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The structure of the title compound, μ-formato-bis­{μ-N,N′-bis[1-(2-oxidophen­yl)eth­yl]-2-hydr­oxy-1,3-propane­diamine}bis­[(N,N-di­methyl­form­amide)nickel(II)] N,N-di­methyl­form­am­ide disolvate, [Ni3(CHO2)2(C19H24N2O3)2(C3H7NO)2]·2C3H7NO, comprises a centrosymmetric linear homotrinuclear nickel(II) complex. The central and terminal nickel(II) atoms have distorted octa­hedral coordination geometries.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805011396/tk6216sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805011396/tk6216Isup2.hkl
Contains datablock I

CCDC reference: 272120

Key indicators

  • Single-crystal X-ray study
  • T = 299 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.050
  • wR factor = 0.129
  • Data-to-parameter ratio = 18.3

checkCIF/PLATON results

No syntax errors found




Alert level B PLAT026_ALERT_3_B Ratio Observed / Unique Reflections too Low .... 35 Perc. PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 4.18 Ratio PLAT222_ALERT_3_B Large Non-Solvent H Ueq(max)/Ueq(min) ... 4.18 Ratio PLAT230_ALERT_2_B Hirshfeld Test Diff for C10 - C11 .. 7.50 su PLAT242_ALERT_2_B Check Low Ueq as Compared to Neighbors for N3
Alert level C PLAT214_ALERT_2_C Atom C25 (Anion/Solvent) ADP max/min Ratio 4.10 prolat PLAT220_ALERT_2_C Large Non-Solvent O Ueq(max)/Ueq(min) ... 2.59 Ratio PLAT223_ALERT_4_C Large Solvent/Anion H Ueq(max)/Ueq(min) ... 3.32 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for O5 - C20 .. 5.34 su PLAT230_ALERT_2_C Hirshfeld Test Diff for O6 - C10 .. 5.30 su PLAT230_ALERT_2_C Hirshfeld Test Diff for N1 - C9 .. 5.95 su PLAT230_ALERT_2_C Hirshfeld Test Diff for N2 - C11 .. 5.34 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C11 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C16 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C10 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for N4 PLAT333_ALERT_2_C Large Average Benzene C-C Dist. C1 -C6 1.43 Ang. PLAT333_ALERT_2_C Large Average Benzene C-C Dist. C14 -C19 1.45 Ang. PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7 PLAT420_ALERT_2_C D-H Without Acceptor N2 - H2A ... ?
Alert level G REFLT03_ALERT_1_G ALERT: Expected hkl max differ from CIF values From the CIF: _diffrn_reflns_theta_max 28.80 From the CIF: _reflns_number_total 8345 From the CIF: _diffrn_reflns_limit_ max hkl 5. 14. 16. From the CIF: _diffrn_reflns_limit_ min hkl -14. -13. -15. TEST1: Expected hkl limits for theta max Calculated maximum hkl 15. 16. 17. Calculated minimum hkl -15. -16. -17.
0 ALERT level A = In general: serious problem 5 ALERT level B = Potentially serious problem 15 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 15 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: CrysAlis CCD (Oxford Diffraction, 2001); cell refinement: CrysAlis RED (Oxford Diffraction, 2001); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2000); software used to prepare material for publication: SHELXL97.

