cis-Dichloro­bis(triphenyl­phosphine-κP)platinum(II)

Fun, H.-K.; Chantrapromma, S.; Liu, Y.-C.; Chen, Z.-F.; Liang, H.

doi:10.1107/S1600536806016540

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cis-Dichlorobis(triphenylphosphine-κP)platinum(II)

H.-K. Fun, S. Chantrapromma, Y.-C. Liu, Z.-F. Chen and H. Liang

The geometry of the Pt atom in the title compound, [PtCl₂(C₁₈H₁₅P)₂], is square planar. There are two crystallographically independent molecules, A and B, in the asymmetric unit. The average Pt—P bond distances are 2.2614 (9) (in A) and 2.2659 (10) Å (in B), with Pt—Cl distances of 2.3463 (8) (in A) and 2.3496 (10) Å (in B). The molecular structure is stabilized by intermolecular C—H

Cl hydrogen bonds and C—H

π interactions.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806016540/sj2059sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806016540/sj2059Isup2.hkl Contains datablock I

CCDC reference: 610898

checkCIF report

Key indicators

Single-crystal X-ray study
T = 297 K
Mean (C-C) = 0.007 Å
R factor = 0.031
wR factor = 0.071
Data-to-parameter ratio = 24.4

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.01 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       C17B
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         14

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL, PLATON (Spek, 2003) and PARST (Nardelli, 1995).

cis-Dichlorobis(triphenylphosphine-κP)platinum(II) top

Crystal data top

[PtCl₂(C₁₈H₁₅P)₂]	F(000) = 3104
M_r = 790.52	D_x = 1.700 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 12898 reflections
a = 32.5958 (4) Å	θ = 0.6–30.0°
b = 9.6895 (1) Å	µ = 4.85 mm⁻¹
c = 19.6170 (2) Å	T = 297 K
β = 94.476 (1)°	Block, purple
V = 6176.88 (12) Å³	0.30 × 0.29 × 0.06 mm
Z = 8

