Rerefinement of catena-poly[triethyl­ammonium [triphenyl­stannate(IV)-μ-2,5-thio­phene­dicarboxyl­ato]] in the space group Pc

Ng, S.W.

doi:10.1107/S1600536805035622

Rerefinement of catena-poly[triethylammonium [triphenylstannate(IV)-μ-2,5-thiophenedicarboxylato]] in the space group Pc

The structure of the title compound, {(C₆H₁₅N)[Sn(C₆H₅)₃(C₆H₂O₄S)]}_n, when refined in Pc, comprises two independent formula units. The polyanionic chain has both Sn atoms in trans-C₃SnO₂ trigonal–bipyramidal geometries.

Read article Similar articles

Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805035622/tk6281sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536805035622/tk6281Isup2.hkl Contains datablock I

CCDC reference: 294014

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.015 Å
R factor = 0.041
wR factor = 0.111
Data-to-parameter ratio = 11.8

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.69 Ratio

Author Response: The ethyl C atoms of the cation have somewhat larger temperature factors.


Alert level B
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C27
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C25
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C28

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.27
PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent .....          ?
PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature        293 K
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.90 Ratio
PLAT223_ALERT_4_C Large Solvent/Anion  H     Ueq(max)/Ueq(min) ...       3.47 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C11
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C26
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C29
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        C53
PLAT243_ALERT_4_C High  'Solvent' Ueq as Compared to Neighbors for        C57
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         N1
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         N2
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         15
PLAT412_ALERT_2_C Short Intra XH3 .. XHn     H50C   ..  H53A    ..       1.87 Ang.
PLAT731_ALERT_1_C Bond    Calc   1.501(19), Rep    1.502(8) ......       2.37 su-Rat
              N1   -C53     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc   1.522(17), Rep    1.522(8) ......       2.12 su-Rat
              C51  -C52     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.50(3), Rep    1.497(9) ......       3.33 su-Rat
              C53  -C54     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.52(2), Rep    1.522(9) ......       2.22 su-Rat
              C55  -C56     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc   1.512(17), Rep    1.512(8) ......       2.12 su-Rat
              C59  -C60     1.555   1.555

Alert level G
REFLT03_ALERT_4_G  WARNING: Large fraction of Friedel related reflns may
                     be needed to determine absolute structure
           From the CIF: _diffrn_reflns_theta_max           25.00
           From the CIF: _reflns_number_total               7034
           Count of symmetry unique reflns         5162
           Completeness (_total/calc)            136.27%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      1872
           Fraction of Friedel pairs measured     0.363
           Are heavy atom types Z>Si present        yes

   1 ALERT level A = In general: serious problem
   3 ALERT level B = Potentially serious problem
  22 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

  10 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1996); cell refinement: SAINT (Bruker, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

catena-poly[triethylammonium [triphenylstannate(IV)-µ-2,5-thiophenedicarboxylato]] top

Crystal data top

(C₆H₁₅N)[Sn(C₆H₅)₃(C₆H₂O₄S)]	F(000) = 1272
M_r = 622.32	D_x = 1.414 Mg m⁻³
Monoclinic, Pc	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P -2yc	Cell parameters from 846 reflections
a = 18.354 (4) Å	θ = 2.4–23.6°
b = 9.658 (2) Å	µ = 0.98 mm⁻¹
c = 18.982 (3) Å	T = 293 K
β = 119.69 (2)°	Block, colorless
V = 2923 (1) Å³	0.25 × 0.14 × 0.07 mm
Z = 4

Data collection top

Bruker SMART area-detector diffractometer	7034 independent reflections
Radiation source: fine-focus sealed tube	5750 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.043
φ and ω scans	θ_max = 25.0°, θ_min = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −21→17
T_min = 0.792, T_max = 0.935	k = −11→11
14964 measured reflections	l = −21→22

