Di-μ-iodo-bis­[(1,10-phenanthroline-κ²N,N′)copper(I)] aceto­nitrile solvate

In the title complex, [Cu₂I₂(C₁₂H₈N₂)₂]·C₂H₃N, two Cu^I atoms are bridged by two I atoms and each Cu^I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.008 Å
• R factor = 0.041
• wR factor = 0.107
• Data-to-parameter ratio = 18.9

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  I1     -   Cu1     ..      21.67 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  I1     -   Cu2     ..      22.12 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  I2     -   Cu1     ..      19.06 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  I2     -   Cu2     ..      12.97 su

Alert level C
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C25
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          2
              C2 H3 N

   0 ALERT level A = In general: serious problem
   4 ALERT level B = Potentially serious problem
   2 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Di-µ₂-Iodo-bis[(1,10-phenanthroline-κ²N,N')copper(I)] acetonitrile solvate

Crystal data

[Cu2I2(C12H8N2)2]·C2H3N	F(000) = 1496
Mr = 782.36	Dx = 1.972 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 4519 reflections
a = 10.4920 (6) Å	θ = 2.6–26.0°
b = 23.6166 (13) Å	µ = 3.98 mm^−1
c = 10.6391 (6) Å	T = 295 K
β = 91.436 (1)°	Prism, red
V = 2635.4 (3) Å^3	0.25 × 0.16 × 0.15 mm
Z = 4

Data collection

Bruker APEX area-detector diffractometer	5991 independent reflections
Radiation source: fine-focus sealed tube	4466 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.029
φ and ω scans	θmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 2002)	h = −13→13
Tmin = 0.409, Tmax = 0.550	k = −30→30
16362 measured reflections	l = −10→13