(I) top
Crystal data top
[Ni3(CO2H)2(C3H7NO)2(C19H24N2O3)2]·2C3H7NOZ = 1
Mr = 1215.29F(000) = 642
Triclinic, P1Dx = 1.266 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.5860 (12) ÅCell parameters from 25 reflections
b = 11.8200 (11) Åθ = 2.9–28.8°
c = 12.6520 (13) ŵ = 0.94 mm1
α = 96.500 (3)°T = 299 K
β = 107.030 (2)°Needle, blue
γ = 101.690 (4)°0.45 × 0.20 × 0.16 mm
V = 1594.5 (3) Å3
Data collection top
Oxford Diffraction Xcalibur CCD
diffractometer
Rint = 0.036
Detector resolution: Sapphire CCD detector pixels mm-1θmax = 28.8°
ω scansh = 145
9225 measured reflectionsk = 1314
8345 independent reflectionsl = 1516
2904 reflections with I > 2σ(I)
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.05Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.129H-atom parameters constrained
S = 0.95 w = 1/[σ2(Fo2) + (0.0574P)2]
where P = (Fo2 + 2Fc2)/3
6404 reflections(Δ/σ)max < 0.001
349 parametersΔρmax = 0.41 e Å3
0 restraintsΔρmin = 0.60 e Å3
Special details top

Experimental. Elemental analysis was carried out with a Leco 932 C, H, N, S analyser and the quantitative determination of nickel was by gravimetric analysis with dimethylglioxyme. Calc. % for C49H71N7O13Ni3, C: 51.52, H: 6.27, N: 8.58, Ni: 15.41. Found % C: 51.09, H: 5.97, N: 8.34, Ni: 14.88. IR spectra were recorded on a Mattson FTIR 1000 apparatus using a KBr disk. IR data (cm-1): ν(N—H) 3285, ν(C—H)Ar 3053, ν(C—H)Aliph 2934–2797, ν(C=O)DMF 1645 ν(C=C)Ar 1604, δCH2 1481, δ(C—H)Ar 737, ν(O—H) 2720 cm-1. Thermogravimetrical analysis was performed with a Shimadzu DTG 60 H instrument. The mass loss for DMF, calc. 19.19%, obs. 20.36%.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ni10.50000.50000.50000.0389 (2)
Ni20.73193 (4)0.70623 (5)0.63957 (4)0.04632 (19)
N10.8329 (3)0.8695 (3)0.6064 (3)0.0577 (10)
N20.8483 (3)0.7380 (3)0.8068 (3)0.0623 (11)
N30.9190 (4)0.4280 (5)0.5774 (5)0.0971 (16)
N40.4007 (6)0.8640 (8)1.0342 (8)0.153 (3)
O10.6251 (2)0.6487 (2)0.47653 (19)0.0446 (7)
O20.6364 (2)0.5338 (2)0.65326 (19)0.0414 (7)
O30.5666 (2)0.3577 (3)0.4259 (2)0.0520 (8)
O40.3937 (3)0.2026 (3)0.3229 (2)0.0599 (8)
O50.8768 (2)0.6200 (3)0.6126 (2)0.0617 (9)
O61.0591 (3)0.9073 (4)0.7761 (3)0.1068 (14)
O70.2493 (4)0.9619 (5)0.9748 (4)0.1404 (19)
H10.90340.85180.59910.069*
H2A0.91660.71520.79990.075*
