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In the cation of the title complex, cis,cis,cis-[Ru([eta]2-O2CMe)(dppe)2]PF6·2MeOH [dppe is 1,2-bis­(di­phenyl­phosphino)­ethane, C26H24P2], the Ru atom is in a pseudo-octahedral coordination environment with two chelating dppe ligands and one chelating acetate ligand. Intra-phosphine and intra-acetate bond lengths and angles are unexceptional. Deviations from idealized octahedral coordination angles at ruthenium [O-Ru-O 59.43 (8)° and P-Ru-P 103.19 (2)°] presumably derive from constraints imposed by the chelate rings. The Ru-P distances for the mutually trans P-donor atoms [2.3785 (6) Å] are significantly longer than those for the Ru-P linkages trans to the acetate ligand [2.3074 (6) Å]. The Ru1, C1 and C2 atoms lie on a twofold axis, and atom P3 of the anion lies on an inversion centre.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270100011082/qa0364sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270100011082/qa0364Isup2.hkl
Contains datablock I

CCDC reference: 150732

Computing details top

Data collection: COLLECT (Nonius, 1999); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: TEXSAN (Molecular Structures Corporation, 1997); software used to prepare material for publication: TEXSAN.

(I) top
Crystal data top
[Ru(C2H3O2)(C26H24P2)2]PF6·2CH4OF(000) = 2400
Mr = 1166.01Dx = 1.457 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.7107 Å
a = 13.4832 (2) ÅCell parameters from 41382 reflections
b = 19.6340 (2) Åθ = 2.9–27.5°
c = 20.3112 (3) ŵ = 0.51 mm1
β = 98.6340 (8)°T = 273 K
V = 5316.0 (1) Å3Block, orange
Z = 40.30 × 0.20 × 0.15 mm
Data collection top
KappaCCD
diffractometer
6127 independent reflections
Radiation source: fine-focus sealed tube4464 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.068
ω scansθmax = 27.5°, θmin = 3.1°
Absorption correction: multi-scan
[SORTAV (Blessing, 1995) implemented in maXus (Mackay et al., 1999)]
h = 1717
Tmin = 0.847, Tmax = 0.926k = 2525
53848 measured reflectionsl = 2526
Refinement top
Refinement on F1 restraint
Least-squares matrix: full0 constraints
R[F2 > 2σ(F2)] = 0.035H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.039Weighting scheme based on measured s.u.'s w = 1/[σ2(Fo) + 0.00040|Fo|2]
S = 0.94(Δ/σ)max = 0.022
4464 reflectionsΔρmax = 0.49 e Å3
328 parametersΔρmin = 0.66 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru11.00000.01398 (1)0.75000.02060 (7)
P10.88724 (5)0.00522 (3)0.64840 (3)0.0234 (2)
