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Alkali copper sulfates form a rapidly developing family of inorganics. Herein, we report synthesis and crystal structure, and evaluate possible ion migration pathways for a novel Na-K-Cu anhydrous sulfate, K(Na,K)Na2[Cu2(SO4)4]. The CuO7 and SO4 polyhedra share common vertices and edges to form [Cu2(SO4)4]4− wide ribbons, which link to each other via common oxygen atoms forming the host part of the structure. Four guest alkali sites are occupied by solely K+, mixture of K+ and Na+, and solely Na+, which agrees well with the size of the cavities. The crystal structure of K(Na,K)Na2[Cu2(SO4)4] contains two symmetry-independent Cu sites with [4+1+(2)] coordination environments. The overall coordination polyhedra of Cu2+ can be considered as `octahedra with one split vertex'. A similar coordination mode was observed also in some other multinary copper sulfates, mostly of the mineral world. These coordination modes were reviewed and five types of CuO7 polyhedra are identified. CuO7 polyhedra are almost restricted to copper sulfates and phosphates. It was found that a larger amount of the smaller SO42− and PO43− anions can cluster around a single Cu2+ cation; in addition, for such relatively small anions, both mono (κ1) and bidentate (κ2) coordination modes to the Cu2+ are possible. The correlation between crystallographic characteristics and bond valence energies showed that the new copper sulfate framework, [Cu2(SO4)4]4−, contains one interconnected path suitable for Na+ mobility at tolerable activation energies and that K(Na,K)Na2[Cu2(SO4)4] can be considered as a potential candidate for novel Na-ion conductors.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520621010350/rm5054sup1.cif
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520621010350/rm5054Isup2.hkl
Contains datablock I

CCDC reference: 2114165

Computing details top

Program(s) used to refine structure: SHELXL2018/3 (Sheldrick, 2018).

(I) top
Crystal data top
Cu8K5.13Na10.87O64S16F(000) = 1217
Mr = 2495.76Dx = 2.920 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 12.5085 (9) ÅCell parameters from 1760 reflections
b = 9.3166 (7) Åθ = 2.8–28.0°
c = 12.7894 (10) ŵ = 4.13 mm1
β = 107.775 (2)°T = 296 K
V = 1419.28 (19) Å3Prism
Z = 10.10 × 0.10 × 0.05 mm
Data collection top
Bruker Apex II Duo
diffractometer
Rint = 0.041
Absorption correction: multi-scanθmax = 28.0°, θmin = 2.8°
h = 1616
13295 measured reflectionsk = 1212
3393 independent reflectionsl = 1613
2656 reflections with I > 2σ(I)
Refinement top
Refinement on F20 restraints
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.0358P)2 + 1.0736P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.030(Δ/σ)max = 0.001
wR(F2) = 0.077Δρmax = 0.54 e Å3
S = 1.02Δρmin = 0.65 e Å3
3393 reflectionsExtinction correction: SHELXL-2018/3 (Sheldrick 2018), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
237 parametersExtinction coefficient: 0.00090 (19)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Cu10.43543 (3)0.59355 (4)0.81573 (3)0.01214 (11)
Cu20.18205 (3)0.89881 (4)0.55924 (3)0.01240 (11)
K10.29227 (6)0.25219 (8)0.70496 (6)0.02114 (18)
Na10.08168 (10)0.76871 (15)0.08627 (11)0.0204 (3)
Na20.43127 (10)0.77780 (15)0.06462 (11)0.0192 (3)
Na30.15076 (11)0.6620 (2)0.33753 (13)0.0590 (8)0.718 (11)
K20.15076 (11)0.6620 (2)0.33753 (13)0.0590 (8)0.282 (11)
S10.38967 (6)0.90637 (8)0.79088 (6)0.01092 (16)
S20.64429 (5)0.59305 (8)0.03189 (6)0.01061 (16)
S30.19659 (6)0.58760 (8)0.61760 (7)0.01284 (17)
S40.03802 (6)0.91496 (9)0.35754 (7)0.01321 (17)
