 (3)
N41—Co1—N61	95.2 (5)	O31^i—Mo21—Mo11^i	46.3 (2)
N51—Co1—N11	94.4 (5)	O31—Mo21—Mo11^i	86.0 (2)
N51—Co1—N41	87.4 (4)	O31—Mo21—Mo31^i	85.8 (2)
N51—Co1—N61	83.2 (4)	O31^i—Mo21—Mo31^i	46.2 (2)
C11—N11—Co1	126.7 (11)	O31^i—Mo21—O31	75.8 (3)
C11—N11—C51	119.0 (12)	O41—Mo21—Mo11^i	131.6 (3)
C51—N11—Co1	114.2 (9)	O41—Mo21—Mo31^i	133.3 (3)
C61—N21—Co1	116.6 (9)	O41—Mo21—O11	95.9 (3)
C61—N21—C101	116.5 (11)	O41—Mo21—O21	97.0 (4)
C101—N21—Co1	126.9 (8)	O41—Mo21—O31^i	156.6 (3)
N11—C11—H11	119.5	O41—Mo21—O31	80.9 (3)
N11—C11—C21	121.0 (16)	O61—Mo21—Mo11^i	89.9 (3)
C21—C11—H11	119.5	O61—Mo21—Mo31^i	90.5 (3)
C11—C21—H21	119.3	O61—Mo21—O11	101.3 (4)
C31—C21—C11	121.3 (16)	O61—Mo21—O21	101.4 (4)
C31—C21—H21	119.3	O61—Mo21—O31^i	98.7 (4)
C21—C31—H31	120.9	O61—Mo21—O31	174.5 (4)
C21—C31—C41	118.1 (15)	O61—Mo21—O41	104.7 (4)
C41—C31—H31	120.9	O11—Mo31—Mo21^i	78.79 (18)
C31—C41—H41	120.4	O21^i—Mo31—Mo21^i	34.8 (2)
C51—C41—C31	119.2 (16)	O21^i—Mo31—O11	71.8 (3)
C51—C41—H41	120.4	O21^i—Mo31—O31	73.2 (3)
N11—C51—C41	121.1 (13)	O31—Mo31—Mo21^i	41.5 (2)
N11—C51—C61	114.1 (11)	O31—Mo31—O11	72.0 (3)
C41—C51—C61	124.8 (14)	O71—Mo31—Mo21^i	119.0 (3)
N21—C61—C51	112.0 (12)	O71—Mo31—O11	85.1 (3)
C71—C61—N21	122.8 (13)	O71—Mo31—O21^i	147.1 (3)
C71—C61—C51	125.2 (12)	O71—Mo31—O31	77.6 (3)
C61—C71—H71	120.2	O91—Mo31—Mo21^i	136.1 (3)
C61—C71—C81	119.6 (13)	O91—Mo31—O11	87.0 (4)
C81—C71—H71	120.2	O91—Mo31—O21^i	101.3 (4)
C71—C81—H81	120.1	O91—Mo31—O31	159.0 (4)
C91—C81—C71	119.8 (14)	O91—Mo31—O71	100.5 (4)
C91—C81—H81	120.1	O111—Mo31—Mo21^i	86.4 (3)
C81—C91—H91	120.7	O111—Mo31—O11	165.1 (4)
C81—C91—C101	118.5 (13)	O111—Mo31—O21^i	96.6 (4)
C101—C91—H91	120.7	O111—Mo31—O31	96.0 (4)
N21—C101—C91	122.6 (12)	O111—Mo31—O71	101.3 (4)
N21—C101—H101	118.7	O111—Mo31—O91	104.8 (4)
C91—C101—H101	118.7	O41—Mo41—O31	69.6 (3)
C111—N31—Co1	125.2 (9)	O51—Mo41—O31	95.2 (3)
C151—N31—Co1	115.8 (9)	O51—Mo41—O41	164.7 (3)
C151—N31—C111	118.9 (12)	O51—Mo41—O71	98.0 (4)
C161—N41—Co1	113.7 (8)	O51—Mo41—O81	98.9 (4)
C201—N41—Co1	129.1 (10)	O51—Mo41—O121	105.0 (4)
C201—N41—C161	117.2 (11)	O71—Mo41—O31	73.5 (3)
N31—C111—H111	119.1	O71—Mo41—O41	77.4 (3)
N31—C111—C121	121.8 (13)	O71—Mo41—O81	143.6 (3)
C121—C111—H111	119.1	O81—Mo41—O31	73.0 (3)
C111—C121—H121	120.9	O81—Mo41—O41	77.8 (3)
C111—C121—C131	118.2 (14)	O121—Mo41—O31	159.8 (4)
C131—C121—H121	120.9	O121—Mo41—O41	90.2 (4)
C121—C131—H131	119.9	O121—Mo41—O71	103.9 (4)
C141—C131—C121	120.1 (14)	O121—Mo41—O81	102.4 (4)
C141—C131—H131	119.9	Mo11^i—O11—Mo31	104.7 (3)
C131—C141—H141	121.7	Mo21—O11—Mo11^i	109.3 (4)
C131—C141—C151	116.6 (13)	Mo21—O11—Mo31	110.4 (3)
C151—C141—H141	121.7	Mo21—O21—Mo11	110.4 (3)
N31—C151—C141	124.1 (13)	Mo21—O21—Mo31^i	108.9 (4)
N31—C151—C161	115.3 (12)	Mo31^i—O21—Mo11	102.9 (3)
C141—C151—C161	120.5 (12)	Mo11—O31—Mo21	97.4 (3)
N41—C161—C151	111.9 (11)	Mo11—O31—Mo41	85.5 (3)
C171—C161—N41	120.0 (13)	Mo21^i—O31—Mo11	92.2 (3)
C171—C161—C151	128.0 (13)	Mo21^i—O31—Mo21	104.2 (3)
C161—C171—H171	119.7	Mo21^i—O31—Mo31	92.3 (3)
C161—C171—C181	120.6 (15)	Mo21—O31—Mo41	91.5 (3)
C181—C171—H171	119.7	Mo21^i—O31—Mo41	164.3 (4)
C171—C181—H181	119.7	Mo31—O31—Mo11	163.2 (4)
C171—C181—C191	120.7 (15)	Mo31—O31—Mo21	97.1 (3)
C191—C181—H181	119.7	Mo31—O31—Mo41	85.8 (3)
C181—C191—H191	122.3	Mo21—O41—Mo41	118.0 (4)
C181—C191—C201	115.4 (15)	Mo31—O71—Mo41	118.4 (4)
C201—C191—H191	122.3	Mo11—O81—Mo41	117.7 (4)
N41—C201—C191	126.1 (14)	O22—Mo12—O42	74.3 (3)
N41—C201—H201	117.0	O22—Mo12—O92	76.7 (3)
C191—C201—H201	117.0	O92—Mo12—O42	68.4 (3)
C261—N51—Co1	112.2 (9)	O102—Mo12—O22	144.9 (4)
C301—N51—Co1	126.8 (9)	O102—Mo12—O42	74.6 (3)
C301—N51—C261	121.0 (11)	O102—Mo12—O92	77.1 (3)
C211—N61—Co1	124.7 (9)	O172—Mo12—O22	99.6 (4)
C251—N61—Co1	113.1 (9)	O172—Mo12—O42	159.1 (4)
C251—N61—C211	121.8 (12)	O172—Mo12—O92	90.7 (4)
N61—C211—H211	119.9	O172—Mo12—O102	103.6 (4)
N61—C211—C221	120.3 (14)	O172—Mo12—O252	104.8 (5)
C221—C211—H211	119.9	O252—Mo12—O22	99.4 (4)