Data collection top

Bruker SMART APEX2 CCD area-detector diffractometer	18034 independent reflections
Radiation source: fine-focus sealed tube	12898 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.049
Detector resolution: 8.33 pixels mm^-1	θ_max = 30.0°, θ_min = 0.6°
ω scans	h = −44→45
Absorption correction: multi-scan (SADABS; Bruker, 2005)	k = −13→13
T_min = 0.255, T_max = 0.748	l = −27→27
150461 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.071	H-atom parameters constrained
S = 1.02	w = 1/[σ²(F_o²) + (0.0197P)² + 12.2287P] where P = (F_o² + 2F_c²)/3
18034 reflections	(Δ/σ)_max = 0.005
739 parameters	Δρ_max = 1.11 e Å⁻³
0 restraints	Δρ_min = −1.15 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1A	0.613662 (4)	0.490933 (13)	0.299274 (5)	0.02517 (3)
Pt1B	0.120412 (4)	0.503993 (15)	0.452710 (7)	0.03677 (4)
Cl1A	0.65817 (3)	0.51346 (10)	0.21043 (4)	0.0411 (2)
Cl2A	0.57167 (3)	0.35423 (12)	0.22525 (5)	0.0511 (3)
Cl1B	0.12780 (4)	0.74509 (11)	0.45921 (7)	0.0604 (3)
Cl2B	0.09982 (4)	0.50994 (11)	0.56475 (5)	0.0527 (3)
P1A	0.66321 (3)	0.61321 (9)	0.36067 (4)	0.02897 (18)
P2A	0.56728 (3)	0.47525 (9)	0.37817 (4)	0.02660 (17)
P1B	0.15321 (3)	0.51771 (10)	0.35495 (5)	0.0377 (2)
P2B	0.10318 (3)	0.27797 (10)	0.45040 (5)	0.0399 (2)
C1A	0.51612 (11)	0.4061 (4)	0.35084 (16)	0.0320 (7)
C2A	0.51162 (13)	0.2646 (4)	0.34207 (19)	0.0423 (9)
H2AA	0.5347	0.2080	0.3467	0.051*
C3A	0.47324 (14)	0.2069 (5)	0.3265 (2)	0.0524 (11)
H3AA	0.4707	0.1120	0.3205	0.063*
C4A	0.43887 (14)	0.2890 (5)	0.3199 (2)	0.0541 (12)
H4AA	0.4131	0.2498	0.3099	0.065*
C5A	0.44267 (14)	0.4275 (6)	0.3279 (2)	0.0598 (13)
H5AA	0.4194	0.4832	0.3231	0.072*
C6A	0.48125 (13)	0.4873 (4)	0.3434 (2)	0.0460 (9)
H6AA	0.4835	0.5824	0.3487	0.055*
C7A	0.58246 (11)	0.3558 (4)	0.44693 (16)	0.0305 (7)
C8A	0.61465 (12)	0.2647 (4)	0.43952 (18)	0.0371 (8)
H8AA	0.6289	0.2676	0.4003	0.044*
C9A	0.62558 (14)	0.1694 (4)	0.4905 (2)	0.0463 (10)
H9AA	0.6470	0.1081	0.4851	0.056*
C10A	0.60492 (14)	0.1650 (4)	0.5489 (2)	0.0499 (11)
H10A	0.6132	0.1040	0.5839	0.060*
C11A	0.57195 (14)	0.2510 (4)	0.55537 (19)	0.0496 (11)
H11A	0.5574	0.2458	0.5942	0.059*
C12A	0.56019 (13)	0.3452 (4)	0.50465 (18)	0.0413 (9)
H12A	0.5374	0.4016	0.5090	0.050*
C13A	0.55626 (11)	0.6456 (4)	0.41083 (17)	0.0311 (7)
C14A	0.56023 (12)	0.6871 (4)	0.47920 (19)	0.0410 (9)
H14A	0.5686	0.6242	0.5133	0.049*
C15A	0.55169 (15)	0.8224 (5)	0.4958 (2)	0.0532 (11)
H15A	0.5549	0.8503	0.5413	0.064*
C16A	0.53859 (14)	0.9160 (5)	0.4463 (3)	0.0554 (12)
H16A	0.5327	1.0062	0.4584	0.067*
C17A	0.53426 (14)	0.8761 (4)	0.3788 (2)	0.0494 (10)
H17A	0.5250	0.9387	0.3451	0.059*
C18A	0.54378 (12)	0.7425 (4)	0.36141 (19)	0.0411 (9)
H18A	0.5418	0.7169	0.3156	0.049*
C19A	0.67093 (12)	0.7811 (4)	0.32065 (17)	0.0344 (8)
C20A	0.70654 (14)	0.8168 (4)	0.2917 (2)	0.0464 (10)
H20A	0.7282	0.7541	0.2920	0.056*
C21A	0.71033 (16)	0.9453 (5)	0.2622 (2)	0.0576 (12)
H21A	0.7346	0.9683	0.2429	0.069*
C22A	0.67889 (17)	1.0392 (5)	0.2611 (2)	0.0578 (13)
H22A	0.6816	1.1253	0.2410	0.069*
C23A	0.64358 (16)	1.0048 (4)	0.2898 (2)	0.0554 (11)
H23A	0.6223	1.0686	0.2898	0.066*
C24A	0.63894 (13)	0.8757 (4)	0.3191 (2)	0.0470 (10)
H24A	0.6144	0.8528	0.3376	0.056*
C25A	0.71204 (11)	0.5190 (4)	0.36574 (16)	0.0327 (7)
C26A	0.71401 (12)	0.3829 (4)	0.34414 (18)	0.0385 (8)
H26A	0.6906	0.3397	0.3241	0.046*
C27A	0.75104 (14)	0.3113 (5)	0.3526 (2)	0.0512 (11)
H27A	0.7522	0.2199	0.3384	0.061*
C28A	0.78568 (14)	0.3740 (5)	0.3815 (2)	0.0548 (12)
H28A	0.8104	0.3257	0.3867	0.066*
C29A	0.78394 (12)	0.5083 (5)	0.4029 (2)	0.0495 (10)
H29A	0.8077	0.5513	0.4219	0.059*
C30A	0.74724 (12)	0.5807 (4)	0.39647 (19)	0.0415 (9)
H30A	0.7461	0.6706	0.4127	0.050*
C31A	0.66114 (10)	0.6542 (4)	0.45168 (16)	0.0303 (7)
C32A	0.66084 (14)	0.7871 (4)	0.4774 (2)	0.0497 (11)
H32A	0.6599	0.8620	0.4477	0.060*
C33A	0.66190 (16)	0.8089 (5)	0.5473 (2)	0.0605 (13)
H33A	0.6620	0.8987	0.5641	0.073*
C34A	0.66280 (14)	0.7008 (5)	0.5921 (2)	0.0501 (11)
H34A	0.6626	0.7165	0.6389	0.060*
C35A	0.66398 (14)	0.5686 (5)	0.5671 (2)	0.0482 (10)
H35A	0.6651	0.4942	0.5971	0.058*
C36A	0.66343 (12)	0.5459 (4)	0.49756 (18)	0.0393 (9)
H36A	0.6646	0.4560	0.4813	0.047*
C1B	0.05914 (12)	0.2362 (4)	0.4988 (2)	0.0425 (9)
C2B	0.05810 (14)	0.1207 (5)	0.5397 (2)	0.0533 (11)