H61.10470.89300.83340.160*
C10.6678 (3)0.6757 (4)0.3925 (3)0.0439 (10)
C20.6333 (4)0.5844 (4)0.2939 (3)0.0552 (12)
H20.58340.51040.28910.066*
C30.6779 (4)0.6122 (5)0.2069 (4)0.0708 (15)
H30.65670.55610.14210.085*
C40.7575 (4)0.7278 (6)0.2157 (4)0.0773 (16)
H40.78830.74280.15720.093*
C50.7898 (4)0.8188 (5)0.3114 (4)0.0688 (14)
H50.83860.89280.31460.083*
C60.7462 (3)0.7938 (4)0.3996 (3)0.0511 (11)
C70.7748 (4)0.9055 (4)0.4953 (4)0.0635 (13)
H70.83860.96710.48440.076*
C80.6613 (5)0.9550 (5)0.4883 (4)0.0935 (19)
H8A0.68421.02310.54620.140*
H8B0.59650.89640.49810.140*
H8C0.63190.97650.41600.140*
C90.8820 (4)0.9797 (4)0.6961 (4)0.0795 (16)
H9A0.92921.04200.67060.095*
H9B0.81301.00570.71070.095*
C100.9639 (4)0.9533 (5)0.8017 (4)0.0718 (16)
H101.00471.02820.85410.086*
C110.9034 (5)0.8668 (5)0.8660 (4)0.0861 (18)
H11A0.96600.86860.93700.103*
H11B0.83760.89640.88330.103*
C120.8009 (4)0.6513 (5)0.8764 (4)0.0707 (15)
H120.86720.66730.94910.085*
C130.6880 (5)0.6782 (5)0.9019 (4)0.0929 (18)
H13A0.70540.76060.93150.139*
H13B0.66950.63350.95630.139*
H13C0.61770.65760.83410.139*
C140.7772 (3)0.5131 (4)0.8270 (3)0.0556 (12)
C150.8333 (4)0.4327 (6)0.8902 (4)0.0811 (17)
H150.89040.46500.96140.097*
C160.8097 (5)0.3053 (6)0.8542 (5)0.0942 (19)
H160.85370.26140.89990.113*
C170.7204 (5)0.2506 (5)0.7504 (4)0.0771 (15)
H170.69990.16970.72580.093*
C180.6622 (4)0.3272 (4)0.6839 (4)0.0563 (12)
H180.60260.29290.61440.068*
C190.6905 (3)0.4590 (4)0.7182 (3)0.0453 (11)
C200.8509 (4)0.5118 (5)0.5595 (4)0.0695 (15)
H200.77550.48740.50100.083*
C211.0300 (7)0.4615 (8)0.6719 (6)0.184 (4)
H21A1.07040.39810.67760.276*
H21B1.00950.47970.73900.276*
H21C1.08490.52950.66270.276*
C220.8761 (7)0.2995 (6)0.5112 (8)0.179 (4)
H22A0.93870.25840.53940.268*
H22B0.86360.30020.43280.268*
H22C0.79930.26070.52030.268*
C230.5073 (4)0.2529 (4)0.3618 (4)0.0589 (13)
H230.55910.20950.34250.071*
C240.3403 (7)0.9443 (8)1.0396 (7)0.142 (3)
H240.37380.99891.10650.170*
C250.5019 (8)0.8507 (14)1.1191 (11)0.376 (12)
H25A0.53030.78541.09310.564*
H25B0.47740.83661.18360.564*
H25C0.56800.92101.13940.564*
C260.3528 (15)0.7737 (10)0.9371 (13)0.319 (10)
H26A0.40680.72130.94250.478*
H26B0.34830.80800.87120.478*
H26C0.27100.73070.93200.478*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ni10.0316 (4)0.0519 (5)0.0298 (4)0.0085 (3)0.0060 (3)0.0079 (3)