C211—C221—H221	121.3	O252—Mo12—O42	96.0 (4)
C231—C221—C211	117.4 (14)	O252—Mo12—O92	164.4 (4)
C231—C221—H221	121.3	O252—Mo12—O102	99.6 (4)
C221—C231—H231	119.5	O12—Mo22—Mo42	126.8 (2)
C241—C231—C221	120.9 (15)	O12—Mo22—O42	78.9 (3)
C241—C231—H231	119.5	O12—Mo22—O72	150.8 (3)
C231—C241—H241	119.9	O12—Mo22—O82	76.8 (3)
C231—C241—C251	120.2 (15)	O42—Mo22—Mo42	47.9 (2)
C251—C241—H241	119.9	O42—Mo22—O82	76.0 (3)
N61—C251—C241	119.3 (13)	O72—Mo22—Mo42	36.1 (2)
N61—C251—C261	115.7 (12)	O72—Mo22—O42	80.2 (3)
C241—C251—C261	124.8 (13)	O72—Mo22—O82	78.6 (3)
N51—C261—C251	114.9 (12)	O82—Mo22—Mo42	87.07 (19)
C271—C261—N51	118.1 (13)	O122—Mo22—Mo42	89.7 (3)
C271—C261—C251	126.9 (13)	O122—Mo22—O12	100.5 (4)
C261—C271—H271	119.2	O122—Mo22—O42	97.5 (4)
C281—C271—C261	121.7 (14)	O122—Mo22—O72	102.2 (4)
C281—C271—H271	119.2	O122—Mo22—O82	173.2 (4)
C271—C281—H281	120.8	O122—Mo22—O132	105.7 (4)
C271—C281—C291	118.4 (14)	O132—Mo22—Mo42	131.4 (3)
C291—C281—H281	120.8	O132—Mo22—O12	95.9 (4)
C281—C291—H291	120.4	O132—Mo22—O42	156.9 (4)
C301—C291—C281	119.3 (13)	O132—Mo22—O72	95.4 (4)
C301—C291—H291	120.4	O132—Mo22—O82	80.9 (3)
N51—C301—C291	121.1 (13)	O42—Mo32—Mo52	86.35 (19)
N51—C301—H301	119.5	O52—Mo32—Mo52	35.9 (2)
C291—C301—H301	119.5	O52—Mo32—O42	78.7 (3)
N12—Co2—N32	178.8 (5)	O52—Mo32—O62	150.7 (3)
N12—Co2—N42	94.1 (5)	O52—Mo32—O82	78.5 (3)
N12—Co2—N52	87.2 (4)	O62—Mo32—Mo52	123.8 (2)
N12—Co2—N62	95.4 (4)	O62—Mo32—O42	78.9 (3)
N22—Co2—N12	83.8 (4)	O62—Mo32—O82	77.7 (3)
N22—Co2—N32	95.5 (4)	O82—Mo32—Mo52	46.1 (2)
N22—Co2—N42	88.7 (4)	O82—Mo32—O42	75.4 (3)
N22—Co2—N52	94.9 (4)	O92—Mo32—Mo52	132.0 (3)
N22—Co2—N62	177.6 (5)	O92—Mo32—O42	80.7 (3)
N32—Co2—N62	85.3 (4)	O92—Mo32—O52	96.2 (4)
N42—Co2—N32	84.9 (5)	O92—Mo32—O62	98.7 (4)
N42—Co2—N52	176.3 (4)	O92—Mo32—O82	156.1 (4)
N42—Co2—N62	93.6 (4)	O162—Mo32—Mo52	89.0 (3)
N52—Co2—N32	93.9 (5)	O162—Mo32—O42	174.0 (4)
N52—Co2—N62	82.8 (4)	O162—Mo32—O52	99.6 (4)
C62—N12—Co2	113.9 (8)	O162—Mo32—O62	100.6 (4)
C102—N12—Co2	127.4 (9)	O162—Mo32—O82	98.7 (4)
C102—N12—C62	118.7 (11)	O162—Mo32—O92	105.2 (4)
C12—N22—Co2	127.9 (9)	O22—Mo42—Mo22	117.0 (2)
C12—N22—C52	117.7 (11)	O22—Mo42—O42	76.0 (3)
C52—N22—Co2	114.4 (8)	O22—Mo42—O52	84.4 (3)
N22—C12—H12	118.5	O22—Mo42—O72	145.6 (3)
N22—C12—C22	122.9 (14)	O42—Mo42—Mo22	41.08 (18)
C22—C12—H12	118.5	O42—Mo42—O52	69.9 (3)
C12—C22—H22	120.5	O52—Mo42—Mo22	77.90 (19)
C12—C22—C32	119.0 (14)	O72—Mo42—Mo22	35.2 (2)
C32—C22—H22	120.5	O72—Mo42—O42	72.9 (3)
C22—C32—H32	120.5	O72—Mo42—O52	71.5 (3)
C22—C32—C42	119.0 (14)	O142—Mo42—Mo22	137.7 (3)
C42—C32—H32	120.5	O142—Mo42—O22	101.2 (4)
C32—C42—H42	120.7	O142—Mo42—O42	158.9 (4)
C52—C42—C32	118.7 (14)	O142—Mo42—O52	89.0 (4)
C52—C42—H42	120.7	O142—Mo42—O72	102.5 (4)
N22—C52—C42	122.2 (12)	O192—Mo42—Mo22	85.2 (3)
N22—C52—C62	115.0 (11)	O192—Mo42—O22	102.4 (4)
C42—C52—C62	122.7 (12)	O192—Mo42—O42	96.5 (3)
N12—C62—C52	112.9 (10)	O192—Mo42—O52	163.1 (4)
C72—C62—N12	120.9 (11)	O192—Mo42—O72	95.3 (4)
C72—C62—C52	126.1 (11)	O192—Mo42—O142	104.5 (4)
C62—C72—H72	120.5	O32—Mo52—Mo32	120.2 (3)
C62—C72—C82	119.0 (12)	O32—Mo52—O52	147.2 (3)
C82—C72—H72	120.5	O32—Mo52—O72	83.7 (3)
C72—C82—H82	121.0	O32—Mo52—O82	78.1 (3)
C92—C82—C72	118.1 (12)	O52—Mo52—Mo32	34.6 (2)
C92—C82—H82	121.0	O52—Mo52—O72	72.1 (3)
C82—C92—H92	119.0	O52—Mo52—O82	73.5 (3)
C82—C92—C102	121.9 (13)	O72—Mo52—Mo32	79.2 (2)
C102—C92—H92	119.0	O82—Mo52—Mo32	42.0 (2)
N12—C102—C92	121.3 (13)	O82—Mo52—O72	71.9 (3)
N12—C102—H102	119.3	O152—Mo52—Mo32	136.2 (3)
C92—C102—H102	119.3	O152—Mo52—O32	99.3 (4)
C162—N32—Co2	110.4 (9)	O152—Mo52—O52	101.5 (4)
C202—N32—Co2	128.8 (11)	O152—Mo52—O72	87.5 (4)
C202—N32—C162	120.7 (12)	O152—Mo52—O82	159.4 (4)
C112—N42—Co2	128.3 (10)	O152—Mo52—O202	105.1 (4)
C112—N42—C152	119.0 (13)	O202—Mo52—Mo32	85.6 (3)
C152—N42—Co2	112.7 (10)	O202—Mo52—O32	102.3 (4)
N42—C112—H112	118.0	O202—Mo52—O52	96.5 (4)
N42—C112—C122	124.0 (14)	O202—Mo52—O72	164.7 (4)
