Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803016398/tk6120sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536803016398/tk6120Isup2.hkl |
CCDC reference: 221660
Data collection: COLLECT (Nonius, 1997-2001); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick 1999); software used to prepare material for publication: SHELXTL.
[Ru2Br2(C4H4N2)(C5H5N)8](PF6)2·2C3H7NO | F(000) = 3016 |
Mr = 1510.98 | Dx = 1.695 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 42564 reflections |
a = 19.0401 (4) Å | θ = 2.6–27.5° |
b = 14.6334 (4) Å | µ = 2.00 mm−1 |
c = 21.2490 (5) Å | T = 293 K |
β = 90.5609 (12)° | Prism, dark red |
V = 5920.1 (2) Å3 | 0.18 × 0.10 × 0.02 mm |
Z = 4 |
Nonius KappaCCD diffractometer | 6741 independent reflections |
Radiation source: fine-focus sealed tube | 5561 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.046 |
φ scans, and ω scans with κ offsets | θmax = 27.5°, θmin = 2.9° |
Absorption correction: multi-scan (DENZO-SMN; Otwinowski & Minor, 1997) | h = −24→24 |
Tmin = 0.715, Tmax = 0.961 | k = −18→18 |
21516 measured reflections | l = −27→27 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.115 | H-atom parameters constrained |
S = 1.07 | w = 1/[σ2(Fo2) + (0.0569P)2 + 4.3116P] where P = (Fo2 + 2Fc2)/3 |
6741 reflections | (Δ/σ)max = 0.001 |
341 parameters | Δρmax = 0.48 e Å−3 |
4 restraints | Δρmin = −0.90 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Some highly disordered solvent peaks of DMF molecule were observed but could not be modelled satisfactorily. The SQUEEZE routine in PLATON was used to modify the HKL file and the solvent equated to one molecule of dimethylformamide, per molecule of complex. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Br1 | 0.323952 (19) | 0.36001 (3) | 0.266899 (16) | 0.03966 (11) | |
Ru1 | 0.294415 (12) | 0.314466 (18) | 0.153748 (12) | 0.02643 (9) | |
P1 | −0.00851 (5) | 0.28739 (7) | 0.05085 (5) | 0.0403 (2) | |
F1A | 0.01396 (18) | 0.2068 (2) | 0.0051 (2) | 0.0811 (11) | 0.91 |
F2A | 0.04451 (16) | 0.2475 (3) | 0.10225 (18) | 0.0836 (12) | 0.91 |
F3A | −0.03014 (19) | 0.3654 (2) | 0.09742 (18) | 0.0781 (10) | 0.91 |