O10.11108 (17)0.9147 (2)0.43257 (18)0.0152 (5)
O20.57170 (16)0.5868 (2)0.10673 (18)0.0130 (5)
O30.67918 (18)0.4464 (3)0.0165 (2)0.0194 (5)
O40.44032 (17)0.7839 (2)0.74766 (18)0.0138 (5)
O50.73711 (18)0.6891 (3)0.0775 (2)0.0202 (5)
O60.23987 (17)0.7019 (2)0.55722 (19)0.0163 (5)
O70.28093 (18)0.9451 (3)0.7094 (2)0.0216 (5)
O80.08985 (18)0.8266 (3)0.2628 (2)0.0220 (5)
O90.07051 (18)0.8473 (3)0.4202 (2)0.0234 (6)
O100.57326 (18)0.6548 (3)0.92613 (19)0.0184 (5)
O110.3676 (2)0.8640 (3)0.8916 (2)0.0236 (6)
O120.46516 (19)1.0300 (3)0.8061 (2)0.0199 (5)
O130.0224 (2)1.0626 (3)0.3289 (2)0.0268 (6)
O140.1579 (2)0.4664 (3)0.5457 (2)0.0288 (6)
O150.29260 (19)0.5395 (3)0.7116 (2)0.0270 (6)
O160.1112 (2)0.6511 (3)0.6580 (2)0.0298 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cu10.01297 (17)0.0105 (2)0.0118 (2)0.00037 (13)0.00202 (14)0.00210 (15)
Cu20.01131 (17)0.0111 (2)0.0138 (2)0.00183 (13)0.00241 (14)0.00013 (16)
K10.0225 (3)0.0141 (4)0.0247 (4)0.0003 (3)0.0041 (3)0.0026 (3)
Na10.0178 (6)0.0240 (8)0.0185 (7)0.0012 (5)0.0044 (5)0.0026 (6)
Na20.0188 (6)0.0233 (8)0.0146 (7)0.0026 (5)0.0038 (5)0.0028 (6)
Na30.0324 (8)0.0979 (16)0.0397 (10)0.0199 (8)0.0005 (6)0.0420 (10)
K20.0324 (8)0.0979 (16)0.0397 (10)0.0199 (8)0.0005 (6)0.0420 (10)
S10.0132 (3)0.0100 (4)0.0093 (4)0.0002 (3)0.0030 (3)0.0008 (3)
S20.0104 (3)0.0112 (4)0.0101 (4)0.0005 (3)0.0029 (3)0.0000 (3)
S30.0115 (3)0.0093 (4)0.0159 (4)0.0003 (3)0.0015 (3)0.0011 (3)
S40.0111 (3)0.0132 (4)0.0135 (4)0.0013 (3)0.0011 (3)0.0025 (3)
O10.0175 (10)0.0146 (12)0.0133 (12)0.0045 (8)0.0043 (9)0.0005 (9)
O20.0151 (9)0.0128 (12)0.0130 (11)0.0011 (8)0.0072 (9)0.0001 (9)
O30.0199 (11)0.0165 (13)0.0239 (13)0.0018 (9)0.0098 (9)0.0030 (10)
O40.0181 (10)0.0099 (11)0.0142 (11)0.0022 (8)0.0061 (8)0.0021 (9)
O50.0150 (10)0.0236 (14)0.0198 (13)0.0082 (9)0.0022 (9)0.0018 (11)
O60.0175 (10)0.0117 (12)0.0205 (13)0.0023 (8)0.0071 (9)0.0039 (10)
O70.0179 (10)0.0217 (14)0.0201 (13)0.0079 (9)0.0018 (9)0.0048 (11)
O80.0193 (11)0.0294 (15)0.0162 (13)0.0020 (10)0.0035 (9)0.0103 (11)
O90.0151 (10)0.0251 (14)0.0235 (14)0.0080 (9)0.0037 (9)0.0075 (11)
O100.0206 (10)0.0170 (13)0.0131 (12)0.0044 (9)0.0015 (9)0.0058 (10)
O110.0325 (13)0.0258 (15)0.0174 (13)0.0046 (10)0.0150 (11)0.0063 (11)
O120.0233 (11)0.0136 (13)0.0229 (13)0.0070 (9)0.0071 (9)0.0035 (10)
O130.0272 (12)0.0164 (14)0.0391 (17)0.0024 (10)0.0133 (11)0.0041 (12)
O140.0339 (13)0.0184 (14)0.0279 (15)0.0068 (11)0.0002 (11)0.0078 (12)
O150.0231 (11)0.0181 (13)0.0300 (15)0.0057 (10)0.0063 (10)0.0108 (12)
O160.0291 (13)0.0257 (15)0.0435 (18)0.0059 (11)0.0241 (12)0.0031 (13)
Geometric parameters (Å, º) top
Cu1—O151.941 (2)Na1—S4ix3.6005 (16)
Cu1—O101.951 (2)Na1—S43.6103 (16)
Cu1—O2i1.967 (2)Na1—S3x3.6354 (14)
Cu1—O41.985 (2)Na1—S2viii3.6682 (14)
Cu1—O12ii2.347 (2)Na1—Na33.750 (2)
Cu1—O112.918 (3)Na2—O11xii2.258 (3)
Cu1—O3i2.946 (2)Na2—O6x2.374 (2)
Cu1—S12.9684 (9)Na2—O4x2.379 (3)
Cu1—S2i3.0002 (9)Na2—O22.442 (2)
Cu1—S2iii3.1715 (8)Na2—O12xiii2.512 (3)
Cu1—S33.2753 (8)Na2—O3xiv2.544 (3)
Cu1—S1ii3.3923 (8)Na2—O10xii3.086 (3)
Cu2—O91.956 (2)Na2—S23.3044 (15)
Cu2—O1iv1.969 (2)Na2—O15x3.381 (3)
Cu2—O61.975 (2)Na2—S3x3.4443 (15)
Cu2—O71.989 (2)Na2—S1x3.5366 (16)
Cu2—O3v2.274 (2)Na2—S1xii3.5846 (16)
Cu2—O13iv2.813 (3)Na3—O92.398 (3)
Cu2—O162.897 (3)Na3—O13ix2.425 (3)
Cu2—S4iv2.9257 (9)Na3—O11x2.598 (3)
Cu2—S32.9856 (9)Na3—O62.714 (3)
Cu2—S43.1495 (8)Na3—O16x2.802 (4)
Cu2—S13.2907 (8)Na3—O7x2.821 (3)
Cu2—S2v3.3012 (9)Na3—O143.204 (4)
K1—O152.678 (3)Na3—O83.251 (3)
K1—O8vi2.785 (2)Na3—S1x3.2836 (16)
K1—O10ii2.861 (2)Na3—S4ix3.3710 (17)