C122—C112—H112	118.0	O202—Mo52—O82	95.4 (4)
C112—C122—H122	121.3	O12—Mo62—O42	72.1 (3)
C112—C122—C132	117.4 (16)	O12—Mo62—O62	70.8 (3)
C132—C122—H122	121.3	O62—Mo62—O42	71.2 (3)
C122—C132—H132	120.0	O102—Mo62—O12	145.2 (3)
C142—C132—C122	120.0 (16)	O102—Mo62—O42	76.4 (3)
C142—C132—H132	120.0	O102—Mo62—O62	85.4 (3)
C132—C142—H142	120.2	O232—Mo62—O12	102.3 (4)
C132—C142—C152	119.7 (15)	O232—Mo62—O42	157.7 (4)
C152—C142—H142	120.2	O232—Mo62—O62	86.5 (4)
N42—C152—C142	119.9 (15)	O232—Mo62—O102	101.2 (4)
N42—C152—C162	114.8 (13)	O232—Mo62—O242	104.2 (5)
C142—C152—C162	125.3 (14)	O242—Mo62—O12	96.6 (4)
N32—C162—C152	117.2 (12)	O242—Mo62—O42	98.0 (4)
N32—C162—C172	117.8 (15)	O242—Mo62—O62	165.2 (4)
C172—C162—C152	125.0 (15)	O242—Mo62—O102	102.2 (4)
C162—C172—H172	119.1	O12—Mo72—O82	71.8 (3)
C182—C172—C162	121.7 (17)	O62—Mo72—O12	72.6 (3)
C182—C172—H172	119.1	O62—Mo72—O82	72.9 (3)
C172—C182—H182	120.2	O112—Mo72—O12	83.9 (3)
C172—C182—C192	119.5 (15)	O112—Mo72—O62	147.4 (4)
C192—C182—H182	120.2	O112—Mo72—O82	78.6 (3)
C182—C192—H192	120.9	O182—Mo72—O12	88.1 (4)
C202—C192—C182	118.2 (16)	O182—Mo72—O62	102.5 (4)
C202—C192—H192	120.9	O182—Mo72—O82	159.8 (4)
N32—C202—C192	122.0 (16)	O182—Mo72—O112	98.9 (5)
N32—C202—H202	119.0	O222—Mo72—O12	165.0 (4)
C192—C202—H202	119.0	O222—Mo72—O62	97.7 (4)
C262—N52—Co2	114.2 (9)	O222—Mo72—O82	94.6 (4)
C302—N52—Co2	124.4 (9)	O222—Mo72—O112	99.9 (5)
C302—N52—C262	120.4 (12)	O222—Mo72—O182	105.5 (5)
C212—N62—Co2	127.4 (9)	O32—Mo82—O82	73.7 (3)
C252—N62—Co2	112.7 (9)	O32—Mo82—O112	144.8 (4)
C252—N62—C212	119.9 (12)	O32—Mo82—O132	79.2 (3)
N62—C212—H212	119.2	O112—Mo82—O82	73.6 (3)
N62—C212—C222	121.7 (14)	O112—Mo82—O132	77.1 (3)
C222—C212—H212	119.2	O132—Mo82—O82	69.0 (3)
C212—C222—H222	119.5	O212—Mo82—O32	103.3 (4)
C232—C222—C212	120.9 (15)	O212—Mo82—O82	160.2 (4)
C232—C222—H222	119.5	O212—Mo82—O112	102.9 (4)
C222—C232—H232	120.5	O212—Mo82—O132	91.3 (4)
C222—C232—C242	119.0 (15)	O262—Mo82—O32	99.3 (4)
C242—C232—H232	120.5	O262—Mo82—O82	94.4 (4)
C232—C242—H242	120.3	O262—Mo82—O112	96.0 (5)
C232—C242—C252	119.4 (14)	O262—Mo82—O132	163.1 (4)
C252—C242—H242	120.3	O262—Mo82—O212	105.3 (5)
N62—C252—C242	118.9 (13)	Mo22—O12—Mo62	109.6 (4)
N62—C252—C262	115.9 (12)	Mo22—O12—Mo72	111.6 (3)
C242—C252—C262	125.1 (13)	Mo62—O12—Mo72	104.8 (4)
N52—C262—C252	113.6 (12)	Mo42—O22—Mo12	117.8 (4)
N52—C262—C272	122.9 (14)	Mo82—O32—Mo52	118.0 (4)
C272—C262—C252	123.3 (13)	Mo22—O42—Mo12	160.6 (4)
C262—C272—H272	122.2	Mo22—O42—Mo32	105.1 (3)
C262—C272—C282	115.7 (15)	Mo22—O42—Mo42	91.0 (3)
C282—C272—H272	122.2	Mo22—O42—Mo62	92.1 (3)
C272—C282—H282	118.7	Mo32—O42—Mo12	94.3 (3)
C292—C282—C272	122.6 (16)	Mo32—O42—Mo42	97.9 (3)
C292—C282—H282	118.7	Mo32—O42—Mo62	97.0 (3)
C282—C292—H292	121.4	Mo42—O42—Mo12	86.0 (2)
C282—C292—C302	117.2 (15)	Mo62—O42—Mo12	85.6 (3)
C302—C292—H292	121.4	Mo62—O42—Mo42	163.4 (4)
N52—C302—C292	120.4 (13)	Mo32—O52—Mo42	110.7 (3)
N52—C302—H302	119.8	Mo32—O52—Mo52	109.5 (4)
C292—C302—H302	119.8	Mo52—O52—Mo42	103.2 (3)
O11^i—Mo11—Mo21^i	35.0 (2)	Mo32—O62—Mo62	109.7 (4)
O11^i—Mo11—O21	71.5 (3)	Mo32—O62—Mo72	110.9 (4)
O11^i—Mo11—O31	73.0 (3)	Mo72—O62—Mo62	101.7 (3)
O21—Mo11—Mo21^i	78.95 (18)	Mo22—O72—Mo42	108.7 (4)
O31—Mo11—Mo21^i	41.4 (2)	Mo22—O72—Mo52	109.2 (4)
O31—Mo11—O21	71.6 (3)	Mo42—O72—Mo52	104.1 (3)
O81—Mo11—Mo21^i	119.5 (2)	Mo22—O82—Mo82	91.0 (3)
O81—Mo11—O11^i	145.9 (3)	Mo32—O82—Mo22	103.5 (3)
O81—Mo11—O21	82.6 (3)	Mo32—O82—Mo52	91.8 (3)
O81—Mo11—O31	78.0 (3)	Mo32—O82—Mo72	93.3 (3)
O101—Mo11—Mo21^i	85.8 (3)	Mo32—O82—Mo82	165.5 (4)
O101—Mo11—O11^i	97.6 (4)	Mo52—O82—Mo22	98.1 (3)
O101—Mo11—O21	164.4 (4)	Mo52—O82—Mo72	162.6 (4)
O101—Mo11—O31	94.8 (4)	Mo52—O82—Mo82	85.7 (3)
O101—Mo11—O81	102.5 (4)	Mo72—O82—Mo22	96.9 (3)
O101—Mo11—O131	104.0 (5)	Mo72—O82—Mo82	85.2 (3)
O131—Mo11—Mo21^i	136.1 (3)	Mo32—O92—Mo12	116.5 (4)
O131—Mo11—O11^i	101.1 (4)	Mo62—O102—Mo12	117.2 (4)
O131—Mo11—O21	89.4 (4)	Mo72—O112—Mo82	117.4 (4)
