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In the title compound, [Fe(C5H5)2]2[SbCl4]2[SbCl3], the cyclo­penta­dienyl rings in both cations are parallel, with a nearly eclipsed conformation. The Sb3+ ions are coordinated by six Cl- ions to form octahedral arrangements, of which two are slightly distorted. These octahedra form infinite chains along the c axis through Cl-Sb-Cl bridges.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270100002912/sk1355sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270100002912/sk1355Isup2.hkl
Contains datablock I

CCDC reference: 146045

Computing details top

Data collection: XSCANS (Siemens, 1994); cell refinement: XSCANS; data reduction: XSCANS; program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 1990).

Bis(ferrocenium) bis[tetrachloroantimonate(III)] trichloroantimony(III) top
Crystal data top
[Fe(C5H5)2]2[SbCl4]2[SbCl3]Z = 2
Mr = 1127.26F(000) = 1064
Triclinic, P1Dx = 2.222 Mg m3
a = 11.615 (2) ÅMo Kα radiation, λ = 0.71073 Å
b = 12.000 (1) ÅCell parameters from 41 reflections
c = 13.789 (1) Åθ = 5.0–12.3°
α = 80.03 (1)°µ = 4.10 mm1
β = 84.42 (1)°T = 293 K
γ = 62.92 (1)°Needle, dark blue
V = 1685.0 (3) Å30.36 × 0.18 × 0.08 mm
Data collection top
Siemens P4
diffractometer
3378 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.046
Graphite monochromatorθmax = 25°, θmin = 1.9°
θ/2θ scansh = 113
Absorption correction: empirical (using intensity measurements)
ψ scans (XSCANS; Siemens, 1994)
k = 1314
Tmin = 0.320, Tmax = 0.735l = 1616
6898 measured reflections3 standard reflections every 97 reflections
5935 independent reflections intensity decay: <3%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.040Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.085H-atom parameters constrained
S = 0.81 w = 1/[σ2(Fo2) + (0.0226P)2]
where P = (Fo2 + 2Fc2)/3
5935 reflections(Δ/σ)max < 0.001
325 parametersΔρmax = 0.71 e Å3
0 restraintsΔρmin = 1.04 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Since there were not enough high-intensity reflections with a ψ-value close to 90°, this may have resulted in the slightly low value of the goodness-of-fit S.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sb10.50308 (6)0.84703 (5)0.10473 (4)0.03887 (16)
Sb20.62331 (6)0.77279 (5)0.21095 (4)0.03795 (16)
Sb30.68274 (6)0.89146 (5)0.42706 (4)0.03969 (16)
Fe10.76761 (12)0.33822 (11)0.48678 (8)0.0403 (3)
Fe21.08012 (12)0.26271 (10)0.99722 (8)0.0357 (3)
Cl10.6049 (3)0.7659 (3)0.2731 (2)0.0937 (11)
