Buy article online - an online subscription or single-article purchase is required to access this article.
Download citation
Download citation
link to html
trans-[MoCl2(dppe)2] [dppe is 1,2-ethane­diyl­bis­(di­phenyl­phos­phine), C26H24P2] was obtained as a side product from the reaction of trans-[Mo(dppe)2(N2)2] with Cp*GeCl to give the germyl­yne complex trans-[Cl(dppe)2Mo[triple bond]Ge([eta]1-Cp*)]. The crystal structures of the hemi­pentane (0.5C5H12) and di­tetra­hydro­furan (2C4H8O) solvates of trans-[MoCl2(dppe)2], (IIIa) and (IIIb), respectively, have been determined.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S010827010001060X/qd0007sup1.cif
Contains datablocks IIIa, IIIb, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010827010001060X/qd0007IIIasup2.hkl
Contains datablock IIIa

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S010827010001060X/qd0007IIIbsup3.hkl
Contains datablock IIIb

CCDC references: 150723; 150724

Computing details top

Data collection: IPDS2.87 (Stoe & Cie, 1997) for (IIIa); STADI4-1.06 (Stoe & Cie, 1997) for (IIIb). Cell refinement: IPDS2.87 for (IIIa); STADI4-1.06 for (IIIb). Data reduction: IPDS2.87 for (IIIa); X-RED1.07 (Stoe & Cie, 1997) for (IIIb). For both compounds, program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XSTEP-2.18 (Stoe & Cie, 1997); software used to prepare material for publication: SHELXL97.

(IIIa) trans-Dichlorobis[1,2-ethandiylbis[diphenylphosphane]-P,P']molybdenum top
Crystal data top
[MoCl2(C26H24P2)2]·0.5C5H12F(000) = 4136
Mr = 999.70Dx = 1.371 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 49.542 (11) ÅCell parameters from 5000 reflections
b = 10.958 (3) Åθ = 5.0–20.3°
c = 18.123 (4) ŵ = 0.55 mm1
β = 100.03 (3)°T = 180 K
V = 9688 (4) Å3Plate, yellow
Z = 80.24 × 0.20 × 0.04 mm
Data collection top
Stoe IPDS
diffractometer
8494 independent reflections
Radiation source: fine-focus sealed X-ray tube2986 reflections with I > 2σ(I)
Planar graphite monochromatorRint = 0.099
Detector resolution: 6.667 pixels mm-1θmax = 25.1°, θmin = 2.2°
φ–oscill., φ–incr. = 1.3°, 183 exposures scansh = 5858
Absorption correction: part of the refinement model (ΔF)
(ABSCOR; Stoe & Cie, 1997)
k = 1313
Tmin = 0.879, Tmax = 0.978l = 2121
29774 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.074Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.157H-atom parameters not refined
S = 0.80 w = 1/[σ2(Fo2) + (0.0326P)2]
where P = (Fo2 + 2Fc2)/3
8494 reflections(Δ/σ)max = 0.028
555 parametersΔρmax = 1.24 e Å3
3 restraintsΔρmin = 1.09 e Å3
Special details top

Experimental. Recrystallized from pentan/toluene. During data collection the crystal was in cold N2 gas of the Cryostream Cooler (Oxford Cryosystems, 1992) mounted on a φ-axis diffractometer supplied with an area detector.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
C10.14558 (18)0.2861 (8)0.2353 (5)0.035 (2)
H1A0.14220.24910.28280.041*
H1B0.14380.37570.23950.041*
C20.1746 (2)0.2545 (9)0.2235 (5)0.040 (3)
H2A0.18790.30070.26010.048*
H2B0.17790.16650.23370.048*
C30.1135 (2)0.4313 (9)0.1444 (5)0.040 (3)
H3A0.11800.42840.19550.048*
H3B0.10400.50930.13890.048*
C40.0945 (2)0.3242 (10)0.1340 (5)0.044 (3)
H4A0.07690.33330.16890.053*
H4B0.10300.24650.14580.053*
C110.0882 (2)0.2785 (10)0.1907 (5)0.041 (3)
C120.0804 (2)0.4009 (10)0.1848 (6)0.048 (3)
H120.09090.45880.16280.057*
C130.0569 (2)0.4365 (12)0.2122 (7)0.065 (4)
H130.05160.51990.20860.078*
C140.0414 (3)0.3568 (14)0.2434 (6)0.071 (4)
H140.02610.38520.26360.085*
C150.0479 (3)0.2331 (13)0.2462 (8)0.083 (5)
H150.03620.17630.26480.099*
C160.0713 (2)0.1928 (12)0.2218 (7)0.069 (4)
H160.07620.10890.22560.083*
C170.1201 (2)0.0667 (9)0.1715 (5)0.039 (3)