K1—O1vi2.866 (2)Na3—O8ix3.376 (3)
K1—O7vii2.866 (3)Na3—S43.4004 (17)
K1—O2i2.906 (2)Na3—S33.519 (2)
K1—O5i2.967 (3)S1—O111.452 (3)
K1—O142.978 (3)S1—O121.464 (2)
K1—O12vii2.988 (3)S1—O71.483 (2)
K1—O4ii3.226 (2)S1—O41.491 (2)
K1—S4vi3.4097 (10)S2—O51.441 (2)
K1—S33.4102 (11)S2—O31.466 (2)
K1—S1vii3.5007 (11)S2—O10xii1.489 (2)
K1—S2i3.5220 (11)S2—O21.508 (2)
Na1—O82.354 (3)S3—O141.443 (3)
Na1—O5viii2.355 (2)S3—O161.447 (3)
Na1—O13ix2.387 (3)S3—O151.486 (2)
Na1—O16x2.423 (3)S3—O61.510 (2)
Na1—O14xi2.483 (3)S4—O81.444 (2)
Na1—O1x2.545 (3)S4—O131.452 (3)
Na1—O9x3.431 (3)S4—O91.489 (2)
Na1—S4x3.5720 (16)S4—O11.514 (2)
O15—Cu1—O10176.08 (12)S4ix—Na3—S4112.69 (4)
O15—Cu1—O2i87.15 (10)O8ix—Na3—S4126.07 (6)
O10—Cu1—O2i92.93 (9)O9—Na3—Cu232.03 (6)
O15—Cu1—O494.37 (10)O13ix—Na3—Cu2145.87 (8)
O10—Cu1—O485.26 (9)O11x—Na3—Cu289.64 (7)
O2i—Cu1—O4175.34 (9)O6—Na3—Cu233.92 (5)
O15—Cu1—O12ii92.41 (11)O16x—Na3—Cu2102.66 (8)
O10—Cu1—O12ii91.38 (9)O7x—Na3—Cu2138.39 (7)
O2i—Cu1—O12ii103.53 (9)O14—Na3—Cu273.68 (6)
O4—Cu1—O12ii80.84 (9)O8—Na3—Cu278.84 (5)
O15—Cu1—O1198.76 (10)S1x—Na3—Cu2112.62 (4)
O10—Cu1—O1177.83 (9)S4ix—Na3—Cu2160.56 (6)
O2i—Cu1—O11120.50 (8)O8ix—Na3—Cu2147.50 (8)
O4—Cu1—O1154.92 (8)S4—Na3—Cu254.12 (3)
O12ii—Cu1—O11134.88 (8)O9—Na3—S369.72 (7)
O15—Cu1—O3i85.21 (10)O13ix—Na3—S3132.57 (10)
O10—Cu1—O3i91.65 (8)O11x—Na3—S383.01 (7)
O2i—Cu1—O3i54.39 (8)O6—Na3—S323.84 (5)
O4—Cu1—O3i121.29 (8)O16x—Na3—S3152.80 (8)
O12ii—Cu1—O3i157.84 (8)O7x—Na3—S3125.29 (7)
O11—Cu1—O3i67.12 (7)O14—Na3—S324.21 (5)
O15—Cu1—S194.27 (8)O8—Na3—S3103.92 (6)
O10—Cu1—S183.64 (7)S1x—Na3—S3105.79 (4)
O2i—Cu1—S1148.85 (7)S4ix—Na3—S3121.33 (7)
O4—Cu1—S126.68 (7)O8ix—Na3—S398.76 (7)
O12ii—Cu1—S1107.49 (6)S4—Na3—S387.77 (4)
O11—Cu1—S128.55 (5)Cu2—Na3—S350.20 (3)
O3i—Cu1—S194.66 (5)O11—S1—O12112.66 (15)
O15—Cu1—S2i82.91 (8)O11—S1—O7107.88 (15)
O10—Cu1—S2i95.45 (7)O12—S1—O7108.56 (15)
O2i—Cu1—S2i26.14 (6)O11—S1—O4109.76 (14)
O4—Cu1—S2i149.72 (7)O12—S1—O4108.76 (13)
O12ii—Cu1—S2i129.31 (6)O7—S1—O4109.16 (13)
O11—Cu1—S2i95.53 (5)O11—S1—Cu173.78 (11)
O3i—Cu1—S2i28.53 (5)O12—S1—Cu1131.49 (10)
S1—Cu1—S2i123.16 (3)O7—S1—Cu1114.80 (11)
O15—Cu1—S2iii159.81 (8)O4—S1—Cu136.71 (9)
O10—Cu1—S2iii19.72 (7)O11—S1—Na3xv49.91 (10)
O2i—Cu1—S2iii73.22 (6)O12—S1—Na3xv135.58 (11)
O4—Cu1—S2iii104.84 (6)O7—S1—Na3xv58.96 (11)
O12ii—Cu1—S2iii96.66 (6)O4—S1—Na3xv115.60 (10)
O11—Cu1—S2iii87.54 (5)Cu1—S1—Na3xv86.93 (4)
O3i—Cu1—S2iii79.59 (5)O11—S1—Cu2118.77 (10)
S1—Cu1—S2iii100.10 (2)O12—S1—Cu2115.88 (10)
S2i—Cu1—S2iii77.38 (2)O7—S1—Cu221.65 (10)
O15—Cu1—S314.88 (8)O4—S1—Cu287.58 (9)
O10—Cu1—S3163.91 (7)Cu1—S1—Cu298.56 (2)
O2i—Cu1—S3101.80 (6)Na3xv—S1—Cu269.36 (3)
O4—Cu1—S379.56 (6)O11—S1—Cu1xvi144.77 (11)
O12ii—Cu1—S391.44 (6)O12—S1—Cu1xvi34.94 (10)
O11—Cu1—S389.01 (5)O7—S1—Cu1xvi99.12 (11)
O3i—Cu1—S391.70 (5)O4—S1—Cu1xvi81.10 (9)
S1—Cu1—S380.40 (2)Cu1—S1—Cu1xvi114.89 (2)
S2i—Cu1—S395.00 (2)Na3xv—S1—Cu1xvi155.12 (4)
S2iii—Cu1—S3171.29 (2)Cu2—S1—Cu1xvi94.46 (2)
O15—Cu1—S1ii99.33 (9)O11—S1—K1xvii112.74 (11)
O10—Cu1—S1ii84.57 (8)O12—S1—K1xvii57.75 (10)
O2i—Cu1—S1ii84.12 (6)O7—S1—K1xvii53.07 (10)
O4—Cu1—S1ii99.96 (7)O4—S1—K1xvii137.28 (9)
O12ii—Cu1—S1ii20.93 (6)Cu1—S1—K1xvii167.03 (3)
O11—Cu1—S1ii150.03 (5)Na3xv—S1—K1xvii89.24 (4)
O3i—Cu1—S1ii138.15 (5)Cu2—S1—K1xvii68.515 (19)
S1—Cu1—S1ii126.060 (19)Cu1xvi—S1—K1xvii66.80 (2)
S2i—Cu1—S1ii110.26 (2)O11—S1—Na2xv135.17 (12)
S2iii—Cu1—S1ii83.62 (2)O12—S1—Na2xv103.92 (11)
S3—Cu1—S1ii103.19 (2)O7—S1—Na2xv82.87 (10)
O9—Cu2—O1iv93.25 (9)O4—S1—Na2xv30.69 (9)
O9—Cu2—O685.57 (10)Cu1—S1—Na2xv62.58 (3)