Ni20.0388 (3)0.0557 (4)0.0343 (3)0.0027 (3)0.0032 (2)0.0074 (3)
N10.051 (2)0.061 (3)0.045 (2)0.0019 (19)0.0002 (17)0.0091 (19)
N20.049 (2)0.075 (3)0.041 (2)0.010 (2)0.0008 (17)0.008 (2)
N30.082 (3)0.127 (5)0.137 (5)0.063 (3)0.073 (3)0.072 (4)
N40.110 (5)0.207 (9)0.209 (8)0.099 (5)0.078 (5)0.127 (7)
O10.0341 (13)0.063 (2)0.0292 (14)0.0003 (13)0.0069 (11)0.0093 (13)
O20.0324 (13)0.0528 (18)0.0308 (14)0.0052 (13)0.0000 (11)0.0127 (13)
O30.0483 (16)0.068 (2)0.0412 (16)0.0195 (16)0.0142 (13)0.0087 (15)
O40.0530 (18)0.067 (2)0.0505 (18)0.0109 (16)0.0099 (14)0.0002 (16)
O50.0428 (16)0.082 (3)0.057 (2)0.0142 (17)0.0111 (14)0.0168 (18)
O60.058 (2)0.141 (4)0.102 (3)0.007 (2)0.002 (2)0.038 (3)
O70.087 (3)0.192 (5)0.116 (4)0.047 (3)0.018 (3)0.038 (3)
C10.034 (2)0.058 (3)0.039 (2)0.013 (2)0.0067 (17)0.016 (2)
C20.048 (2)0.074 (3)0.042 (3)0.012 (2)0.012 (2)0.016 (2)
C30.067 (3)0.113 (5)0.041 (3)0.031 (3)0.023 (2)0.020 (3)
C40.057 (3)0.130 (5)0.059 (3)0.025 (3)0.029 (3)0.042 (3)
C50.048 (3)0.094 (4)0.064 (3)0.010 (3)0.014 (2)0.038 (3)
C60.038 (2)0.068 (3)0.041 (2)0.006 (2)0.0055 (18)0.018 (2)
C70.056 (3)0.063 (3)0.061 (3)0.005 (2)0.006 (2)0.025 (3)
C80.100 (4)0.099 (5)0.071 (4)0.034 (4)0.006 (3)0.010 (3)
C90.062 (3)0.076 (4)0.078 (4)0.005 (3)0.004 (3)0.017 (3)
C100.034 (2)0.105 (4)0.054 (3)0.013 (3)0.004 (2)0.026 (3)
C110.073 (3)0.111 (5)0.045 (3)0.008 (3)0.004 (3)0.005 (3)
C120.062 (3)0.097 (4)0.036 (3)0.001 (3)0.002 (2)0.017 (3)
C130.104 (4)0.109 (5)0.051 (3)0.004 (4)0.023 (3)0.003 (3)
C140.039 (2)0.074 (4)0.046 (3)0.004 (2)0.0064 (19)0.022 (2)
C150.052 (3)0.112 (5)0.065 (3)0.011 (3)0.004 (2)0.038 (3)
C160.073 (3)0.130 (6)0.088 (4)0.043 (4)0.009 (3)0.062 (4)
C170.082 (4)0.081 (4)0.082 (4)0.033 (3)0.031 (3)0.032 (3)
C180.054 (3)0.069 (4)0.050 (3)0.021 (2)0.015 (2)0.020 (2)
C190.0310 (19)0.070 (3)0.033 (2)0.009 (2)0.0078 (17)0.015 (2)
C200.045 (3)0.095 (4)0.080 (4)0.018 (3)0.029 (3)0.035 (3)
C210.133 (6)0.359 (13)0.143 (7)0.166 (8)0.065 (6)0.137 (8)
C220.187 (8)0.098 (6)0.338 (13)0.065 (6)0.192 (9)0.046 (7)
C230.064 (3)0.070 (4)0.050 (3)0.029 (3)0.023 (2)0.010 (3)
C240.087 (5)0.202 (10)0.136 (7)0.028 (6)0.023 (5)0.080 (7)
C250.146 (8)0.79 (3)0.393 (18)0.255 (14)0.153 (10)0.48 (2)
C260.42 (2)0.200 (14)0.39 (2)0.013 (14)0.287 (19)0.010 (13)