C180.1088 (2)0.0126 (9)0.1110 (6)0.047 (3)
H180.10100.02140.06380.056*
C190.1091 (2)0.1372 (10)0.1204 (6)0.054 (3)
H190.10140.18850.08000.065*
C200.1206 (2)0.1875 (11)0.1876 (6)0.053 (3)
H200.12060.27370.19320.064*
C210.1325 (2)0.1141 (10)0.2490 (6)0.057 (3)
H210.14060.15090.29500.068*
C220.1320 (2)0.0118 (9)0.2415 (5)0.043 (3)
H220.13960.06180.28280.051*
C310.20196 (19)0.1591 (8)0.1085 (4)0.028 (2)
C320.1918 (2)0.0387 (9)0.1154 (5)0.040 (3)
H320.17460.02690.13110.048*
C330.2069 (2)0.0611 (10)0.0991 (5)0.045 (3)
H330.19970.14070.10340.054*
C340.2320 (2)0.0481 (10)0.0768 (5)0.048 (3)
H340.24220.11840.06730.057*
C350.2424 (2)0.0667 (11)0.0683 (5)0.054 (3)
H350.25930.07650.05110.065*
C360.22741 (19)0.1707 (9)0.0859 (5)0.036 (2)
H360.23490.24980.08210.043*
C370.2066 (2)0.4117 (9)0.1435 (5)0.034 (2)
C380.2269 (2)0.4185 (10)0.2071 (5)0.044 (3)
H380.22780.35800.24500.053*
C390.2458 (2)0.5139 (10)0.2155 (5)0.046 (3)
H390.25910.51970.25990.056*
C400.2453 (2)0.6005 (10)0.1592 (6)0.048 (3)
H400.25840.66440.16470.057*
C410.2254 (2)0.5933 (11)0.0949 (6)0.055 (3)
H410.22490.65240.05630.066*
C420.2065 (2)0.5005 (9)0.0873 (5)0.043 (3)
H420.19310.49600.04310.052*
C510.1697 (2)0.3522 (8)0.1262 (4)0.033 (2)
C520.1872 (2)0.2589 (9)0.0941 (5)0.037 (3)
H520.18700.23650.04360.045*
C530.2050 (2)0.1972 (9)0.1334 (5)0.041 (3)
H530.21680.13460.11010.049*
C540.2050 (2)0.2301 (10)0.2080 (5)0.047 (3)
H540.21660.18810.23600.056*
C550.1883 (2)0.3232 (10)0.2416 (5)0.044 (3)
H550.18880.34620.29190.053*
C560.1710 (2)0.3822 (9)0.2016 (5)0.043 (3)
H560.15950.44520.22540.052*
C570.1554 (2)0.5840 (8)0.0727 (5)0.034 (2)
C580.1376 (2)0.6764 (10)0.0551 (5)0.046 (3)
H580.12010.65320.04470.055*
C590.1446 (3)0.8018 (10)0.0522 (5)0.051 (3)
H590.13200.86150.04080.061*
C600.1700 (2)0.8351 (11)0.0663 (5)0.053 (3)
H600.17460.91930.06630.064*
C610.1893 (2)0.7496 (10)0.0807 (5)0.049 (3)
H610.20710.77470.08760.058*
C620.1819 (2)0.6251 (10)0.0847 (5)0.046 (3)
H620.19480.56670.09570.055*
C710.0627 (2)0.4424 (10)0.0402 (5)0.038 (3)
C720.0684 (2)0.5485 (11)0.0022 (6)0.050 (3)
H7250.08590.55890.03290.060*
C730.0492 (3)0.6365 (11)0.0004 (7)0.064 (4)
H730.05350.70910.02790.076*
C740.0230 (3)0.6234 (11)0.0439 (8)0.062 (3)
H740.00970.68610.04510.074*
C750.0170 (2)0.5192 (13)0.0843 (7)0.062 (4)
H750.00080.50800.11290.074*
C760.0366 (2)0.4298 (11)0.0840 (6)0.052 (3)
H760.03240.35890.11390.063*
C770.0670 (2)0.1852 (10)0.0333 (5)0.045 (3)
C780.0690 (2)0.0818 (10)0.0771 (6)0.055 (3)
H780.08020.08300.11480.066*
C790.0541 (3)0.0255 (11)0.0647 (7)0.064 (3)
H790.05570.09780.09250.076*
C800.0370 (3)0.0222 (13)0.0108 (8)0.073 (4)
H800.02660.09250.00350.087*
C810.0349 (2)0.0807 (12)0.0322 (7)0.060 (3)
H810.02340.08050.06890.072*
C820.0495 (2)0.1817 (12)0.0212 (6)0.056 (3)
H820.04810.25220.05080.067*
C830.00000.210 (3)0.25000.21 (2)
H83A0.01260.26200.28480.252*0.50
H83B0.01260.26200.21520.252*0.50
C840.0152 (6)0.123 (2)0.209 (2)0.288 (19)
H84A0.00270.09300.16400.345*
H84B0.02130.05250.24140.345*
C850.0395 (5)0.181 (2)0.1853 (13)0.249 (19)
H85A0.04520.13170.14540.374*
H85B0.03480.26320.16680.374*
H85C0.05460.18440.22820.374*
Cl10.13622 (5)0.5178 (2)0.10646 (12)0.0399 (6)
Cl20.13788 (5)0.1276 (2)0.02028 (13)0.0422 (6)
P10.11998 (6)0.2306 (2)0.15804 (13)0.0344 (7)
P20.18085 (6)0.2888 (2)0.12733 (13)0.0341 (7)
P30.14594 (5)0.4242 (2)0.07361 (12)0.0335 (6)
P40.08827 (5)0.3205 (3)0.03786 (13)0.0357 (7)
Mo0.13465 (2)0.32020 (8)0.04336 (4)0.0322 (2)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.037 (6)0.038 (6)0.029 (5)0.007 (5)0.008 (4)0.017 (4)
C20.058 (8)0.032 (6)0.033 (5)0.005 (5)0.015 (5)0.000 (4)
C30.051 (7)0.047 (6)0.027 (5)0.003 (5)0.020 (5)0.004 (4)
