Bis[4-bromo-2-(pyridin-2-ylmethyl­imino­methyl)phenolato]manganese(III) nitrate

The title compound, [Mn(C₁₃H₁₀BrN₂O)₂]NO₃, consists of a mononuclear manganese(III) complex cation and a nitrate anion. In the cation, the Mn^III atom is coordinated by four N atoms and two O atoms from two tridentate Schiff base ligands, forming an octa­hedral complex.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](C-C) = 0.006 Å
• Disorder in solvent or counterion
• R factor = 0.046
• wR factor = 0.125
• Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         N5
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      43.00 Perc.
PLAT431_ALERT_2_C Short Inter HL..A Contact  Br1    ..  Br2     ..       3.53 Ang.
PLAT432_ALERT_2_C Short Inter X...Y Contact  C7     ..  O5'     ..       2.97 Ang.
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         14
            N3  -MN1 -N1  -C8    166.00  3.00   1.555   1.555   1.555   1.555

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

Bis[4-Bromo-2-(pyridin-2-ylmethyliminomethyl)phenolato]manganese(III) nitrate

Crystal data

[Mn(C13H10BrN2O)2]NO3	Dx = 1.734 Mg m^−3
Mr = 697.23	Mo Kα radiation, λ = 0.71073 Å
Tetragonal, P42/n	Cell parameters from 8655 reflections
Hall symbol: -P 4bc	θ = 2.3–21.7°
a = 17.608 (3) Å	µ = 3.53 mm^−1
c = 17.224 (3) Å	T = 298 K
V = 5340.2 (16) Å^3	Block, brown
Z = 8	0.23 × 0.21 × 0.17 mm
F(000) = 2768

Data collection

Bruker SMART CCD area-detector diffractometer	6135 independent reflections
Radiation source: fine-focus sealed tube	3995 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.067
ω scans	θmax = 27.5°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −22→22
Tmin = 0.466, Tmax = 0.548	k = −22→22
60512 measured reflections	l = −22→22

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.125	H-atom parameters constrained
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0504P)^2 + 7.176P] where P = (Fo^2 + 2Fc^2)/3
6135 reflections	(Δ/σ)max < 0.001
380 parameters	Δρmax = 0.90 e Å^−3
36 restraints	Δρmin = −0.66 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Mn1	0.49193 (3)	0.67507 (3)	0.23975 (3)	0.03109 (14)
Br1	0.64021 (4)	0.67760 (4)	0.63262 (3)	0.0830 (2)
Br2	0.59045 (3)	0.64660 (3)	−0.17137 (3)	0.06481 (17)
O1	0.58272 (16)	0.70387 (16)	0.28947 (17)	0.0498 (7)
O2	0.54479 (16)	0.60704 (15)	0.17321 (16)	0.0478 (7)
