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Green [Cu(NO2)2(phen)] contains six-coordinate copper(II) with a distorted tetragonal [CuIIN2O4] core. The nitrito ligands are bonded to copper using both O atoms [Cu-O 1.999(3) and 2.056 (2) Å, and longer Cu-O 2.470 (3) and 2.396 (3) Å]. The Cu-N distances are 1.995 (3) and 2.021 (2) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, I

hkl

Structure factor file (CIF format)
Contains datablock I

CCDC reference: 139734

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