O131—Mo11—O31	161.0 (4)	Mo22—O132—Mo82	119.2 (4)
Co1—N11—C11—C21	171.4 (11)	Co2—N62—C252—C262	9.6 (14)
Co1—N11—C51—C41	−174.8 (10)	N12—C62—C72—C82	−2.6 (18)
Co1—N11—C51—C61	5.5 (14)	N22—C12—C22—C32	−7 (2)
Co1—N21—C61—C51	−1.4 (14)	N22—C52—C62—N12	−0.8 (16)
Co1—N21—C61—C71	−179.4 (11)	N22—C52—C62—C72	175.6 (12)
Co1—N21—C101—C91	−177.7 (10)	C12—N22—C52—C42	0 (2)
Co1—N31—C111—C121	179.0 (11)	C12—N22—C52—C62	180.0 (12)
Co1—N31—C151—C141	−176.1 (9)	C12—C22—C32—C42	7 (2)
Co1—N31—C151—C161	−0.3 (14)	C22—C32—C42—C52	−4 (2)
Co1—N41—C161—C151	0.3 (13)	C32—C42—C52—N22	0 (2)
Co1—N41—C161—C171	−178.3 (10)	C32—C42—C52—C62	−179.4 (13)
Co1—N41—C201—C191	179.7 (11)	C42—C52—C62—N12	178.9 (12)
Co1—N51—C261—C251	−1.3 (16)	C42—C52—C62—C72	−5 (2)
Co1—N51—C261—C271	177.1 (12)	C52—N22—C12—C22	3 (2)
Co1—N51—C301—C291	178.5 (11)	C52—C62—C72—C82	−178.7 (12)
Co1—N61—C211—C221	173.3 (11)	C62—N12—C102—C92	−0.3 (19)
Co1—N61—C251—C241	−175.0 (11)	C62—C72—C82—C92	0.4 (19)
Co1—N61—C251—C261	10.4 (15)	C72—C82—C92—C102	2 (2)
N11—Co1—N21—C61	3.4 (9)	C82—C92—C102—N12	−2 (2)
N11—Co1—N21—C101	−178.8 (11)	C102—N12—C62—C52	179.1 (11)
N11—C11—C21—C31	5 (3)	C102—N12—C62—C72	2.5 (18)
N11—C51—C61—N21	−2.7 (16)	N32—C162—C172—C182	−2 (2)
N11—C51—C61—C71	175.3 (13)	N42—C112—C122—C132	−2 (2)
N21—C61—C71—C81	−5 (2)	N42—C152—C162—N32	−2.5 (18)
C11—N11—C51—C41	2 (2)	N42—C152—C162—C172	174.7 (13)
C11—N11—C51—C61	−177.7 (12)	C112—N42—C152—C142	−1 (2)
C11—C21—C31—C41	−2 (3)	C112—N42—C152—C162	178.9 (13)
C21—C31—C41—C51	−1 (2)	C112—C122—C132—C142	0 (2)
C31—C41—C51—N11	1 (2)	C122—C132—C142—C152	2 (2)
C31—C41—C51—C61	−179.4 (14)	C132—C142—C152—N42	−1 (2)
C41—C51—C61—N21	177.5 (12)	C132—C142—C152—C162	178.4 (14)
C41—C51—C61—C71	−4 (2)	C142—C152—C162—N32	177.8 (13)
C51—N11—C11—C21	−5 (2)	C142—C152—C162—C172	−5 (2)
C51—C61—C71—C81	177.6 (13)	C152—N42—C112—C122	3 (2)
C61—N21—C101—C91	0.0 (19)	C152—C162—C172—C182	−178.7 (14)
C61—C71—C81—C91	4 (2)	C162—N32—C202—C192	−1 (2)
C71—C81—C91—C101	−2 (2)	C162—C172—C182—C192	0 (2)
C81—C91—C101—N21	0 (2)	C172—C182—C192—C202	1 (2)
C101—N21—C61—C51	−179.3 (11)	C182—C192—C202—N32	0 (2)
C101—N21—C61—C71	3 (2)	C202—N32—C162—C152	179.5 (12)
N31—Co1—N21—C61	100.0 (10)	C202—N32—C162—C172	2.0 (19)
N31—Co1—N21—C101	−82.3 (11)	N52—C262—C272—C282	10 (2)
N31—C111—C121—C131	2 (2)	N62—C212—C222—C232	2 (2)
N31—C151—C161—N41	0.0 (16)	N62—C252—C262—N52	−8.9 (17)
N31—C151—C161—C171	178.5 (13)	N62—C252—C262—C272	174.7 (13)
N41—Co1—N21—C61	−177.0 (9)	C212—N62—C252—C242	5.6 (18)
N41—Co1—N21—C101	0.7 (11)	C212—N62—C252—C262	−173.3 (11)
N41—C161—C171—C181	−1 (2)	C212—C222—C232—C242	−1 (2)
C111—N31—C151—C141	6.8 (19)	C222—C232—C242—C252	2 (2)
C111—N31—C151—C161	−177.5 (11)	C232—C242—C252—N62	−4.7 (19)
C111—C121—C131—C141	−2 (2)	C232—C242—C252—C262	174.1 (13)
C121—C131—C141—C151	4.1 (19)	C242—C252—C262—N52	172.3 (12)
C131—C141—C151—N31	−6.8 (19)	C242—C252—C262—C272	−4 (2)
C131—C141—C151—C161	177.7 (12)	C252—N62—C212—C222	−4.3 (18)
C141—C151—C161—N41	175.9 (11)	C252—C262—C272—C282	−174.4 (13)
C141—C151—C161—C171	−6 (2)	C262—N52—C302—C292	5.5 (18)
C151—N31—C111—C121	−4 (2)	C262—C272—C282—C292	−2 (2)
C151—C161—C171—C181	−179.8 (13)	C272—C282—C292—C302	−3 (2)
C161—N41—C201—C191	3 (2)	C282—C292—C302—N52	1 (2)
C161—C171—C181—C191	2 (2)	C302—N52—C262—C252	172.2 (11)
C171—C181—C191—C201	0 (2)	C302—N52—C262—C272	−11 (2)
C181—C191—C201—N41	−2 (2)	Mo11^i—Mo21—O41—Mo41	77.6 (5)
C201—N41—C161—C151	177.6 (11)	Mo21^i—Mo11—O81—Mo41	22.3 (6)
C201—N41—C161—C171	−1.1 (18)	Mo31^i—Mo21—O41—Mo41	−74.1 (5)
N51—C261—C271—C281	3 (2)	O11^i—Mo11—O81—Mo41	54.7 (8)
N61—Co1—N21—C61	−81.3 (10)	O11—Mo21—O41—Mo41	77.6 (4)
N61—Co1—N21—C101	96.4 (11)	O21—Mo11—O81—Mo41	95.1 (5)
N61—C211—C221—C231	−1 (2)	O21—Mo21—O41—Mo41	−75.3 (4)
N61—C251—C261—N51	−6.1 (19)	O31—Mo11—O81—Mo41	22.4 (4)
N61—C251—C261—C271	175.6 (15)	O31^i—Mo21—O41—Mo41	3.4 (11)
C211—N61—C251—C241	−1 (2)	O31—Mo21—O41—Mo41	1.3 (4)
C211—N61—C251—C261	−176.0 (13)	O61—Mo21—O41—Mo41	−179.1 (4)