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.041	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.107	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0544P)^2 + 0.5635P] where P = (Fo^2 + 2Fc^2)/3
5991 reflections	(Δ/σ)max = 0.001
317 parameters	Δρmax = 1.57 e Å^−3
0 restraints	Δρmin = −1.06 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
I1	0.47039 (3)	0.614041 (14)	0.29745 (3)	0.05763 (12)
I2	0.06800 (3)	0.588132 (17)	0.40901 (3)	0.06676 (13)
Cu1	0.23059 (6)	0.60719 (3)	0.23507 (5)	0.05500 (16)
Cu2	0.29632 (6)	0.62236 (2)	0.47009 (5)	0.05487 (16)
C1	0.1268 (4)	0.63606 (19)	−0.0094 (4)	0.0444 (9)
C2	0.1399 (5)	0.7182 (2)	0.1041 (5)	0.0601 (12)
H2	0.1614	0.7372	0.1783	0.072*
C3	0.0884 (5)	0.7497 (2)	0.0036 (6)	0.0739 (16)
H3	0.0770	0.7886	0.0110	0.089*
C4	0.0552 (5)	0.7225 (3)	−0.1050 (5)	0.0686 (15)
H4	0.0205	0.7428	−0.1725	0.082*
C5	0.0732 (4)	0.6646 (2)	−0.1152 (4)	0.0573 (12)
C6	0.0431 (5)	0.6321 (3)	−0.2260 (5)	0.0750 (17)
H6	0.0089	0.6504	−0.2965	0.090*
C7	0.0623 (5)	0.5769 (3)	−0.2309 (5)	0.0751 (16)
H7	0.0415	0.5574	−0.3045	0.090*
C8	0.1144 (4)	0.5465 (2)	−0.1254 (4)	0.0595 (13)
C9	0.1333 (6)	0.4873 (3)	−0.1247 (6)	0.0780 (16)
H9	0.1116	0.4658	−0.1952	0.094*
C10	0.1830 (5)	0.4625 (2)	−0.0207 (6)	0.0806 (17)
H10	0.1954	0.4235	−0.0190	0.097*
C11	0.2160 (5)	0.4949 (2)	0.0844 (5)	0.0630 (13)
H11	0.2522	0.4770	0.1545	0.076*
C12	0.1472 (4)	0.57570 (19)	−0.0151 (4)	0.0455 (10)
C13	0.3771 (3)	0.64695 (18)	0.7260 (4)	0.0426 (9)
C14	0.4047 (4)	0.5520 (2)	0.6970 (4)	0.0549 (11)
H14	0.3994	0.5202	0.6454	0.066*
C15	0.4495 (5)	0.5449 (2)	0.8205 (5)	0.0635 (13)
H15	0.4741	0.5093	0.8498	0.076*
C16	0.4567 (4)	0.5901 (2)	0.8962 (5)	0.0573 (12)
H16	0.4856	0.5858	0.9790	0.069*
C17	0.4214 (4)	0.6434 (2)	0.8525 (4)	0.0477 (10)
C18	0.4284 (5)	0.6941 (3)	0.9258 (5)	0.0650 (14)
H18	0.4577	0.6922	1.0089	0.078*
C19	0.3939 (5)	0.7440 (2)	0.8781 (5)	0.0698 (15)
H19	0.4012	0.7762	0.9281	0.084*
C20	0.3456 (4)	0.7494 (2)	0.7512 (5)	0.0555 (12)
C21	0.3022 (5)	0.8000 (2)	0.6967 (6)	0.0776 (16)
H21	0.3060	0.8335	0.7428	0.093*
C22	0.2548 (5)	0.8007 (2)	0.5776 (7)	0.0833 (18)
H22	0.2251	0.8342	0.5418	0.100*
C23	0.2510 (5)	0.7505 (2)	0.5091 (5)	0.0661 (13)
H23	0.2192	0.7514	0.4268	0.079*
C24	0.3363 (4)	0.70046 (17)	0.6760 (4)	0.0430 (9)
C25	−0.2762 (6)	0.6138 (4)	0.6593 (8)	0.089 (2)
C26	−0.2711 (6)	0.5687 (4)	0.5692 (7)	0.117 (3)
H26A	−0.1843	0.5627	0.5458	0.176*
H26B	−0.3217	0.5785	0.4960	0.176*
H26C	−0.3038	0.5346	0.6056	0.176*
N1	0.1595 (3)	0.66280 (16)	0.0992 (3)	0.0481 (8)
N2	0.1976 (3)	0.55025 (15)	0.0880 (3)	0.0475 (8)
