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In the title compound, 1,4-dimethylpyridinium [4,5-dimercapto-1,3-dithiole-2-thione-S4,S5)(isothiocyanato)diphenylstannate(1-), (C7H10N)[Sn(NCS)(C6H5)2(C3S5)], the anion has distorted trigonal-bipyramidal coordination at the Sn atom, with the thiocyanato N and a thiolato S atom axial [Sn-N 2.262 (3), Sn-S 2.5917 (10) Å and N-Sn-S 164.58 (8)°]. The remaining thiolato S and two phenyl C atoms complete the equatorial coordination at Sn [Sn-S 2.4399 (10), and Sn-C 2.137 (4) and 2.139 (4) Å].

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 9715

fcf

Structure factor file (CIF format)
Contains datablock 9715

CCDC reference: 130527

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