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.041	H-atom parameters constrained
wR(F²) = 0.111	w = 1/[σ²(F_o²) + (0.0616P)²] where P = (F_o² + 2F_c²)/3
S = 1.03	(Δ/σ)_max = 0.001
7034 reflections	Δρ_max = 0.84 e Å⁻³
595 parameters	Δρ_min = −0.37 e Å⁻³
386 restraints	Absolute structure: Flack (1983), from 1284 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.01 (3)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Sn1	0.50000 (3)	0.54737 (5)	0.50000 (2)	0.03666 (16)
Sn2	−0.03219 (3)	0.03827 (5)	0.00773 (3)	0.04380 (18)
S1	0.69143 (13)	0.8292 (2)	0.76148 (14)	0.0462 (5)
S2	0.22403 (13)	0.2842 (2)	0.22456 (13)	0.0480 (5)
O1	0.5712 (4)	0.6532 (5)	0.6230 (3)	0.0448 (13)
O2	0.4553 (4)	0.7658 (6)	0.6025 (4)	0.0568 (16)
O3	0.8431 (4)	0.9426 (5)	0.9224 (4)	0.0589 (17)
O4	0.7786 (4)	1.1445 (6)	0.9049 (4)	0.0569 (15)
O5	0.4413 (4)	0.4385 (5)	0.3827 (3)	0.0488 (14)
O6	0.3139 (4)	0.4765 (8)	0.3661 (4)	0.071 (2)
O7	0.0942 (4)	0.1239 (6)	0.0924 (4)	0.0564 (15)
O8	0.1636 (4)	0.0751 (7)	0.0269 (4)	0.0649 (18)
N1	0.6925 (4)	1.3621 (7)	0.8031 (4)	0.063 (2)
H1N	0.7149	1.2892	0.8377	0.076*
N2	0.2095 (5)	0.1153 (8)	−0.0870 (5)	0.090 (3)
H2N	0.1955	0.1036	−0.0476	0.108*
C1	0.6183 (3)	0.4659 (5)	0.5204 (3)	0.0397 (18)
C2	0.6203 (3)	0.3442 (5)	0.4823 (3)	0.047 (2)
H2	0.5706	0.2987	0.4475	0.057*
C3	0.6966 (4)	0.2904 (5)	0.4963 (4)	0.066 (3)
H3	0.6979	0.2089	0.4708	0.080*
C4	0.7709 (3)	0.3584 (7)	0.5483 (4)	0.079 (3)
H4	0.8219	0.3224	0.5577	0.095*
C5	0.7689 (3)	0.4802 (7)	0.5864 (4)	0.073 (3)
H5	0.8186	0.5257	0.6212	0.087*
C6	0.6926 (3)	0.5339 (5)	0.5724 (4)	0.056 (2)
H6	0.6913	0.6154	0.5979	0.067*
C7	0.4772 (4)	0.7471 (5)	0.4428 (4)	0.050 (2)
C8	0.5355 (4)	0.8506 (6)	0.4843 (3)	0.067 (3)
H8	0.5804	0.8334	0.5358	0.080*
C9	0.5268 (5)	0.9799 (5)	0.4488 (5)	0.086 (3)
H9	0.5658	1.0492	0.4766	0.103*
C10	0.4597 (5)	1.0057 (6)	0.3718 (5)	0.084 (3)
H10	0.4538	1.0922	0.3480	0.100*
C11	0.4013 (4)	0.9021 (8)	0.3303 (4)	0.097 (4)
H11	0.3564	0.9193	0.2788	0.116*
C12	0.4101 (4)	0.7728 (7)	0.3658 (4)	0.068 (3)
H12	0.3710	0.7035	0.3380	0.081*
C13	0.4457 (4)	0.4064 (4)	0.5493 (3)	0.0414 (19)
C14	0.4046 (4)	0.4474 (4)	0.5908 (4)	0.058 (2)
H14	0.3948	0.5408	0.5945	0.070*
C15	0.3784 (4)	0.3487 (6)	0.6267 (4)	0.074 (3)
H15	0.3509	0.3761	0.6544	0.089*
C16	0.3931 (4)	0.2090 (6)	0.6211 (4)	0.072 (3)
H16	0.3755	0.1430	0.6451	0.086*
C17	0.4341 (4)	0.1681 (4)	0.5796 (4)	0.073 (3)
H17	0.4440	0.0746	0.5759	0.087*
C18	0.4604 (4)	0.2668 (5)	0.5437 (4)	0.056 (2)
H18	0.4879	0.2394	0.5159	0.067*
C19	−0.0409 (4)	0.1644 (5)	−0.0897 (3)	0.048 (2)
C20	−0.0762 (4)	0.1136 (5)	−0.1684 (3)	0.062 (2)
H20	−0.0961	0.0231	−0.1797	0.075*
C21	−0.0818 (4)	0.1979 (7)	−0.2302 (3)	0.074 (3)
H21	−0.1054	0.1639	−0.2828	0.089*
C22	−0.0520 (5)	0.3331 (7)	−0.2134 (4)	0.082 (3)
H22	−0.0557	0.3895	−0.2547	0.099*
C23	−0.0167 (5)	0.3839 (5)	−0.1347 (4)	0.078 (3)
H23	0.0032	0.4744	−0.1234	0.094*
C24	−0.0111 (4)	0.2996 (6)	−0.0729 (3)	0.067 (3)
H24	0.0125	0.3336	−0.0203	0.080*
C25	0.0143 (5)	−0.1681 (6)	0.0321 (4)	0.055 (2)
C26	0.0814 (6)	−0.2109 (9)	0.0229 (6)	0.134 (5)
H26	0.1037	−0.1517	−0.0002	0.161*
C27	0.1153 (6)	−0.3423 (11)	0.0482 (8)	0.169 (7)
H27	0.1602	−0.3710	0.0421	0.203*
C28	0.0820 (7)	−0.4309 (7)	0.0828 (7)	0.116 (5)
H28	0.1046	−0.5189	0.0997	0.139*
C29	0.0149 (8)	−0.3881 (8)	0.0920 (6)	0.133 (5)
H29	−0.0074	−0.4474	0.1151	0.159*
C30	−0.0189 (5)	−0.2567 (8)	0.0667 (6)	0.101 (4)
H30	−0.0638	−0.2280	0.0728	0.121*
C31	−0.0692 (4)	0.1118 (6)	0.0941 (4)	0.053 (2)
C32	−0.0178 (4)	0.2035 (7)	0.1550 (4)	0.073 (3)
H32	0.0323	0.2333	0.1590	0.087*
C33	−0.0413 (5)	0.2508 (7)	0.2101 (4)	0.089 (3)
H33	−0.0070	0.3121	0.2509	0.107*
C34	−0.1162 (5)	0.2063 (8)	0.2041 (4)	0.089 (4)