C40.045 (7)0.067 (7)0.022 (4)0.005 (6)0.010 (4)0.001 (5)
C110.043 (7)0.052 (7)0.031 (5)0.010 (5)0.015 (5)0.015 (5)
C120.048 (7)0.038 (7)0.060 (7)0.012 (5)0.018 (6)0.001 (5)
C130.053 (9)0.068 (9)0.076 (8)0.016 (7)0.016 (7)0.013 (7)
C140.055 (9)0.105 (12)0.058 (7)0.017 (8)0.026 (7)0.005 (7)
C150.074 (11)0.078 (10)0.111 (12)0.011 (8)0.058 (9)0.027 (9)
C160.051 (8)0.070 (9)0.098 (9)0.014 (7)0.042 (7)0.036 (8)
C170.041 (7)0.043 (6)0.036 (5)0.002 (5)0.014 (5)0.000 (5)
C180.069 (9)0.033 (6)0.041 (6)0.002 (6)0.020 (6)0.005 (5)
C190.071 (9)0.043 (7)0.050 (7)0.005 (6)0.012 (6)0.008 (5)
C200.074 (9)0.036 (6)0.052 (6)0.001 (6)0.019 (6)0.006 (6)
C210.074 (9)0.056 (8)0.042 (6)0.009 (7)0.012 (6)0.011 (6)
C220.068 (8)0.034 (6)0.027 (5)0.001 (5)0.009 (5)0.003 (4)
C310.039 (6)0.026 (6)0.022 (4)0.009 (5)0.009 (4)0.003 (4)
C320.052 (7)0.035 (6)0.031 (5)0.012 (5)0.004 (5)0.004 (4)
C330.056 (8)0.042 (7)0.034 (5)0.005 (6)0.003 (5)0.004 (5)
C340.067 (9)0.035 (6)0.043 (6)0.004 (6)0.015 (6)0.004 (5)
C350.073 (9)0.059 (8)0.032 (5)0.009 (7)0.015 (6)0.006 (5)
C360.043 (6)0.029 (5)0.036 (5)0.005 (5)0.010 (5)0.002 (5)
C370.038 (7)0.044 (6)0.024 (5)0.001 (5)0.012 (4)0.002 (4)
C380.036 (7)0.060 (7)0.034 (5)0.008 (6)0.004 (5)0.012 (5)
C390.046 (8)0.054 (7)0.036 (5)0.001 (6)0.003 (5)0.001 (5)
C400.048 (8)0.052 (7)0.046 (6)0.018 (6)0.012 (6)0.019 (5)
C410.072 (9)0.064 (8)0.030 (5)0.025 (7)0.012 (6)0.004 (5)
C420.055 (8)0.048 (7)0.027 (5)0.004 (6)0.011 (5)0.003 (5)
C510.044 (7)0.040 (6)0.015 (4)0.003 (5)0.002 (4)0.004 (4)
C520.029 (6)0.062 (7)0.023 (5)0.000 (5)0.013 (4)0.001 (5)
C530.051 (7)0.031 (6)0.043 (5)0.012 (5)0.012 (5)0.008 (5)
C540.052 (8)0.059 (7)0.034 (5)0.004 (6)0.021 (5)0.006 (5)
C550.061 (7)0.043 (6)0.030 (5)0.002 (6)0.016 (5)0.000 (5)
C560.066 (8)0.036 (6)0.030 (5)0.002 (5)0.015 (5)0.003 (4)
C570.042 (7)0.030 (6)0.030 (5)0.005 (5)0.009 (5)0.006 (4)
C580.064 (8)0.039 (6)0.039 (5)0.008 (6)0.020 (5)0.005 (5)
C590.082 (10)0.031 (7)0.042 (6)0.005 (6)0.017 (6)0.010 (5)
C600.082 (9)0.049 (7)0.029 (5)0.006 (7)0.011 (6)0.013 (5)
C610.072 (9)0.043 (7)0.030 (5)0.006 (6)0.009 (5)0.007 (5)
C620.049 (8)0.059 (8)0.030 (5)0.009 (6)0.007 (5)0.007 (5)
C710.035 (7)0.047 (7)0.033 (5)0.001 (5)0.012 (5)0.009 (5)
C720.046 (8)0.067 (8)0.039 (6)0.022 (6)0.009 (5)0.011 (6)
C730.054 (9)0.058 (9)0.078 (8)0.018 (7)0.009 (7)0.002 (7)
C740.050 (9)0.038 (7)0.100 (10)0.017 (6)0.021 (8)0.005 (7)
C750.035 (8)0.085 (10)0.064 (8)0.002 (7)0.007 (6)0.025 (7)
C760.034 (7)0.066 (8)0.057 (7)0.012 (6)0.008 (6)0.014 (6)
C770.047 (7)0.045 (7)0.042 (6)0.006 (6)0.008 (5)0.009 (6)
C780.064 (9)0.041 (7)0.054 (7)0.015 (6)0.005 (6)0.001 (6)
C790.075 (10)0.040 (7)0.072 (8)0.013 (7)0.003 (7)0.001 (6)
C800.046 (9)0.082 (11)0.084 (9)0.018 (7)0.004 (7)0.024 (8)
C810.052 (8)0.068 (9)0.062 (7)0.003 (7)0.013 (6)0.000 (7)
C820.035 (7)0.078 (9)0.057 (7)0.026 (7)0.010 (6)0.015 (7)
C830.38 (6)0.11 (3)0.10 (2)0.0000.09 (3)0.000
C840.36 (6)0.17 (3)0.31 (6)0.02 (3)0.00 (4)0.08 (3)
C850.42 (5)0.22 (3)0.15 (2)0.20 (3)0.15 (3)0.09 (2)
Cl10.0513 (18)0.0397 (15)0.0302 (12)0.0025 (13)0.0116 (12)0.0038 (11)
Cl20.0479 (17)0.0458 (15)0.0339 (13)0.0031 (12)0.0102 (12)0.0006 (11)
P10.0429 (18)0.0381 (16)0.0236 (12)0.0011 (13)0.0097 (12)0.0024 (11)
P20.0406 (18)0.0405 (17)0.0228 (12)0.0009 (13)0.0102 (12)0.0001 (11)
P30.0411 (17)0.0390 (16)0.0225 (12)0.0015 (13)0.0115 (12)0.0016 (11)
P40.0367 (18)0.0430 (16)0.0276 (13)0.0011 (15)0.0066 (12)0.0012 (13)
Mo0.0393 (6)0.0372 (5)0.0216 (4)0.0002 (5)0.0095 (4)0.0004 (4)
Geometric parameters (Å, º) top
C1—C21.529 (12)C51—P31.820 (9)
C1—P11.822 (10)C52—C531.402 (12)
C2—P21.861 (8)C53—C541.399 (12)
C3—C41.537 (13)C54—C551.386 (14)
C3—P31.876 (10)C55—C561.375 (12)
C4—P41.823 (8)C57—C581.415 (13)