C211—C221—C231—C241	2 (3)	O101—Mo11—O81—Mo41	−69.9 (5)
C221—C231—C241—C251	−3 (3)	O131—Mo11—O81—Mo41	−176.9 (5)
C231—C241—C251—N61	3 (2)	Mo22—Mo42—O22—Mo12	−19.4 (5)
C231—C241—C251—C261	176.9 (15)	Mo42—Mo22—O132—Mo82	77.9 (5)
C241—C251—C261—N51	179.7 (13)	Mo52—Mo32—O92—Mo12	77.7 (5)
C241—C251—C261—C271	1 (3)	O12—Mo22—O132—Mo82	−75.5 (5)
C251—N61—C211—C221	1 (2)	O12—Mo62—O102—Mo12	48.3 (9)
C251—C261—C271—C281	−178.5 (16)	O12—Mo72—O112—Mo82	94.1 (5)
C261—N51—C301—C291	1 (2)	O42—Mo22—O132—Mo82	0.0 (12)
C261—C271—C281—C291	3 (3)	O42—Mo32—O92—Mo12	1.3 (4)
C271—C281—C291—C301	−7 (3)	O42—Mo42—O22—Mo12	−22.1 (4)
C281—C291—C301—N51	5 (2)	O42—Mo62—O102—Mo12	22.6 (4)
C301—N51—C261—C251	176.3 (12)	O52—Mo32—O92—Mo12	78.7 (4)
C301—N51—C261—C271	−5 (2)	O52—Mo42—O22—Mo12	−92.8 (5)
Co2—N12—C62—C52	−0.7 (13)	O62—Mo32—O92—Mo12	−75.9 (5)
Co2—N12—C62—C72	−177.3 (9)	O62—Mo62—O102—Mo12	94.3 (5)
Co2—N12—C102—C92	179.5 (9)	O62—Mo72—O112—Mo82	50.6 (9)
Co2—N22—C12—C22	−179.2 (12)	O72—Mo22—O132—Mo82	77.6 (5)
Co2—N22—C52—C42	−177.7 (11)	O72—Mo42—O22—Mo12	−47.8 (8)
Co2—N22—C52—C62	1.9 (14)	O82—Mo22—O132—Mo82	0.1 (4)
Co2—N32—C162—C152	3.5 (15)	O82—Mo32—O92—Mo12	3.4 (11)
Co2—N32—C162—C172	−173.9 (10)	O82—Mo72—O112—Mo82	21.5 (4)
Co2—N32—C202—C192	174.0 (10)	O122—Mo22—O132—Mo82	−178.1 (4)
Co2—N42—C112—C122	−178.1 (10)	O142—Mo42—O22—Mo12	179.3 (5)
Co2—N42—C152—C142	179.9 (10)	O162—Mo32—O92—Mo12	−179.5 (4)
Co2—N42—C152—C162	0.1 (15)	O182—Mo72—O112—Mo82	−178.8 (6)
Co2—N52—C262—C252	3.6 (14)	O192—Mo42—O22—Mo12	71.6 (5)
Co2—N52—C262—C272	−180.0 (11)	O222—Mo72—O112—Mo82	−71.2 (6)
Co2—N52—C302—C292	172.9 (9)	O232—Mo62—O102—Mo12	179.8 (5)
Co2—N62—C212—C222	172.4 (9)	O242—Mo62—O102—Mo12	−72.8 (5)
Co2—N62—C252—C242	−171.5 (9)

Symmetry code: (i) −x+4, −y+1, −z+2.

Bis(2,2'-bipyridine)hemi(octamolybdate)cobaltate(II) (4)

Crystal data

[Co(C10H8N2)2{Mo8O26}0.5]	F(000) = 1852
Mr = 963.06	Dx = 2.501 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71069 Å
a = 10.053 (3) Å	Cell parameters from 4768 reflections
b = 16.408 (5) Å	θ = 1.8–25.0°
c = 15.749 (4) Å	µ = 2.62 mm^−1
β = 100.06 (2)°	T = 298 K
V = 2557.9 (14) Å^3	Irregular, light violet
Z = 4	0.36 × 0.15 × 0.13 mm

Data collection

Rigaku AFC-7S Mercury (2x2 bin mode) diffractometer	3587 reflections with I > 2σ(I)
Detector resolution: 14.6306 pixels mm^-1	Rint = 0.028
ω scans	θmax = 25.0°, θmin = 1.8°
Absorption correction: multi-scan (CrystalClear; Rigaku, 2005)	h = 0→11
Tmin = 0.646, Tmax = 0.695	k = 0→19
4768 measured reflections	l = −18→18
4494 independent reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.049	H-atom parameters constrained
wR(F^2) = 0.147	w = 1/[σ^2(Fo^2) + (0.1038P)^2 + 4.7663P] where P = (Fo^2 + 2Fc^2)/3
S = 1.02	(Δ/σ)max = 0.001
4494 reflections	Δρmax = 1.16 e Å^−3
379 parameters	Δρmin = −2.18 e Å^−3
174 restraints

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mo10	0.73775 (7)	0.06623 (4)	0.36096 (4)	0.0281 (2)
Mo2	0.54509 (6)	0.04402 (4)	0.60599 (4)	0.0255 (2)
Mo3	0.77315 (6)	−0.05377 (4)	0.52938 (4)	0.0268 (2)
Mo4	0.50479 (7)	0.16561 (4)	0.44358 (4)	0.0287 (2)
Co5	0.98889 (10)	0.22713 (6)	0.41224 (7)	0.0276 (3)
O13	0.8594 (6)	0.1303 (3)	0.4183 (4)	0.0350 (13)
O3	0.8000 (5)	−0.0327 (3)	0.4154 (3)	0.0312 (12)
O2	0.4226 (5)	0.1205 (3)	0.5402 (3)	0.0269 (11)
N1	1.1033 (7)	0.3362 (4)	0.4263 (4)	0.0306 (14)
O1	0.6132 (5)	0.0419 (3)	0.4852 (3)	0.0279 (11)
N2	0.9763 (6)	0.2644 (4)	0.5388 (4)	0.0295 (13)
N4	0.9886 (7)	0.2051 (4)	0.2808 (4)	0.0347 (15)
O4	1.1530 (5)	0.1490 (3)	0.4541 (4)	0.0336 (13)
N5	0.8192 (7)	0.2959 (4)	0.3500 (4)	0.0338 (14)
C6	1.0242 (8)	0.3387 (5)	0.5617 (5)	0.0319 (16)
C20	1.0756 (9)	0.1553 (5)	0.2500 (6)	0.0404 (19)
H20	1.1477	0.1330	0.2880	0.048*
C8	0.9175 (9)	0.3389 (6)	0.6848 (6)	0.0424 (19)
H8	0.8942	0.3648	0.7326	0.051*
C7	0.9982 (9)	0.3790 (6)	0.6343 (5)	0.0395 (19)
H7	1.0330	0.4306	0.6488	0.047*
C16	0.8866 (8)	0.2387 (5)	0.2252 (5)	0.0330 (16)
