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The title compounds, (3a[alpha],5[alpha],6[alpha])-4,4,6-trichloro-7-methoxy-3,4,5,6-tetrahydro-2H-3a,5- methanoazulene and (3a[alpha],6[alpha])-(E)-8,8-dichloro-5-chloromethylene-6-methoxy- 1,2,3,4,5,6-hexahydro-3a,6-methano-3aH-indene, both C12H13Cl3O, were formed by mild thermolyses of two related [4.3.1]propellanes and are of interest in the development of new methods for preparing novel analogues of the anti-cancer drug TaxolTM.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 2, 4, global

hkl

Structure factor file (CIF format)
Contains datablock 2

hkl

Structure factor file (CIF format)
Contains datablock 4

CCDC references: 129498; 129499

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