F4A | −0.06082 (16) | 0.3261 (3) | −0.00082 (18) | 0.0843 (12) | 0.91 |
F1B | −0.0229 (19) | 0.255 (3) | −0.0198 (7) | 0.069 (8)* | 0.09 |
F2B | 0.0471 (10) | 0.2075 (13) | 0.0574 (14) | 0.042 (5)* | 0.09 |
F3B | 0.0214 (19) | 0.321 (3) | 0.1174 (9) | 0.070 (9)* | 0.09 |
F4B | −0.0550 (13) | 0.3781 (13) | 0.0442 (16) | 0.056 (7)* | 0.09 |
F5 | 0.05360 (12) | 0.34935 (17) | 0.02347 (12) | 0.0518 (6) | |
F6 | −0.06946 (13) | 0.2253 (2) | 0.07838 (15) | 0.0644 (7) | |
N1 | 0.20645 (14) | 0.2482 (2) | 0.19077 (13) | 0.0324 (6) | |
N2 | 0.35535 (14) | 0.19496 (19) | 0.16546 (14) | 0.0320 (6) | |
N3 | 0.38489 (14) | 0.3855 (2) | 0.12560 (13) | 0.0307 (6) | |
N4 | 0.23714 (14) | 0.43628 (19) | 0.14201 (13) | 0.0307 (6) | |
N5 | 0.26864 (13) | 0.27619 (18) | 0.06217 (12) | 0.0269 (5) | |
C1 | 0.16471 (18) | 0.2920 (3) | 0.23229 (17) | 0.0384 (8) | |
H1 | 0.1729 | 0.3550 | 0.2402 | 0.046* | |
C2 | 0.1102 (2) | 0.2485 (4) | 0.2643 (2) | 0.0524 (11) | |
H2 | 0.0819 | 0.2813 | 0.2931 | 0.063* | |
C3 | 0.0983 (2) | 0.1575 (4) | 0.2534 (2) | 0.0574 (13) | |
H3 | 0.0626 | 0.1258 | 0.2754 | 0.069* | |
C4 | 0.1388 (2) | 0.1127 (3) | 0.2099 (2) | 0.0515 (11) | |
H4 | 0.1303 | 0.0501 | 0.2008 | 0.062* | |
C5 | 0.19202 (19) | 0.1592 (3) | 0.17967 (19) | 0.0394 (8) | |
H5 | 0.2194 | 0.1272 | 0.1498 | 0.047* | |
C6 | 0.35035 (19) | 0.1445 (3) | 0.21843 (19) | 0.0392 (8) | |
H6 | 0.3194 | 0.1642 | 0.2505 | 0.047* | |
C7 | 0.3889 (2) | 0.0650 (3) | 0.2278 (2) | 0.0506 (10) | |
H7 | 0.3840 | 0.0311 | 0.2656 | 0.061* | |
C8 | 0.4340 (3) | 0.0360 (3) | 0.1823 (2) | 0.0590 (12) | |
H8 | 0.4602 | −0.0188 | 0.1876 | 0.071* | |
C9 | 0.4405 (2) | 0.0874 (3) | 0.1286 (2) | 0.0551 (11) | |
H9 | 0.4719 | 0.0694 | 0.0964 | 0.066* | |
C10 | 0.4009 (2) | 0.1660 (3) | 0.12217 (19) | 0.0426 (9) | |
H10 | 0.4062 | 0.2013 | 0.0850 | 0.051* | |
C11 | 0.44568 (17) | 0.3750 (3) | 0.15845 (17) | 0.0372 (8) | |
H11 | 0.4482 | 0.3290 | 0.1899 | 0.045* | |
C12 | 0.50432 (18) | 0.4289 (3) | 0.1481 (2) | 0.0448 (9) | |
H12 | 0.5460 | 0.4196 | 0.1721 | 0.054* | |
C13 | 0.50156 (19) | 0.4958 (3) | 0.10305 (19) | 0.0442 (9) | |
