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Within systematic studies on the K–Co–Mo–O system so-called high-temperature and high-pressure modifications of K2Co2Mo3O12 were found. The Birch–Murnaghan fits for the ambient-conditions modification α (Z = 4) and the high-pressure phase II (Z = 8) lead to V0 = 1193.09 (4) Å3, K = 30.8 (8) GPa, K_0^{\prime} = 5.4 (4) and V0 = 2170 (10) Å3, K = 51 (2) GPa with K_0^{\prime} fixed at 4.0, respectively. The high-pressure phase transition is denoted as pseudoreconstructive [Wiesmann et al. (1997). J. Solid State Chem. 132, 88–97], because some [MoO4] tetrahedra turn into edge-sharing pairs of [MoO5] pyramids or face-sharing pairs of [MoO6] octahedra. The new phases are presented and compared with the α phase.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108768108038536/sn5075sup1.cif
Contains datablocks alpha, beta, II

fcf

Structure factor file (CIF format) https://doi.org/10.1107/S0108768108038536/sn5075alphasup2.fcf
Contains datablock alpha

fcf

Structure factor file (CIF format) https://doi.org/10.1107/S0108768108038536/sn5075betasup3.fcf
Contains datablock beta

fcf

Structure factor file (CIF format) https://doi.org/10.1107/S0108768108038536/sn5075IIsup4.fcf
Contains datablock II

pdf

Portable Document Format (PDF) file https://doi.org/10.1107/S0108768108038536/sn5075sup5.pdf
High-pressure data

Computing details top

For all compounds, data collection: CrysAlis CCD, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45); cell refinement: CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45); data reduction: CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45). Program(s) used to solve structure: SHELXS97 (Sheldrick, 1990) for alpha; SHELXS97 (Sheldrick, 1997) for beta, (II). For all compounds, program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: Brandenburg et al. Diamond 3.0b; software used to prepare material for publication: SHELXL97 (Sheldrick, 1997).

