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The mixed-valence tetranuclear title complex, di-[mu]-ethoxo-1:2[kappa]4O-tetraethoxo-3[kappa]2O, 4[kappa]2O-di-[mu]-oxo-1:3[kappa]2O; 2:4[kappa]2O-tetraoxo-1[kappa]O,2[kappa]O,3[kappa]O,4[kappa]O-bis(1,10-phenanthroline)-1[kappa]2N,N'; 2[kappa]2N,N'-tetravanadium, [V4O6(C2H5O)6(C12H8N2)2], was prepared and the crystal structure analysis showed it to have an alkoxo-bridged dinuclear oxovanadium core. The complex has a crystallographic inversion centre.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, scoob

CCDC reference: 127149

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