Cl20.3924 (3)0.9321 (2)0.07215 (18)0.0629 (7)
Cl30.4538 (3)0.6735 (2)0.12231 (19)0.0588 (7)
Cl40.2989 (3)0.9819 (2)0.17531 (19)0.0643 (7)
Cl50.5271 (2)0.8210 (2)0.39897 (17)0.0580 (6)
Cl60.5515 (2)0.6156 (2)0.17989 (17)0.0529 (6)
Cl70.7293 (2)0.6949 (2)0.04529 (16)0.0581 (6)
Cl80.8288 (2)0.6394 (2)0.27700 (16)0.0543 (6)
Cl90.8514 (2)0.6802 (2)0.45212 (17)0.0574 (6)
Cl100.8081 (3)0.9565 (2)0.30316 (18)0.0718 (8)
Cl110.7545 (3)0.9583 (2)0.55247 (17)0.0612 (7)
C10.8438 (14)0.2852 (19)0.6268 (7)0.097 (5)
H1A0.93410.22940.64440.116*
C20.789 (2)0.4120 (19)0.6044 (9)0.095 (5)
H2A0.83450.46420.60170.114*
C30.663 (2)0.4563 (13)0.5893 (8)0.104 (6)
H3A0.60240.54590.57380.125*
C40.6316 (14)0.355 (2)0.5995 (8)0.105 (6)
H4A0.54580.35940.59570.126*
C50.747 (2)0.2488 (11)0.6209 (8)0.090 (5)
H5A0.75800.16170.63470.108*
C60.8363 (16)0.4042 (13)0.3581 (8)0.079 (4)
H6A0.85530.47720.34720.095*
C70.9200 (10)0.2834 (13)0.3874 (7)0.066 (3)
H7A1.01070.25390.40310.080*
C80.8611 (14)0.2083 (9)0.3909 (7)0.068 (3)
H8A0.90210.11620.40910.082*
C90.7351 (13)0.2822 (15)0.3624 (8)0.078 (4)
H9A0.67100.25180.35680.093*
C100.7157 (14)0.4057 (13)0.3402 (7)0.092 (5)
H10A0.63660.47940.31530.110*
C111.2367 (11)0.3748 (11)0.9166 (7)0.075 (4)
H11A1.31940.44190.94240.090*
C121.2070 (10)0.2497 (10)0.8864 (7)0.058 (3)
H12A1.26550.21190.88900.070*
C131.0828 (11)0.1854 (9)0.8505 (6)0.060 (3)
H13A1.03900.09540.82360.072*
C141.0323 (10)0.2707 (10)0.8577 (6)0.060 (3)
H14A0.94650.25250.83680.072*
C151.1273 (13)0.3885 (10)0.8988 (6)0.067 (3)
H15A1.11950.46770.91130.080*
C161.1265 (11)0.3114 (10)1.1441 (6)0.068 (3)
H16A1.20960.37631.17100.081*
C171.0942 (10)0.1833 (9)1.1149 (6)0.057 (3)
H17A1.14870.14141.11840.069*
C180.9628 (10)0.1248 (9)1.0847 (6)0.057 (3)
H18A0.91130.03461.06120.068*
C190.9205 (10)0.2169 (10)1.0947 (6)0.057 (3)
H19A0.83410.20281.07870.069*
C201.0193 (12)0.3315 (10)1.1303 (6)0.064 (3)
H20A1.01480.41231.14570.077*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sb10.0467 (4)0.0386 (3)0.0394 (3)0.0253 (3)0.0036 (3)0.0064 (2)
Sb20.0432 (4)0.0377 (3)0.0392 (3)0.0234 (3)0.0013 (3)0.0055 (2)
Sb30.0458 (4)0.0416 (3)0.0337 (3)0.0210 (3)0.0030 (3)0.0050 (2)
Fe10.0447 (8)0.0504 (7)0.0326 (6)0.0258 (7)0.0062 (6)0.0138 (5)
Fe20.0350 (7)0.0405 (7)0.0336 (6)0.0172 (6)0.0013 (5)0.0106 (5)
Cl10.125 (3)0.101 (2)0.077 (2)0.069 (2)0.050 (2)0.0153 (16)
Cl20.0597 (18)0.0547 (14)0.0707 (16)0.0192 (14)0.0201 (14)0.0080 (12)
Cl30.0628 (17)0.0436 (13)0.0836 (17)0.0352 (13)0.0069 (14)0.0145 (12)