C11—C121.394 (13)C57—C621.441 (13)
C11—C161.435 (13)C57—P31.813 (9)
C11—P11.852 (10)C58—C591.416 (14)
C12—C131.399 (13)C59—C601.380 (14)
C13—C141.350 (16)C60—C611.394 (14)
C14—C151.392 (16)C61—C621.411 (13)
C15—C161.384 (14)C71—C721.395 (14)
C17—C181.434 (13)C71—C761.401 (14)
C17—C221.435 (13)C71—P41.836 (11)
C17—P11.813 (10)C72—C731.352 (14)
C18—C191.376 (13)C73—C741.402 (16)
C19—C201.368 (15)C74—C751.360 (16)
C20—C211.415 (15)C75—C761.379 (15)
C21—C221.387 (13)C77—C781.398 (14)
C31—C361.398 (11)C77—C821.421 (12)
C31—C321.426 (12)C77—P41.830 (11)
C31—P21.831 (9)C78—C791.428 (14)
C32—C331.385 (13)C79—C801.398 (16)
C33—C341.384 (13)C80—C811.384 (16)
C34—C351.378 (14)C81—C821.356 (15)
C35—C361.427 (13)C83—C841.489 (17)
C37—C381.392 (13)C83—C84i1.489 (17)
C37—C421.408 (12)C84—C851.483 (18)
C37—P21.844 (10)Cl1—Mo2.444 (3)
C38—C391.395 (13)Cl2—Mo2.424 (3)
C39—C401.390 (13)P1—Mo2.518 (2)
C40—C411.391 (14)P2—Mo2.542 (3)
C41—C421.372 (14)P3—Mo2.553 (2)
C51—C521.399 (13)P4—Mo2.504 (3)
C51—C561.417 (11)
C2—C1—P1111.2 (6)C73—C72—C71120.0 (12)
C1—C2—P2113.6 (7)C72—C73—C74121.7 (13)
C4—C3—P3110.8 (7)C75—C74—C73118.7 (11)
C3—C4—P4110.1 (7)C74—C75—C76120.5 (13)
C12—C11—C16119.2 (9)C75—C76—C71120.8 (12)
C12—C11—P1119.1 (7)C78—C77—C82119.1 (10)
C16—C11—P1121.7 (8)C78—C77—P4122.1 (7)
C11—C12—C13118.5 (10)C82—C77—P4118.6 (9)
C14—C13—C12122.5 (12)C77—C78—C79119.1 (10)
C13—C14—C15120.1 (11)C80—C79—C78118.8 (12)
C16—C15—C14120.0 (12)C81—C80—C79121.9 (12)
C15—C16—C11119.6 (11)C82—C81—C80119.2 (11)
C18—C17—C22117.9 (9)C81—C82—C77121.9 (12)
C18—C17—P1120.4 (7)C84—C83—C84i101 (3)
C22—C17—P1121.7 (8)C85—C84—C83112.5 (16)
C19—C18—C17120.8 (10)C17—P1—C1104.0 (4)
C20—C19—C18120.3 (11)C17—P1—C11102.7 (5)
C19—C20—C21121.5 (11)C1—P1—C11100.2 (4)
C22—C21—C20119.4 (10)C17—P1—Mo120.2 (3)
C21—C22—C17120.0 (10)C1—P1—Mo104.0 (3)
C36—C31—C32117.5 (8)C11—P1—Mo122.5 (3)
C36—C31—P2123.9 (7)C31—P2—C37101.2 (4)
C32—C31—P2118.6 (7)C31—P2—C2102.2 (4)
C33—C32—C31119.9 (9)C37—P2—C2102.9 (4)
C34—C33—C32122.0 (10)C31—P2—Mo118.5 (3)
C35—C34—C33119.9 (10)C37—P2—Mo121.5 (3)
C34—C35—C36119.1 (10)C2—P2—Mo107.9 (3)
C31—C36—C35121.6 (9)C57—P3—C51103.5 (4)
C38—C37—C42118.3 (9)C57—P3—C398.9 (5)
C38—C37—P2123.4 (7)C51—P3—C3102.4 (4)
C42—C37—P2118.3 (7)C57—P3—Mo121.1 (3)
C37—C38—C39120.2 (9)C51—P3—Mo119.8 (3)
C40—C39—C38120.4 (10)C3—P3—Mo107.5 (3)
C39—C40—C41119.7 (10)C4—P4—C77104.8 (5)
C42—C41—C40119.8 (10)C4—P4—C71101.1 (5)
C41—C42—C37121.5 (10)C77—P4—C71100.9 (5)
C52—C51—C56116.2 (8)C4—P4—Mo105.8 (3)
C52—C51—P3120.6 (6)C77—P4—Mo116.7 (4)
C56—C51—P3123.2 (8)C71—P4—Mo125.0 (4)
C51—C52—C53122.7 (8)Cl2—Mo—Cl1174.24 (10)
C54—C53—C52118.2 (9)Cl2—Mo—P481.45 (10)
C55—C54—C53120.9 (9)Cl1—Mo—P4103.00 (10)
C56—C55—C54119.6 (9)Cl2—Mo—P196.08 (9)
C55—C56—C51122.4 (10)Cl1—Mo—P187.09 (8)
C58—C57—C62115.5 (9)P4—Mo—P196.81 (9)
C58—C57—P3121.6 (7)Cl2—Mo—P292.28 (9)
C62—C57—P3122.8 (8)Cl1—Mo—P283.57 (9)
C57—C58—C59123.0 (10)P4—Mo—P2172.21 (10)
C60—C59—C58118.4 (10)P1—Mo—P279.18 (9)
C59—C60—C61122.3 (11)Cl2—Mo—P387.21 (8)
C60—C61—C62118.6 (11)Cl1—Mo—P389.97 (8)
C61—C62—C57122.0 (10)P4—Mo—P379.78 (9)
C72—C71—C76118.2 (10)P1—Mo—P3174.89 (10)
C72—C71—P4121.4 (8)P2—Mo—P3104.65 (9)
C76—C71—P4120.4 (9)
P1—C1—C2—P246.4 (8)C1—C2—P2—C31141.2 (7)
P3—C3—C4—P454.5 (8)C1—C2—P2—C37114.1 (7)
C16—C11—C12—C132.3 (17)C1—C2—P2—Mo15.5 (8)
P1—C11—C12—C13177.7 (9)C58—C57—P3—C51162.8 (8)
C11—C12—C13—C140.4 (19)C62—C57—P3—C5121.4 (9)
C12—C13—C14—C153 (2)C58—C57—P3—C357.7 (8)
C13—C14—C15—C165 (2)C62—C57—P3—C3126.6 (8)
C14—C15—C16—C113 (2)C58—C57—P3—Mo59.1 (9)
C12—C11—C16—C150.7 (19)C62—C57—P3—Mo116.6 (7)
P1—C11—C16—C15179.3 (11)C52—C51—P3—C57122.0 (8)
C22—C17—C18—C191.0 (15)C56—C51—P3—C5760.8 (9)