H2BA	0.0811	0.0639	0.5458	0.064*
C3B	0.02247 (15)	0.0891 (5)	0.5721 (3)	0.0638 (13)
H3BA	0.0221	0.0125	0.6006	0.077*
C4B	−0.01157 (15)	0.1697 (5)	0.5620 (3)	0.0634 (13)
H4BA	−0.0351	0.1484	0.5837	0.076*
C5B	−0.01115 (15)	0.2824 (5)	0.5197 (3)	0.0630 (13)
H5BA	−0.0347	0.3363	0.5121	0.076*
C6B	0.02409 (14)	0.3163 (5)	0.4885 (2)	0.0565 (12)
H6BA	0.0242	0.3935	0.4603	0.068*
C7B	0.14567 (13)	0.1716 (4)	0.4866 (2)	0.0453 (10)
C8B	0.16975 (15)	0.0909 (5)	0.4476 (3)	0.0592 (12)
H8BA	0.1633	0.0827	0.4008	0.071*
C9B	0.20328 (17)	0.0228 (5)	0.4781 (3)	0.0754 (16)
H9BA	0.2192	−0.0319	0.4515	0.090*
C10B	0.21379 (17)	0.0339 (6)	0.5468 (3)	0.0754 (16)
H10B	0.2366	−0.0131	0.5667	0.090*
C11B	0.19043 (15)	0.1150 (6)	0.5864 (3)	0.0657 (14)
H11B	0.1976	0.1241	0.6330	0.079*
C12B	0.15613 (14)	0.1833 (5)	0.5566 (2)	0.0550 (11)
H12B	0.1401	0.2370	0.5834	0.066*
C13B	0.08413 (14)	0.2143 (5)	0.3664 (2)	0.0491 (10)
C14B	0.06385 (14)	0.3073 (6)	0.3226 (2)	0.0590 (12)
H14B	0.0606	0.3979	0.3368	0.071*
C15B	0.04821 (18)	0.2684 (8)	0.2576 (3)	0.0868 (19)
H15B	0.0345	0.3326	0.2288	0.104*
C16B	0.0529 (2)	0.1360 (10)	0.2361 (4)	0.113 (3)
H16B	0.0435	0.1099	0.1920	0.136*
C17B	0.0719 (3)	0.0414 (8)	0.2807 (4)	0.113 (3)
H17B	0.0747	−0.0493	0.2663	0.135*
C18B	0.08667 (19)	0.0780 (6)	0.3461 (3)	0.0788 (17)
H18B	0.0982	0.0118	0.3761	0.095*
C19B	0.12408 (13)	0.5896 (4)	0.2806 (2)	0.0456 (10)
C20B	0.13866 (16)	0.5879 (5)	0.2165 (2)	0.0575 (12)
H20B	0.1643	0.5491	0.2110	0.069*
C21B	0.1161 (2)	0.6425 (6)	0.1599 (3)	0.0782 (18)
H21B	0.1269	0.6431	0.1174	0.094*
C22B	0.0780 (2)	0.6952 (6)	0.1671 (4)	0.091 (2)
H22B	0.0628	0.7316	0.1293	0.109*
C23B	0.06196 (18)	0.6950 (6)	0.2298 (4)	0.0830 (19)
H23B	0.0355	0.7279	0.2339	0.100*
C24B	0.08538 (15)	0.6454 (5)	0.2876 (3)	0.0636 (13)
H24B	0.0751	0.6498	0.3304	0.076*
C25B	0.19929 (12)	0.6259 (4)	0.37062 (19)	0.0377 (8)
C26B	0.22094 (13)	0.6197 (5)	0.4337 (2)	0.0512 (11)
H26B	0.2107	0.5672	0.4683	0.061*
C27B	0.25775 (14)	0.6905 (5)	0.4465 (2)	0.0558 (12)
H27B	0.2720	0.6851	0.4894	0.067*
C28B	0.27308 (13)	0.7685 (5)	0.3959 (2)	0.0515 (11)
H28B	0.2981	0.8142	0.4041	0.062*
C29B	0.25156 (14)	0.7789 (5)	0.3336 (2)	0.0516 (11)
H29B	0.2618	0.8329	0.2996	0.062*
C30B	0.21454 (13)	0.7096 (4)	0.3204 (2)	0.0442 (9)
H30B	0.1999	0.7188	0.2781	0.053*
C31B	0.17618 (13)	0.3599 (4)	0.3222 (2)	0.0418 (9)
C32B	0.21348 (14)	0.3110 (5)	0.3522 (2)	0.0540 (11)
H32B	0.2270	0.3587	0.3885	0.065*
C33B	0.23053 (17)	0.1902 (5)	0.3278 (3)	0.0648 (14)
H33B	0.2556	0.1582	0.3475	0.078*
C34B	0.21048 (18)	0.1187 (5)	0.2750 (3)	0.0664 (14)
H34B	0.2221	0.0384	0.2591	0.080*
C35B	0.17367 (17)	0.1640 (5)	0.2456 (3)	0.0624 (13)
H35B	0.1602	0.1142	0.2100	0.075*
C36B	0.15628 (15)	0.2845 (5)	0.2686 (2)	0.0525 (11)
H36B	0.1312	0.3152	0.2482	0.063*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1A	0.02875 (7)	0.02752 (6)	0.01936 (5)	0.00182 (6)	0.00256 (4)	−0.00071 (5)
Pt1B	0.03297 (8)	0.03188 (8)	0.04640 (8)	−0.00062 (6)	0.00914 (6)	−0.00109 (6)
Cl1A	0.0435 (5)	0.0540 (6)	0.0271 (4)	−0.0028 (5)	0.0117 (3)	−0.0008 (4)
Cl2A	0.0512 (6)	0.0673 (7)	0.0352 (5)	−0.0169 (5)	0.0060 (4)	−0.0206 (5)
Cl1B	0.0599 (7)	0.0327 (5)	0.0913 (9)	−0.0041 (5)	0.0236 (6)	−0.0066 (5)
Cl2B	0.0555 (6)	0.0542 (6)	0.0504 (5)	−0.0003 (5)	0.0164 (5)	−0.0084 (5)
P1A	0.0293 (5)	0.0306 (4)	0.0271 (4)	0.0011 (4)	0.0028 (3)	−0.0031 (3)
P2A	0.0274 (4)	0.0293 (4)	0.0233 (4)	0.0023 (3)	0.0031 (3)	0.0007 (3)
P1B	0.0343 (5)	0.0360 (5)	0.0434 (5)	0.0011 (4)	0.0066 (4)	0.0044 (4)
P2B	0.0387 (6)	0.0332 (5)	0.0490 (6)	−0.0016 (4)	0.0103 (5)	0.0008 (4)
C1A	0.033 (2)	0.0375 (19)	0.0261 (16)	0.0010 (15)	0.0061 (14)	0.0001 (14)
C2A	0.041 (2)	0.040 (2)	0.046 (2)	−0.0030 (18)	−0.0010 (18)	0.0050 (17)
C3A	0.058 (3)	0.053 (3)	0.046 (2)	−0.021 (2)	0.000 (2)	0.0011 (19)
C4A	0.035 (2)	0.084 (4)	0.043 (2)	−0.013 (2)	0.0001 (18)	−0.011 (2)
C5A	0.038 (3)	0.075 (3)	0.065 (3)	0.007 (2)	−0.004 (2)	−0.021 (3)
C6A	0.040 (2)	0.049 (2)	0.048 (2)	0.006 (2)	−0.0003 (17)	−0.0117 (19)
C7A	0.0319 (19)	0.0314 (18)	0.0282 (16)	−0.0007 (15)	0.0020 (14)	0.0032 (13)
C8A	0.044 (2)	0.0324 (19)	0.0357 (18)	0.0058 (17)	0.0060 (16)	0.0016 (15)
C9A	0.051 (3)	0.038 (2)	0.049 (2)	0.0114 (19)	−0.0006 (19)	0.0040 (17)
C10A	0.067 (3)	0.045 (2)	0.037 (2)	0.008 (2)	0.000 (2)	0.0152 (17)