H13 | 0.5406 | 0.5348 | 0.0962 | 0.053* | |
C14 | 0.44085 (19) | 0.5053 (3) | 0.06793 (18) | 0.0399 (8) | |
H14 | 0.4383 | 0.5499 | 0.0355 | 0.048* | |
C15 | 0.38409 (17) | 0.4498 (2) | 0.07970 (15) | 0.0324 (7) | |
H15 | 0.3428 | 0.4572 | 0.0548 | 0.039* | |
C16 | 0.26637 (18) | 0.5171 (2) | 0.15867 (16) | 0.0345 (7) | |
H16 | 0.3096 | 0.5165 | 0.1814 | 0.041* | |
C17 | 0.2364 (2) | 0.6003 (3) | 0.1442 (2) | 0.0458 (9) | |
H17 | 0.2588 | 0.6555 | 0.1567 | 0.055* | |
C18 | 0.1732 (2) | 0.6028 (3) | 0.1110 (2) | 0.0536 (10) | |
H18 | 0.1522 | 0.6593 | 0.0994 | 0.064* | |
C19 | 0.1419 (2) | 0.5212 (3) | 0.0958 (2) | 0.0469 (9) | |
H19 | 0.0978 | 0.5205 | 0.0743 | 0.056* | |
C20 | 0.17450 (18) | 0.4406 (3) | 0.11142 (17) | 0.0357 (7) | |
H20 | 0.1520 | 0.3849 | 0.1002 | 0.043* | |
C21 | 0.20344 (16) | 0.2471 (2) | 0.04590 (15) | 0.0287 (6) | |
H21 | 0.1685 | 0.2444 | 0.0774 | 0.034* | |
C22 | 0.18596 (16) | 0.2217 (2) | −0.01457 (16) | 0.0298 (6) | |
H22 | 0.1394 | 0.2014 | −0.0229 | 0.036* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Br1 | 0.0421 (2) | 0.0472 (2) | 0.02950 (19) | −0.00843 (15) | −0.00730 (15) | −0.00066 (15) |
Ru1 | 0.02395 (14) | 0.02955 (15) | 0.02571 (15) | −0.00255 (9) | −0.00417 (10) | 0.00040 (10) |
P1 | 0.0318 (4) | 0.0449 (6) | 0.0442 (5) | 0.0007 (4) | 0.0019 (4) | −0.0018 (4) |
F1A | 0.069 (2) | 0.063 (2) | 0.112 (3) | −0.0135 (17) | 0.042 (2) | −0.032 (2) |
F2A | 0.0494 (16) | 0.123 (3) | 0.079 (2) | 0.0046 (19) | −0.0102 (16) | 0.044 (2) |
F3A | 0.084 (2) | 0.066 (2) | 0.085 (2) | −0.0133 (17) | 0.034 (2) | −0.0324 (18) |
F4A | 0.0462 (16) | 0.132 (3) | 0.075 (2) | −0.0038 (19) | −0.0168 (16) | 0.038 (2) |
F5 | 0.0422 (12) | 0.0551 (15) | 0.0582 (15) | −0.0093 (11) | 0.0046 (11) | 0.0005 (12) |
F6 | 0.0452 (13) | 0.0613 (16) | 0.087 (2) | −0.0041 (12) | 0.0202 (13) | 0.0031 (15) |
N1 | 0.0287 (13) | 0.0381 (16) | 0.0303 (14) | −0.0024 (12) | −0.0044 (11) | 0.0027 (12) |
N2 | 0.0292 (13) | 0.0336 (15) | 0.0331 (15) | −0.0002 (11) | −0.0048 (12) | 0.0031 (12) |
N3 | 0.0267 (12) | 0.0355 (15) | 0.0299 (14) | −0.0022 (11) | −0.0043 (11) | −0.0001 (12) |