O1iv—Cu2—O6173.47 (9)Na3xv—S1—Na2xv115.08 (5)
O9—Cu2—O7172.86 (11)Cu2—S1—Na2xv61.69 (3)
O1iv—Cu2—O785.12 (9)Cu1xvi—S1—Na2xv69.30 (3)
O6—Cu2—O795.26 (10)K1xvii—S1—Na2xv108.28 (3)
O9—Cu2—O3v94.93 (10)O11—S1—Na2iii18.73 (10)
O1iv—Cu2—O3v105.41 (9)O12—S1—Na2iii103.73 (11)
O6—Cu2—O3v81.10 (9)O7—S1—Na2iii126.56 (11)
O7—Cu2—O3v92.21 (10)O4—S1—Na2iii98.91 (9)
O9—Cu2—O13iv94.24 (9)Cu1—S1—Na2iii66.52 (3)
O1iv—Cu2—O13iv57.20 (8)Na3xv—S1—Na2iii68.07 (4)
O6—Cu2—O13iv116.44 (9)Cu2—S1—Na2iii135.35 (3)
O7—Cu2—O13iv79.02 (9)Cu1xvi—S1—Na2iii130.18 (3)
O3v—Cu2—O13iv160.80 (8)K1xvii—S1—Na2iii123.16 (3)
O9—Cu2—O1688.46 (10)Na2xv—S1—Na2iii128.55 (3)
O1iv—Cu2—O16118.50 (8)O11—S1—Na2xiii91.28 (11)
O6—Cu2—O1655.09 (8)O12—S1—Na2xiii21.51 (10)
O7—Cu2—O1686.23 (10)O7—S1—Na2xiii115.43 (11)
O3v—Cu2—O16135.70 (8)O4—S1—Na2xiii121.11 (9)
O13iv—Cu2—O1661.36 (7)Cu1—S1—Na2xiii129.77 (3)
O9—Cu2—S4iv97.40 (7)Na3xv—S1—Na2xiii119.59 (5)
O1iv—Cu2—S4iv28.29 (7)Cu2—S1—Na2xiii129.62 (3)
O6—Cu2—S4iv145.52 (7)Cu1xvi—S1—Na2xiii56.16 (2)
O7—Cu2—S4iv77.91 (7)K1xvii—S1—Na2xiii62.54 (3)
O3v—Cu2—S4iv132.38 (7)Na2xv—S1—Na2xiii124.00 (3)
O13iv—Cu2—S4iv29.23 (5)Na2iii—S1—Na2xiii84.02 (4)
O16—Cu2—S4iv90.55 (5)O5—S2—O3113.40 (14)
O9—Cu2—S387.79 (8)O5—S2—O10xii108.13 (14)
O1iv—Cu2—S3146.93 (7)O3—S2—O10xii110.94 (15)
O6—Cu2—S326.70 (7)O5—S2—O2109.52 (14)
O7—Cu2—S389.80 (8)O3—S2—O2108.13 (13)
O3v—Cu2—S3107.43 (6)O10xii—S2—O2106.48 (13)
O13iv—Cu2—S389.74 (6)O5—S2—Cu1i118.93 (11)
O16—Cu2—S328.43 (5)O3—S2—Cu1i73.68 (10)
S4iv—Cu2—S3118.83 (3)O10xii—S2—Cu1i126.13 (9)
O9—Cu2—S420.66 (7)O2—S2—Cu1i35.07 (8)
O1iv—Cu2—S472.89 (6)O5—S2—Cu1xii134.38 (11)
O6—Cu2—S4105.41 (7)O3—S2—Cu1xii94.81 (10)
O7—Cu2—S4155.66 (7)O10xii—S2—Cu1xii26.25 (9)
O3v—Cu2—S4103.41 (6)O2—S2—Cu1xii93.33 (8)
O13iv—Cu2—S480.32 (6)Cu1i—S2—Cu1xii102.62 (2)
O16—Cu2—S495.06 (6)O5—S2—Cu2xviii86.99 (10)
S4iv—Cu2—S477.78 (3)O3—S2—Cu2xviii35.56 (9)
S3—Cu2—S4102.85 (2)O10xii—S2—Cu2xviii99.53 (10)
O9—Cu2—S1166.37 (7)O2—S2—Cu2xviii142.32 (9)
O1iv—Cu2—S1100.25 (7)Cu1i—S2—Cu2xviii107.26 (2)
O6—Cu2—S180.80 (7)Cu1xii—S2—Cu2xviii98.56 (2)
O7—Cu2—S115.97 (7)O5—S2—Na2101.92 (11)
O3v—Cu2—S183.33 (6)O3—S2—Na2141.94 (10)
O13iv—Cu2—S191.54 (6)O10xii—S2—Na268.48 (10)
O16—Cu2—S183.50 (6)O2—S2—Na243.51 (9)
S4iv—Cu2—S193.68 (2)Cu1i—S2—Na277.22 (3)
S3—Cu2—S179.90 (2)Cu1xii—S2—Na268.17 (3)
S4—Cu2—S1171.34 (2)Cu2xviii—S2—Na2166.72 (3)
O9—Cu2—S2v100.19 (8)O5—S2—K1i55.97 (10)
O1iv—Cu2—S2v83.74 (7)O3—S2—K1i121.38 (11)
O6—Cu2—S2v102.79 (7)O10xii—S2—K1i127.44 (10)
O7—Cu2—S2v86.56 (8)O2—S2—K1i54.06 (8)
O3v—Cu2—S2v22.01 (6)Cu1i—S2—K1i68.84 (2)
O13iv—Cu2—S2v139.07 (6)Cu1xii—S2—K1i135.86 (3)
O16—Cu2—S2v155.86 (5)Cu2xviii—S2—K1i125.53 (2)
S4iv—Cu2—S2v110.36 (2)Na2—S2—K1i67.72 (3)
S3—Cu2—S2v128.62 (2)O5—S2—Na1xix19.11 (10)
S4—Cu2—S2v100.92 (2)O3—S2—Na1xix98.16 (9)
S1—Cu2—S2v83.26 (2)O10xii—S2—Na1xix105.29 (9)
O15—K1—O8vi104.57 (8)O2—S2—Na1xix127.27 (9)
O15—K1—O10ii109.88 (9)Cu1i—S2—Na1xix127.73 (3)
O8vi—K1—O10ii136.61 (7)Cu1xii—S2—Na1xix129.64 (3)
O15—K1—O1vi123.70 (7)Cu2xviii—S2—Na1xix68.53 (3)
O8vi—K1—O1vi50.47 (7)Na2—S2—Na1xix119.11 (4)
O10ii—K1—O1vi87.97 (7)K1i—S2—Na1xix73.22 (3)
O15—K1—O7vii175.39 (9)O5—S2—K1v74.48 (10)
O8vi—K1—O7vii71.40 (7)O3—S2—K1v96.72 (11)
O10ii—K1—O7vii74.73 (7)O10xii—S2—K1v46.64 (9)
O1vi—K1—O7vii55.67 (6)O2—S2—K1v149.67 (9)
O15—K1—O2i57.52 (7)Cu1i—S2—K1v165.61 (3)
O8vi—K1—O2i110.01 (7)Cu1xii—S2—K1v66.93 (2)
O10ii—K1—O2i110.44 (6)Cu2xviii—S2—K1v66.34 (2)
O1vi—K1—O2i160.39 (7)Na2—S2—K1v106.26 (3)
O7vii—K1—O2i121.25 (7)K1i—S2—K1v125.51 (2)
O15—K1—O5i77.61 (8)Na1xix—S2—K1v63.34 (3)
O8vi—K1—O5i62.05 (6)O5—S2—Na2xiv143.97 (11)