C11A	0.065 (3)	0.053 (3)	0.0328 (19)	0.005 (2)	0.0127 (19)	0.0097 (18)
C12A	0.044 (2)	0.045 (2)	0.0355 (19)	0.0074 (18)	0.0099 (17)	0.0079 (16)
C13A	0.0296 (19)	0.0324 (18)	0.0320 (17)	0.0025 (15)	0.0066 (14)	−0.0023 (14)
C14A	0.042 (2)	0.045 (2)	0.037 (2)	0.0061 (18)	0.0039 (17)	−0.0026 (16)
C15A	0.065 (3)	0.051 (3)	0.044 (2)	0.005 (2)	0.013 (2)	−0.017 (2)
C16A	0.054 (3)	0.038 (2)	0.076 (3)	0.004 (2)	0.022 (2)	−0.013 (2)
C17A	0.051 (3)	0.036 (2)	0.062 (3)	0.0100 (19)	0.012 (2)	0.0075 (19)
C18A	0.047 (2)	0.039 (2)	0.0379 (19)	0.0051 (18)	0.0076 (17)	0.0012 (16)
C19A	0.039 (2)	0.0325 (18)	0.0311 (17)	−0.0015 (16)	−0.0009 (15)	−0.0006 (14)
C20A	0.050 (3)	0.043 (2)	0.048 (2)	−0.0013 (19)	0.0129 (19)	0.0008 (18)
C21A	0.065 (3)	0.054 (3)	0.056 (3)	−0.018 (2)	0.018 (2)	0.005 (2)
C22A	0.086 (4)	0.037 (2)	0.050 (2)	−0.016 (2)	0.002 (2)	0.0056 (19)
C23A	0.066 (3)	0.038 (2)	0.060 (3)	0.007 (2)	−0.010 (2)	0.002 (2)
C24A	0.041 (2)	0.045 (2)	0.054 (2)	0.0013 (19)	−0.0003 (19)	0.0080 (19)
C25A	0.0283 (18)	0.042 (2)	0.0288 (15)	0.0038 (16)	0.0045 (13)	0.0019 (14)
C26A	0.039 (2)	0.041 (2)	0.0351 (18)	0.0056 (17)	0.0025 (16)	0.0019 (15)
C27A	0.058 (3)	0.049 (3)	0.047 (2)	0.020 (2)	0.005 (2)	−0.0001 (19)
C28A	0.042 (3)	0.072 (3)	0.051 (2)	0.022 (2)	0.004 (2)	0.008 (2)
C29A	0.031 (2)	0.075 (3)	0.042 (2)	−0.001 (2)	0.0001 (16)	0.006 (2)
C30A	0.036 (2)	0.047 (2)	0.041 (2)	−0.0008 (18)	0.0030 (17)	−0.0017 (17)
C31A	0.0244 (18)	0.0378 (19)	0.0286 (16)	0.0024 (15)	0.0008 (13)	−0.0061 (14)
C32A	0.074 (3)	0.039 (2)	0.035 (2)	0.008 (2)	0.002 (2)	−0.0059 (17)
C33A	0.089 (4)	0.048 (3)	0.043 (2)	0.014 (3)	0.000 (2)	−0.017 (2)
C34A	0.056 (3)	0.063 (3)	0.0313 (19)	0.009 (2)	−0.0004 (18)	−0.0122 (19)
C35A	0.054 (3)	0.056 (3)	0.0335 (19)	0.002 (2)	0.0014 (18)	0.0035 (18)
C36A	0.044 (2)	0.039 (2)	0.0347 (18)	−0.0006 (17)	0.0009 (16)	−0.0036 (15)
C1B	0.034 (2)	0.040 (2)	0.054 (2)	−0.0016 (17)	0.0083 (18)	−0.0010 (18)
C2B	0.043 (3)	0.048 (3)	0.071 (3)	0.002 (2)	0.014 (2)	0.015 (2)
C3B	0.053 (3)	0.067 (3)	0.074 (3)	−0.005 (3)	0.018 (2)	0.022 (3)
C4B	0.045 (3)	0.070 (3)	0.077 (3)	−0.008 (3)	0.022 (2)	0.004 (3)
C5B	0.041 (3)	0.063 (3)	0.086 (4)	0.008 (2)	0.010 (2)	0.004 (3)
C6B	0.049 (3)	0.049 (3)	0.073 (3)	0.003 (2)	0.014 (2)	0.012 (2)
C7B	0.042 (2)	0.032 (2)	0.063 (3)	−0.0007 (17)	0.014 (2)	0.0053 (18)
C8B	0.064 (3)	0.046 (3)	0.070 (3)	0.011 (2)	0.025 (3)	0.005 (2)
C9B	0.065 (4)	0.062 (3)	0.103 (5)	0.025 (3)	0.031 (3)	0.018 (3)
C10B	0.057 (3)	0.061 (3)	0.108 (5)	0.015 (3)	0.010 (3)	0.032 (3)
C11B	0.046 (3)	0.071 (3)	0.079 (3)	−0.003 (3)	0.000 (3)	0.011 (3)
C12B	0.042 (3)	0.055 (3)	0.069 (3)	0.000 (2)	0.007 (2)	0.000 (2)
C13B	0.051 (3)	0.046 (2)	0.051 (2)	−0.018 (2)	0.013 (2)	−0.0063 (19)
C14B	0.048 (3)	0.071 (3)	0.057 (3)	−0.015 (2)	0.004 (2)	0.001 (2)
C15B	0.070 (4)	0.123 (6)	0.064 (3)	−0.027 (4)	−0.010 (3)	0.001 (4)
C16B	0.108 (6)	0.154 (8)	0.078 (5)	−0.049 (6)	0.008 (4)	−0.045 (5)
C17B	0.130 (7)	0.095 (5)	0.116 (6)	−0.042 (5)	0.021 (5)	−0.060 (5)
C18B	0.093 (4)	0.051 (3)	0.095 (4)	−0.019 (3)	0.021 (3)	−0.026 (3)
C19B	0.043 (2)	0.035 (2)	0.057 (2)	−0.0051 (18)	−0.0073 (19)	0.0066 (18)
C20B	0.064 (3)	0.055 (3)	0.051 (3)	−0.014 (2)	−0.009 (2)	0.008 (2)
C21B	0.104 (5)	0.067 (4)	0.058 (3)	−0.033 (3)	−0.028 (3)	0.018 (3)
C22B	0.099 (5)	0.059 (4)	0.105 (5)	−0.020 (3)	−0.053 (4)	0.025 (3)
C23B	0.060 (4)	0.058 (3)	0.126 (6)	0.004 (3)	−0.028 (4)	0.015 (3)
C24B	0.050 (3)	0.048 (3)	0.091 (4)	0.000 (2)	−0.003 (3)	0.007 (3)
C25B	0.033 (2)	0.038 (2)	0.042 (2)	−0.0005 (16)	0.0066 (16)	0.0007 (16)
C26B	0.043 (3)	0.066 (3)	0.045 (2)	−0.001 (2)	0.0035 (19)	0.010 (2)
C27B	0.043 (3)	0.072 (3)	0.051 (3)	0.005 (2)	−0.006 (2)	−0.003 (2)
C28B	0.033 (2)	0.053 (3)	0.069 (3)	−0.005 (2)	0.006 (2)	−0.008 (2)
C29B	0.050 (3)	0.049 (3)	0.058 (3)	−0.008 (2)	0.013 (2)	0.003 (2)
C30B	0.044 (2)	0.046 (2)	0.043 (2)	−0.0051 (19)	0.0038 (18)	0.0052 (17)
C31B	0.040 (2)	0.039 (2)	0.048 (2)	0.0032 (18)	0.0162 (18)	0.0080 (17)
C32B	0.050 (3)	0.054 (3)	0.059 (3)	0.009 (2)	0.011 (2)	0.011 (2)
C33B	0.062 (3)	0.060 (3)	0.075 (3)	0.020 (3)	0.021 (3)	0.016 (3)
C34B	0.083 (4)	0.050 (3)	0.072 (3)	0.017 (3)	0.035 (3)	0.007 (2)
C35B	0.078 (4)	0.052 (3)	0.059 (3)	−0.001 (3)	0.023 (3)	−0.008 (2)
C36B	0.060 (3)	0.048 (2)	0.052 (2)	0.002 (2)	0.018 (2)	−0.001 (2)