P1—C17—C18—C19179.1 (8)C52—C51—P3—C3135.5 (8)
C17—C18—C19—C200.9 (17)C56—C51—P3—C341.7 (9)
C18—C19—C20—C210.2 (17)C52—C51—P3—Mo16.7 (9)
C19—C20—C21—C221.3 (17)C56—C51—P3—Mo160.5 (7)
C20—C21—C22—C171.1 (16)C4—C3—P3—C57156.1 (6)
C18—C17—C22—C210.1 (15)C4—C3—P3—C5197.8 (6)
P1—C17—C22—C21178.0 (8)C4—C3—P3—Mo29.3 (7)
C36—C31—C32—C330.7 (13)C3—C4—P4—C77177.3 (7)
P2—C31—C32—C33177.9 (7)C3—C4—P4—C7178.2 (8)
C31—C32—C33—C340.7 (15)C3—C4—P4—Mo53.3 (7)
C32—C33—C34—C351.7 (16)C78—C77—P4—C430.8 (10)
C33—C34—C35—C362.6 (16)C82—C77—P4—C4154.6 (9)
C32—C31—C36—C351.6 (14)C78—C77—P4—C71135.5 (9)
P2—C31—C36—C35176.9 (7)C82—C77—P4—C7149.9 (9)
C34—C35—C36—C312.7 (15)C78—C77—P4—Mo85.8 (9)
C42—C37—C38—C392.3 (14)C82—C77—P4—Mo88.8 (9)
P2—C37—C38—C39179.7 (7)C72—C71—P4—C4115.1 (8)
C37—C38—C39—C402.3 (15)C76—C71—P4—C466.0 (8)
C38—C39—C40—C411.2 (16)C72—C71—P4—C77137.2 (8)
C39—C40—C41—C420.2 (16)C76—C71—P4—C7741.7 (8)
C40—C41—C42—C370.2 (16)C72—C71—P4—Mo3.2 (9)
C38—C37—C42—C411.3 (15)C76—C71—P4—Mo175.7 (6)
P2—C37—C42—C41178.8 (8)C4—P4—Mo—Cl263.0 (4)
C56—C51—C52—C530.2 (15)C77—P4—Mo—Cl253.1 (4)
P3—C51—C52—C53177.2 (8)C71—P4—Mo—Cl2179.2 (3)
C51—C52—C53—C540.6 (15)C4—P4—Mo—Cl1113.2 (4)
C52—C53—C54—C551.5 (16)C77—P4—Mo—Cl1130.7 (4)
C53—C54—C55—C561.5 (16)C71—P4—Mo—Cl13.0 (3)
C54—C55—C56—C510.7 (16)C4—P4—Mo—P1158.2 (4)
C52—C51—C56—C550.2 (15)C77—P4—Mo—P142.1 (4)
P3—C51—C56—C55177.1 (8)C71—P4—Mo—P185.6 (3)
C62—C57—C58—C592.5 (14)C4—P4—Mo—P299.7 (7)
P3—C57—C58—C59178.5 (7)C77—P4—Mo—P216.4 (8)
C57—C58—C59—C600.8 (15)C71—P4—Mo—P2144.1 (7)
C58—C59—C60—C612.2 (15)C4—P4—Mo—P325.6 (4)
C59—C60—C61—C623.4 (15)C77—P4—Mo—P3141.8 (4)
C60—C61—C62—C571.5 (15)C71—P4—Mo—P390.6 (3)
C58—C57—C62—C611.3 (14)C17—P1—Mo—Cl28.0 (4)
P3—C57—C62—C61177.3 (8)C1—P1—Mo—Cl2123.7 (3)
C76—C71—C72—C730.8 (14)C11—P1—Mo—Cl2124.2 (4)
P4—C71—C72—C73179.7 (8)C17—P1—Mo—Cl1167.2 (4)
C71—C72—C73—C741.4 (16)C1—P1—Mo—Cl151.4 (3)
C72—C73—C74—C750.1 (18)C11—P1—Mo—Cl160.6 (4)
C73—C74—C75—C761.8 (17)C17—P1—Mo—P490.1 (4)
C74—C75—C76—C712.3 (16)C1—P1—Mo—P4154.2 (3)
C72—C71—C76—C751.0 (14)C11—P1—Mo—P442.2 (4)
P4—C71—C76—C75178.0 (8)C17—P1—Mo—P283.1 (4)
C82—C77—C78—C791.6 (16)C1—P1—Mo—P232.6 (3)
P4—C77—C78—C79172.9 (9)C11—P1—Mo—P2144.6 (4)
C77—C78—C79—C802.4 (18)C17—P1—Mo—P3137.9 (11)
C78—C79—C80—C812.0 (19)C1—P1—Mo—P3106.4 (12)
C79—C80—C81—C820.8 (19)C11—P1—Mo—P35.7 (13)
C80—C81—C82—C770.1 (18)C31—P2—Mo—Cl27.5 (3)
C78—C77—C82—C810.4 (17)C37—P2—Mo—Cl2133.8 (3)
P4—C77—C82—C81174.3 (9)C2—P2—Mo—Cl2108.0 (3)
C84i—C83—C84—C85159 (4)C31—P2—Mo—Cl1168.5 (3)
C18—C17—P1—C1161.5 (8)C37—P2—Mo—Cl142.2 (3)
C22—C17—P1—C116.6 (9)C2—P2—Mo—Cl176.1 (3)
C18—C17—P1—C1194.5 (8)C31—P2—Mo—P443.7 (8)
C22—C17—P1—C1187.5 (9)C37—P2—Mo—P4170.0 (6)
C18—C17—P1—Mo45.7 (9)C2—P2—Mo—P471.7 (7)
C22—C17—P1—Mo132.3 (7)C31—P2—Mo—P1103.2 (3)
C2—C1—P1—C1772.4 (7)C37—P2—Mo—P1130.4 (3)
C2—C1—P1—C11178.4 (6)C2—P2—Mo—P112.2 (3)
C2—C1—P1—Mo54.2 (6)C31—P2—Mo—P380.2 (3)
C12—C11—P1—C17176.6 (9)C37—P2—Mo—P346.1 (3)
C16—C11—P1—C173.3 (10)C2—P2—Mo—P3164.3 (3)
C12—C11—P1—C176.4 (9)C57—P3—Mo—Cl2167.0 (4)
C16—C11—P1—C1103.7 (10)C51—P3—Mo—Cl235.6 (4)
C12—C11—P1—Mo37.6 (10)C3—P3—Mo—Cl280.6 (3)
C16—C11—P1—Mo142.4 (8)C57—P3—Mo—Cl18.0 (4)
C36—C31—P2—C3720.4 (9)C51—P3—Mo—Cl1139.4 (4)
C32—C31—P2—C37161.1 (7)C3—P3—Mo—Cl1104.4 (3)
C36—C31—P2—C2126.3 (8)C57—P3—Mo—P4111.2 (4)
C32—C31—P2—C255.2 (8)C51—P3—Mo—P4117.4 (4)
C36—C31—P2—Mo115.2 (8)C3—P3—Mo—P41.2 (3)
C32—C31—P2—Mo63.3 (7)C57—P3—Mo—P162.8 (13)
C38—C37—P2—C3171.3 (9)C51—P3—Mo—P1165.8 (11)
C42—C37—P2—C31106.1 (8)C3—P3—Mo—P149.6 (12)
C38—C37—P2—C234.2 (9)C57—P3—Mo—P275.4 (4)
C42—C37—P2—C2148.4 (7)C51—P3—Mo—P256.1 (4)
C38—C37—P2—Mo154.9 (7)C3—P3—Mo—P2172.2 (3)
C42—C37—P2—Mo27.7 (8)
Symmetry code: (i) x, y, z1/2.