O10ii—K1—O5i150.63 (7)O3—S2—Na2xiv30.62 (9)
O1vi—K1—O5i111.99 (7)O10xii—S2—Na2xiv92.12 (10)
O7vii—K1—O5i98.29 (7)O2—S2—Na2xiv91.94 (9)
O2i—K1—O5i48.42 (6)Cu1i—S2—Na2xiv64.73 (3)
O15—K1—O1449.22 (7)Cu1xii—S2—Na2xiv69.60 (3)
O8vi—K1—O1485.94 (8)Cu2xviii—S2—Na2xiv59.87 (2)
O10ii—K1—O1496.99 (8)Na2—S2—Na2xiv113.31 (3)
O1vi—K1—O1476.60 (7)K1i—S2—Na2xiv131.48 (3)
O7vii—K1—O14131.43 (7)Na1xix—S2—Na2xiv127.57 (4)
O2i—K1—O14106.64 (7)K1v—S2—Na2xiv101.53 (3)
O5i—K1—O14108.20 (8)O14—S3—O16114.02 (16)
O15—K1—O12vii133.23 (7)O14—S3—O15108.10 (16)
O8vi—K1—O12vii108.89 (7)O16—S3—O15109.68 (17)
O10ii—K1—O12vii63.69 (7)O14—S3—O6109.18 (15)
O1vi—K1—O12vii102.84 (6)O16—S3—O6108.25 (14)
O7vii—K1—O12vii48.19 (6)O15—S3—O6107.41 (13)
O2i—K1—O12vii80.53 (6)O14—S3—Cu2128.11 (12)
O5i—K1—O12vii90.12 (7)O16—S3—Cu272.37 (11)
O14—K1—O12vii160.61 (8)O15—S3—Cu2117.90 (10)
O15—K1—O4ii84.90 (7)O6—S3—Cu235.99 (9)
O8vi—K1—O4ii159.03 (7)O14—S3—Cu1123.75 (11)
O10ii—K1—O4ii51.51 (6)O16—S3—Cu1108.35 (12)
O1vi—K1—O4ii138.19 (6)O15—S3—Cu119.60 (10)
O7vii—K1—O4ii98.19 (6)O6—S3—Cu189.94 (9)
O2i—K1—O4ii59.06 (6)Cu2—S3—Cu198.54 (2)
O5i—K1—O4ii103.02 (6)O14—S3—K160.53 (11)
O14—K1—O4ii113.79 (7)O16—S3—K1118.75 (12)
O12vii—K1—O4ii53.86 (6)O15—S3—K148.86 (10)
O15—K1—S4vi117.14 (6)O6—S3—K1132.02 (9)
O8vi—K1—S4vi24.39 (5)Cu2—S3—K1163.80 (3)
O10ii—K1—S4vi113.01 (5)Cu1—S3—K167.419 (19)
O1vi—K1—S4vi26.12 (5)O14—S3—Na2xv107.42 (12)
O7vii—K1—S4vi60.03 (5)O16—S3—Na2xv133.44 (12)
O2i—K1—S4vi134.29 (5)O15—S3—Na2xv75.05 (11)
O5i—K1—S4vi86.01 (5)O6—S3—Na2xv35.14 (8)
O14—K1—S4vi81.63 (5)Cu2—S3—Na2xv65.66 (3)
O12vii—K1—S4vi106.56 (5)Cu1—S3—Na2xv61.00 (3)
O4ii—K1—S4vi157.72 (5)K1—S3—Na2xv99.39 (3)
O15—K1—S324.70 (5)O14—S3—Na365.58 (12)
O8vi—K1—S392.64 (6)O16—S3—Na3111.99 (12)
O10ii—K1—S3108.00 (6)O15—S3—Na3136.32 (12)
O1vi—K1—S399.39 (5)O6—S3—Na346.59 (10)
O7vii—K1—S3155.06 (5)Cu2—S3—Na364.89 (4)
O2i—K1—S381.76 (5)Cu1—S3—Na3127.65 (3)
O5i—K1—S390.39 (5)K1—S3—Na3116.48 (4)
O14—K1—S324.96 (5)Na2xv—S3—Na367.16 (4)
O12vii—K1—S3155.78 (5)O14—S3—Na1xv95.41 (11)
O4ii—K1—S3102.58 (5)O16—S3—Na1xv26.22 (12)
S4vi—K1—S397.63 (2)O15—S3—Na1xv135.29 (13)
O15—K1—S1vii155.92 (6)O6—S3—Na1xv99.47 (9)
O8vi—K1—S1vii87.47 (6)Cu2—S3—Na1xv68.39 (3)
O10ii—K1—S1vii71.43 (5)Cu1—S3—Na1xv134.07 (3)
O1vi—K1—S1vii80.08 (5)K1—S3—Na1xv127.01 (3)
O7vii—K1—S1vii24.43 (4)Na2xv—S3—Na1xv133.56 (4)
O2i—K1—S1vii98.94 (5)Na3—S3—Na1xv87.84 (3)
O5i—K1—S1vii90.35 (5)O14—S3—Na3xv148.03 (12)
O14—K1—S1vii154.32 (6)O16—S3—Na3xv36.53 (12)
O12vii—K1—S1vii24.48 (4)O15—S3—Na3xv81.66 (12)
O4ii—K1—S1vii77.51 (4)O6—S3—Na3xv95.93 (10)
S4vi—K1—S1vii82.16 (2)Cu2—S3—Na3xv65.21 (3)
S3—K1—S1vii179.21 (3)Cu1—S3—Na3xv74.17 (3)
O15—K1—S2i64.08 (6)K1—S3—Na3xv115.71 (4)
O8vi—K1—S2i85.20 (5)Na2xv—S3—Na3xv104.50 (4)
O10ii—K1—S2i133.52 (5)Na3—S3—Na3xv127.82 (3)
O1vi—K1—S2i135.55 (5)Na1xv—S3—Na3xv60.25 (3)
O7vii—K1—S2i112.81 (6)O8—S4—O13112.86 (16)
O2i—K1—S2i24.85 (4)O8—S4—O9108.19 (15)
O5i—K1—S2i23.73 (4)O13—S4—O9111.45 (15)
O14—K1—S2i107.14 (6)O8—S4—O1109.11 (14)
O12vii—K1—S2i87.01 (5)O13—S4—O1108.40 (15)
O4ii—K1—S2i82.23 (4)O9—S4—O1106.61 (14)
S4vi—K1—S2i109.45 (3)O8—S4—Cu2iv118.33 (10)
S3—K1—S2i83.80 (3)O13—S4—Cu2iv71.06 (11)
S1vii—K1—S2i96.98 (3)O9—S4—Cu2iv128.07 (11)
O8—Na1—O5viii78.17 (9)O1—S4—Cu2iv38.05 (9)
O8—Na1—O13ix85.73 (10)O8—S4—Cu2135.73 (10)
O5viii—Na1—O13ix98.73 (10)O13—S4—Cu295.78 (11)
O8—Na1—O16x84.02 (9)O9—S4—Cu227.61 (10)
O5viii—Na1—O16x161.45 (11)O1—S4—Cu291.52 (9)
O13ix—Na1—O16x74.57 (10)Cu2iv—S4—Cu2102.22 (3)
O8—Na1—O14xi111.20 (11)O8—S4—Na3xi77.83 (12)
O5viii—Na1—O14xi92.11 (10)O13—S4—Na3xi39.13 (11)