H34	−0.1319	0.2379	0.2409	0.107*
C35	−0.1676 (4)	0.1146 (8)	0.1432 (5)	0.083 (3)
H35	−0.2177	0.0848	0.1392	0.099*
C36	−0.1441 (4)	0.0673 (6)	0.0881 (4)	0.068 (3)
H36	−0.1784	0.0059	0.0473	0.082*
C37	0.5315 (5)	0.7442 (8)	0.6401 (5)	0.0393 (18)
C38	0.5834 (5)	0.8292 (7)	0.7127 (4)	0.0357 (17)
C39	0.5559 (5)	0.9209 (8)	0.7492 (5)	0.0446 (19)
H39	0.4995	0.9346	0.7324	0.054*
C40	0.6208 (6)	0.9928 (8)	0.8146 (5)	0.046 (2)
H40	0.6116	1.0588	0.8449	0.055*
C41	0.6993 (5)	0.9556 (7)	0.8290 (5)	0.0395 (18)
C42	0.7787 (6)	1.0203 (8)	0.8887 (5)	0.043 (2)
C43	0.3597 (5)	0.4244 (8)	0.3439 (5)	0.046 (2)
C44	0.3261 (5)	0.3359 (8)	0.2698 (5)	0.0419 (19)
C45	0.3626 (5)	0.2929 (8)	0.2258 (5)	0.0434 (19)
H45	0.4176	0.3143	0.2400	0.052*
C46	0.3097 (5)	0.2136 (9)	0.1575 (5)	0.048 (2)
H46	0.3262	0.1745	0.1228	0.057*
C47	0.2313 (5)	0.2003 (8)	0.1476 (4)	0.0365 (17)
C48	0.1576 (6)	0.1273 (8)	0.0828 (5)	0.048 (2)
C49	0.7612 (6)	1.4533 (11)	0.8081 (6)	0.096 (4)
H49A	0.7368	1.5308	0.7713	0.115*
H49B	0.7955	1.4011	0.7916	0.115*
C50	0.8164 (7)	1.5073 (13)	0.8946 (7)	0.106 (4)
H50A	0.8592	1.5667	0.8962	0.159*
H50B	0.8421	1.4307	0.9308	0.159*
H50C	0.7825	1.5585	0.9110	0.159*
C51	0.6412 (6)	1.3109 (10)	0.7174 (5)	0.082 (3)
H51A	0.6204	1.3897	0.6810	0.099*
H51B	0.5932	1.2601	0.7121	0.099*
C52	0.6913 (8)	1.2177 (10)	0.6923 (6)	0.080 (3)
H52A	0.6563	1.1885	0.6371	0.120*
H52B	0.7106	1.1381	0.7270	0.120*
H52C	0.7386	1.2679	0.6968	0.120*
C53	0.6392 (9)	1.4477 (14)	0.8261 (11)	0.165 (8)
H53A	0.6748	1.4919	0.8780	0.198*
H53B	0.6116	1.5200	0.7860	0.198*
C54	0.5743 (11)	1.362 (2)	0.8319 (13)	0.176 (8)
H54A	0.5428	1.4198	0.8484	0.264*
H54B	0.6013	1.2898	0.8710	0.264*
H54C	0.5371	1.3222	0.7799	0.264*
C55	0.1301 (6)	0.1138 (15)	−0.1647 (7)	0.135 (6)
H55A	0.0957	0.1909	−0.1657	0.163*
H55B	0.1001	0.0291	−0.1683	0.163*
C56	0.1422 (12)	0.124 (2)	−0.2383 (7)	0.168 (8)
H56A	0.0886	0.1209	−0.2869	0.252*
H56B	0.1758	0.0473	−0.2381	0.252*
H56C	0.1699	0.2091	−0.2364	0.252*
C57	0.2653 (7)	−0.0021 (10)	−0.0788 (9)	0.120 (5)
H57A	0.3160	0.0036	−0.0264	0.143*
H57B	0.2813	0.0057	−0.1203	0.143*
C58	0.2244 (9)	−0.1422 (10)	−0.0864 (9)	0.116 (5)
H58A	0.2636	−0.2143	−0.0789	0.174*
H58B	0.1758	−0.1505	−0.1393	0.174*
H58C	0.2079	−0.1502	−0.0458	0.174*
C59	0.2552 (6)	0.2494 (9)	−0.0694 (7)	0.094 (4)
H59A	0.2694	0.2675	−0.1114	0.113*
H59B	0.3072	0.2415	−0.0183	0.113*
C60	0.2057 (9)	0.3706 (10)	−0.0646 (9)	0.120 (5)
H60A	0.2385	0.4536	−0.0530	0.180*
H60B	0.1925	0.3545	−0.0223	0.180*
H60C	0.1548	0.3806	−0.1155	0.180*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.0328 (3)	0.0367 (3)	0.0338 (3)	−0.0041 (3)	0.0115 (3)	−0.0040 (3)
Sn2	0.0375 (4)	0.0451 (3)	0.0384 (4)	−0.0072 (3)	0.0109 (3)	−0.0039 (3)
S1	0.0329 (11)	0.0449 (11)	0.0520 (13)	−0.0019 (9)	0.0143 (10)	−0.0080 (10)
S2	0.0312 (11)	0.0695 (13)	0.0381 (11)	−0.0073 (11)	0.0132 (10)	−0.0116 (11)
O1	0.047 (4)	0.043 (3)	0.038 (3)	−0.001 (3)	0.016 (3)	−0.009 (2)
O2	0.036 (4)	0.069 (4)	0.056 (4)	−0.015 (3)	0.015 (3)	−0.020 (3)
O3	0.045 (4)	0.045 (3)	0.070 (5)	−0.009 (3)	0.015 (3)	−0.004 (3)
O4	0.053 (4)	0.046 (3)	0.047 (4)	−0.010 (3)	0.007 (3)	−0.007 (3)
O5	0.036 (3)	0.062 (3)	0.033 (3)	−0.011 (3)	0.005 (3)	−0.008 (3)
O6	0.041 (4)	0.113 (5)	0.049 (4)	0.007 (4)	0.014 (3)	−0.024 (4)
O7	0.040 (3)	0.073 (4)	0.056 (4)	−0.018 (3)	0.023 (3)	−0.016 (3)
O8	0.067 (4)	0.083 (4)	0.047 (4)	−0.028 (4)	0.030 (4)	−0.032 (3)
N1	0.057 (5)	0.075 (5)	0.048 (5)	0.016 (5)	0.019 (4)	−0.001 (4)
N2	0.058 (6)	0.151 (9)	0.069 (6)	0.031 (7)	0.038 (5)	0.016 (7)
C1	0.038 (4)	0.039 (4)	0.043 (4)	0.002 (3)	0.021 (4)	0.008 (3)
C2	0.041 (4)	0.044 (4)	0.053 (5)	0.004 (4)	0.021 (4)	0.001 (4)
C3	0.072 (6)	0.062 (5)	0.077 (6)	0.014 (5)	0.046 (5)	0.006 (5)