Figures top
[Figure 1]
[Figure 2]
[Figure 3]
[Figure 4]
[Figure 5]
[Figure 6]
[Figure 7]
[Figure 8]
[Figure 9]
[Figure 10]
(alpha) top
Crystal data top
Co2K2Mo3O12F(000) = 1256
Mr = 675.88Dx = 3.763 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 7.0093 (1) ÅCell parameters from 7011 reflections
b = 8.9624 (2) Åθ = 2.5–30.1°
c = 19.9977 (4) ŵ = 6.59 mm1
β = 108.247 (2)°T = 293 K
V = 1193.09 (4) Å3Prism, blue
Z = 40.14 × 0.11 × 0.06 mm
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.2435 independent reflections
Radiation source: Enhance (Mo) X-ray Source2152 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.017
Detector resolution: 8.4012 pixels mm-1θmax = 26.4°, θmin = 2.5°
Rotation method data acquisition using ω and phi scans.h = 58
Absorption correction: analytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
k = 1111
Tmin = 0.573, Tmax = 0.751l = 2424
8014 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.028 w = 1/[σ2(Fo2) + (0.098P)2]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.137(Δ/σ)max < 0.001
S = 1.24Δρmax = 2.94 e Å3
2435 reflectionsΔρmin = 1.61 e Å3
173 parametersExtinction correction: SHELXL, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
0 restraintsExtinction coefficient: 0.0075 (7)
Crystal data top
Co2K2Mo3O12V = 1193.09 (4) Å3
Mr = 675.88Z = 4
Monoclinic, P21/cMo Kα radiation
a = 7.0093 (1) ŵ = 6.59 mm1
b = 8.9624 (2) ÅT = 293 K
c = 19.9977 (4) Å0.14 × 0.11 × 0.06 mm
β = 108.247 (2)°
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.2435 independent reflections
Absorption correction: analytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
2152 reflections with I > 2σ(I)
Tmin = 0.573, Tmax = 0.751Rint = 0.017
8014 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.028173 parameters
wR(F2) = 0.1370 restraints
S = 1.24Δρmax = 2.94 e Å3
2435 reflectionsΔρmin = 1.61 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mo10.04914 (8)0.34200 (6)0.27004 (3)0.0103 (2)
Mo20.80582 (8)0.73501 (6)0.40157 (3)0.0090 (2)
Mo30.58498 (8)0.33816 (6)0.45880 (3)0.0098 (2)
Co10.27783 (13)0.65556 (9)0.36482 (4)0.0077 (3)
Co20.07178 (12)0.41935 (9)0.43901 (4)0.0078 (3)
K10.1961 (3)0.04268 (18)0.40919 (9)0.0245 (4)
K20.5042 (3)0.0135 (3)0.27230 (11)0.0410 (6)
O10.2132 (8)0.2065 (6)0.2592 (3)0.0256 (12)
O20.1740 (7)0.5164 (5)0.2797 (2)0.0163 (10)
O30.0096 (7)0.3013 (6)0.3486 (2)0.0190 (11)
O40.1777 (7)0.3429 (5)0.1962 (2)0.0120 (10)
O60.5621 (7)0.6710 (5)0.3549 (3)0.0137 (10)
O50.8305 (7)0.9128 (5)0.3723 (3)0.0189 (11)
O70.8403 (7)0.7553 (5)0.4934 (2)0.0152 (10)
O81.0029 (6)0.6221 (5)0.3884 (2)0.0115 (9)
O90.5421 (8)0.2074 (6)0.3943 (3)0.0258 (12)
O100.6224 (7)0.2339 (5)0.5369 (2)0.0146 (10)
O110.8061 (7)0.4433 (5)0.4606 (2)0.0136 (10)
O120.3644 (7)0.4571 (5)0.4350 (3)0.0147 (10)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mo10.0097 (3)0.0122 (4)0.0080 (3)0.00045 (19)0.0012 (2)0.00164 (19)
Mo20.0076 (3)0.0104 (3)0.0087 (3)0.0009 (2)0.0021 (2)0.00107 (19)
Mo30.0073 (3)0.0114 (4)0.0098 (3)0.00017 (19)0.0012 (2)0.00075 (19)
Co10.0060 (4)0.0091 (5)0.0077 (5)0.0003 (3)0.0019 (3)0.0001 (3)
Co20.0071 (4)0.0098 (5)0.0074 (4)0.0018 (3)0.0037 (3)0.0016 (3)
K10.0274 (9)0.0161 (8)0.0309 (9)0.0021 (6)0.0105 (7)0.0063 (6)
K20.0316 (10)0.0644 (14)0.0329 (11)0.0273 (10)0.0186 (8)0.0238 (10)
O10.016 (3)0.027 (3)0.029 (3)0.006 (2)0.001 (2)0.010 (2)
O20.018 (2)0.018 (2)0.015 (2)0.006 (2)0.008 (2)0.0063 (19)
O30.027 (3)0.021 (2)0.011 (2)0.010 (2)0.010 (2)0.002 (2)
O40.011 (2)0.011 (2)0.012 (2)0.0001 (16)0.0001 (19)0.0025 (16)
O60.008 (2)0.021 (3)0.013 (2)0.0016 (18)0.0045 (19)0.0017 (18)
O50.019 (3)0.016 (3)0.021 (3)0.002 (2)0.005 (2)0.007 (2)
O70.020 (3)0.014 (2)0.013 (2)0.0031 (19)0.006 (2)0.0004 (18)
O80.010 (2)0.014 (2)0.012 (2)0.0005 (18)0.0050 (18)0.0027 (18)
O90.027 (3)0.025 (3)0.022 (3)0.001 (2)0.003 (2)0.010 (2)
O100.014 (2)0.015 (2)0.014 (2)0.0004 (18)0.003 (2)0.0024 (18)
O110.013 (2)0.017 (2)0.012 (2)0.0018 (19)0.0052 (19)0.0006 (18)
O120.010 (2)0.016 (2)0.017 (2)0.0019 (18)0.0029 (19)0.0073 (19)
Geometric parameters (Å, º) top
Mo1—O11.732 (5)K1—O5vii2.698 (5)
Mo1—O21.772 (5)K1—O7v2.728 (5)
Mo1—O31.783 (5)K1—O4viii2.738 (5)
Mo1—O41.799 (5)K1—O32.797 (6)
Mo1—K13.7691 (18)K1—O10ix2.840 (5)
Mo1—K2i3.8134 (19)K1—O92.933 (6)
Mo1—K1ii3.8959 (18)K1—O13.376 (6)
Mo1—K2ii4.008 (2)K1—Co1x3.6704 (18)
Mo2—O51.725 (5)K1—Mo2vii3.8534 (17)
Mo2—O61.766 (5)K2—O12.624 (6)
Mo2—O71.786 (5)K2—O5x2.679 (5)
Mo2—O81.797 (4)K2—O2xi2.764 (5)
Mo2—K2iii3.736 (2)K2—O6xi2.818 (5)
Mo2—K1iv3.8534 (17)K2—O92.939 (6)
Mo2—K2i4.0024 (19)K2—O4viii2.979 (5)
Mo3—O91.698 (5)K2—Mo2x3.736 (2)
Mo3—O101.768 (5)K2—Co1xi3.755 (2)
Mo3—O111.805 (5)K2—Mo1xi3.8134 (19)
Mo3—O121.815 (4)K2—Mo2xi4.0024 (19)
Mo3—K13.7059 (17)K2—Mo1viii4.008 (2)
Co1—O22.051 (5)O2—K2i2.764 (5)
Co1—O4ii2.065 (4)O4—Co1viii2.065 (4)
Co1—O62.068 (5)O4—K1ii2.738 (5)
Co1—O10v2.114 (5)O4—K2ii2.979 (5)
Co1—O8vi2.144 (4)O6—K2i2.818 (5)
Co1—O122.229 (5)O5—K2iii2.679 (5)
Co1—K1iii3.6704 (18)O5—K1iv2.698 (5)
Co1—K2i3.755 (2)O7—Co2v2.033 (5)
Co2—O32.016 (5)O7—K1v2.728 (5)
Co2—O7v2.033 (5)O8—Co2xii2.062 (5)
Co2—O11vi2.050 (5)O8—Co1xii2.144 (4)
Co2—O8vi2.062 (5)O10—Co1v2.114 (5)
Co2—O122.105 (5)O10—K1ix2.840 (5)
Co2—O11v2.281 (5)O11—Co2xii2.050 (5)
Co2—K13.5828 (18)O11—Co2v2.281 (5)
O1—Mo1—O2107.9 (3)O10ix—K1—Co1x35.04 (10)
O1—Mo1—O3108.2 (3)O9—K1—Co1x104.75 (12)
O2—Mo1—O3109.1 (2)O1—K1—Co1x98.32 (10)
O1—Mo1—O4110.6 (2)Co2—K1—Co1x174.51 (6)
O2—Mo1—O4111.4 (2)O5vii—K1—Mo3159.62 (12)
O3—Mo1—O4109.6 (2)O7v—K1—Mo363.90 (11)
O1—Mo1—K163.6 (2)O4viii—K1—Mo3121.79 (11)
O2—Mo1—K1122.39 (16)O3—K1—Mo376.11 (11)
O3—Mo1—K144.66 (18)O10ix—K1—Mo3108.52 (11)
O4—Mo1—K1125.17 (14)O9—K1—Mo326.52 (10)
O1—Mo1—K2i68.4 (2)O1—K1—Mo372.49 (10)
O2—Mo1—K2i42.00 (16)Co2—K1—Mo358.60 (3)
O3—Mo1—K2i135.28 (16)Co1x—K1—Mo3125.65 (5)
O4—Mo1—K2i113.08 (15)O5vii—K1—Mo195.07 (11)
K1—Mo1—K2i113.41 (5)O7v—K1—Mo189.40 (11)
O1—Mo1—K1ii109.11 (19)O4viii—K1—Mo187.76 (10)
O2—Mo1—K1ii75.74 (16)O3—K1—Mo126.61 (10)
O3—Mo1—K1ii138.45 (17)O10ix—K1—Mo1152.58 (11)
O4—Mo1—K1ii38.84 (15)O9—K1—Mo167.07 (11)
K1—Mo1—K1ii161.38 (4)O1—K1—Mo127.35 (9)
K2i—Mo1—K1ii76.47 (4)Co2—K1—Mo155.10 (3)
O1—Mo1—K2ii151.52 (18)Co1x—K1—Mo1121.44 (5)
O2—Mo1—K2ii95.57 (17)Mo3—K1—Mo172.37 (3)
O3—Mo1—K2ii77.84 (17)O5vii—K1—Mo2vii22.92 (10)
O4—Mo1—K2ii43.69 (15)O7v—K1—Mo2vii106.22 (11)
K1—Mo1—K2ii116.85 (4)O4viii—K1—Mo2vii68.89 (10)
K2i—Mo1—K2ii127.29 (7)O3—K1—Mo2vii108.21 (11)
K1ii—Mo1—K2ii60.63 (4)O10ix—K1—Mo2vii67.58 (10)
O5—Mo2—O6107.7 (2)O9—K1—Mo2vii162.84 (12)
O5—Mo2—O7105.1 (2)O1—K1—Mo2vii119.90 (10)
O6—Mo2—O7111.9 (2)Co2—K1—Mo2vii118.31 (5)
O5—Mo2—O8107.9 (2)Co1x—K1—Mo2vii58.44 (3)
O6—Mo2—O8113.6 (2)Mo3—K1—Mo2vii167.29 (6)
O7—Mo2—O8110.2 (2)Mo1—K1—Mo2vii116.97 (5)
O5—Mo2—K2iii40.81 (16)O1—K2—O5x138.76 (18)
O6—Mo2—K2iii66.89 (16)O1—K2—O2xi131.05 (19)
O7—Mo2—K2iii120.57 (15)O5x—K2—O2xi71.17 (15)
O8—Mo2—K2iii124.72 (14)O1—K2—O6xi71.12 (17)
O5—Mo2—K1iv37.53 (16)O5x—K2—O6xi134.69 (16)
O6—Mo2—K1iv144.16 (16)O2xi—K2—O6xi65.10 (14)
O7—Mo2—K1iv91.19 (16)O1—K2—O963.81 (16)
O8—Mo2—K1iv80.81 (15)O5x—K2—O975.26 (16)
K2iii—Mo2—K1iv77.89 (5)O2xi—K2—O9115.77 (18)
O5—Mo2—K2i104.35 (17)O6xi—K2—O9113.59 (17)
O6—Mo2—K2i37.62 (15)O1—K2—O4viii74.63 (16)
O7—Mo2—K2i143.70 (16)O5x—K2—O4viii101.67 (15)
O8—Mo2—K2i80.02 (15)O2xi—K2—O4viii148.84 (16)
K2iii—Mo2—K2i72.221 (13)O6xi—K2—O4viii121.83 (15)
K1iv—Mo2—K2i125.09 (4)O9—K2—O4viii90.21 (15)
O9—Mo3—O10104.4 (3)O1—K2—Mo2x139.75 (14)
O9—Mo3—O11108.8 (2)O5x—K2—Mo2x24.88 (11)
O10—Mo3—O11111.7 (2)O2xi—K2—Mo2x85.12 (11)
O9—Mo3—O12105.8 (2)O6xi—K2—Mo2x148.97 (11)
O10—Mo3—O12114.9 (2)O9—K2—Mo2x86.33 (12)
O11—Mo3—O12110.7 (2)O4viii—K2—Mo2x79.43 (10)
O9—Mo3—K150.44 (19)O1—K2—Co1xi100.65 (15)
O10—Mo3—K175.65 (15)O5x—K2—Co1xi102.21 (12)
O11—Mo3—K1158.99 (15)O2xi—K2—Co1xi32.37 (10)
O12—Mo3—K181.64 (15)O6xi—K2—Co1xi32.92 (10)
O2—Co1—O4ii92.15 (19)O9—K2—Co1xi117.02 (14)
O2—Co1—O693.63 (19)O4viii—K2—Co1xi147.52 (12)
O4ii—Co1—O692.77 (19)Mo2x—K2—Co1xi117.40 (5)
O2—Co1—O10v169.83 (19)O1—K2—Mo1xi155.51 (15)
O4ii—Co1—O10v96.92 (18)O5x—K2—Mo1xi57.41 (11)
O6—Co1—O10v90.53 (18)O2xi—K2—Mo1xi25.41 (10)
O2—Co1—O8vi89.30 (18)O6xi—K2—Mo1xi85.19 (10)
O4ii—Co1—O8vi94.68 (18)O9—K2—Mo1xi123.75 (13)
O6—Co1—O8vi171.88 (18)O4viii—K2—Mo1xi125.34 (11)
O10v—Co1—O8vi85.39 (17)Mo2x—K2—Mo1xi63.78 (3)
O2—Co1—O1289.60 (19)Co1xi—K2—Mo1xi54.86 (3)
O4ii—Co1—O12174.90 (19)O1—K2—K156.96 (14)
O6—Co1—O1291.89 (18)O5x—K2—K191.68 (12)
O10v—Co1—O1280.98 (17)O2xi—K2—K1159.74 (13)
O8vi—Co1—O1280.55 (17)O6xi—K2—K1127.94 (11)
O2—Co1—K1iii137.21 (15)O9—K2—K147.12 (12)
O4ii—Co1—K1iii47.50 (13)O4viii—K2—K143.29 (10)
O6—Co1—K1iii100.83 (13)Mo2x—K2—K183.09 (4)
O10v—Co1—K1iii50.48 (13)Co1xi—K2—K1155.52 (7)
O8vi—Co1—K1iii81.96 (13)Mo1xi—K2—K1146.81 (6)
O12—Co1—K1iii129.38 (13)O1—K2—Mo2xi52.61 (13)
O2—Co1—K2i46.17 (14)O5x—K2—Mo2xi156.87 (13)
O4ii—Co1—K2i89.12 (14)O2xi—K2—Mo2xi87.34 (11)
O6—Co1—K2i47.79 (14)O6xi—K2—Mo2xi22.49 (9)
O10v—Co1—K2i138.22 (13)O9—K2—Mo2xi108.15 (13)
O8vi—Co1—K2i135.46 (13)O4viii—K2—Mo2xi101.19 (10)
O12—Co1—K2i95.54 (13)Mo2x—K2—Mo2xi165.47 (7)
K1iii—Co1—K2i128.83 (5)Co1xi—K2—Mo2xi55.38 (3)
O3—Co2—O7v97.7 (2)Mo1xi—K2—Mo2xi105.50 (5)
O3—Co2—O11vi102.86 (19)K1—K2—Mo2xi107.47 (5)
O7v—Co2—O11vi92.72 (19)O1—K2—Mo1viii63.98 (13)
O3—Co2—O8vi93.8 (2)O5x—K2—Mo1viii124.88 (12)
O7v—Co2—O8vi168.55 (19)O2xi—K2—Mo1viii140.69 (13)
O11vi—Co2—O8vi85.54 (17)O6xi—K2—Mo1viii97.25 (11)
O3—Co2—O1293.2 (2)O9—K2—Mo1viii103.42 (12)
O7v—Co2—O1293.02 (18)O4viii—K2—Mo1viii24.66 (9)
O11vi—Co2—O12162.06 (19)Mo2x—K2—Mo1viii100.97 (5)
O8vi—Co2—O1285.46 (18)Co1xi—K2—Mo1viii124.32 (6)
O3—Co2—O11v174.29 (19)Mo1xi—K2—Mo1viii127.29 (7)
O7v—Co2—O11v83.01 (17)K1—K2—Mo1viii58.29 (4)
O11vi—Co2—O11v82.75 (18)Mo2xi—K2—Mo1viii77.32 (4)
O8vi—Co2—O11v85.54 (18)Mo1—O1—K2167.3 (3)
O12—Co2—O11v81.10 (18)Mo1—O1—K189.1 (2)
O3—Co2—K151.08 (16)K2—O1—K182.37 (16)
O7v—Co2—K149.17 (13)Mo1—O2—Co1131.4 (3)
O11vi—Co2—K1114.71 (13)Mo1—O2—K2i112.6 (2)
O8vi—Co2—K1141.29 (13)Co1—O2—K2i101.46 (18)
O12—Co2—K181.63 (13)Mo1—O3—Co2127.2 (3)
O11v—Co2—K1127.67 (12)Mo1—O3—K1108.7 (2)
O5vii—K1—O7v100.88 (16)Co2—O3—K194.81 (19)
O5vii—K1—O4viii72.27 (15)Mo1—O4—Co1viii122.0 (2)
O7v—K1—O4viii172.30 (16)Mo1—O4—K1ii116.8 (2)
O5vii—K1—O385.55 (15)Co1viii—O4—K1ii98.70 (18)
O7v—K1—O366.95 (15)Mo1—O4—K2ii111.7 (2)
O4viii—K1—O3108.35 (15)Co1viii—O4—K2ii113.63 (19)
O5vii—K1—O10ix90.08 (14)K1ii—O4—K2ii88.45 (14)
O7v—K1—O10ix116.07 (15)Mo2—O6—Co1140.6 (3)
O4viii—K1—O10ix68.21 (14)Mo2—O6—K2i119.9 (2)
O3—K1—O10ix175.16 (15)Co1—O6—K2i99.29 (18)
O5vii—K1—O9159.06 (16)Mo2—O5—K2iii114.3 (2)
O7v—K1—O990.19 (16)Mo2—O5—K1iv119.6 (2)
O4viii—K1—O995.28 (15)K2iii—O5—K1iv125.06 (19)
O3—K1—O982.51 (15)Mo2—O7—Co2v121.3 (2)
O10ix—K1—O9101.03 (16)Mo2—O7—K1v142.1 (2)
O5vii—K1—O1103.85 (15)Co2v—O7—K1v96.52 (18)
O7v—K1—O1112.50 (15)Mo2—O8—Co2xii119.8 (2)
O4viii—K1—O166.82 (13)Mo2—O8—Co1xii137.6 (3)
O3—K1—O153.97 (14)Co2xii—O8—Co1xii98.22 (18)
O10ix—K1—O1125.48 (14)Mo3—O9—K1103.0 (2)
O9—K1—O155.27 (14)Mo3—O9—K2170.7 (3)
O5vii—K1—Co2101.10 (12)K1—O9—K285.64 (16)
O7v—K1—Co234.32 (10)Mo3—O10—Co1v119.2 (2)
O4viii—K1—Co2142.10 (11)Mo3—O10—K1ix136.2 (2)
O3—K1—Co234.11 (10)Co1v—O10—K1ix94.47 (17)
O10ix—K1—Co2149.62 (12)Mo3—O11—Co2xii140.6 (3)
O9—K1—Co278.15 (12)Mo3—O11—Co2v112.5 (2)
O1—K1—Co279.41 (10)Co2xii—O11—Co2v97.25 (18)
O5vii—K1—Co1x74.50 (11)Mo3—O12—Co2131.0 (2)
O7v—K1—Co1x148.90 (12)Mo3—O12—Co1132.5 (2)
O4viii—K1—Co1x33.80 (10)Co2—O12—Co194.35 (18)
O3—K1—Co1x140.98 (12)
O3—Co2—K1—O5vii64.5 (2)Co2—K1—K2—Mo1viii114.95 (6)
O7v—Co2—K1—O5vii93.1 (2)Co1x—K1—K2—Mo1viii59.10 (3)
O11vi—Co2—K1—O5vii22.26 (18)Mo3—K1—K2—Mo1viii159.57 (4)
O8vi—Co2—K1—O5vii93.7 (2)Mo1—K1—K2—Mo1viii82.37 (3)
O12—Co2—K1—O5vii165.52 (17)Mo2vii—K1—K2—Mo1viii27.58 (4)
O11v—Co2—K1—O5vii122.61 (18)O2—Mo1—O1—K270.2 (15)
O3—Co2—K1—O7v157.6 (3)O3—Mo1—O1—K247.7 (16)
O11vi—Co2—K1—O7v70.8 (2)O4—Mo1—O1—K2167.7 (15)
O8vi—Co2—K1—O7v173.2 (3)K1—Mo1—O1—K247.7 (15)
O12—Co2—K1—O7v101.4 (2)K2i—Mo1—O1—K284.7 (15)
O11v—Co2—K1—O7v29.5 (2)K1ii—Mo1—O1—K2150.9 (15)
O3—Co2—K1—O4viii10.8 (3)K2ii—Mo1—O1—K2145.8 (12)
O7v—Co2—K1—O4viii168.4 (3)O2—Mo1—O1—K1117.92 (19)
O11vi—Co2—K1—O4viii97.6 (2)O3—Mo1—O1—K10.0 (2)
O8vi—Co2—K1—O4viii18.3 (3)O4—Mo1—O1—K1120.04 (18)
O12—Co2—K1—O4viii90.2 (2)K2i—Mo1—O1—K1132.42 (15)
O11v—Co2—K1—O4viii162.1 (2)K1ii—Mo1—O1—K1161.41 (5)
O7v—Co2—K1—O3157.6 (3)K2ii—Mo1—O1—K198.1 (4)
O11vi—Co2—K1—O386.8 (2)O5x—K2—O1—Mo11.8 (17)
O8vi—Co2—K1—O329.2 (3)O2xi—K2—O1—Mo1108.3 (15)
O12—Co2—K1—O3101.0 (2)O6xi—K2—O1—Mo1135.7 (15)
O11v—Co2—K1—O3172.9 (2)O9—K2—O1—Mo16.0 (15)
O3—Co2—K1—O10ix174.2 (3)O4viii—K2—O1—Mo192.0 (15)
O7v—Co2—K1—O10ix16.6 (3)Mo2x—K2—O1—Mo140.3 (17)
O11vi—Co2—K1—O10ix87.5 (3)Co1xi—K2—O1—Mo1121.0 (15)
O8vi—Co2—K1—O10ix156.6 (3)Mo1xi—K2—O1—Mo1120.4 (14)
O12—Co2—K1—O10ix84.8 (3)K1—K2—O1—Mo148.2 (15)
O11v—Co2—K1—O10ix12.9 (3)Mo2xi—K2—O1—Mo1150.4 (16)
O3—Co2—K1—O994.1 (2)Mo1viii—K2—O1—Mo1115.9 (16)
O7v—Co2—K1—O9108.3 (2)O5x—K2—O1—K146.5 (3)
O11vi—Co2—K1—O9179.10 (18)O2xi—K2—O1—K1156.57 (19)
O8vi—Co2—K1—O965.0 (2)O6xi—K2—O1—K1176.03 (16)
O12—Co2—K1—O96.88 (17)O9—K2—O1—K154.21 (15)
O11v—Co2—K1—O978.75 (18)O4viii—K2—O1—K143.80 (12)
O3—Co2—K1—O137.7 (2)Mo2x—K2—O1—K17.9 (3)
O7v—Co2—K1—O1164.70 (19)Co1xi—K2—O1—K1169.21 (9)
O11vi—Co2—K1—O1124.47 (17)Mo1xi—K2—O1—K1168.7 (3)
O8vi—Co2—K1—O18.5 (2)Mo2xi—K2—O1—K1161.41 (17)
O12—Co2—K1—O163.30 (16)Mo1viii—K2—O1—K167.65 (9)
O11v—Co2—K1—O1135.18 (17)O5vii—K1—O1—Mo173.8 (2)
O3—Co2—K1—Co1x28.3 (6)O7v—K1—O1—Mo134.4 (2)
O7v—Co2—K1—Co1x129.3 (6)O4viii—K1—O1—Mo1137.3 (2)
O11vi—Co2—K1—Co1x58.5 (6)O3—K1—O1—Mo10.02 (16)
O8vi—Co2—K1—Co1x57.4 (7)O10ix—K1—O1—Mo1174.06 (18)
O12—Co2—K1—Co1x129.3 (6)O9—K1—O1—Mo1108.0 (2)
O11v—Co2—K1—Co1x158.8 (6)Co2—K1—O1—Mo125.12 (16)
O3—Co2—K1—Mo3113.57 (18)Co1x—K1—O1—Mo1149.82 (17)
O7v—Co2—K1—Mo388.85 (18)Mo3—K1—O1—Mo185.33 (18)
O11vi—Co2—K1—Mo3159.67 (14)Mo2vii—K1—O1—Mo191.56 (19)
O8vi—Co2—K1—Mo384.4 (2)O5vii—K1—O1—K2115.64 (17)
O12—Co2—K1—Mo312.55 (13)O7v—K1—O1—K2136.14 (16)
O11v—Co2—K1—Mo359.33 (15)O4viii—K1—O1—K252.18 (15)
O3—Co2—K1—Mo123.96 (18)O3—K1—O1—K2170.5 (2)
O7v—Co2—K1—Mo1178.46 (18)O10ix—K1—O1—K215.4 (2)
O11vi—Co2—K1—Mo1110.71 (14)O9—K1—O1—K262.56 (17)
O8vi—Co2—K1—Mo15.2 (2)Co2—K1—O1—K2145.41 (14)
O12—Co2—K1—Mo177.07 (14)Co1x—K1—O1—K239.66 (13)
O11v—Co2—K1—Mo1148.94 (15)Mo3—K1—O1—K285.20 (12)
O3—Co2—K1—Mo2vii80.66 (18)Mo1—K1—O1—K2170.5 (3)
