cis-[Bis(diphenyl­phosphino)ethane-κ²P,P′]dichloro­ruthenium(II) dichloromethane disolvate

The title compound, cis-[RuCl₂(C₂₆H₂₄P₂)₂]·2CH₂Cl₂, was obtained as an unexpected product from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Three solvates and a solvent-free structure of the isomeric complex with the chloride anions in a trans geometry have already been reported, while the cis isomer has been described only in solution studies prior to this work.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.008 Å
• Disorder in solvent or counterion
• R factor = 0.071
• wR factor = 0.182
• Data-to-parameter ratio = 18.6

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.97
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT221_ALERT_4_C Large Solvent/Anion Cl     Ueq(max)/Ueq(min) ...       3.45 Ratio
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C62A
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for       C62B
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C61
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....       2.16
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      33.00 Perc.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   8 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: COLLECT (Hooft, 1998); cell refinement: EVALCCD (Duisenberg et al., 2003); data reduction: EVALCCD; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Burnett & Johnson, 1996); software used to prepare material for publication: SHELXTL (Sheldrick, 2001) and CIFTAB (Sheldrick, 1993).

cis-[Bis(diphenylphosphino)ethane-κ₂P,P']dichlororuthenium(II) dichlomethane disolvate

Crystal data

[RuCl2(C26H24P2)2]·2CH2Cl2	F(000) = 2328
Mr = 1138.61	Dx = 1.464 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 7370 reflections
a = 17.054 (3) Å	θ = 2.5–27.5°
b = 13.182 (3) Å	µ = 0.77 mm^−1
c = 23.592 (5) Å	T = 173 K
β = 103.05 (3)°	Block, yellow
V = 5167 (2) Å^3	0.20 × 0.15 × 0.15 mm
Z = 4

Data collection

Nonius KappaCCD diffractometer	11446 independent reflections
Radiation source: fine-focus sealed tube	7242 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.100
φ and ω scans	θmax = 27.5°, θmin = 5.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 2003)	h = −22→18
Tmin = 0.861, Tmax = 0.893	k = −16→15
29691 measured reflections	l = −30→30

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.071	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.182	H-atom parameters constrained
S = 1.04	w = 1/[σ^2(Fo^2) + (0.0675P)^2] where P = (Fo^2 + 2Fc^2)/3
11446 reflections	(Δ/σ)max = 0.001
614 parameters	Δρmax = 1.19 e Å^−3
43 restraints	Δρmin = −1.22 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.36918 (2)	0.50617 (3)	0.171098 (15)	0.01901 (13)
P1	0.32812 (8)	0.37481 (10)	0.10134 (5)	0.0211 (3)
Cl1	0.47712 (7)	0.39284 (10)	0.22311 (5)	0.0265 (3)
Cl2	0.27927 (7)	0.42665 (10)	0.22731 (5)	0.0256 (3)
C2	0.2228 (3)	0.3553 (4)	0.0628 (2)	0.0270 (12)
C3	0.1913 (3)	0.4082 (5)	0.0123 (2)	0.0380 (15)