Cl40.0646 (18)0.0522 (14)0.0748 (17)0.0236 (14)0.0147 (14)0.0218 (12)
Cl50.0518 (17)0.0634 (15)0.0562 (14)0.0242 (14)0.0077 (12)0.0031 (12)
Cl60.0548 (16)0.0489 (13)0.0665 (15)0.0350 (13)0.0060 (12)0.0064 (11)
Cl70.0575 (17)0.0692 (16)0.0489 (13)0.0294 (14)0.0104 (12)0.0036 (12)
Cl80.0416 (15)0.0696 (15)0.0520 (14)0.0257 (13)0.0051 (11)0.0108 (11)
Cl90.0589 (17)0.0449 (13)0.0621 (15)0.0149 (13)0.0104 (13)0.0112 (11)
Cl100.094 (2)0.0771 (17)0.0528 (15)0.0499 (17)0.0253 (15)0.0120 (13)
Cl110.080 (2)0.0555 (14)0.0569 (14)0.0327 (14)0.0174 (13)0.0151 (11)
C10.096 (12)0.155 (15)0.028 (6)0.043 (12)0.012 (6)0.014 (8)
C20.158 (17)0.139 (14)0.051 (7)0.116 (14)0.022 (9)0.043 (9)
C30.132 (15)0.082 (9)0.046 (7)0.003 (11)0.026 (9)0.024 (6)
C40.067 (11)0.231 (19)0.051 (7)0.090 (13)0.031 (7)0.054 (11)
C50.181 (16)0.053 (7)0.045 (6)0.065 (10)0.046 (9)0.019 (5)
C60.128 (13)0.105 (10)0.051 (7)0.094 (10)0.043 (7)0.036 (7)
C70.047 (7)0.108 (10)0.042 (6)0.030 (8)0.011 (5)0.026 (6)
C80.107 (11)0.049 (6)0.046 (6)0.033 (7)0.022 (7)0.022 (5)
C90.077 (10)0.147 (12)0.053 (7)0.078 (10)0.026 (6)0.058 (8)
C100.084 (11)0.087 (9)0.044 (6)0.016 (8)0.002 (6)0.014 (6)
C110.054 (8)0.077 (8)0.058 (6)0.008 (7)0.010 (6)0.032 (6)
C120.053 (7)0.084 (8)0.052 (6)0.040 (7)0.014 (5)0.028 (6)
C130.082 (9)0.052 (6)0.036 (5)0.021 (6)0.007 (5)0.013 (4)
C140.060 (7)0.091 (8)0.040 (5)0.036 (7)0.003 (5)0.029 (5)
C150.115 (11)0.058 (7)0.038 (5)0.044 (7)0.010 (6)0.023 (5)
C160.075 (8)0.083 (8)0.023 (5)0.015 (7)0.012 (5)0.003 (5)
C170.064 (8)0.073 (7)0.049 (6)0.035 (6)0.001 (5)0.034 (5)
C180.054 (7)0.056 (6)0.052 (6)0.009 (6)0.002 (5)0.032 (5)
C190.046 (7)0.087 (8)0.051 (6)0.039 (6)0.019 (5)0.025 (6)
C200.101 (10)0.068 (7)0.037 (5)0.053 (8)0.012 (6)0.005 (5)
Geometric parameters (Å, º) top
Sb1—Cl32.367 (2)Fe2—C152.057 (9)
Sb1—Cl42.407 (3)Fe2—C112.061 (9)
Sb1—Cl12.538 (3)Fe2—C162.062 (8)
Sb1—Cl22.683 (2)Fe2—C172.073 (8)
Sb1—Cl73.225 (3)Fe2—C202.074 (9)
Sb1—Cl2i3.334 (3)Fe2—C132.078 (9)
Sb2—Cl62.350 (2)Fe2—C142.083 (8)
Sb2—Cl82.386 (2)Fe2—C182.090 (8)
Sb2—Cl72.523 (2)Fe2—C192.095 (9)
Sb2—Cl52.786 (2)C1—C21.345 (17)
Sb2—Cl23.180 (3)C1—C51.390 (18)
Sb2—Cl4i3.568 (3)C2—C31.331 (18)
Sb3—Cl92.386 (2)C3—C41.403 (18)
Sb3—Cl112.387 (2)C4—C51.380 (17)
Sb3—Cl102.395 (3)C6—C71.342 (14)
Sb3—Cl5ii3.096 (3)C6—C101.437 (17)
Sb3—Cl5i3.172 (2)C7—C81.349 (14)
Sb3—Cl13.212 (3)C8—C91.376 (14)
Fe1—C52.021 (10)C9—C101.377 (15)
Fe1—C72.055 (10)C11—C121.373 (13)
Fe1—C62.055 (10)C11—C151.403 (15)
Fe1—C82.061 (9)C12—C131.383 (13)
Fe1—C22.063 (11)C13—C141.379 (13)
