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The title compounds, [Cu(C6H7NS)4][BF4] and [Ag(C6H7NS)4][BF4], are both mononuclear complexes in which the central metal(I) cation (MI) is surrounded by four donor S atoms of the ligands. The MIS4 unit adopts a distorted tetrahedral geometry.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, II, global

fcf

Structure factor file (CIF format)
Contains datablock I

fcf

Structure factor file (CIF format)
Contains datablock (II)

CCDC references: 127133; 127134

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