C11	0.7955 (8)	0.2932 (5)	0.2644 (6)	0.0345 (16)
C9	0.8731 (9)	0.2618 (6)	0.6638 (6)	0.044 (2)
H9	0.8235	0.2337	0.6990	0.053*
C17	0.8687 (10)	0.2223 (6)	0.1370 (6)	0.046 (2)
H17	0.7971	0.2456	0.0995	0.055*
C10	0.9022 (8)	0.2256 (6)	0.5899 (5)	0.0370 (18)
H10	0.8700	0.1735	0.5751	0.044*
C5	1.1708 (9)	0.3662 (6)	0.3675 (6)	0.0399 (19)
H5	1.1700	0.3375	0.3165	0.048*
C14	0.6321 (9)	0.3864 (6)	0.3444 (7)	0.049 (2)
H14	0.5787	0.4184	0.3738	0.059*
C12	0.6921 (10)	0.3358 (6)	0.2145 (7)	0.049 (2)
H12	0.6788	0.3328	0.1547	0.058*
C15	0.7380 (9)	0.3405 (5)	0.3890 (6)	0.0400 (19)
H15	0.7525	0.3412	0.4490	0.048*
C1	1.1049 (8)	0.3760 (5)	0.5017 (5)	0.0339 (16)
C2	1.1773 (11)	0.4474 (6)	0.5191 (6)	0.048 (2)
H2	1.1799	0.4743	0.5713	0.057*
C13	0.6080 (10)	0.3834 (6)	0.2556 (7)	0.052 (2)
H13	0.5369	0.4125	0.2238	0.062*
C4	1.2412 (11)	0.4379 (6)	0.3801 (7)	0.050 (2)
H4	1.2848	0.4589	0.3374	0.060*
C19	1.0599 (12)	0.1367 (7)	0.1635 (6)	0.054 (2)
H19	1.1189	0.1005	0.1438	0.065*
C18	0.9567 (11)	0.1719 (6)	0.1063 (6)	0.051 (2)
H18	0.9473	0.1614	0.0475	0.061*
C3	1.2463 (11)	0.4783 (6)	0.4569 (7)	0.052 (2)
H3	1.2957	0.5263	0.4674	0.063*
O7	0.6211 (6)	0.2248 (3)	0.5046 (4)	0.0387 (14)
O9	0.8828 (6)	0.0104 (4)	0.5883 (4)	0.0367 (13)
O5	0.7762 (6)	0.0607 (4)	0.2605 (4)	0.0381 (14)
O8	0.3862 (6)	0.2322 (4)	0.3966 (4)	0.0418 (15)
O6	0.5917 (5)	0.1415 (3)	0.3492 (3)	0.0306 (12)
O11	0.4416 (5)	0.0174 (3)	0.6802 (3)	0.0318 (12)
O10	0.6626 (6)	0.1055 (3)	0.6624 (4)	0.0358 (13)
O12	0.6430 (5)	−0.0592 (3)	0.6108 (3)	0.0288 (12)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mo10	0.0224 (4)	0.0345 (4)	0.0266 (4)	−0.0006 (3)	0.0023 (3)	0.0014 (3)
Mo2	0.0208 (3)	0.0315 (4)	0.0228 (3)	−0.0002 (3)	−0.0003 (3)	−0.0024 (3)
Mo3	0.0181 (3)	0.0333 (4)	0.0274 (4)	0.0022 (3)	−0.0001 (3)	0.0016 (3)
Mo4	0.0234 (4)	0.0314 (4)	0.0306 (4)	0.0005 (3)	0.0028 (3)	0.0011 (3)
Co5	0.0253 (6)	0.0307 (6)	0.0250 (5)	0.0013 (4)	−0.0005 (4)	0.0007 (4)
O13	0.028 (3)	0.035 (3)	0.042 (3)	−0.003 (2)	0.006 (3)	0.006 (3)
O3	0.025 (3)	0.038 (3)	0.032 (3)	0.008 (2)	0.006 (2)	−0.006 (2)
O2	0.018 (3)	0.034 (3)	0.028 (3)	−0.003 (2)	0.002 (2)	0.002 (2)
N1	0.030 (3)	0.030 (3)	0.031 (3)	0.001 (3)	0.005 (3)	0.002 (2)
O1	0.023 (3)	0.034 (3)	0.024 (3)	0.001 (2)	−0.002 (2)	0.002 (2)
N2	0.024 (3)	0.037 (3)	0.026 (3)	0.003 (2)	−0.001 (2)	−0.002 (2)
N4	0.037 (3)	0.039 (3)	0.027 (3)	0.000 (3)	0.004 (3)	0.000 (3)
O4	0.028 (3)	0.036 (3)	0.036 (3)	0.001 (2)	0.003 (2)	0.009 (2)
N5	0.029 (3)	0.035 (3)	0.034 (3)	0.000 (3)	−0.004 (3)	0.005 (3)
C6	0.025 (4)	0.039 (4)	0.028 (3)	0.002 (3)	−0.005 (3)	0.000 (3)
C20	0.042 (4)	0.047 (5)	0.035 (4)	0.001 (4)	0.012 (3)	0.001 (3)
C8	0.034 (4)	0.064 (5)	0.026 (4)	0.003 (3)	−0.005 (3)	−0.006 (3)
C7	0.035 (4)	0.052 (5)	0.028 (4)	−0.001 (3)	−0.004 (3)	−0.010 (3)
C16	0.034 (4)	0.033 (4)	0.031 (3)	−0.011 (3)	0.001 (3)	0.009 (3)
C11	0.033 (4)	0.032 (4)	0.035 (3)	−0.006 (3)	−0.005 (3)	0.005 (3)
C9	0.035 (5)	0.066 (5)	0.030 (4)	−0.004 (4)	0.002 (3)	−0.001 (3)
C17	0.051 (5)	0.053 (5)	0.031 (4)	−0.016 (4)	0.001 (3)	0.004 (3)
C10	0.028 (4)	0.050 (4)	0.031 (4)	−0.002 (3)	−0.002 (3)	0.002 (3)
C5	0.040 (5)	0.046 (4)	0.036 (4)	−0.006 (4)	0.010 (3)	0.003 (3)
C14	0.038 (4)	0.043 (5)	0.061 (5)	0.007 (4)	−0.007 (4)	0.004 (4)
C12	0.043 (4)	0.042 (5)	0.054 (5)	0.000 (4)	−0.011 (4)	0.010 (4)
C15	0.035 (4)	0.036 (4)	0.046 (4)	−0.001 (3)	−0.001 (3)	0.003 (3)
C1	0.035 (4)	0.034 (4)	0.032 (3)	0.006 (3)	0.003 (3)	−0.002 (3)
C2	0.055 (5)	0.048 (4)	0.037 (4)	−0.010 (4)	0.004 (4)	−0.005 (3)
C13	0.038 (5)	0.046 (5)	0.063 (5)	0.007 (4)	−0.015 (4)	0.012 (4)
C4	0.058 (6)	0.046 (5)	0.048 (5)	−0.012 (4)	0.012 (4)	0.005 (4)
C19	0.069 (6)	0.058 (6)	0.038 (4)	0.001 (5)	0.013 (4)	−0.007 (4)
C18	0.065 (5)	0.058 (5)	0.031 (4)	−0.016 (4)	0.009 (4)	0.000 (4)
C3	0.062 (6)	0.045 (5)	0.051 (5)	−0.012 (4)	0.012 (4)	−0.002 (4)
O7	0.038 (3)	0.040 (3)	0.039 (3)	−0.011 (3)	0.010 (3)	−0.004 (3)
O9	0.028 (3)	0.044 (3)	0.039 (3)	−0.006 (3)	0.007 (2)	−0.006 (3)