O3	0.3606 (17)	0.8085 (18)	0.0208 (19)	0.105 (7)	0.51 (5)
O4	0.4357 (17)	0.9011 (8)	0.0417 (13)	0.111 (6)	0.51 (5)
O5	0.4428 (16)	0.8397 (16)	−0.0612 (10)	0.092 (6)	0.51 (5)
O3'	0.365 (2)	0.7977 (19)	−0.0047 (18)	0.091 (6)	0.49 (5)
O4'	0.4057 (15)	0.8877 (15)	0.0624 (12)	0.109 (7)	0.49 (5)
O5'	0.4578 (16)	0.862 (2)	−0.0454 (18)	0.136 (10)	0.49 (5)
N1	0.47677 (18)	0.59266 (18)	0.30850 (19)	0.0409 (7)
N2	0.39661 (19)	0.63972 (19)	0.19428 (19)	0.0447 (8)
N3	0.50885 (18)	0.75980 (17)	0.17439 (18)	0.0411 (8)
N4	0.43491 (18)	0.74906 (18)	0.30143 (19)	0.0420 (8)
N5	0.4109 (2)	0.8498 (3)	0.0021 (3)	0.0657 (11)
C1	0.5570 (2)	0.6395 (2)	0.4103 (2)	0.0428 (9)
C2	0.5924 (2)	0.6960 (2)	0.3643 (2)	0.0431 (9)
C3	0.6424 (2)	0.7455 (2)	0.4027 (3)	0.0544 (11)
H3	0.6676	0.7827	0.3743	0.065*
C4	0.6549 (3)	0.7401 (3)	0.4811 (3)	0.0581 (12)
H4	0.6874	0.7744	0.5054	0.070*
C5	0.6197 (3)	0.6841 (3)	0.5242 (3)	0.0527 (11)
C6	0.5719 (2)	0.6340 (2)	0.4901 (3)	0.0493 (10)
H6	0.5490	0.5960	0.5195	0.059*
C7	0.5056 (2)	0.5848 (2)	0.3760 (2)	0.0445 (10)
H7	0.4929	0.5418	0.4046	0.053*
C8	0.4265 (3)	0.5343 (2)	0.2774 (3)	0.0508 (11)
H8A	0.3984	0.5104	0.3192	0.061*
H8B	0.4559	0.4956	0.2510	0.061*
C9	0.3728 (2)	0.5717 (2)	0.2216 (2)	0.0470 (10)
C10	0.3051 (3)	0.5410 (3)	0.1991 (3)	0.0626 (13)
H10	0.2892	0.4945	0.2190	0.075*
C11	0.2605 (3)	0.5798 (3)	0.1465 (3)	0.0729 (15)
H11	0.2141	0.5598	0.1306	0.088*
C12	0.2851 (3)	0.6476 (3)	0.1182 (3)	0.0710 (15)
H12	0.2560	0.6739	0.0821	0.085*
C13	0.3530 (3)	0.6768 (3)	0.1431 (3)	0.0576 (12)
H13	0.3692	0.7234	0.1240	0.069*
C14	0.5478 (2)	0.6906 (2)	0.0617 (2)	0.0415 (9)
C15	0.5535 (2)	0.6183 (2)	0.0986 (2)	0.0423 (9)
C16	0.5720 (3)	0.5567 (2)	0.0502 (3)	0.0557 (11)
H16	0.5769	0.5088	0.0723	0.067*
C17	0.5831 (3)	0.5643 (3)	−0.0278 (3)	0.0585 (12)
H17	0.5955	0.5221	−0.0577	0.070*
C18	0.5759 (2)	0.6351 (3)	−0.0625 (2)	0.0495 (10)
C19	0.5596 (2)	0.6974 (2)	−0.0187 (2)	0.0459 (10)
H19	0.5563	0.7449	−0.0422	0.055*
C20	0.5326 (2)	0.7587 (2)	0.1044 (2)	0.0423 (9)
H20	0.5404	0.8049	0.0796	0.051*
C21	0.4996 (3)	0.8324 (2)	0.2143 (2)	0.0483 (10)
H21A	0.4820	0.8709	0.1783	0.058*
H21B	0.5478	0.8489	0.2359	0.058*
C22	0.4428 (2)	0.8214 (2)	0.2776 (2)	0.0452 (10)
C23	0.4009 (3)	0.8789 (3)	0.3093 (3)	0.0603 (12)
H23	0.4061	0.9283	0.2908	0.072*
C24	0.3509 (3)	0.8633 (3)	0.3686 (3)	0.0690 (14)