H3A	0.2243	0.4539	−0.0030	0.046*
C4	0.1105 (4)	0.3943 (6)	−0.0164 (3)	0.0537 (19)
H4A	0.0886	0.4314	−0.0509	0.064*
C5	0.0624 (4)	0.3262 (6)	0.0055 (3)	0.0532 (18)
H5A	0.0082	0.3153	−0.0146	0.064*
C6	0.0934 (4)	0.2750 (5)	0.0563 (3)	0.0445 (16)
H6A	0.0601	0.2301	0.0718	0.053*
C7	0.1730 (3)	0.2882 (4)	0.0850 (2)	0.0320 (13)
H7A	0.1941	0.2518	0.1199	0.038*
C8	0.3514 (3)	0.2407 (4)	0.1229 (2)	0.0250 (11)
C9	0.3583 (3)	0.1696 (4)	0.0792 (2)	0.0339 (13)
H9A	0.3559	0.1921	0.0406	0.041*
C10	0.3685 (4)	0.0670 (5)	0.0926 (3)	0.0412 (15)
H10A	0.3736	0.0201	0.0631	0.049*
C11	0.3712 (4)	0.0324 (4)	0.1482 (3)	0.0371 (14)
H11A	0.3776	−0.0379	0.1568	0.045*
C12	0.3644 (3)	0.1023 (4)	0.1919 (2)	0.0329 (13)
H12A	0.3661	0.0792	0.2304	0.039*
C13	0.3552 (3)	0.2056 (4)	0.1788 (2)	0.0262 (12)
H13A	0.3515	0.2525	0.2087	0.031*
C14	0.3798 (3)	0.3932 (4)	0.04075 (19)	0.0261 (12)
H14A	0.4295	0.3518	0.0478	0.031*
H14B	0.3442	0.3705	0.0038	0.031*
C15	0.4012 (3)	0.5055 (4)	0.0360 (2)	0.0240 (11)
H15A	0.3518	0.5441	0.0188	0.029*
H15B	0.4388	0.5123	0.0098	0.029*
P16	0.44846 (8)	0.55994 (10)	0.10830 (5)	0.0210 (3)
C17	0.4639 (3)	0.6930 (4)	0.0878 (2)	0.0246 (11)
C18	0.4605 (3)	0.7224 (4)	0.0300 (2)	0.0323 (13)
H18A	0.4414	0.6754	−0.0005	0.039*
C19	0.4845 (4)	0.8187 (5)	0.0162 (2)	0.0399 (15)
H19A	0.4806	0.8371	−0.0233	0.048*
C20	0.5142 (4)	0.8880 (5)	0.0605 (2)	0.0409 (15)
H20A	0.5323	0.9529	0.0516	0.049*
C21	0.5169 (4)	0.8607 (4)	0.1178 (2)	0.0356 (14)
H21A	0.5354	0.9083	0.1481	0.043*
C22	0.4929 (3)	0.7655 (4)	0.1311 (2)	0.0292 (12)
H22A	0.4961	0.7485	0.1707	0.035*
C23	0.5541 (3)	0.5169 (4)	0.11597 (19)	0.0249 (12)
C24	0.6173 (3)	0.5843 (4)	0.1139 (2)	0.0274 (12)
H24A	0.6068	0.6552	0.1120	0.033*
C25	0.6950 (3)	0.5506 (5)	0.1143 (2)	0.0325 (13)
H25A	0.7364	0.5983	0.1134	0.039*
C26	0.7119 (4)	0.4474 (5)	0.1161 (2)	0.0372 (14)
H26A	0.7643	0.4240	0.1154	0.045*
C27	0.6508 (3)	0.3787 (5)	0.1190 (2)	0.0348 (14)
H27A	0.6622	0.3081	0.1205	0.042*
C28	0.5741 (3)	0.4112 (4)	0.1197 (2)	0.0293 (12)
H28A	0.5340	0.3627	0.1228	0.035*
P31	0.40949 (8)	0.60849 (11)	0.25642 (5)	0.0221 (3)
C32	0.4174 (3)	0.5471 (4)	0.32734 (19)	0.0268 (12)
C33	0.4908 (4)	0.5087 (5)	0.3582 (2)	0.0392 (15)
H33A	0.5379	0.5159	0.3434	0.047*
C34	0.4942 (4)	0.4590 (5)	0.4118 (2)	0.0521 (18)
H34A	0.5442	0.4317	0.4323	0.063*
C35	0.4275 (4)	0.4487 (5)	0.4352 (3)	0.0496 (18)
H35A	0.4311	0.4148	0.4713	0.060*
C36	0.3563 (4)	0.4883 (5)	0.4054 (2)	0.0415 (15)
H36A	0.3101	0.4835	0.4215	0.050*
C37	0.3497 (4)	0.5357 (4)	0.3518 (2)	0.0334 (13)
H37A	0.2989	0.5608	0.3314	0.040*
C38	0.5045 (3)	0.6794 (4)	0.2689 (2)	0.0278 (12)
C39	0.5118 (4)	0.7811 (5)	0.2875 (2)	0.0381 (14)
H39A	0.4667	0.8148	0.2962	0.046*
C40	0.5842 (4)	0.8331 (5)	0.2932 (3)	0.0516 (18)
H40A	0.5878	0.9022	0.3048	0.062*
C41	0.6510 (4)	0.7842 (6)	0.2820 (3)	0.0522 (19)
H41A	0.7004	0.8197	0.2862	0.063*
C42	0.6455 (4)	0.6827 (5)	0.2645 (2)	0.0417 (16)
H42A	0.6914	0.6491	0.2570	0.050*
C43	0.5732 (3)	0.6308 (5)	0.2581 (2)	0.0336 (13)