O5	0.037 (3)	0.047 (4)	0.033 (3)	0.004 (3)	0.013 (3)	0.001 (3)
O8	0.034 (3)	0.044 (4)	0.047 (4)	0.003 (3)	0.005 (3)	0.011 (3)
O6	0.025 (3)	0.039 (3)	0.028 (3)	0.001 (2)	0.004 (2)	0.005 (2)
O11	0.027 (3)	0.041 (3)	0.026 (3)	−0.001 (2)	0.001 (2)	0.004 (2)
O10	0.033 (3)	0.039 (3)	0.034 (3)	−0.003 (3)	0.001 (2)	−0.007 (3)
O12	0.024 (3)	0.032 (3)	0.028 (3)	0.003 (2)	0.000 (2)	−0.003 (2)

Geometric parameters (Å, º)

Mo10—O13	1.740 (6)	O4—Mo3^ii	1.730 (5)
Mo10—O3	1.891 (6)	N5—C11	1.329 (11)
Mo10—O1	2.532 (5)	N5—C15	1.325 (11)
Mo10—O5	1.695 (6)	C6—C7	1.385 (12)
Mo10—O6	1.903 (5)	C6—C1	1.482 (11)
Mo10—O11^i	2.269 (5)	C20—H20	0.9300
Mo2—Mo3	3.2021 (12)	C20—C19	1.379 (13)
Mo2—Mo4	3.2132 (12)	C8—H8	0.9300
Mo2—O2	1.929 (5)	C8—C7	1.395 (13)
Mo2—O1^i	2.405 (5)	C8—C9	1.364 (13)
Mo2—O1	2.132 (5)	C7—H7	0.9300
Mo2—O11	1.750 (5)	C16—C11	1.488 (12)
Mo2—O10	1.684 (5)	C16—C17	1.395 (12)
Mo2—O12	1.953 (5)	C11—C12	1.379 (12)
Mo3—O3	1.892 (5)	C9—H9	0.9300
Mo3—O2^i	2.349 (5)	C9—C10	1.384 (12)
Mo3—O1	2.267 (5)	C17—H17	0.9300
Mo3—O4^ii	1.730 (5)	C17—C18	1.360 (14)
Mo3—O9	1.682 (6)	C10—H10	0.9300
Mo3—O12	1.988 (5)	C5—H5	0.9300
Mo4—O2	1.996 (5)	C5—C4	1.371 (13)
Mo4—O1	2.343 (5)	C14—H14	0.9300
Mo4—O7	1.685 (6)	C14—C15	1.391 (12)
Mo4—O8	1.690 (6)	C14—C13	1.377 (15)
Mo4—O6	1.893 (5)	C12—H12	0.9300
Mo4—O12^i	2.355 (5)	C12—C13	1.391 (14)
Co5—O13	2.067 (5)	C15—H15	0.9300
Co5—N1	2.118 (7)	C1—C2	1.381 (12)
Co5—N2	2.110 (6)	C2—H2	0.9300
Co5—N4	2.100 (7)	C2—C3	1.390 (13)
Co5—O4	2.102 (6)	C13—H13	0.9300
Co5—N5	2.136 (7)	C4—H4	0.9300
O2—Mo3^i	2.349 (5)	C4—C3	1.372 (14)
N1—C5	1.334 (10)	C19—H19	0.9300
N1—C1	1.352 (10)	C19—C18	1.376 (15)
O1—Mo2^i	2.405 (5)	C18—H18	0.9300
N2—C6	1.337 (10)	C3—H3	0.9300
N2—C10	1.347 (10)	O11—Mo10^i	2.269 (5)
N4—C20	1.348 (11)	O12—Mo4^i	2.355 (5)
N4—C16	1.346 (10)
O13—Mo10—O3	97.8 (3)	O4—Co5—N1	95.7 (2)
O13—Mo10—O1	95.3 (2)	O4—Co5—N2	93.1 (2)
O13—Mo10—O6	96.8 (3)	O4—Co5—N5	170.6 (3)
O13—Mo10—O11^i	164.8 (2)	Mo10—O13—Co5	146.2 (3)
O3—Mo10—O1	71.5 (2)	Mo10—O3—Mo3	119.8 (3)
O3—Mo10—O6	142.2 (2)	Mo2—O2—Mo3^i	110.6 (2)
O3—Mo10—O11^i	78.1 (2)	Mo2—O2—Mo4	109.9 (2)
O5—Mo10—O13	105.2 (3)	Mo4—O2—Mo3^i	104.0 (2)
O5—Mo10—O3	105.4 (3)	C5—N1—Co5	124.9 (6)
O5—Mo10—O1	159.5 (2)	C5—N1—C1	120.1 (7)
O5—Mo10—O6	104.0 (3)	C1—N1—Co5	115.0 (5)
O5—Mo10—O11^i	90.0 (2)	Mo2—O1—Mo10	165.1 (3)
O6—Mo10—O1	72.6 (2)	Mo2^i—O1—Mo10	89.77 (17)
O6—Mo10—O11^i	78.7 (2)	Mo2—O1—Mo2^i	105.1 (2)
O11^i—Mo10—O1	69.50 (18)	Mo2—O1—Mo3	93.4 (2)
Mo3—Mo2—Mo4	90.59 (3)	Mo2—O1—Mo4	91.65 (19)
O2—Mo2—Mo3	123.75 (15)	Mo3—O1—Mo10	85.80 (17)
O2—Mo2—Mo4	35.74 (15)	Mo3—O1—Mo2^i	97.9 (2)
O2—Mo2—O1	78.8 (2)	Mo3—O1—Mo4	162.9 (3)
O2—Mo2—O1^i	76.5 (2)	Mo4—O1—Mo10	85.16 (17)
O2—Mo2—O12	148.8 (2)	Mo4—O1—Mo2^i	96.53 (18)
O1^i—Mo2—Mo3	85.65 (13)	C6—N2—Co5	116.1 (5)
O1—Mo2—Mo3	44.98 (14)	C6—N2—C10	118.7 (7)
O1—Mo2—Mo4	46.80 (14)	C10—N2—Co5	123.9 (6)
O1^i—Mo2—Mo4	84.85 (13)	C20—N4—Co5	124.7 (6)
O1—Mo2—O1^i	74.9 (2)	C16—N4—Co5	116.2 (6)
O11—Mo2—Mo3	132.45 (18)	C16—N4—C20	118.9 (7)
O11—Mo2—Mo4	132.78 (18)	Mo3^ii—O4—Co5	152.9 (3)
O11—Mo2—O2	97.0 (2)	C11—N5—Co5	115.8 (6)
O11—Mo2—O1	155.9 (2)	C15—N5—Co5	125.9 (6)
O11—Mo2—O1^i	81.0 (2)	C15—N5—C11	118.3 (7)
O11—Mo2—O12	96.4 (2)	N2—C6—C7	123.1 (8)
O10—Mo2—Mo3	90.94 (19)	N2—C6—C1	114.7 (7)
O10—Mo2—Mo4	91.6 (2)	C7—C6—C1	122.2 (8)
O10—Mo2—O2	102.5 (3)	N4—C20—H20	119.3
O10—Mo2—O1^i	175.0 (2)	N4—C20—C19	121.4 (9)
O10—Mo2—O1	100.1 (2)	C19—C20—H20	119.3
O10—Mo2—O11	104.0 (3)	C7—C8—H8	120.1
O10—Mo2—O12	101.3 (3)	C9—C8—H8	120.1
O12—Mo2—Mo3	36.03 (16)	C9—C8—C7	119.8 (8)
O12—Mo2—Mo4	124.19 (16)	C6—C7—C8	117.3 (8)
O12—Mo2—O1^i	78.0 (2)	C6—C7—H7	121.4
O12—Mo2—O1	77.4 (2)	C8—C7—H7	121.4
O3—Mo3—Mo2	119.72 (16)	N4—C16—C11	115.4 (7)
O3—Mo3—O2^i	83.7 (2)	N4—C16—C17	121.3 (8)
O3—Mo3—O1	78.1 (2)	C17—C16—C11	123.2 (8)
O3—Mo3—O12	147.0 (2)	N5—C11—C16	115.3 (7)
O2^i—Mo3—Mo2	79.21 (13)	N5—C11—C12	123.0 (9)
O1—Mo3—Mo2	41.65 (13)	C12—C11—C16	121.7 (8)
O1—Mo3—O2^i	71.84 (19)	C8—C9—H9	120.2