Geometric parameters (Å, º) top
Ni1—Ni23.1421 (6)C12—C131.521 (7)
Ni1—O12.148 (3)C12—N21.545 (5)
Ni1—O1i2.148 (3)C12—C141.618 (6)
Ni1—O2i2.047 (2)C12—H120.9800
Ni1—O22.047 (2)C13—H13A0.9600
Ni1—O32.213 (3)C13—H13B0.9600
Ni1—O3i2.213 (3)C13—H13C0.9600
Ni2—O12.024 (2)C14—C191.429 (5)
Ni2—O22.165 (3)C14—C151.444 (6)
Ni2—O4i2.105 (3)C15—C161.468 (7)
Ni2—O52.218 (3)C15—H150.9300
Ni2—N12.196 (3)C16—C171.398 (6)
Ni2—N22.093 (3)C16—H160.9300
O6—H60.8200C17—C181.439 (6)
N1—H10.9100C17—H170.9300
N2—H2A0.9100C18—C191.510 (6)
C1—O11.341 (4)C18—H180.9300
C1—C21.453 (5)C19—O21.392 (4)
C1—C61.480 (6)C20—O51.308 (6)
C2—C31.390 (6)C20—N31.385 (6)
C2—H20.9300C20—H200.9300
C3—C41.458 (7)C21—N31.423 (8)
C3—H30.9300C21—H21A0.9600
C4—C51.428 (7)C21—H21B0.9600
C4—H40.9300C21—H21C0.9600
C5—C61.390 (6)C22—N31.555 (8)
C5—H50.9300C22—H22A0.9600
C6—C71.595 (6)C22—H22B0.9600
C7—N11.519 (5)C22—H22C0.9600
C7—C81.527 (6)C23—O41.251 (5)
C7—H70.9800C23—O31.329 (5)
C8—H8A0.9600C23—H230.9300
C8—H8B0.9600C24—O71.204 (7)
C8—H8C0.9600C24—N41.294 (9)
C9—C101.501 (6)C24—H240.9300
C9—N11.516 (5)C25—N41.390 (10)
C9—H9A0.9700C25—H25A0.9600
C9—H9B0.9700C25—H25B0.9600
C10—O61.426 (6)C25—H25C0.9600
C10—C111.559 (6)C26—N41.421 (12)
C10—H100.9800C26—H26A0.9600
C11—N21.533 (6)C26—H26B0.9600
C11—H11A0.9700C26—H26C0.9600
C11—H11B0.9700
Ni2—O1—Ni197.68 (10)N2—C11—H11B108.0
Ni1—O2—Ni296.43 (10)C10—C11—H11B108.0
O1—Ni1—O1i180.0H11A—C11—H11B107.2
O1—Ni1—O399.04 (10)C13—C12—N2110.8 (4)
O1i—Ni1—O380.96 (10)C13—C12—C14111.7 (4)
O1—Ni1—O3i80.96 (10)N2—C12—C14116.0 (4)
O1i—Ni1—O3i99.04 (10)C13—C12—H12105.8
O2i—Ni1—O2180.0N2—C12—H12105.8
O2i—Ni1—O198.87 (9)C14—C12—H12105.8
O2—Ni1—O181.13 (9)C12—C13—H13A109.5
O2i—Ni1—O1i81.13 (9)C12—C13—H13B109.5
O2—Ni1—O1i98.87 (9)H13A—C13—H13B109.5
O2i—Ni1—O385.13 (10)C12—C13—H13C109.5
O2—Ni1—O394.87 (10)H13A—C13—H13C109.5
O2i—Ni1—O3i94.87 (10)H13B—C13—H13C109.5
O2—Ni1—O3i85.13 (10)C19—C14—C15114.2 (4)
O3—Ni1—O3i180.00 (13)C19—C14—C12121.8 (4)
O1—Ni2—N2170.49 (13)C15—C14—C12123.8 (4)
O1—Ni2—O4i93.50 (10)C14—C15—C16127.0 (4)
N2—Ni2—O4i93.90 (13)C14—C15—H15116.5
O1—Ni2—O281.25 (10)C16—C15—H15116.5
N2—Ni2—O291.93 (12)C17—C16—C15119.2 (5)
O4i—Ni2—O296.91 (11)C17—C16—H16120.4
O1—Ni2—N193.56 (11)C15—C16—H16120.4
N2—Ni2—N192.56 (13)C16—C17—C18115.9 (5)
O4i—Ni2—N188.80 (13)C16—C17—H17122.1