N4 | 0.0296 (13) | 0.0319 (15) | 0.0305 (14) | −0.0020 (11) | −0.0034 (11) | −0.0033 (11) |
N5 | 0.0253 (12) | 0.0268 (13) | 0.0285 (13) | 0.0022 (10) | −0.0014 (10) | 0.0011 (11) |
C1 | 0.0326 (16) | 0.051 (2) | 0.0313 (17) | −0.0002 (15) | 0.0014 (14) | 0.0029 (15) |
C2 | 0.0323 (18) | 0.083 (3) | 0.043 (2) | 0.002 (2) | 0.0041 (16) | 0.016 (2) |
C3 | 0.0309 (19) | 0.076 (3) | 0.065 (3) | −0.013 (2) | −0.0075 (19) | 0.034 (3) |
C4 | 0.041 (2) | 0.049 (2) | 0.064 (3) | −0.0176 (18) | −0.023 (2) | 0.021 (2) |
C5 | 0.0360 (18) | 0.0370 (19) | 0.045 (2) | −0.0071 (15) | −0.0128 (16) | 0.0106 (16) |
C6 | 0.0371 (18) | 0.041 (2) | 0.040 (2) | 0.0030 (15) | −0.0034 (15) | 0.0060 (16) |
C7 | 0.057 (2) | 0.047 (2) | 0.048 (2) | 0.0108 (19) | −0.0066 (19) | 0.0144 (19) |
C8 | 0.064 (3) | 0.051 (3) | 0.062 (3) | 0.024 (2) | −0.006 (2) | 0.008 (2) |
C9 | 0.051 (2) | 0.061 (3) | 0.053 (3) | 0.023 (2) | −0.003 (2) | 0.000 (2) |
C10 | 0.0383 (19) | 0.047 (2) | 0.042 (2) | 0.0066 (16) | −0.0030 (16) | 0.0036 (17) |
C11 | 0.0294 (16) | 0.046 (2) | 0.0360 (18) | −0.0071 (14) | −0.0069 (14) | 0.0035 (16) |
C12 | 0.0286 (16) | 0.058 (2) | 0.048 (2) | −0.0094 (16) | −0.0098 (16) | 0.0005 (19) |
C13 | 0.0329 (17) | 0.053 (2) | 0.047 (2) | −0.0130 (17) | −0.0008 (16) | 0.0040 (18) |
C14 | 0.0393 (18) | 0.044 (2) | 0.0365 (18) | −0.0083 (16) | −0.0002 (15) | 0.0037 (16) |
C15 | 0.0312 (15) | 0.0376 (18) | 0.0285 (16) | −0.0045 (14) | −0.0030 (13) | 0.0010 (14) |
C16 | 0.0374 (17) | 0.0328 (18) | 0.0332 (17) | −0.0035 (14) | −0.0006 (14) | −0.0044 (14) |
C17 | 0.053 (2) | 0.035 (2) | 0.049 (2) | −0.0008 (17) | −0.0005 (18) | −0.0007 (17) |
C18 | 0.058 (2) | 0.042 (2) | 0.061 (3) | 0.0122 (19) | −0.007 (2) | 0.005 (2) |
C19 | 0.046 (2) | 0.049 (2) | 0.046 (2) | 0.0112 (18) | −0.0099 (18) | −0.0061 (18) |
C20 | 0.0345 (16) | 0.0360 (18) | 0.0364 (18) | 0.0024 (14) | −0.0081 (14) | −0.0048 (15) |
C21 | 0.0253 (14) | 0.0303 (17) | 0.0304 (16) | −0.0018 (12) | −0.0010 (12) | −0.0024 (13) |
C22 | 0.0245 (14) | 0.0319 (16) | 0.0328 (16) | −0.0025 (12) | −0.0027 (12) | 0.0001 (14) |