H43A	0.5700	0.5617	0.2462	0.040*
C44	0.3321 (3)	0.7066 (4)	0.2518 (2)	0.0267 (12)
H44A	0.2834	0.6778	0.2619	0.032*
H44B	0.3524	0.7627	0.2791	0.032*
C45	0.3122 (3)	0.7460 (4)	0.18863 (19)	0.0255 (12)
H45A	0.3609	0.7747	0.1786	0.031*
H45B	0.2706	0.7997	0.1839	0.031*
P46	0.27461 (8)	0.63683 (10)	0.14103 (5)	0.0216 (3)
C47	0.1708 (3)	0.6241 (4)	0.15143 (19)	0.0244 (11)
C48	0.1304 (3)	0.5302 (4)	0.1407 (2)	0.0258 (12)
H48A	0.1585	0.4719	0.1322	0.031*
C49	0.0501 (3)	0.5224 (4)	0.1424 (2)	0.0312 (13)
H49A	0.0234	0.4591	0.1342	0.037*
C50	0.0079 (3)	0.6060 (5)	0.1558 (2)	0.0376 (14)
H50A	−0.0470	0.5993	0.1574	0.045*
C51	0.0466 (3)	0.6997 (5)	0.1670 (2)	0.0352 (14)
H51A	0.0183	0.7570	0.1765	0.042*
C52	0.1268 (3)	0.7085 (4)	0.1641 (2)	0.0305 (13)
H52A	0.1526	0.7727	0.1708	0.037*
C53	0.2472 (3)	0.6981 (4)	0.0678 (2)	0.0253 (12)
C54	0.2844 (3)	0.7845 (4)	0.0532 (2)	0.0327 (13)
H54A	0.3276	0.8140	0.0809	0.039*
C55	0.2588 (4)	0.8294 (5)	−0.0021 (2)	0.0430 (16)
H55A	0.2845	0.8892	−0.0113	0.052*
C56	0.1973 (4)	0.7874 (5)	−0.0429 (3)	0.0460 (17)
H56A	0.1810	0.8168	−0.0805	0.055*
C57	0.1593 (4)	0.7015 (5)	−0.0285 (2)	0.0466 (17)
H57A	0.1161	0.6725	−0.0564	0.056*
C58	0.1830 (3)	0.6570 (5)	0.0259 (2)	0.0353 (14)
H58A	0.1557	0.5985	0.0349	0.042*
C61	0.9226 (5)	0.6535 (6)	0.2881 (3)	0.069 (2)
H61A	0.9744	0.6250	0.2831	0.083*
H61B	0.9250	0.7282	0.2842	0.083*
Cl3	0.90924 (17)	0.62320 (17)	0.35642 (9)	0.0951 (8)
Cl4	0.84392 (12)	0.6054 (2)	0.23400 (9)	0.0910 (8)
C62A	0.7653 (8)	0.3532 (15)	0.3482 (5)	0.075 (5)	0.552 (8)
H62A	0.8090	0.4004	0.3444	0.090*	0.552 (8)
H62B	0.7814	0.2842	0.3387	0.090*	0.552 (8)
Cl5A	0.6785 (3)	0.3871 (4)	0.2989 (2)	0.091 (2)	0.552 (8)
Cl6A	0.7548 (5)	0.3549 (9)	0.4195 (3)	0.176 (4)	0.552 (8)
C62B	0.678 (2)	0.356 (2)	0.3500 (11)	0.191 (16)	0.448 (8)
H62C	0.6219	0.3807	0.3385	0.230*	0.448 (8)
H62D	0.6860	0.3037	0.3217	0.230*	0.448 (8)
Cl5B	0.7425 (9)	0.4536 (15)	0.3495 (8)	0.314 (11)	0.448 (8)
Cl6B	0.6953 (9)	0.3064 (10)	0.4166 (5)	0.199 (6)	0.448 (8)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ru1	0.0188 (2)	0.0195 (2)	0.0192 (2)	0.00052 (17)	0.00520 (15)	0.00045 (16)
P1	0.0202 (7)	0.0222 (8)	0.0204 (6)	0.0003 (6)	0.0035 (5)	0.0003 (5)
Cl1	0.0248 (7)	0.0246 (7)	0.0293 (6)	0.0026 (5)	0.0047 (5)	0.0040 (5)
Cl2	0.0250 (7)	0.0259 (7)	0.0276 (6)	−0.0026 (5)	0.0096 (5)	0.0024 (5)
C2	0.028 (3)	0.025 (3)	0.027 (3)	0.001 (2)	0.004 (2)	−0.010 (2)
C3	0.028 (3)	0.051 (4)	0.032 (3)	0.001 (3)	0.001 (2)	0.001 (3)
C4	0.034 (4)	0.074 (6)	0.044 (4)	−0.007 (4)	−0.010 (3)	0.009 (3)
C5	0.023 (4)	0.067 (5)	0.062 (4)	−0.007 (3)	−0.007 (3)	−0.007 (4)
C6	0.025 (3)	0.043 (4)	0.065 (4)	−0.011 (3)	0.011 (3)	−0.007 (3)
C7	0.026 (3)	0.027 (3)	0.040 (3)	−0.003 (2)	0.002 (2)	−0.001 (2)
C8	0.019 (3)	0.022 (3)	0.032 (3)	−0.002 (2)	0.003 (2)	−0.007 (2)
C9	0.044 (4)	0.024 (3)	0.035 (3)	0.005 (3)	0.012 (2)	0.002 (2)
C10	0.047 (4)	0.026 (4)	0.053 (4)	−0.001 (3)	0.017 (3)	−0.012 (3)
C11	0.041 (4)	0.020 (3)	0.051 (4)	0.004 (3)	0.011 (3)	0.006 (3)