(IIIb) trans-Dichlorobis[1,2-ethandiylbis[diphenylphosphane]-P,P']molybdenum top
Crystal data top
[MoCl2(C26H24P2)2]·2C4H8OF(000) = 1152
Mr = 1107.83Dx = 1.397 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 11.3197 (11) ÅCell parameters from 26 reflections
b = 13.4052 (14) Åθ = 13.5–16.4°
c = 17.455 (2) ŵ = 0.52 mm1
β = 96.093 (11)°T = 180 K
V = 2633.7 (4) Å3Block, brown
Z = 20.80 × 0.54 × 0.28 mm
Data collection top
Stoe Stadi-4
diffractometer
4065 reflections with I > 2σ(I)
Radiation source: fine-focus sealed X-ray tubeRint = 0.032
Planar graphite monochromatorθmax = 25.0°, θmin = 1.8°
2θ/ω scans, ratio = 1.0, width (ω) = 1.2–1.68°h = 1313
Absorption correction: ψ scan
(North et al., 1968)
k = 015
Tmin = 0.683, Tmax = 0.869l = 2020
6801 measured reflections3 standard reflections every 120 min
4617 independent reflections intensity decay: 8.6%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.033Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.094H-atom parameters not refined
S = 1.07 w = 1/[σ2(Fo2) + (0.0565P)2 + 1.227P]
where P = (Fo2 + 2Fc2)/3
4617 reflections(Δ/σ)max = 0.009
313 parametersΔρmax = 0.80 e Å3
1 restraintΔρmin = 0.85 e Å3
Special details top

Experimental. Recrystallized from tetrahydrofurane. During data collection the crystal was in cold N2 gas of the Cryostream Cooler (Oxford Cryosystems, 1992) mounted on a φ-axis diffractometer supplied with an area detector.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.2744 (2)0.09477 (17)0.10487 (14)0.0253 (5)
C20.3390 (2)0.05496 (19)0.17043 (15)0.0316 (6)
H20.29980.03890.21430.038*
C30.4607 (2)0.0387 (2)0.17162 (18)0.0422 (7)
H30.50400.01090.21620.051*
C40.5185 (2)0.0625 (2)0.10882 (19)0.0436 (7)
H40.60130.05050.10970.052*
C50.4558 (2)0.1042 (2)0.04412 (18)0.0388 (7)
H50.49630.12290.00130.047*
C60.3340 (2)0.11877 (19)0.04172 (15)0.0303 (5)
H60.29110.14530.00340.036*
C70.0943 (2)0.24637 (18)0.09879 (13)0.0255 (5)
C80.1893 (2)0.31124 (19)0.11594 (16)0.0337 (6)
H80.26710.28540.12850.040*
C90.1708 (3)0.4140 (2)0.11482 (18)0.0420 (7)
H90.23610.45790.12640.050*
C100.0582 (3)0.4523 (2)0.09695 (17)0.0398 (7)
H100.04600.52240.09590.048*
C110.0361 (3)0.3890 (2)0.08070 (17)0.0403 (7)
H110.11380.41550.06900.048*
C120.0190 (2)0.28608 (19)0.08119 (16)0.0335 (6)
H120.08490.24280.06950.040*
C130.0666 (2)0.07568 (18)0.19102 (13)0.0259 (5)
H13A0.01330.10390.19530.031*
H13B0.12220.10620.23200.031*
C140.1449 (2)0.20764 (18)0.13228 (14)0.0281 (5)
C150.2447 (2)0.2041 (2)0.09352 (17)0.0395 (6)
H150.25010.15590.05420.047*
C160.3383 (3)0.2712 (3)0.11179 (18)0.0490 (8)
H160.40690.26820.08490.059*
C170.3311 (3)0.3417 (2)0.16882 (19)0.0458 (7)
H170.39380.38810.18030.055*
C180.2332 (3)0.3447 (2)0.20896 (19)0.0441 (7)
H180.22890.39220.24900.053*
C190.1403 (2)0.2781 (2)0.19089 (17)0.0382 (6)
H190.07280.28060.21880.046*
C200.1049 (2)0.18610 (18)0.13252 (14)0.0259 (5)
C210.1917 (2)0.1512 (2)0.17613 (16)0.0381 (6)
H210.18080.08920.20220.046*
C220.2945 (3)0.2062 (3)0.18209 (19)0.0514 (8)
H220.35380.18110.21160.062*
C230.3107 (3)0.2973 (3)0.14507 (19)0.0503 (8)
H230.38050.33500.14980.060*
C240.2256 (3)0.3330 (2)0.10151 (18)0.0432 (7)
H240.23690.39530.07580.052*
C250.1231 (2)0.27803 (19)0.09508 (15)0.0315 (6)
H250.06460.30310.06490.038*
C260.0625 (2)0.03727 (19)0.20475 (14)0.0310 (6)
H26A0.00210.05130.24040.037*
H26B0.14050.05900.23040.037*
C270.5564 (3)0.3270 (3)0.1901 (2)0.0569 (9)
H27A0.51650.26120.18850.068*
H27B0.58890.34110.24390.068*
C280.6540 (3)0.3272 (3)0.1384 (2)0.0693 (11)
H28A0.72910.35180.16620.083*
H28B0.66720.25930.11870.083*
C290.6129 (4)0.3936 (5)0.0761 (3)0.108 (2)
H29A0.66490.45310.07690.129*
H29B0.61510.35930.02600.129*