Fe1—C32.067 (11)C14—C151.400 (13)
Fe1—C42.072 (11)C16—C171.398 (13)
Fe1—C92.073 (9)C16—C201.407 (14)
Fe1—C12.076 (10)C17—C181.430 (13)
Fe1—C102.081 (10)C18—C191.382 (12)
Fe2—C122.054 (9)C19—C201.374 (13)
Cl3—Sb1—Cl493.46 (9)C11—Fe2—C17124.0 (5)
Cl3—Sb1—Cl189.35 (9)C16—Fe2—C1739.5 (4)
Cl4—Sb1—Cl191.27 (11)C12—Fe2—C20157.7 (5)
Cl3—Sb1—Cl290.00 (9)C15—Fe2—C20109.8 (4)
Cl4—Sb1—Cl288.16 (9)C11—Fe2—C20123.1 (5)
Cl1—Sb1—Cl2179.11 (10)C16—Fe2—C2039.8 (4)
Cl3—Sb1—Cl785.30 (8)C17—Fe2—C2066.8 (4)
Cl4—Sb1—Cl7163.82 (8)C12—Fe2—C1339.1 (4)
Cl1—Sb1—Cl7104.84 (10)C15—Fe2—C1365.5 (4)
Cl2—Sb1—Cl775.71 (7)C11—Fe2—C1366.1 (4)
Cl3—Sb1—Cl2i173.24 (8)C16—Fe2—C13158.1 (5)
Cl4—Sb1—Cl2i93.24 (8)C17—Fe2—C13124.1 (4)
Cl1—Sb1—Cl2i89.58 (8)C20—Fe2—C13161.3 (5)
Cl2—Sb1—Cl2i91.14 (7)C12—Fe2—C1465.4 (4)
Cl6—Sb2—Cl894.61 (9)C15—Fe2—C1439.5 (4)
Cl6—Sb2—Cl789.41 (8)C11—Fe2—C1466.6 (4)
Cl8—Sb2—Cl786.41 (8)C16—Fe2—C14161.2 (5)
Cl6—Sb2—Cl585.40 (8)C17—Fe2—C14158.4 (4)
Cl8—Sb2—Cl587.10 (8)C20—Fe2—C14126.0 (4)
Cl7—Sb2—Cl5171.34 (8)C13—Fe2—C1438.7 (4)
Cl6—Sb2—Cl287.87 (8)C12—Fe2—C18127.4 (4)
Cl8—Sb2—Cl2164.86 (7)C15—Fe2—C18158.2 (5)
Cl7—Sb2—Cl278.67 (7)C11—Fe2—C18161.2 (5)
Cl5—Sb2—Cl2108.00 (7)C16—Fe2—C1865.9 (4)
Cl6—Sb2—Cl4i161.15 (7)C17—Fe2—C1840.2 (3)
Cl8—Sb2—Cl4i96.94 (7)C20—Fe2—C1865.2 (4)
Cl7—Sb2—Cl4i76.54 (7)C13—Fe2—C18111.8 (4)
Cl5—Sb2—Cl4i109.97 (7)C14—Fe2—C18124.4 (4)
Cl2—Sb2—Cl4i77.20 (6)C12—Fe2—C19162.5 (4)
Cl9—Sb3—Cl1194.08 (8)C15—Fe2—C19124.2 (4)
Cl9—Sb3—Cl1091.82 (10)C11—Fe2—C19157.7 (5)
Cl11—Sb3—Cl1091.86 (10)C16—Fe2—C1965.5 (4)
Cl9—Sb3—Cl5ii89.55 (8)C17—Fe2—C1966.3 (4)
Cl11—Sb3—Cl5ii82.59 (8)C20—Fe2—C1938.5 (4)
Cl10—Sb3—Cl5ii174.37 (8)C13—Fe2—C19127.5 (4)
Cl9—Sb3—Cl5i175.73 (8)C14—Fe2—C19111.5 (4)
Cl11—Sb3—Cl5i82.22 (8)C18—Fe2—C1938.6 (3)
Cl10—Sb3—Cl5i86.20 (8)C2—C1—C5106.7 (13)
Cl5ii—Sb3—Cl5i92.07 (6)C2—C1—Fe170.5 (7)
Cl9—Sb3—Cl179.29 (8)C5—C1—Fe168.0 (6)
Cl11—Sb3—Cl1172.73 (8)C3—C2—C1109.9 (14)
Cl10—Sb3—Cl191.32 (9)C3—C2—Fe171.4 (7)
Cl5ii—Sb3—Cl194.30 (8)C1—C2—Fe171.6 (7)
Cl5i—Sb3—Cl1104.51 (7)C2—C3—C4109.6 (14)
C5—Fe1—C7129.6 (6)C2—C3—Fe171.0 (7)
C5—Fe1—C6165.8 (8)C4—C3—Fe170.4 (7)
C7—Fe1—C638.1 (4)C5—C4—C3104.4 (12)
C5—Fe1—C8109.9 (4)C5—C4—Fe168.3 (6)
C7—Fe1—C838.3 (4)C3—C4—Fe170.0 (7)
C6—Fe1—C864.7 (4)C4—C5—C1109.4 (12)
C5—Fe1—C265.0 (5)C4—C5—Fe172.3 (7)
C7—Fe1—C2116.2 (6)C1—C5—Fe172.3 (6)
C6—Fe1—C2111.2 (5)C7—C6—C10107.2 (10)
C8—Fe1—C2145.2 (7)C7—C6—Fe170.9 (6)
C5—Fe1—C365.1 (5)C10—C6—Fe170.6 (6)
C7—Fe1—C3147.9 (8)C6—C7—C8109.9 (11)
C6—Fe1—C3121.1 (6)C6—C7—Fe171.0 (6)