O7v—Co2—K1—Mo2vii76.92 (19)Mo2vii—K1—O1—K297.92 (13)
O11vi—Co2—K1—Mo2vii6.09 (15)O1—Mo1—O2—Co1110.5 (4)
O8vi—Co2—K1—Mo2vii109.8 (2)O3—Mo1—O2—Co16.8 (4)
O12—Co2—K1—Mo2vii178.31 (14)O4—Mo1—O2—Co1128.0 (3)
O11v—Co2—K1—Mo2vii106.44 (15)K1—Mo1—O2—Co140.9 (4)
O9—Mo3—K1—O5vii127.7 (4)K2i—Mo1—O2—Co1130.9 (5)
O10—Mo3—K1—O5vii109.3 (4)K1ii—Mo1—O2—Co1143.6 (4)
O11—Mo3—K1—O5vii137.2 (5)K2ii—Mo1—O2—Co185.9 (3)
O12—Mo3—K1—O5vii9.1 (4)O1—Mo1—O2—K2i20.3 (3)
O9—Mo3—K1—O7v172.1 (3)O3—Mo1—O2—K2i137.7 (2)
O10—Mo3—K1—O7v64.98 (19)O4—Mo1—O2—K2i101.2 (2)
O11—Mo3—K1—O7v178.5 (4)K1—Mo1—O2—K2i89.9 (2)
O12—Mo3—K1—O7v53.48 (19)K1ii—Mo1—O2—K2i85.49 (18)
O9—Mo3—K1—O4viii2.0 (3)K2ii—Mo1—O2—K2i143.27 (18)
O10—Mo3—K1—O4viii121.0 (2)O4ii—Co1—O2—Mo1138.7 (4)
O11—Mo3—K1—O4viii7.5 (4)O6—Co1—O2—Mo1128.4 (4)
O12—Mo3—K1—O4viii120.6 (2)O10v—Co1—O2—Mo114.4 (13)
O9—Mo3—K1—O3101.2 (3)O8vi—Co1—O2—Mo144.1 (4)
O10—Mo3—K1—O3135.84 (19)O12—Co1—O2—Mo136.5 (4)
O11—Mo3—K1—O3110.7 (4)K1iii—Co1—O2—Mo1121.4 (3)
O12—Mo3—K1—O317.38 (19)K2i—Co1—O2—Mo1134.6 (5)
O9—Mo3—K1—O10ix77.3 (3)O4ii—Co1—O2—K2i86.7 (2)
O10—Mo3—K1—O10ix45.6 (2)O6—Co1—O2—K2i6.2 (2)
O11—Mo3—K1—O10ix67.9 (4)O10v—Co1—O2—K2i120.2 (10)
O12—Mo3—K1—O10ix164.08 (19)O8vi—Co1—O2—K2i178.62 (19)
O10—Mo3—K1—O9122.9 (3)O12—Co1—O2—K2i98.07 (19)
O11—Mo3—K1—O99.4 (5)K1iii—Co1—O2—K2i104.03 (19)
O12—Mo3—K1—O9118.6 (3)O1—Mo1—O3—Co2111.6 (4)
O9—Mo3—K1—O145.1 (3)O2—Mo1—O3—Co25.6 (4)
O10—Mo3—K1—O1168.04 (19)O4—Mo1—O3—Co2127.8 (3)
O11—Mo3—K1—O154.5 (4)K1—Mo1—O3—Co2111.6 (4)
O12—Mo3—K1—O173.50 (18)K2i—Mo1—O3—Co234.2 (5)
O9—Mo3—K1—Co2133.2 (2)K1ii—Mo1—O3—Co295.4 (3)
O10—Mo3—K1—Co2103.86 (16)K2ii—Mo1—O3—Co297.3 (3)
O11—Mo3—K1—Co2142.6 (4)O1—Mo1—O3—K10.0 (3)
O12—Mo3—K1—Co214.60 (16)O2—Mo1—O3—K1117.2 (2)
O9—Mo3—K1—Co1x42.6 (3)O4—Mo1—O3—K1120.6 (2)
O10—Mo3—K1—Co1x80.31 (17)K2i—Mo1—O3—K177.4 (3)
O11—Mo3—K1—Co1x33.2 (4)K1ii—Mo1—O3—K1152.99 (11)
O12—Mo3—K1—Co1x161.23 (17)K2ii—Mo1—O3—K1151.1 (2)
O9—Mo3—K1—Mo173.8 (2)O7v—Co2—O3—Mo1134.8 (3)
O10—Mo3—K1—Mo1163.24 (16)O11vi—Co2—O3—Mo1130.6 (3)
O11—Mo3—K1—Mo183.3 (4)O8vi—Co2—O3—Mo144.3 (4)
O12—Mo3—K1—Mo144.78 (16)O12—Co2—O3—Mo141.4 (4)
O9—Mo3—K1—Mo2vii147.2 (4)O11v—Co2—O3—Mo138 (2)
O10—Mo3—K1—Mo2vii24.3 (3)K1—Co2—O3—Mo1117.9 (4)
O11—Mo3—K1—Mo2vii137.8 (4)O7v—Co2—O3—K116.92 (19)
O12—Mo3—K1—Mo2vii94.2 (3)O11vi—Co2—O3—K1111.51 (17)
O1—Mo1—K1—O5vii110.6 (2)O8vi—Co2—O3—K1162.22 (16)
O2—Mo1—K1—O5vii154.2 (2)O12—Co2—O3—K176.56 (17)
O3—Mo1—K1—O5vii69.4 (3)O11v—Co2—O3—K180 (2)
O4—Mo1—K1—O5vii13.1 (2)O5vii—K1—O3—Mo1110.7 (2)
K2i—Mo1—K1—O5vii158.98 (12)O7v—K1—O3—Mo1145.5 (3)
K1ii—Mo1—K1—O5vii39.87 (13)O4viii—K1—O3—Mo141.0 (2)
K2ii—Mo1—K1—O5vii37.47 (12)O10ix—K1—O3—Mo185.1 (18)
O1—Mo1—K1—O7v148.5 (2)O9—K1—O3—Mo152.1 (2)
O2—Mo1—K1—O7v53.3 (2)O1—K1—O3—Mo10.02 (16)
O3—Mo1—K1—O7v31.4 (2)Co2—K1—O3—Mo1132.0 (3)
O4—Mo1—K1—O7v114.0 (2)Co1x—K1—O3—Mo152.1 (3)
K2i—Mo1—K1—O7v100.15 (11)Mo3—K1—O3—Mo178.3 (2)
K1ii—Mo1—K1—O7v140.74 (12)Mo2vii—K1—O3—Mo1114.16 (19)
K2ii—Mo1—K1—O7v63.40 (11)O5vii—K1—O3—Co2117.33 (19)
O1—Mo1—K1—O4viii38.6 (2)O7v—K1—O3—Co213.51 (16)
O2—Mo1—K1—O4viii133.8 (2)O4viii—K1—O3—Co2173.02 (17)
O3—Mo1—K1—O4viii141.4 (2)O10ix—K1—O3—Co2142.9 (18)
O4—Mo1—K1—O4viii58.8 (3)O9—K1—O3—Co279.91 (18)
K2i—Mo1—K1—O4viii87.01 (11)O1—K1—O3—Co2132.0 (2)
K1ii—Mo1—K1—O4viii32.10 (12)Co1x—K1—O3—Co2175.88 (9)
K2ii—Mo1—K1—O4viii109.44 (11)Mo3—K1—O3—Co253.70 (14)
O1—Mo1—K1—O3180.0 (3)Mo1—K1—O3—Co2132.0 (3)
O2—Mo1—K1—O384.8 (3)Mo2vii—K1—O3—Co2113.86 (14)
O4—Mo1—K1—O382.6 (3)O1—Mo1—O4—Co1viii25.8 (4)
K2i—Mo1—K1—O3131.6 (2)O2—Mo1—O4—Co1viii145.8 (3)
K1ii—Mo1—K1—O3109.3 (2)O3—Mo1—O4—Co1viii93.4 (3)
K2ii—Mo1—K1—O332.0 (2)K1—Mo1—O4—Co1viii45.7 (3)
O1—Mo1—K1—O10ix10.6 (3)K2i—Mo1—O4—Co1viii100.3 (3)
O2—Mo1—K1—O10ix105.8 (3)K1ii—Mo1—O4—Co1viii121.1 (4)
O3—Mo1—K1—O10ix169.5 (3)K2ii—Mo1—O4—Co1viii139.2 (4)
O4—Mo1—K1—O10ix86.9 (3)O1—Mo1—O4—K1ii95.2 (3)
K2i—Mo1—K1—O10ix59.0 (2)O2—Mo1—O4—K1ii24.7 (3)
K1ii—Mo1—K1—O10ix60.2 (2)O3—Mo1—O4—K1ii145.5 (2)
K2ii—Mo1—K1—O10ix137.5 (2)K1—Mo1—O4—K1ii166.76 (9)
O1—Mo1—K1—O958.1 (2)K2i—Mo1—O4—K1ii20.8 (2)
O2—Mo1—K1—O937.1 (2)K2ii—Mo1—O4—K1ii99.7 (2)
O3—Mo1—K1—O9121.9 (3)O1—Mo1—O4—K2ii165.1 (2)
O4—Mo1—K1—O9155.5 (2)O2—Mo1—O4—K2ii75.0 (2)
K2i—Mo1—K1—O99.68 (12)O3—Mo1—O4—K2ii45.8 (3)
K1ii—Mo1—K1—O9128.80 (13)K1—Mo1—O4—K2ii93.56 (17)
K2ii—Mo1—K1—O9153.86 (12)K2i—Mo1—O4—K2ii120.49 (16)
O2—Mo1—K1—O195.2 (3)K1ii—Mo1—O4—K2ii99.7 (2)
O3—Mo1—K1—O1180.0 (3)O5—Mo2—O6—Co195.8 (4)
O4—Mo1—K1—O197.5 (3)O7—Mo2—O6—Co119.1 (5)
K2i—Mo1—K1—O148.4 (2)O8—Mo2—O6—Co1144.7 (4)
K1ii—Mo1—K1—O170.7 (2)K2iii—Mo2—O6—Co196.0 (4)
K2ii—Mo1—K1—O1148.1 (2)K1iv—Mo2—O6—Co1107.4 (4)
O1—Mo1—K1—Co2149.4 (2)K2i—Mo2—O6—Co1173.5 (6)
O2—Mo1—K1—Co254.20 (19)O5—Mo2—O6—K2i90.7 (3)
O3—Mo1—K1—Co230.6 (2)O7—Mo2—O6—K2i154.3 (2)
O4—Mo1—K1—Co2113.13 (18)O8—Mo2—O6—K2i28.7 (3)
K2i—Mo1—K1—Co2101.01 (4)K2iii—Mo2—O6—K2i90.6 (2)
K1ii—Mo1—K1—Co2139.87 (7)K1iv—Mo2—O6—K2i79.2 (3)
K2ii—Mo1—K1—Co262.53 (4)O2—Co1—O6—Mo2168.2 (4)
O1—Mo1—K1—Co1x35.7 (2)O4ii—Co1—O6—Mo299.4 (4)
O2—Mo1—K1—Co1x130.88 (19)O10v—Co1—O6—Mo22.5 (4)
O3—Mo1—K1—Co1x144.4 (2)O8vi—Co1—O6—Mo257.2 (15)
O4—Mo1—K1—Co1x61.79 (19)O12—Co1—O6—Mo278.5 (4)
K2i—Mo1—K1—Co1x84.07 (6)K1iii—Co1—O6—Mo252.2 (4)
K1ii—Mo1—K1—Co1x35.05 (8)K2i—Co1—O6—Mo2174.3 (5)
K2ii—Mo1—K1—Co1x112.39 (6)O2—Co1—O6—K2i6.0 (2)
O1—Mo1—K1—Mo385.8 (2)O4ii—Co1—O6—K2i86.30 (18)
O2—Mo1—K1—Mo39.38 (19)O10v—Co1—O6—K2i176.75 (17)
O3—Mo1—K1—Mo394.1 (2)O8vi—Co1—O6—K2i117.1 (13)
O4—Mo1—K1—Mo3176.71 (18)O12—Co1—O6—K2i95.76 (18)
K2i—Mo1—K1—Mo337.43 (4)K1iii—Co1—O6—K2i133.50 (12)
K1ii—Mo1—K1—Mo3156.55 (6)O6—Mo2—O5—K2iii0.2 (3)
K2ii—Mo1—K1—Mo3126.12 (4)O7—Mo2—O5—K2iii119.6 (2)
O1—Mo1—K1—Mo2vii103.5 (2)O8—Mo2—O5—K2iii122.8 (2)
O2—Mo1—K1—Mo2vii161.28 (19)K1iv—Mo2—O5—K2iii168.7 (4)
O3—Mo1—K1—Mo2vii76.5 (2)K2i—Mo2—O5—K2iii38.9 (2)
O4—Mo1—K1—Mo2vii6.05 (19)O6—Mo2—O5—K1iv168.9 (2)
K2i—Mo1—K1—Mo2vii151.91 (5)O7—Mo2—O5—K1iv71.6 (3)
K1ii—Mo1—K1—Mo2vii32.79 (8)O8—Mo2—O5—K1iv45.9 (3)
K2ii—Mo1—K1—Mo2vii44.55 (6)K2iii—Mo2—O5—K1iv168.7 (4)
O5vii—K1—K2—O179.5 (2)K2i—Mo2—O5—K1iv129.9 (2)
O7v—K1—K2—O168.2 (2)O5—Mo2—O7—Co2v157.1 (3)
O4viii—K1—K2—O1103.3 (2)O6—Mo2—O7—Co2v86.3 (3)
O3—K1—K2—O17.68 (19)O8—Mo2—O7—Co2v41.2 (3)
O10ix—K1—K2—O1167.47 (18)K2iii—Mo2—O7—Co2v161.58 (18)
O9—K1—K2—O183.4 (2)K1iv—Mo2—O7—Co2v121.8 (3)
Co2—K1—K2—O137.26 (16)K2i—Mo2—O7—Co2v59.7 (4)
Co1x—K1—K2—O1136.79 (16)O5—Mo2—O7—K1v25.9 (4)
Mo3—K1—K2—O181.89 (15)O6—Mo2—O7—K1v90.7 (4)
Mo1—K1—K2—O14.69 (15)O8—Mo2—O7—K1v141.9 (4)
Mo2vii—K1—K2—O1105.26 (16)K2iii—Mo2—O7—K1v15.4 (5)
O5vii—K1—K2—O5x129.1 (2)K1iv—Mo2—O7—K1v61.2 (4)
O7v—K1—K2—O5x83.2 (2)K2i—Mo2—O7—K1v117.2 (3)
O4viii—K1—K2—O5x105.31 (18)O5—Mo2—O8—Co2xii164.3 (2)
O3—K1—K2—O5x143.75 (16)O6—Mo2—O8—Co2xii76.4 (3)
O10ix—K1—K2—O5x41.10 (16)O7—Mo2—O8—Co2xii50.1 (3)
O9—K1—K2—O5x68.01 (19)K2iii—Mo2—O8—Co2xii153.78 (15)
O1—K1—K2—O5x151.4 (2)K1iv—Mo2—O8—Co2xii138.0 (2)
Co2—K1—K2—O5x114.17 (12)K2i—Mo2—O8—Co2xii93.7 (2)
Co1x—K1—K2—O5x71.78 (12)O5—Mo2—O8—Co1xii13.6 (4)
Mo3—K1—K2—O5x69.55 (12)O6—Mo2—O8—Co1xii132.9 (3)
Mo1—K1—K2—O5x146.75 (13)O7—Mo2—O8—Co1xii100.6 (4)
Mo2vii—K1—K2—O5x103.30 (13)K2iii—Mo2—O8—Co1xii55.5 (4)
O5vii—K1—K2—O2xi160.5 (4)K1iv—Mo2—O8—Co1xii12.7 (3)
O7v—K1—K2—O2xi51.8 (4)K2i—Mo2—O8—Co1xii115.6 (3)
O4viii—K1—K2—O2xi136.7 (4)O10—Mo3—O9—K157.1 (2)
O3—K1—K2—O2xi112.3 (4)O11—Mo3—O9—K1176.44 (18)
O10ix—K1—K2—O2xi72.5 (4)O12—Mo3—O9—K164.5 (3)
O9—K1—K2—O2xi36.6 (4)O10—Mo3—O9—K2143.9 (18)
O1—K1—K2—O2xi120.0 (4)O11—Mo3—O9—K224.5 (19)
Co2—K1—K2—O2xi82.8 (4)O12—Mo3—O9—K294.5 (18)
Co1x—K1—K2—O2xi103.2 (4)K1—Mo3—O9—K2159 (2)
Mo3—K1—K2—O2xi38.1 (4)O5vii—K1—O9—Mo3129.6 (4)
Mo1—K1—K2—O2xi115.3 (4)O7v—K1—O9—Mo37.1 (2)
Mo2vii—K1—K2—O2xi134.7 (4)O4viii—K1—O9—Mo3178.3 (2)
O5vii—K1—K2—O6xi74.7 (2)O3—K1—O9—Mo373.8 (2)
O7v—K1—K2—O6xi73.0 (2)O10ix—K1—O9—Mo3109.5 (2)
O4viii—K1—K2—O6xi98.5 (2)O1—K1—O9—Mo3124.7 (3)
O3—K1—K2—O6xi12.44 (19)Co2—K1—O9—Mo339.5 (2)
O10ix—K1—K2—O6xi162.70 (18)Co1x—K1—O9—Mo3145.3 (2)
O9—K1—K2—O6xi88.2 (2)Mo1—K1—O9—Mo396.4 (2)
O1—K1—K2—O6xi4.76 (19)Mo2vii—K1—O9—Mo3156.2 (3)
Co2—K1—K2—O6xi42.02 (17)O5vii—K1—O9—K247.1 (5)
Co1x—K1—K2—O6xi132.03 (16)O7v—K1—O9—K2169.57 (15)
Mo3—K1—K2—O6xi86.65 (16)O4viii—K1—O9—K25.00 (16)
Mo1—K1—K2—O6xi9.45 (15)O3—K1—O9—K2102.86 (16)
Mo2vii—K1—K2—O6xi100.50 (16)O10ix—K1—O9—K273.79 (16)
O5vii—K1—K2—O9162.9 (2)O1—K1—O9—K251.97 (14)
O7v—K1—K2—O915.2 (2)Co2—K1—O9—K2137.21 (13)
O4viii—K1—K2—O9173.3 (2)Co1x—K1—O9—K238.01 (14)
O3—K1—K2—O975.75 (19)Mo3—K1—O9—K2176.7 (3)
O10ix—K1—K2—O9109.10 (19)Mo1—K1—O9—K280.30 (11)
O1—K1—K2—O983.4 (2)Mo2vii—K1—O9—K227.1 (5)
Co2—K1—K2—O946.17 (16)O1—K2—O9—Mo391.4 (18)
Co1x—K1—K2—O9139.78 (16)O5x—K2—O9—Mo393.9 (18)
Mo3—K1—K2—O91.54 (15)O2xi—K2—O9—Mo333.7 (19)
Mo1—K1—K2—O978.74 (16)O6xi—K2—O9—Mo338.9 (19)
Mo2vii—K1—K2—O9171.31 (17)O4viii—K2—O9—Mo3164.1 (18)
O5vii—K1—K2—O4viii23.79 (18)Mo2x—K2—O9—Mo3116.5 (18)
O7v—K1—K2—O4viii171.5 (2)Co1xi—K2—O9—Mo32.5 (19)
O3—K1—K2—O4viii110.94 (16)Mo1xi—K2—O9—Mo361.6 (19)
O10ix—K1—K2—O4viii64.21 (16)K1—K2—O9—Mo3159.5 (19)
O9—K1—K2—O4viii173.3 (2)Mo2xi—K2—O9—Mo362.3 (18)
O1—K1—K2—O4viii103.3 (2)Mo1viii—K2—O9—Mo3143.1 (18)
Co2—K1—K2—O4viii140.52 (14)O1—K2—O9—K168.14 (18)
Co1x—K1—K2—O4viii33.53 (13)O5x—K2—O9—K1106.59 (17)
Mo3—K1—K2—O4viii174.86 (14)O2xi—K2—O9—K1166.75 (14)
Mo1—K1—K2—O4viii107.94 (13)O6xi—K2—O9—K1120.67 (15)
Mo2vii—K1—K2—O4viii2.01 (13)O4viii—K2—O9—K14.58 (14)
O5vii—K1—K2—Mo2x105.69 (13)Mo2x—K2—O9—K183.97 (11)
O7v—K1—K2—Mo2x106.63 (17)Co1xi—K2—O9—K1157.01 (9)
O4viii—K1—K2—Mo2x81.91 (13)Mo1xi—K2—O9—K1138.86 (10)
O3—K1—K2—Mo2x167.16 (11)Mo2xi—K2—O9—K197.28 (12)
O10ix—K1—K2—Mo2x17.70 (10)Mo1viii—K2—O9—K116.44 (14)
O9—K1—K2—Mo2x91.41 (16)O9—Mo3—O10—Co1v171.5 (3)
O1—K1—K2—Mo2x174.84 (16)O11—Mo3—O10—Co1v54.1 (3)
Co2—K1—K2—Mo2x137.58 (5)O12—Mo3—O10—Co1v73.1 (3)
Co1x—K1—K2—Mo2x48.37 (4)K1—Mo3—O10—Co1v146.6 (3)
Mo3—K1—K2—Mo2x92.95 (4)O9—Mo3—O10—K1ix36.1 (4)
Mo1—K1—K2—Mo2x170.15 (6)O11—Mo3—O10—K1ix81.2 (3)
Mo2vii—K1—K2—Mo2x79.90 (6)O12—Mo3—O10—K1ix151.6 (3)
O5vii—K1—K2—Co1xi105.8 (2)K1—Mo3—O10—K1ix78.1 (3)
O7v—K1—K2—Co1xi41.9 (3)O9—Mo3—O11—Co2xii29.4 (5)
O4viii—K1—K2—Co1xi129.6 (2)O10—Mo3—O11—Co2xii85.3 (4)
O3—K1—K2—Co1xi18.7 (2)O12—Mo3—O11—Co2xii145.3 (4)
O10ix—K1—K2—Co1xi166.19 (19)K1—Mo3—O11—Co2xii21.7 (7)
O9—K1—K2—Co1xi57.1 (2)O9—Mo3—O11—Co2v165.3 (2)
O1—K1—K2—Co1xi26.3 (2)O10—Mo3—O11—Co2v50.6 (3)
Co2—K1—K2—Co1xi10.9 (2)O12—Mo3—O11—Co2v78.8 (3)
Co1x—K1—K2—Co1xi163.13 (18)K1—Mo3—O11—Co2v157.6 (2)
Mo3—K1—K2—Co1xi55.54 (18)O9—Mo3—O12—Co273.7 (4)
Mo1—K1—K2—Co1xi21.66 (17)O10—Mo3—O12—Co240.9 (4)
Mo2vii—K1—K2—Co1xi131.61 (16)O11—Mo3—O12—Co2168.6 (3)
O5vii—K1—K2—Mo1xi109.09 (18)K1—Mo3—O12—Co229.0 (3)
O7v—K1—K2—Mo1xi103.2 (2)O9—Mo3—O12—Co185.1 (4)
O4viii—K1—K2—Mo1xi85.31 (19)O10—Mo3—O12—Co1160.3 (3)
O3—K1—K2—Mo1xi163.75 (16)O11—Mo3—O12—Co132.6 (4)
O10ix—K1—K2—Mo1xi21.10 (17)K1—Mo3—O12—Co1129.9 (3)
O9—K1—K2—Mo1xi88.0 (2)O3—Co2—O12—Mo380.0 (4)
O1—K1—K2—Mo1xi171.4 (2)O7v—Co2—O12—Mo317.9 (4)
Co2—K1—K2—Mo1xi134.17 (13)O11vi—Co2—O12—Mo3126.4 (5)
Co1x—K1—K2—Mo1xi51.78 (13)O8vi—Co2—O12—Mo3173.5 (4)
Mo3—K1—K2—Mo1xi89.55 (14)O11v—Co2—O12—Mo3100.3 (3)
Mo1—K1—K2—Mo1xi166.75 (15)K1—Co2—O12—Mo330.1 (3)
Mo2vii—K1—K2—Mo1xi83.30 (15)O3—Co2—O12—Co184.5 (2)
O5vii—K1—K2—Mo2xi64.07 (14)O7v—Co2—O12—Co1177.60 (18)
O7v—K1—K2—Mo2xi83.61 (17)O11vi—Co2—O12—Co169.1 (6)
O4viii—K1—K2—Mo2xi87.86 (14)O8vi—Co2—O12—Co18.98 (18)
O3—K1—K2—Mo2xi23.08 (12)O11v—Co2—O12—Co195.16 (18)
O10ix—K1—K2—Mo2xi152.07 (11)K1—Co2—O12—Co1134.43 (16)
O9—K1—K2—Mo2xi98.83 (16)O2—Co1—O12—Mo383.5 (4)
O1—K1—K2—Mo2xi15.40 (14)O4ii—Co1—O12—Mo3166.4 (19)
Co2—K1—K2—Mo2xi52.66 (8)O6—Co1—O12—Mo310.1 (4)
Co1x—K1—K2—Mo2xi121.39 (7)O10v—Co1—O12—Mo3100.3 (4)
Mo3—K1—K2—Mo2xi97.28 (6)O8vi—Co1—O12—Mo3172.9 (4)
Mo1—K1—K2—Mo2xi20.08 (5)K1iii—Co1—O12—Mo3115.8 (3)
Mo2vii—K1—K2—Mo2xi89.87 (7)K2i—Co1—O12—Mo337.7 (3)
O5vii—K1—K2—Mo1viii1.78 (12)O2—Co1—O12—Co280.6 (2)
O7v—K1—K2—Mo1viii145.90 (17)O4ii—Co1—O12—Co229 (2)
O4viii—K1—K2—Mo1viii25.57 (13)O6—Co1—O12—Co2174.26 (19)
O3—K1—K2—Mo1viii85.37 (11)O10v—Co1—O12—Co295.5 (2)
O10ix—K1—K2—Mo1viii89.78 (10)O8vi—Co1—O12—Co28.72 (18)
O9—K1—K2—Mo1viii161.12 (16)K1iii—Co1—O12—Co280.1 (2)
O1—K1—K2—Mo1viii77.69 (15)K2i—Co1—O12—Co2126.50 (14)
Symmetry codes: (i) x+1, y+1/2, z+1/2; (ii) x, y+1/2, z+1/2; (iii) x, y+1, z; (iv) x+1, y+1, z; (v) x+1, y+1, z+1; (vi) x1, y, z; (vii) x1, y1, z; (viii) x, y1/2, z+1/2; (ix) x+1, y, z+1; (x) x, y1, z; (xi) x+1, y1/2, z+1/2; (xii) x+1, y, z.
(beta) top
Crystal data top
Co2K2Mo3O12F(000) = 2512
Mr = 675.88Dx = 3.754 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 7.0418 (3) ÅCell parameters from 4486 reflections
b = 19.3329 (7) Åθ = 2.3–29.2°
c = 17.7267 (7) ŵ = 6.53 mm1
β = 97.608 (4)°T = 298 K
V = 2392.04 (16) Å3Needle, blue
Z = 80.12 × 0.04 × 0.03 mm
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.3025 independent reflections
Radiation source: Enhance (Mo) X-ray Source1739 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.071
Detector resolution: 8.4012 pixels mm-1θmax = 29.2°, θmin = 2.3°
Rotation method data acquisition using ω and phi scans.h = 99
Absorption correction: analytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
k = 2526
Tmin = 0.509, Tmax = 0.871l = 2324
15336 measured reflections
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullPrimary atom site location: structure-invariant direct methods
R[F2 > 2σ(F2)] = 0.038Secondary atom site location: difference Fourier map
wR(F2) = 0.121 w = 1/[σ2(Fo2) + (0.0529P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max < 0.001
3025 reflectionsΔρmax = 1.76 e Å3
178 parametersΔρmin = 1.78 e Å3
Crystal data top
Co2K2Mo3O12V = 2392.04 (16) Å3
Mr = 675.88Z = 8
Monoclinic, C2/cMo Kα radiation
a = 7.0418 (3) ŵ = 6.53 mm1
b = 19.3329 (7) ÅT = 298 K
c = 17.7267 (7) Å0.12 × 0.04 × 0.03 mm
β = 97.608 (4)°
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.3025 independent reflections
Absorption correction: analytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
1739 reflections with I > 2σ(I)
Tmin = 0.509, Tmax = 0.871Rint = 0.071
15336 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.038178 parameters
wR(F2) = 0.1210 restraints
S = 1.05Δρmax = 1.76 e Å3
3025 reflectionsΔρmin = 1.78 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Mo10.44455 (12)0.54543 (4)0.36986 (5)0.0130 (2)
Mo20.12869 (12)0.63426 (5)0.59743 (5)0.0146 (2)
Mo30.09676 (12)0.72629 (4)0.41307 (5)0.0132 (2)
Co10.34851 (18)0.60621 (7)0.54411 (7)0.0138 (3)