C4	0.061 (6)	0.097 (6)	0.085 (7)	0.022 (5)	0.040 (5)	0.010 (5)
C5	0.058 (6)	0.076 (6)	0.083 (7)	−0.001 (5)	0.034 (5)	−0.011 (5)
C6	0.041 (5)	0.057 (5)	0.067 (6)	−0.005 (4)	0.025 (5)	−0.006 (4)
C7	0.062 (5)	0.046 (4)	0.049 (5)	0.010 (4)	0.034 (4)	0.007 (4)
C8	0.087 (6)	0.045 (4)	0.078 (6)	−0.007 (5)	0.049 (5)	0.001 (4)
C9	0.107 (8)	0.077 (6)	0.092 (7)	−0.008 (6)	0.063 (6)	0.003 (5)
C10	0.103 (8)	0.072 (5)	0.095 (7)	0.018 (6)	0.064 (6)	0.011 (5)
C11	0.100 (8)	0.117 (8)	0.094 (7)	0.020 (6)	0.063 (6)	0.017 (6)
C12	0.067 (6)	0.080 (6)	0.060 (5)	0.010 (5)	0.034 (5)	0.024 (5)
C13	0.032 (4)	0.046 (4)	0.035 (4)	−0.007 (3)	0.008 (3)	0.002 (3)
C14	0.059 (5)	0.057 (5)	0.068 (6)	−0.005 (4)	0.038 (5)	−0.002 (4)
C15	0.076 (6)	0.093 (6)	0.061 (6)	−0.012 (5)	0.040 (5)	0.000 (5)
C16	0.079 (6)	0.072 (5)	0.065 (6)	−0.014 (5)	0.036 (5)	0.016 (5)
C17	0.071 (6)	0.062 (5)	0.077 (6)	−0.022 (5)	0.030 (5)	0.008 (5)
C18	0.065 (6)	0.039 (4)	0.055 (5)	−0.008 (4)	0.023 (4)	−0.002 (4)
C19	0.047 (5)	0.045 (4)	0.045 (5)	−0.004 (4)	0.018 (4)	0.000 (4)
C20	0.062 (6)	0.067 (5)	0.051 (5)	−0.006 (5)	0.023 (4)	0.001 (4)
C21	0.070 (6)	0.092 (6)	0.056 (5)	0.002 (5)	0.027 (5)	0.008 (5)
C22	0.066 (6)	0.100 (7)	0.078 (7)	0.000 (6)	0.033 (5)	0.032 (6)
C23	0.074 (6)	0.060 (5)	0.092 (7)	0.004 (5)	0.035 (5)	0.014 (5)
C24	0.066 (6)	0.061 (5)	0.074 (6)	−0.013 (5)	0.036 (5)	−0.002 (5)
C25	0.051 (5)	0.051 (4)	0.042 (5)	−0.013 (4)	0.008 (4)	−0.010 (4)
C26	0.124 (9)	0.102 (8)	0.187 (10)	0.005 (7)	0.085 (8)	0.003 (7)
C27	0.146 (11)	0.141 (10)	0.213 (12)	0.028 (8)	0.083 (9)	−0.009 (8)
C28	0.114 (9)	0.074 (6)	0.125 (9)	0.021 (6)	0.033 (7)	0.008 (6)
C29	0.145 (10)	0.108 (8)	0.136 (9)	−0.006 (8)	0.062 (8)	0.019 (7)
C30	0.102 (8)	0.080 (6)	0.120 (8)	0.000 (6)	0.055 (7)	0.024 (6)
C31	0.056 (5)	0.053 (4)	0.051 (5)	−0.003 (4)	0.027 (4)	0.000 (4)
C32	0.080 (6)	0.079 (5)	0.071 (6)	−0.004 (5)	0.046 (5)	−0.025 (5)
C33	0.100 (7)	0.086 (6)	0.075 (6)	0.002 (6)	0.039 (6)	−0.017 (5)
C34	0.099 (8)	0.101 (7)	0.084 (7)	0.025 (6)	0.057 (6)	0.017 (6)
C35	0.074 (6)	0.091 (6)	0.099 (7)	0.008 (6)	0.055 (6)	0.018 (6)
C36	0.063 (6)	0.087 (6)	0.059 (6)	−0.004 (5)	0.034 (5)	0.002 (5)
C37	0.036 (4)	0.043 (4)	0.033 (4)	−0.009 (4)	0.013 (4)	−0.007 (3)
C38	0.032 (4)	0.041 (4)	0.029 (4)	−0.008 (3)	0.011 (3)	−0.004 (3)
C39	0.033 (4)	0.055 (4)	0.049 (5)	−0.005 (4)	0.022 (4)	−0.010 (4)
C40	0.049 (5)	0.049 (4)	0.039 (4)	−0.007 (4)	0.022 (4)	−0.007 (4)
C41	0.038 (4)	0.034 (4)	0.036 (4)	−0.008 (3)	0.011 (3)	−0.001 (3)
C42	0.045 (5)	0.043 (4)	0.026 (4)	−0.008 (4)	0.007 (4)	−0.005 (3)
C43	0.036 (4)	0.052 (4)	0.041 (5)	0.002 (4)	0.013 (4)	−0.002 (4)
C44	0.033 (4)	0.045 (4)	0.035 (4)	−0.006 (3)	0.008 (3)	0.003 (3)
C45	0.038 (4)	0.055 (4)	0.035 (4)	−0.007 (4)	0.016 (4)	0.007 (4)
C46	0.043 (5)	0.062 (5)	0.034 (4)	−0.001 (4)	0.016 (4)	−0.004 (4)
C47	0.032 (4)	0.050 (4)	0.022 (4)	−0.006 (3)	0.009 (3)	0.001 (3)
C48	0.047 (5)	0.055 (5)	0.043 (5)	−0.008 (4)	0.024 (4)	−0.009 (4)
C49	0.099 (8)	0.089 (7)	0.091 (7)	−0.003 (6)	0.040 (6)	0.001 (6)
C50	0.097 (8)	0.115 (7)	0.092 (8)	0.001 (7)	0.037 (6)	−0.025 (6)
C51	0.083 (7)	0.092 (7)	0.051 (6)	0.015 (6)	0.018 (5)	0.005 (5)
C52	0.098 (7)	0.085 (6)	0.068 (6)	0.010 (6)	0.050 (5)	0.007 (5)
C53	0.167 (12)	0.181 (12)	0.161 (11)	−0.003 (8)	0.093 (9)	−0.029 (8)
C54	0.188 (12)	0.189 (12)	0.173 (11)	−0.005 (9)	0.107 (9)	−0.011 (8)
C55	0.108 (9)	0.140 (9)	0.144 (10)	0.013 (7)	0.052 (8)	−0.025 (8)
C56	0.177 (12)	0.161 (10)	0.138 (11)	0.001 (9)	0.056 (8)	0.002 (8)
C57	0.110 (9)	0.153 (9)	0.105 (8)	0.019 (7)	0.061 (7)	0.012 (7)
C58	0.118 (9)	0.129 (8)	0.114 (8)	0.042 (7)	0.067 (7)	−0.008 (7)
C59	0.073 (7)	0.125 (8)	0.088 (7)	−0.017 (6)	0.042 (6)	0.009 (6)
C60	0.117 (9)	0.120 (8)	0.131 (9)	−0.023 (7)	0.067 (7)	−0.002 (7)