C300.4928 (4)0.4234 (4)0.0856 (2)0.0745 (12)
H30A0.48190.49550.07440.089*
H30B0.43560.38550.04990.089*
P10.11330 (5)0.11024 (4)0.09633 (3)0.02144 (15)
P20.02695 (5)0.11315 (4)0.11497 (3)0.02242 (15)
Mo0.00000.00000.00000.01831 (10)
O0.4741 (2)0.4033 (2)0.16214 (13)0.0627 (7)
Cl0.17261 (5)0.05089 (4)0.06254 (3)0.02631 (15)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0237 (11)0.0177 (11)0.0342 (13)0.0022 (9)0.0012 (10)0.0084 (10)
C20.0322 (13)0.0280 (13)0.0332 (13)0.0002 (11)0.0024 (11)0.0040 (11)
C30.0307 (14)0.0390 (16)0.0536 (18)0.0033 (12)0.0111 (13)0.0068 (14)
C40.0228 (13)0.0403 (16)0.067 (2)0.0010 (11)0.0009 (13)0.0145 (15)
C50.0321 (14)0.0354 (15)0.0509 (17)0.0061 (11)0.0132 (12)0.0138 (13)
C60.0284 (13)0.0265 (13)0.0361 (14)0.0036 (10)0.0036 (11)0.0064 (11)
C70.0317 (12)0.0195 (12)0.0252 (12)0.0014 (10)0.0027 (10)0.0013 (9)
C80.0344 (14)0.0232 (13)0.0423 (15)0.0004 (11)0.0014 (11)0.0047 (11)
C90.0460 (16)0.0234 (14)0.0563 (18)0.0063 (12)0.0042 (14)0.0059 (12)
C100.0567 (18)0.0181 (13)0.0458 (16)0.0049 (12)0.0105 (13)0.0017 (12)
C110.0389 (15)0.0295 (14)0.0525 (17)0.0116 (12)0.0046 (13)0.0028 (13)
C120.0324 (13)0.0238 (13)0.0441 (15)0.0014 (11)0.0033 (11)0.0019 (11)
C130.0277 (12)0.0254 (12)0.0246 (12)0.0007 (10)0.0033 (9)0.0032 (10)
C140.0289 (12)0.0217 (12)0.0322 (13)0.0007 (10)0.0032 (10)0.0023 (10)
C150.0374 (14)0.0411 (16)0.0398 (15)0.0092 (12)0.0039 (12)0.0103 (13)
C160.0390 (16)0.058 (2)0.0500 (18)0.0185 (14)0.0037 (14)0.0065 (15)
C170.0408 (16)0.0334 (15)0.0598 (19)0.0128 (13)0.0107 (14)0.0026 (14)
C180.0457 (17)0.0247 (14)0.0584 (19)0.0030 (12)0.0112 (14)0.0162 (13)
C190.0349 (14)0.0302 (14)0.0489 (16)0.0023 (11)0.0011 (12)0.0158 (12)
C200.0258 (12)0.0241 (12)0.0274 (12)0.0006 (10)0.0004 (10)0.0088 (10)
C210.0382 (15)0.0376 (15)0.0401 (15)0.0009 (12)0.0114 (12)0.0069 (12)
C220.0347 (15)0.064 (2)0.058 (2)0.0063 (15)0.0178 (14)0.0200 (17)
C230.0309 (15)0.058 (2)0.061 (2)0.0148 (14)0.0021 (14)0.0254 (17)
C240.0397 (15)0.0377 (16)0.0499 (17)0.0141 (13)0.0069 (13)0.0107 (14)
C250.0328 (13)0.0272 (13)0.0338 (13)0.0027 (10)0.0001 (11)0.0064 (11)
C260.0421 (14)0.0270 (13)0.0233 (12)0.0049 (11)0.0007 (11)0.0024 (10)
C270.064 (2)0.052 (2)0.055 (2)0.0090 (16)0.0099 (17)0.0110 (16)
C280.054 (2)0.077 (3)0.079 (3)0.0112 (19)0.0151 (19)0.019 (2)
C290.096 (4)0.138 (5)0.097 (4)0.046 (3)0.048 (3)0.057 (4)
C300.078 (3)0.091 (3)0.055 (2)0.022 (2)0.0090 (19)0.018 (2)
P10.0224 (3)0.0172 (3)0.0245 (3)0.0002 (2)0.0016 (2)0.0027 (2)
P20.0245 (3)0.0185 (3)0.0242 (3)0.0010 (2)0.0024 (2)0.0022 (2)
Mo0.01917 (16)0.01492 (16)0.02092 (16)0.00038 (10)0.00245 (11)0.00078 (10)
O0.0626 (15)0.0755 (17)0.0507 (14)0.0217 (13)0.0086 (11)0.0092 (12)
Cl0.0232 (3)0.0258 (3)0.0307 (3)0.0019 (2)0.0063 (2)0.0016 (2)
Geometric parameters (Å, º) top
C1—C61.390 (4)C18—C191.389 (4)
C1—C21.397 (4)C20—C211.387 (4)
C1—P11.825 (2)C20—C251.400 (4)
C2—C31.393 (4)C20—P21.837 (2)
C3—C41.372 (4)C21—C221.390 (4)
C4—C51.386 (4)C22—C231.385 (5)
C5—C61.389 (4)C23—C241.375 (5)
C7—C81.391 (3)C24—C251.389 (4)
C7—C121.392 (4)C26—C13i1.534 (3)
C7—P11.838 (2)C26—P21.876 (3)
C8—C91.393 (4)C27—O1.435 (4)
C9—C101.379 (4)C27—C281.499 (5)
C10—C111.369 (4)C28—C291.444 (6)
C11—C121.393 (4)C29—C301.443 (6)
C13—C26i1.534 (3)C30—O1.402 (4)
C13—P11.847 (2)P1—Mo2.4896 (6)
C14—C151.379 (4)P2—Mo2.5082 (6)
C14—C191.398 (4)Mo—Cl2.4346 (5)
C14—P21.842 (2)Mo—Cli2.4346 (5)
C15—C161.400 (4)Mo—P1i2.4896 (6)
C16—C171.381 (4)Mo—P2i2.5082 (6)
C17—C181.373 (5)
C6—C1—C2118.8 (2)C13i—C26—P2114.33 (16)
C6—C1—P1118.28 (19)O—C27—C28106.7 (3)
C2—C1—P1122.83 (19)C29—C28—C27104.8 (3)
C3—C2—C1120.2 (3)C30—C29—C28108.5 (4)
C4—C3—C2120.4 (3)O—C30—C29107.2 (3)