H24	0.3221	0.9018	0.3911	0.083*
C25	0.3445 (3)	0.7899 (3)	0.3939 (3)	0.0655 (13)
H25	0.3120	0.7780	0.4347	0.079*
C26	0.3859 (3)	0.7344 (3)	0.3589 (3)	0.0526 (11)
H26	0.3799	0.6845	0.3755	0.063*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mn1	0.0339 (3)	0.0276 (3)	0.0318 (3)	−0.0014 (2)	0.0009 (2)	0.0054 (2)
Br1	0.0910 (4)	0.1053 (5)	0.0526 (3)	0.0109 (3)	−0.0146 (3)	−0.0164 (3)
Br2	0.0769 (4)	0.0714 (3)	0.0461 (3)	−0.0089 (3)	0.0071 (2)	−0.0095 (2)
O1	0.0453 (16)	0.0540 (18)	0.0502 (17)	−0.0099 (13)	−0.0031 (13)	0.0125 (14)
O2	0.0541 (17)	0.0412 (16)	0.0482 (17)	0.0065 (13)	0.0055 (13)	0.0086 (13)
O3	0.066 (9)	0.135 (19)	0.113 (18)	−0.010 (9)	0.036 (12)	0.048 (11)
O4	0.121 (10)	0.088 (7)	0.123 (9)	0.016 (6)	−0.036 (7)	0.000 (6)
O5	0.117 (14)	0.092 (11)	0.067 (8)	0.035 (8)	0.026 (7)	0.026 (7)
O3'	0.091 (15)	0.098 (9)	0.085 (13)	−0.020 (9)	−0.003 (8)	−0.008 (10)
O4'	0.094 (12)	0.135 (13)	0.100 (10)	0.029 (9)	−0.023 (8)	−0.047 (9)
O5'	0.081 (10)	0.14 (2)	0.19 (2)	0.022 (10)	0.065 (15)	0.097 (15)
N1	0.0424 (18)	0.0374 (18)	0.0430 (18)	−0.0043 (14)	0.0018 (15)	0.0049 (14)
N2	0.0424 (19)	0.048 (2)	0.0436 (18)	0.0001 (15)	0.0001 (15)	0.0005 (16)
N3	0.0470 (19)	0.0331 (17)	0.0431 (19)	−0.0001 (14)	0.0024 (15)	0.0039 (14)
N4	0.0407 (19)	0.044 (2)	0.0412 (18)	−0.0039 (15)	0.0012 (15)	0.0006 (15)
N5	0.054 (3)	0.070 (3)	0.073 (3)	0.013 (2)	−0.009 (3)	0.020 (3)
C1	0.043 (2)	0.041 (2)	0.045 (2)	0.0025 (18)	−0.0001 (18)	0.0030 (18)
C2	0.039 (2)	0.038 (2)	0.052 (2)	0.0022 (17)	0.0003 (18)	0.0013 (18)
C3	0.047 (3)	0.047 (3)	0.069 (3)	−0.006 (2)	−0.006 (2)	0.001 (2)
C4	0.047 (3)	0.059 (3)	0.069 (3)	0.001 (2)	−0.013 (2)	−0.017 (2)
C5	0.048 (3)	0.062 (3)	0.047 (2)	0.011 (2)	−0.006 (2)	−0.008 (2)
C6	0.050 (3)	0.049 (3)	0.049 (2)	0.007 (2)	0.001 (2)	0.001 (2)
C7	0.048 (2)	0.039 (2)	0.046 (2)	0.0005 (18)	0.0038 (19)	0.0063 (18)
C8	0.059 (3)	0.037 (2)	0.056 (3)	−0.0104 (19)	−0.002 (2)	0.0039 (19)
C9	0.048 (2)	0.045 (2)	0.048 (2)	−0.0052 (19)	0.0023 (19)	−0.0033 (19)
C10	0.057 (3)	0.058 (3)	0.073 (3)	−0.011 (2)	0.000 (3)	−0.007 (3)
C11	0.050 (3)	0.079 (4)	0.090 (4)	−0.008 (3)	−0.018 (3)	−0.008 (3)
C12	0.061 (3)	0.075 (4)	0.077 (4)	0.006 (3)	−0.021 (3)	0.003 (3)
C13	0.053 (3)	0.060 (3)	0.059 (3)	0.003 (2)	−0.008 (2)	0.005 (2)
C14	0.042 (2)	0.039 (2)	0.044 (2)	−0.0001 (17)	0.0021 (17)	0.0001 (17)