O2—Ni2—N1172.48 (11)C18—C17—H17122.1
O1—Ni2—O591.01 (10)C17—C18—C19125.0 (4)
N2—Ni2—O581.80 (13)C17—C18—H18117.5
O4i—Ni2—O5175.14 (11)C19—C18—H18117.5
O2—Ni2—O585.55 (11)O2—C19—C14116.2 (4)
N1—Ni2—O589.13 (13)O2—C19—C18125.3 (3)
C1—O1—Ni2121.5 (2)C14—C19—C18118.5 (4)
C1—O1—Ni1135.1 (2)O5—C20—N3129.7 (5)
C19—O2—Ni1131.4 (2)O5—C20—H20115.2
C19—O2—Ni2125.6 (2)N3—C20—H20115.2
C23—O3—Ni1132.4 (3)N3—C21—H21A109.5
C23—O4—Ni2i117.5 (3)N3—C21—H21B109.5
C20—O5—Ni2122.9 (3)H21A—C21—H21B109.5
C10—O6—H6109.5N3—C21—H21C109.5
O1—C1—C2117.2 (4)H21A—C21—H21C109.5
O1—C1—C6121.5 (4)H21B—C21—H21C109.5
C2—C1—C6121.4 (4)N3—C22—H22A109.5
C3—C2—C1117.2 (4)N3—C22—H22B109.5
C3—C2—H2121.4H22A—C22—H22B109.5
C1—C2—H2121.4N3—C22—H22C109.5
C2—C3—C4121.0 (5)H22A—C22—H22C109.5
C2—C3—H3119.5H22B—C22—H22C109.5
C4—C3—H3119.5O4—C23—O3131.1 (4)
C5—C4—C3122.0 (4)O4—C23—H23114.5
C5—C4—H4119.0O3—C23—H23114.5
C3—C4—H4119.0O7—C24—N4132.4 (10)
C6—C5—C4118.3 (5)O7—C24—H24113.8
C6—C5—H5120.9N4—C24—H24113.8
C4—C5—H5120.9N4—C25—H25A109.5
C5—C6—C1120.0 (4)N4—C25—H25B109.5
C5—C6—C7113.8 (4)H25A—C25—H25B109.5
C1—C6—C7125.7 (4)N4—C25—H25C109.5
N1—C7—C8115.3 (4)H25A—C25—H25C109.5
N1—C7—C6106.4 (3)H25B—C25—H25C109.5
C8—C7—C6112.9 (3)N4—C26—H26A109.5
N1—C7—H7107.3N4—C26—H26B109.5
C8—C7—H7107.3H26A—C26—H26B109.5
C6—C7—H7107.3N4—C26—H26C109.5
C7—C8—H8A109.5H26A—C26—H26C109.5
C7—C8—H8B109.5H26B—C26—H26C109.5
H8A—C8—H8B109.5C9—N1—C7107.3 (3)
C7—C8—H8C109.5C9—N1—Ni2120.0 (3)
H8A—C8—H8C109.5C7—N1—Ni2117.0 (2)
H8B—C8—H8C109.5C9—N1—H1103.4
C10—C9—N1109.0 (4)C7—N1—H1103.4
C10—C9—H9A109.9Ni2—N1—H1103.4
N1—C9—H9A109.9C11—N2—C12116.5 (3)
C10—C9—H9B109.9C11—N2—Ni2117.2 (3)
N1—C9—H9B109.9C12—N2—Ni2112.9 (2)
H9A—C9—H9B108.3C11—N2—H2A102.4
O6—C10—C9108.7 (4)C12—N2—H2A102.4
O6—C10—C11106.9 (4)Ni2—N2—H2A102.4
C9—C10—C11118.7 (4)C20—N3—C21115.5 (6)
O6—C10—H10107.3C20—N3—C22125.0 (6)
C9—C10—H10107.3C21—N3—C22119.1 (6)
C11—C10—H10107.3C24—N4—C25126.1 (12)
N2—C11—C10117.3 (4)C24—N4—C26117.7 (10)
N2—C11—H11A108.0C25—N4—C26115.9 (10)
C10—C11—H11A108.0
Symmetry code: (i) x+1, y+1, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O6—H6···O7ii0.822.012.721 (6)145
N1—H1···O60.912.352.773 (5)108
N2—H2···O50.912.372.825 (5)110
Symmetry code: (ii) x, y, z+1.
 

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