Geometric parameters (Å, º) top

Pt1A—P2A	2.2515 (8)	C31A—C32A	1.383 (5)
Pt1A—P1A	2.2713 (9)	C32A—C33A	1.386 (5)
Pt1A—Cl2A	2.3294 (9)	C32A—H32A	0.9300
Pt1A—Cl1A	2.3632 (8)	C33A—C34A	1.366 (6)
Pt1B—P2B	2.2605 (10)	C33A—H33A	0.9300
Pt1B—P1B	2.2713 (10)	C34A—C35A	1.373 (6)
Pt1B—Cl2B	2.3483 (10)	C34A—H34A	0.9300
Pt1B—Cl1B	2.3509 (11)	C35A—C36A	1.380 (5)
P1A—C25A	1.831 (4)	C35A—H35A	0.9300
P1A—C19A	1.832 (4)	C36A—H36A	0.9300
P1A—C31A	1.835 (3)	C1B—C2B	1.379 (6)
P2A—C7A	1.817 (3)	C1B—C6B	1.383 (6)
P2A—C13A	1.817 (3)	C2B—C3B	1.401 (6)
P2A—C1A	1.838 (4)	C2B—H2BA	0.9300
P1B—C19B	1.816 (4)	C3B—C4B	1.359 (7)
P1B—C25B	1.838 (4)	C3B—H3BA	0.9300
P1B—C31B	1.840 (4)	C4B—C5B	1.372 (7)
P2B—C13B	1.822 (4)	C4B—H4BA	0.9300
P2B—C7B	1.825 (4)	C5B—C6B	1.383 (6)
P2B—C1B	1.827 (4)	C5B—H5BA	0.9300
C1A—C6A	1.381 (5)	C6B—H6BA	0.9300
C1A—C2A	1.388 (5)	C7B—C8B	1.380 (6)
C2A—C3A	1.383 (6)	C7B—C12B	1.393 (6)
C2A—H2AA	0.9300	C8B—C9B	1.373 (7)
C3A—C4A	1.372 (6)	C8B—H8BA	0.9300
C3A—H3AA	0.9300	C9B—C10B	1.369 (8)
C4A—C5A	1.356 (7)	C9B—H9BA	0.9300
C4A—H4AA	0.9300	C10B—C11B	1.375 (7)
C5A—C6A	1.396 (6)	C10B—H10B	0.9300
C5A—H5AA	0.9300	C11B—C12B	1.388 (6)
C6A—H6AA	0.9300	C11B—H11B	0.9300
C7A—C8A	1.387 (5)	C12B—H12B	0.9300
C7A—C12A	1.396 (5)	C13B—C14B	1.378 (6)
C8A—C9A	1.387 (5)	C13B—C18B	1.384 (6)
C8A—H8AA	0.9300	C14B—C15B	1.387 (7)
C9A—C10A	1.374 (6)	C14B—H14B	0.9300
C9A—H9AA	0.9300	C15B—C16B	1.363 (10)
C10A—C11A	1.374 (6)	C15B—H15B	0.9300
C10A—H10A	0.9300	C16B—C17B	1.379 (11)
C11A—C12A	1.382 (5)	C16B—H16B	0.9300
C11A—H11A	0.9300	C17B—C18B	1.382 (9)
C12A—H12A	0.9300	C17B—H17B	0.9300
C13A—C18A	1.388 (5)	C18B—H18B	0.9300
C13A—C14A	1.396 (5)	C19B—C20B	1.379 (6)
C14A—C15A	1.384 (5)	C19B—C24B	1.389 (6)
C14A—H14A	0.9300	C20B—C21B	1.388 (6)
C15A—C16A	1.372 (6)	C20B—H20B	0.9300
C15A—H15A	0.9300	C21B—C22B	1.358 (9)
C16A—C17A	1.377 (6)	C21B—H21B	0.9300
C16A—H16A	0.9300	C22B—C23B	1.374 (9)
C17A—C18A	1.379 (5)	C22B—H22B	0.9300
C17A—H17A	0.9300	C23B—C24B	1.401 (7)
C18A—H18A	0.9300	C23B—H23B	0.9300
C19A—C20A	1.375 (5)	C24B—H24B	0.9300
C19A—C24A	1.387 (5)	C25B—C26B	1.378 (5)
C20A—C21A	1.383 (6)	C25B—C30B	1.396 (5)
C20A—H20A	0.9300	C26B—C27B	1.388 (6)
C21A—C22A	1.369 (7)	C26B—H26B	0.9300
C21A—H21A	0.9300	C27B—C28B	1.372 (6)
C22A—C23A	1.362 (7)	C27B—H27B	0.9300
C22A—H22A	0.9300	C28B—C29B	1.366 (6)
C23A—C24A	1.389 (6)	C28B—H28B	0.9300
C23A—H23A	0.9300	C29B—C30B	1.387 (6)
C24A—H24A	0.9300	C29B—H29B	0.9300
C25A—C26A	1.388 (5)	C30B—H30B	0.9300
C25A—C30A	1.389 (5)	C31B—C32B	1.392 (6)
C26A—C27A	1.391 (5)	C31B—C36B	1.398 (6)
C26A—H26A	0.9300	C32B—C33B	1.396 (6)
C27A—C28A	1.366 (6)	C32B—H32B	0.9300
C27A—H27A	0.9300	C33B—C34B	1.368 (7)
C28A—C29A	1.370 (6)	C33B—H33B	0.9300
C28A—H28A	0.9300	C34B—C35B	1.363 (7)
C29A—C30A	1.384 (6)	C34B—H34B	0.9300
C29A—H29A	0.9300	C35B—C36B	1.388 (6)
C30A—H30A	0.9300	C35B—H35B	0.9300
C31A—C36A	1.380 (5)	C36B—H36B	0.9300

P2A—Pt1A—P1A	99.12 (3)	C36A—C31A—C32A	118.1 (3)
P2A—Pt1A—Cl2A	89.82 (3)	C36A—C31A—P1A	117.8 (3)
P1A—Pt1A—Cl2A	170.41 (3)	C32A—C31A—P1A	123.9 (3)
P2A—Pt1A—Cl1A	175.57 (3)	C31A—C32A—C33A	120.2 (4)
P1A—Pt1A—Cl1A	83.73 (3)	C31A—C32A—H32A	119.9
Cl2A—Pt1A—Cl1A	87.56 (3)	C33A—C32A—H32A	119.9
P2B—Pt1B—P1B	99.93 (4)	C34A—C33A—C32A	121.2 (4)
P2B—Pt1B—Cl2B	87.35 (4)	C34A—C33A—H33A	119.4
P1B—Pt1B—Cl2B	167.58 (4)	C32A—C33A—H33A	119.4
P2B—Pt1B—Cl1B	171.13 (4)	C33A—C34A—C35A	119.0 (4)
P1B—Pt1B—Cl1B	86.25 (4)	C33A—C34A—H34A	120.5
Cl2B—Pt1B—Cl1B	87.73 (4)	C35A—C34A—H34A	120.5
C25A—P1A—C19A	108.55 (17)	C34A—C35A—C36A	120.2 (4)
C25A—P1A—C31A	98.78 (15)	C34A—C35A—H35A	119.9
C19A—P1A—C31A	103.97 (16)	C36A—C35A—H35A	119.9
C25A—P1A—Pt1A	110.36 (12)	C35A—C36A—C31A	121.3 (4)
C19A—P1A—Pt1A	110.60 (12)	C35A—C36A—H36A	119.4
C31A—P1A—Pt1A	123.37 (12)	C31A—C36A—H36A	119.4
C7A—P2A—C13A	111.55 (16)	C2B—C1B—C6B	118.9 (4)
C7A—P2A—C1A	99.94 (16)	C2B—C1B—P2B	122.6 (3)
C13A—P2A—C1A	103.55 (16)	C6B—C1B—P2B	118.2 (3)
C7A—P2A—Pt1A	113.25 (12)	C1B—C2B—C3B	120.0 (4)
C13A—P2A—Pt1A	110.06 (11)	C1B—C2B—H2BA	120.0
C1A—P2A—Pt1A	117.81 (11)	C3B—C2B—H2BA	120.0
C19B—P1B—C25B	106.55 (18)	C4B—C3B—C2B	120.3 (5)
C19B—P1B—C31B	103.88 (19)	C4B—C3B—H3BA	119.8
C25B—P1B—C31B	100.55 (18)	C2B—C3B—H3BA	119.8
C19B—P1B—Pt1B	116.72 (15)	C3B—C4B—C5B	119.9 (4)
C25B—P1B—Pt1B	108.94 (12)	C3B—C4B—H4BA	120.0
C31B—P1B—Pt1B	118.49 (12)	C5B—C4B—H4BA	120.0
C13B—P2B—C7B	110.8 (2)	C4B—C5B—C6B	120.3 (5)
C13B—P2B—C1B	99.71 (19)	C4B—C5B—H5BA	119.8
C7B—P2B—C1B	106.01 (19)	C6B—C5B—H5BA	119.8
C13B—P2B—Pt1B	114.37 (15)	C5B—C6B—C1B	120.5 (4)
C7B—P2B—Pt1B	111.06 (14)	C5B—C6B—H6BA	119.8
C1B—P2B—Pt1B	114.10 (14)	C1B—C6B—H6BA	119.8
C6A—C1A—C2A	118.1 (4)	C8B—C7B—C12B	119.1 (4)
C6A—C1A—P2A	122.9 (3)	C8B—C7B—P2B	123.5 (4)
C2A—C1A—P2A	118.8 (3)	C12B—C7B—P2B	117.2 (3)
C3A—C2A—C1A	120.8 (4)	C9B—C8B—C7B	119.9 (5)
C3A—C2A—H2AA	119.6	C9B—C8B—H8BA	120.0
C1A—C2A—H2AA	119.6	C7B—C8B—H8BA	120.0
C4A—C3A—C2A	120.3 (4)	C10B—C9B—C8B	121.4 (5)
C4A—C3A—H3AA	119.8	C10B—C9B—H9BA	119.3
C2A—C3A—H3AA	119.8	C8B—C9B—H9BA	119.3
C5A—C4A—C3A	119.8 (4)	C9B—C10B—C11B	119.5 (5)
C5A—C4A—H4AA	120.1	C9B—C10B—H10B	120.2
C3A—C4A—H4AA	120.1	C11B—C10B—H10B	120.2
C4A—C5A—C6A	120.6 (4)	C10B—C11B—C12B	119.9 (5)
C4A—C5A—H5AA	119.7	C10B—C11B—H11B	120.1
C6A—C5A—H5AA	119.7	C12B—C11B—H11B	120.1
C1A—C6A—C5A	120.4 (4)	C11B—C12B—C7B	120.2 (5)
C1A—C6A—H6AA	119.8	C11B—C12B—H12B	119.9
C5A—C6A—H6AA	119.8	C7B—C12B—H12B	119.9
C8A—C7A—C12A	119.0 (3)	C14B—C13B—C18B	118.7 (5)
C8A—C7A—P2A	119.5 (3)	C14B—C13B—P2B	117.1 (3)
C12A—C7A—P2A	121.3 (3)	C18B—C13B—P2B	124.0 (4)
C7A—C8A—C9A	120.1 (3)	C13B—C14B—C15B	121.3 (5)
C7A—C8A—H8AA	119.9	C13B—C14B—H14B	119.4
C9A—C8A—H8AA	119.9	C15B—C14B—H14B	119.4
C10A—C9A—C8A	120.4 (4)	C16B—C15B—C14B	119.9 (7)
C10A—C9A—H9AA	119.8	C16B—C15B—H15B	120.1
C8A—C9A—H9AA	119.8	C14B—C15B—H15B	120.1
C11A—C10A—C9A	119.8 (4)	C15B—C16B—C17B	119.0 (7)
C11A—C10A—H10A	120.1	C15B—C16B—H16B	120.5
C9A—C10A—H10A	120.1	C17B—C16B—H16B	120.5
C10A—C11A—C12A	120.6 (4)	C16B—C17B—C18B	121.7 (7)
C10A—C11A—H11A	119.7	C16B—C17B—H17B	119.2
C12A—C11A—H11A	119.7	C18B—C17B—H17B	119.2
C11A—C12A—C7A	120.0 (4)	C17B—C18B—C13B	119.2 (7)
C11A—C12A—H12A	120.0	C17B—C18B—H18B	120.4
C7A—C12A—H12A	120.0	C13B—C18B—H18B	120.4
C18A—C13A—C14A	118.5 (3)	C20B—C19B—C24B	118.3 (4)
C18A—C13A—P2A	115.1 (3)	C20B—C19B—P1B	122.2 (4)
C14A—C13A—P2A	126.4 (3)	C24B—C19B—P1B	119.5 (4)
C15A—C14A—C13A	119.6 (4)	C19B—C20B—C21B	121.8 (5)
C15A—C14A—H14A	120.2	C19B—C20B—H20B	119.1
C13A—C14A—H14A	120.2	C21B—C20B—H20B	119.1
C16A—C15A—C14A	121.1 (4)	C22B—C21B—C20B	119.4 (6)
C16A—C15A—H15A	119.5	C22B—C21B—H21B	120.3
C14A—C15A—H15A	119.5	C20B—C21B—H21B	120.3
C15A—C16A—C17A	119.9 (4)	C21B—C22B—C23B	120.5 (5)
C15A—C16A—H16A	120.1	C21B—C22B—H22B	119.7
C17A—C16A—H16A	120.1	C23B—C22B—H22B	119.7
C16A—C17A—C18A	119.6 (4)	C22B—C23B—C24B	120.2 (6)
C16A—C17A—H17A	120.2	C22B—C23B—H23B	119.9
C18A—C17A—H17A	120.2	C24B—C23B—H23B	119.9
C17A—C18A—C13A	121.4 (4)	C19B—C24B—C23B	119.7 (5)
C17A—C18A—H18A	119.3	C19B—C24B—H24B	120.1
C13A—C18A—H18A	119.3	C23B—C24B—H24B	120.1
C20A—C19A—C24A	118.8 (4)	C26B—C25B—C30B	118.3 (4)
C20A—C19A—P1A	123.2 (3)	C26B—C25B—P1B	118.7 (3)
C24A—C19A—P1A	117.9 (3)	C30B—C25B—P1B	123.0 (3)
C19A—C20A—C21A	120.3 (4)	C25B—C26B—C27B	121.0 (4)
C19A—C20A—H20A	119.8	C25B—C26B—H26B	119.5
C21A—C20A—H20A	119.8	C27B—C26B—H26B	119.5
C22A—C21A—C20A	120.9 (4)	C28B—C27B—C26B	120.0 (4)
C22A—C21A—H21A	119.5	C28B—C27B—H27B	120.0
C20A—C21A—H21A	119.5	C26B—C27B—H27B	120.0
C23A—C22A—C21A	119.1 (4)	C29B—C28B—C27B	119.8 (4)
C23A—C22A—H22A	120.5	C29B—C28B—H28B	120.1
C21A—C22A—H22A	120.5	C27B—C28B—H28B	120.1
C22A—C23A—C24A	120.9 (4)	C28B—C29B—C30B	120.6 (4)
C22A—C23A—H23A	119.5	C28B—C29B—H29B	119.7
C24A—C23A—H23A	119.5	C30B—C29B—H29B	119.7
C19A—C24A—C23A	119.9 (4)	C29B—C30B—C25B	120.1 (4)
C19A—C24A—H24A	120.1	C29B—C30B—H30B	119.9
C23A—C24A—H24A	120.1	C25B—C30B—H30B	119.9
C26A—C25A—C30A	119.0 (3)	C32B—C31B—C36B	118.6 (4)
C26A—C25A—P1A	121.2 (3)	C32B—C31B—P1B	120.1 (3)
C30A—C25A—P1A	119.6 (3)	C36B—C31B—P1B	121.3 (3)
C25A—C26A—C27A	119.8 (4)	C31B—C32B—C33B	119.9 (5)
C25A—C26A—H26A	120.1	C31B—C32B—H32B	120.1
C27A—C26A—H26A	120.1	C33B—C32B—H32B	120.1
C28A—C27A—C26A	120.6 (4)	C34B—C33B—C32B	120.3 (5)
C28A—C27A—H27A	119.7	C34B—C33B—H33B	119.8
C26A—C27A—H27A	119.7	C32B—C33B—H33B	119.8
C27A—C28A—C29A	119.8 (4)	C35B—C34B—C33B	120.7 (5)
C27A—C28A—H28A	120.1	C35B—C34B—H34B	119.7
C29A—C28A—H28A	120.1	C33B—C34B—H34B	119.7
C28A—C29A—C30A	120.6 (4)	C34B—C35B—C36B	120.1 (5)
C28A—C29A—H29A	119.7	C34B—C35B—H35B	120.0
C30A—C29A—H29A	119.7	C36B—C35B—H35B	120.0
C29A—C30A—C25A	120.0 (4)	C35B—C36B—C31B	120.5 (5)
C29A—C30A—H30A	120.0	C35B—C36B—H36B	119.8
C25A—C30A—H30A	120.0	C31B—C36B—H36B	119.8

P2A—Pt1A—P1A—C25A	122.79 (12)	C19A—P1A—C31A—C36A	−167.8 (3)
Cl1A—Pt1A—P1A—C25A	−60.63 (12)	Pt1A—P1A—C31A—C36A	65.5 (3)
P2A—Pt1A—P1A—C19A	−117.08 (13)	C25A—P1A—C31A—C32A	118.4 (4)
Cl1A—Pt1A—P1A—C19A	59.50 (13)	C19A—P1A—C31A—C32A	6.7 (4)
P2A—Pt1A—P1A—C31A	6.73 (14)	Pt1A—P1A—C31A—C32A	−120.0 (3)
Cl1A—Pt1A—P1A—C31A	−176.69 (14)	C36A—C31A—C32A—C33A	−1.4 (6)
P1A—Pt1A—P2A—C7A	−73.02 (13)	P1A—C31A—C32A—C33A	−175.9 (4)
Cl2A—Pt1A—P2A—C7A	103.49 (13)	C31A—C32A—C33A—C34A	−0.7 (8)
P1A—Pt1A—P2A—C13A	52.61 (13)	C32A—C33A—C34A—C35A	2.1 (8)
Cl2A—Pt1A—P2A—C13A	−130.88 (13)	C33A—C34A—C35A—C36A	−1.3 (7)
P1A—Pt1A—P2A—C1A	170.94 (13)	C34A—C35A—C36A—C31A	−0.9 (7)
Cl2A—Pt1A—P2A—C1A	−12.55 (14)	C32A—C31A—C36A—C35A	2.2 (6)
P2B—Pt1B—P1B—C19B	100.76 (15)	P1A—C31A—C36A—C35A	177.0 (3)
Cl2B—Pt1B—P1B—C19B	−134.0 (2)	C13B—P2B—C1B—C2B	99.6 (4)
Cl1B—Pt1B—P1B—C19B	−72.83 (15)	C7B—P2B—C1B—C2B	−15.5 (4)
P2B—Pt1B—P1B—C25B	−138.59 (13)	Pt1B—P2B—C1B—C2B	−138.0 (3)
Cl2B—Pt1B—P1B—C25B	−13.4 (2)	C13B—P2B—C1B—C6B	−73.9 (4)
Cl1B—Pt1B—P1B—C25B	47.82 (14)	C7B—P2B—C1B—C6B	171.0 (4)
P2B—Pt1B—P1B—C31B	−24.60 (16)	Pt1B—P2B—C1B—C6B	48.5 (4)
Cl2B—Pt1B—P1B—C31B	100.6 (2)	C6B—C1B—C2B—C3B	−2.4 (7)
Cl1B—Pt1B—P1B—C31B	161.81 (16)	P2B—C1B—C2B—C3B	−175.8 (4)
P1B—Pt1B—P2B—C13B	−42.16 (17)	C1B—C2B—C3B—C4B	1.7 (8)
Cl2B—Pt1B—P2B—C13B	147.97 (17)	C2B—C3B—C4B—C5B	0.2 (8)
P1B—Pt1B—P2B—C7B	84.17 (15)	C3B—C4B—C5B—C6B	−1.4 (8)
Cl2B—Pt1B—P2B—C7B	−85.69 (15)	C4B—C5B—C6B—C1B	0.7 (8)
P1B—Pt1B—P2B—C1B	−156.08 (15)	C2B—C1B—C6B—C5B	1.2 (7)
Cl2B—Pt1B—P2B—C1B	34.05 (15)	P2B—C1B—C6B—C5B	174.9 (4)
C7A—P2A—C1A—C6A	129.2 (3)	C13B—P2B—C7B—C8B	22.6 (4)
C13A—P2A—C1A—C6A	14.0 (3)	C1B—P2B—C7B—C8B	129.9 (4)
Pt1A—P2A—C1A—C6A	−107.8 (3)	Pt1B—P2B—C7B—C8B	−105.7 (4)
C7A—P2A—C1A—C2A	−45.9 (3)	C13B—P2B—C7B—C12B	−163.2 (3)
C13A—P2A—C1A—C2A	−161.1 (3)	C1B—P2B—C7B—C12B	−56.0 (4)
Pt1A—P2A—C1A—C2A	77.1 (3)	Pt1B—P2B—C7B—C12B	68.5 (3)
C6A—C1A—C2A—C3A	−0.1 (6)	C12B—C7B—C8B—C9B	0.5 (7)
P2A—C1A—C2A—C3A	175.2 (3)	P2B—C7B—C8B—C9B	174.6 (4)
C1A—C2A—C3A—C4A	−0.4 (6)	C7B—C8B—C9B—C10B	−0.6 (8)
C2A—C3A—C4A—C5A	0.7 (7)	C8B—C9B—C10B—C11B	−0.2 (9)
C3A—C4A—C5A—C6A	−0.5 (7)	C9B—C10B—C11B—C12B	0.9 (8)
C2A—C1A—C6A—C5A	0.4 (6)	C10B—C11B—C12B—C7B	−1.0 (7)
P2A—C1A—C6A—C5A	−174.7 (3)	C8B—C7B—C12B—C11B	0.3 (7)
C4A—C5A—C6A—C1A	−0.1 (7)	P2B—C7B—C12B—C11B	−174.2 (4)
C13A—P2A—C7A—C8A	−138.5 (3)	C7B—P2B—C13B—C14B	−156.4 (3)
C1A—P2A—C7A—C8A	112.6 (3)	C1B—P2B—C13B—C14B	92.2 (4)
Pt1A—P2A—C7A—C8A	−13.6 (3)	Pt1B—P2B—C13B—C14B	−29.9 (4)
C13A—P2A—C7A—C12A	47.1 (4)	C7B—P2B—C13B—C18B	27.6 (5)
C1A—P2A—C7A—C12A	−61.8 (3)	C1B—P2B—C13B—C18B	−83.7 (4)
Pt1A—P2A—C7A—C12A	172.0 (3)	Pt1B—P2B—C13B—C18B	154.1 (4)
C12A—C7A—C8A—C9A	−3.0 (6)	C18B—C13B—C14B—C15B	−3.7 (7)
P2A—C7A—C8A—C9A	−177.6 (3)	P2B—C13B—C14B—C15B	−179.9 (4)
C7A—C8A—C9A—C10A	−0.5 (6)	C13B—C14B—C15B—C16B	−0.2 (9)
C8A—C9A—C10A—C11A	3.2 (7)	C14B—C15B—C16B—C17B	2.5 (11)
C9A—C10A—C11A—C12A	−2.1 (7)	C15B—C16B—C17B—C18B	−0.9 (12)
C10A—C11A—C12A—C7A	−1.5 (7)	C16B—C17B—C18B—C13B	−3.0 (11)
C8A—C7A—C12A—C11A	4.0 (6)	C14B—C13B—C18B—C17B	5.2 (8)
P2A—C7A—C12A—C11A	178.5 (3)	P2B—C13B—C18B—C17B	−178.9 (5)
C7A—P2A—C13A—C18A	−179.0 (3)	C25B—P1B—C19B—C20B	66.2 (4)
C1A—P2A—C13A—C18A	−72.4 (3)	C31B—P1B—C19B—C20B	−39.5 (4)
Pt1A—P2A—C13A—C18A	54.4 (3)	Pt1B—P1B—C19B—C20B	−171.9 (3)
C7A—P2A—C13A—C14A	2.8 (4)	C25B—P1B—C19B—C24B	−115.4 (4)
C1A—P2A—C13A—C14A	109.4 (3)	C31B—P1B—C19B—C24B	138.9 (4)
Pt1A—P2A—C13A—C14A	−123.8 (3)	Pt1B—P1B—C19B—C24B	6.5 (4)
C18A—C13A—C14A—C15A	0.1 (6)	C24B—C19B—C20B—C21B	1.3 (7)
P2A—C13A—C14A—C15A	178.2 (3)	P1B—C19B—C20B—C21B	179.7 (4)
C13A—C14A—C15A—C16A	1.3 (7)	C19B—C20B—C21B—C22B	−2.2 (8)
C14A—C15A—C16A—C17A	−0.8 (7)	C20B—C21B—C22B—C23B	0.2 (9)
C15A—C16A—C17A—C18A	−1.0 (7)	C21B—C22B—C23B—C24B	2.6 (9)
C16A—C17A—C18A—C13A	2.4 (7)	C20B—C19B—C24B—C23B	1.5 (7)
C14A—C13A—C18A—C17A	−1.9 (6)	P1B—C19B—C24B—C23B	−177.0 (4)
P2A—C13A—C18A—C17A	179.8 (3)	C22B—C23B—C24B—C19B	−3.4 (8)
C25A—P1A—C19A—C20A	8.1 (4)	C19B—P1B—C25B—C26B	162.3 (3)
C31A—P1A—C19A—C20A	112.5 (3)	C31B—P1B—C25B—C26B	−89.7 (4)
Pt1A—P1A—C19A—C20A	−113.1 (3)	Pt1B—P1B—C25B—C26B	35.5 (4)
C25A—P1A—C19A—C24A	−172.6 (3)	C19B—P1B—C25B—C30B	−20.9 (4)
C31A—P1A—C19A—C24A	−68.2 (3)	C31B—P1B—C25B—C30B	87.2 (4)
Pt1A—P1A—C19A—C24A	66.2 (3)	Pt1B—P1B—C25B—C30B	−147.6 (3)
C24A—C19A—C20A—C21A	0.6 (6)	C30B—C25B—C26B—C27B	−2.3 (7)
P1A—C19A—C20A—C21A	179.9 (3)	P1B—C25B—C26B—C27B	174.7 (4)
C19A—C20A—C21A—C22A	−0.1 (7)	C25B—C26B—C27B—C28B	0.1 (7)
C20A—C21A—C22A—C23A	0.3 (7)	C26B—C27B—C28B—C29B	1.5 (7)
C21A—C22A—C23A—C24A	−1.0 (7)	C27B—C28B—C29B—C30B	−0.9 (7)
C20A—C19A—C24A—C23A	−1.3 (6)	C28B—C29B—C30B—C25B	−1.3 (7)
P1A—C19A—C24A—C23A	179.4 (3)	C26B—C25B—C30B—C29B	2.9 (6)
C22A—C23A—C24A—C19A	1.5 (7)	P1B—C25B—C30B—C29B	−174.0 (3)
C19A—P1A—C25A—C26A	−131.4 (3)	C19B—P1B—C31B—C32B	151.0 (3)
C31A—P1A—C25A—C26A	120.5 (3)	C25B—P1B—C31B—C32B	40.8 (4)
Pt1A—P1A—C25A—C26A	−10.1 (3)	Pt1B—P1B—C31B—C32B	−77.7 (3)
C19A—P1A—C25A—C30A	53.5 (3)	C19B—P1B—C31B—C36B	−31.0 (4)
C31A—P1A—C25A—C30A	−54.5 (3)	C25B—P1B—C31B—C36B	−141.1 (3)
Pt1A—P1A—C25A—C30A	174.9 (3)	Pt1B—P1B—C31B—C36B	100.4 (3)
C30A—C25A—C26A—C27A	−0.9 (5)	C36B—C31B—C32B—C33B	1.1 (6)
P1A—C25A—C26A—C27A	−176.0 (3)	P1B—C31B—C32B—C33B	179.2 (3)
C25A—C26A—C27A—C28A	−0.5 (6)	C31B—C32B—C33B—C34B	−0.8 (7)
C26A—C27A—C28A—C29A	0.5 (7)	C32B—C33B—C34B—C35B	0.0 (8)
C27A—C28A—C29A—C30A	1.1 (6)	C33B—C34B—C35B—C36B	0.6 (7)
C28A—C29A—C30A—C25A	−2.5 (6)	C34B—C35B—C36B—C31B	−0.3 (7)
C26A—C25A—C30A—C29A	2.4 (5)	C32B—C31B—C36B—C35B	−0.5 (6)
P1A—C25A—C30A—C29A	177.5 (3)	P1B—C31B—C36B—C35B	−178.6 (3)
C25A—P1A—C31A—C36A	−56.1 (3)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C11A—H11A···Cl2Aⁱ	0.93	2.75	3.486 (4)	136
C8B—H8BA···Cg1	0.93	2.75	3.395 (6)	127
C36B—H36B···Cg2	0.93	2.75	3.185 (6)	110

Symmetry code: (i) x, −y+1/2, z+1/2.

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