C8—Fe1—C3173.6 (7)C8—C7—Fe171.1 (6)
C2—Fe1—C337.6 (5)C7—C8—C9108.7 (10)
C5—Fe1—C439.4 (5)C7—C8—Fe170.6 (5)
C7—Fe1—C4168.4 (8)C9—C8—Fe171.0 (6)
C6—Fe1—C4153.4 (8)C8—C9—C10108.1 (11)
C8—Fe1—C4134.0 (7)C8—C9—Fe170.1 (6)
C2—Fe1—C465.4 (5)C10—C9—Fe171.0 (6)
C3—Fe1—C439.6 (5)C9—C10—C6106.1 (11)
C5—Fe1—C9119.0 (6)C9—C10—Fe170.3 (6)
C7—Fe1—C964.9 (4)C6—C10—Fe168.7 (6)
C6—Fe1—C966.0 (4)C12—C11—C15106.3 (10)
C8—Fe1—C938.9 (4)C12—C11—Fe270.2 (5)
C2—Fe1—C9174.4 (8)C15—C11—Fe269.9 (6)
C3—Fe1—C9139.0 (7)C11—C12—C13109.9 (10)
C4—Fe1—C9114.7 (5)C11—C12—Fe270.8 (6)
C5—Fe1—C139.6 (5)C13—C12—Fe271.4 (6)
C7—Fe1—C1107.6 (5)C14—C13—C12108.0 (9)
C6—Fe1—C1128.9 (7)C14—C13—Fe270.8 (5)
C8—Fe1—C1115.3 (6)C12—C13—Fe269.5 (5)
C2—Fe1—C137.9 (5)C13—C14—C15107.3 (9)
C3—Fe1—C163.8 (5)C13—C14—Fe270.5 (5)
C4—Fe1—C166.0 (5)C15—C14—Fe269.2 (5)
C9—Fe1—C1147.7 (7)C14—C15—C11108.5 (10)
C5—Fe1—C10151.1 (8)C14—C15—Fe271.2 (5)
C7—Fe1—C1065.5 (4)C11—C15—Fe270.3 (5)
C6—Fe1—C1040.6 (5)C17—C16—C20108.8 (10)
C8—Fe1—C1065.1 (4)C17—C16—Fe270.7 (5)
C2—Fe1—C10136.0 (7)C20—C16—Fe270.6 (5)
C3—Fe1—C10117.1 (5)C16—C17—C18105.9 (9)
C4—Fe1—C10122.2 (6)C16—C17—Fe269.8 (5)
C9—Fe1—C1038.7 (4)C18—C17—Fe270.6 (5)
C1—Fe1—C10169.2 (8)C19—C18—C17108.3 (9)
C12—Fe2—C1565.4 (4)C19—C18—Fe270.9 (5)
C12—Fe2—C1139.0 (4)C17—C18—Fe269.3 (5)
C15—Fe2—C1139.8 (4)C20—C19—C18109.1 (9)
C12—Fe2—C16123.3 (5)C20—C19—Fe269.9 (6)
C15—Fe2—C16125.2 (4)C18—C19—Fe270.5 (5)
C11—Fe2—C16108.7 (4)C19—C20—C16107.8 (9)
C12—Fe2—C17109.8 (4)C19—C20—Fe271.6 (5)
C15—Fe2—C17160.1 (5)C16—C20—Fe269.6 (5)
C5—Fe1—C1—C2118.1 (13)C1—Fe1—C10—C615 (3)
C7—Fe1—C1—C2110.3 (11)C15—Fe2—C11—C12116.7 (9)
C6—Fe1—C1—C273.8 (11)C16—Fe2—C11—C12120.3 (7)
C8—Fe1—C1—C2150.7 (10)C17—Fe2—C11—C1279.3 (7)
C3—Fe1—C1—C236.3 (9)C20—Fe2—C11—C12161.9 (6)
C4—Fe1—C1—C280.2 (10)C13—Fe2—C11—C1236.8 (6)
C9—Fe1—C1—C2179.0 (9)C14—Fe2—C11—C1279.2 (7)
C10—Fe1—C1—C261 (3)C18—Fe2—C11—C1250.7 (15)
C7—Fe1—C1—C5131.6 (9)C19—Fe2—C11—C12169.0 (9)
C6—Fe1—C1—C5168.1 (8)C12—Fe2—C11—C15116.7 (9)
C8—Fe1—C1—C591.2 (9)C16—Fe2—C11—C15123.0 (7)
C2—Fe1—C1—C5118.1 (13)C17—Fe2—C11—C15164.0 (6)
C3—Fe1—C1—C581.8 (9)C20—Fe2—C11—C1581.4 (8)
C4—Fe1—C1—C537.9 (8)C13—Fe2—C11—C1579.9 (7)
C9—Fe1—C1—C560.9 (13)C14—Fe2—C11—C1537.5 (6)
C10—Fe1—C1—C5179 (2)C18—Fe2—C11—C15167.4 (10)
C5—C1—C2—C32.7 (14)C19—Fe2—C11—C1552.3 (14)
Fe1—C1—C2—C361.4 (9)Fe2—C11—C12—C1361.0 (7)
C5—C1—C2—Fe158.7 (8)C15—C11—C12—Fe260.9 (7)
C5—Fe1—C2—C381.0 (10)C15—Fe2—C12—C1139.0 (6)
C7—Fe1—C2—C3155.3 (10)C16—Fe2—C12—C1178.2 (8)
