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The single-crystal X-ray structures of two photochemical products of 2-cyclohexenone have identified them as the head-to-head and head-to-tail cis-anti-cis dimers (C12H16O2) formed by 2 + 2 addition. The cyclobutane ring is twisted in the head-to-head isomer but flat in the head-to-tail compound.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 1, 2

CCDC references: 129495; 129496

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