Co20.60605 (18)0.69965 (7)0.44820 (7)0.0139 (3)
K10.50000.39013 (19)0.25000.0359 (10)
K20.0624 (4)0.53650 (13)0.35597 (17)0.0360 (7)
K30.6121 (9)0.6985 (3)0.2478 (3)0.048 (2)0.532 (9)
O10.2949 (10)0.5470 (4)0.2850 (4)0.0207 (16)
O20.3062 (10)0.5473 (3)0.4456 (4)0.0189 (16)
O30.5938 (10)0.6206 (3)0.3720 (4)0.0195 (16)
O40.5915 (9)0.4704 (3)0.3759 (4)0.0154 (16)
O50.1570 (11)0.5871 (4)0.6769 (4)0.0280 (18)
O60.0602 (9)0.5976 (4)0.5559 (4)0.0214 (17)
O70.0766 (9)0.7209 (4)0.6286 (4)0.0185 (16)
O80.3549 (9)0.6278 (3)0.5362 (4)0.0151 (15)
O90.0419 (12)0.6736 (4)0.3378 (4)0.034 (2)
O100.1213 (9)0.8099 (3)0.3751 (4)0.0177 (16)
O110.0987 (9)0.7202 (3)0.4664 (4)0.0145 (15)
O120.3185 (9)0.6925 (3)0.4651 (4)0.0153 (15)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mo10.0126 (5)0.0095 (4)0.0165 (4)0.0004 (4)0.0007 (4)0.0004 (4)
Mo20.0123 (5)0.0118 (5)0.0191 (4)0.0006 (4)0.0002 (4)0.0023 (4)
Mo30.0127 (5)0.0101 (5)0.0167 (4)0.0003 (4)0.0011 (4)0.0014 (4)
Co10.0131 (7)0.0105 (7)0.0178 (7)0.0002 (6)0.0022 (6)0.0017 (6)
Co20.0123 (7)0.0110 (7)0.0183 (7)0.0007 (6)0.0023 (6)0.0000 (6)
K10.058 (3)0.031 (2)0.0187 (17)0.0000.0042 (18)0.000
K20.0162 (13)0.0261 (15)0.0646 (19)0.0006 (11)0.0012 (13)0.0067 (14)
K30.084 (5)0.034 (4)0.023 (3)0.004 (3)0.004 (3)0.003 (2)
O10.019 (4)0.023 (4)0.018 (4)0.001 (3)0.003 (3)0.005 (3)
O20.018 (4)0.009 (4)0.030 (4)0.007 (3)0.005 (3)0.004 (3)
O30.022 (4)0.014 (4)0.022 (4)0.012 (3)0.003 (3)0.001 (3)
O40.014 (4)0.017 (4)0.016 (3)0.001 (3)0.007 (3)0.001 (3)
O50.034 (5)0.018 (4)0.030 (4)0.003 (4)0.004 (4)0.004 (3)
O60.013 (4)0.019 (4)0.034 (4)0.006 (3)0.007 (3)0.002 (3)
O70.019 (4)0.017 (4)0.020 (4)0.009 (3)0.002 (3)0.003 (3)
O80.008 (3)0.015 (4)0.023 (4)0.001 (3)0.004 (3)0.005 (3)
O90.047 (5)0.024 (5)0.028 (4)0.005 (4)0.006 (4)0.000 (4)
O100.021 (4)0.014 (4)0.018 (3)0.003 (3)0.001 (3)0.001 (3)
O110.009 (3)0.012 (4)0.022 (3)0.001 (3)0.003 (3)0.000 (3)
O120.012 (4)0.013 (4)0.023 (4)0.003 (3)0.012 (3)0.004 (3)
Geometric parameters (Å, º) top
Mo1—O11.718 (7)K1—Mo1ii3.729 (3)
Mo1—O21.761 (7)K1—Mo2iii4.0306 (10)
Mo1—O41.776 (7)K1—Mo2viii4.0306 (10)
Mo1—O31.791 (6)K2—O92.781 (8)
Mo1—K2i3.517 (3)K2—O1x2.808 (7)
Mo1—K23.550 (3)K2—O4xi2.815 (7)
Mo1—K3ii3.612 (5)K2—O22.866 (8)
Mo1—K13.729 (3)K2—O5iii2.946 (8)
Mo1—K33.937 (6)K2—O3xi2.961 (8)
Mo2—O51.712 (7)K2—O12.965 (7)
Mo2—O61.753 (7)K2—O6iii3.026 (7)
Mo2—O71.786 (7)K2—Mo1xi3.517 (3)
Mo2—O81.810 (6)K2—Mo2iii3.619 (3)
Mo2—K2iii3.619 (3)K3—K3ii1.590 (13)
Mo2—K1iii4.0306 (10)K3—O32.684 (8)
Mo3—O91.683 (7)K3—O7v2.727 (8)
Mo3—O101.768 (7)K3—O7xii2.814 (9)
Mo3—O111.774 (7)K3—O3ii2.840 (9)
Mo3—O121.826 (7)K3—O9ii3.074 (10)
Mo3—K3ii3.766 (6)K3—O1ii3.074 (9)
Mo3—K23.930 (3)K3—O9i3.264 (10)
Co1—O4iv2.056 (7)K3—Co2ii3.609 (5)
Co1—O22.073 (7)K3—Mo1ii3.612 (5)
Co1—O62.075 (7)K3—Mo3ii3.766 (6)
Co1—O8i2.153 (6)O1—K2x2.808 (7)
Co1—O10v2.155 (7)O1—K3ii3.074 (9)
Co1—O122.170 (6)O3—K3ii2.840 (9)
Co1—K1iv3.6651 (13)O3—K2i2.961 (8)
Co1—K2iii3.969 (3)O4—Co1iv2.056 (7)
Co2—O32.033 (7)O4—K2i2.815 (7)
Co2—O7v2.046 (7)O5—K1iii2.921 (8)
Co2—O8i2.080 (6)O5—K2iii2.946 (8)
Co2—O122.091 (6)O6—K2iii3.026 (7)
Co2—O11i2.099 (6)O7—Co2v2.046 (7)
Co2—O11v2.172 (7)O7—K3v2.727 (8)
Co2—K33.558 (5)O7—K3xiii2.814 (9)
Co2—K3ii3.609 (5)O8—Co2xi2.080 (6)
K1—O42.725 (7)O8—Co1xi2.153 (6)
K1—O4ii2.725 (7)O9—K3ii3.074 (10)
K1—O10vi2.748 (7)O9—K3xi3.264 (10)
K1—O10vii2.748 (7)O10—Co1v2.155 (7)
K1—O5iii2.921 (8)O10—K1xiv2.748 (7)
K1—O5viii2.921 (8)O11—Co2xi2.099 (6)
K1—Co1iv3.6651 (13)O11—Co2v2.172 (6)
K1—Co1ix3.6651 (13)
O1—Mo1—O2109.3 (3)O9—K2—O1x87.7 (2)
O1—Mo1—O4110.6 (3)O9—K2—O4xi133.9 (2)
O2—Mo1—O4110.3 (3)O1x—K2—O4xi74.4 (2)
O1—Mo1—O3107.1 (3)O9—K2—O276.2 (2)
O2—Mo1—O3110.5 (3)O1x—K2—O2150.1 (2)
O4—Mo1—O3109.0 (3)O4xi—K2—O2134.4 (2)
O1—Mo1—K2i115.9 (2)O9—K2—O5iii126.7 (2)
O2—Mo1—K2i134.9 (2)O1x—K2—O5iii98.1 (2)
O4—Mo1—K2i52.5 (2)O4xi—K2—O5iii98.2 (2)
O3—Mo1—K2i57.3 (2)O2—K2—O5iii73.1 (2)
O1—Mo1—K256.3 (2)O9—K2—O3xi73.7 (2)
O2—Mo1—K253.2 (2)O1x—K2—O3xi70.0 (2)
O4—Mo1—K2122.5 (2)O4xi—K2—O3xi60.32 (19)
O3—Mo1—K2128.5 (2)O2—K2—O3xi126.8 (2)
K2i—Mo1—K2170.29 (10)O5iii—K2—O3xi157.1 (2)
O1—Mo1—K3ii58.2 (2)O9—K2—O168.5 (2)
O2—Mo1—K3ii113.2 (2)O1x—K2—O192.6 (2)
O4—Mo1—K3ii136.2 (2)O4xi—K2—O1151.8 (2)
O3—Mo1—K3ii50.7 (2)O2—K2—O158.20 (19)
K2i—Mo1—K3ii91.96 (11)O5iii—K2—O158.3 (2)
K2—Mo1—K3ii88.09 (11)O3xi—K2—O1138.9 (2)
O1—Mo1—K167.3 (2)O9—K2—O6iii153.3 (2)
O2—Mo1—K1124.1 (2)O1x—K2—O6iii118.9 (2)
O4—Mo1—K143.3 (2)O4xi—K2—O6iii59.45 (19)
O3—Mo1—K1124.1 (2)O2—K2—O6iii80.43 (19)
K2i—Mo1—K175.03 (5)O5iii—K2—O6iii56.0 (2)
K2—Mo1—K195.83 (5)O3xi—K2—O6iii111.7 (2)
K3ii—Mo1—K1110.02 (9)O1—K2—O6iii109.3 (2)
O1—Mo1—K372.5 (2)O9—K2—Mo1xi103.86 (19)
O2—Mo1—K3129.8 (2)O1x—K2—Mo1xi66.06 (15)
O4—Mo1—K3115.6 (2)O4xi—K2—Mo1xi30.05 (14)
O3—Mo1—K335.3 (2)O2—K2—Mo1xi141.96 (18)
K2i—Mo1—K368.17 (10)O5iii—K2—Mo1xi127.02 (17)
K2—Mo1—K3111.72 (10)O3xi—K2—Mo1xi30.59 (13)
K3ii—Mo1—K323.82 (19)O1—K2—Mo1xi158.03 (16)
K1—Mo1—K3103.33 (8)O6iii—K2—Mo1xi86.76 (14)
O5—Mo2—O6107.9 (4)O9—K2—Mo171.53 (18)
O5—Mo2—O7106.6 (3)O1x—K2—Mo1121.38 (17)
O6—Mo2—O7111.9 (3)O4xi—K2—Mo1153.23 (16)
O5—Mo2—O8105.5 (3)O2—K2—Mo129.47 (14)
O6—Mo2—O8112.1 (3)O5iii—K2—Mo160.28 (15)
O7—Mo2—O8112.3 (3)O3xi—K2—Mo1142.56 (15)
O5—Mo2—K2iii53.6 (3)O1—K2—Mo128.84 (13)
O6—Mo2—K2iii56.4 (2)O6iii—K2—Mo193.99 (14)
O7—Mo2—K2iii136.9 (2)Mo1xi—K2—Mo1170.29 (10)
O8—Mo2—K2iii110.2 (2)O9—K2—Mo2iii143.15 (19)
O5—Mo2—K1iii39.5 (3)O1x—K2—Mo2iii115.10 (16)
O6—Mo2—K1iii146.1 (2)O4xi—K2—Mo2iii81.92 (15)
O7—Mo2—K1iii91.6 (2)O2—K2—Mo2iii69.98 (14)
O8—Mo2—K1iii78.3 (2)O5iii—K2—Mo2iii27.90 (14)
K2iii—Mo2—K1iii89.70 (7)O3xi—K2—Mo2iii139.74 (15)
O9—Mo3—O10105.9 (3)O1—K2—Mo2iii81.27 (14)
O9—Mo3—O11105.7 (4)O6iii—K2—Mo2iii28.87 (13)
O10—Mo3—O11112.7 (3)Mo1xi—K2—Mo2iii111.68 (7)
O9—Mo3—O12106.0 (3)Mo1—K2—Mo2iii71.85 (5)
O10—Mo3—O12113.5 (3)O9—K2—Mo321.44 (15)
O11—Mo3—O12112.2 (3)O1x—K2—Mo3105.95 (16)
O9—Mo3—K3ii53.4 (3)O4xi—K2—Mo3127.84 (16)
O10—Mo3—K3ii75.6 (2)O2—K2—Mo365.35 (14)
O11—Mo3—K3ii158.9 (2)O5iii—K2—Mo3132.02 (17)
O12—Mo3—K3ii79.5 (2)O3xi—K2—Mo370.81 (14)
O9—Mo3—K237.2 (3)O1—K2—Mo379.42 (15)
O10—Mo3—K2142.6 (2)O6iii—K2—Mo3133.26 (16)
O11—Mo3—K282.0 (2)Mo1xi—K2—Mo3100.75 (7)
O12—Mo3—K289.5 (2)Mo1—K2—Mo371.75 (5)
K3ii—Mo3—K280.61 (9)Mo2iii—K2—Mo3135.09 (8)
O4iv—Co1—O2100.3 (3)K3ii—K3—O378.8 (3)
O4iv—Co1—O689.3 (3)K3ii—K3—O7v76.4 (3)
O2—Co1—O690.4 (3)O3—K3—O7v69.1 (2)
O4iv—Co1—O8i94.1 (3)K3ii—K3—O7xii70.3 (3)
O2—Co1—O8i94.8 (3)O3—K3—O7xii149.1 (3)
O6—Co1—O8i173.1 (3)O7v—K3—O7xii101.7 (3)
O4iv—Co1—O10v95.2 (3)K3ii—K3—O3ii67.9 (3)
O2—Co1—O10v164.5 (3)O3—K3—O3ii104.0 (3)
O6—Co1—O10v90.3 (3)O7v—K3—O3ii144.3 (3)
O8i—Co1—O10v83.5 (3)O7xii—K3—O3ii65.7 (2)
O4iv—Co1—O12173.0 (3)K3ii—K3—O9ii151.7 (4)
O2—Co1—O1283.6 (3)O3—K3—O9ii116.4 (3)
O6—Co1—O1296.5 (3)O7v—K3—O9ii130.4 (3)
O8i—Co1—O1279.7 (2)O7xii—K3—O9ii92.4 (2)
O10v—Co1—O1280.9 (3)O3ii—K3—O9ii84.7 (2)
O4iv—Co1—K1iv47.22 (19)K3ii—K3—O1ii104.3 (2)
O2—Co1—K1iv147.1 (2)O3—K3—O1ii69.9 (2)
O6—Co1—K1iv93.49 (19)O7v—K3—O1ii137.9 (3)
O8i—Co1—K1iv84.51 (17)O7xii—K3—O1ii118.5 (3)
O10v—Co1—K1iv48.23 (18)O3ii—K3—O1ii56.9 (2)
O12—Co1—K1iv128.18 (19)O9ii—K3—O1ii63.6 (2)
O4iv—Co1—K2iii42.38 (19)K3ii—K3—O9i147.0 (4)
O2—Co1—K2iii88.22 (19)O3—K3—O9i70.1 (2)
O6—Co1—K2iii48.6 (2)O7v—K3—O9i82.5 (2)
O8i—Co1—K2iii135.89 (18)O7xii—K3—O9i139.7 (3)
O10v—Co1—K2iii103.75 (18)O3ii—K3—O9i129.5 (3)
O12—Co1—K2iii144.13 (18)O9ii—K3—O9i58.2 (3)
K1iv—Co1—K2iii70.55 (6)O1ii—K3—O9i75.2 (2)
O3—Co2—O7v97.5 (3)K3ii—K3—Co279.0 (3)
O3—Co2—O8i89.2 (3)O3—K3—Co234.57 (15)
O7v—Co2—O8i173.2 (3)O7v—K3—Co234.92 (15)
O3—Co2—O1295.1 (3)O7xii—K3—Co2132.8 (2)
O7v—Co2—O1297.5 (3)O3ii—K3—Co2132.7 (2)
O8i—Co2—O1283.3 (2)O9ii—K3—Co2127.5 (2)
O3—Co2—O11i101.4 (3)O1ii—K3—Co2103.09 (19)
O7v—Co2—O11i88.4 (3)O9i—K3—Co269.29 (17)
O8i—Co2—O11i88.9 (2)K3ii—K3—Co2ii75.4 (4)
O12—Co2—O11i161.6 (3)O3—K3—Co2ii137.1 (2)
O3—Co2—O11v175.1 (3)O7v—K3—Co2ii134.2 (2)
O7v—Co2—O11v85.3 (3)O7xii—K3—Co2ii34.40 (15)
O8i—Co2—O11v88.1 (3)O3ii—K3—Co2ii34.20 (15)
O12—Co2—O11v80.5 (2)O9ii—K3—Co2ii77.86 (17)
O11i—Co2—O11v82.7 (3)O1ii—K3—Co2ii84.12 (17)
O3—Co2—K348.5 (2)O9i—K3—Co2ii136.1 (2)
O7v—Co2—K349.7 (2)Co2—K3—Co2ii154.4 (2)
O8i—Co2—K3136.6 (2)K3ii—K3—Mo1ii89.6 (2)
O12—Co2—K3106.4 (2)O3—K3—Mo1ii90.0 (2)
O11i—Co2—K390.7 (2)O7v—K3—Mo1ii156.6 (2)
O11v—Co2—K3134.82 (19)O7xii—K3—Mo1ii90.86 (19)
O3—Co2—K3ii51.7 (2)O3ii—K3—Mo1ii29.23 (14)
O7v—Co2—K3ii51.0 (2)O9ii—K3—Mo1ii67.73 (17)
O8i—Co2—K3ii135.6 (2)O1ii—K3—Mo1ii28.35 (14)
O12—Co2—K3ii80.9 (2)O9i—K3—Mo1ii100.7 (2)
O11i—Co2—K3ii115.8 (2)Co2—K3—Mo1ii124.54 (15)
O11v—Co2—K3ii129.00 (19)Co2ii—K3—Mo1ii56.53 (8)
K3—Co2—K3ii25.6 (2)K3ii—K3—Mo3ii132.8 (4)
O4—K1—O4ii110.5 (3)O3—K3—Mo3ii142.3 (3)
O4—K1—O10vi175.58 (19)O7v—K3—Mo3ii130.1 (2)
O4ii—K1—O10vi69.28 (19)O7xii—K3—Mo3ii66.55 (17)
O4—K1—O10vii69.28 (19)O3ii—K3—Mo3ii77.54 (18)
O4ii—K1—O10vii175.58 (19)O9ii—K3—Mo3ii26.06 (14)
O10vi—K1—O10vii111.3 (3)O1ii—K3—Mo3ii80.87 (18)
O4—K1—O5iii70.78 (19)O9i—K3—Mo3ii80.10 (19)
O4ii—K1—O5iii99.1 (2)Co2—K3—Mo3ii146.61 (19)
O10vi—K1—O5iii104.8 (2)Co2ii—K3—Mo3ii58.31 (8)
O10vii—K1—O5iii85.1 (2)Mo1ii—K3—Mo3ii73.08 (10)
O4—K1—O5viii99.1 (2)Mo1—O1—K2x174.5 (4)
O4ii—K1—O5viii70.78 (19)Mo1—O1—K294.8 (3)
O10vi—K1—O5viii85.1 (2)K2x—O1—K286.8 (2)
O10vii—K1—O5viii104.8 (2)Mo1—O1—K3ii93.5 (3)
O5iii—K1—O5viii162.7 (3)K2x—O1—K3ii90.8 (2)
O4—K1—Co1iv33.63 (14)K2—O1—K3ii111.1 (3)
O4ii—K1—Co1iv144.16 (19)Mo1—O2—Co1128.4 (4)
O10vi—K1—Co1iv146.40 (19)Mo1—O2—K297.3 (3)
O10vii—K1—Co1iv35.80 (14)Co1—O2—K2121.7 (3)
O5iii—K1—Co1iv72.80 (14)Mo1—O3—Co2126.6 (4)
O5viii—K1—Co1iv106.85 (14)Mo1—O3—K3122.0 (3)
O4—K1—Co1ix144.16 (19)Co2—O3—K397.0 (3)
O4ii—K1—Co1ix33.63 (14)Mo1—O3—K3ii100.0 (3)
O10vi—K1—Co1ix35.80 (14)Co2—O3—K3ii94.1 (3)
O10vii—K1—Co1ix146.40 (19)K3—O3—K3ii33.3 (3)
O5iii—K1—Co1ix106.85 (14)Mo1—O3—K2i92.1 (3)
O5viii—K1—Co1ix72.80 (14)Co2—O3—K2i120.9 (3)
Co1iv—K1—Co1ix177.78 (12)K3—O3—K2i95.8 (2)
O4—K1—Mo126.58 (14)K3ii—O3—K2i124.2 (3)
O4ii—K1—Mo188.66 (17)Mo1—O4—Co1iv134.0 (3)
O10vi—K1—Mo1150.41 (15)Mo1—O4—K1110.1 (3)
O10vii—K1—Mo192.26 (14)Co1iv—O4—K199.2 (3)
O5iii—K1—Mo158.06 (15)Mo1—O4—K2i97.4 (3)
O5viii—K1—Mo1106.65 (16)Co1iv—O4—K2i108.1 (3)
Co1iv—K1—Mo157.01 (4)K1—O4—K2i105.7 (2)
Co1ix—K1—Mo1120.88 (9)Mo2—O5—K1iii118.6 (4)
O4—K1—Mo1ii88.66 (17)Mo2—O5—K2iii98.5 (3)
O4ii—K1—Mo1ii26.58 (14)K1iii—O5—K2iii134.1 (3)
O10vi—K1—Mo1ii92.26 (14)Mo2—O6—Co1144.8 (4)
O10vii—K1—Mo1ii150.41 (15)Mo2—O6—K2iii94.7 (3)
O5iii—K1—Mo1ii106.65 (16)Co1—O6—K2iii100.5 (3)
O5viii—K1—Mo1ii58.06 (15)Mo2—O7—Co2v120.0 (3)
Co1iv—K1—Mo1ii120.88 (9)Mo2—O7—K3v138.4 (3)
Co1ix—K1—Mo1ii57.01 (4)Co2v—O7—K3v95.3 (3)
Mo1—K1—Mo1ii72.73 (7)Mo2—O7—K3xiii144.0 (4)
O4—K1—Mo2iii67.74 (13)Co2v—O7—K3xiii94.6 (3)
O4ii—K1—Mo2iii120.81 (14)K3v—O7—K3xiii33.3 (3)
O10vi—K1—Mo2iii108.39 (15)Mo2—O8—Co2xi115.0 (3)
O10vii—K1—Mo2iii63.42 (14)Mo2—O8—Co1xi139.4 (3)
O5iii—K1—Mo2iii21.91 (14)Co2xi—O8—Co1xi98.4 (3)
O5viii—K1—Mo2iii164.37 (14)Mo3—O9—K2121.4 (4)
Co1iv—K1—Mo2iii57.53 (2)Mo3—O9—K3ii100.6 (4)
Co1ix—K1—Mo2iii122.77 (3)K2—O9—K3ii116.4 (3)
Mo1—K1—Mo2iii65.52 (3)Mo3—O9—K3xi113.5 (4)
Mo1ii—K1—Mo2iii127.07 (8)K2—O9—K3xi87.4 (2)
O4—K1—Mo2viii120.81 (14)K3ii—O9—K3xi118.7 (3)
O4ii—K1—Mo2viii67.74 (13)Mo3—O10—Co1v116.2 (3)
O10vi—K1—Mo2viii63.42 (14)Mo3—O10—K1xiv141.9 (3)
O10vii—K1—Mo2viii108.39 (15)Co1v—O10—K1xiv96.0 (2)
O5iii—K1—Mo2viii164.37 (14)Mo3—O11—Co2xi138.9 (4)
O5viii—K1—Mo2viii21.91 (14)Mo3—O11—Co2v114.6 (3)
Co1iv—K1—Mo2viii122.77 (3)Co2xi—O11—Co2v97.3 (3)
Co1ix—K1—Mo2viii57.53 (2)Mo3—O12—Co2133.1 (3)
Mo1—K1—Mo2viii127.07 (8)Mo3—O12—Co1127.2 (3)
Mo1ii—K1—Mo2viii65.52 (3)Co2—O12—Co197.5 (3)
Mo2iii—K1—Mo2viii166.56 (11)
O1—Mo1—K1—O4177.6 (4)O3—Mo1—O2—Co117.7 (6)
O2—Mo1—K1—O483.9 (4)K2i—Mo1—O2—Co146.1 (6)
O3—Mo1—K1—O481.7 (4)K2—Mo1—O2—Co1141.1 (6)
K2i—Mo1—K1—O450.6 (3)K3ii—Mo1—O2—Co172.6 (5)
K2—Mo1—K1—O4132.7 (3)K1—Mo1—O2—Co1149.6 (3)
K3ii—Mo1—K1—O4137.2 (3)K3—Mo1—O2—Co152.3 (6)
K3—Mo1—K1—O4113.3 (3)O1—Mo1—O2—K25.8 (3)
O1—Mo1—K1—O4ii31.4 (3)O4—Mo1—O2—K2116.0 (3)
O2—Mo1—K1—O4ii130.0 (3)O3—Mo1—O2—K2123.4 (3)
O4—Mo1—K1—O4ii146.2 (2)K2i—Mo1—O2—K2172.83 (13)
O3—Mo1—K1—O4ii64.4 (3)K3ii—Mo1—O2—K268.5 (2)
K2i—Mo1—K1—O4ii95.54 (15)K1—Mo1—O2—K269.3 (3)
K2—Mo1—K1—O4ii81.13 (14)K3—Mo1—O2—K288.7 (3)
K3ii—Mo1—K1—O4ii8.96 (17)O4iv—Co1—O2—Mo1114.3 (5)
K3—Mo1—K1—O4ii32.85 (17)O6—Co1—O2—Mo1156.4 (5)
O1—Mo1—K1—O10vi9.3 (4)O8i—Co1—O2—Mo119.2 (5)
O2—Mo1—K1—O10vi89.2 (4)O10v—Co1—O2—Mo163.8 (12)
O4—Mo1—K1—O10vi173.1 (4)O12—Co1—O2—Mo159.9 (5)
O3—Mo1—K1—O10vi105.2 (4)K1iv—Co1—O2—Mo1106.5 (4)
K2i—Mo1—K1—O10vi136.3 (3)K2iii—Co1—O2—Mo1155.1 (4)
K2—Mo1—K1—O10vi40.4 (3)O4iv—Co1—O2—K2112.8 (3)
K3ii—Mo1—K1—O10vi49.7 (3)O6—Co1—O2—K223.5 (3)
K3—Mo1—K1—O10vi73.6 (3)O8i—Co1—O2—K2152.1 (3)
O1—Mo1—K1—O10vii152.9 (3)O10v—Co1—O2—K269.1 (11)
O2—Mo1—K1—O10vii54.4 (3)O12—Co1—O2—K273.0 (3)
O4—Mo1—K1—O10vii29.5 (3)K1iv—Co1—O2—K2120.6 (3)
O3—Mo1—K1—O10vii111.2 (3)K2iii—Co1—O2—K272.0 (3)
K2i—Mo1—K1—O10vii80.14 (15)O9—K2—O2—Mo176.8 (3)
K2—Mo1—K1—O10vii103.19 (15)O1x—K2—O2—Mo117.5 (6)
K3ii—Mo1—K1—O10vii166.71 (18)O4xi—K2—O2—Mo1143.9 (3)
K3—Mo1—K1—O10vii142.82 (17)O5iii—K2—O2—Mo159.1 (3)
O1—Mo1—K1—O5iii70.1 (3)O3xi—K2—O2—Mo1133.8 (3)
O2—Mo1—K1—O5iii28.4 (3)O1—K2—O2—Mo13.7 (2)
O4—Mo1—K1—O5iii112.3 (3)O6iii—K2—O2—Mo1116.2 (3)
O3—Mo1—K1—O5iii166.0 (3)Mo1xi—K2—O2—Mo1171.74 (16)
K2i—Mo1—K1—O5iii162.91 (17)Mo2iii—K2—O2—Mo188.3 (2)
K2—Mo1—K1—O5iii20.42 (17)Mo3—K2—O2—Mo196.4 (2)
K3ii—Mo1—K1—O5iii110.5 (2)O9—K2—O2—Co167.9 (3)
K3—Mo1—K1—O5iii134.41 (19)O1x—K2—O2—Co1127.2 (4)
O1—Mo1—K1—O5viii100.9 (3)O4xi—K2—O2—Co171.5 (4)
O2—Mo1—K1—O5viii160.6 (3)O5iii—K2—O2—Co1156.3 (4)
O4—Mo1—K1—O5viii76.7 (3)O3xi—K2—O2—Co110.8 (4)
O3—Mo1—K1—O5viii5.0 (3)O1—K2—O2—Co1140.9 (4)
K2i—Mo1—K1—O5viii26.06 (16)O6iii—K2—O2—Co199.1 (3)
K2—Mo1—K1—O5viii150.61 (16)Mo1xi—K2—O2—Co127.1 (5)
K3ii—Mo1—K1—O5viii60.52 (18)Mo1—K2—O2—Co1144.6 (5)
K3—Mo1—K1—O5viii36.62 (18)Mo2iii—K2—O2—Co1127.0 (3)
O1—Mo1—K1—Co1iv159.5 (3)Mo3—K2—O2—Co148.2 (3)
O2—Mo1—K1—Co1iv61.0 (3)O1—Mo1—O3—Co2118.0 (5)
O4—Mo1—K1—Co1iv22.9 (3)O2—Mo1—O3—Co21.0 (5)
O3—Mo1—K1—Co1iv104.6 (3)O4—Mo1—O3—Co2122.4 (4)
K2i—Mo1—K1—Co1iv73.53 (5)K2i—Mo1—O3—Co2131.9 (5)
K2—Mo1—K1—Co1iv109.80 (6)K2—Mo1—O3—Co257.7 (5)
K3ii—Mo1—K1—Co1iv160.10 (11)K3ii—Mo1—O3—Co2102.8 (5)
K3—Mo1—K1—Co1iv136.21 (10)K1—Mo1—O3—Co2168.3 (3)
O1—Mo1—K1—Co1ix21.3 (3)K3—Mo1—O3—Co2129.9 (7)
O2—Mo1—K1—Co1ix119.8 (3)O1—Mo1—O3—K312.0 (5)
O4—Mo1—K1—Co1ix156.3 (3)O2—Mo1—O3—K3130.9 (4)