C6—Fe1—C2—C3113.9 (11)C17—Fe2—C12—C11120.1 (7)
C8—Fe1—C2—C3170.3 (9)C20—Fe2—C12—C1143.3 (13)
C4—Fe1—C2—C337.4 (9)C13—Fe2—C12—C11119.8 (9)
C9—Fe1—C2—C355 (6)C14—Fe2—C12—C1182.7 (7)
C1—Fe1—C2—C3119.4 (14)C18—Fe2—C12—C11161.7 (6)
C10—Fe1—C2—C374.3 (12)C19—Fe2—C12—C11166.1 (12)
C5—Fe1—C2—C138.4 (9)C15—Fe2—C12—C1380.8 (6)
C7—Fe1—C2—C185.3 (11)C11—Fe2—C12—C13119.8 (9)
C6—Fe1—C2—C1126.7 (11)C16—Fe2—C12—C13162.0 (6)
C8—Fe1—C2—C150.9 (14)C17—Fe2—C12—C13120.1 (6)
C3—Fe1—C2—C1119.4 (14)C20—Fe2—C12—C13163.2 (9)
C4—Fe1—C2—C182.0 (10)C14—Fe2—C12—C1337.2 (5)
C9—Fe1—C2—C1174 (5)C18—Fe2—C12—C1378.5 (7)
C10—Fe1—C2—C1166.3 (9)C19—Fe2—C12—C1346.3 (15)
C1—C2—C3—C41.5 (15)Fe2—C12—C13—C1460.7 (6)
Fe1—C2—C3—C460.0 (9)C11—C12—C13—Fe260.6 (7)
C1—C2—C3—Fe161.5 (9)C12—Fe2—C13—C14118.6 (8)
C5—Fe1—C3—C280.8 (10)C15—Fe2—C13—C1438.1 (6)
C7—Fe1—C3—C244.8 (15)C11—Fe2—C13—C1481.9 (7)
C6—Fe1—C3—C284.7 (11)C16—Fe2—C13—C14162.4 (10)
C8—Fe1—C3—C2120 (6)C17—Fe2—C13—C14162.0 (6)
C4—Fe1—C3—C2120.0 (13)C20—Fe2—C13—C1441.4 (14)
C9—Fe1—C3—C2173.0 (9)C18—Fe2—C13—C14118.3 (6)
C1—Fe1—C3—C236.6 (9)C19—Fe2—C13—C1477.3 (7)
C10—Fe1—C3—C2131.3 (11)C15—Fe2—C13—C1280.5 (7)
C5—Fe1—C3—C439.2 (8)C11—Fe2—C13—C1236.7 (6)
C7—Fe1—C3—C4164.8 (10)C16—Fe2—C13—C1243.8 (13)
C6—Fe1—C3—C4155.3 (10)C17—Fe2—C13—C1279.4 (7)
C2—Fe1—C3—C4120.0 (13)C20—Fe2—C13—C12160.0 (11)
C9—Fe1—C3—C467.1 (12)C14—Fe2—C13—C12118.6 (8)
C1—Fe1—C3—C483.3 (9)C18—Fe2—C13—C12123.1 (6)
C10—Fe1—C3—C4108.7 (11)C19—Fe2—C13—C12164.1 (6)
Fe1—C3—C4—C560.0 (8)Fe2—C13—C14—C1559.7 (6)
C2—C3—C4—Fe160.4 (9)C12—C13—C14—Fe259.8 (6)
C7—Fe1—C4—C521 (3)C12—Fe2—C14—C1337.5 (6)
C6—Fe1—C4—C5168.4 (11)C15—Fe2—C14—C13118.1 (9)
C8—Fe1—C4—C564.6 (11)C11—Fe2—C14—C1380.4 (7)
C2—Fe1—C4—C579.9 (9)C16—Fe2—C14—C13159.5 (12)
C3—Fe1—C4—C5115.4 (12)C17—Fe2—C14—C1344.0 (14)
C9—Fe1—C4—C5106.3 (10)C20—Fe2—C14—C13164.8 (6)
C1—Fe1—C4—C538.1 (8)C18—Fe2—C14—C1382.2 (7)
C10—Fe1—C4—C5149.8 (10)C19—Fe2—C14—C13123.7 (6)
C5—Fe1—C4—C3115.4 (12)C12—Fe2—C14—C1580.6 (7)
C7—Fe1—C4—C3136 (3)C11—Fe2—C14—C1537.8 (7)
C6—Fe1—C4—C353.0 (15)C16—Fe2—C14—C1541.3 (16)
C8—Fe1—C4—C3180.0 (10)C17—Fe2—C14—C15162.1 (10)
C2—Fe1—C4—C335.5 (8)C20—Fe2—C14—C1577.1 (8)
C9—Fe1—C4—C3138.3 (10)C13—Fe2—C14—C15118.1 (9)
C1—Fe1—C4—C377.3 (9)C18—Fe2—C14—C15159.7 (7)
C10—Fe1—C4—C394.8 (11)C19—Fe2—C14—C15118.2 (7)
C3—C4—C5—C12.1 (13)Fe2—C14—C15—C1160.6 (7)
Fe1—C4—C5—C163.2 (8)C13—C14—C15—Fe260.5 (6)
C3—C4—C5—Fe161.2 (8)Fe2—C11—C15—C1461.3 (7)
C2—C1—C5—C43.0 (13)C12—C11—C15—Fe261.1 (6)
Fe1—C1—C5—C463.2 (8)C12—Fe2—C15—C1480.5 (7)
