Acta Crystallographica Section E

Structure Reports Online

Volume 60, Part 6 (June 2004)

metal-organic compounds


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Acta Cryst. (2004). E60, m868-m870    [ doi:10.1107/S1600536804012541 ]

trans-Bis(glycinato-[kappa]2N,O)copper(II) 4-bromophenol solvate

M. Bakir, S. A. Clarke, I. Hassan, R. J. Lancashire and M. Singh-Wilmot

Abstract: The title compound, trans-[Cu(gly)2]·4-BrC6H4OH, (I), crystallized in the non-centrosymmetric orthorhombic space group Pca21 when trans-bis(glycinato-N,O)copper(II) and 4-bromophenol were allowed to stand in water for several days. Structural analysis reveals that the 4-bromophenol is not coordinated to the copper and that the glycinato units are trans in N,O-bidentate binding mode. The packing of the molecules shows well defined units of (I), interlocked via a network of secondary covalent and non-covalent bonds, with the Cu atom in a [4 + 2] coordination mode.

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