O3—Mo1—K1—Co1ix74.5 (3)O4—Mo1—O3—K3107.7 (4)
K2i—Mo1—K1—Co1ix105.65 (7)K2i—Mo1—O3—K398.2 (4)
K2—Mo1—K1—Co1ix71.02 (7)K2—Mo1—O3—K372.2 (4)
K3ii—Mo1—K1—Co1ix19.07 (12)K3ii—Mo1—O3—K327.1 (3)
K3—Mo1—K1—Co1ix42.97 (10)K1—Mo1—O3—K361.8 (4)
O1—Mo1—K1—Mo1ii53.1 (3)O1—Mo1—O3—K3ii15.2 (4)
O2—Mo1—K1—Mo1ii151.6 (3)O2—Mo1—O3—K3ii103.8 (3)
O4—Mo1—K1—Mo1ii124.5 (3)O4—Mo1—O3—K3ii134.8 (3)
O3—Mo1—K1—Mo1ii42.8 (3)K2i—Mo1—O3—K3ii125.3 (3)
K2i—Mo1—K1—Mo1ii73.90 (5)K2—Mo1—O3—K3ii45.1 (3)
K2—Mo1—K1—Mo1ii102.77 (5)K1—Mo1—O3—K3ii88.9 (3)
K3ii—Mo1—K1—Mo1ii12.68 (11)K3—Mo1—O3—K3ii27.1 (3)
K3—Mo1—K1—Mo1ii11.21 (9)O1—Mo1—O3—K2i110.1 (3)
O1—Mo1—K1—Mo2iii93.5 (3)O2—Mo1—O3—K2i130.9 (3)
O2—Mo1—K1—Mo2iii5.0 (3)O4—Mo1—O3—K2i9.5 (3)
O4—Mo1—K1—Mo2iii88.8 (3)K2—Mo1—O3—K2i170.41 (13)
O3—Mo1—K1—Mo2iii170.6 (3)K3ii—Mo1—O3—K2i125.3 (3)
K2i—Mo1—K1—Mo2iii139.47 (5)K1—Mo1—O3—K2i36.4 (3)
K2—Mo1—K1—Mo2iii43.86 (5)K3—Mo1—O3—K2i98.2 (4)
K3ii—Mo1—K1—Mo2iii133.95 (11)O7v—Co2—O3—Mo1129.9 (4)
K3—Mo1—K1—Mo2iii157.85 (10)O8i—Co2—O3—Mo151.6 (5)
O1—Mo1—K1—Mo2viii91.9 (3)O12—Co2—O3—Mo131.6 (5)
O2—Mo1—K1—Mo2viii169.6 (3)O11i—Co2—O3—Mo1140.3 (4)
O4—Mo1—K1—Mo2viii85.7 (3)O11v—Co2—O3—Mo15 (3)
O3—Mo1—K1—Mo2viii3.9 (3)K3—Co2—O3—Mo1139.1 (6)
K2i—Mo1—K1—Mo2viii35.04 (6)K3ii—Co2—O3—Mo1105.7 (5)
K2—Mo1—K1—Mo2viii141.63 (6)O7v—Co2—O3—K39.2 (3)
K3ii—Mo1—K1—Mo2viii51.53 (12)O8i—Co2—O3—K3169.4 (3)
K3—Mo1—K1—Mo2viii27.64 (11)O12—Co2—O3—K3107.5 (3)
O1—Mo1—K2—O978.8 (3)O11i—Co2—O3—K380.7 (3)
O2—Mo1—K2—O994.6 (3)O11v—Co2—O3—K3134 (3)
O4—Mo1—K2—O9173.2 (3)K3ii—Co2—O3—K333.3 (3)
O3—Mo1—K2—O96.7 (3)O7v—Co2—O3—K3ii24.2 (3)
K2i—Mo1—K2—O9117.1 (5)O8i—Co2—O3—K3ii157.3 (3)
K3ii—Mo1—K2—O926.57 (18)O12—Co2—O3—K3ii74.1 (3)
K1—Mo1—K2—O9136.50 (17)O11i—Co2—O3—K3ii114.0 (3)
K3—Mo1—K2—O929.64 (19)O11v—Co2—O3—K3ii100 (3)
O1—Mo1—K2—O1x3.51 (14)K3—Co2—O3—K3ii33.3 (3)
O2—Mo1—K2—O1x169.9 (3)O7v—Co2—O3—K2i110.2 (3)
O4—Mo1—K2—O1x97.9 (3)O8i—Co2—O3—K2i68.4 (3)
O3—Mo1—K2—O1x82.0 (3)O12—Co2—O3—K2i151.5 (3)
K2i—Mo1—K2—O1x41.7 (6)O11i—Co2—O3—K2i20.4 (4)
K3ii—Mo1—K2—O1x48.7 (2)O11v—Co2—O3—K2i125 (3)
K1—Mo1—K2—O1x61.18 (19)K3—Co2—O3—K2i101.0 (4)
K3—Mo1—K2—O1x45.7 (2)K3ii—Co2—O3—K2i134.4 (4)
O1—Mo1—K2—O4xi117.3 (5)K3ii—K3—O3—Mo154.8 (4)
O2—Mo1—K2—O4xi69.3 (4)O7v—K3—O3—Mo1134.4 (4)
O4—Mo1—K2—O4xi22.9 (3)O7xii—K3—O3—Mo157.0 (7)
O3—Mo1—K2—O4xi157.2 (4)O3ii—K3—O3—Mo18.8 (4)
K2i—Mo1—K2—O4xi79.0 (7)O9ii—K3—O3—Mo199.8 (4)
K3ii—Mo1—K2—O4xi169.5 (4)O1ii—K3—O3—Mo155.1 (4)
K1—Mo1—K2—O4xi59.6 (4)O9i—K3—O3—Mo1136.2 (4)
K3—Mo1—K2—O4xi166.5 (4)Co2—K3—O3—Mo1141.7 (6)
O1—Mo1—K2—O2173.4 (4)Co2ii—K3—O3—Mo11.2 (6)
O4—Mo1—K2—O292.2 (4)Mo1ii—K3—O3—Mo134.8 (4)
O3—Mo1—K2—O287.9 (4)Mo3ii—K3—O3—Mo196.4 (5)
K2i—Mo1—K2—O2148.4 (6)K3ii—K3—O3—Co286.9 (3)
K3ii—Mo1—K2—O2121.2 (3)O7v—K3—O3—Co27.3 (2)
K1—Mo1—K2—O2128.9 (3)O7xii—K3—O3—Co284.7 (6)
K3—Mo1—K2—O2124.2 (3)O3ii—K3—O3—Co2150.5 (3)
O1—Mo1—K2—O5iii77.4 (3)O9ii—K3—O3—Co2118.5 (3)
O2—Mo1—K2—O5iii109.1 (3)O1ii—K3—O3—Co2163.2 (3)
O4—Mo1—K2—O5iii17.0 (3)O9i—K3—O3—Co282.1 (3)
O3—Mo1—K2—O5iii163.0 (3)Co2ii—K3—O3—Co2140.5 (3)
K2i—Mo1—K2—O5iii39.2 (6)Mo1ii—K3—O3—Co2176.5 (2)
K3ii—Mo1—K2—O5iii129.69 (18)Mo3ii—K3—O3—Co2121.9 (4)
K1—Mo1—K2—O5iii19.76 (17)O7v—K3—O3—K3ii79.6 (3)
K3—Mo1—K2—O5iii126.62 (18)O7xii—K3—O3—K3ii2.1 (5)
O1—Mo1—K2—O3xi101.4 (4)O3ii—K3—O3—K3ii63.6 (3)
O2—Mo1—K2—O3xi72.0 (4)O9ii—K3—O3—K3ii154.6 (4)
O4—Mo1—K2—O3xi164.2 (3)O1ii—K3—O3—K3ii109.9 (3)
O3—Mo1—K2—O3xi15.9 (2)O9i—K3—O3—K3ii169.0 (3)
K2i—Mo1—K2—O3xi139.7 (5)Co2—K3—O3—K3ii86.9 (3)
K3ii—Mo1—K2—O3xi49.2 (3)Co2ii—K3—O3—K3ii53.7 (4)
K1—Mo1—K2—O3xi159.1 (3)Mo1ii—K3—O3—K3ii89.6 (2)
K3—Mo1—K2—O3xi52.3 (3)Mo3ii—K3—O3—K3ii151.2 (4)
O2—Mo1—K2—O1173.4 (4)K3ii—K3—O3—K2i151.0 (3)
O4—Mo1—K2—O194.4 (4)O7v—K3—O3—K2i129.4 (3)
O3—Mo1—K2—O185.5 (4)O7xii—K3—O3—K2i153.2 (5)
K2i—Mo1—K2—O138.2 (6)O3ii—K3—O3—K2i87.4 (2)
K3ii—Mo1—K2—O152.3 (3)O9ii—K3—O3—K2i3.6 (3)
K1—Mo1—K2—O157.7 (3)O1ii—K3—O3—K2i41.1 (2)
K3—Mo1—K2—O149.2 (3)O9i—K3—O3—K2i40.0 (2)
O1—Mo1—K2—O6iii124.1 (3)Co2—K3—O3—K2i122.1 (3)
O2—Mo1—K2—O6iii62.5 (3)Co2ii—K3—O3—K2i97.3 (3)
O4—Mo1—K2—O6iii29.7 (3)Mo1ii—K3—O3—K2i61.39 (18)
O3—Mo1—K2—O6iii150.3 (3)Mo3ii—K3—O3—K2i0.2 (4)
K2i—Mo1—K2—O6iii85.9 (6)O1—Mo1—O4—Co1iv128.4 (5)
K3ii—Mo1—K2—O6iii176.37 (16)O2—Mo1—O4—Co1iv7.4 (6)
K1—Mo1—K2—O6iii66.44 (15)O3—Mo1—O4—Co1iv114.1 (5)
K3—Mo1—K2—O6iii173.30 (16)K2i—Mo1—O4—Co1iv124.2 (6)
O1—Mo1—K2—Mo1xi141.8 (6)K2—Mo1—O4—Co1iv66.0 (5)
O2—Mo1—K2—Mo1xi31.6 (6)K3ii—Mo1—O4—Co1iv166.6 (3)
O4—Mo1—K2—Mo1xi123.8 (6)K1—Mo1—O4—Co1iv126.0 (6)
O3—Mo1—K2—Mo1xi56.2 (6)K3—Mo1—O4—Co1iv151.7 (4)
K2i—Mo1—K2—Mo1xi180.000 (3)O1—Mo1—O4—K12.4 (4)
K3ii—Mo1—K2—Mo1xi89.5 (5)O2—Mo1—O4—K1118.6 (3)
K1—Mo1—K2—Mo1xi160.6 (5)O3—Mo1—O4—K1119.9 (3)
K3—Mo1—K2—Mo1xi92.6 (5)K2i—Mo1—O4—K1109.8 (3)
O1—Mo1—K2—Mo2iii105.3 (3)K2—Mo1—O4—K160.1 (3)
O2—Mo1—K2—Mo2iii81.3 (3)K3ii—Mo1—O4—K167.3 (4)
O4—Mo1—K2—Mo2iii10.9 (2)K3—Mo1—O4—K182.2 (3)
O3—Mo1—K2—Mo2iii169.1 (3)O1—Mo1—O4—K2i107.4 (3)
K2i—Mo1—K2—Mo2iii67.1 (5)O2—Mo1—O4—K2i131.6 (3)
K3ii—Mo1—K2—Mo2iii157.59 (9)O3—Mo1—O4—K2i10.1 (3)
K1—Mo1—K2—Mo2iii47.66 (5)K2—Mo1—O4—K2i169.83 (13)
K3—Mo1—K2—Mo2iii154.52 (8)K3ii—Mo1—O4—K2i42.4 (4)
O1—Mo1—K2—Mo3101.4 (3)K1—Mo1—O4—K2i109.8 (3)
O2—Mo1—K2—Mo372.0 (3)K3—Mo1—O4—K2i27.5 (3)
O4—Mo1—K2—Mo3164.2 (2)O4ii—K1—O4—Mo136.5 (2)
O3—Mo1—K2—Mo315.9 (3)O10vi—K1—O4—Mo150 (3)
K2i—Mo1—K2—Mo3139.7 (5)O10vii—K1—O4—Mo1148.3 (3)
K3ii—Mo1—K2—Mo349.17 (9)O5iii—K1—O4—Mo156.3 (3)
K1—Mo1—K2—Mo3159.10 (5)O5viii—K1—O4—Mo1109.2 (3)
K3—Mo1—K2—Mo352.24 (9)Co1iv—K1—O4—Mo1143.9 (4)
O10—Mo3—K2—O912.4 (6)Co1ix—K1—O4—Mo136.1 (4)
O11—Mo3—K2—O9129.6 (5)Mo1ii—K1—O4—Mo151.9 (3)
O12—Mo3—K2—O9117.9 (5)Mo2iii—K1—O4—Mo179.5 (3)
K3ii—Mo3—K2—O938.5 (5)Mo2viii—K1—O4—Mo1112.1 (3)
O9—Mo3—K2—O1x32.6 (5)O4ii—K1—O4—Co1iv179.6 (3)
O10—Mo3—K2—O1x20.2 (4)O10vi—K1—O4—Co1iv94 (3)
O11—Mo3—K2—O1x97.0 (3)O10vii—K1—O4—Co1iv4.4 (2)
O12—Mo3—K2—O1x150.5 (3)O5iii—K1—O4—Co1iv87.6 (3)
K3ii—Mo3—K2—O1x71.10 (19)O5viii—K1—O4—Co1iv106.9 (3)
O9—Mo3—K2—O4xi115.1 (5)Co1ix—K1—O4—Co1iv179.980 (17)
O10—Mo3—K2—O4xi102.7 (4)Mo1—K1—O4—Co1iv143.9 (4)
O11—Mo3—K2—O4xi14.5 (3)Mo1ii—K1—O4—Co1iv164.2 (2)
O12—Mo3—K2—O4xi127.1 (3)Mo2iii—K1—O4—Co1iv64.41 (19)
K3ii—Mo3—K2—O4xi153.6 (2)Mo2viii—K1—O4—Co1iv104.0 (2)
O9—Mo3—K2—O2116.8 (5)O4ii—K1—O4—K2i67.75 (17)
O10—Mo3—K2—O2129.2 (4)O10vi—K1—O4—K2i154 (3)
O11—Mo3—K2—O2113.6 (3)O10vii—K1—O4—K2i107.5 (3)
O12—Mo3—K2—O21.1 (2)O5iii—K1—O4—K2i160.5 (3)
K3ii—Mo3—K2—O278.31 (18)O5viii—K1—O4—K2i5.0 (3)
O9—Mo3—K2—O5iii84.5 (5)Co1iv—K1—O4—K2i111.9 (3)
O10—Mo3—K2—O5iii96.9 (4)Co1ix—K1—O4—K2i68.1 (3)
O11—Mo3—K2—O5iii145.9 (3)Mo1—K1—O4—K2i104.2 (4)
O12—Mo3—K2—O5iii33.4 (3)Mo1ii—K1—O4—K2i52.32 (19)
K3ii—Mo3—K2—O5iii46.0 (2)Mo2iii—K1—O4—K2i176.3 (2)
O9—Mo3—K2—O3xi94.2 (5)Mo2viii—K1—O4—K2i7.9 (3)
O10—Mo3—K2—O3xi81.8 (4)O6—Mo2—O5—K1iii168.1 (3)
O11—Mo3—K2—O3xi35.4 (2)O7—Mo2—O5—K1iii71.5 (4)
O12—Mo3—K2—O3xi147.9 (2)O8—Mo2—O5—K1iii48.1 (4)
K3ii—Mo3—K2—O3xi132.68 (17)K2iii—Mo2—O5—K1iii151.9 (5)
O9—Mo3—K2—O157.1 (5)O6—Mo2—O5—K2iii16.2 (4)
O10—Mo3—K2—O169.5 (4)O7—Mo2—O5—K2iii136.5 (3)
O11—Mo3—K2—O1173.4 (2)O8—Mo2—O5—K2iii103.9 (3)
O12—Mo3—K2—O160.8 (2)K1iii—Mo2—O5—K2iii151.9 (5)
K3ii—Mo3—K2—O118.59 (17)O5—Mo2—O6—Co1100.1 (7)
O9—Mo3—K2—O6iii163.7 (5)O7—Mo2—O6—Co116.9 (8)
O10—Mo3—K2—O6iii176.1 (4)O8—Mo2—O6—Co1144.1 (6)
O11—Mo3—K2—O6iii66.7 (3)K2iii—Mo2—O6—Co1115.7 (7)
O12—Mo3—K2—O6iii45.8 (3)K1iii—Mo2—O6—Co1113.7 (6)
K3ii—Mo3—K2—O6iii125.2 (2)O5—Mo2—O6—K2iii15.6 (3)
O9—Mo3—K2—Mo1xi100.6 (5)O7—Mo2—O6—K2iii132.6 (3)
O10—Mo3—K2—Mo1xi88.2 (4)O8—Mo2—O6—K2iii100.2 (3)
O11—Mo3—K2—Mo1xi29.0 (2)K1iii—Mo2—O6—K2iii2.1 (5)
O12—Mo3—K2—Mo1xi141.6 (2)O4iv—Co1—O6—Mo2101.0 (7)
K3ii—Mo3—K2—Mo1xi139.05 (11)O2—Co1—O6—Mo2158.7 (7)
O9—Mo3—K2—Mo185.8 (5)O8i—Co1—O6—Mo219 (3)
O10—Mo3—K2—Mo198.2 (4)O10v—Co1—O6—Mo25.8 (7)
O11—Mo3—K2—Mo1144.6 (2)O12—Co1—O6—Mo275.1 (7)
O12—Mo3—K2—Mo132.06 (19)K1iv—Co1—O6—Mo254.0 (7)
K3ii—Mo3—K2—Mo147.33 (10)K2iii—Co1—O6—Mo2114.0 (7)
O9—Mo3—K2—Mo2iii123.1 (5)O4iv—Co1—O6—K2iii13.0 (3)
O10—Mo3—K2—Mo2iii135.5 (4)O2—Co1—O6—K2iii87.3 (3)
O11—Mo3—K2—Mo2iii107.3 (2)O8i—Co1—O6—K2iii133 (2)
O12—Mo3—K2—Mo2iii5.2 (2)O10v—Co1—O6—K2iii108.2 (2)
K3ii—Mo3—K2—Mo2iii84.63 (14)O12—Co1—O6—K2iii170.8 (2)
O3—Co2—K3—K3ii86.1 (3)K1iv—Co1—O6—K2iii60.08 (19)
O7v—Co2—K3—K3ii81.9 (3)O5—Mo2—O7—Co2v162.7 (4)
O8i—Co2—K3—K3ii101.7 (3)O6—Mo2—O7—Co2v79.5 (4)
O12—Co2—K3—K3ii3.99 (19)O8—Mo2—O7—Co2v47.6 (5)
O11i—Co2—K3—K3ii169.17 (18)K2iii—Mo2—O7—Co2v143.2 (2)
O11v—Co2—K3—K3ii88.8 (3)K1iii—Mo2—O7—Co2v125.5 (3)
O7v—Co2—K3—O3168.0 (4)O5—Mo2—O7—K3v18.5 (6)
O8i—Co2—K3—O315.5 (4)O6—Mo2—O7—K3v136.3 (5)
O12—Co2—K3—O382.1 (3)O8—Mo2—O7—K3v96.6 (5)
O11i—Co2—K3—O3104.7 (3)K2iii—Mo2—O7—K3v72.5 (6)
O11v—Co2—K3—O3175.0 (4)K1iii—Mo2—O7—K3v18.7 (5)
K3ii—Co2—K3—O386.1 (3)O5—Mo2—O7—K3xiii35.3 (7)
O3—Co2—K3—O7v168.0 (4)O6—Mo2—O7—K3xiii82.5 (6)
O8i—Co2—K3—O7v176.4 (3)O8—Mo2—O7—K3xiii150.4 (5)
O12—Co2—K3—O7v85.9 (3)K2iii—Mo2—O7—K3xiii18.8 (8)
O11i—Co2—K3—O7v87.3 (3)K1iii—Mo2—O7—K3xiii72.4 (6)
O11v—Co2—K3—O7v6.9 (4)O5—Mo2—O8—Co2xi164.5 (4)
K3ii—Co2—K3—O7v81.9 (3)O6—Mo2—O8—Co2xi78.2 (4)
O3—Co2—K3—O7xii135.8 (4)O7—Mo2—O8—Co2xi48.7 (4)
O7v—Co2—K3—O7xii32.3 (4)K2iii—Mo2—O8—Co2xi139.1 (3)
O8i—Co2—K3—O7xii151.3 (4)K1iii—Mo2—O8—Co2xi135.6 (3)
O12—Co2—K3—O7xii53.6 (4)O5—Mo2—O8—Co1xi22.4 (6)
O11i—Co2—K3—O7xii119.5 (4)O6—Mo2—O8—Co1xi139.7 (5)
O11v—Co2—K3—O7xii39.2 (5)O7—Mo2—O8—Co1xi93.3 (6)
K3ii—Co2—K3—O7xii49.6 (3)K2iii—Mo2—O8—Co1xi78.8 (5)
O3—Co2—K3—O3ii40.6 (4)K1iii—Mo2—O8—Co1xi6.5 (5)
O7v—Co2—K3—O3ii127.5 (4)O10—Mo3—O9—K2172.2 (4)
O8i—Co2—K3—O3ii56.1 (4)O11—Mo3—O9—K252.4 (5)
O12—Co2—K3—O3ii41.6 (4)O12—Mo3—O9—K266.9 (5)
O11i—Co2—K3—O3ii145.3 (3)K3ii—Mo3—O9—K2130.1 (5)
O11v—Co2—K3—O3ii134.4 (3)O10—Mo3—O9—K3ii57.7 (4)
K3ii—Co2—K3—O3ii45.6 (3)O11—Mo3—O9—K3ii177.5 (3)
O3—Co2—K3—O9ii82.7 (4)O12—Mo3—O9—K3ii63.2 (3)
O7v—Co2—K3—O9ii109.2 (4)K2—Mo3—O9—K3ii130.1 (5)
O8i—Co2—K3—O9ii67.2 (4)O10—Mo3—O9—K3xi70.2 (4)
O12—Co2—K3—O9ii164.9 (3)O11—Mo3—O9—K3xi49.6 (4)
O11i—Co2—K3—O9ii22.0 (3)O12—Mo3—O9—K3xi168.9 (3)
O11v—Co2—K3—O9ii102.3 (4)K3ii—Mo3—O9—K3xi127.9 (4)
K3ii—Co2—K3—O9ii168.9 (3)K2—Mo3—O9—K3xi102.0 (5)
O3—Co2—K3—O1ii16.2 (3)O1x—K2—O9—Mo3148.8 (5)
O7v—Co2—K3—O1ii175.8 (4)O4xi—K2—O9—Mo383.0 (5)
O8i—Co2—K3—O1ii0.6 (4)O2—K2—O9—Mo356.7 (4)
O12—Co2—K3—O1ii98.3 (3)O5iii—K2—O9—Mo3112.8 (4)
O11i—Co2—K3—O1ii88.5 (3)O3xi—K2—O9—Mo378.9 (5)
O11v—Co2—K3—O1ii168.9 (3)O1—K2—O9—Mo3117.6 (5)
K3ii—Co2—K3—O1ii102.3 (2)O6iii—K2—O9—Mo327.1 (8)
O3—Co2—K3—O9i84.6 (3)Mo1xi—K2—O9—Mo384.1 (4)
O7v—Co2—K3—O9i107.3 (3)Mo1—K2—O9—Mo387.0 (4)
O8i—Co2—K3—O9i69.1 (3)Mo2iii—K2—O9—Mo380.4 (5)
O12—Co2—K3—O9i166.7 (2)O1x—K2—O9—K3ii88.3 (3)
O11i—Co2—K3—O9i20.1 (2)O4xi—K2—O9—K3ii154.1 (3)
O11v—Co2—K3—O9i100.4 (3)O2—K2—O9—K3ii66.2 (3)
K3ii—Co2—K3—O9i170.74 (16)O5iii—K2—O9—K3ii10.1 (4)
O3—Co2—K3—Co2ii87.8 (5)O3xi—K2—O9—K3ii158.2 (3)
O7v—Co2—K3—Co2ii80.2 (4)O1—K2—O9—K3ii5.3 (3)
O8i—Co2—K3—Co2ii103.3 (4)O6iii—K2—O9—K3ii95.8 (5)
O12—Co2—K3—Co2ii5.7 (5)Mo1xi—K2—O9—K3ii153.0 (2)
O11i—Co2—K3—Co2ii167.5 (4)Mo1—K2—O9—K3ii35.9 (2)
O11v—Co2—K3—Co2ii87.2 (5)Mo2iii—K2—O9—K3ii42.5 (4)
K3ii—Co2—K3—Co2ii1.7 (4)Mo3—K2—O9—K3ii122.9 (6)
O3—Co2—K3—Mo1ii4.3 (3)O1x—K2—O9—K3xi32.6 (2)
O7v—Co2—K3—Mo1ii163.7 (4)O4xi—K2—O9—K3xi33.1 (4)
O8i—Co2—K3—Mo1ii19.8 (4)O2—K2—O9—K3xi172.8 (2)
O12—Co2—K3—Mo1ii77.8 (3)O5iii—K2—O9—K3xi131.0 (3)
O11i—Co2—K3—Mo1ii109.0 (3)O3xi—K2—O9—K3xi37.22 (19)
O11v—Co2—K3—Mo1ii170.7 (3)O1—K2—O9—K3xi126.3 (2)
K3ii—Co2—K3—Mo1ii81.8 (2)O6iii—K2—O9—K3xi143.2 (4)
O3—Co2—K3—Mo3ii109.4 (4)Mo1xi—K2—O9—K3xi32.02 (19)
O7v—Co2—K3—Mo3ii82.5 (4)Mo1—K2—O9—K3xi156.9 (2)
O8i—Co2—K3—Mo3ii93.9 (4)Mo2iii—K2—O9—K3xi163.5 (2)
O12—Co2—K3—Mo3ii168.4 (3)Mo3—K2—O9—K3xi116.1 (5)
O11i—Co2—K3—Mo3ii4.7 (3)O9—Mo3—O10—Co1v171.4 (4)
O11v—Co2—K3—Mo3ii75.6 (4)O11—Mo3—O10—Co1v56.3 (4)
K3ii—Co2—K3—Mo3ii164.5 (3)O12—Mo3—O10—Co1v72.7 (4)
O2—Mo1—O1—K2x113 (4)K3ii—Mo3—O10—Co1v144.1 (4)
O4—Mo1—O1—K2x8 (4)K2—Mo3—O10—Co1v163.64 (12)
O3—Mo1—O1—K2x127 (4)O9—Mo3—O10—K1xiv26.7 (6)
K2i—Mo1—O1—K2x66 (4)O11—Mo3—O10—K1xiv88.3 (6)
K2—Mo1—O1—K2x108 (4)O12—Mo3—O10—K1xiv142.6 (5)
K3ii—Mo1—O1—K2x141 (4)K3ii—Mo3—O10—K1xiv71.2 (5)
K1—Mo1—O1—K2x7 (4)K2—Mo3—O10—K1xiv18.9 (8)
K3—Mo1—O1—K2x120 (4)O9—Mo3—O11—Co2xi28.2 (6)
O2—Mo1—O1—K25.6 (3)O10—Mo3—O11—Co2xi87.0 (6)
O4—Mo1—O1—K2116.0 (3)O12—Mo3—O11—Co2xi143.3 (5)
O3—Mo1—O1—K2125.3 (3)K3ii—Mo3—O11—Co2xi22.6 (10)
K2i—Mo1—O1—K2173.34 (11)K2—Mo3—O11—Co2xi57.1 (5)
K3ii—Mo1—O1—K2111.5 (3)O9—Mo3—O11—Co2v165.6 (3)
K1—Mo1—O1—K2114.3 (2)O10—Mo3—O11—Co2v50.4 (4)
K3—Mo1—O1—K2132.5 (2)O12—Mo3—O11—Co2v79.3 (4)
O2—Mo1—O1—K3ii105.9 (3)K3ii—Mo3—O11—Co2v160.0 (4)
O4—Mo1—O1—K3ii132.5 (3)K2—Mo3—O11—Co2v165.4 (3)
O3—Mo1—O1—K3ii13.8 (3)O9—Mo3—O12—Co278.7 (5)
K2i—Mo1—O1—K3ii75.2 (2)O10—Mo3—O12—Co237.2 (6)
K2—Mo1—O1—K3ii111.5 (3)O11—Mo3—O12—Co2166.4 (4)
K1—Mo1—O1—K3ii134.2 (3)K3ii—Mo3—O12—Co231.9 (4)
K3—Mo1—O1—K3ii21.01 (19)K2—Mo3—O12—Co2112.5 (4)
O9—K2—O1—Mo190.5 (3)O9—Mo3—O12—Co180.4 (5)
O1x—K2—O1—Mo1177.00 (12)O10—Mo3—O12—Co1163.7 (4)
O4xi—K2—O1—Mo1122.0 (4)O11—Mo3—O12—Co134.4 (5)
O2—K2—O1—Mo13.8 (2)K3ii—Mo3—O12—Co1127.2 (4)
O5iii—K2—O1—Mo185.0 (3)K2—Mo3—O12—Co146.7 (4)
O3xi—K2—O1—Mo1115.0 (3)O3—Co2—O12—Mo383.2 (5)
O6iii—K2—O1—Mo161.1 (3)O7v—Co2—O12—Mo315.1 (5)
Mo1xi—K2—O1—Mo1163.8 (3)O8i—Co2—O12—Mo3171.8 (5)
Mo2iii—K2—O1—Mo168.0 (2)O11i—Co2—O12—Mo3122.8 (8)
Mo3—K2—O1—Mo171.3 (2)O11v—Co2—O12—Mo399.0 (5)
O9—K2—O1—K2x94.7 (2)K3—Co2—O12—Mo335.1 (5)
O1x—K2—O1—K2x8.2 (3)K3ii—Co2—O12—Mo333.3 (4)
O4xi—K2—O1—K2x52.8 (5)O3—Co2—O12—Co180.2 (3)
O2—K2—O1—K2x178.6 (3)O7v—Co2—O12—Co1178.5 (3)
O5iii—K2—O1—K2x89.7 (2)O8i—Co2—O12—Co18.4 (3)
O3xi—K2—O1—K2x70.3 (4)O11i—Co2—O12—Co173.8 (9)
O6iii—K2—O1—K2x113.68 (19)O11v—Co2—O12—Co197.6 (3)
Mo1xi—K2—O1—K2x21.4 (5)K3—Co2—O12—Co1128.3 (2)
Mo1—K2—O1—K2x174.7 (4)K3ii—Co2—O12—Co1130.0 (2)
Mo2iii—K2—O1—K2x106.75 (15)O4iv—Co1—O12—Mo3158.9 (18)
Mo3—K2—O1—K2x114.00 (15)O2—Co1—O12—Mo376.9 (4)
O9—K2—O1—K3ii5.1 (2)O6—Co1—O12—Mo312.8 (5)
O1x—K2—O1—K3ii81.4 (3)O8i—Co1—O12—Mo3173.0 (4)
O4xi—K2—O1—K3ii142.4 (4)O10v—Co1—O12—Mo3102.0 (4)
O2—K2—O1—K3ii91.8 (3)K1iv—Co1—O12—Mo3112.5 (4)
O5iii—K2—O1—K3ii179.3 (3)K2iii—Co1—O12—Mo31.1 (6)
O3xi—K2—O1—K3ii19.3 (4)O4iv—Co1—O12—Co236 (2)
O6iii—K2—O1—K3ii156.7 (2)O2—Co1—O12—Co287.9 (3)
Mo1xi—K2—O1—K3ii68.2 (5)O6—Co1—O12—Co2177.6 (3)
Mo1—K2—O1—K3ii95.6 (3)O8i—Co1—O12—Co28.2 (3)
Mo2iii—K2—O1—K3ii163.6 (2)O10v—Co1—O12—Co293.2 (3)
Mo3—K2—O1—K3ii24.4 (2)K1iv—Co1—O12—Co282.7 (3)
O1—Mo1—O2—Co1135.3 (5)K2iii—Co1—O12—Co2165.85 (13)
