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Reaction of carbazole with barium metal in dry tetrahydrofuran yields colourless blocks of the title compound, [Ba(C4H8O)5](C12H8N)2.C4H8O. The structure contains sevenfold-coordinated barium counter cations, which are surrounded by two carbazole monoanions and five tetrahydrofuran molecules in a C2 symmetric environment.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks Carbazole-barium, global

sft

Structure factor file (SHELXL table format)
Supplementary material

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Portable Document Format (PDF) file
Supplementary material

CCDC reference: 129003

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