Ru1—Br1 | 2.5524 (4) | C4—H4 | 0.9499 |
Ru1—N1 | 2.095 (3) | C5—H5 | 0.9500 |
Ru1—N2 | 2.112 (3) | C6—C7 | 1.389 (5) |
Ru1—N3 | 2.103 (3) | C6—H6 | 0.9501 |
Ru1—N4 | 2.103 (3) | C7—C8 | 1.367 (7) |
Ru1—N5 | 2.079 (3) | C7—H7 | 0.9499 |
P1—F1A | 1.591 (3) | C8—C9 | 1.373 (7) |
P1—F2A | 1.591 (3) | C8—H8 | 0.9500 |
P1—F3A | 1.569 (3) | C9—C10 | 1.381 (6) |
P1—F4A | 1.580 (3) | C9—H9 | 0.9500 |
P1—F1B | 1.595 (10) | C10—H10 | 0.9500 |
P1—F2B | 1.582 (10) | C11—C12 | 1.386 (5) |
P1—F3B | 1.597 (10) | C11—H11 | 0.9500 |
P1—F4B | 1.601 (10) | C12—C13 | 1.370 (6) |
P1—F5 | 1.604 (2) | C12—H12 | 0.9501 |
P1—F6 | 1.590 (3) | C13—C14 | 1.377 (5) |
N1—C5 | 1.351 (5) | C13—H13 | 0.9502 |
N1—C1 | 1.354 (5) | C14—C15 | 1.376 (5) |
N2—C10 | 1.339 (5) | C14—H14 | 0.9499 |
N2—C6 | 1.350 (5) | C15—H15 | 0.9500 |
N3—C11 | 1.354 (4) | C16—C17 | 1.379 (5) |
N3—C15 | 1.356 (4) | C16—H16 | 0.9500 |
N4—C16 | 1.353 (4) | C17—C18 | 1.389 (6) |
N4—C20 | 1.354 (4) | C17—H17 | 0.9500 |
N5—C22i | 1.337 (4) | C18—C19 | 1.372 (6) |
N5—C21 | 1.354 (4) | C18—H18 | 0.9499 |
C1—C2 | 1.400 (5) | C19—C20 | 1.374 (5) |
C1—H1 | 0.9500 | C19—H19 | 0.9500 |
C2—C3 | 1.370 (7) | C20—H20 | 0.9499 |
C2—H2 | 0.9499 | C21—C22 | 1.375 (5) |
C3—C4 | 1.376 (7) | C21—H21 | 0.9500 |
C3—H3 | 0.9501 | C22—N5i | 1.337 (4) |
C4—C5 | 1.384 (5) | C22—H22 | 0.9499 |
N1—Ru1—N2 | 90.73 (11) | C3—C2—H2 | 120.5 |
N1—Ru1—N3 | 174.38 (11) | C1—C2—H2 | 120.7 |
N1—Ru1—N4 | 91.22 (11) | C2—C3—C4 | 118.9 (4) |
N1—Ru1—N5 | 92.55 (10) | C2—C3—H3 | 120.6 |
N2—Ru1—N3 | 89.54 (11) | C4—C3—H3 | 120.5 |
N2—Ru1—N4 | 177.91 (10) | C3—C4—C5 | 119.7 (4) |
N2—Ru1—N5 | 90.66 (11) | C3—C4—H4 | 120.0 |
N3—Ru1—N4 | 88.44 (11) | C5—C4—H4 | 120.3 |
N3—Ru1—N5 | 93.06 (10) | N1—C5—C4 | 122.8 (4) |
N4—Ru1—N5 | 90.00 (10) | N1—C5—H5 | 118.7 |
N1—Ru1—Br1 | 86.38 (8) | C4—C5—H5 | 118.5 |
N2—Ru1—Br1 | 89.40 (8) | N2—C6—C7 | 122.4 (4) |
N3—Ru1—Br1 | 88.02 (8) | N2—C6—H6 | 118.8 |
N4—Ru1—Br1 | 89.98 (8) | C7—C6—H6 | 118.8 |
N5—Ru1—Br1 | 178.92 (7) | C8—C7—C6 | 119.6 (4) |
F3A—P1—F4A | 90.6 (2) | C8—C7—H7 | 120.3 |
F3A—P1—F6 | 89.27 (16) | C6—C7—H7 | 120.1 |