O4—Mo1—O2—Co1102.9 (5)
Symmetry codes: (i) x+1, y, z; (ii) x+1, y, z+1/2; (iii) x, y+1, z+1; (iv) x+1, y+1, z+1; (v) x+1/2, y+3/2, z+1; (vi) x+1/2, y1/2, z+1/2; (vii) x+1/2, y1/2, z; (viii) x+1, y+1, z1/2; (ix) x, y+1, z1/2; (x) x, y, z+1/2; (xi) x1, y, z; (xii) x+1/2, y+3/2, z1/2; (xiii) x1/2, y+3/2, z+1/2; (xiv) x1/2, y+1/2, z.
(II) top
Crystal data top
Co2K2Mo3O12F(000) = 2512
Mr = 675.88Dx = 4.754 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 13.5237 (8) ÅCell parameters from 4390 reflections
b = 7.6440 (4) Åθ = 2.1–25.9°
c = 18.850 (1) ŵ = 8.26 mm1
β = 104.260 (6)°T = 298 K
V = 1888.58 (18) Å3Plate, purple
Z = 80.11 × 0.05 × 0.03 mm
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.791 reflections with I > 2σ(I)
Radiation source: Enhance (Mo) X-ray SourceRint = 0.130
Graphite monochromatorθmax = 26.0°, θmin = 2.2°
Detector resolution: 8.4012 pixels mm-1h = 1616
Rotation method data acquisition using ω and phi scans.k = 32
7020 measured reflectionsl = 2022
1154 independent reflections
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullPrimary atom site location: structure-invariant direct methods
R[F2 > 2σ(F2)] = 0.047Secondary atom site location: difference Fourier map
wR(F2) = 0.110 w = 1/[σ2(Fo2) + (0.0538P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max < 0.001
1154 reflectionsΔρmax = 1.07 e Å3
195 parametersΔρmin = 0.89 e Å3
Crystal data top
Co2K2Mo3O12V = 1888.58 (18) Å3
Mr = 675.88Z = 8
Monoclinic, P21/cMo Kα radiation
a = 13.5237 (8) ŵ = 8.26 mm1
b = 7.6440 (4) ÅT = 298 K
c = 18.850 (1) Å0.11 × 0.05 × 0.03 mm
β = 104.260 (6)°
Data collection top
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.791 reflections with I > 2σ(I)
7020 measured reflectionsRint = 0.130
1154 independent reflections
Refinement top
R[F2 > 2σ(F2)] = 0.047195 parameters
wR(F2) = 0.1100 restraints
S = 1.05Δρmax = 1.07 e Å3
1154 reflectionsΔρmin = 0.89 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mo1A0.24962 (11)0.3685 (7)0.26601 (11)0.010 (4)
Mo1B0.25987 (11)0.7825 (8)0.24996 (10)0.019 (4)
Mo2A0.67270 (12)0.7542 (7)0.39151 (11)0.011 (3)
Mo2B0.12143 (11)0.7131 (7)0.40837 (10)0.010 (3)
Mo3A0.53078 (11)0.2909 (7)0.44848 (11)0.014 (3)
Mo3B0.04318 (11)0.3513 (7)0.45044 (10)0.014 (3)
Co1A0.41748 (18)0.6830 (11)0.38075 (16)0.026 (5)
Co1B0.10865 (17)0.4358 (11)0.65596 (16)0.0133 (8)*
Co2A0.28968 (17)0.4449 (11)0.44681 (17)0.012 (5)
Co2B0.22303 (18)0.6460 (11)0.57217 (17)0.016 (5)
K1A0.2852 (3)0.023 (2)0.4158 (3)0.026 (10)
K1B0.0983 (3)0.0195 (19)0.5872 (3)0.017 (9)
K2A0.4974 (3)0.0323 (19)0.2553 (3)0.025 (7)
K2B0.0147 (3)0.1841 (18)0.2842 (3)0.028 (9)
O1A0.3390 (8)0.231 (5)0.2443 (8)0.0161 (9)*
O1B0.1707 (9)0.587 (5)0.2295 (8)0.0161 (9)*
O2A0.3453 (9)0.553 (5)0.2893 (8)0.0161 (9)*
O2B0.1599 (9)0.929 (5)0.2485 (8)0.0161 (9)*
O3A0.2327 (9)0.307 (5)0.3534 (7)0.0161 (9)*
O3B0.3064 (8)0.803 (5)0.1726 (8)0.0161 (9)*
O4A0.1366 (8)0.287 (5)0.2067 (8)0.0161 (9)*
O4B0.3588 (8)0.879 (5)0.3176 (8)0.0161 (9)*
O5A0.7007 (9)0.964 (6)0.3654 (8)0.0161 (9)*
O5B0.0577 (9)0.875 (5)0.3525 (8)0.0161 (9)*
O6A0.5470 (8)0.689 (5)0.3518 (7)0.0161 (9)*
O6B0.0426 (9)0.487 (5)0.6401 (8)0.0161 (9)*
O7A0.6779 (8)0.764 (5)0.4848 (7)0.0161 (9)*
O7B0.1686 (8)0.825 (5)0.4936 (7)0.0161 (9)*
O8A0.7737 (9)0.608 (5)0.3860 (8)0.0161 (9)*
O8B0.2376 (9)0.685 (5)0.3822 (8)0.0161 (9)*
O9A0.5077 (9)0.158 (5)0.3755 (7)0.0161 (9)*
O9B0.0954 (9)0.156 (5)0.4392 (8)0.0161 (9)*
O10A0.5389 (9)0.164 (5)0.5276 (7)0.0161 (9)*
O10B0.0173 (8)0.335 (5)0.5413 (7)0.0161 (9)*
O11A0.6512 (8)0.403 (5)0.4600 (7)0.0161 (9)*
O11B0.1593 (8)0.493 (5)0.4795 (8)0.0161 (9)*
O12A0.4307 (8)0.452 (5)0.4344 (8)0.0161 (9)*
O12B0.0886 (9)0.321 (5)0.3996 (8)0.0161 (9)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mo1A0.0114 (9)0.008 (12)0.0122 (13)0.0004 (16)0.0048 (7)0.000 (2)
Mo1B0.0120 (9)0.035 (12)0.0108 (12)0.0010 (17)0.0038 (7)0.001 (2)
Mo2A0.0121 (9)0.007 (10)0.0130 (12)0.0006 (17)0.0032 (7)0.003 (2)
Mo2B0.0132 (9)0.009 (10)0.0085 (12)0.0008 (16)0.0046 (7)0.000 (2)
Mo3A0.0105 (8)0.020 (10)0.0130 (12)0.0023 (16)0.0030 (7)0.001 (2)
Mo3B0.0099 (9)0.025 (11)0.0085 (12)0.0001 (16)0.0052 (7)0.002 (2)
Co1A0.0137 (14)0.057 (17)0.0094 (18)0.003 (3)0.0050 (11)0.000 (4)
Co2A0.0108 (13)0.008 (16)0.018 (2)0.001 (2)0.0071 (11)0.001 (4)
Co2B0.0149 (14)0.022 (17)0.012 (2)0.003 (2)0.0075 (11)0.005 (3)
K1A0.033 (3)0.02 (3)0.024 (4)0.001 (5)0.013 (2)0.001 (7)
K1B0.020 (2)0.02 (3)0.009 (3)0.015 (4)0.0061 (18)0.001 (6)
K2A0.019 (2)0.04 (2)0.022 (3)0.002 (5)0.0081 (18)0.015 (6)
K2B0.023 (2)0.05 (3)0.014 (3)0.001 (4)0.0086 (19)0.011 (6)
Geometric parameters (Å, º) top
Mo1A—O1A1.73 (3)K1A—O7Av2.44 (3)
Mo1A—O4A1.769 (18)K1A—O3A2.49 (4)
Mo1A—O3A1.781 (17)K1A—O4Bxi2.55 (2)
Mo1A—O2A1.89 (3)K1A—O8Bxi2.69 (4)
Mo1A—O1B2.01 (3)K1A—O10Avii2.75 (2)
Mo1A—Mo1B3.185 (7)K1A—O7Bxi2.84 (3)
Mo1A—K2B3.568 (7)K1A—O9B2.90 (2)
Mo1A—K1Bi3.589 (6)K1A—O5Bxi3.219 (19)
Mo1A—K2Aii3.622 (6)K1A—Mo2Bxi3.220 (12)
Mo1A—K1A3.811 (12)K1A—O2Bxi3.270 (17)
Mo1B—O3B1.731 (15)K1A—Co1Axi3.310 (14)
Mo1B—O2B1.75 (3)K1B—O12Bviii2.63 (4)
Mo1B—O4B1.77 (2)K1B—O4Aix2.64 (3)
Mo1B—O1B1.90 (3)K1B—O5Av2.646 (13)
Mo1B—O2A2.13 (3)K1B—O7Bxi2.66 (3)
Mo1B—Co1A2.934 (4)K1B—O10B2.70 (4)
Mo1B—K2Aiii3.489 (8)K1B—O1Bix2.74 (2)
Mo1B—K1Aiii3.568 (10)K1B—O5Bvi2.753 (18)
Mo1B—K2Biv3.687 (5)K1B—O9Bviii2.88 (2)
Mo1B—K1Bi4.027 (10)K1B—O9B2.97 (2)
Mo1B—K2Aii4.091 (10)K1B—O8Av3.30 (4)
Mo2A—O5A1.74 (4)K1B—Co2Bxi3.363 (15)
Mo2A—O7A1.744 (14)K1B—Mo3Bviii3.396 (13)
Mo2A—O6A1.752 (15)K2A—O4Bxi2.537 (17)
Mo2A—O8A1.79 (3)K2A—O2Axii2.556 (17)
Mo2A—K2Aiii3.446 (9)K2A—O6Axii2.59 (3)
Mo2A—K1Bv3.483 (8)K2A—O9A2.67 (3)
Mo2A—K2Aii3.822 (10)K2A—O6Axi2.77 (3)
Mo2A—K1Av3.925 (9)K2A—O1Axii2.86 (3)
Mo2B—O5B1.71 (3)K2A—O1A2.91 (3)
Mo2B—O8B1.772 (14)K2A—O3Bxi2.95 (2)
Mo2B—O7B1.79 (2)K2A—O5Axi3.010 (13)
Mo2B—O6Bvi1.96 (3)K2A—O9Axii3.41 (3)
Mo2B—O11B2.14 (3)K2A—Mo2Axi3.446 (9)
Mo2B—O10Bvi2.330 (14)K2A—Co1Axii3.473 (9)
Mo2B—Co2A3.015 (7)K2B—O1Bxiii2.567 (17)
Mo2B—Co2B3.097 (4)K2B—O4A2.581 (19)
Mo2B—Mo3B3.132 (7)K2B—O5Bxi2.69 (4)
Mo2B—K1Aiii3.220 (12)K2B—O9B2.864 (15)
Mo2B—K1Bvi3.625 (10)K2B—O6Bvi2.87 (4)
Mo2B—K2Biv3.651 (5)K2B—O5Bxiii2.91 (2)
Mo3A—O9A1.68 (3)K2B—O6Bi2.94 (2)
Mo3A—O10A1.76 (2)K2B—O2Bxi2.96 (3)
Mo3A—O12A1.80 (3)K2B—O2Bxiii2.96 (3)
Mo3A—O11A1.81 (2)K2B—O12B3.05 (2)
Mo3A—K1A3.822 (10)K2B—O3A3.062 (17)
Mo3A—K1Avii3.917 (11)K2B—Co1Bi3.132 (7)
Mo3A—K2Aii4.000 (8)O1A—K2Aii2.86 (3)
Mo3B—O9B1.68 (4)O1B—K2Biv2.567 (17)
Mo3B—O12B1.818 (13)O1B—K1Bi2.742 (19)
Mo3B—O10B1.835 (14)O2A—K2Aii2.556 (17)
Mo3B—O11B1.87 (3)O2B—Co1Bxiv2.00 (2)
Mo3B—O6Bvi2.10 (3)O2B—K2Biii2.96 (3)
Mo3B—Co1Bvi2.976 (6)O2B—K2Biv2.96 (3)
Mo3B—K2B3.317 (7)O2B—K1Aiii3.270 (17)
Mo3B—K1Bviii3.396 (13)O3B—Co2Bxiv1.989 (15)
Mo3B—K1B3.562 (12)O3B—K2Aiii2.95 (2)
Co1A—O4B1.96 (3)O4A—Co1Bi1.95 (4)
Co1A—O6A1.960 (13)O4A—K1Bi2.64 (3)
Co1A—O12A2.02 (3)O4B—K2Aiii2.537 (17)
Co1A—O2A2.02 (2)O4B—K1Aiii2.55 (2)
Co1A—O10Av2.05 (2)O5A—K1Bv2.646 (13)
Co1A—Co2A2.985 (8)O5A—K2Aiii3.010 (13)
Co1A—K1Aiii3.310 (14)O5B—K2Biii2.69 (4)
Co1A—K2Aii3.473 (9)O5B—K1Bvi2.753 (18)
Co1A—K2Aiii3.571 (11)O5B—K2Biv2.91 (2)
Co1B—O4Aix1.95 (4)O5B—K1Aiii3.219 (19)
Co1B—O8Av1.971 (15)O6A—K2Aii2.59 (3)
Co1B—O2Bx2.00 (2)O6A—K2Aiii2.77 (3)
Co1B—O6B2.032 (14)O6B—Mo2Bvi1.96 (3)
Co1B—O12Bvi2.11 (4)O6B—Mo3Bvi2.10 (3)
Co1B—O10B2.342 (19)O6B—K2Bvi2.87 (4)
Co1B—Co2B2.945 (7)O6B—K2Bix2.94 (2)
Co1B—Mo3Bvi2.976 (6)O7A—Co2Av2.03 (3)
Co1B—K2Bix3.132 (7)O7A—K1Av2.44 (3)
Co1B—K1B3.426 (16)O7B—K1Biii2.66 (3)
Co1B—K2Bvi3.664 (13)O7B—K1Aiii2.84 (3)
Co2A—O12A1.979 (12)O8A—Co1Bv1.971 (15)
Co2A—O7Av2.03 (3)O8A—Co2Bv2.09 (4)
Co2A—O3A2.03 (2)O8A—K1Bv3.30 (4)
Co2A—O11B2.039 (15)O8B—K1Aiii2.69 (4)
Co2A—O11Av2.09 (2)O9A—K2Aii3.41 (3)
Co2A—O8B2.22 (3)O9B—K1Bviii2.88 (2)
Co2A—K1A3.278 (16)O10A—Co1Av2.05 (2)
Co2B—O11Av1.977 (15)O10A—K1Avii2.75 (2)
Co2B—O3Bx1.989 (15)O10B—Mo2Bvi2.330 (14)
Co2B—O7B2.02 (3)O11A—Co2Bv1.977 (15)
Co2B—O12Bvi2.032 (14)O11A—Co2Av2.09 (2)
Co2B—O8Av2.09 (4)O12B—Co2Bvi2.032 (14)
Co2B—O11B2.10 (3)O12B—Co1Bvi2.11 (4)
Co2B—K1Biii3.363 (15)O12B—K1Bviii2.63 (4)
O1A—Mo1A—O4A100.5 (12)O11Av—Co2B—Co1B131.7 (11)
O1A—Mo1A—O3A108.4 (12)O3Bx—Co2B—Co1B81.2 (7)
O4A—Mo1A—O3A101.8 (9)O7B—Co2B—Co1B128.2 (4)
O1A—Mo1A—O2A91.8 (12)O12Bvi—Co2B—Co1B45.9 (10)
O4A—Mo1A—O2A147.5 (13)O8Av—Co2B—Co1B42.0 (4)
O3A—Mo1A—O2A102.6 (10)O11B—Co2B—Co1B88.8 (7)
O1A—Mo1A—O1B140.3 (9)O11Av—Co2B—Mo2B86.0 (4)
O4A—Mo1A—O1B76.8 (13)O3Bx—Co2B—Mo2B157.6 (11)
O3A—Mo1A—O1B111.0 (11)O7B—Co2B—Mo2B33.3 (9)
O2A—Mo1A—O1B74.6 (11)O12Bvi—Co2B—Mo2B92.0 (4)
O1A—Mo1A—Mo1B122.3 (10)O8Av—Co2B—Mo2B119.5 (6)
O4A—Mo1A—Mo1B109.8 (12)O11B—Co2B—Mo2B43.5 (10)
O3A—Mo1A—Mo1B111.6 (12)Co1B—Co2B—Mo2B117.54 (15)
O2A—Mo1A—Mo1B40.3 (8)O11Av—Co2B—K1Biii132.4 (11)
O1B—Mo1A—Mo1B34.3 (7)O3Bx—Co2B—K1Biii86.0 (10)
O1A—Mo1A—K2B118.3 (10)O7B—Co2B—K1Biii52.1 (7)
O4A—Mo1A—K2B43.2 (5)O12Bvi—Co2B—K1Biii51.3 (11)
O3A—Mo1A—K2B59.1 (5)O8Av—Co2B—K1Biii136.1 (5)
O2A—Mo1A—K2B147.9 (7)O11B—Co2B—K1Biii115.6 (8)
O1B—Mo1A—K2B87.2 (6)Co1B—Co2B—K1Biii94.4 (2)
Mo1B—Mo1A—K2B117.5 (2)Mo2B—Co2B—K1Biii80.50 (18)
O1A—Mo1A—K1Bi101.1 (5)O7Av—K1A—O3A76.1 (10)
O4A—Mo1A—K1Bi44.5 (10)O7Av—K1A—O4Bxi143.1 (7)
O3A—Mo1A—K1Bi139.3 (4)O3A—K1A—O4Bxi98.6 (9)
O2A—Mo1A—K1Bi103.8 (7)O7Av—K1A—O8Bxi144.3 (9)
O1B—Mo1A—K1Bi49.3 (6)O3A—K1A—O8Bxi134.4 (6)
Mo1B—Mo1A—K1Bi72.7 (2)O4Bxi—K1A—O8Bxi62.1 (8)
K2B—Mo1A—K1Bi82.50 (16)O7Av—K1A—O10Avii93.1 (8)
O1A—Mo1A—K2Aii50.7 (10)O3A—K1A—O10Avii138.9 (8)
O4A—Mo1A—K2Aii134.1 (5)O4Bxi—K1A—O10Avii66.7 (6)
O3A—Mo1A—K2Aii119.9 (4)O8Bxi—K1A—O10Avii74.3 (9)
O2A—Mo1A—K2Aii42.1 (7)O7Av—K1A—O7Bxi89.7 (9)
O1B—Mo1A—K2Aii102.9 (6)O3A—K1A—O7Bxi125.3 (7)
Mo1B—Mo1A—K2Aii73.6 (2)O4Bxi—K1A—O7Bxi120.7 (12)
K2B—Mo1A—K2Aii168.8 (3)O8Bxi—K1A—O7Bxi58.8 (8)
K1Bi—Mo1A—K2Aii100.46 (16)O10Avii—K1A—O7Bxi93.5 (8)
O1A—Mo1A—K1A77.6 (8)O7Av—K1A—O9B70.6 (6)
O4A—Mo1A—K1A99.0 (11)O3A—K1A—O9B66.6 (7)
O3A—Mo1A—K1A32.2 (11)O4Bxi—K1A—O9B141.3 (5)
O2A—Mo1A—K1A113.0 (7)O8Bxi—K1A—O9B101.8 (8)
O1B—Mo1A—K1A142.2 (4)O10Avii—K1A—O9B146.9 (6)
Mo1B—Mo1A—K1A139.38 (19)O7Bxi—K1A—O9B58.9 (9)
K2B—Mo1A—K1A66.90 (18)O7Av—K1A—O5Bxi121.0 (6)
K1Bi—Mo1A—K1A143.1 (3)O3A—K1A—O5Bxi89.8 (8)
K2Aii—Mo1A—K1A106.09 (19)O4Bxi—K1A—O5Bxi95.0 (6)
O3B—Mo1B—O2B111.6 (11)O8Bxi—K1A—O5Bxi54.9 (7)
O3B—Mo1B—O4B101.7 (8)O10Avii—K1A—O5Bxi128.1 (11)
O2B—Mo1B—O4B100.8 (12)O7Bxi—K1A—O5Bxi53.3 (5)
O3B—Mo1B—O1B104.0 (11)O9B—K1A—O5Bxi51.6 (8)
O2B—Mo1B—O1B93.0 (11)O7Av—K1A—Mo2Bxi122.2 (5)
O4B—Mo1B—O1B143.7 (12)O3A—K1A—Mo2Bxi120.5 (4)
O3B—Mo1B—O2A95.0 (11)O4Bxi—K1A—Mo2Bxi92.3 (8)
O2B—Mo1B—O2A152.0 (9)O8Bxi—K1A—Mo2Bxi33.4 (3)
O4B—Mo1B—O2A81.0 (12)O10Avii—K1A—Mo2Bxi99.0 (8)
O1B—Mo1B—O2A71.7 (10)O7Bxi—K1A—Mo2Bxi33.7 (5)
O3B—Mo1B—Co1A113.0 (5)O9B—K1A—Mo2Bxi68.9 (7)
O2B—Mo1B—Co1A125.3 (5)O5Bxi—K1A—Mo2Bxi30.8 (6)
O4B—Mo1B—Co1A40.4 (11)O7Av—K1A—O2Bxi147.7 (10)
O1B—Mo1B—Co1A105.1 (7)O3A—K1A—O2Bxi73.4 (9)
O2A—Mo1B—Co1A43.5 (6)O4Bxi—K1A—O2Bxi53.8 (4)
O3B—Mo1B—Mo1A101.6 (13)O8Bxi—K1A—O2Bxi61.8 (8)
O2B—Mo1B—Mo1A125.9 (10)O10Avii—K1A—O2Bxi117.0 (8)
O4B—Mo1B—Mo1A113.0 (12)O7Bxi—K1A—O2Bxi99.2 (6)
O1B—Mo1B—Mo1A36.6 (8)O9B—K1A—O2Bxi87.5 (5)
O2A—Mo1B—Mo1A35.1 (7)O5Bxi—K1A—O2Bxi49.1 (4)
Co1A—Mo1B—Mo1A72.69 (19)Mo2Bxi—K1A—O2Bxi67.1 (5)
O3B—Mo1B—K2Aiii57.7 (6)O7Av—K1A—Co2A38.2 (7)
O2B—Mo1B—K2Aiii116.2 (10)O3A—K1A—Co2A38.3 (6)
O4B—Mo1B—K2Aiii44.1 (5)O4Bxi—K1A—Co2A123.9 (9)
O1B—Mo1B—K2Aiii149.2 (8)O8Bxi—K1A—Co2A167.6 (4)
O2A—Mo1B—K2Aiii84.7 (6)O10Avii—K1A—Co2A117.7 (7)
Co1A—Mo1B—K2Aiii66.91 (17)O7Bxi—K1A—Co2A114.8 (8)
Mo1A—Mo1B—K2Aiii117.5 (2)O9B—K1A—Co2A66.6 (8)
O3B—Mo1B—K1Aiii135.7 (11)O5Bxi—K1A—Co2A112.7 (7)
O2B—Mo1B—K1Aiii65.9 (6)Mo2Bxi—K1A—Co2A135.5 (2)
O4B—Mo1B—K1Aiii42.3 (6)O2Bxi—K1A—Co2A111.6 (7)
O1B—Mo1B—K1Aiii120.1 (5)O7Av—K1A—Co1Axi131.2 (5)
O2A—Mo1B—K1Aiii101.1 (6)O3A—K1A—Co1Axi134.1 (4)
Co1A—Mo1B—K1Aiii60.3 (2)O4Bxi—K1A—Co1Axi36.2 (7)
Mo1A—Mo1B—K1Aiii115.1 (2)O8Bxi—K1A—Co1Axi46.6 (4)
K2Aiii—Mo1B—K1Aiii82.94 (19)O10Avii—K1A—Co1Axi38.1 (6)
O3B—Mo1B—K2Biv115.5 (4)O7Bxi—K1A—Co1Axi94.7 (8)
O2B—Mo1B—K2Biv52.3 (10)O9B—K1A—Co1Axi148.2 (9)
O4B—Mo1B—K2Biv139.7 (5)O5Bxi—K1A—Co1Axi99.5 (7)
O1B—Mo1B—K2Biv40.7 (8)Mo2Bxi—K1A—Co1Axi79.3 (4)
O2A—Mo1B—K2Biv109.2 (7)O2Bxi—K1A—Co1Axi79.3 (6)
Co1A—Mo1B—K2Biv125.87 (18)Co2A—K1A—Co1Axi145.1 (2)
Mo1A—Mo1B—K2Biv75.4 (2)O12Bviii—K1B—O4Aix118.6 (8)
K2Aiii—Mo1B—K2Biv165.5 (3)O12Bviii—K1B—O5Av95.0 (10)
K1Aiii—Mo1B—K2Biv97.66 (16)O4Aix—K1B—O5Av73.5 (7)
O3B—Mo1B—K1Bi69.6 (9)O12Bviii—K1B—O7Bxi62.7 (9)
O2B—Mo1B—K1Bi94.8 (8)O4Aix—K1B—O7Bxi148.7 (4)
O4B—Mo1B—K1Bi164.2 (9)O5Av—K1B—O7Bxi75.3 (7)
O1B—Mo1B—K1Bi36.5 (5)O12Bviii—K1B—O10B153.0 (6)
O2A—Mo1B—K1Bi86.5 (7)O4Aix—K1B—O10B75.7 (9)
Co1A—Mo1B—K1Bi129.6 (3)O5Av—K1B—O10B111.5 (11)
Mo1A—Mo1B—K1Bi58.30 (19)O7Bxi—K1B—O10B118.0 (8)
K2Aiii—Mo1B—K1Bi125.27 (16)O12Bviii—K1B—O1Bix68.0 (9)
K1Aiii—Mo1B—K1Bi151.58 (12)O4Aix—K1B—O1Bix51.9 (10)
K2Biv—Mo1B—K1Bi54.25 (16)O5Av—K1B—O1Bix66.1 (6)
O3B—Mo1B—K2Aii64.7 (9)O7Bxi—K1B—O1Bix112.5 (9)
O2B—Mo1B—K2Aii175.6 (9)O10B—K1B—O1Bix126.7 (9)
O4B—Mo1B—K2Aii78.1 (9)O12Bviii—K1B—O5Bvi101.0 (9)
O1B—Mo1B—K2Aii90.3 (8)O4Aix—K1B—O5Bvi59.4 (5)
O2A—Mo1B—K2Aii32.3 (4)O5Av—K1B—O5Bvi132.4 (7)
Co1A—Mo1B—K2Aii56.41 (14)O7Bxi—K1B—O5Bvi151.0 (8)
Mo1A—Mo1B—K2Aii58.12 (18)O10B—K1B—O5Bvi65.1 (8)
K2Aiii—Mo1B—K2Aii60.05 (6)O1Bix—K1B—O5Bvi79.0 (6)
K1Aiii—Mo1B—K2Aii114.79 (16)O12Bviii—K1B—O9Bviii59.2 (8)
K2Biv—Mo1B—K2Aii131.0 (3)O4Aix—K1B—O9Bviii112.9 (6)
K1Bi—Mo1B—K2Aii86.12 (19)O5Av—K1B—O9Bviii153.8 (12)
O5A—Mo2A—O7A106.7 (14)O7Bxi—K1B—O9Bviii94.7 (8)
O5A—Mo2A—O6A113.3 (11)O10B—K1B—O9Bviii94.6 (9)
O7A—Mo2A—O6A103.7 (7)O1Bix—K1B—O9Bviii97.0 (7)
O5A—Mo2A—O8A109.6 (12)O5Bvi—K1B—O9Bviii56.7 (9)
O7A—Mo2A—O8A104.1 (10)O12Bviii—K1B—O9B116.7 (9)
O6A—Mo2A—O8A118.2 (14)O4Aix—K1B—O9B124.0 (11)
O5A—Mo2A—K2Aiii60.8 (5)O5Av—K1B—O9B94.3 (6)
O7A—Mo2A—K2Aiii125.5 (9)O7Bxi—K1B—O9B59.8 (10)
O6A—Mo2A—K2Aiii53.0 (10)O10B—K1B—O9B58.3 (7)
O8A—Mo2A—K2Aiii130.4 (5)O1Bix—K1B—O9B160.4 (4)
O5A—Mo2A—K1Bv47.7 (5)O5Bvi—K1B—O9B116.8 (8)
O7A—Mo2A—K1Bv92.8 (7)O9Bviii—K1B—O9B101.6 (6)
O6A—Mo2A—K1Bv158.7 (9)O12Bviii—K1B—O8Av151.3 (5)
O8A—Mo2A—K1Bv69.3 (10)O4Aix—K1B—O8Av53.2 (7)
K2Aiii—Mo2A—K1Bv106.2 (3)O5Av—K1B—O8Av56.7 (10)
O5A—Mo2A—K2Aii117.1 (5)O7Bxi—K1B—O8Av108.9 (7)
O7A—Mo2A—K2Aii128.4 (10)O10B—K1B—O8Av55.7 (7)
O6A—Mo2A—K2Aii35.0 (8)O1Bix—K1B—O8Av93.4 (8)
O8A—Mo2A—K2Aii86.1 (8)O5Bvi—K1B—O8Av96.3 (9)
K2Aiii—Mo2A—K2Aii63.32 (5)O9Bviii—K1B—O8Av148.1 (9)
K1Bv—Mo2A—K2Aii136.67 (15)O9B—K1B—O8Av74.1 (7)
O5A—Mo2A—K1Av82.5 (7)O12Bviii—K1B—Co2Bxi37.1 (3)
O7A—Mo2A—K1Av24.2 (13)O4Aix—K1B—Co2Bxi123.4 (6)
O6A—Mo2A—K1Av115.0 (6)O5Av—K1B—Co2Bxi64.9 (9)
O8A—Mo2A—K1Av112.8 (5)O7Bxi—K1B—Co2Bxi36.8 (6)
K2Aiii—Mo2A—K1Av113.6 (3)O10B—K1B—Co2Bxi154.6 (4)
K1Bv—Mo2A—K1Av75.84 (17)O1Bix—K1B—Co2Bxi76.4 (7)
K2Aii—Mo2A—K1Av147.47 (14)O5Bvi—K1B—Co2Bxi137.3 (9)
O5B—Mo2B—O8B105.1 (11)O9Bviii—K1B—Co2Bxi92.5 (8)
O5B—Mo2B—O7B102.8 (14)O9B—K1B—Co2Bxi96.4 (7)
O8B—Mo2B—O7B99.3 (8)O8Av—K1B—Co2Bxi119.3 (4)
O5B—Mo2B—O6Bvi98.2 (10)O12Bviii—K1B—Mo3Bviii32.0 (3)
O8B—Mo2B—O6Bvi101.2 (12)O4Aix—K1B—Mo3Bviii128.9 (6)
O7B—Mo2B—O6Bvi145.5 (11)O5Av—K1B—Mo3Bviii126.2 (10)
O5B—Mo2B—O11B164.2 (7)O7Bxi—K1B—Mo3Bviii70.7 (7)
O8B—Mo2B—O11B89.4 (11)O10B—K1B—Mo3Bviii121.0 (5)
O7B—Mo2B—O11B80.6 (11)O1Bix—K1B—Mo3Bviii90.2 (8)
O6Bvi—Mo2B—O11B72.2 (10)O5Bvi—K1B—Mo3Bviii83.2 (8)
O5B—Mo2B—O10Bvi91.7 (9)O9Bviii—K1B—Mo3Bviii29.7 (7)
O8B—Mo2B—O10Bvi162.4 (14)O9B—K1B—Mo3Bviii102.8 (6)
O7B—Mo2B—O10Bvi81.6 (7)O8Av—K1B—Mo3Bviii176.2 (4)
O6Bvi—Mo2B—O10Bvi70.6 (9)Co2Bxi—K1B—Mo3Bviii62.8 (3)
O11B—Mo2B—O10Bvi73.4 (8)O4Bxi—K2A—O2Axii171.7 (5)
O5B—Mo2B—Co2A150.9 (5)O4Bxi—K2A—O6Axii118.6 (7)
O8B—Mo2B—Co2A47.0 (11)O2Axii—K2A—O6Axii68.2 (7)
O7B—Mo2B—Co2A91.6 (9)O4Bxi—K2A—O9A69.0 (8)
O6Bvi—Mo2B—Co2A82.7 (8)O2Axii—K2A—O9A105.5 (8)
O11B—Mo2B—Co2A42.5 (4)O6Axii—K2A—O9A105.0 (11)
O10Bvi—Mo2B—Co2A115.6 (8)O4Bxi—K2A—O6Axi65.1 (7)
O5B—Mo2B—Co2B139.9 (9)O2Axii—K2A—O6Axi108.9 (8)
O8B—Mo2B—Co2B93.0 (5)O6Axii—K2A—O6Axi170.3 (11)
O7B—Mo2B—Co2B38.1 (12)O9A—K2A—O6Axi84.7 (8)
O6Bvi—Mo2B—Co2B113.1 (7)O4Bxi—K2A—O1Axii119.3 (10)
O11B—Mo2B—Co2B42.7 (7)O2Axii—K2A—O1Axii57.0 (10)
O10Bvi—Mo2B—Co2B76.8 (3)O6Axii—K2A—O1Axii116.6 (6)
Co2A—Mo2B—Co2B61.62 (14)O9A—K2A—O1Axii117.7 (5)
O5B—Mo2B—Mo3B130.0 (8)O6Axi—K2A—O1Axii56.6 (6)
O8B—Mo2B—Mo3B110.1 (12)O4Bxi—K2A—O1A66.5 (9)
O7B—Mo2B—Mo3B105.2 (11)O2Axii—K2A—O1A117.3 (11)
O6Bvi—Mo2B—Mo3B41.3 (7)O6Axii—K2A—O1A57.8 (6)
O11B—Mo2B—Mo3B35.7 (5)O9A—K2A—O1A64.3 (6)
O10Bvi—Mo2B—Mo3B53.3 (10)O6Axi—K2A—O1A129.2 (5)
Co2A—Mo2B—Mo3B67.72 (16)O1Axii—K2A—O1A174.1 (9)
Co2B—Mo2B—Mo3B72.30 (16)O4Bxi—K2A—O3Bxi58.7 (5)
O5B—Mo2B—K1Aiii74.5 (9)O2Axii—K2A—O3Bxi128.8 (6)
O8B—Mo2B—K1Aiii56.8 (12)O6Axii—K2A—O3Bxi82.1 (8)
O7B—Mo2B—K1Aiii61.4 (8)O9A—K2A—O3Bxi122.5 (5)
O6Bvi—Mo2B—K1Aiii152.1 (5)O6Axi—K2A—O3Bxi93.3 (8)
O11B—Mo2B—K1Aiii119.8 (6)O1Axii—K2A—O3Bxi107.9 (9)
O10Bvi—Mo2B—K1Aiii135.3 (9)O1A—K2A—O3Bxi74.0 (8)
Co2A—Mo2B—K1Aiii91.1 (2)O4Bxi—K2A—O5Axi109.4 (5)
Co2B—Mo2B—K1Aiii86.95 (18)O2Axii—K2A—O5Axi62.4 (5)
Mo3B—Mo2B—K1Aiii155.41 (18)O6Axii—K2A—O5Axi122.8 (9)
O5B—Mo2B—K1Bvi46.9 (5)O9A—K2A—O5Axi64.7 (6)
O8B—Mo2B—K1Bvi149.5 (12)O6Axi—K2A—O5Axi60.5 (8)
O7B—Mo2B—K1Bvi79.8 (7)O1Axii—K2A—O5Axi54.3 (8)
O6Bvi—Mo2B—K1Bvi95.5 (7)O1A—K2A—O5Axi126.0 (9)
O11B—Mo2B—K1Bvi120.1 (4)O3Bxi—K2A—O5Axi153.1 (12)
O10Bvi—Mo2B—K1Bvi48.1 (9)O4Bxi—K2A—O9Axii105.3 (9)
Co2A—Mo2B—K1Bvi162.22 (18)O2Axii—K2A—O9Axii79.0 (8)
Co2B—Mo2B—K1Bvi103.61 (14)O6Axii—K2A—O9Axii86.1 (7)
Mo3B—Mo2B—K1Bvi99.3 (2)O9A—K2A—O9Axii168.9 (12)
K1Aiii—Mo2B—K1Bvi98.3 (3)O6Axi—K2A—O9Axii84.2 (9)
O5B—Mo2B—K2Biv51.5 (10)O1Axii—K2A—O9Axii55.9 (5)
O8B—Mo2B—K2Biv88.9 (4)O1A—K2A—O9Axii123.1 (5)
O7B—Mo2B—K2Biv154.3 (12)O3Bxi—K2A—O9Axii57.4 (5)
O6Bvi—Mo2B—K2Biv53.5 (7)O5Axi—K2A—O9Axii110.1 (7)
O11B—Mo2B—K2Biv124.1 (8)O4Bxi—K2A—Mo2Axi88.8 (5)
O10Bvi—Mo2B—K2Biv97.8 (3)O2Axii—K2A—Mo2Axi83.7 (5)
Co2A—Mo2B—K2Biv111.3 (2)O6Axii—K2A—Mo2Axi151.1 (4)
Co2B—Mo2B—K2Biv166.5 (3)O9A—K2A—Mo2Axi75.1 (6)
Mo3B—Mo2B—K2Biv94.5 (2)O6Axi—K2A—Mo2Axi30.3 (4)
K1Aiii—Mo2B—K2Biv105.1 (2)O1Axii—K2A—Mo2Axi46.2 (3)
K1Bvi—Mo2B—K2Biv80.88 (17)O1A—K2A—Mo2Axi137.7 (4)
O9A—Mo3A—O10A108.7 (15)O3Bxi—K2A—Mo2Axi122.9 (8)
O9A—Mo3A—O12A108.2 (10)O5Axi—K2A—Mo2Axi30.4 (8)
O10A—Mo3A—O12A113.0 (10)O9Axii—K2A—Mo2Axi95.6 (5)
O9A—Mo3A—O11A111.5 (9)O4Bxi—K2A—Co1Axii152.3 (6)
O10A—Mo3A—O11A107.1 (8)O2Axii—K2A—Co1Axii35.2 (5)
O12A—Mo3A—O11A108.4 (14)O6Axii—K2A—Co1Axii33.9 (3)
O9A—Mo3A—K1A64.1 (6)O9A—K2A—Co1Axii114.3 (8)
O10A—Mo3A—K1A73.2 (6)O6Axi—K2A—Co1Axii141.0 (4)
O12A—Mo3A—K1A75.6 (10)O1Axii—K2A—Co1Axii84.6 (5)
O11A—Mo3A—K1A175.1 (10)O1A—K2A—Co1Axii89.5 (5)
O9A—Mo3A—K1Avii97.2 (10)O3Bxi—K2A—Co1Axii102.6 (4)
O10A—Mo3A—K1Avii38.0 (5)O5Axi—K2A—Co1Axii95.8 (5)
O12A—Mo3A—K1Avii148.0 (5)O9Axii—K2A—Co1Axii75.3 (5)
O11A—Mo3A—K1Avii78.7 (9)Mo2Axi—K2A—Co1Axii118.83 (14)
K1A—Mo3A—K1Avii99.43 (14)O1Bxiii—K2B—O4A140.9 (5)
O9A—Mo3A—K2Aii57.5 (11)O1Bxiii—K2B—O5Bxi83.4 (9)
O10A—Mo3A—K2Aii166.2 (11)O4A—K2B—O5Bxi116.6 (9)
O12A—Mo3A—K2Aii74.7 (5)O1Bxiii—K2B—O9B101.4 (5)
O11A—Mo3A—K2Aii79.9 (5)O4A—K2B—O9B117.7 (5)
K1A—Mo3A—K2Aii98.81 (16)O5Bxi—K2B—O9B57.5 (9)
K1Avii—Mo3A—K2Aii136.77 (16)O1Bxiii—K2B—O6Bvi108.0 (8)
O9B—Mo3B—O12B102.1 (14)O4A—K2B—O6Bvi89.4 (10)
O9B—Mo3B—O10B103.7 (13)O5Bxi—K2B—O6Bvi123.1 (6)
O12B—Mo3B—O10B95.5 (6)O9B—K2B—O6Bvi65.6 (9)
O9B—Mo3B—O11B101.5 (12)O1Bxiii—K2B—O5Bxiii87.0 (6)
O12B—Mo3B—O11B150.3 (16)O4A—K2B—O5Bxiii57.9 (5)
O10B—Mo3B—O11B96.1 (9)O5Bxi—K2B—O5Bxiii148.2 (12)
O9B—Mo3B—O6Bvi109.6 (11)O9B—K2B—O5Bxiii154.2 (12)
O12B—Mo3B—O6Bvi80.7 (10)O6Bvi—K2B—O5Bxiii88.6 (10)
O10B—Mo3B—O6Bvi146.6 (14)O1Bxiii—K2B—O6Bi75.5 (6)
O11B—Mo3B—O6Bvi74.6 (9)O4A—K2B—O6Bi70.9 (8)
O9B—Mo3B—Co1Bvi129.8 (5)O5Bxi—K2B—O6Bi91.5 (10)
O12B—Mo3B—Co1Bvi44.7 (12)O9B—K2B—O6Bi148.9 (11)
O10B—Mo3B—Co1Bvi114.1 (7)O6Bvi—K2B—O6Bi145.2 (12)
O11B—Mo3B—Co1Bvi105.8 (10)O5Bxiii—K2B—O6Bi56.7 (8)
O6Bvi—Mo3B—Co1Bvi43.0 (4)O1Bxiii—K2B—O2Bxi118.3 (12)
O9B—Mo3B—Mo2B124.8 (8)O4A—K2B—O2Bxi61.3 (9)
O12B—Mo3B—Mo2B109.0 (12)O5Bxi—K2B—O2Bxi56.8 (6)
O10B—Mo3B—Mo2B116.9 (12)O9B—K2B—O2Bxi94.4 (7)
O11B—Mo3B—Mo2B41.7 (9)O6Bvi—K2B—O2Bxi132.6 (5)
O6Bvi—Mo3B—Mo2B37.9 (8)O5Bxiii—K2B—O2Bxi103.0 (6)
Co1Bvi—Mo3B—Mo2B64.32 (15)O6Bi—K2B—O2Bxi62.3 (5)
O9B—Mo3B—K2B59.7 (5)O1Bxiii—K2B—O2Bxiii56.8 (9)
O12B—Mo3B—K2B65.3 (6)O4A—K2B—O2Bxiii106.1 (9)
O10B—Mo3B—K2B148.2 (11)O5Bxi—K2B—O2Bxiii136.4 (6)
O11B—Mo3B—K2B113.1 (5)O9B—K2B—O2Bxiii110.1 (7)
O6Bvi—Mo3B—K2B58.9 (9)O6Bvi—K2B—O2Bxiii63.2 (7)
Co1Bvi—Mo3B—K2B71.0 (2)O5Bxiii—K2B—O2Bxiii54.7 (5)
Mo2B—Mo3B—K2B93.9 (2)O6Bi—K2B—O2Bxiii94.3 (7)
O9B—Mo3B—K1Bviii57.8 (7)O2Bxi—K2B—O2Bxiii155.5 (2)
O12B—Mo3B—K1Bviii49.9 (12)O1Bxiii—K2B—O12B64.1 (7)
O10B—Mo3B—K1Bviii84.8 (10)O4A—K2B—O12B140.2 (12)
O11B—Mo3B—K1Bviii158.6 (11)O5Bxi—K2B—O12B92.6 (8)
O6Bvi—Mo3B—K1Bviii115.5 (8)O9B—K2B—O12B54.8 (5)
Co1Bvi—Mo3B—K1Bviii93.2 (2)O6Bvi—K2B—O12B51.0 (8)
Mo2B—Mo3B—K1Bviii153.16 (13)O5Bxiii—K2B—O12B110.2 (8)
K2B—Mo3B—K1Bviii63.4 (2)O6Bi—K2B—O12B138.5 (4)
O9B—Mo3B—K1B56.0 (6)O2Bxi—K2B—O12B146.7 (7)
O12B—Mo3B—K1B107.2 (11)O2Bxiii—K2B—O12B56.4 (5)
O10B—Mo3B—K1B47.8 (11)O1Bxiii—K2B—O3A161.0 (5)
O11B—Mo3B—K1B100.8 (8)O4A—K2B—O3A57.7 (4)
O6Bvi—Mo3B—K1B164.3 (7)O5Bxi—K2B—O3A89.7 (7)
Co1Bvi—Mo3B—K1B149.74 (13)O9B—K2B—O3A60.2 (5)
Mo2B—Mo3B—K1B142.04 (15)O6Bvi—K2B—O3A61.6 (7)
K2B—Mo3B—K1B111.4 (3)O5Bxiii—K2B—O3A107.6 (7)
K1Bviii—Mo3B—K1B64.12 (15)O6Bi—K2B—O3A122.5 (5)
O4B—Co1A—O6A93.9 (10)O2Bxi—K2B—O3A71.1 (8)
O4B—Co1A—O12A161.2 (8)O2Bxiii—K2B—O3A122.0 (10)
O6A—Co1A—O12A100.7 (11)O12B—K2B—O3A98.8 (6)
O4B—Co1A—O2A79.6 (11)O1Bxiii—K2B—Co1Bi114.2 (6)
O6A—Co1A—O2A92.9 (7)O4A—K2B—Co1Bi38.3 (8)
O12A—Co1A—O2A87.8 (12)O5Bxi—K2B—Co1Bi91.8 (5)
O4B—Co1A—O10Av93.7 (12)O9B—K2B—Co1Bi129.8 (5)
O6A—Co1A—O10Av97.5 (8)O6Bvi—K2B—Co1Bi127.7 (5)
O12A—Co1A—O10Av96.1 (10)O5Bxiii—K2B—Co1Bi64.9 (5)
O2A—Co1A—O10Av168.0 (8)O6Bi—K2B—Co1Bi38.9 (3)
O4B—Co1A—Mo1B35.8 (8)O2Bxi—K2B—Co1Bi38.1 (4)
O6A—Co1A—Mo1B105.9 (5)O2Bxiii—K2B—Co1Bi118.6 (4)
O12A—Co1A—Mo1B127.1 (6)O12B—K2B—Co1Bi175.1 (6)
O2A—Co1A—Mo1B46.6 (10)O3A—K2B—Co1Bi83.6 (4)
O10Av—Co1A—Mo1B124.0 (8)Mo1A—O1A—K2Aii101.5 (16)
O4B—Co1A—Co2A122.1 (5)Mo1A—O1A—K2A162.0 (9)
O6A—Co1A—Co2A141.3 (11)K2Aii—O1A—K2A83.2 (3)
O12A—Co1A—Co2A41.2 (4)Mo1B—O1B—Mo1A109.1 (6)
O2A—Co1A—Co2A81.3 (7)Mo1B—O1B—K2Biv110.4 (16)
O10Av—Co1A—Co2A94.2 (7)Mo1A—O1B—K2Biv134.2 (14)
Mo1B—Co1A—Co2A97.65 (13)Mo1B—O1B—K1Bi119.3 (10)
O4B—Co1A—K1Aiii50.4 (6)Mo1A—O1B—K1Bi96.9 (13)
O6A—Co1A—K1Aiii126.9 (11)K2Biv—O1B—K1Bi83.3 (4)
O12A—Co1A—K1Aiii124.8 (6)Mo1A—O2A—Co1A136.4 (10)
O2A—Co1A—K1Aiii112.6 (8)Mo1A—O2A—Mo1B104.6 (6)
O10Av—Co1A—K1Aiii56.0 (7)Co1A—O2A—Mo1B89.9 (15)
Mo1B—Co1A—K1Aiii69.40 (17)Mo1A—O2A—K2Aii108.1 (15)
Co2A—Co1A—K1Aiii89.9 (2)Co1A—O2A—K2Aii98.0 (5)
O4B—Co1A—K2Aii94.2 (7)Mo1B—O2A—K2Aii121.3 (11)
O6A—Co1A—K2Aii47.5 (8)Mo1B—O2B—Co1Bxiv116.4 (8)
O12A—Co1A—K2Aii87.2 (7)Mo1B—O2B—K2Biii166.1 (7)
O2A—Co1A—K2Aii46.8 (4)Co1Bxiv—O2B—K2Biii75.6 (9)
O10Av—Co1A—K2Aii144.5 (4)Mo1B—O2B—K2Biv99.8 (15)
Mo1B—Co1A—K2Aii78.86 (15)Co1Bxiv—O2B—K2Biv93.3 (6)
Co2A—Co1A—K2Aii110.5 (3)K2Biii—O2B—K2Biv85.6 (3)
K1Aiii—Co1A—K2Aii144.4 (3)Mo1B—O2B—K1Aiii84.8 (5)
O4B—Co1A—K2Aiii43.4 (4)Co1Bxiv—O2B—K1Aiii135.7 (16)
O6A—Co1A—K2Aiii50.5 (9)K2Biii—O2B—K1Aiii81.5 (6)
O12A—Co1A—K2Aiii149.3 (6)K2Biv—O2B—K1Aiii122.4 (7)
O2A—Co1A—K2Aiii84.0 (8)Mo1A—O3A—Co2A123.8 (17)
O10Av—Co1A—K2Aiii98.0 (8)Mo1A—O3A—K1A125.5 (14)
Mo1B—Co1A—K2Aiii63.99 (14)Co2A—O3A—K1A92.3 (7)
Co2A—Co1A—K2Aiii161.53 (13)Mo1A—O3A—K2B91.0 (5)
K1Aiii—Co1A—K2Aiii85.5 (3)Co2A—O3A—K2B130.4 (7)
K2Aii—Co1A—K2Aiii65.82 (6)K1A—O3A—K2B93.8 (10)
O4Aix—Co1B—O8Av88.3 (11)Mo1B—O3B—Co2Bxiv125.5 (7)
O4Aix—Co1B—O2Bx92.3 (11)Mo1B—O3B—K2Aiii92.6 (7)
O8Av—Co1B—O2Bx107.3 (8)Co2Bxiv—O3B—K2Aiii129.4 (13)
O4Aix—Co1B—O6B108.0 (11)Mo1A—O4A—Co1Bi130.6 (16)
O8Av—Co1B—O6B148.9 (6)Mo1A—O4A—K2B108.8 (7)
O2Bx—Co1B—O6B98.6 (9)Co1Bi—O4A—K2B86.4 (12)
O4Aix—Co1B—O12Bvi176.2 (5)Mo1A—O4A—K1Bi107.5 (14)
O8Av—Co1B—O12Bvi88.2 (11)Co1Bi—O4A—K1Bi95.6 (6)
O2Bx—Co1B—O12Bvi87.4 (12)K2B—O4A—K1Bi129.5 (7)
O6B—Co1B—O12Bvi75.9 (11)Mo1B—O4B—Co1A103.9 (19)
O4Aix—Co1B—O10B99.1 (12)Mo1B—O4B—K2Aiii107.0 (7)
O8Av—Co1B—O10B82.4 (6)Co1A—O4B—K2Aiii104.5 (7)
O2Bx—Co1B—O10B165.4 (11)Mo1B—O4B—K1Aiii110.0 (6)
O6B—Co1B—O10B69.2 (7)Co1A—O4B—K1Aiii93.5 (6)
O12Bvi—Co1B—O10B81.9 (11)K2Aiii—O4B—K1Aiii133.3 (15)
O4Aix—Co1B—Co2B132.7 (4)Mo2A—O5A—K1Bv103.1 (12)
O8Av—Co1B—Co2B45.2 (11)Mo2A—O5A—K2Aiii88.8 (8)
O2Bx—Co1B—Co2B94.1 (8)K1Bv—O5A—K2Aiii156.9 (7)
O6B—Co1B—Co2B117.3 (9)Mo2B—O5B—K2Biii161.2 (12)
O12Bvi—Co1B—Co2B43.6 (4)Mo2B—O5B—K1Bvi106.2 (8)
O10B—Co1B—Co2B85.0 (6)K2Biii—O5B—K1Bvi80.9 (9)
O4Aix—Co1B—Mo3Bvi145.9 (6)Mo2B—O5B—K2Biv101.1 (15)
O8Av—Co1B—Mo3Bvi108.3 (7)K2Biii—O5B—K2Biv91.8 (5)
O2Bx—Co1B—Mo3Bvi109.9 (9)K1Bvi—O5B—K2Biv112.8 (5)
O6B—Co1B—Mo3Bvi45.0 (7)Mo2B—O5B—K1Aiii74.6 (5)
O12Bvi—Co1B—Mo3Bvi37.2 (4)K2Biii—O5B—K1Aiii86.7 (9)
O10B—Co1B—Mo3Bvi55.9 (9)K1Bvi—O5B—K1Aiii120.2 (10)
Co2B—Co1B—Mo3Bvi72.94 (17)K2Biv—O5B—K1Aiii125.9 (5)
O4Aix—Co1B—K2Bix55.3 (5)Mo2A—O6A—Co1A136.7 (10)
O8Av—Co1B—K2Bix141.3 (9)Mo2A—O6A—K2Aii122.2 (10)
O2Bx—Co1B—K2Bix66.2 (7)Co1A—O6A—K2Aii98.6 (9)
O6B—Co1B—K2Bix65.5 (6)Mo2A—O6A—K2Aiii96.6 (13)
O12Bvi—Co1B—K2Bix127.7 (6)Co1A—O6A—K2Aiii96.5 (9)
O10B—Co1B—K2Bix113.2 (6)K2Aii—O6A—K2Aiii91.1 (4)
Co2B—Co1B—K2Bix160.1 (3)Mo2Bvi—O6B—Co1B109.3 (16)
Mo3Bvi—Co1B—K2Bix109.67 (17)Mo2Bvi—O6B—Mo3Bvi100.8 (6)
O4Aix—Co1B—K1B50.0 (7)Co1B—O6B—Mo3Bvi92.0 (7)
O8Av—Co1B—K1B69.6 (11)Mo2Bvi—O6B—K2Bvi155.1 (8)
O2Bx—Co1B—K1B141.5 (10)Co1B—O6B—K2Bvi95.3 (10)
O6B—Co1B—K1B100.3 (11)Mo3Bvi—O6B—K2Bvi82.1 (13)
O12Bvi—Co1B—K1B129.7 (6)Mo2Bvi—O6B—K2Bix94.1 (13)
O10B—Co1B—K1B51.7 (9)Co1B—O6B—K2Bix75.6 (7)
Co2B—Co1B—K1B106.4 (2)Mo3Bvi—O6B—K2Bix163.1 (10)
Mo3Bvi—Co1B—K1B107.20 (17)K2Bvi—O6B—K2Bix87.6 (5)
K2Bix—Co1B—K1B91.9 (3)Mo2A—O7A—Co2Av123.8 (19)
O4Aix—Co1B—K2Bvi126.3 (6)Mo2A—O7A—K1Av138.7 (19)
O8Av—Co1B—K2Bvi137.1 (12)Co2Av—O7A—K1Av93.8 (6)
O2Bx—Co1B—K2Bvi53.7 (7)Mo2B—O7B—Co2B109 (2)
O6B—Co1B—K2Bvi51.2 (10)Mo2B—O7B—K1Biii139.1 (6)
O12Bvi—Co1B—K2Bvi56.2 (6)Co2B—O7B—K1Biii91.0 (6)
O10B—Co1B—K2Bvi111.7 (7)Mo2B—O7B—K1Aiii84.9 (6)
Co2B—Co1B—K2Bvi94.1 (3)Co2B—O7B—K1Aiii126.2 (5)
Mo3Bvi—Co1B—K2Bvi58.87 (16)K1Biii—O7B—K1Aiii112.4 (14)
K2Bix—Co1B—K2Bvi72.10 (15)Mo2A—O8A—Co1Bv146.5 (19)
K1B—Co1B—K2Bvi150.90 (17)Mo2A—O8A—Co2Bv120.2 (10)
O12A—Co2A—O7Av91.9 (10)Co1Bv—O8A—Co2Bv92.8 (14)
O12A—Co2A—O3A94.7 (8)Mo2A—O8A—K1Bv80.3 (13)
O7Av—Co2A—O3A96.9 (12)Co1Bv—O8A—K1Bv76.4 (9)
O12A—Co2A—O11B164.0 (14)Co2Bv—O8A—K1Bv141.3 (6)
O7Av—Co2A—O11B90.9 (11)Mo2B—O8B—Co2A97.4 (11)
O3A—Co2A—O11B100.5 (8)Mo2B—O8B—K1Aiii89.9 (13)
O12A—Co2A—O11Av84.5 (8)Co2A—O8B—K1Aiii129.6 (6)
O7Av—Co2A—O11Av85.7 (10)Mo3A—O9A—K2A171.0 (10)
O3A—Co2A—O11Av177.4 (13)Mo3A—O9A—K2Aii98.0 (15)
O11B—Co2A—O11Av80.0 (8)K2A—O9A—K2Aii77.1 (4)
O12A—Co2A—O8B95.5 (10)Mo3B—O9B—K2B89.8 (9)
O7Av—Co2A—O8B171.2 (7)Mo3B—O9B—K1Bviii92.5 (6)
O3A—Co2A—O8B87.3 (10)K2B—O9B—K1Bviii75.9 (4)
O11B—Co2A—O8B80.6 (11)Mo3B—O9B—K1A138.3 (15)
O11Av—Co2A—O8B90.3 (11)K2B—O9B—K1A90.0 (5)
O12A—Co2A—Co1A42.2 (10)K1Bviii—O9B—K1A127.7 (14)
O7Av—Co2A—Co1A133.4 (4)Mo3B—O9B—K1B95.9 (7)
O3A—Co2A—Co1A95.1 (7)K2B—O9B—K1B153.9 (10)
O11B—Co2A—Co1A130.5 (12)K1Bviii—O9B—K1B78.4 (6)
O11Av—Co2A—Co1A82.6 (7)K1A—O9B—K1B102.2 (8)
O8B—Co2A—Co1A53.5 (4)Mo3A—O10A—Co1Av110.1 (18)
O12A—Co2A—Mo2B130.2 (11)Mo3A—O10A—K1Avii118.8 (6)
O7Av—Co2A—Mo2B136.0 (4)Co1Av—O10A—K1Avii85.8 (5)
O3A—Co2A—Mo2B92.4 (7)Mo3B—O10B—Mo2Bvi138.5 (7)
O11B—Co2A—Mo2B45.1 (9)Mo3B—O10B—Co1B131.3 (11)
O11Av—Co2A—Mo2B86.2 (7)Mo2Bvi—O10B—Co1B88.3 (5)
O8B—Co2A—Mo2B35.6 (3)Mo3B—O10B—K1B101.9 (12)
Co1A—Co2A—Mo2B88.0 (2)Mo2Bvi—O10B—K1B92.0 (11)
O12A—Co2A—K1A89.0 (11)Co1B—O10B—K1B85.3 (7)
O7Av—Co2A—K1A48.0 (8)Mo3A—O11A—Co2Bv133.7 (18)
O3A—Co2A—K1A49.4 (9)Mo3A—O11A—Co2Av120.7 (7)
O11B—Co2A—K1A104.5 (12)Co2Bv—O11A—Co2Av100.5 (7)
O11Av—Co2A—K1A133.0 (9)Mo3B—O11B—Co2A122.3 (17)
O8B—Co2A—K1A136.7 (7)Mo3B—O11B—Co2B135.0 (7)
Co1A—Co2A—K1A120.9 (2)Co2A—O11B—Co2B98.2 (7)
Mo2B—Co2A—K1A130.31 (17)Mo3B—O11B—Mo2B102.5 (7)
O11Av—Co2B—O3Bx90.0 (6)Co2A—O11B—Mo2B92.4 (9)
O11Av—Co2B—O7B95.2 (9)Co2B—O11B—Mo2B93.8 (16)
O3Bx—Co2B—O7B125.7 (14)Mo3A—O12A—Co2A132.4 (19)
O11Av—Co2B—O12Bvi175.2 (14)Mo3A—O12A—Co1A130.0 (9)
O3Bx—Co2B—O12Bvi93.4 (6)Co2A—O12A—Co1A96.6 (11)
O7B—Co2B—O12Bvi85.5 (9)Mo3B—O12B—Co2Bvi132.1 (10)
O11Av—Co2B—O8Av90.0 (11)Mo3B—O12B—Co1Bvi98.1 (15)
O3Bx—Co2B—O8Av82.5 (12)Co2Bvi—O12B—Co1Bvi90.5 (12)
O7B—Co2B—O8Av151.2 (10)Mo3B—O12B—K1Bviii98.0 (13)
O12Bvi—Co2B—O8Av87.2 (12)Co2Bvi—O12B—K1Bviii91.6 (12)
O11Av—Co2B—O11B81.2 (8)Co1Bvi—O12B—K1Bviii156.2 (9)
O3Bx—Co2B—O11B156.9 (14)Mo3B—O12B—K2B81.8 (5)
O7B—Co2B—O11B76.6 (10)Co2Bvi—O12B—K2B145.8 (9)
O12Bvi—Co2B—O11B94.3 (8)Co1Bvi—O12B—K2B88.5 (6)
O8Av—Co2B—O11B76.2 (11)K1Bviii—O12B—K2B76.6 (9)
Symmetry codes: (i) x, y+1/2, z1/2; (ii) x+1, y+1/2, z+1/2; (iii) x, y+1, z; (iv) x, y+1/2, z+1/2; (v) x+1, y+1, z+1; (vi) x, y+1, z+1; (vii) x+1, y, z+1; (viii) x, y, z+1; (ix) x, y+1/2, z+1/2; (x) x, y+3/2, z+1/2; (xi) x, y1, z; (xii) x+1, y1/2, z+1/2; (xiii) x, y1/2, z+1/2; (xiv) x, y+3/2, z1/2.

Experimental details

(alpha)(beta)(II)
Crystal data
Chemical formulaCo2K2Mo3O12Co2K2Mo3O12Co2K2Mo3O12
Mr675.88675.88675.88
Crystal system, space groupMonoclinic, P21/cMonoclinic, C2/cMonoclinic, P21/c
Temperature (K)293298298
a, b, c (Å)7.0093 (1), 8.9624 (2), 19.9977 (4)7.0418 (3), 19.3329 (7), 17.7267 (7)13.5237 (8), 7.6440 (4), 18.850 (1)
α, β, γ (°)90, 108.247 (2), 9090, 97.608 (4), 9090, 104.260 (6), 90
V3)1193.09 (4)2392.04 (16)1888.58 (18)
Z488
Radiation typeMo KαMo KαMo Kα
µ (mm1)6.596.538.26
Crystal size (mm)0.14 × 0.11 × 0.060.12 × 0.04 × 0.030.11 × 0.05 × 0.03
Data collection
DiffractometerOxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer with Sapphire CCD Detector.
Absorption correctionAnalytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Analytical
CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45) Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Tmin, Tmax0.573, 0.7510.509, 0.871
No. of measured, independent and
observed [I > 2σ(I)] reflections
8014, 2435, 2152 15336, 3025, 1739 7020, 1154, 791
Rint0.0170.0710.130
(sin θ/λ)max1)0.6250.6870.617
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.028, 0.137, 1.24 0.038, 0.121, 1.05 0.047, 0.110, 1.05
No. of reflections243530251154
No. of parameters173178195
Δρmax, Δρmin (e Å3)2.94, 1.611.76, 1.781.07, 0.89

Computer programs: CrysAlis CCD, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45), CrysAlis RED, Oxford Diffraction Ltd., Version 1.171.31.4 (release 06-08-2006 CrysAlis171 .NET) (compiled Aug 6 2006,16:44:45), SHELXS97 (Sheldrick, 1990), SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), Brandenburg et al. Diamond 3.0b.

 

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