Geometric parameters (Å, º) top

Sn1—C1	2.157 (4)	C24—H24	0.9300
Sn1—C7	2.150 (4)	C25—C26	1.3900
Sn1—C13	2.155 (4)	C25—C30	1.3900
Sn1—O1	2.276 (5)	C26—C27	1.3900
Sn1—O5	2.203 (5)	C26—H26	0.9300
Sn2—C19	2.154 (4)	C27—C28	1.3900
Sn2—C25	2.127 (6)	C27—H27	0.9300
Sn2—C31	2.180 (5)	C28—C29	1.3900
Sn2—O7	2.226 (6)	C28—H28	0.9300
Sn2—O3ⁱ	2.246 (6)	C29—C30	1.3900
S1—C41	1.723 (8)	C29—H29	0.9300
S1—C38	1.724 (8)	C30—H30	0.9300
S2—C44	1.703 (8)	C31—C32	1.3900
S2—C47	1.732 (7)	C31—C36	1.3900
O1—C37	1.282 (9)	C32—C33	1.3900
O2—C37	1.233 (10)	C32—H32	0.9300
O3—C42	1.273 (10)	C33—C34	1.3900
O3—Sn2ⁱⁱ	2.246 (6)	C33—H33	0.9300
O4—C42	1.238 (9)	C34—C35	1.3900
O5—C43	1.307 (10)	C34—H34	0.9300
O6—C43	1.220 (10)	C35—C36	1.3900
O7—C48	1.266 (10)	C35—H35	0.9300
O8—C48	1.229 (9)	C36—H36	0.9300
N1—C53	1.502 (8)	C37—C38	1.477 (10)
N1—C49	1.503 (8)	C38—C39	1.365 (10)
N1—C51	1.504 (7)	C39—C40	1.406 (12)
N1—H1N	0.9100	C39—H39	0.9300
N2—C55	1.473 (8)	C40—C41	1.374 (12)
N2—C57	1.483 (8)	C40—H40	0.9300
N2—C59	1.487 (7)	C41—C42	1.470 (11)
N2—H2N	0.9100	C43—C44	1.493 (11)
C1—C2	1.3900	C44—C45	1.370 (11)
C1—C6	1.3900	C45—C46	1.401 (11)
C2—C3	1.3900	C45—H45	0.9300
C2—H2	0.9300	C46—C47	1.362 (11)
C3—C4	1.3900	C46—H46	0.9300
C3—H3	0.9300	C47—C48	1.481 (11)
C4—C5	1.3900	C49—C50	1.532 (9)
C4—H4	0.9300	C49—H49A	0.9700
C5—C6	1.3900	C49—H49B	0.9700
C5—H5	0.9300	C50—H50A	0.9600
C6—H6	0.9300	C50—H50B	0.9600
C7—C8	1.3900	C50—H50C	0.9600
C7—C12	1.3900	C51—C52	1.522 (8)
C8—C9	1.3900	C51—H51A	0.9700
C8—H8	0.9300	C51—H51B	0.9700
C9—C10	1.3900	C52—H52A	0.9600
C9—H9	0.9300	C52—H52B	0.9600
C10—C11	1.3900	C52—H52C	0.9600
C10—H10	0.9300	C53—C54	1.497 (9)
C11—C12	1.3900	C53—H53A	0.9700
C11—H11	0.9300	C53—H53B	0.9700
C12—H12	0.9300	C54—H54A	0.9600
C13—C14	1.3900	C54—H54B	0.9600
C13—C18	1.3900	C54—H54C	0.9600
C14—C15	1.3900	C55—C56	1.522 (9)
C14—H14	0.9300	C55—H55A	0.9700
C15—C16	1.3900	C55—H55B	0.9700
C15—H15	0.9300	C56—H56A	0.9600
C16—C17	1.3900	C56—H56B	0.9600
C16—H16	0.9300	C56—H56C	0.9600
C17—C18	1.3900	C57—C58	1.519 (9)
C17—H17	0.9300	C57—H57A	0.9700
C18—H18	0.9300	C57—H57B	0.9700
C19—C20	1.3900	C58—H58A	0.9600
C19—C24	1.3900	C58—H58B	0.9600
C20—C21	1.3900	C58—H58C	0.9600
C20—H20	0.9300	C59—C60	1.512 (8)
C21—C22	1.3900	C59—H59A	0.9700
C21—H21	0.9300	C59—H59B	0.9700
C22—C23	1.3900	C60—H60A	0.9600
C22—H22	0.9300	C60—H60B	0.9600
C23—C24	1.3900	C60—H60C	0.9600
C23—H23	0.9300