O13ix—Na1—O14xi161.57 (11)O9—S4—Na3xi142.53 (12)
O16x—Na1—O14xi99.20 (10)O1—S4—Na3xi105.86 (9)
O8—Na1—O1x148.92 (10)Cu2iv—S4—Na3xi72.50 (4)
O5viii—Na1—O1x80.89 (9)Cu2—S4—Na3xi134.62 (4)
O13ix—Na1—O1x75.01 (9)O8—S4—Na371.71 (10)
O16x—Na1—O1x113.07 (9)O13—S4—Na3119.17 (11)
O14xi—Na1—O1x92.19 (10)O9—S4—Na337.57 (10)
O8—Na1—O9x149.41 (8)O1—S4—Na3127.87 (10)
O5viii—Na1—O9x125.38 (9)Cu2iv—S4—Na3163.18 (4)
O13ix—Na1—O9x72.51 (8)Cu2—S4—Na364.86 (3)
O16x—Na1—O9x69.82 (8)Na3xi—S4—Na3124.11 (3)
O14xi—Na1—O9x89.06 (9)O8—S4—K1vi52.80 (10)
O1x—Na1—O9x44.52 (6)O13—S4—K1vi124.14 (10)
O8—Na1—S4x163.26 (9)O9—S4—K1vi124.39 (11)
O5viii—Na1—S4x101.28 (7)O1—S4—K1vi56.45 (9)
O13ix—Na1—S4x77.79 (8)Cu2iv—S4—K1vi73.88 (2)
O16x—Na1—S4x94.26 (8)Cu2—S4—K1vi133.60 (3)
O14xi—Na1—S4x85.52 (8)Na3xi—S4—K1vi89.36 (3)
O1x—Na1—S4x21.25 (5)Na3—S4—K1vi106.58 (4)
O9x—Na1—S4x24.45 (4)O8—S4—Na1xv105.80 (12)
O8—Na1—S4ix98.95 (8)O13—S4—Na1xv136.61 (12)
O5viii—Na1—S4ix93.26 (7)O9—S4—Na1xv72.48 (11)
O13ix—Na1—S4ix15.63 (7)O1—S4—Na1xv37.54 (9)
O16x—Na1—S4ix84.33 (8)Cu2iv—S4—Na1xv73.80 (3)
O14xi—Na1—S4ix149.84 (9)Cu2—S4—Na1xv67.68 (3)
O1x—Na1—S4ix59.53 (6)Na3xi—S4—Na1xv143.05 (4)
O9x—Na1—S4ix63.88 (5)Na3—S4—Na1xv90.74 (5)
S4x—Na1—S4ix64.33 (3)K1vi—S4—Na1xv66.94 (3)
O8—Na1—S414.03 (6)O8—S4—Na1xi137.90 (12)
O5viii—Na1—S491.48 (7)O13—S4—Na1xi26.30 (11)
O13ix—Na1—S488.00 (8)O9—S4—Na1xi91.41 (11)
O16x—Na1—S471.26 (7)O1—S4—Na1xi99.78 (10)
O14xi—Na1—S4106.68 (8)Cu2iv—S4—Na1xi69.47 (3)
O1x—Na1—S4159.95 (8)Cu2—S4—Na1xi70.97 (3)
O9x—Na1—S4139.82 (5)Na3xi—S4—Na1xi64.99 (4)
S4x—Na1—S4162.12 (4)Na3—S4—Na1xi113.16 (4)
S4ix—Na1—S4102.82 (4)K1vi—S4—Na1xi140.01 (3)
O8—Na1—S3x97.49 (7)Na1xv—S4—Na1xi115.67 (3)
O5viii—Na1—S3x175.22 (8)S4—O1—Cu2iv113.67 (13)
O13ix—Na1—S3x82.83 (7)S4—O1—Na1xv121.20 (12)
O16x—Na1—S3x15.30 (7)Cu2iv—O1—Na1xv120.84 (11)
O14xi—Na1—S3x87.58 (7)S4—O1—K1vi97.43 (11)
O1x—Na1—S3x103.89 (6)Cu2iv—O1—K1vi103.09 (8)
O9x—Na1—S3x59.39 (5)Na1xv—O1—K1vi90.61 (8)
S4x—Na1—S3x83.46 (3)S4—O1—Na3xi53.09 (8)
S4ix—Na1—S3x89.38 (3)Cu2iv—O1—Na3xi66.66 (7)
S4—Na1—S3x84.04 (3)Na1xv—O1—Na3xi172.21 (9)
O8—Na1—S2viii88.42 (7)K1vi—O1—Na3xi85.25 (6)
O5viii—Na1—S2viii11.56 (6)S4—O1—Na1xi59.08 (8)
O13ix—Na1—S2viii94.34 (7)Cu2iv—O1—Na1xi65.13 (6)
O16x—Na1—S2viii166.98 (9)Na1xv—O1—Na1xi129.13 (7)
O14xi—Na1—S2viii93.41 (7)K1vi—O1—Na1xi139.70 (8)
O1x—Na1—S2viii69.38 (6)Na3xi—O1—Na1xi54.48 (4)
O9x—Na1—S2viii113.89 (5)S2—O2—Cu1i118.79 (13)
S4x—Na1—S2viii89.92 (3)S2—O2—Na2111.33 (12)
S4ix—Na1—S2viii86.39 (3)Cu1i—O2—Na2126.40 (10)
S4—Na1—S2viii102.06 (4)S2—O2—K1i101.10 (10)
S3x—Na1—S2viii173.21 (5)Cu1i—O2—K1i97.37 (8)
O8—Na1—Na359.21 (7)Na2—O2—K1i90.37 (8)
O5viii—Na1—Na3116.15 (8)S2—O2—Na2xiv66.13 (8)
O13ix—Na1—Na339.16 (7)Cu1i—O2—Na2xiv63.93 (6)
O16x—Na1—Na348.33 (8)Na2—O2—Na2xiv127.35 (8)
O14xi—Na1—Na3144.60 (8)K1i—O2—Na2xiv142.22 (7)
O1x—Na1—Na3112.05 (7)S2—O3—Cu2xviii122.43 (14)
O9x—Na1—Na390.89 (5)S2—O3—Na2xiv132.31 (13)
S4x—Na1—Na3107.61 (4)Cu2xviii—O3—Na2xiv93.25 (9)
S4ix—Na1—Na354.55 (4)S2—O3—Cu1i77.79 (10)
S4—Na1—Na354.99 (3)Cu2xviii—O3—Cu1i152.86 (11)
S3x—Na1—Na362.44 (4)Na2xiv—O3—Cu1i82.46 (7)
S2viii—Na1—Na3118.64 (5)S2—O3—Na3xviii141.25 (14)
O11xii—Na2—O6x83.29 (9)Cu2xviii—O3—Na3xviii70.48 (6)
O11xii—Na2—O4x161.19 (10)Na2xiv—O3—Na3xviii76.43 (7)
O6x—Na2—O4x78.64 (9)Cu1i—O3—Na3xviii82.49 (7)
O11xii—Na2—O2119.34 (10)S2—O3—K1v62.52 (9)
O6x—Na2—O2135.66 (10)Cu2xviii—O3—K1v66.65 (6)
O4x—Na2—O278.00 (8)Na2xiv—O3—K1v116.05 (8)
O11xii—Na2—O12xiii110.37 (10)Cu1i—O3—K1v138.91 (7)
O6x—Na2—O12xiii106.30 (9)Na3xviii—O3—K1v135.71 (7)
O4x—Na2—O12xiii70.41 (9)S2—O3—Na1xix61.31 (9)