C15	0.040 (2)	0.042 (2)	0.045 (2)	−0.0029 (17)	0.0010 (18)	−0.0010 (18)
C16	0.066 (3)	0.038 (2)	0.063 (3)	0.000 (2)	0.004 (2)	−0.001 (2)
C17	0.069 (3)	0.051 (3)	0.056 (3)	−0.001 (2)	0.008 (2)	−0.013 (2)
C18	0.050 (3)	0.054 (3)	0.044 (2)	−0.007 (2)	0.0024 (19)	−0.003 (2)
C19	0.046 (2)	0.043 (2)	0.048 (2)	−0.0025 (18)	0.0051 (19)	0.0023 (19)
C20	0.047 (2)	0.038 (2)	0.043 (2)	−0.0007 (18)	0.0007 (18)	0.0073 (17)
C21	0.066 (3)	0.034 (2)	0.045 (2)	−0.005 (2)	0.004 (2)	−0.0015 (18)
C22	0.051 (2)	0.040 (2)	0.044 (2)	−0.0035 (19)	−0.0023 (19)	−0.0015 (18)
C23	0.069 (3)	0.042 (2)	0.070 (3)	0.005 (2)	0.003 (3)	−0.007 (2)
C24	0.059 (3)	0.067 (3)	0.081 (4)	0.008 (3)	0.016 (3)	−0.017 (3)
C25	0.062 (3)	0.068 (3)	0.067 (3)	−0.004 (3)	0.018 (3)	−0.007 (3)
C26	0.054 (3)	0.050 (3)	0.054 (3)	−0.007 (2)	0.007 (2)	−0.001 (2)

Geometric parameters (Å, º)

Mn1—O1	1.883 (3)	C7—H7	0.9300
Mn1—N1	1.892 (3)	C8—C9	1.500 (6)
Mn1—N3	1.893 (3)	C8—H8A	0.9700
Mn1—O2	1.901 (3)	C8—H8B	0.9700
Mn1—N2	1.954 (3)	C9—C10	1.365 (6)
Mn1—N4	1.958 (3)	C10—C11	1.380 (7)
Br1—C5	1.905 (4)	C10—H10	0.9300
Br2—C18	1.903 (4)	C11—C12	1.360 (8)
O1—C2	1.307 (5)	C11—H11	0.9300
O2—C15	1.309 (5)	C12—C13	1.371 (7)
O3—N5	1.191 (10)	C12—H12	0.9300
O4—N5	1.212 (10)	C13—H13	0.9300
O5—N5	1.240 (10)	C14—C19	1.405 (6)
O3'—N5	1.229 (11)	C14—C15	1.426 (5)
O4'—N5	1.237 (10)	C14—C20	1.432 (5)
O5'—N5	1.182 (11)	C15—C16	1.406 (6)
N1—C7	1.276 (5)	C16—C17	1.366 (6)
N1—C8	1.457 (5)	C16—H16	0.9300
N2—C13	1.338 (5)	C17—C18	1.388 (6)
N2—C9	1.354 (5)	C17—H17	0.9300
N3—C20	1.276 (5)	C18—C19	1.363 (6)
N3—C21	1.461 (5)	C19—H19	0.9300
N4—C26	1.339 (5)	C20—H20	0.9300
N4—C22	1.344 (5)	C21—C22	1.493 (6)
C1—C6	1.404 (6)	C21—H21A	0.9700
C1—C2	1.417 (6)	C21—H21B	0.9700
C1—C7	1.448 (6)	C22—C23	1.368 (6)
C2—C3	1.404 (6)	C23—C24	1.377 (7)
C3—C4	1.372 (7)	C23—H23	0.9300
C3—H3	0.9300	C24—C25	1.369 (7)
C4—C5	1.382 (7)	C24—H24	0.9300
C4—H4	0.9300	C25—C26	1.359 (6)
C5—C6	1.354 (6)	C25—H25	0.9300
C6—H6	0.9300	C26—H26	0.9300
O1—Mn1—N1	92.39 (13)	N1—C8—H8A	110.1
O1—Mn1—N3	85.68 (13)	C9—C8—H8A	110.1
N1—Mn1—N3	177.65 (14)	N1—C8—H8B	110.1
O1—Mn1—O2	91.62 (13)	C9—C8—H8B	110.1
N1—Mn1—O2	87.88 (13)	H8A—C8—H8B	108.4
N3—Mn1—O2	93.50 (13)	N2—C9—C10	121.5 (4)
O1—Mn1—N2	175.77 (13)	N2—C9—C8	114.6 (4)
N1—Mn1—N2	83.41 (14)	C10—C9—C8	124.0 (4)
N3—Mn1—N2	98.51 (14)	C9—C10—C11	119.1 (5)