P21.07225 (5)0.09704 (3)0.69230 (3)0.0243 (2)
P30.75000.25000.50000.0391 (3)
F10.7197 (2)0.3242 (1)0.5187 (1)0.0877 (8)
F20.8302 (2)0.2805 (1)0.4579 (1)0.0668 (7)
F30.8338 (2)0.2478 (1)0.5633 (1)0.0833 (8)
O10.9338 (1)0.08288 (9)0.77453 (8)0.0258 (5)
O21.0276 (2)0.3288 (2)0.5381 (2)0.097 (1)
C11.00000.1163 (2)0.75000.0266 (9)
C21.00000.1924 (2)0.75000.040 (1)
C31.0052 (4)0.3866 (2)0.5708 (2)0.092 (2)
C1010.9285 (2)0.0628 (1)0.5872 (1)0.0300 (7)
C1110.8819 (2)0.0790 (1)0.6089 (1)0.0280 (7)
C1120.9611 (2)0.1018 (1)0.5779 (1)0.0351 (8)
C1130.9610 (2)0.1664 (2)0.5511 (1)0.0426 (9)
C1140.8818 (3)0.2095 (2)0.5544 (2)0.049 (1)
C1150.8028 (3)0.1882 (2)0.5843 (2)0.052 (1)
C1160.8027 (2)0.1234 (2)0.6121 (1)0.0380 (8)
C1210.7557 (2)0.0233 (1)0.6515 (1)0.0255 (7)
C1220.7142 (2)0.0049 (1)0.7045 (1)0.0300 (7)
C1230.6163 (2)0.0082 (2)0.7122 (1)0.0376 (8)
C1240.5578 (2)0.0502 (2)0.6672 (2)0.0428 (9)
C1250.5970 (2)0.0778 (2)0.6145 (2)0.0407 (8)
C1260.6958 (2)0.0644 (1)0.6058 (1)0.0325 (7)
C2010.9756 (2)0.1254 (1)0.6236 (1)0.0283 (7)
C2111.1267 (2)0.1780 (1)0.7251 (1)0.0302 (7)
C2121.0854 (2)0.2405 (2)0.7061 (2)0.0418 (9)
C2131.1319 (3)0.3003 (2)0.7311 (2)0.055 (1)
C2141.2195 (3)0.2979 (2)0.7754 (2)0.056 (1)
C2151.2616 (3)0.2364 (2)0.7944 (2)0.050 (1)
C2161.2166 (2)0.1766 (2)0.7689 (1)0.0404 (8)
C2211.1696 (2)0.0687 (1)0.6434 (1)0.0269 (7)
C2221.2232 (2)0.1163 (1)0.6122 (2)0.0396 (9)
C2231.2896 (2)0.0957 (2)0.5704 (2)0.0460 (9)
C2241.3044 (2)0.0278 (2)0.5597 (2)0.0423 (9)
C2251.2525 (2)0.0201 (2)0.5906 (1)0.0383 (9)
C2261.1855 (2)0.0003 (1)0.6321 (1)0.0304 (7)
H1c1.05880.20850.73450.048*0.500
H1a0.99880.20850.79400.048*0.500
H1b0.94240.20850.72150.048*0.500
H3c1.05730.39540.60680.111*
H3a0.94370.38040.58750.111*
H3b0.99920.42400.54080.111*
H40.96150.31350.51770.043*
H101a0.87270.07610.55560.036*
H101b0.97660.04060.56500.036*
H1121.01630.07230.57520.042*
H1131.01590.18110.53030.051*
H1140.88170.25400.53590.059*
H1150.74760.21780.58620.062*
H1160.74800.10950.63340.046*
H1220.75420.03360.73550.036*
H1230.58890.01140.74830.045*
H1240.49060.06000.67280.051*
H1250.55630.10630.58370.049*
H1260.72210.08320.56890.039*
H201b1.00560.15300.59360.034*
H210a0.92550.15080.64100.034*
H2121.02460.24270.67570.050*
H2131.10290.34310.71750.066*
H2141.25060.33890.79270.067*
H2151.32200.23460.82520.060*
H2161.24750.13410.78160.049*
H2221.21410.16350.61970.048*
H2231.32510.12880.54910.055*
H2241.35020.01390.53100.051*
H2251.26280.06720.58340.046*