O2—Na2—O12xiii100.52 (8)Cu2xviii—O3—Na1xix68.78 (6)
O11xii—Na2—O3xiv84.69 (10)Na2xiv—O3—Na1xix161.88 (9)
O6x—Na2—O3xiv68.50 (8)Cu1i—O3—Na1xix114.51 (7)
O4x—Na2—O3xiv93.41 (9)Na3xviii—O3—Na1xix98.65 (6)
O2—Na2—O3xiv75.89 (8)K1v—O3—Na1xix55.70 (4)
O12xiii—Na2—O3xiv163.80 (10)S1—O4—Cu1116.60 (13)
O11xii—Na2—O10xii70.26 (8)S1—O4—Na2xv130.66 (13)
O6x—Na2—O10xii139.16 (9)Cu1—O4—Na2xv102.54 (10)
O4x—Na2—O10xii127.74 (8)S1—O4—K1xvi122.28 (11)
O2—Na2—O10xii49.82 (7)Cu1—O4—K1xvi90.28 (7)
O12xiii—Na2—O10xii111.77 (8)Na2xv—O4—K1xvi84.14 (7)
O3xiv—Na2—O10xii78.31 (8)S1—O4—Na2iii59.98 (8)
O11xii—Na2—S296.77 (8)Cu1—O4—Na2iii62.55 (6)
O6x—Na2—S2151.47 (8)Na2xv—O4—Na2iii164.66 (8)
O4x—Na2—S2101.58 (7)K1xvi—O4—Na2iii98.83 (6)
O2—Na2—S225.16 (5)S1—O4—Na3xv45.50 (7)
O12xiii—Na2—S2100.42 (7)Cu1—O4—Na3xv80.83 (7)
O3xiv—Na2—S283.07 (6)Na2xv—O4—Na3xv121.21 (8)
O10xii—Na2—S226.66 (4)K1xvi—O4—Na3xv154.34 (7)
O11xii—Na2—O15x106.17 (9)Na2iii—O4—Na3xv55.73 (4)
O6x—Na2—O15x45.57 (7)S2—O5—Na1xix149.33 (16)
O4x—Na2—O15x56.84 (7)S2—O5—K1i100.29 (12)
O2—Na2—O15x134.49 (8)Na1xix—O5—K1i106.87 (9)
O12xiii—Na2—O15x61.59 (7)S2—O5—K1v82.61 (11)
O3xiv—Na2—O15x109.45 (8)Na1xix—O5—K1v78.26 (7)
O10xii—Na2—O15x171.42 (8)K1i—O5—K1v156.30 (9)
S2—Na2—O15x154.57 (6)S2—O5—Na256.71 (9)
O11xii—Na2—Cu1x134.16 (8)Na1xix—O5—Na2149.30 (10)
O6x—Na2—Cu1x74.64 (7)K1i—O5—Na266.19 (5)
O4x—Na2—Cu1x34.58 (6)K1v—O5—Na297.30 (6)
O2—Na2—Cu1x104.18 (7)S3—O6—Cu2117.30 (13)
O12xiii—Na2—Cu1x43.43 (6)S3—O6—Na2xv123.39 (12)
O3xiv—Na2—Cu1x121.48 (7)Cu2—O6—Na2xv107.13 (10)
O10xii—Na2—Cu1x145.50 (6)S3—O6—Na3109.56 (12)
S2—Na2—Cu1x121.39 (4)Cu2—O6—Na396.00 (9)
O15x—Na2—Cu1x33.19 (4)Na2xv—O6—Na398.20 (9)
O11xii—Na2—S3x89.80 (7)S3—O6—Na1xv59.55 (8)
O6x—Na2—S3x21.47 (6)Cu2—O6—Na1xv64.52 (6)
O4x—Na2—S3x71.45 (6)Na2xv—O6—Na1xv169.08 (10)
O2—Na2—S3x145.15 (7)Na3—O6—Na1xv89.93 (6)
O12xiii—Na2—S3x84.85 (7)S1—O7—Cu2142.39 (16)
O3xiv—Na2—S3x89.41 (6)S1—O7—Na3xv94.27 (13)
O10xii—Na2—S3x157.28 (6)Cu2—O7—Na3xv100.67 (10)
S2—Na2—S3x169.49 (5)S1—O7—K1xvii102.50 (12)
O15x—Na2—S3x25.12 (4)Cu2—O7—K1xvii102.54 (10)
Cu1x—Na2—S3x57.06 (3)Na3xv—O7—K1xvii113.93 (10)
O11xii—Na2—Cu2x95.86 (7)S1—O7—Na2xv73.43 (10)
O6x—Na2—Cu2x32.55 (6)Cu2—O7—Na2xv69.66 (7)
O4x—Na2—Cu2x71.40 (6)Na3xv—O7—Na2xv124.73 (10)
O2—Na2—Cu2x103.75 (7)K1xvii—O7—Na2xv121.32 (9)
O12xiii—Na2—Cu2x128.62 (7)S4—O8—Na1142.69 (16)
O3xiv—Na2—Cu2x40.35 (6)S4—O8—K1vi102.81 (12)
O10xii—Na2—Cu2x118.58 (6)Na1—O8—K1vi112.90 (9)
S2—Na2—Cu2x119.96 (4)S4—O8—Na383.34 (10)
O15x—Na2—Cu2x69.10 (5)Na1—O8—Na382.32 (8)
Cu1x—Na2—Cu2x86.64 (3)K1vi—O8—Na3129.36 (10)
S3x—Na2—Cu2x50.86 (2)S4—O8—Na3xi77.45 (11)
O11xii—Na2—S1x151.44 (8)Na1—O8—Na3xi85.32 (9)
O6x—Na2—S1x70.90 (7)K1vi—O8—Na3xi100.98 (7)
O4x—Na2—S1x18.65 (5)Na3—O8—Na3xi129.03 (8)
O2—Na2—S1x75.03 (6)S4—O9—Cu2131.73 (16)
O12xiii—Na2—S1x89.00 (7)S4—O9—Na3120.19 (14)
O3xiv—Na2—S1x74.80 (7)Cu2—O9—Na3107.39 (10)
O10xii—Na2—S1x122.93 (6)S4—O9—Na1xv83.07 (11)
S2—Na2—S1x100.18 (4)Cu2—O9—Na1xv83.73 (9)
O15x—Na2—S1x63.95 (5)Na3—O9—Na1xv115.59 (11)
Cu1x—Na2—S1x50.53 (2)S4—O9—Na1xi66.33 (10)
S3x—Na2—S1x70.64 (3)Cu2—O9—Na1xi75.76 (8)
Cu2x—Na2—S1x55.70 (2)Na3—O9—Na1xi133.43 (11)
O11xii—Na2—S1xii11.92 (6)Na1xv—O9—Na1xi110.96 (7)
O6x—Na2—S1xii95.20 (7)S2iii—O10—Cu1134.03 (15)
O4x—Na2—S1xii172.19 (7)S2iii—O10—K1xvi111.13 (11)
O2—Na2—S1xii109.82 (7)Cu1—O10—K1xvi102.50 (9)
O12xiii—Na2—S1xii107.24 (7)S2iii—O10—Na2iii84.86 (11)
O3xiv—Na2—S1xii88.71 (7)Cu1—O10—Na2iii89.29 (8)
O10xii—Na2—S1xii60.06 (5)K1xvi—O10—Na2iii139.71 (9)
S2—Na2—S1xii86.13 (4)S2iii—O10—Na2i66.23 (9)
O15x—Na2—S1xii115.38 (6)Cu1—O10—Na2i73.24 (7)