N3	0.3694 (3)	0.60119 (15)	0.6494 (3)	0.0457 (8)
N4	0.2904 (3)	0.70142 (14)	0.5559 (3)	0.0490 (8)
N5	−0.2796 (7)	0.6481 (3)	0.7325 (9)	0.125 (3)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
I1	0.05207 (19)	0.0682 (2)	0.0524 (2)	−0.00030 (14)	−0.00392 (14)	−0.01020 (15)
I2	0.0624 (2)	0.0930 (3)	0.04467 (19)	−0.02340 (18)	−0.00263 (14)	−0.00242 (16)
Cu1	0.0653 (4)	0.0623 (4)	0.0369 (3)	−0.0036 (3)	−0.0099 (3)	−0.0005 (2)
Cu2	0.0648 (4)	0.0569 (3)	0.0423 (3)	−0.0046 (3)	−0.0106 (3)	−0.0068 (2)
C1	0.033 (2)	0.063 (3)	0.037 (2)	0.0018 (19)	0.0019 (16)	0.005 (2)
C2	0.066 (3)	0.059 (3)	0.056 (3)	0.006 (2)	0.007 (2)	0.002 (2)
C3	0.070 (3)	0.065 (3)	0.088 (4)	0.023 (3)	0.018 (3)	0.024 (3)
C4	0.055 (3)	0.087 (4)	0.064 (3)	0.017 (3)	0.002 (2)	0.030 (3)
C5	0.038 (2)	0.088 (4)	0.046 (3)	0.003 (2)	0.0000 (19)	0.015 (2)
C6	0.049 (3)	0.132 (5)	0.043 (3)	0.000 (3)	−0.012 (2)	0.020 (3)
C7	0.062 (3)	0.123 (5)	0.040 (3)	−0.010 (3)	−0.011 (2)	−0.008 (3)
C8	0.044 (2)	0.092 (4)	0.043 (3)	−0.009 (2)	0.0006 (19)	−0.017 (3)
C9	0.079 (4)	0.085 (4)	0.070 (4)	−0.016 (3)	−0.001 (3)	−0.035 (3)
C10	0.082 (4)	0.061 (3)	0.100 (5)	0.001 (3)	−0.002 (3)	−0.030 (3)
C11	0.066 (3)	0.054 (3)	0.068 (3)	0.001 (2)	−0.009 (3)	−0.002 (2)
C12	0.033 (2)	0.065 (3)	0.039 (2)	−0.0029 (19)	0.0036 (16)	−0.006 (2)
C13	0.033 (2)	0.054 (2)	0.041 (2)	−0.0057 (18)	−0.0006 (16)	−0.0059 (19)
C14	0.057 (3)	0.051 (3)	0.057 (3)	0.002 (2)	0.000 (2)	0.000 (2)
C15	0.058 (3)	0.066 (3)	0.066 (3)	0.006 (2)	−0.004 (2)	0.021 (3)
C16	0.045 (3)	0.083 (4)	0.044 (3)	−0.004 (2)	−0.004 (2)	0.010 (2)
C17	0.035 (2)	0.067 (3)	0.040 (2)	−0.005 (2)	0.0013 (17)	−0.006 (2)
C18	0.060 (3)	0.093 (4)	0.042 (3)	−0.010 (3)	−0.006 (2)	−0.017 (3)
C19	0.070 (3)	0.072 (3)	0.067 (3)	−0.016 (3)	0.001 (3)	−0.034 (3)
C20	0.047 (3)	0.054 (3)	0.066 (3)	−0.006 (2)	0.003 (2)	−0.016 (2)
C21	0.077 (4)	0.047 (3)	0.108 (5)	−0.002 (3)	−0.003 (3)	−0.023 (3)
C22	0.086 (4)	0.045 (3)	0.117 (5)	0.003 (3)	−0.019 (4)	0.007 (3)
C23	0.069 (3)	0.056 (3)	0.073 (3)	0.002 (2)	−0.014 (3)	0.007 (3)
C24	0.035 (2)	0.045 (2)	0.048 (2)	−0.0036 (17)	0.0034 (17)	−0.0046 (19)
C25	0.061 (4)	0.101 (5)	0.105 (6)	0.006 (4)	0.001 (4)	0.029 (4)
C26	0.082 (5)	0.186 (9)	0.083 (5)	0.017 (5)	0.000 (4)	0.016 (6)
N1	0.049 (2)	0.056 (2)	0.0395 (19)	0.0043 (17)	0.0027 (15)	0.0025 (17)
N2	0.0434 (19)	0.053 (2)	0.046 (2)	0.0011 (16)	−0.0039 (16)	−0.0050 (17)
N3	0.0426 (19)	0.048 (2)	0.046 (2)	−0.0015 (16)	−0.0034 (16)	−0.0028 (16)
N4	0.046 (2)	0.047 (2)	0.054 (2)	−0.0030 (16)	−0.0028 (16)	0.0009 (17)
N5	0.092 (4)	0.098 (5)	0.185 (8)	0.004 (4)	0.005 (5)	0.018 (5)