O2—Mn1—N2	88.75 (13)	C9—C10—H10	120.4
O1—Mn1—N4	90.54 (13)	C11—C10—H10	120.4
N1—Mn1—N4	95.65 (14)	C12—C11—C10	119.3 (5)
N3—Mn1—N4	83.05 (14)	C12—C11—H11	120.4
O2—Mn1—N4	175.78 (13)	C10—C11—H11	120.4
N2—Mn1—N4	89.37 (14)	C11—C12—C13	119.7 (5)
C2—O1—Mn1	122.0 (3)	C11—C12—H12	120.2
C15—O2—Mn1	123.6 (2)	C13—C12—H12	120.2
C7—N1—C8	120.0 (3)	N2—C13—C12	121.6 (5)
C7—N1—Mn1	126.7 (3)	N2—C13—H13	119.2
C8—N1—Mn1	113.4 (3)	C12—C13—H13	119.2
C13—N2—C9	118.9 (4)	C19—C14—C15	120.4 (4)
C13—N2—Mn1	126.9 (3)	C19—C14—C20	117.5 (4)
C9—N2—Mn1	114.1 (3)	C15—C14—C20	122.1 (4)
C20—N3—C21	119.6 (3)	O2—C15—C16	119.5 (4)
C20—N3—Mn1	127.0 (3)	O2—C15—C14	124.4 (4)
C21—N3—Mn1	113.1 (2)	C16—C15—C14	116.1 (4)
C26—N4—C22	118.3 (4)	C17—C16—C15	122.8 (4)
C26—N4—Mn1	127.2 (3)	C17—C16—H16	118.6
C22—N4—Mn1	114.3 (3)	C15—C16—H16	118.6
O5'—N5—O3	144.9 (15)	C16—C17—C18	119.9 (4)
O5'—N5—O4	90.1 (13)	C16—C17—H17	120.0
O3—N5—O4	124.8 (11)	C18—C17—H17	120.0
O5'—N5—O3'	122.1 (12)	C19—C18—C17	120.2 (4)
O4—N5—O3'	147.8 (12)	C19—C18—Br2	119.2 (3)
O5'—N5—O4'	122.2 (11)	C17—C18—Br2	120.5 (3)
O3—N5—O4'	92.8 (13)	C18—C19—C14	120.5 (4)
O3'—N5—O4'	115.7 (11)	C18—C19—H19	119.7
O3—N5—O5	119.1 (11)	C14—C19—H19	119.7
O4—N5—O5	116.1 (10)	N3—C20—C14	124.0 (4)
O3'—N5—O5	96.1 (14)	N3—C20—H20	118.0
O4'—N5—O5	148.1 (13)	C14—C20—H20	118.0
C6—C1—C2	121.0 (4)	N3—C21—C22	107.7 (3)
C6—C1—C7	118.0 (4)	N3—C21—H21A	110.2
C2—C1—C7	121.0 (4)	C22—C21—H21A	110.2
O1—C2—C3	118.7 (4)	N3—C21—H21B	110.2
O1—C2—C1	124.6 (4)	C22—C21—H21B	110.2
C3—C2—C1	116.7 (4)	H21A—C21—H21B	108.5
C4—C3—C2	121.4 (4)	N4—C22—C23	121.6 (4)
C4—C3—H3	119.3	N4—C22—C21	114.6 (4)
C2—C3—H3	119.3	C23—C22—C21	123.8 (4)
C3—C4—C5	120.5 (4)	C22—C23—C24	119.5 (5)
C3—C4—H4	119.8	C22—C23—H23	120.2
C5—C4—H4	119.8	C24—C23—H23	120.2
C6—C5—C4	120.7 (4)	C25—C24—C23	118.5 (5)
C6—C5—Br1	120.2 (4)	C25—C24—H24	120.7
C4—C5—Br1	119.0 (3)	C23—C24—H24	120.7
C5—C6—C1	119.7 (4)	C26—C25—C24	119.5 (5)
C5—C6—H6	120.1	C26—C25—H25	120.2
C1—C6—H6	120.1	C24—C25—H25	120.2
N1—C7—C1	123.2 (4)	N4—C26—C25	122.4 (4)
N1—C7—H7	118.4	N4—C26—H26	118.8
C1—C7—H7	118.4	C25—C26—H26	118.8
N1—C8—C9	108.0 (3)
N1—Mn1—O1—C2	−34.1 (3)	C7—C1—C6—C5	180.0 (4)
N3—Mn1—O1—C2	144.6 (3)	C8—N1—C7—C1	178.9 (4)
O2—Mn1—O1—C2	−122.0 (3)	Mn1—N1—C7—C1	−1.1 (6)
N4—Mn1—O1—C2	61.6 (3)	C6—C1—C7—N1	166.2 (4)
O1—Mn1—O2—C15	−110.4 (3)	C2—C1—C7—N1	−15.0 (6)
