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The title compound, hexacarbonyl-1[kappa]3C,2[kappa]3C-[mu]-dicyclohexylphosphido-1:2[kappa]2P-bis(dicyclohexylphosphine)-1[kappa]P,2[kappa]P-[mu]-hydrido-dirhenium(Re-Re), [Re2H(C12H22P)(C12H23P)2(CO)6], has an Re-Re bond length of 3.2185 (8) Å which is symmetrically bridged by a H and a P atom. Two terminal PH(C6H11)2 ligands adopt cis positions with respect to the phosphido bridge and have a mutually trans configuration.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, default

fcf

Structure factor file (CIF format)
Contains datablock s239

CCDC reference: 128616

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