Geometric parameters (Å, º)

I1—Cu1	2.5909 (6)	C11—H11	0.9300
I1—Cu2	2.6297 (7)	C12—N2	1.348 (5)
I2—Cu1	2.5876 (7)	C13—N3	1.355 (5)
I2—Cu2	2.5953 (7)	C13—C17	1.415 (6)
Cu1—N1	2.078 (3)	C13—C24	1.432 (6)
Cu1—N2	2.085 (3)	C14—N3	1.317 (5)
Cu2—N3	2.099 (4)	C14—C15	1.394 (6)
Cu2—N4	2.080 (4)	C14—H14	0.9300
Cu1—Cu2	2.6018 (8)	C15—C16	1.339 (7)
C1—N1	1.353 (5)	C15—H15	0.9300
C1—C5	1.417 (6)	C16—C17	1.388 (6)
C1—C12	1.443 (6)	C16—H16	0.9300
C2—N1	1.326 (6)	C17—C18	1.432 (7)
C2—C3	1.400 (7)	C18—C19	1.330 (8)
C2—H2	0.9300	C18—H18	0.9300
C3—C4	1.360 (8)	C19—C20	1.435 (7)
C3—H3	0.9300	C19—H19	0.9300
C4—C5	1.384 (8)	C20—C21	1.400 (7)
C4—H4	0.9300	C20—C24	1.409 (6)
C5—C6	1.436 (8)	C21—C22	1.349 (8)
C6—C7	1.320 (8)	C21—H21	0.9300
C6—H6	0.9300	C22—C23	1.392 (7)
C7—C8	1.429 (7)	C22—H22	0.9300
C7—H7	0.9300	C23—N4	1.322 (6)
C8—C12	1.396 (6)	C23—H23	0.9300
C8—C9	1.412 (8)	C24—N4	1.354 (5)
C9—C10	1.346 (8)	C25—N5	1.125 (9)
C9—H9	0.9300	C25—C26	1.435 (11)
C10—C11	1.392 (7)	C26—H26A	0.9600
C10—H10	0.9300	C26—H26B	0.9600
C11—N2	1.322 (6)	C26—H26C	0.9600
I1—Cu1—I2	118.75 (2)	C8—C12—C1	119.3 (4)
I1—Cu1—N1	117.9 (1)	N3—C13—C17	122.5 (4)
I1—Cu1—N2	112.0 (1)	N3—C13—C24	117.9 (4)
I2—Cu1—N1	112.1 (1)	C17—C13—C24	119.6 (4)
I2—Cu1—N2	108.9 (1)	N3—C14—C15	123.6 (5)
N1—Cu1—N2	80.6 (1)	N3—C14—H14	118.2
Cu1—I1—Cu2	59.78 (2)	C15—C14—H14	118.2
Cu1—I2—Cu2	60.26 (2)	C16—C15—C14	118.9 (5)
N1—Cu1—Cu2	131.57 (10)	C16—C15—H15	120.5
N2—Cu1—Cu2	147.64 (10)	C14—C15—H15	120.5
I2—Cu1—Cu2	60.02 (2)	C15—C16—C17	120.7 (4)
I1—Cu1—Cu2	60.852 (19)	C15—C16—H16	119.6
N4—Cu2—N3	80.17 (14)	C17—C16—H16	119.6
N4—Cu2—I2	110.60 (10)	C16—C17—C13	116.8 (4)
N3—Cu2—I2	117.87 (10)	C16—C17—C18	124.5 (4)
N4—Cu2—Cu1	122.35 (10)	C13—C17—C18	118.6 (4)
N3—Cu2—Cu1	157.34 (10)	C19—C18—C17	121.6 (4)
I2—Cu2—Cu1	59.720 (19)	C19—C18—H18	119.2
N4—Cu2—I1	113.73 (10)	C17—C18—H18	119.2
N3—Cu2—I1	111.88 (10)	C18—C19—C20	121.6 (5)
I2—Cu2—I1	117.04 (2)	C18—C19—H19	119.2
Cu1—Cu2—I1	59.37 (2)	C20—C19—H19	119.2
N1—C1—C5	122.9 (4)	C21—C20—C24	116.6 (4)
N1—C1—C12	117.5 (4)	C21—C20—C19	124.7 (5)
C5—C1—C12	119.5 (4)	C24—C20—C19	118.7 (5)
N1—C2—C3	123.5 (5)	C22—C21—C20	120.5 (5)
N1—C2—H2	118.3	C22—C21—H21	119.8