O4^ii—Mo3—Mo2	135.46 (18)	C8—C9—C10	119.5 (9)
O4^ii—Mo3—O3	100.3 (2)	C10—C9—H9	120.2
O4^ii—Mo3—O2^i	87.2 (2)	C16—C17—H17	120.2
O4^ii—Mo3—O1	159.1 (2)	C18—C17—C16	119.5 (9)
O4^ii—Mo3—O12	100.2 (2)	C18—C17—H17	120.2
O9—Mo3—Mo2	85.49 (19)	N2—C10—C9	121.4 (8)
O9—Mo3—O3	102.8 (3)	N2—C10—H10	119.3
O9—Mo3—O2^i	164.6 (2)	C9—C10—H10	119.3
O9—Mo3—O1	95.6 (2)	N1—C5—H5	119.0
O9—Mo3—O4^ii	105.1 (3)	N1—C5—C4	121.9 (9)
O9—Mo3—O12	96.5 (2)	C4—C5—H5	119.0
O12—Mo3—Mo2	35.31 (15)	C15—C14—H14	120.8
O12—Mo3—O2^i	71.8 (2)	C13—C14—H14	120.8
O12—Mo3—O1	73.6 (2)	C13—C14—C15	118.5 (9)
O2—Mo4—Mo2	34.37 (15)	C11—C12—H12	120.7
O2—Mo4—O1	72.5 (2)	C11—C12—C13	118.6 (10)
O2—Mo4—O12^i	71.5 (2)	C13—C12—H12	120.7
O1—Mo4—Mo2	41.54 (13)	N5—C15—C14	123.0 (9)
O1—Mo4—O12^i	72.08 (18)	N5—C15—H15	118.5
O7—Mo4—Mo2	85.7 (2)	C14—C15—H15	118.5
O7—Mo4—O2	96.8 (2)	N1—C1—C6	115.8 (7)
O7—Mo4—O1	95.6 (2)	N1—C1—C2	120.6 (8)
O7—Mo4—O8	104.0 (3)	C2—C1—C6	123.6 (8)
O7—Mo4—O6	101.5 (3)	C1—C2—H2	120.7
O7—Mo4—O12^i	164.9 (2)	C1—C2—C3	118.7 (9)
O8—Mo4—Mo2	137.0 (2)	C3—C2—H2	120.7
O8—Mo4—O2	102.6 (3)	C14—C13—C12	118.7 (9)
O8—Mo4—O1	160.3 (3)	C14—C13—H13	120.7
O8—Mo4—O6	100.3 (3)	C12—C13—H13	120.7
O8—Mo4—O12^i	88.2 (2)	C5—C4—H4	120.6
O6—Mo4—Mo2	118.94 (17)	C5—C4—C3	118.8 (9)
O6—Mo4—O2	146.1 (2)	C3—C4—H4	120.6
O6—Mo4—O1	77.4 (2)	C20—C19—H19	120.1
O6—Mo4—O12^i	84.7 (2)	C18—C19—C20	119.8 (10)
O12^i—Mo4—Mo2	79.23 (13)	C18—C19—H19	120.1
O13—Co5—N1	168.4 (2)	C17—C18—C19	119.0 (9)
O13—Co5—N2	92.1 (2)	C17—C18—H18	120.5
O13—Co5—N4	91.2 (3)	C19—C18—H18	120.5
O13—Co5—O4	89.0 (2)	C2—C3—H3	120.1
O13—Co5—N5	88.2 (2)	C4—C3—C2	119.9 (9)
N1—Co5—N5	88.7 (3)	C4—C3—H3	120.1
N2—Co5—N1	77.1 (3)	Mo4—O6—Mo10	120.9 (3)
N2—Co5—N5	96.1 (3)	Mo2—O11—Mo10^i	119.7 (3)
N4—Co5—N1	99.0 (3)	Mo2—O12—Mo3	108.7 (3)
N4—Co5—N2	172.2 (3)	Mo2—O12—Mo4^i	110.3 (2)
N4—Co5—O4	94.0 (3)	Mo3—O12—Mo4^i	104.1 (2)
N4—Co5—N5	77.0 (3)
Mo2—Mo3—O3—Mo10	20.3 (4)	C20—N4—C16—C17	0.8 (12)
Mo2—Mo4—O6—Mo10	−17.3 (4)	C20—C19—C18—C17	−2.4 (15)
Mo3—Mo2—O11—Mo10^i	−75.6 (3)	C8—C9—C10—N2	1.5 (13)
Mo4—Mo2—O11—Mo10^i	74.4 (4)	C7—C6—C1—N1	−169.2 (8)
Co5—N1—C5—C4	178.9 (7)	C7—C6—C1—C2	10.1 (13)
Co5—N1—C1—C6	−1.4 (9)	C7—C8—C9—C10	−3.6 (13)
Co5—N1—C1—C2	179.2 (7)	C16—N4—C20—C19	−1.7 (13)
Co5—N2—C6—C7	165.8 (6)	C16—C11—C12—C13	177.8 (8)
Co5—N2—C6—C1	−12.6 (8)	C16—C17—C18—C19	1.5 (14)
Co5—N2—C10—C9	−165.4 (6)	C11—N5—C15—C14	−2.1 (13)
Co5—N4—C20—C19	172.7 (7)	C11—C16—C17—C18	179.8 (8)
Co5—N4—C16—C11	5.4 (9)	C11—C12—C13—C14	0.5 (14)
Co5—N4—C16—C17	−174.1 (6)	C9—C8—C7—C6	3.0 (13)
Co5—N5—C11—C16	3.3 (9)	C17—C16—C11—N5	173.8 (8)
Co5—N5—C11—C12	−178.3 (7)	C17—C16—C11—C12	−4.7 (12)
Co5—N5—C15—C14	177.5 (7)	C10—N2—C6—C7	−1.9 (12)
O13—Mo10—O3—Mo3	73.4 (3)	C10—N2—C6—C1	179.7 (7)
O3—Mo10—O13—Co5	137.6 (6)	C5—N1—C1—C6	178.6 (7)
O2—Mo2—O11—Mo10^i	75.1 (3)	C5—N1—C1—C2	−0.8 (12)
O2^i—Mo3—O3—Mo10	94.0 (3)	C5—C4—C3—C2	−1.9 (16)
O2—Mo4—O6—Mo10	−47.0 (6)	C15—N5—C11—C16	−177.1 (7)
N1—C5—C4—C3	2.5 (15)	C15—N5—C11—C12	1.3 (12)
N1—C1—C2—C3	1.3 (14)	C15—C14—C13—C12	−1.1 (14)
O1—Mo10—O13—Co5	−150.4 (5)	C1—N1—C5—C4	−1.1 (13)
O1—Mo10—O3—Mo3	−19.6 (3)	C1—C6—C7—C8	178.1 (7)
O1—Mo2—O11—Mo10^i	−3.2 (7)	C1—C2—C3—C4	0.1 (16)
O1^i—Mo2—O11—Mo10^i	0.0 (3)	C13—C14—C15—N5	2.0 (14)
O1—Mo3—O3—Mo10	21.3 (3)	O7—Mo4—O6—Mo10	74.1 (4)
O1—Mo4—O6—Mo10	−19.1 (3)	O9—Mo3—O3—Mo10	−71.8 (4)
N2—C6—C7—C8	−0.2 (13)	O5—Mo10—O13—Co5	29.2 (6)
N2—C6—C1—N1	9.2 (10)	O5—Mo10—O3—Mo3	−178.4 (3)
N2—C6—C1—C2	−171.4 (8)	O8—Mo4—O6—Mo10	−179.1 (3)
N4—C20—C19—C18	2.6 (15)	O6—Mo10—O13—Co5	−77.4 (6)
N4—C16—C11—N5	−5.8 (10)	O6—Mo10—O3—Mo3	−38.5 (5)
N4—C16—C11—C12	175.8 (8)	O11^i—Mo10—O13—Co5	−149.2 (6)
N4—C16—C17—C18	−0.7 (13)	O11^i—Mo10—O3—Mo3	−91.7 (3)
O4^ii—Mo3—O3—Mo10	180.0 (3)	O10—Mo2—O11—Mo10^i	179.9 (3)
N5—C11—C12—C13	−0.5 (14)	O12—Mo2—O11—Mo10^i	−76.7 (3)
C6—N2—C10—C9	1.3 (12)	O12—Mo3—O3—Mo10	52.4 (6)
C6—C1—C2—C3	−178.1 (9)	O12^i—Mo4—O6—Mo10	−91.9 (3)
C20—N4—C16—C11	−179.7 (7)

Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+2, −y, −z+1.