C12	0.029 (3)	0.032 (3)	0.035 (3)	0.000 (3)	0.001 (2)	0.008 (3)
C13	0.023 (3)	0.022 (3)	0.031 (3)	−0.004 (2)	0.003 (2)	−0.002 (2)
C14	0.029 (3)	0.031 (3)	0.019 (2)	−0.003 (2)	0.008 (2)	−0.003 (2)
C15	0.024 (3)	0.025 (3)	0.024 (2)	−0.002 (2)	0.008 (2)	0.001 (2)
P16	0.0220 (7)	0.0208 (8)	0.0210 (6)	0.0005 (6)	0.0064 (5)	0.0003 (5)
C17	0.024 (3)	0.021 (3)	0.031 (3)	0.005 (2)	0.009 (2)	−0.003 (2)
C18	0.039 (4)	0.030 (3)	0.032 (3)	0.002 (3)	0.016 (2)	−0.002 (2)
C19	0.051 (4)	0.036 (4)	0.037 (3)	0.007 (3)	0.018 (3)	0.010 (3)
C20	0.059 (4)	0.022 (3)	0.047 (4)	0.000 (3)	0.024 (3)	0.010 (3)
C21	0.043 (4)	0.026 (3)	0.041 (3)	−0.002 (3)	0.015 (3)	−0.008 (3)
C22	0.031 (3)	0.027 (3)	0.033 (3)	−0.001 (2)	0.014 (2)	0.004 (2)
C23	0.029 (3)	0.028 (3)	0.020 (2)	−0.002 (2)	0.008 (2)	−0.002 (2)
C24	0.023 (3)	0.030 (3)	0.029 (3)	0.000 (2)	0.004 (2)	−0.001 (2)
C25	0.024 (3)	0.041 (4)	0.031 (3)	−0.004 (3)	0.004 (2)	0.002 (3)
C26	0.029 (3)	0.049 (4)	0.035 (3)	0.011 (3)	0.010 (2)	0.007 (3)
C27	0.038 (4)	0.033 (4)	0.035 (3)	0.014 (3)	0.011 (2)	0.009 (3)
C28	0.028 (3)	0.033 (3)	0.026 (3)	0.002 (3)	0.005 (2)	0.004 (2)
P31	0.0209 (7)	0.0246 (8)	0.0216 (6)	0.0000 (6)	0.0063 (5)	−0.0010 (5)
C32	0.032 (3)	0.027 (3)	0.021 (2)	0.000 (2)	0.006 (2)	−0.001 (2)
C33	0.032 (3)	0.051 (4)	0.032 (3)	0.003 (3)	0.001 (2)	0.004 (3)
C34	0.054 (5)	0.060 (5)	0.036 (3)	0.012 (4)	−0.005 (3)	0.019 (3)
C35	0.068 (5)	0.049 (5)	0.034 (3)	0.000 (4)	0.017 (3)	0.008 (3)
C36	0.058 (4)	0.035 (4)	0.036 (3)	−0.003 (3)	0.021 (3)	−0.002 (3)
C37	0.039 (4)	0.032 (3)	0.030 (3)	−0.005 (3)	0.010 (2)	0.004 (2)
C38	0.029 (3)	0.031 (3)	0.022 (3)	−0.004 (2)	0.004 (2)	−0.001 (2)
C39	0.034 (4)	0.040 (4)	0.040 (3)	−0.011 (3)	0.009 (3)	−0.010 (3)
C40	0.047 (4)	0.044 (4)	0.066 (4)	−0.023 (3)	0.019 (3)	−0.016 (3)
C41	0.034 (4)	0.073 (6)	0.052 (4)	−0.030 (4)	0.013 (3)	−0.019 (4)
C42	0.023 (3)	0.057 (5)	0.046 (3)	−0.010 (3)	0.009 (3)	−0.010 (3)
C43	0.030 (3)	0.040 (4)	0.030 (3)	−0.001 (3)	0.005 (2)	−0.002 (3)
C44	0.025 (3)	0.027 (3)	0.029 (3)	0.002 (2)	0.010 (2)	−0.005 (2)
C45	0.026 (3)	0.021 (3)	0.029 (3)	0.002 (2)	0.007 (2)	0.005 (2)
P46	0.0208 (7)	0.0216 (8)	0.0228 (6)	0.0023 (6)	0.0061 (5)	0.0012 (5)
C47	0.023 (3)	0.029 (3)	0.022 (2)	0.002 (2)	0.005 (2)	0.002 (2)
C48	0.025 (3)	0.028 (3)	0.024 (3)	0.004 (2)	0.006 (2)	0.002 (2)
C49	0.023 (3)	0.036 (4)	0.032 (3)	−0.001 (3)	0.001 (2)	−0.003 (2)
C50	0.023 (3)	0.053 (4)	0.037 (3)	0.002 (3)	0.007 (2)	−0.003 (3)
C51	0.025 (3)	0.042 (4)	0.039 (3)	0.007 (3)	0.009 (2)	−0.008 (3)
C52	0.023 (3)	0.032 (3)	0.036 (3)	0.007 (2)	0.005 (2)	−0.002 (2)
C53	0.027 (3)	0.022 (3)	0.028 (3)	0.008 (2)	0.010 (2)	0.003 (2)
C54	0.031 (3)	0.035 (4)	0.032 (3)	0.005 (3)	0.008 (2)	0.002 (2)
C55	0.049 (4)	0.042 (4)	0.041 (3)	0.012 (3)	0.017 (3)	0.020 (3)
C56	0.042 (4)	0.061 (5)	0.036 (3)	0.018 (3)	0.010 (3)	0.013 (3)
C57	0.045 (4)	0.062 (5)	0.030 (3)	0.003 (3)	0.003 (3)	0.001 (3)
C58	0.030 (3)	0.045 (4)	0.029 (3)	−0.008 (3)	0.004 (2)	−0.003 (3)
C61	0.051 (5)	0.073 (6)	0.075 (5)	−0.009 (4)	−0.004 (4)	−0.010 (4)
Cl3	0.151 (2)	0.0539 (14)	0.0672 (13)	0.0325 (14)	−0.0026 (13)	−0.0025 (10)
Cl4	0.0424 (12)	0.156 (3)	0.0767 (13)	−0.0028 (13)	0.0180 (9)	−0.0398 (14)
C62A	0.041 (9)	0.069 (12)	0.117 (13)	0.025 (8)	0.021 (8)	0.010 (10)
Cl5A	0.076 (3)	0.085 (4)	0.098 (3)	0.022 (3)	−0.008 (2)	−0.003 (2)
Cl6A	0.128 (7)	0.306 (12)	0.082 (4)	0.008 (7)	0.001 (4)	0.036 (5)
C62B	0.16 (3)	0.17 (3)	0.22 (4)	−0.04 (3)	0.00 (3)	0.08 (3)
Cl5B	0.211 (14)	0.31 (2)	0.38 (2)	−0.103 (14)	−0.015 (13)	0.164 (17)
Cl6B	0.204 (13)	0.192 (12)	0.233 (11)	0.067 (9)	0.118 (10)	0.111 (9)

Geometric parameters (Å, º)

Ru1—P1	2.3825 (14)	C32—C33	1.394 (7)
Ru1—Cl1	2.4710 (14)	C32—C37	1.409 (7)
Ru1—Cl2	2.4752 (13)	C33—H33A	0.9500
Ru1—P16	2.3301 (14)	C33—C34	1.413 (8)
Ru1—P31	2.3915 (14)	C34—H34A	0.9500
Ru1—P46	2.3568 (14)	C34—C35	1.380 (9)
P1—C2	1.839 (5)	C35—H35A	0.9500
P1—C8	1.857 (5)	C35—C36	1.364 (9)
P1—C14	1.857 (5)	C36—H36A	0.9500
C2—C3	1.380 (7)	C36—C37	1.392 (7)
C2—C7	1.407 (7)	C37—H37A	0.9500
C3—H3A	0.9500	C38—C39	1.407 (8)
C3—C4	1.404 (8)	C38—C43	1.409 (7)
C4—H4A	0.9500	C39—H39A	0.9500
C4—C5	1.393 (9)	C39—C40	1.391 (8)
C5—H5A	0.9500	C40—H40A	0.9500
C5—C6	1.372 (9)	C40—C41	1.385 (9)
C6—H6A	0.9500	C41—H41A	0.9500
C6—C7	1.385 (8)	C41—C42	1.397 (9)
C7—H7A	0.9500	C42—H42A	0.9500
C8—C9	1.417 (7)	C42—C43	1.389 (8)
C8—C13	1.386 (7)	C43—H43A	0.9500
C9—H9A	0.9500	C44—H44A	0.9900
C9—C10	1.391 (8)	C44—H44B	0.9900
C10—H10A	0.9500	C44—C45	1.541 (6)
C10—C11	1.378 (8)	C45—H45A	0.9900
C11—H11A	0.9500	C45—H45B	0.9900
C11—C12	1.408 (8)	C45—P46	1.848 (5)
C12—H12A	0.9500	P46—C47	1.850 (5)
C12—C13	1.398 (7)	P46—C53	1.869 (5)
C13—H13A	0.9500	C47—C48	1.412 (7)
C14—H14A	0.9900	C47—C52	1.412 (7)
C14—H14B	0.9900	C48—H48A	0.9500
C14—C15	1.535 (7)	C48—C49	1.382 (7)
C15—H15A	0.9900	C49—H49A	0.9500
C15—H15B	0.9900	C49—C50	1.391 (8)
C15—P16	1.858 (5)	C50—H50A	0.9500
P16—C17	1.854 (5)	C50—C51	1.398 (8)
P16—C23	1.858 (5)	C51—H51A	0.9500
C17—C18	1.407 (7)	C51—C52	1.390 (7)
C17—C22	1.405 (7)	C52—H52A	0.9500
C18—H18A	0.9500	C53—C54	1.384 (7)
C18—C19	1.394 (8)	C53—C58	1.407 (7)
C19—H19A	0.9500	C54—H54A	0.9500
C19—C20	1.394 (8)	C54—C55	1.410 (7)
C20—H20A	0.9500	C55—H55A	0.9500
C20—C21	1.389 (7)	C55—C56	1.369 (9)
C21—H21A	0.9500	C56—H56A	0.9500
C21—C22	1.378 (7)	C56—C57	1.385 (9)
C22—H22A	0.9500	C57—H57A	0.9500
C23—C24	1.408 (7)	C57—C58	1.384 (8)
C23—C28	1.432 (7)	C58—H58A	0.9500
C24—H24A	0.9500	C61—H61A	0.9900
C24—C25	1.394 (7)	C61—H61B	0.9900
C25—H25A	0.9500	C61—Cl3	1.724 (8)
C25—C26	1.389 (8)	C61—Cl4	1.749 (7)
C26—H26A	0.9500	C62A—H62A	0.9900
C26—C27	1.393 (8)	C62A—H62B	0.9900
C27—H27A	0.9500	C62A—Cl5A	1.722 (11)
C27—C28	1.381 (7)	C62A—Cl6A	1.732 (12)
C28—H28A	0.9500	C62B—H62C	0.9900
P31—C32	1.836 (5)	C62B—H62D	0.9900
P31—C38	1.836 (6)	C62B—Cl5B	1.692 (16)
P31—C44	1.833 (5)	C62B—Cl6B	1.668 (17)
P1—Ru1—Cl1	88.48 (5)	Ru1—P31—C44	106.35 (17)
P1—Ru1—Cl2	86.63 (5)	C32—P31—C38	101.4 (2)
P1—Ru1—P16	84.50 (5)	C32—P31—C44	105.6 (2)
P1—Ru1—P31	167.19 (5)	C38—P31—C44	104.3 (3)
P1—Ru1—P46	104.41 (5)	P31—C32—C33	120.6 (4)
Cl1—Ru1—Cl2	87.71 (4)	P31—C32—C37	121.4 (4)
Cl1—Ru1—P16	91.46 (5)	C33—C32—C37	118.0 (5)
Cl1—Ru1—P31	83.26 (5)	C32—C33—H33A	120.4
Cl1—Ru1—P46	166.84 (4)	C32—C33—C34	119.1 (6)
Cl2—Ru1—P16	171.11 (5)	H33A—C33—C34	120.4
Cl2—Ru1—P31	83.28 (5)	C33—C34—H34A	118.9
Cl2—Ru1—P46	90.35 (5)	C33—C34—C35	122.2 (6)
P16—Ru1—P31	105.41 (5)	H34A—C34—C35	118.9
P16—Ru1—P46	92.42 (5)	C34—C35—H35A	120.8
P31—Ru1—P46	83.58 (5)	C34—C35—C36	118.4 (6)
Ru1—P1—C2	123.04 (17)	H35A—C35—C36	120.8
Ru1—P1—C8	119.43 (16)	C35—C36—H36A	119.3
Ru1—P1—C14	108.67 (17)	C35—C36—C37	121.4 (6)
C2—P1—C8	97.3 (2)	H36A—C36—C37	119.3
C2—P1—C14	102.6 (2)	C32—C37—C36	120.9 (5)
C8—P1—C14	103.0 (2)	C32—C37—H37A	119.5
P1—C2—C3	120.2 (4)	C36—C37—H37A	119.5
P1—C2—C7	120.5 (4)	P31—C38—C39	123.3 (4)
C3—C2—C7	119.3 (5)	P31—C38—C43	118.6 (4)
C2—C3—H3A	120.0	C39—C38—C43	118.1 (5)
C2—C3—C4	120.0 (6)	C38—C39—H39A	119.5
H3A—C3—C4	120.0	C38—C39—C40	120.9 (6)
C3—C4—H4A	120.0	H39A—C39—C40	119.5
C3—C4—C5	120.1 (6)	C39—C40—H40A	119.9
H4A—C4—C5	120.0	C39—C40—C41	120.2 (7)
C4—C5—H5A	120.1	H40A—C40—C41	119.9
C4—C5—C6	119.8 (6)	C40—C41—H41A	120.0
H5A—C5—C6	120.1	C40—C41—C42	119.9 (6)
C5—C6—H6A	119.7	H41A—C41—C42	120.0
C5—C6—C7	120.5 (6)	C41—C42—H42A	119.9
H6A—C6—C7	119.7	C41—C42—C43	120.2 (6)
C2—C7—C6	120.2 (5)	H42A—C42—C43	119.9
C2—C7—H7A	119.9	C38—C43—C42	120.7 (6)
C6—C7—H7A	119.9	C38—C43—H43A	119.7
P1—C8—C9	118.6 (4)	C42—C43—H43A	119.7
P1—C8—C13	122.6 (4)	P31—C44—H44A	110.3
C9—C8—C13	118.5 (5)	P31—C44—H44B	110.3
C8—C9—H9A	119.8	P31—C44—C45	107.1 (3)
C8—C9—C10	120.3 (5)	H44A—C44—H44B	108.6
H9A—C9—C10	119.8	H44A—C44—C45	110.3
C9—C10—H10A	119.6	H44B—C44—C45	110.3
C9—C10—C11	120.9 (5)	C44—C45—H45A	110.3
H10A—C10—C11	119.6	C44—C45—H45B	110.3
C10—C11—H11A	120.3	C44—C45—P46	107.2 (3)
C10—C11—C12	119.3 (5)	H45A—C45—H45B	108.5
H11A—C11—C12	120.3	H45A—C45—P46	110.3
C11—C12—H12A	120.0	H45B—C45—P46	110.3
C11—C12—C13	120.0 (5)	Ru1—P46—C45	105.43 (17)
H12A—C12—C13	120.0	Ru1—P46—C47	120.29 (17)
C8—C13—C12	121.0 (5)	Ru1—P46—C53	127.25 (16)
C8—C13—H13A	119.5	C45—P46—C47	101.6 (2)
C12—C13—H13A	119.5	C45—P46—C53	101.9 (2)
P1—C14—H14A	109.6	C47—P46—C53	96.6 (2)
P1—C14—H14B	109.6	P46—C47—C48	119.9 (4)
P1—C14—C15	110.2 (3)	P46—C47—C52	121.8 (4)
H14A—C14—H14B	108.1	C48—C47—C52	118.0 (5)
H14A—C14—C15	109.6	C47—C48—H48A	119.8
H14B—C14—C15	109.6	C47—C48—C49	120.4 (5)
C14—C15—H15A	109.3	H48A—C48—C49	119.8
C14—C15—H15B	109.3	C48—C49—H49A	119.5
C14—C15—P16	111.5 (3)	C48—C49—C50	121.0 (5)
H15A—C15—H15B	108.0	H49A—C49—C50	119.5
H15A—C15—P16	109.3	C49—C50—H50A	120.1
H15B—C15—P16	109.3	C49—C50—C51	119.8 (5)
Ru1—P16—C15	105.83 (16)	H50A—C50—C51	120.1
Ru1—P16—C17	126.18 (16)	C50—C51—H51A	120.3
Ru1—P16—C23	122.28 (16)	C50—C51—C52	119.5 (5)
C15—P16—C17	100.6 (2)	H51A—C51—C52	120.3
C15—P16—C23	100.4 (2)	C47—C52—C51	121.4 (5)
C17—P16—C23	97.1 (2)	C47—C52—H52A	119.3
P16—C17—C18	122.4 (4)	C51—C52—H52A	119.3
P16—C17—C22	120.1 (4)	P46—C53—C54	123.5 (4)
C18—C17—C22	116.6 (5)	P46—C53—C58	118.4 (4)
C17—C18—H18A	119.1	C54—C53—C58	118.0 (5)
C17—C18—C19	121.8 (5)	C53—C54—H54A	119.6
H18A—C18—C19	119.1	C53—C54—C55	120.7 (5)
C18—C19—H19A	120.1	H54A—C54—C55	119.6
C18—C19—C20	119.8 (5)	C54—C55—H55A	119.7
H19A—C19—C20	120.1	C54—C55—C56	120.6 (6)
C19—C20—H20A	120.4	H55A—C55—C56	119.7
C19—C20—C21	119.2 (5)	C55—C56—H56A	120.5
H20A—C20—C21	120.4	C55—C56—C57	119.0 (5)
C20—C21—H21A	119.6	H56A—C56—C57	120.5
C20—C21—C22	120.7 (5)	C56—C57—H57A	119.4
H21A—C21—C22	119.6	C56—C57—C58	121.2 (6)
C17—C22—C21	121.8 (5)	H57A—C57—C58	119.4
C17—C22—H22A	119.1	C53—C58—C57	120.4 (6)
C21—C22—H22A	119.1	C53—C58—H58A	119.8
P16—C23—C24	122.5 (4)	C57—C58—H58A	119.8
P16—C23—C28	121.0 (4)	H61A—C61—H61B	108.1
C24—C23—C28	116.3 (5)	H61A—C61—Cl3	109.5
C23—C24—H24A	118.9	H61A—C61—Cl4	109.5
C23—C24—C25	122.1 (5)	H61B—C61—Cl3	109.5
H24A—C24—C25	118.9	H61B—C61—Cl4	109.5
C24—C25—H25A	119.9	Cl3—C61—Cl4	110.9 (4)
C24—C25—C26	120.2 (5)	H62A—C62A—H62B	107.8
H25A—C25—C26	119.9	H62A—C62A—Cl5A	109.0
C25—C26—H26A	120.5	H62A—C62A—Cl6A	109.0
C25—C26—C27	119.1 (5)	H62B—C62A—Cl5A	109.0
H26A—C26—C27	120.5	H62B—C62A—Cl6A	109.0
C26—C27—H27A	119.3	Cl5A—C62A—Cl6A	113.0 (8)
C26—C27—C28	121.4 (6)	H62C—C62B—H62D	108.3
H27A—C27—C28	119.3	H62C—C62B—Cl5B	109.8
C23—C28—C27	120.9 (5)	H62C—C62B—Cl6B	109.8
C23—C28—H28A	119.6	H62D—C62B—Cl5B	109.8
C27—C28—H28A	119.6	H62D—C62B—Cl6B	109.8
Ru1—P31—C32	117.82 (18)	Cl5B—C62B—Cl6B	109.2 (16)
Ru1—P31—C38	119.88 (17)
Cl1—Ru1—P1—C2	148.0 (2)	Cl1—Ru1—P31—C32	−50.6 (2)
Cl1—Ru1—P1—C8	25.22 (19)	Cl1—Ru1—P31—C38	73.5 (2)
Cl1—Ru1—P1—C14	−92.43 (19)	Cl1—Ru1—P31—C44	−168.77 (18)
Cl2—Ru1—P1—C2	60.2 (2)	Cl2—Ru1—P31—C32	37.9 (2)
Cl2—Ru1—P1—C8	−62.58 (19)	Cl2—Ru1—P31—C38	161.9 (2)
Cl2—Ru1—P1—C14	179.77 (19)	Cl2—Ru1—P31—C44	−80.29 (18)
P16—Ru1—P1—C2	−120.4 (2)	P16—Ru1—P31—C32	−140.3 (2)
P16—Ru1—P1—C8	116.83 (19)	P16—Ru1—P31—C38	−16.2 (2)
P16—Ru1—P1—C14	−0.81 (19)	P16—Ru1—P31—C44	101.57 (18)
P31—Ru1—P1—C2	98.2 (3)	P46—Ru1—P31—C32	129.0 (2)
P31—Ru1—P1—C8	−24.5 (3)	P46—Ru1—P31—C38	−106.9 (2)
P31—Ru1—P1—C14	−142.2 (3)	P46—Ru1—P31—C44	10.83 (18)
P46—Ru1—P1—C2	−29.3 (2)	Ru1—P31—C32—C33	93.8 (5)
P46—Ru1—P1—C8	−152.08 (19)	Ru1—P31—C32—C37	−85.0 (5)
P46—Ru1—P1—C14	90.28 (19)	C38—P31—C32—C33	−39.1 (5)
Ru1—P1—C2—C3	86.2 (4)	C38—P31—C32—C37	142.1 (5)
Ru1—P1—C2—C7	−92.4 (4)	C44—P31—C32—C33	−147.6 (5)
C8—P1—C2—C3	−141.4 (4)	C44—P31—C32—C37	33.5 (5)
C8—P1—C2—C7	40.0 (5)	P31—C32—C33—C34	−177.9 (5)
C14—P1—C2—C3	−36.3 (5)	C37—C32—C33—C34	1.0 (8)
C14—P1—C2—C7	145.1 (4)	C32—C33—C34—C35	−1.2 (10)
P1—C2—C3—C4	−178.9 (5)	C33—C34—C35—C36	−0.1 (10)
C7—C2—C3—C4	−0.3 (9)	C34—C35—C36—C37	1.7 (10)
C2—C3—C4—C5	−0.9 (10)	C35—C36—C37—C32	−2.0 (9)
C3—C4—C5—C6	1.9 (11)	P31—C32—C37—C36	179.5 (4)
C4—C5—C6—C7	−1.8 (10)	C33—C32—C37—C36	0.6 (8)
C5—C6—C7—C2	0.7 (9)	Ru1—P31—C38—C39	135.2 (4)
P1—C2—C7—C6	179.0 (4)	Ru1—P31—C38—C43	−43.1 (4)
C3—C2—C7—C6	0.4 (8)	C32—P31—C38—C39	−93.2 (5)
Ru1—P1—C8—C9	−154.2 (4)	C32—P31—C38—C43	88.5 (4)
Ru1—P1—C8—C13	31.8 (5)	C44—P31—C38—C39	16.4 (5)
C2—P1—C8—C9	71.1 (4)	C44—P31—C38—C43	−161.9 (4)
C2—P1—C8—C13	−102.9 (4)	P31—C38—C39—C40	−176.4 (4)
C14—P1—C8—C9	−33.6 (5)	C43—C38—C39—C40	1.9 (8)
C14—P1—C8—C13	152.4 (4)	C38—C39—C40—C41	−1.6 (9)
P1—C8—C9—C10	−174.2 (5)	C39—C40—C41—C42	0.4 (10)
C13—C8—C9—C10	0.0 (8)	C40—C41—C42—C43	0.3 (9)
C8—C9—C10—C11	0.8 (9)	C41—C42—C43—C38	0.1 (8)
C9—C10—C11—C12	−0.7 (9)	P31—C38—C43—C42	177.2 (4)
C10—C11—C12—C13	−0.1 (8)	C39—C38—C43—C42	−1.2 (7)
P1—C8—C13—C12	173.1 (4)	Ru1—P31—C44—C45	−43.5 (4)
C9—C8—C13—C12	−0.9 (8)	C32—P31—C44—C45	−169.4 (3)
C11—C12—C13—C8	0.9 (8)	C38—P31—C44—C45	84.2 (4)
Ru1—P1—C14—C15	−26.1 (4)	P31—C44—C45—P46	60.2 (4)
C2—P1—C14—C15	105.5 (4)	C44—C45—P46—Ru1	−49.1 (3)
C8—P1—C14—C15	−153.8 (3)	C44—C45—P46—C47	77.1 (4)
P1—C14—C15—P16	46.7 (4)	C44—C45—P46—C53	176.5 (3)
C14—C15—P16—Ru1	−46.0 (4)	P1—Ru1—P46—C45	−172.98 (16)
C14—C15—P16—C17	−178.7 (4)	P1—Ru1—P46—C47	73.26 (18)
C14—C15—P16—C23	82.0 (4)	P1—Ru1—P46—C53	−54.4 (2)
P1—Ru1—P16—C15	22.09 (18)	Cl1—Ru1—P46—C45	19.0 (3)
P1—Ru1—P16—C17	138.4 (2)	Cl1—Ru1—P46—C47	−94.8 (3)
P1—Ru1—P16—C23	−91.6 (2)	Cl1—Ru1—P46—C53	137.5 (3)
P31—Ru1—P16—C15	−166.16 (17)	Cl2—Ru1—P46—C45	100.41 (17)
P31—Ru1—P16—C17	−49.8 (2)	Cl2—Ru1—P46—C47	−13.35 (18)
P31—Ru1—P16—C23	80.1 (2)	Cl2—Ru1—P46—C53	−141.0 (2)
P46—Ru1—P16—C15	−82.15 (18)	P16—Ru1—P46—C45	−88.04 (17)
P46—Ru1—P16—C17	34.2 (2)	P16—Ru1—P46—C47	158.20 (18)
P46—Ru1—P16—C23	164.1 (2)	P16—Ru1—P46—C53	30.5 (2)
Ru1—P16—C17—C18	−135.0 (4)	P31—Ru1—P46—C45	17.21 (17)
Ru1—P16—C17—C22	55.8 (5)	P31—Ru1—P46—C47	−96.55 (18)
C15—P16—C17—C18	−16.2 (5)	P31—Ru1—P46—C53	135.8 (2)
C15—P16—C17—C22	174.6 (4)	Ru1—P46—C47—C48	−40.9 (4)
C23—P16—C17—C18	85.8 (4)	Ru1—P46—C47—C52	145.8 (3)
C23—P16—C17—C22	−83.4 (4)	C45—P46—C47—C48	−156.7 (4)
P16—C17—C18—C19	−169.8 (4)	C45—P46—C47—C52	30.0 (4)
C22—C17—C18—C19	−0.2 (8)	C53—P46—C47—C48	99.7 (4)
C17—C18—C19—C20	1.3 (8)	C53—P46—C47—C52	−73.6 (4)
C18—C19—C20—C21	−2.1 (9)	P46—C47—C48—C49	−173.2 (4)
C19—C20—C21—C22	2.0 (9)	C52—C47—C48—C49	0.3 (7)
C20—C21—C22—C17	−0.9 (8)	C47—C48—C49—C50	−1.3 (7)
P16—C17—C22—C21	169.8 (4)	C48—C49—C50—C51	0.9 (8)
C18—C17—C22—C21	0.0 (8)	C49—C50—C51—C52	0.5 (8)
Ru1—P16—C23—C24	−133.1 (3)	C50—C51—C52—C47	−1.5 (7)
Ru1—P16—C23—C28	52.0 (4)	P46—C47—C52—C51	174.5 (4)
C15—P16—C23—C24	110.5 (4)	C48—C47—C52—C51	1.1 (7)
C15—P16—C23—C28	−64.4 (4)	Ru1—P46—C53—C54	−91.9 (5)
C17—P16—C23—C24	8.4 (4)	Ru1—P46—C53—C58	91.1 (4)
C17—P16—C23—C28	−166.6 (4)	C45—P46—C53—C54	28.2 (5)
P16—C23—C24—C25	−174.0 (4)	C45—P46—C53—C58	−148.8 (4)
C28—C23—C24—C25	1.1 (7)	C47—P46—C53—C54	131.6 (5)
C23—C24—C25—C26	0.9 (7)	C47—P46—C53—C58	−45.4 (5)
C24—C25—C26—C27	−1.7 (7)	P46—C53—C54—C55	−177.5 (4)
C25—C26—C27—C28	0.4 (7)	C58—C53—C54—C55	−0.5 (8)
C26—C27—C28—C23	1.8 (7)	C53—C54—C55—C56	−0.8 (9)
P16—C23—C28—C27	172.8 (4)	C54—C55—C56—C57	1.5 (9)
C24—C23—C28—C27	−2.4 (6)	C55—C56—C57—C58	−0.8 (9)
P1—Ru1—P31—C32	−0.4 (3)	C56—C57—C58—C53	−0.6 (9)
P1—Ru1—P31—C38	123.7 (3)	P46—C53—C58—C57	178.4 (4)
P1—Ru1—P31—C44	−118.6 (3)	C54—C53—C58—C57	1.2 (8)