C1—Sn1—C7	110.2 (2)	C25—C30—H30	120.0
C1—Sn1—C13	109.5 (2)	C32—C31—C36	120.0
C1—Sn1—O1	87.9 (2)	C32—C31—Sn2	119.9 (3)
C1—Sn1—O5	87.3 (2)	C36—C31—Sn2	120.1 (3)
C7—Sn1—C13	140.3 (2)	C31—C32—C33	120.0
C7—Sn1—O1	89.1 (2)	C31—C32—H32	120.0
C7—Sn1—O5	92.4 (2)	C33—C32—H32	120.0
C13—Sn1—O1	89.6 (2)	C34—C33—C32	120.0
C13—Sn1—O5	92.1 (2)	C34—C33—H33	120.0
O1—Sn1—O5	175.2 (2)	C32—C33—H33	120.0
C19—Sn2—C25	124.6 (3)	C33—C34—C35	120.0
C19—Sn2—C31	122.9 (2)	C33—C34—H34	120.0
C19—Sn2—O3ⁱ	89.9 (2)	C35—C34—H34	120.0
C19—Sn2—O7	91.0 (2)	C34—C35—C36	120.0
C25—Sn2—C31	112.5 (3)	C34—C35—H35	120.0
C25—Sn2—O3ⁱ	85.8 (3)	C36—C35—H35	120.0
C25—Sn2—O7	91.7 (3)	C35—C36—C31	120.0
C31—Sn2—O3ⁱ	95.2 (2)	C35—C36—H36	120.0
C31—Sn2—O7	86.4 (2)	C31—C36—H36	120.0
O3ⁱ—Sn2—O7	177.4 (2)	O2—C37—O1	126.4 (7)
C41—S1—C38	92.8 (4)	O2—C37—C38	117.9 (7)
C44—S2—C47	92.2 (4)	O1—C37—C38	115.7 (7)
C37—O1—Sn1	117.2 (5)	C39—C38—C37	127.3 (7)
C42—O3—Sn2ⁱⁱ	118.7 (5)	C39—C38—S1	110.1 (6)
C43—O5—Sn1	118.0 (5)	C37—C38—S1	122.6 (6)
C48—O7—Sn2	127.5 (5)	C38—C39—C40	113.8 (8)
C53—N1—C49	107.9 (6)	C38—C39—H39	123.1
C53—N1—C51	110.3 (7)	C40—C39—H39	123.1
C49—N1—C51	108.5 (6)	C41—C40—C39	113.2 (7)
C53—N1—H1N	110.0	C41—C40—H40	123.4
C49—N1—H1N	110.0	C39—C40—H40	123.4
C51—N1—H1N	110.0	C40—C41—C42	125.7 (7)
C55—N2—C57	112.7 (7)	C40—C41—S1	110.1 (6)
C55—N2—C59	113.7 (7)	C42—C41—S1	124.1 (7)
C57—N2—C59	111.0 (6)	O4—C42—O3	124.1 (8)
C55—N2—H2N	106.2	O4—C42—C41	118.7 (8)
C57—N2—H2N	106.2	O3—C42—C41	117.1 (7)
C59—N2—H2N	106.2	O6—C43—O5	123.8 (8)
C2—C1—C6	120.0	O6—C43—C44	121.8 (8)
C2—C1—Sn1	119.9 (3)	O5—C43—C44	114.4 (7)
C6—C1—Sn1	120.1 (3)	C45—C44—C43	130.5 (7)
C1—C2—C3	120.0	C45—C44—S2	110.6 (6)
C1—C2—H2	120.0	C43—C44—S2	118.8 (6)
C3—C2—H2	120.0	C44—C45—C46	113.9 (7)
C4—C3—C2	120.0	C44—C45—H45	123.0
C4—C3—H3	120.0	C46—C45—H45	123.0
C2—C3—H3	120.0	C47—C46—C45	112.3 (7)
C3—C4—C5	120.0	C47—C46—H46	123.8
C3—C4—H4	120.0	C45—C46—H46	123.8
C5—C4—H4	120.0	C46—C47—C48	128.8 (7)
C6—C5—C4	120.0	C46—C47—S2	110.9 (6)
C6—C5—H5	120.0	C48—C47—S2	120.2 (6)
C4—C5—H5	120.0	O8—C48—O7	126.7 (8)
C5—C6—C1	120.0	O8—C48—C47	118.5 (8)
C5—C6—H6	120.0	O7—C48—C47	114.8 (7)
C1—C6—H6	120.0	N1—C49—C50	110.9 (7)
C8—C7—C12	120.0	N1—C49—H49A	109.5
C8—C7—Sn1	117.2 (3)	C50—C49—H49A	109.5
C12—C7—Sn1	122.7 (3)	N1—C49—H49B	109.5
C7—C8—C9	120.0	C50—C49—H49B	109.5
C7—C8—H8	120.0	H49A—C49—H49B	108.1
C9—C8—H8	120.0	C49—C50—H50A	109.5
C10—C9—C8	120.0	C49—C50—H50B	109.5