N1—Mn1—O2—C15	157.3 (3)	C7—N1—C8—C9	152.0 (4)
N3—Mn1—O2—C15	−24.6 (3)	Mn1—N1—C8—C9	−28.0 (4)
N2—Mn1—O2—C15	73.8 (3)	C13—N2—C9—C10	−1.1 (6)
O1—Mn1—N1—C7	21.1 (4)	Mn1—N2—C9—C10	176.2 (4)
O2—Mn1—N1—C7	112.6 (4)	C13—N2—C9—C8	178.9 (4)
N2—Mn1—N1—C7	−158.4 (4)	Mn1—N2—C9—C8	−3.8 (5)
N4—Mn1—N1—C7	−69.7 (4)	N1—C8—C9—N2	20.1 (5)
O1—Mn1—N1—C8	−158.9 (3)	N1—C8—C9—C10	−159.9 (4)
N3—Mn1—N1—C8	166 (3)	N2—C9—C10—C11	0.9 (7)
O2—Mn1—N1—C8	−67.3 (3)	C8—C9—C10—C11	−179.1 (5)
N2—Mn1—N1—C8	21.6 (3)	C9—C10—C11—C12	0.2 (8)
N4—Mn1—N1—C8	110.3 (3)	C10—C11—C12—C13	−1.0 (9)
N1—Mn1—N2—C13	167.2 (4)	C9—N2—C13—C12	0.3 (7)
N3—Mn1—N2—C13	−11.4 (4)	Mn1—N2—C13—C12	−176.7 (4)
O2—Mn1—N2—C13	−104.8 (4)	C11—C12—C13—N2	0.8 (8)
N4—Mn1—N2—C13	71.5 (4)	Mn1—O2—C15—C16	−160.7 (3)
N1—Mn1—N2—C9	−9.9 (3)	Mn1—O2—C15—C14	21.3 (5)
N3—Mn1—N2—C9	171.5 (3)	C19—C14—C15—O2	178.7 (4)
O2—Mn1—N2—C9	78.1 (3)	C20—C14—C15—O2	0.8 (6)
N4—Mn1—N2—C9	−105.6 (3)	C19—C14—C15—C16	0.7 (6)
O1—Mn1—N3—C20	104.6 (4)	C20—C14—C15—C16	−177.3 (4)
O2—Mn1—N3—C20	13.3 (4)	O2—C15—C16—C17	−179.0 (4)
N2—Mn1—N3—C20	−76.0 (4)	C14—C15—C16—C17	−0.8 (7)
N4—Mn1—N3—C20	−164.3 (4)	C15—C16—C17—C18	−0.3 (7)
O1—Mn1—N3—C21	−69.2 (3)	C16—C17—C18—C19	1.6 (7)
O2—Mn1—N3—C21	−160.6 (3)	C16—C17—C18—Br2	−179.6 (4)
N2—Mn1—N3—C21	110.2 (3)	C17—C18—C19—C14	−1.8 (7)
N4—Mn1—N3—C21	21.9 (3)	Br2—C18—C19—C14	179.4 (3)
O1—Mn1—N4—C26	−108.8 (4)	C15—C14—C19—C18	0.6 (6)
N1—Mn1—N4—C26	−16.4 (4)	C20—C14—C19—C18	178.7 (4)
N3—Mn1—N4—C26	165.6 (4)	C21—N3—C20—C14	176.1 (4)
N2—Mn1—N4—C26	66.9 (4)	Mn1—N3—C20—C14	2.7 (6)
O1—Mn1—N4—C22	76.8 (3)	C19—C14—C20—N3	168.2 (4)
N1—Mn1—N4—C22	169.3 (3)	C15—C14—C20—N3	−13.8 (6)
N3—Mn1—N4—C22	−8.8 (3)	C20—N3—C21—C22	156.1 (4)
N2—Mn1—N4—C22	−107.4 (3)	Mn1—N3—C21—C22	−29.5 (4)
Mn1—O1—C2—C3	−152.4 (3)	C26—N4—C22—C23	−1.7 (6)
Mn1—O1—C2—C1	29.1 (5)	Mn1—N4—C22—C23	173.2 (3)
C6—C1—C2—O1	178.5 (4)	C26—N4—C22—C21	179.0 (4)
C7—C1—C2—O1	−0.2 (6)	Mn1—N4—C22—C21	−6.1 (4)
C6—C1—C2—C3	−0.1 (6)	N3—C21—C22—N4	22.6 (5)
C7—C1—C2—C3	−178.8 (4)	N3—C21—C22—C23	−156.7 (4)
O1—C2—C3—C4	180.0 (4)	N4—C22—C23—C24	2.1 (7)
C1—C2—C3—C4	−1.3 (6)	C21—C22—C23—C24	−178.7 (5)
C2—C3—C4—C5	1.6 (7)	C22—C23—C24—C25	−0.4 (8)
C3—C4—C5—C6	−0.4 (7)	C23—C24—C25—C26	−1.5 (8)
C3—C4—C5—Br1	178.8 (3)	C22—N4—C26—C25	−0.3 (7)
C4—C5—C6—C1	−1.0 (7)	Mn1—N4—C26—C25	−174.5 (4)
Br1—C5—C6—C1	179.8 (3)	C24—C25—C26—N4	1.9 (8)
C2—C1—C6—C5	1.2 (6)