H2261.14990.03310.65310.037*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0205 (1)0.0189 (1)0.0230 (2)0.00000.0052 (1)0.0000
P10.0220 (3)0.0253 (4)0.0233 (4)0.0005 (3)0.0042 (3)0.0004 (3)
P20.0251 (4)0.0213 (4)0.0272 (4)0.0016 (3)0.0064 (3)0.0017 (3)
P30.0446 (7)0.0299 (6)0.0424 (7)0.0075 (5)0.0047 (5)0.0069 (5)
F10.108 (2)0.036 (1)0.125 (2)0.014 (1)0.041 (2)0.011 (1)
F20.068 (1)0.073 (1)0.064 (1)0.006 (1)0.024 (1)0.016 (1)
F30.070 (1)0.118 (2)0.055 (1)0.001 (1)0.014 (1)0.019 (1)
O10.026 (1)0.0215 (9)0.031 (1)0.0001 (7)0.0080 (8)0.0012 (8)
O20.070 (2)0.091 (2)0.130 (3)0.005 (2)0.018 (2)0.041 (2)
C10.026 (2)0.025 (2)0.028 (2)0.00000.003 (2)0.0000
C20.042 (2)0.024 (2)0.059 (3)0.00000.020 (2)0.0000
C30.099 (4)0.088 (3)0.083 (3)0.020 (3)0.008 (3)0.026 (2)
C1010.027 (1)0.036 (2)0.027 (1)0.001 (1)0.004 (1)0.005 (1)
C1110.031 (1)0.028 (1)0.024 (1)0.000 (1)0.000 (1)0.003 (1)
C1120.033 (2)0.038 (2)0.035 (2)0.001 (1)0.006 (1)0.008 (1)
C1130.049 (2)0.043 (2)0.037 (2)0.010 (1)0.009 (1)0.010 (1)
C1140.066 (2)0.032 (2)0.048 (2)0.001 (1)0.009 (2)0.013 (1)
C1150.059 (2)0.033 (2)0.064 (2)0.014 (2)0.014 (2)0.011 (2)
C1160.040 (2)0.032 (2)0.044 (2)0.005 (1)0.013 (1)0.007 (1)
C1210.023 (1)0.026 (1)0.027 (1)0.002 (1)0.003 (1)0.005 (1)
C1220.028 (1)0.033 (2)0.029 (1)0.001 (1)0.005 (1)0.000 (1)
C1230.031 (1)0.045 (2)0.039 (2)0.001 (1)0.012 (1)0.002 (1)
C1240.025 (2)0.055 (2)0.050 (2)0.005 (1)0.009 (1)0.001 (1)
C1250.031 (1)0.047 (2)0.043 (2)0.009 (1)0.000 (1)0.006 (1)
C1260.030 (1)0.035 (2)0.033 (2)0.002 (1)0.003 (1)0.002 (1)
C2010.029 (1)0.028 (1)0.029 (1)0.001 (1)0.008 (1)0.008 (1)
C2110.037 (1)0.025 (1)0.031 (1)0.007 (1)0.013 (1)0.000 (1)
C2120.040 (2)0.028 (1)0.058 (2)0.001 (1)0.009 (2)0.000 (1)
C2130.064 (2)0.022 (2)0.081 (3)0.006 (1)0.019 (2)0.004 (2)
C2140.076 (2)0.039 (2)0.055 (2)0.028 (2)0.017 (2)0.011 (2)
C2150.062 (2)0.048 (2)0.039 (2)0.028 (2)0.000 (2)0.003 (1)
C2160.048 (2)0.035 (2)0.037 (2)0.012 (1)0.003 (1)0.009 (1)
C2210.025 (1)0.030 (1)0.025 (1)0.000 (1)0.003 (1)0.003 (1)
C2220.043 (2)0.030 (2)0.050 (2)0.001 (1)0.021 (1)0.007 (1)
C2230.048 (2)0.046 (2)0.051 (2)0.006 (2)0.027 (2)0.007 (2)
C2240.039 (2)0.052 (2)0.041 (2)0.000 (1)0.022 (1)0.004 (1)
C2250.038 (2)0.038 (2)0.041 (2)0.001 (1)0.014 (1)0.008 (1)
C2260.030 (2)0.031 (1)0.031 (1)0.005 (1)0.007 (1)0.001 (1)
Geometric parameters (Å, º) top
Ru1—P12.3787 (6)C114—C1151.369 (4)
Ru1—P1i2.3787 (6)C114—H1140.95
Ru1—P22.3075 (7)C115—C1161.391 (4)
Ru1—P2i2.3075 (7)C115—H1150.95
Ru1—O12.190 (2)C116—H1160.95
Ru1—O1i2.190 (2)C121—C1221.398 (4)
P1—C1011.828 (3)C121—C1261.394 (4)
P1—C1111.835 (3)C122—C1231.378 (4)
P1—C1211.819 (2)C122—H1220.95
P2—C2011.847 (2)C123—C1241.387 (4)
P2—C2111.833 (3)C123—H1230.95
P2—C2211.847 (3)C124—C1251.373 (4)
P3—F11.574 (2)C124—H1240.95
P3—F1ii1.574 (2)C125—C1261.396 (4)
P3—F21.592 (2)C125—H1250.95
P3—F2ii1.592 (2)C126—H1260.95
P3—F31.579 (2)C201—H201b0.95
P3—F3ii1.579 (2)C201—H210a0.95
O1—C11.268 (2)C211—C2121.378 (4)
O2—C31.371 (5)C211—C2161.393 (4)
O2—H40.97C212—C2131.391 (4)
C1—C21.495 (5)C212—H2120.95
C2—H1c0.95C213—C2141.373 (5)
C2—H1ci0.95C213—H2130.95
C2—H1a0.95C214—C2151.366 (5)
C2—H1ai0.95C214—H2140.95
C2—H1b0.95C215—C2161.385 (4)
C2—H1bi0.95C215—H2150.95
C3—H3c0.95C216—H2160.95
C3—H3a0.95C221—C2221.390 (4)
C3—H3b0.95C221—C2261.385 (4)
C101—C2011.522 (4)C222—C2231.384 (4)
C101—H101a0.95C222—H2220.95
C101—H101b0.95C223—C2241.370 (4)
C111—C1121.393 (4)C223—H2230.95
C111—C1161.387 (4)C224—C2251.379 (4)
C112—C1131.380 (4)C224—H2240.95
C112—H1120.95C225—C2261.385 (4)
C113—C1141.373 (4)C225—H2250.95
C113—H1130.95C226—H2260.95
F1···C225iii3.388 (4)F3···O23.166 (4)
F1···C101ii3.500 (4)F3···C2013.199 (3)
F2···O23.055 (4)F3···C215i3.344 (4)
F2···C126ii3.307 (3)F3···C33.562 (5)
F2···C215iv3.328 (4)F3···C214i3.596 (4)
F2···C125ii3.363 (4)O2···C114v3.346 (4)
P1—Ru1—P1i171.71 (3)H101a—C101—H101b109.5
P1—Ru1—P282.77 (2)P1—C111—C112120.3 (2)
P1—Ru1—P2i103.19 (2)P1—C111—C116121.7 (2)
P1—Ru1—O184.56 (5)C112—C111—C116117.9 (2)
P1—Ru1—O1i88.24 (5)C111—C112—C113121.2 (3)
P1i—Ru1—P2103.19 (2)C111—C112—H112119.4
P1i—Ru1—P2i82.77 (2)C113—C112—H112119.4
P1i—Ru1—O188.24 (5)C112—C113—C114120.2 (3)
P1i—Ru1—O1i84.56 (5)C112—C113—H113119.9
P2—Ru1—P2i90.07 (3)C114—C113—H113119.9
P2—Ru1—O1161.24 (5)C113—C114—C115119.7 (3)
P2—Ru1—O1i106.29 (5)C113—C114—H114120.1
P2i—Ru1—O1106.29 (5)C115—C114—H114120.2
P2i—Ru1—O1i161.24 (5)C114—C115—C116120.5 (3)
O1—Ru1—O1i59.45 (9)C114—C115—H115119.7
Ru1—P1—C101108.96 (8)C116—C115—H115119.7
Ru1—P1—C111115.02 (8)C111—C116—C115120.6 (3)
Ru1—P1—C121117.07 (8)C111—C116—H116119.7
C101—P1—C111104.8 (1)C115—C116—H116119.7
C101—P1—C121107.6 (1)P1—C121—C122117.0 (2)
C111—P1—C121102.5 (1)P1—C121—C126124.0 (2)
Ru1—P2—C201107.03 (8)C122—C121—C126118.9 (2)
Ru1—P2—C211127.21 (9)C121—C122—C123121.0 (2)
Ru1—P2—C221116.68 (9)C121—C122—H122119.5
C201—P2—C211102.3 (1)C123—C122—H122119.5
C201—P2—C22199.3 (1)C122—C123—C124119.7 (3)
C211—P2—C221100.2 (1)C122—C123—H123120.1
F1—P3—F1ii180.00C124—C123—H123120.1
F1—P3—F290.2 (1)C123—C124—C125120.1 (3)
F1—P3—F2ii89.8 (1)C123—C124—H124119.9
F1—P3—F390.5 (1)C125—C124—H124119.9
F1—P3—F3ii89.5 (1)C124—C125—C126120.7 (3)
F1ii—P3—F289.8 (1)C124—C125—H125119.6
F1ii—P3—F2ii90.2 (1)C126—C125—H125119.6
F1ii—P3—F389.5 (1)C121—C126—C125119.5 (3)
F1ii—P3—F3ii90.5 (1)C121—C126—H126120.2
F2—P3—F2ii180.00C125—C126—H126120.2
F2—P3—F389.2 (1)P2—C201—C101108.6 (2)
F2—P3—F3ii90.8 (1)P2—C201—H201b109.7
F2ii—P3—F390.8 (1)P2—C201—H210a109.7
F2ii—P3—F3ii89.2 (1)C101—C201—H201b109.7
F3—P3—F3ii180.00C101—C201—H210a109.7
Ru1—O1—C191.4 (2)H201b—C201—H210a109.5
C3—O2—H4102.0P2—C211—C212123.2 (2)
O1—C1—O1i117.8 (3)P2—C211—C216118.6 (2)
O1—C1—C2121.1 (2)C212—C211—C216118.2 (3)
O1i—C1—C2121.1 (2)C211—C212—C213120.6 (3)
C1—C2—H1c109.5C211—C212—H212119.7
C1—C2—H1ci109.5C213—C212—H212119.7
C1—C2—H1a109.5C212—C213—C214120.4 (3)
C1—C2—H1ai109.5C212—C213—H213119.8
C1—C2—H1b109.5C214—C213—H213119.8
C1—C2—H1bi109.5C213—C214—C215119.7 (3)
H1c—C2—H1ci141.1C213—C214—H214120.1
H1c—C2—H1a109.5C215—C214—H214120.1
H1c—C2—H1ai56.3C214—C215—C216120.2 (3)
H1c—C2—H1b109.5C214—C215—H215119.9
H1c—C2—H1bi56.3C216—C215—H215119.9
H1ci—C2—H1a56.3C211—C216—C215120.8 (3)
H1ci—C2—H1ai109.5C211—C216—H216119.6
H1ci—C2—H1b56.3C215—C216—H216119.6
H1ci—C2—H1bi109.5P2—C221—C222120.1 (2)
H1a—C2—H1ai141.1P2—C221—C226121.3 (2)
H1a—C2—H1b109.5C222—C221—C226118.3 (2)
H1a—C2—H1bi56.3C221—C222—C223120.7 (3)
H1ai—C2—H1b56.3C221—C222—H222119.6
H1ai—C2—H1bi109.5C223—C222—H222119.6
H1b—C2—H1bi141.1C222—C223—C224120.4 (3)
O2—C3—H3c109.5C222—C223—H223119.8
O2—C3—H3a109.5C224—C223—H223119.8
O2—C3—H3b109.5C223—C224—C225119.7 (3)
H3c—C3—H3a109.5C223—C224—H224120.2
H3c—C3—H3b109.5C225—C224—H224120.2
H3a—C3—H3b109.5C224—C225—C226120.2 (3)
P1—C101—C201108.4 (2)C224—C225—H225119.9
P1—C101—H101a109.7C226—C225—H225119.9
P1—C101—H101b109.7C221—C226—C225120.8 (2)
C201—C101—H101a109.7C221—C226—H226119.6
C201—C101—H101b109.7C225—C226—H226119.6
Ru1—P1—C101—C20133.5 (2)O1—Ru1—P1—C11145.4 (1)
Ru1—P1—C111—C11272.7 (2)O1—Ru1—P1—C12175.0 (1)
Ru1—P1—C111—C116103.4 (2)O1—Ru1—P1i—C101i103.2 (1)
Ru1—P1—C121—C12244.3 (2)O1—Ru1—P1i—C111i14.1 (1)
Ru1—P1—C121—C126134.0 (2)O1—Ru1—P1i—C121i134.5 (1)
Ru1—P1i—C101i—C201i33.5 (2)O1—Ru1—P2—C20169.1 (2)
Ru1—P1i—C111i—C112i72.7 (2)O1—Ru1—P2—C211170.1 (2)
Ru1—P1i—C111i—C116i103.4 (2)O1—Ru1—P2—C22141.0 (2)
Ru1—P1i—C121i—C122i44.3 (2)O1—Ru1—P2i—C201i107.3 (1)
Ru1—P1i—C121i—C126i134.0 (2)O1—Ru1—P2i—C211i131.9 (1)
Ru1—P2—C201—C10149.0 (2)O1—Ru1—P2i—C221i2.8 (1)
Ru1—P2—C211—C212112.6 (2)O1—Ru1—O1i—C10.0000 (1)
Ru1—P2—C211—C21670.4 (2)C101—P1—C111—C11246.9 (2)
Ru1—P2—C221—C222174.1 (2)C101—P1—C111—C116137.0 (2)
Ru1—P2—C221—C22611.3 (2)C101—P1—C121—C122167.3 (2)
Ru1—P2i—C201i—C101i49.0 (2)C101—P1—C121—C12611.0 (3)
Ru1—P2i—C211i—C212i112.6 (2)C101—C201—P2—C211175.5 (2)
Ru1—P2i—C211i—C216i70.4 (2)C101—C201—P2—C22172.7 (2)
Ru1—P2i—C221i—C222i174.1 (2)C111—P1—C101—C201157.1 (2)
Ru1—P2i—C221i—C226i11.3 (2)C111—P1—C121—C12282.6 (2)
Ru1—O1—C1—O1i0.0000C111—P1—C121—C12699.1 (2)
Ru1—O1—C1—C2180.0000 (1)C111—C112—C113—C1140.2 (5)
Ru1—O1i—C1—O10.0000C111—C116—C115—C1141.1 (5)
Ru1—O1i—C1—C2180.0000 (1)C112—C111—P1—C121159.1 (2)
P1—Ru1—P1i—C101i132.90 (9)C112—C111—C116—C1150.8 (4)
P1—Ru1—P1i—C111i15.6 (1)C112—C113—C114—C1150.0 (5)
P1—Ru1—P1i—C121i104.84 (9)C113—C112—C111—C1160.2 (4)
P1—Ru1—P2—C20121.29 (9)C113—C114—C115—C1160.6 (5)
P1—Ru1—P2—C211142.0 (1)C116—C111—P1—C12124.8 (3)
P1—Ru1—P2—C22188.81 (9)C121—P1—C101—C20194.3 (2)
P1—Ru1—P2i—C201i164.58 (9)C121—C122—C123—C1240.3 (4)
P1—Ru1—P2i—C211i43.8 (1)C121—C126—C125—C1240.8 (4)
P1—Ru1—P2i—C221i85.32 (9)C122—C121—C126—C1251.4 (4)
P1—Ru1—O1—C191.16 (8)C122—C123—C124—C1251.0 (5)
P1—Ru1—O1i—C184.72 (8)C123—C122—C121—C1260.9 (4)
P1—C101—C201—P252.3 (2)C123—C124—C125—C1260.4 (5)
P1—C111—C112—C113176.4 (2)C201—P2—C211—C21210.1 (3)
P1—C111—C116—C115177.0 (2)C201—P2—C211—C216166.8 (2)
P1—C121—C122—C123177.5 (2)C201—P2—C221—C22271.4 (2)
P1—C121—C126—C125176.8 (2)C201—P2—C221—C226103.2 (2)
P2—Ru1—P1—C1013.44 (9)C211—P2—C221—C22233.0 (2)
P2—Ru1—P1—C111120.8 (1)C211—P2—C221—C226152.5 (2)
P2—Ru1—P1—C121118.8 (1)C211—C212—C213—C2140.4 (5)
P2—Ru1—P1i—C101i91.80 (9)C211—C216—C215—C2141.6 (5)
P2—Ru1—P1i—C111i150.9 (1)C212—C211—P2—C221112.1 (2)
P2—Ru1—P1i—C121i30.5 (1)C212—C211—C216—C2152.0 (4)
P2—Ru1—P2i—C201i82.00 (9)C212—C213—C214—C2150.7 (5)
P2—Ru1—P2i—C211i38.8 (1)C213—C212—C211—C2161.0 (4)
P2—Ru1—P2i—C221i167.9 (1)C213—C214—C215—C2160.3 (5)
P2—Ru1—O1—C143.5 (2)C216—C211—P2—C22164.8 (2)
P2—Ru1—O1i—C1166.66 (7)C221—C222—C223—C2240.7 (5)
P2—C211—C212—C213177.9 (2)C221—C226—C225—C2240.2 (4)
P2—C211—C216—C215179.1 (2)C222—C221—C226—C2250.3 (4)
P2—C221—C222—C223173.9 (2)C222—C223—C224—C2250.2 (5)
P2—C221—C226—C225174.3 (2)C223—C222—C221—C2260.8 (4)
O1—Ru1—P1—C101162.7 (1)C223—C224—C225—C2260.3 (5)
Symmetry codes: (i) x+2, y, z+3/2; (ii) x+3/2, y+1/2, z+1; (iii) x1/2, y+1/2, z; (iv) x1/2, y+1/2, z1/2; (v) x+2, y, z+1.
 

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