C3—C4—C5119.9 (3)C1—P1—C7103.25 (11)
C4—C5—C6120.1 (3)C1—P1—C13106.06 (11)
C5—C6—C1120.5 (3)C7—P1—C13100.53 (11)
C8—C7—C12118.8 (2)C1—P1—Mo115.23 (8)
C8—C7—P1122.40 (19)C7—P1—Mo123.49 (8)
C12—C7—P1118.80 (19)C13—P1—Mo106.24 (8)
C7—C8—C9120.2 (2)C20—P2—C14101.18 (11)
C10—C9—C8120.4 (3)C20—P2—C26104.80 (11)
C11—C10—C9119.8 (2)C14—P2—C2698.54 (12)
C10—C11—C12120.5 (3)C20—P2—Mo115.05 (7)
C7—C12—C11120.3 (2)C14—P2—Mo124.87 (8)
C26i—C13—P1113.79 (16)C26—P2—Mo109.73 (8)
C15—C14—C19118.6 (2)Cl—Mo—Cli180.00 (2)
C15—C14—P2120.9 (2)Cl—Mo—P195.093 (19)
C19—C14—P2120.2 (2)Cli—Mo—P184.907 (19)
C14—C15—C16120.4 (3)Cl—Mo—P1i84.907 (19)
C17—C16—C15120.2 (3)Cli—Mo—P1i95.093 (19)
C18—C17—C16120.0 (3)P1—Mo—P1i180.00 (3)
C17—C18—C19119.8 (3)Cl—Mo—P281.136 (19)
C18—C19—C14121.0 (3)Cli—Mo—P298.864 (19)
C21—C20—C25118.4 (2)P1—Mo—P2101.048 (19)
C21—C20—P2123.2 (2)P1i—Mo—P278.952 (19)
C25—C20—P2118.23 (19)Cl—Mo—P2i98.864 (19)
C20—C21—C22120.7 (3)Cli—Mo—P2i81.136 (19)
C23—C22—C21120.2 (3)P1—Mo—P2i78.952 (19)
C24—C23—C22120.0 (3)P1i—Mo—P2i101.048 (19)
C23—C24—C25120.0 (3)P2—Mo—P2i180.00 (3)
C24—C25—C20120.8 (3)C30—O—C27107.6 (3)
C6—C1—C2—C30.8 (4)C26i—C13—P1—Mo45.57 (18)
P1—C1—C2—C3175.6 (2)C21—C20—P2—C14134.9 (2)
C1—C2—C3—C40.7 (4)C25—C20—P2—C1450.3 (2)
C2—C3—C4—C50.8 (4)C21—C20—P2—C2632.8 (2)
C3—C4—C5—C62.2 (4)C25—C20—P2—C26152.34 (19)
C4—C5—C6—C12.1 (4)C21—C20—P2—Mo87.8 (2)
C2—C1—C6—C50.6 (4)C25—C20—P2—Mo87.07 (19)
P1—C1—C6—C5177.2 (2)C15—C14—P2—C20149.3 (2)
C12—C7—C8—C90.5 (4)C19—C14—P2—C2037.5 (2)
P1—C7—C8—C9178.1 (2)C15—C14—P2—C26103.7 (2)
C7—C8—C9—C100.2 (4)C19—C14—P2—C2669.6 (2)
C8—C9—C10—C110.4 (5)C15—C14—P2—Mo17.7 (3)
C9—C10—C11—C120.8 (5)C19—C14—P2—Mo169.04 (18)
C8—C7—C12—C110.2 (4)C13i—C26—P2—C20123.38 (18)
P1—C7—C12—C11178.5 (2)C13i—C26—P2—C14132.59 (19)
C10—C11—C12—C70.5 (4)C13i—C26—P2—Mo0.7 (2)
C19—C14—C15—C161.2 (4)C1—P1—Mo—Cl13.75 (9)
P2—C14—C15—C16174.6 (2)C7—P1—Mo—Cl114.24 (10)
C14—C15—C16—C170.1 (5)C13—P1—Mo—Cl130.87 (8)
C15—C16—C17—C181.5 (5)C1—P1—Mo—Cli166.25 (9)
C16—C17—C18—C191.4 (5)C7—P1—Mo—Cli65.76 (10)
C17—C18—C19—C140.1 (4)C13—P1—Mo—Cli49.13 (8)
C15—C14—C19—C181.2 (4)C1—P1—Mo—P1i87.11 (9)
P2—C14—C19—C18174.7 (2)C7—P1—Mo—P1i144.89 (10)
C25—C20—C21—C220.3 (4)C13—P1—Mo—P1i30.00 (8)
P2—C20—C21—C22174.5 (2)C1—P1—Mo—P295.69 (9)
C20—C21—C22—C230.8 (4)C7—P1—Mo—P232.30 (10)
C21—C22—C23—C240.8 (5)C13—P1—Mo—P2147.19 (8)
C22—C23—C24—C250.4 (4)C1—P1—Mo—P2i84.31 (9)
C23—C24—C25—C200.0 (4)C7—P1—Mo—P2i147.70 (10)
C21—C20—C25—C240.1 (4)C13—P1—Mo—P2i32.81 (8)
P2—C20—C25—C24175.1 (2)C20—P2—Mo—Cl50.85 (9)
O—C27—C28—C298.6 (5)C14—P2—Mo—Cl176.75 (10)
C27—C28—C29—C305.5 (6)C26—P2—Mo—Cl67.00 (9)
C28—C29—C30—O18.1 (7)C20—P2—Mo—Cli129.15 (9)
C6—C1—P1—C772.9 (2)C14—P2—Mo—Cli3.25 (10)
C2—C1—P1—C7110.6 (2)C26—P2—Mo—Cli113.00 (9)
C6—C1—P1—C13178.16 (19)C20—P2—Mo—P142.65 (9)
C2—C1—P1—C135.4 (2)C14—P2—Mo—P183.25 (10)
C6—C1—P1—Mo64.6 (2)C26—P2—Mo—P1160.50 (9)
C2—C1—P1—Mo111.85 (19)C20—P2—Mo—P1i137.35 (9)
C8—C7—P1—C18.7 (2)C14—P2—Mo—P1i96.75 (10)
C12—C7—P1—C1169.8 (2)C26—P2—Mo—P1i19.50 (9)
C8—C7—P1—C13100.7 (2)C20—P2—Mo—P2i179.12 (9)
C12—C7—P1—C1380.7 (2)C14—P2—Mo—P2i54.98 (10)
C8—C7—P1—Mo141.62 (19)C26—P2—Mo—P2i61.27 (9)
C12—C7—P1—Mo36.9 (2)C29—C30—O—C2723.6 (5)
C26i—C13—P1—C177.51 (19)C28—C27—O—C3020.0 (4)
C26i—C13—P1—C7175.26 (18)
Symmetry code: (i) x, y, z.
 

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.
E-mail address* 
Repeat e-mail address* 
(for error checking) 

Format*   PDF (US $40)
   HTML (US $40)
   PDF+HTML (US $50)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number 
(non-UK EC countries only) 
Country* 
 

Terms and conditions of use
Contact us

Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds