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In the title complex, {[Cu(C
12H
10N
2)
2]BF
4}
n, each copper(I) centre is tetrahedrally coordinated by N atoms from four bridging
trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (TPPE) ligands. The ligands bridge adjacent copper(I) centres to form one-dimensional folded chains. Adjacent uniform chains are further interlinked into a three-dimensional framework through weak C—H
F interactions.
Supporting information
CCDC reference: 277792
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.006 Å
- R factor = 0.046
- wR factor = 0.111
- Data-to-parameter ratio = 13.2
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ?
PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature 293 K
PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature . 293 K
PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for B1
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
5 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
0 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
2 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.
catena-Poly[[copper(I)-di-µ-
trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene-
κ2N2:
N4;
κ2N4:
N2]
tetrafluoroborate]
top
Crystal data top
[Cu(C12H10N2)2]BF4 | F(000) = 1048 |
Mr = 514.79 | Dx = 1.494 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 9.9969 (6) Å | Cell parameters from 10795 reflections |
b = 16.5736 (10) Å | θ = 3–23° |
c = 14.6322 (9) Å | µ = 1.01 mm−1 |
β = 109.248 (1)° | T = 293 K |
V = 2288.8 (2) Å3 | Block, dark red |
Z = 4 | 0.39 × 0.25 × 0.14 mm |
Data collection top
Bruker SMART CCD 1K area-detector diffractometer | 4045 independent reflections |
Radiation source: fine-focus sealed tube | 2273 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.047 |
Detector resolution: 100 pixels mm-1 | θmax = 25.0°, θmin = 1.9° |
φ and ω scans | h = −11→11 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −17→19 |
Tmin = 0.696, Tmax = 0.869 | l = −17→17 |
12314 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.046 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.111 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0457P)2] where P = (Fo2 + 2Fc2)/3 |
4045 reflections | (Δ/σ)max < 0.001 |
307 parameters | Δρmax = 0.38 e Å−3 |
0 restraints | Δρmin = −0.32 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Cu1 | 0.36504 (5) | 0.25142 (3) | 0.37368 (3) | 0.06085 (18) | |
N1 | 0.1581 (3) | 0.21134 (17) | 0.3140 (2) | 0.0529 (8) | |
N2 | 0.4761 (3) | −0.17416 (16) | 0.5516 (2) | 0.0506 (8) | |
C1 | 0.0651 (4) | 0.2693 (2) | 0.2702 (3) | 0.0638 (11) | |
H1A | 0.1014 | 0.3182 | 0.2579 | 0.077* | |
C2 | −0.0777 (4) | 0.2617 (2) | 0.2427 (3) | 0.0628 (11) | |
H2A | −0.1366 | 0.3044 | 0.2131 | 0.075* | |
C3 | −0.1338 (4) | 0.1895 (2) | 0.2595 (3) | 0.0572 (10) | |
H3A | −0.2312 | 0.1822 | 0.2419 | 0.069* | |
C4 | −0.0414 (4) | 0.1284 (2) | 0.3031 (2) | 0.0490 (9) | |
H4A | −0.0768 | 0.0791 | 0.3151 | 0.059* | |
C5 | 0.1026 (4) | 0.13966 (19) | 0.3291 (2) | 0.0459 (9) | |
C6 | 0.2040 (4) | 0.07448 (19) | 0.3701 (2) | 0.0486 (9) | |
H6A | 0.2887 | 0.0752 | 0.3568 | 0.058* | |
C7 | 0.1849 (4) | 0.0148 (2) | 0.4245 (2) | 0.0513 (9) | |
H7A | 0.1012 | 0.0152 | 0.4392 | 0.062* | |
C8 | 0.2832 (4) | −0.05203 (19) | 0.4638 (2) | 0.0464 (9) | |
C9 | 0.2741 (4) | −0.0952 (2) | 0.5420 (3) | 0.0629 (11) | |
H9A | 0.2016 | −0.0842 | 0.5669 | 0.075* | |
C10 | 0.3711 (4) | −0.1541 (2) | 0.5835 (3) | 0.0656 (11) | |
H10A | 0.3628 | −0.1815 | 0.6368 | 0.079* | |
C11 | 0.4811 (4) | −0.1350 (2) | 0.4733 (3) | 0.0535 (10) | |
H11A | 0.5509 | −0.1497 | 0.4472 | 0.064* | |
C12 | 0.3890 (4) | −0.0742 (2) | 0.4286 (3) | 0.0519 (9) | |
H12A | 0.3984 | −0.0483 | 0.3747 | 0.062* | |
N3 | 0.4063 (3) | 0.28007 (18) | 0.2433 (2) | 0.0573 (8) | |
N4 | 0.6260 (4) | 0.66026 (17) | 0.5260 (2) | 0.0541 (8) | |
C13 | 0.3884 (5) | 0.2196 (2) | 0.1801 (3) | 0.0677 (11) | |
H13A | 0.3334 | 0.1758 | 0.1857 | 0.081* | |
C14 | 0.4467 (5) | 0.2186 (3) | 0.1075 (3) | 0.0772 (13) | |
H14A | 0.4297 | 0.1758 | 0.0640 | 0.093* | |
C15 | 0.5300 (5) | 0.2816 (3) | 0.1007 (3) | 0.0815 (13) | |
H15A | 0.5732 | 0.2818 | 0.0532 | 0.098* | |
C16 | 0.5499 (4) | 0.3451 (2) | 0.1643 (3) | 0.0687 (12) | |
H16A | 0.6061 | 0.3887 | 0.1600 | 0.082* | |
C17 | 0.4858 (4) | 0.3434 (2) | 0.2346 (3) | 0.0551 (10) | |
C18 | 0.4904 (4) | 0.4130 (2) | 0.3017 (3) | 0.0606 (11) | |
H18A | 0.4095 | 0.4239 | 0.3177 | 0.073* | |
C19 | 0.6007 (5) | 0.4589 (2) | 0.3388 (3) | 0.0688 (11) | |
H19A | 0.6818 | 0.4469 | 0.3237 | 0.083* | |
C20 | 0.6072 (5) | 0.5288 (2) | 0.4034 (3) | 0.0572 (10) | |
C21 | 0.7346 (5) | 0.5579 (2) | 0.4598 (3) | 0.0682 (11) | |
H21A | 0.8179 | 0.5341 | 0.4579 | 0.082* | |
C22 | 0.7401 (5) | 0.6222 (2) | 0.5191 (3) | 0.0648 (11) | |
H22A | 0.8289 | 0.6407 | 0.5571 | 0.078* | |
C23 | 0.5005 (4) | 0.6334 (2) | 0.4690 (3) | 0.0555 (10) | |
H23A | 0.4193 | 0.6599 | 0.4707 | 0.067* | |
C24 | 0.4847 (4) | 0.5681 (2) | 0.4076 (3) | 0.0589 (10) | |
H24A | 0.3952 | 0.5506 | 0.3699 | 0.071* | |
B1 | 0.5483 (6) | −0.0098 (3) | 0.2181 (4) | 0.0737 (15) | |
F1 | 0.4152 (3) | 0.0041 (2) | 0.2198 (2) | 0.1280 (11) | |
F2 | 0.5481 (3) | −0.05683 (16) | 0.1409 (2) | 0.1010 (9) | |
F3 | 0.6225 (3) | −0.05003 (15) | 0.3033 (2) | 0.1138 (10) | |
F4 | 0.6183 (3) | 0.06071 (15) | 0.2170 (2) | 0.1156 (10) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Cu1 | 0.0582 (3) | 0.0462 (3) | 0.0687 (3) | 0.0017 (2) | 0.0081 (2) | 0.0021 (2) |
N1 | 0.0517 (19) | 0.0365 (16) | 0.062 (2) | −0.0026 (15) | 0.0079 (16) | 0.0050 (14) |
N2 | 0.055 (2) | 0.0389 (17) | 0.055 (2) | 0.0024 (14) | 0.0135 (16) | 0.0032 (15) |
C1 | 0.060 (3) | 0.039 (2) | 0.082 (3) | −0.0042 (18) | 0.009 (2) | 0.0092 (19) |
C2 | 0.056 (3) | 0.047 (3) | 0.076 (3) | 0.0091 (19) | 0.009 (2) | 0.0088 (19) |
C3 | 0.049 (2) | 0.051 (2) | 0.070 (3) | 0.0025 (19) | 0.018 (2) | 0.001 (2) |
C4 | 0.055 (2) | 0.038 (2) | 0.057 (2) | −0.0024 (17) | 0.021 (2) | 0.0007 (17) |
C5 | 0.055 (2) | 0.035 (2) | 0.044 (2) | 0.0009 (17) | 0.0107 (18) | −0.0021 (15) |
C6 | 0.048 (2) | 0.040 (2) | 0.053 (2) | −0.0028 (16) | 0.0114 (18) | 0.0010 (17) |
C7 | 0.048 (2) | 0.046 (2) | 0.060 (2) | 0.0008 (17) | 0.0175 (19) | 0.0022 (18) |
C8 | 0.048 (2) | 0.035 (2) | 0.053 (2) | −0.0016 (16) | 0.0134 (19) | 0.0001 (17) |
C9 | 0.059 (3) | 0.064 (3) | 0.076 (3) | 0.012 (2) | 0.035 (2) | 0.023 (2) |
C10 | 0.065 (3) | 0.067 (3) | 0.069 (3) | 0.008 (2) | 0.029 (2) | 0.025 (2) |
C11 | 0.054 (3) | 0.053 (2) | 0.054 (3) | 0.0069 (19) | 0.019 (2) | 0.0025 (19) |
C12 | 0.061 (3) | 0.051 (2) | 0.045 (2) | 0.0021 (19) | 0.0191 (19) | 0.0063 (18) |
N3 | 0.064 (2) | 0.0440 (18) | 0.053 (2) | −0.0012 (15) | 0.0046 (16) | 0.0052 (16) |
N4 | 0.056 (2) | 0.0474 (18) | 0.058 (2) | −0.0004 (16) | 0.0178 (17) | 0.0028 (15) |
C13 | 0.075 (3) | 0.049 (2) | 0.066 (3) | −0.004 (2) | 0.005 (2) | −0.002 (2) |
C14 | 0.094 (4) | 0.061 (3) | 0.071 (3) | 0.009 (3) | 0.019 (3) | −0.011 (2) |
C15 | 0.085 (4) | 0.086 (3) | 0.078 (3) | 0.019 (3) | 0.034 (3) | 0.002 (3) |
C16 | 0.066 (3) | 0.059 (3) | 0.080 (3) | 0.001 (2) | 0.023 (3) | 0.006 (2) |
C17 | 0.055 (3) | 0.047 (2) | 0.055 (3) | 0.0027 (19) | 0.007 (2) | 0.0084 (19) |
C18 | 0.066 (3) | 0.057 (3) | 0.054 (3) | −0.007 (2) | 0.013 (2) | 0.016 (2) |
C19 | 0.068 (3) | 0.071 (3) | 0.064 (3) | 0.002 (2) | 0.017 (2) | 0.012 (2) |
C20 | 0.082 (3) | 0.040 (2) | 0.054 (3) | 0.007 (2) | 0.030 (2) | 0.0084 (18) |
C21 | 0.065 (3) | 0.064 (3) | 0.073 (3) | 0.001 (2) | 0.019 (2) | −0.002 (2) |
C22 | 0.060 (3) | 0.060 (3) | 0.074 (3) | 0.002 (2) | 0.021 (2) | 0.004 (2) |
C23 | 0.062 (3) | 0.044 (2) | 0.059 (3) | 0.0043 (19) | 0.018 (2) | 0.0074 (19) |
C24 | 0.067 (3) | 0.058 (2) | 0.046 (2) | −0.007 (2) | 0.011 (2) | 0.0047 (19) |
B1 | 0.083 (4) | 0.054 (3) | 0.090 (4) | −0.004 (3) | 0.035 (3) | −0.002 (3) |
F1 | 0.093 (2) | 0.173 (3) | 0.136 (3) | 0.015 (2) | 0.062 (2) | 0.019 (2) |
F2 | 0.102 (2) | 0.101 (2) | 0.105 (2) | −0.0309 (16) | 0.0400 (18) | −0.0252 (17) |
F3 | 0.151 (3) | 0.0751 (18) | 0.106 (2) | 0.0160 (18) | 0.030 (2) | 0.0009 (16) |
F4 | 0.158 (3) | 0.0634 (17) | 0.149 (3) | −0.0358 (17) | 0.082 (2) | −0.0100 (16) |
Geometric parameters (Å, º) top
Cu1—N2i | 2.052 (3) | N3—C13 | 1.335 (5) |
Cu1—N4ii | 2.054 (3) | N3—C17 | 1.347 (4) |
Cu1—N1 | 2.072 (3) | N4—C23 | 1.334 (4) |
Cu1—N3 | 2.133 (3) | N4—C22 | 1.337 (5) |
N1—C1 | 1.343 (4) | N4—Cu1ii | 2.054 (3) |
N1—C5 | 1.360 (4) | C13—C14 | 1.369 (6) |
N2—C10 | 1.323 (4) | C13—H13A | 0.9300 |
N2—C11 | 1.332 (4) | C14—C15 | 1.361 (6) |
N2—Cu1i | 2.052 (3) | C14—H14A | 0.9300 |
C1—C2 | 1.356 (5) | C15—C16 | 1.375 (6) |
C1—H1A | 0.9300 | C15—H15A | 0.9300 |
C2—C3 | 1.378 (5) | C16—C17 | 1.380 (5) |
C2—H2A | 0.9300 | C16—H16A | 0.9300 |
C3—C4 | 1.377 (5) | C17—C18 | 1.506 (5) |
C3—H3A | 0.9300 | C18—C19 | 1.302 (5) |
C4—C5 | 1.376 (5) | C18—H18A | 0.9300 |
C4—H4A | 0.9300 | C19—C20 | 1.483 (5) |
C5—C6 | 1.467 (4) | C19—H19A | 0.9300 |
C6—C7 | 1.322 (4) | C20—C21 | 1.358 (5) |
C6—H6A | 0.9300 | C20—C24 | 1.405 (5) |
C7—C8 | 1.467 (5) | C21—C22 | 1.364 (5) |
C7—H7A | 0.9300 | C21—H21A | 0.9300 |
C8—C12 | 1.370 (5) | C22—H22A | 0.9300 |
C8—C9 | 1.377 (5) | C23—C24 | 1.382 (5) |
C9—C10 | 1.369 (5) | C23—H23A | 0.9300 |
C9—H9A | 0.9300 | C24—H24A | 0.9300 |
C10—H10A | 0.9300 | B1—F1 | 1.358 (6) |
C11—C12 | 1.377 (5) | B1—F4 | 1.365 (5) |
C11—H11A | 0.9300 | B1—F2 | 1.372 (6) |
C12—H12A | 0.9300 | B1—F3 | 1.393 (6) |
| | | |
N2i—Cu1—N4ii | 102.70 (12) | C13—N3—C17 | 117.9 (4) |
N2i—Cu1—N1 | 120.96 (11) | C13—N3—Cu1 | 115.5 (3) |
N4ii—Cu1—N1 | 109.40 (12) | C17—N3—Cu1 | 123.5 (3) |
N2i—Cu1—N3 | 105.74 (12) | C23—N4—C22 | 116.5 (3) |
N4ii—Cu1—N3 | 120.31 (11) | C23—N4—Cu1ii | 119.7 (3) |
N1—Cu1—N3 | 98.91 (11) | C22—N4—Cu1ii | 123.6 (3) |
C1—N1—C5 | 116.6 (3) | N3—C13—C14 | 123.5 (4) |
C1—N1—Cu1 | 114.2 (2) | N3—C13—H13A | 118.2 |
C5—N1—Cu1 | 128.0 (2) | C14—C13—H13A | 118.2 |
C10—N2—C11 | 116.1 (3) | C15—C14—C13 | 118.4 (4) |
C10—N2—Cu1i | 122.2 (3) | C15—C14—H14A | 120.8 |
C11—N2—Cu1i | 121.3 (3) | C13—C14—H14A | 120.8 |
N1—C1—C2 | 124.8 (3) | C14—C15—C16 | 119.5 (4) |
N1—C1—H1A | 117.6 | C14—C15—H15A | 120.2 |
C2—C1—H1A | 117.6 | C16—C15—H15A | 120.2 |
C1—C2—C3 | 118.5 (3) | C15—C16—C17 | 119.4 (4) |
C1—C2—H2A | 120.7 | C15—C16—H16A | 120.3 |
C3—C2—H2A | 120.7 | C17—C16—H16A | 120.3 |
C4—C3—C2 | 118.2 (4) | N3—C17—C16 | 121.3 (4) |
C4—C3—H3A | 120.9 | N3—C17—C18 | 115.3 (3) |
C2—C3—H3A | 120.9 | C16—C17—C18 | 123.3 (4) |
C3—C4—C5 | 120.6 (3) | C19—C18—C17 | 124.0 (4) |
C3—C4—H4A | 119.7 | C19—C18—H18A | 118.0 |
C5—C4—H4A | 119.7 | C17—C18—H18A | 118.0 |
N1—C5—C4 | 121.3 (3) | C18—C19—C20 | 125.1 (4) |
N1—C5—C6 | 116.5 (3) | C18—C19—H19A | 117.5 |
C4—C5—C6 | 122.2 (3) | C20—C19—H19A | 117.5 |
C7—C6—C5 | 125.4 (3) | C21—C20—C24 | 117.7 (4) |
C7—C6—H6A | 117.3 | C21—C20—C19 | 120.0 (4) |
C5—C6—H6A | 117.3 | C24—C20—C19 | 122.3 (4) |
C6—C7—C8 | 126.2 (3) | C20—C21—C22 | 119.8 (4) |
C6—C7—H7A | 116.9 | C20—C21—H21A | 120.1 |
C8—C7—H7A | 116.9 | C22—C21—H21A | 120.1 |
C12—C8—C9 | 116.3 (3) | N4—C22—C21 | 124.1 (4) |
C12—C8—C7 | 123.7 (3) | N4—C22—H22A | 118.0 |
C9—C8—C7 | 119.9 (3) | C21—C22—H22A | 118.0 |
C10—C9—C8 | 120.5 (4) | N4—C23—C24 | 123.4 (4) |
C10—C9—H9A | 119.8 | N4—C23—H23A | 118.3 |
C8—C9—H9A | 119.8 | C24—C23—H23A | 118.3 |
N2—C10—C9 | 123.5 (3) | C23—C24—C20 | 118.5 (4) |
N2—C10—H10A | 118.3 | C23—C24—H24A | 120.7 |
C9—C10—H10A | 118.3 | C20—C24—H24A | 120.7 |
N2—C11—C12 | 123.7 (3) | F1—B1—F4 | 111.3 (4) |
N2—C11—H11A | 118.1 | F1—B1—F2 | 112.0 (5) |
C12—C11—H11A | 118.1 | F4—B1—F2 | 109.8 (4) |
C8—C12—C11 | 119.8 (3) | F1—B1—F3 | 107.5 (4) |
C8—C12—H12A | 120.1 | F4—B1—F3 | 107.2 (5) |
C11—C12—H12A | 120.1 | F2—B1—F3 | 108.7 (4) |
| | | |
N2i—Cu1—N1—C1 | 177.8 (3) | N2i—Cu1—N3—C13 | 68.9 (3) |
N4ii—Cu1—N1—C1 | 58.9 (3) | N4ii—Cu1—N3—C13 | −175.7 (3) |
N3—Cu1—N1—C1 | −67.8 (3) | N1—Cu1—N3—C13 | −56.9 (3) |
N2i—Cu1—N1—C5 | 11.2 (3) | N2i—Cu1—N3—C17 | −90.7 (3) |
N4ii—Cu1—N1—C5 | −107.7 (3) | N4ii—Cu1—N3—C17 | 24.7 (3) |
N3—Cu1—N1—C5 | 125.7 (3) | N1—Cu1—N3—C17 | 143.5 (3) |
C5—N1—C1—C2 | 1.5 (6) | C17—N3—C13—C14 | 0.2 (6) |
Cu1—N1—C1—C2 | −166.6 (3) | Cu1—N3—C13—C14 | −160.6 (3) |
N1—C1—C2—C3 | −0.5 (6) | N3—C13—C14—C15 | 1.6 (7) |
C1—C2—C3—C4 | −0.4 (6) | C13—C14—C15—C16 | −1.9 (7) |
C2—C3—C4—C5 | 0.1 (5) | C14—C15—C16—C17 | 0.5 (7) |
C1—N1—C5—C4 | −1.7 (5) | C13—N3—C17—C16 | −1.7 (5) |
Cu1—N1—C5—C4 | 164.5 (3) | Cu1—N3—C17—C16 | 157.5 (3) |
C1—N1—C5—C6 | 175.5 (3) | C13—N3—C17—C18 | 174.4 (3) |
Cu1—N1—C5—C6 | −18.2 (4) | Cu1—N3—C17—C18 | −26.5 (4) |
C3—C4—C5—N1 | 1.0 (5) | C15—C16—C17—N3 | 1.4 (6) |
C3—C4—C5—C6 | −176.1 (3) | C15—C16—C17—C18 | −174.3 (4) |
N1—C5—C6—C7 | 151.5 (3) | N3—C17—C18—C19 | 146.0 (4) |
C4—C5—C6—C7 | −31.3 (5) | C16—C17—C18—C19 | −38.1 (6) |
C5—C6—C7—C8 | 178.2 (3) | C17—C18—C19—C20 | 178.7 (3) |
C6—C7—C8—C12 | −18.8 (6) | C18—C19—C20—C21 | 161.0 (4) |
C6—C7—C8—C9 | 159.7 (4) | C18—C19—C20—C24 | −20.4 (6) |
C12—C8—C9—C10 | 3.0 (6) | C24—C20—C21—C22 | 1.3 (6) |
C7—C8—C9—C10 | −175.6 (4) | C19—C20—C21—C22 | 180.0 (3) |
C11—N2—C10—C9 | −2.0 (6) | C23—N4—C22—C21 | −1.3 (5) |
Cu1i—N2—C10—C9 | 171.4 (3) | Cu1ii—N4—C22—C21 | 172.9 (3) |
C8—C9—C10—N2 | −1.0 (7) | C20—C21—C22—N4 | −0.4 (6) |
C10—N2—C11—C12 | 3.1 (5) | C22—N4—C23—C24 | 2.1 (5) |
Cu1i—N2—C11—C12 | −170.3 (3) | Cu1ii—N4—C23—C24 | −172.4 (3) |
C9—C8—C12—C11 | −1.9 (5) | N4—C23—C24—C20 | −1.2 (5) |
C7—C8—C12—C11 | 176.6 (3) | C21—C20—C24—C23 | −0.6 (5) |
N2—C11—C12—C8 | −1.2 (6) | C19—C20—C24—C23 | −179.2 (3) |
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+1, −y+1, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
C12—H12A···F1 | 0.93 | 2.48 | 3.409 (5) | 173 |
C22—H22A···F2iii | 0.93 | 2.54 | 3.195 (5) | 128 |
C2—H2A···F3iv | 0.93 | 2.43 | 3.192 (4) | 139 |
C3—H3A···F4v | 0.93 | 2.47 | 3.174 (5) | 133 |
Symmetry codes: (iii) x+1/2, −y+1/2, z+1/2; (iv) −x+1/2, y+1/2, −z+1/2; (v) x−1, y, z. |
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