F4A—P1—F6 | 90.18 (17) | C7—C8—C9 | 118.6 (4) |
F2B—P1—F6 | 92.0 (9) | C7—C8—H8 | 120.7 |
F3A—P1—F1A | 178.6 (3) | C9—C8—H8 | 120.7 |
F4A—P1—F1A | 90.7 (2) | C8—C9—C10 | 119.1 (4) |
F6—P1—F1A | 90.15 (16) | C8—C9—H9 | 120.5 |
F3A—P1—F2A | 90.1 (2) | C10—C9—H9 | 120.5 |
F4A—P1—F2A | 179.3 (3) | N2—C10—C9 | 123.5 (4) |
F6—P1—F2A | 89.91 (17) | N2—C10—H10 | 118.3 |
F1A—P1—F2A | 88.6 (3) | C9—C10—H10 | 118.2 |
F2B—P1—F1B | 88.4 (18) | N3—C11—C12 | 122.7 (3) |
F6—P1—F1B | 93.3 (12) | N3—C11—H11 | 118.6 |
F2B—P1—F3B | 85.2 (18) | C12—C11—H11 | 118.7 |
F6—P1—F3B | 96.0 (13) | C13—C12—C11 | 119.4 (3) |
F1B—P1—F3B | 168.9 (19) | C13—C12—H12 | 120.3 |
F2B—P1—F4B | 171.5 (14) | C11—C12—H12 | 120.3 |
F6—P1—F4B | 95.9 (10) | C12—C13—C14 | 118.5 (3) |
F1B—P1—F4B | 94.2 (19) | C12—C13—H13 | 120.8 |
F3B—P1—F4B | 90.9 (19) | C14—C13—H13 | 120.7 |
F3A—P1—F5 | 90.93 (16) | C13—C14—C15 | 119.9 (4) |
F4A—P1—F5 | 90.43 (16) | C13—C14—H14 | 120.0 |
F2B—P1—F5 | 87.4 (9) | C15—C14—H14 | 120.1 |
F6—P1—F5 | 179.36 (17) | N3—C15—C14 | 122.5 (3) |
F1A—P1—F5 | 89.64 (15) | N3—C15—H15 | 118.9 |
F2A—P1—F5 | 89.48 (16) | C14—C15—H15 | 118.7 |
F1B—P1—F5 | 87.0 (12) | N4—C16—C17 | 123.1 (3) |
F3B—P1—F5 | 83.7 (13) | N4—C16—H16 | 118.4 |
F4B—P1—F5 | 84.7 (10) | C17—C16—H16 | 118.5 |
C5—N1—C1 | 116.7 (3) | C16—C17—C18 | 119.3 (4) |
C5—N1—Ru1 | 122.8 (2) | C16—C17—H17 | 120.4 |
C1—N1—Ru1 | 120.1 (2) | C18—C17—H17 | 120.3 |
C10—N2—C6 | 116.8 (3) | C19—C18—C17 | 118.1 (4) |
C10—N2—Ru1 | 122.7 (2) | C19—C18—H18 | 121.0 |
C6—N2—Ru1 | 120.5 (2) | C17—C18—H18 | 120.9 |
C11—N3—C15 | 116.9 (3) | C20—C19—C18 | 119.7 (4) |
C11—N3—Ru1 | 119.7 (2) | C20—C19—H19 | 120.1 |
C15—N3—Ru1 | 123.0 (2) | C18—C19—H19 | 120.2 |
C16—N4—C20 | 116.3 (3) | N4—C20—C19 | 123.4 (3) |
C16—N4—Ru1 | 119.9 (2) | N4—C20—H20 | 118.3 |
C20—N4—Ru1 | 123.3 (2) | C19—C20—H20 | 118.3 |
C22i—N5—C21 | 114.3 (3) | N5—C21—C22 | 122.5 (3) |
C22i—N5—Ru1 | 123.6 (2) | N5—C21—H21 | 118.7 |
C21—N5—Ru1 | 122.1 (2) | C22—C21—H21 | 118.8 |
N1—C1—C2 | 123.0 (4) | N5i—C22—C21 | 123.2 (3) |
N1—C1—H1 | 118.6 | N5i—C22—H22 | 118.3 |
C2—C1—H1 | 118.5 | C21—C22—H22 | 118.4 |