Cu1x—Na2—S1xii139.25 (4)K1xvi—O10—Na2i110.50 (8)
S3x—Na2—S1xii101.08 (4)Na2iii—O10—Na2i109.79 (7)
Cu2x—Na2—S1xii105.93 (3)S1—O11—Na2iii149.35 (15)
S1x—Na2—S1xii161.35 (4)S1—O11—Na3xv104.77 (13)
O9—Na3—O13ix114.06 (10)Na2iii—O11—Na3xv104.77 (10)
O9—Na3—O11x119.56 (10)S1—O11—Cu177.67 (11)
O13ix—Na3—O11x123.76 (10)Na2iii—O11—Cu188.14 (9)
O9—Na3—O662.61 (8)Na3xv—O11—Cu1102.52 (10)
O13ix—Na3—O6156.04 (12)S1—O11—Na2xiii68.05 (10)
O11x—Na3—O670.83 (8)Na2iii—O11—Na2xiii97.88 (9)
O9—Na3—O16x85.46 (10)Na3xv—O11—Na2xiii131.10 (10)
O13ix—Na3—O16x67.32 (10)Cu1—O11—Na2xiii121.20 (7)
O11x—Na3—O16x100.65 (10)S1—O12—Cu1xvi124.12 (14)
O6—Na3—O16x132.62 (11)S1—O12—Na2xiii146.15 (16)
O9—Na3—O7x154.67 (13)Cu1xvi—O12—Na2xiii89.18 (8)
O13ix—Na3—O7x72.55 (8)S1—O12—K1xvii97.77 (11)
O11x—Na3—O7x51.74 (7)Cu1xvi—O12—K1xvii89.87 (8)
O6—Na3—O7x121.48 (8)Na2xiii—O12—K1xvii87.17 (8)
O16x—Na3—O7x74.50 (9)S1—O12—K1xvi87.25 (11)
O9—Na3—O1487.28 (10)Cu1xvi—O12—K1xvi65.22 (6)
O13ix—Na3—O14110.78 (11)Na2xiii—O12—K1xvi103.82 (7)
O11x—Na3—O1487.92 (9)K1xvii—O12—K1xvi152.17 (8)
O6—Na3—O1447.11 (7)S1—O12—Na2xv56.01 (9)
O16x—Na3—O14170.75 (9)Cu1xvi—O12—Na2xv68.52 (6)
O7x—Na3—O14113.99 (9)Na2xiii—O12—Na2xv154.08 (8)
O9—Na3—O846.81 (7)K1xvii—O12—Na2xv105.13 (7)
O13ix—Na3—O867.46 (8)K1xvi—O12—Na2xv55.58 (4)
O11x—Na3—O8156.93 (11)S4—O13—Na1xi138.07 (17)
O6—Na3—O8106.89 (8)S4—O13—Na3xi118.66 (15)
O16x—Na3—O863.27 (8)Na1xi—O13—Na3xi102.40 (11)
O7x—Na3—O8130.01 (9)S4—O13—Cu2iv79.71 (11)
O14—Na3—O8107.51 (8)Na1xi—O13—Cu2iv92.24 (10)
O9—Na3—S1x138.27 (9)Na3xi—O13—Cu2iv90.86 (9)
O13ix—Na3—S1x99.32 (8)S4—O13—Na162.87 (11)
O11x—Na3—S1x25.32 (6)Na1xi—O13—Na1147.41 (10)
O6—Na3—S1x96.07 (6)Na3xi—O13—Na170.57 (9)
O16x—Na3—S1x85.09 (7)Cu2iv—O13—Na1119.07 (8)
O7x—Na3—S1x26.77 (5)S3—O14—Na1ix176.16 (18)
O14—Na3—S1x104.15 (7)S3—O14—K194.51 (12)
O8—Na3—S1x148.27 (8)Na1ix—O14—K189.25 (9)
O9—Na3—S4ix132.91 (7)S3—O14—Na390.21 (13)
O13ix—Na3—S4ix22.21 (6)Na1ix—O14—Na387.13 (9)
O11x—Na3—S4ix107.47 (7)K1—O14—Na3144.70 (10)
O6—Na3—S4ix143.77 (10)S3—O14—Na1xv63.74 (10)
O16x—Na3—S4ix83.61 (7)Na1ix—O14—Na1xv113.26 (8)
O7x—Na3—S4ix60.92 (5)K1—O14—Na1xv127.44 (9)
O14—Na3—S4ix97.22 (7)Na3—O14—Na1xv85.74 (7)
O8—Na3—S4ix87.94 (5)S3—O14—Na2xv53.02 (10)
S1x—Na3—S4ix86.06 (4)Na1ix—O14—Na2xv127.55 (10)
O9—Na3—O8ix139.25 (10)K1—O14—Na2xv93.58 (6)
O13ix—Na3—O8ix45.61 (8)Na3—O14—Na2xv62.06 (6)
O11x—Na3—O8ix96.37 (8)Na1xv—O14—Na2xv105.95 (7)
O6—Na3—O8ix119.62 (10)S3—O15—Cu1145.52 (17)
O16x—Na3—O8ix107.50 (8)S3—O15—K1106.45 (13)
O7x—Na3—O8ix63.58 (7)Cu1—O15—K1105.87 (10)
O14—Na3—O8ix74.65 (8)S3—O15—Na2xv79.83 (11)
O8—Na3—O8ix104.10 (5)Cu1—O15—Na2xv74.32 (8)
S1x—Na3—O8ix82.16 (5)K1—O15—Na2xv118.80 (10)
S4ix—Na3—O8ix24.72 (4)S3—O15—Na3xv76.21 (11)
O9—Na3—S422.24 (6)Cu1—O15—Na3xv88.34 (10)
O13ix—Na3—S492.40 (7)K1—O15—Na3xv136.81 (10)
O11x—Na3—S4137.50 (9)Na2xv—O15—Na3xv104.23 (7)
O6—Na3—S484.39 (6)S3—O16—Na1xv138.48 (18)
O16x—Na3—S471.23 (7)S3—O16—Na3xv125.57 (15)
O7x—Na3—S4145.69 (9)Na1xv—O16—Na3xv91.43 (9)
O14—Na3—S4100.10 (7)S3—O16—Cu279.20 (11)
O8—Na3—S424.95 (4)Na1xv—O16—Cu289.48 (9)
S1x—Na3—S4147.10 (8)Na3xv—O16—Cu282.03 (8)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y1/2, z+3/2; (iii) x, y, z+1; (iv) x, y+2, z+1; (v) x+1, y+1/2, z+1/2; (vi) x, y+1, z+1; (vii) x, y1, z; (viii) x1, y, z; (ix) x, y1/2, z+1/2; (x) x, y+3/2, z1/2; (xi) x, y+1/2, z+1/2; (xii) x, y, z1; (xiii) x+1, y+2, z+1; (xiv) x+1, y+1, z; (xv) x, y+3/2, z+1/2; (xvi) x+1, y+1/2, z+3/2; (xvii) x, y+1, z; (xviii) x+1, y1/2, z+1/2; (xix) x+1, y, z.
 

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