C3—C2—H2	118.3	C20—C21—H21	119.8
C4—C3—C2	118.9 (5)	C21—C22—C23	119.2 (5)
C4—C3—H3	120.5	C21—C22—H22	120.4
C2—C3—H3	120.5	C23—C22—H22	120.4
C3—C4—C5	120.1 (5)	N4—C23—C22	123.0 (5)
C3—C4—H4	120.0	N4—C23—H23	118.5
C5—C4—H4	120.0	C22—C23—H23	118.5
C4—C5—C1	117.4 (5)	N4—C24—C20	122.7 (4)
C4—C5—C6	124.4 (5)	N4—C24—C13	117.5 (4)
C1—C5—C6	118.2 (5)	C20—C24—C13	119.8 (4)
C7—C6—C5	122.0 (5)	N5—C25—C26	178.1 (9)
C7—C6—H6	119.0	C25—C26—H26A	109.5
C5—C6—H6	119.0	C25—C26—H26B	109.5
C6—C7—C8	121.3 (5)	H26A—C26—H26B	109.5
C6—C7—H7	119.3	C25—C26—H26C	109.5
C8—C7—H7	119.3	H26A—C26—H26C	109.5
C12—C8—C9	116.9 (5)	H26B—C26—H26C	109.5
C12—C8—C7	119.6 (5)	C2—N1—C1	117.3 (4)
C9—C8—C7	123.5 (5)	C2—N1—Cu1	130.5 (3)
C10—C9—C8	119.2 (5)	C1—N1—Cu1	112.2 (3)
C10—C9—H9	120.4	C11—N2—C12	118.1 (4)
C8—C9—H9	120.4	C11—N2—Cu1	129.6 (3)
C9—C10—C11	120.3 (5)	C12—N2—Cu1	112.2 (3)
C9—C10—H10	119.9	C14—N3—C13	117.5 (4)
C11—C10—H10	119.9	C14—N3—Cu2	130.7 (3)
N2—C11—C10	122.3 (5)	C13—N3—Cu2	111.8 (3)
N2—C11—H11	118.9	C23—N4—C24	118.0 (4)
C10—C11—H11	118.9	C23—N4—Cu2	129.3 (3)
N2—C12—C8	123.2 (4)	C24—N4—Cu2	112.6 (3)
N2—C12—C1	117.5 (4)
Cu2—I2—Cu1—N1	−126.34 (11)	C20—C21—C22—C23	−0.7 (9)
Cu2—I2—Cu1—N2	146.42 (11)	C21—C22—C23—N4	0.8 (9)
Cu2—I2—Cu1—I1	16.68 (2)	C21—C20—C24—N4	1.3 (6)
Cu2—I1—Cu1—N1	124.35 (12)	C19—C20—C24—N4	179.1 (4)
Cu2—I1—Cu1—N2	−144.88 (11)	C21—C20—C24—C13	−179.0 (4)
Cu2—I1—Cu1—I2	−16.54 (2)	C19—C20—C24—C13	−1.2 (6)
Cu1—I2—Cu2—N4	116.26 (11)	N3—C13—C24—N4	1.3 (5)
Cu1—I2—Cu2—N3	−154.16 (11)	C17—C13—C24—N4	−177.7 (4)
Cu1—I2—Cu2—I1	−16.16 (2)	N3—C13—C24—C20	−178.4 (4)
N1—Cu1—Cu2—N4	−2.52 (18)	C17—C13—C24—C20	2.6 (6)
N2—Cu1—Cu2—N4	−174.3 (2)	C3—C2—N1—C1	−0.4 (7)
I2—Cu1—Cu2—N4	−96.46 (12)	C3—C2—N1—Cu1	−178.7 (3)
I1—Cu1—Cu2—N4	100.29 (12)	C5—C1—N1—C2	−0.2 (6)
N1—Cu1—Cu2—N3	−175.7 (3)	C12—C1—N1—C2	−179.6 (4)
N2—Cu1—Cu2—N3	12.5 (3)	C5—C1—N1—Cu1	178.5 (3)
I2—Cu1—Cu2—N3	90.4 (3)	C12—C1—N1—Cu1	−1.0 (4)
I1—Cu1—Cu2—N3	−72.9 (3)	N2—Cu1—N1—C2	179.6 (4)
N1—Cu1—Cu2—I2	93.93 (13)	I2—Cu1—N1—C2	72.9 (4)
N2—Cu1—Cu2—I2	−77.84 (18)	I1—Cu1—N1—C2	−70.4 (4)
I1—Cu1—Cu2—I2	−163.26 (2)	Cu2—Cu1—N1—C2	4.1 (5)
N1—Cu1—Cu2—I1	−102.81 (13)	N2—Cu1—N1—C1	1.2 (3)