C3—C2—C1 | 118.8 (4) | ||
N5—Ru1—N1—C5 | 54.0 (3) | N3—Ru1—N5—C21 | −162.2 (3) |
N4—Ru1—N1—C5 | 144.1 (3) | N2—Ru1—N5—C21 | 108.2 (3) |
N2—Ru1—N1—C5 | −36.7 (3) | C5—N1—C1—C2 | 1.8 (5) |
Br1—Ru1—N1—C5 | −126.0 (3) | Ru1—N1—C1—C2 | −172.3 (3) |
N5—Ru1—N1—C1 | −132.2 (3) | N1—C1—C2—C3 | 0.1 (6) |
N4—Ru1—N1—C1 | −42.1 (3) | C1—C2—C3—C4 | −2.0 (6) |
N2—Ru1—N1—C1 | 137.1 (3) | C2—C3—C4—C5 | 2.0 (6) |
Br1—Ru1—N1—C1 | 47.8 (2) | C1—N1—C5—C4 | −1.8 (5) |
N5—Ru1—N2—C10 | 45.9 (3) | Ru1—N1—C5—C4 | 172.1 (3) |
N1—Ru1—N2—C10 | 138.5 (3) | C3—C4—C5—N1 | 0.0 (6) |
N3—Ru1—N2—C10 | −47.2 (3) | C10—N2—C6—C7 | −1.6 (5) |
Br1—Ru1—N2—C10 | −135.2 (3) | Ru1—N2—C6—C7 | 179.3 (3) |
N5—Ru1—N2—C6 | −135.0 (3) | N2—C6—C7—C8 | 0.4 (6) |
N1—Ru1—N2—C6 | −42.4 (3) | C6—C7—C8—C9 | 0.6 (7) |
N3—Ru1—N2—C6 | 131.9 (3) | C7—C8—C9—C10 | −0.4 (7) |
Br1—Ru1—N2—C6 | 43.9 (3) | C6—N2—C10—C9 | 1.8 (6) |
N5—Ru1—N3—C11 | −135.5 (3) | Ru1—N2—C10—C9 | −179.1 (3) |
N4—Ru1—N3—C11 | 134.6 (3) | C8—C9—C10—N2 | −0.9 (7) |
N2—Ru1—N3—C11 | −44.8 (3) | C15—N3—C11—C12 | 2.3 (5) |
Br1—Ru1—N3—C11 | 44.6 (3) | Ru1—N3—C11—C12 | −170.7 (3) |
N5—Ru1—N3—C15 | 52.0 (3) | N3—C11—C12—C13 | 0.0 (6) |
N4—Ru1—N3—C15 | −37.9 (3) | C11—C12—C13—C14 | −2.0 (6) |
N2—Ru1—N3—C15 | 142.6 (3) | C12—C13—C14—C15 | 1.7 (6) |
Br1—Ru1—N3—C15 | −128.0 (3) | C11—N3—C15—C14 | −2.6 (5) |
N5—Ru1—N4—C16 | −131.4 (3) | Ru1—N3—C15—C14 | 170.2 (3) |
N1—Ru1—N4—C16 | 136.1 (3) | C13—C14—C15—N3 | 0.6 (6) |
N3—Ru1—N4—C16 | −38.3 (3) | C20—N4—C16—C17 | −2.0 (5) |
Br1—Ru1—N4—C16 | 49.7 (2) | Ru1—N4—C16—C17 | 170.4 (3) |
N5—Ru1—N4—C20 | 40.5 (3) | N4—C16—C17—C18 | 0.0 (6) |
N1—Ru1—N4—C20 | −52.1 (3) | C16—C17—C18—C19 | 2.2 (7) |
N3—Ru1—N4—C20 | 133.5 (3) | C17—C18—C19—C20 | −2.3 (7) |
Br1—Ru1—N4—C20 | −138.4 (3) | C16—N4—C20—C19 | 1.9 (5) |
N1—Ru1—N5—C22i | −162.8 (3) | Ru1—N4—C20—C19 | −170.3 (3) |
N4—Ru1—N5—C22i | 105.9 (3) | C18—C19—C20—N4 | 0.3 (6) |
N3—Ru1—N5—C22i | 17.5 (3) | C22i—N5—C21—C22 | 0.3 (5) |
N2—Ru1—N5—C22i | −72.1 (3) | Ru1—N5—C21—C22 | 180.0 (2) |
N1—Ru1—N5—C21 | 17.5 (3) | N5—C21—C22—N5i | −0.3 (6) |
N4—Ru1—N5—C21 | −73.8 (3) |
Symmetry code: (i) −x+1/2, −y+1/2, −z. |