C2—C1—C5—Fe160.2 (8)C11—Fe2—C15—C14118.6 (10)
C7—Fe1—C5—C4174.6 (9)C16—Fe2—C15—C14164.9 (7)
C6—Fe1—C5—C4158.6 (16)C17—Fe2—C15—C14160.7 (11)
C8—Fe1—C5—C4136.2 (10)C20—Fe2—C15—C14123.1 (7)
C2—Fe1—C5—C481.1 (9)C13—Fe2—C15—C1437.3 (6)
C3—Fe1—C5—C439.4 (8)C18—Fe2—C15—C1450.5 (13)
C9—Fe1—C5—C494.5 (10)C19—Fe2—C15—C1482.7 (7)
C1—Fe1—C5—C4117.8 (11)C12—Fe2—C15—C1138.2 (6)
C10—Fe1—C5—C461.9 (13)C16—Fe2—C15—C1176.5 (8)
C7—Fe1—C5—C167.5 (10)C17—Fe2—C15—C1142.1 (15)
C6—Fe1—C5—C141 (2)C20—Fe2—C15—C11118.3 (7)
C8—Fe1—C5—C1105.9 (10)C13—Fe2—C15—C1181.3 (7)
C2—Fe1—C5—C136.8 (8)C14—Fe2—C15—C11118.6 (10)
C3—Fe1—C5—C178.4 (9)C18—Fe2—C15—C11169.1 (9)
C4—Fe1—C5—C1117.8 (11)C19—Fe2—C15—C11158.7 (7)
C9—Fe1—C5—C1147.7 (9)C12—Fe2—C16—C1780.7 (7)
C10—Fe1—C5—C1179.8 (10)C15—Fe2—C16—C17162.4 (7)
C5—Fe1—C6—C734 (2)C11—Fe2—C16—C17121.3 (7)
C8—Fe1—C6—C736.4 (7)C20—Fe2—C16—C17119.1 (10)
C2—Fe1—C6—C7105.9 (10)C13—Fe2—C16—C1749.2 (13)
C3—Fe1—C6—C7146.5 (9)C14—Fe2—C16—C17166.7 (12)
C4—Fe1—C6—C7176.9 (11)C18—Fe2—C16—C1739.4 (6)
C9—Fe1—C6—C779.4 (7)C19—Fe2—C16—C1781.9 (7)
C1—Fe1—C6—C766.6 (10)C12—Fe2—C16—C20160.2 (6)
C10—Fe1—C6—C7117.0 (10)C15—Fe2—C16—C2078.5 (8)
C5—Fe1—C6—C10151.2 (17)C11—Fe2—C16—C20119.6 (7)
C7—Fe1—C6—C10117.0 (10)C17—Fe2—C16—C20119.1 (10)
C8—Fe1—C6—C1080.5 (7)C13—Fe2—C16—C20168.3 (9)
C2—Fe1—C6—C10137.2 (10)C14—Fe2—C16—C2047.6 (16)
C3—Fe1—C6—C1096.5 (10)C18—Fe2—C16—C2079.7 (7)
C4—Fe1—C6—C1060.0 (13)C19—Fe2—C16—C2037.2 (6)
C9—Fe1—C6—C1037.6 (7)C20—C16—C17—C181.2 (10)
C1—Fe1—C6—C10176.4 (9)Fe2—C16—C17—C1861.7 (6)
Fe1—C6—C7—C860.7 (7)C20—C16—C17—Fe260.5 (6)
C10—C6—C7—Fe161.7 (7)C12—Fe2—C17—C16118.8 (7)
C5—Fe1—C7—C6169.7 (9)C15—Fe2—C17—C1646.6 (15)
C8—Fe1—C7—C6119.9 (10)C11—Fe2—C17—C1677.8 (8)
C2—Fe1—C7—C691.4 (9)C20—Fe2—C17—C1637.5 (7)
C3—Fe1—C7—C662.8 (12)C13—Fe2—C17—C16160.0 (7)
C4—Fe1—C7—C6173 (2)C14—Fe2—C17—C16168.4 (10)
C9—Fe1—C7—C682.5 (8)C18—Fe2—C17—C16116.1 (9)
C1—Fe1—C7—C6131.4 (9)C19—Fe2—C17—C1679.6 (7)
C10—Fe1—C7—C639.6 (7)C12—Fe2—C17—C18125.1 (6)
C5—Fe1—C7—C870.5 (10)C15—Fe2—C17—C18162.7 (11)
C6—Fe1—C7—C8119.9 (10)C11—Fe2—C17—C18166.2 (6)
C2—Fe1—C7—C8148.7 (9)C16—Fe2—C17—C18116.1 (9)
C3—Fe1—C7—C8177.3 (9)C20—Fe2—C17—C1878.6 (7)
C4—Fe1—C7—C853 (3)C13—Fe2—C17—C1883.9 (7)
C9—Fe1—C7—C837.4 (7)C14—Fe2—C17—C1852.3 (14)
C1—Fe1—C7—C8108.7 (9)C19—Fe2—C17—C1836.5 (6)
C10—Fe1—C7—C880.2 (7)Fe2—C17—C18—C1960.4 (6)
Fe1—C7—C8—C961.1 (7)C16—C17—C18—Fe261.2 (6)
C6—C7—C8—Fe160.6 (7)C12—Fe2—C18—C19165.1 (6)
C5—Fe1—C8—C7129.4 (9)C15—Fe2—C18—C1945.0 (13)
C6—Fe1—C8—C736.3 (7)C11—Fe2—C18—C19157.1 (12)
C2—Fe1—C8—C754.9 (11)C16—Fe2—C18—C1980.4 (7)
C3—Fe1—C8—C7167 (5)C17—Fe2—C18—C19119.2 (8)
C4—Fe1—C8—C7167.0 (8)C20—Fe2—C18—C1936.5 (6)
C9—Fe1—C8—C7118.8 (9)C13—Fe2—C18—C19123.4 (7)
C1—Fe1—C8—C786.7 (9)C14—Fe2—C18—C1981.5 (7)
C10—Fe1—C8—C781.4 (8)C12—Fe2—C18—C1775.7 (7)
C5—Fe1—C8—C9111.8 (10)C15—Fe2—C18—C17164.1 (9)
C7—Fe1—C8—C9118.8 (9)C11—Fe2—C18—C1738.0 (15)
C6—Fe1—C8—C982.5 (8)C16—Fe2—C18—C1738.8 (6)
C2—Fe1—C8—C9173.6 (9)C20—Fe2—C18—C1782.7 (6)
C3—Fe1—C8—C974 (5)C13—Fe2—C18—C17117.5 (6)
C4—Fe1—C8—C974.2 (9)C14—Fe2—C18—C17159.3 (6)
C1—Fe1—C8—C9154.5 (9)C19—Fe2—C18—C17119.2 (8)
C10—Fe1—C8—C937.4 (7)Fe2—C18—C19—C2059.5 (6)
Fe1—C8—C9—C1061.1 (7)C17—C18—C19—Fe259.4 (6)
C7—C8—C9—Fe160.8 (7)C12—Fe2—C19—C20162.5 (12)
C5—Fe1—C9—C886.2 (9)C15—Fe2—C19—C2078.7 (7)
C7—Fe1—C9—C836.8 (6)C11—Fe2—C19—C2040.9 (14)
C6—Fe1—C9—C878.9 (7)C16—Fe2—C19—C2038.4 (6)
C2—Fe1—C9—C8140 (5)C17—Fe2—C19—C2081.9 (7)
C3—Fe1—C9—C8170.6 (9)C13—Fe2—C19—C20162.4 (6)
C4—Fe1—C9—C8130.3 (9)C14—Fe2—C19—C20121.4 (7)
C1—Fe1—C9—C846.6 (13)C18—Fe2—C19—C20119.9 (9)
C10—Fe1—C9—C8118.3 (10)C12—Fe2—C19—C1842.7 (15)
C5—Fe1—C9—C10155.5 (10)C15—Fe2—C19—C18161.5 (6)
C7—Fe1—C9—C1081.5 (8)C11—Fe2—C19—C18160.7 (10)
C6—Fe1—C9—C1039.4 (8)C16—Fe2—C19—C1881.4 (6)
C8—Fe1—C9—C10118.3 (10)C17—Fe2—C19—C1838.0 (5)
C2—Fe1—C9—C1022 (6)C20—Fe2—C19—C18119.9 (9)
C3—Fe1—C9—C1071.1 (12)C13—Fe2—C19—C1877.8 (7)
C4—Fe1—C9—C10111.4 (10)C14—Fe2—C19—C18118.7 (6)
C1—Fe1—C9—C10164.9 (11)Fe2—C19—C20—C1660.5 (7)
Fe1—C9—C10—C659.7 (7)C18—C19—C20—Fe259.9 (6)
C8—C9—C10—Fe160.6 (7)C17—C16—C20—C191.1 (11)
C7—C6—C10—C91.1 (12)Fe2—C16—C20—C1961.7 (6)
Fe1—C6—C10—C960.8 (7)C17—C16—C20—Fe260.6 (6)
C7—C6—C10—Fe161.9 (7)C12—Fe2—C20—C19166.2 (9)
C5—Fe1—C10—C948.8 (13)C15—Fe2—C20—C19120.5 (7)
C7—Fe1—C10—C979.9 (8)C11—Fe2—C20—C19162.8 (7)
C6—Fe1—C10—C9117.1 (10)C16—Fe2—C20—C19117.9 (9)
C8—Fe1—C10—C937.6 (7)C17—Fe2—C20—C1980.7 (6)
C2—Fe1—C10—C9177.0 (10)C13—Fe2—C20—C1948.4 (14)
C3—Fe1—C10—C9135.8 (10)C14—Fe2—C20—C1979.2 (7)
C4—Fe1—C10—C990.2 (10)C18—Fe2—C20—C1936.5 (6)
C1—Fe1—C10—C9132 (3)C12—Fe2—C20—C1648.3 (13)
C5—Fe1—C10—C6165.8 (10)C15—Fe2—C20—C16121.6 (7)
C7—Fe1—C10—C637.2 (6)C11—Fe2—C20—C1679.3 (8)
C8—Fe1—C10—C679.5 (7)C17—Fe2—C20—C1637.3 (6)
C2—Fe1—C10—C665.9 (11)C13—Fe2—C20—C16166.4 (10)
C3—Fe1—C10—C6107.2 (10)C14—Fe2—C20—C16162.9 (6)
C4—Fe1—C10—C6152.8 (10)C18—Fe2—C20—C1681.4 (7)
C9—Fe1—C10—C6117.1 (10)C19—Fe2—C20—C16117.9 (9)
Symmetry codes: (i) x+1, y+2, z; (ii) x, y, z+1.
 

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