C10—C9—H9	120.0	H50A—C50—H50B	109.5
C8—C9—H9	120.0	C49—C50—H50C	109.5
C11—C10—C9	120.0	H50A—C50—H50C	109.5
C11—C10—H10	120.0	H50B—C50—H50C	109.5
C9—C10—H10	120.0	N1—C51—C52	112.5 (7)
C10—C11—C12	120.0	N1—C51—H51A	109.1
C10—C11—H11	120.0	C52—C51—H51A	109.1
C12—C11—H11	120.0	N1—C51—H51B	109.1
C11—C12—C7	120.0	C52—C51—H51B	109.1
C11—C12—H12	120.0	H51A—C51—H51B	107.8
C7—C12—H12	120.0	C51—C52—H52A	109.5
C14—C13—C18	120.0	C51—C52—H52B	109.5
C14—C13—Sn1	124.3 (3)	H52A—C52—H52B	109.5
C18—C13—Sn1	115.5 (3)	C51—C52—H52C	109.5
C15—C14—C13	120.0	H52A—C52—H52C	109.5
C15—C14—H14	120.0	H52B—C52—H52C	109.5
C13—C14—H14	120.0	C54—C53—N1	111.9 (9)
C14—C15—C16	120.0	C54—C53—H53A	109.2
C14—C15—H15	120.0	N1—C53—H53A	109.2
C16—C15—H15	120.0	C54—C53—H53B	109.2
C17—C16—C15	120.0	N1—C53—H53B	109.2
C17—C16—H16	120.0	H53A—C53—H53B	107.9
C15—C16—H16	120.0	C53—C54—H54A	109.5
C16—C17—C18	120.0	C53—C54—H54B	109.5
C16—C17—H17	120.0	H54A—C54—H54B	109.5
C18—C17—H17	120.0	C53—C54—H54C	109.5
C17—C18—C13	120.0	H54A—C54—H54C	109.5
C17—C18—H18	120.0	H54B—C54—H54C	109.5
C13—C18—H18	120.0	N2—C55—C56	113.4 (8)
C20—C19—C24	120.0	N2—C55—H55A	108.9
C20—C19—Sn2	121.3 (3)	C56—C55—H55A	108.9
C24—C19—Sn2	118.7 (3)	N2—C55—H55B	108.9
C19—C20—C21	120.0	C56—C55—H55B	108.9
C19—C20—H20	120.0	H55A—C55—H55B	107.7
C21—C20—H20	120.0	C55—C56—H56A	109.5
C20—C21—C22	120.0	C55—C56—H56B	109.5
C20—C21—H21	120.0	H56A—C56—H56B	109.5
C22—C21—H21	120.0	C55—C56—H56C	109.5
C23—C22—C21	120.0	H56A—C56—H56C	109.5
C23—C22—H22	120.0	H56B—C56—H56C	109.5
C21—C22—H22	120.0	N2—C57—C58	112.8 (8)
C22—C23—C24	120.0	N2—C57—H57A	109.0
C22—C23—H23	120.0	C58—C57—H57A	109.0
C24—C23—H23	120.0	N2—C57—H57B	109.0
C23—C24—C19	120.0	C58—C57—H57B	109.0
C23—C24—H24	120.0	H57A—C57—H57B	107.8
C19—C24—H24	120.0	C57—C58—H58A	109.5
C26—C25—C30	120.0	C57—C58—H58B	109.5
C26—C25—Sn2	122.5 (5)	H58A—C58—H58B	109.5
C30—C25—Sn2	117.2 (5)	C57—C58—H58C	109.5
C27—C26—C25	120.0	H58A—C58—H58C	109.5
C27—C26—H26	120.0	H58B—C58—H58C	109.5
C25—C26—H26	120.0	N2—C59—C60	113.5 (7)
C26—C27—C28	120.0	N2—C59—H59A	108.9
C26—C27—H27	120.0	C60—C59—H59A	108.9
C28—C27—H27	120.0	N2—C59—H59B	108.9
C29—C28—C27	120.0	C60—C59—H59B	108.9
C29—C28—H28	120.0	H59A—C59—H59B	107.7
C27—C28—H28	120.0	C59—C60—H60A	109.5
C30—C29—C28	120.0	C59—C60—H60B	109.5
C30—C29—H29	120.0	H60A—C60—H60B	109.5
C28—C29—H29	120.0	C59—C60—H60C	109.5
C29—C30—C25	120.0	H60A—C60—H60C	109.5
C29—C30—H30	120.0	H60B—C60—H60C	109.5

C7—Sn1—O1—C37	57.8 (5)	O3ⁱ—Sn2—C25—C30	−62.6 (5)
C13—Sn1—O1—C37	−82.5 (5)	C30—C25—C26—C27	0.0
C1—Sn1—O1—C37	168.0 (5)	Sn2—C25—C26—C27	172.8 (5)
C7—Sn1—O5—C43	−83.9 (6)	C25—C26—C27—C28	0.0
C13—Sn1—O5—C43	56.6 (6)	C26—C27—C28—C29	0.0
C1—Sn1—O5—C43	166.0 (6)	C27—C28—C29—C30	0.0
C25—Sn2—O7—C48	70.8 (7)	C28—C29—C30—C25	0.0
C19—Sn2—O7—C48	−53.9 (7)	C26—C25—C30—C29	0.0
C31—Sn2—O7—C48	−176.8 (7)	Sn2—C25—C30—C29	−173.2 (5)
C7—Sn1—C1—C2	−117.3 (3)	C25—Sn2—C31—C32	103.9 (4)
C13—Sn1—C1—C2	65.6 (4)	C19—Sn2—C31—C32	−75.3 (4)
O5—Sn1—C1—C2	−25.7 (3)	O7—Sn2—C31—C32	13.6 (3)
O1—Sn1—C1—C2	154.4 (3)	O3ⁱ—Sn2—C31—C32	−168.5 (3)
C7—Sn1—C1—C6	63.7 (3)	C25—Sn2—C31—C36	−76.3 (4)
C13—Sn1—C1—C6	−113.5 (3)	C19—Sn2—C31—C36	104.6 (4)
O5—Sn1—C1—C6	155.2 (3)	O7—Sn2—C31—C36	−166.6 (4)
O1—Sn1—C1—C6	−24.6 (3)	O3ⁱ—Sn2—C31—C36	11.4 (4)
C6—C1—C2—C3	0.0	C36—C31—C32—C33	0.0
Sn1—C1—C2—C3	−179.0 (4)	Sn2—C31—C32—C33	179.9 (5)
C1—C2—C3—C4	0.0	C31—C32—C33—C34	0.0
C2—C3—C4—C5	0.0	C32—C33—C34—C35	0.0
C3—C4—C5—C6	0.0	C33—C34—C35—C36	0.0
C4—C5—C6—C1	0.0	C34—C35—C36—C31	0.0
C2—C1—C6—C5	0.0	C32—C31—C36—C35	0.0
Sn1—C1—C6—C5	179.0 (4)	Sn2—C31—C36—C35	−179.9 (5)
C13—Sn1—C7—C8	116.0 (4)	Sn1—O1—C37—O2	12.0 (10)
C1—Sn1—C7—C8	−59.7 (4)	Sn1—O1—C37—C38	−168.8 (5)
O5—Sn1—C7—C8	−147.7 (3)	O2—C37—C38—C39	7.6 (12)
O1—Sn1—C7—C8	27.8 (3)	O1—C37—C38—C39	−171.7 (7)
C13—Sn1—C7—C12	−67.4 (5)	O2—C37—C38—S1	−169.6 (6)
C1—Sn1—C7—C12	116.8 (4)	O1—C37—C38—S1	11.1 (9)
O5—Sn1—C7—C12	28.8 (4)	C41—S1—C38—C39	−1.5 (6)
O1—Sn1—C7—C12	−155.7 (4)	C41—S1—C38—C37	176.1 (6)
C12—C7—C8—C9	0.0	C37—C38—C39—C40	−176.2 (7)
Sn1—C7—C8—C9	176.6 (4)	S1—C38—C39—C40	1.3 (9)
C7—C8—C9—C10	0.0	C38—C39—C40—C41	−0.3 (11)
C8—C9—C10—C11	0.0	C39—C40—C41—C42	174.8 (7)
C9—C10—C11—C12	0.0	C39—C40—C41—S1	−0.8 (9)
C10—C11—C12—C7	0.0	C38—S1—C41—C40	1.3 (6)
C8—C7—C12—C11	0.0	C38—S1—C41—C42	−174.4 (7)
Sn1—C7—C12—C11	−176.4 (4)	Sn2ⁱⁱ—O3—C42—O4	−6.4 (12)
C7—Sn1—C13—C14	−36.0 (5)	Sn2ⁱⁱ—O3—C42—C41	175.9 (5)
C1—Sn1—C13—C14	139.8 (3)	C40—C41—C42—O4	−30.4 (12)
O5—Sn1—C13—C14	−132.4 (4)	S1—C41—C42—O4	144.6 (7)
O1—Sn1—C13—C14	52.1 (4)	C40—C41—C42—O3	147.4 (8)
C7—Sn1—C13—C18	149.6 (4)	S1—C41—C42—O3	−37.6 (11)
C1—Sn1—C13—C18	−34.6 (4)	Sn1—O5—C43—O6	5.4 (11)
O5—Sn1—C13—C18	53.2 (3)	Sn1—O5—C43—C44	−173.4 (5)
O1—Sn1—C13—C18	−122.3 (3)	O6—C43—C44—C45	164.6 (9)
C18—C13—C14—C15	0.0	O5—C43—C44—C45	−16.5 (12)
Sn1—C13—C14—C15	−174.2 (4)	O6—C43—C44—S2	−10.6 (11)
C13—C14—C15—C16	0.0	O5—C43—C44—S2	168.3 (6)
C14—C15—C16—C17	0.0	C47—S2—C44—C45	1.5 (6)
C15—C16—C17—C18	0.0	C47—S2—C44—C43	177.6 (6)
C16—C17—C18—C13	0.0	C43—C44—C45—C46	−177.9 (8)
C14—C13—C18—C17	0.0	S2—C44—C45—C46	−2.4 (9)
Sn1—C13—C18—C17	174.7 (4)	C44—C45—C46—C47	2.3 (10)
C25—Sn2—C19—C20	48.2 (5)	C45—C46—C47—C48	178.9 (7)
C31—Sn2—C19—C20	−132.8 (4)	C45—C46—C47—S2	−1.0 (9)
O7—Sn2—C19—C20	140.9 (4)	C44—S2—C47—C46	−0.3 (6)
O3ⁱ—Sn2—C19—C20	−36.7 (4)	C44—S2—C47—C48	179.8 (6)
C25—Sn2—C19—C24	−132.5 (4)	Sn2—O7—C48—O8	−5.4 (14)
C31—Sn2—C19—C24	46.6 (4)	Sn2—O7—C48—C47	175.8 (5)
O7—Sn2—C19—C24	−39.8 (4)	C46—C47—C48—O8	−3.7 (13)
O3ⁱ—Sn2—C19—C24	142.7 (4)	S2—C47—C48—O8	176.3 (7)
C24—C19—C20—C21	0.0	C46—C47—C48—O7	175.2 (8)
Sn2—C19—C20—C21	179.3 (5)	S2—C47—C48—O7	−4.8 (10)
C19—C20—C21—C22	0.0	C53—N1—C49—C50	61.2 (13)
C20—C21—C22—C23	0.0	C51—N1—C49—C50	−179.3 (9)
C21—C22—C23—C24	0.0	C53—N1—C51—C52	−177.3 (9)
C22—C23—C24—C19	0.0	C49—N1—C51—C52	64.8 (10)
C20—C19—C24—C23	0.0	C49—N1—C53—C54	−173.7 (14)
Sn2—C19—C24—C23	−179.3 (4)	C51—N1—C53—C54	68.0 (17)
C19—Sn2—C25—C26	37.5 (6)	C57—N2—C55—C56	−60.6 (15)
C31—Sn2—C25—C26	−141.7 (5)	C59—N2—C55—C56	66.9 (14)
O7—Sn2—C25—C26	−54.9 (5)	C55—N2—C57—C58	−58.0 (15)
O3ⁱ—Sn2—C25—C26	124.5 (5)	C59—N2—C57—C58	173.1 (11)
C19—Sn2—C25—C30	−149.5 (5)	C55—N2—C59—C60	60.1 (13)
C31—Sn2—C25—C30	31.3 (5)	C57—N2—C59—C60	−171.5 (11)
O7—Sn2—C25—C30	118.1 (5)

Symmetry codes: (i) x−1, y−1, z−1; (ii) x+1, y+1, z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1n···O4	0.91	1.86	2.762 (9)	169
N2—H2n···O8	0.91	1.80	2.709 (10)	177

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Rerefinement of catena-poly[triethyl­ammonium [triphenyl­stannate(IV)-μ-2,5-thio­phene­dicarboxyl­ato]] in the space group Pc

Supporting information

Key indicators

checkCIF/PLATON results

Rerefinement of catena-poly[triethylammonium [triphenylstannate(IV)-μ-2,5-thiophenedicarboxylato]] in the space group Pc