N2—Cu1—Cu2—I1	85.42 (18)	I2—Cu1—N1—C1	−105.5 (3)
I2—Cu1—Cu2—I1	163.26 (2)	I1—Cu1—N1—C1	111.1 (3)
Cu1—I1—Cu2—N4	−114.77 (11)	Cu2—Cu1—N1—C1	−174.4 (2)
Cu1—I1—Cu2—N3	156.63 (11)	C10—C11—N2—C12	−1.2 (7)
Cu1—I1—Cu2—I2	16.22 (2)	C10—C11—N2—Cu1	176.9 (4)
N1—C2—C3—C4	0.6 (8)	C8—C12—N2—C11	−0.4 (6)
C2—C3—C4—C5	−0.3 (7)	C1—C12—N2—C11	179.5 (4)
C3—C4—C5—C1	−0.1 (7)	C8—C12—N2—Cu1	−178.8 (3)
C3—C4—C5—C6	−179.2 (5)	C1—C12—N2—Cu1	1.1 (4)
N1—C1—C5—C4	0.4 (6)	N1—Cu1—N2—C11	−179.4 (4)
C12—C1—C5—C4	179.9 (4)	I2—Cu1—N2—C11	−69.2 (4)
N1—C1—C5—C6	179.5 (4)	I1—Cu1—N2—C11	64.2 (4)
C12—C1—C5—C6	−1.0 (6)	Cu2—Cu1—N2—C11	−5.6 (5)
C4—C5—C6—C7	179.9 (5)	N1—Cu1—N2—C12	−1.2 (3)
C1—C5—C6—C7	0.9 (7)	I2—Cu1—N2—C12	109.0 (3)
C5—C6—C7—C8	0.0 (8)	I1—Cu1—N2—C12	−117.6 (3)
C6—C7—C8—C12	−0.8 (8)	Cu2—Cu1—N2—C12	172.54 (19)
C6—C7—C8—C9	178.1 (5)	C15—C14—N3—C13	−0.4 (7)
C12—C8—C9—C10	−1.1 (8)	C15—C14—N3—Cu2	−178.6 (3)
C7—C8—C9—C10	−180.0 (5)	C17—C13—N3—C14	0.3 (6)
C8—C9—C10—C11	−0.4 (9)	C24—C13—N3—C14	−178.7 (4)
C9—C10—C11—N2	1.6 (9)	C17—C13—N3—Cu2	178.9 (3)
C9—C8—C12—N2	1.5 (7)	C24—C13—N3—Cu2	−0.1 (4)
C7—C8—C12—N2	−179.5 (4)	N4—Cu2—N3—C14	177.7 (4)
C9—C8—C12—C1	−178.3 (4)	I2—Cu2—N3—C14	69.5 (4)
C7—C8—C12—C1	0.6 (6)	Cu1—Cu2—N3—C14	−8.2 (6)
N1—C1—C12—N2	−0.1 (5)	I1—Cu2—N3—C14	−70.6 (4)
C5—C1—C12—N2	−179.6 (4)	N4—Cu2—N3—C13	−0.7 (3)
N1—C1—C12—C8	179.8 (4)	I2—Cu2—N3—C13	−108.9 (3)
C5—C1—C12—C8	0.3 (6)	Cu1—Cu2—N3—C13	173.47 (19)
N3—C14—C15—C16	0.6 (7)	I1—Cu2—N3—C13	111.1 (3)
C14—C15—C16—C17	−0.7 (7)	C22—C23—N4—C24	0.1 (8)
C15—C16—C17—C13	0.6 (7)	C22—C23—N4—Cu2	−178.7 (4)
C15—C16—C17—C18	−178.7 (5)	C20—C24—N4—C23	−1.2 (6)
N3—C13—C17—C16	−0.4 (6)	C13—C24—N4—C23	179.2 (4)
C24—C13—C17—C16	178.5 (4)	C20—C24—N4—Cu2	177.8 (3)
N3—C13—C17—C18	178.9 (4)	C13—C24—N4—Cu2	−1.8 (4)
C24—C13—C17—C18	−2.2 (6)	N3—Cu2—N4—C23	−179.8 (4)
C16—C17—C18—C19	179.5 (5)	I2—Cu2—N4—C23	−63.6 (4)
C13—C17—C18—C19	0.3 (7)	Cu1—Cu2—N4—C23	2.9 (5)
C17—C18—C19—C20	1.2 (8)	I1—Cu2—N4—C23	70.5 (4)
C18—C19—C20—C21	176.9 (5)	N3—Cu2—N4—C24	1.4 (3)
C18—C19—C20—C24	−0.7 (7)	I2—Cu2—N4—C24	117.6 (3)
C24—C20—C21—C22	−0.3 (8)	Cu1—Cu2—N4—C24	−176.0 (2)
C19—C20—C21—C22	−178.0 (5)	I1—Cu2—N4—C24	−108.3 (3)