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The title compound, [CoCl(tren)(dmso)](ClO4)2 [tren is tris-(2-amino­ethyl)­amine, C6H18N4; dmso is di­methyl sulfoxide, C2H6OS], is the first crystal structure reported with dmso coordinated to CoIII. It crystallizes with two independent mol­ecules in the asymmetric unit. A localized non-crystallographic inversion centre is observed between the two cations.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270100011069/qa0349sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270100011069/qa0349Isup2.hkl
Contains datablock I

CCDC reference: 150730

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SMART (Bruker, 1998); data reduction: SAINT-Plus (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: SHELXTL (Bruker, 1998).

chloro tris-(2-aminoethyl)amine (dimethyl sulfoxide-O)- cobalt (III) perchlorate top
Crystal data top
[CoCl(C6H18N4)(C2H6OS)](ClO4)2F(000) = 2128
Mr = 517.65Dx = 1.739 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 20.0177 (10) ÅCell parameters from 8192 reflections
b = 15.7193 (8) Åθ = 1.7–27.0°
c = 12.9074 (7) ŵ = 1.43 mm1
β = 103.235 (1)°T = 293 K
V = 3953.6 (4) Å3Column, red
Z = 80.3 × 0.2 × 0.15 mm
Data collection top
Bruker SMART CCD area-detector
diffractometer
8616 independent reflections
Radiation source: fine-focus sealed tube6484 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.025
φ and ω scansθmax = 27.0°, θmin = 1.7°
Absorption correction: empirical (using intensity measurements)
(Blessing, 1995)
h = 2525
Tmin = 0.674, Tmax = 0.814k = 1520
23159 measured reflectionsl = 1615
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.044 w = 1/[σ2(Fo2) + (0.0977P)2 + 1.2289P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.130(Δ/σ)max = 0.002
S = 1.04Δρmax = 0.99 e Å3
8616 reflectionsΔρmin = 0.84 e Å3
466 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Co10.41961 (2)0.41694 (3)0.82622 (3)0.02703 (11)
Cl10.44355 (4)0.39637 (6)1.00340 (6)0.0384 (2)
C10.4004 (2)0.2793 (2)0.6763 (3)0.0474 (9)
H1A0.44070.26850.64840.057*
H1B0.37060.23000.66160.057*
C20.3634 (2)0.3571 (2)0.6244 (3)0.0432 (9)
H2A0.36030.35570.54830.052*
H2B0.31730.35890.63610.052*
C30.3624 (2)0.5142 (2)0.6485 (3)0.0420 (8)
H3A0.31510.50440.65200.050*
H3B0.36290.53410.57760.050*
C40.3948 (2)0.5798 (2)0.7303 (3)0.0449 (9)
H4A0.43840.59840.71740.054*
H4B0.36500.62890.72620.054*
C50.47061 (19)0.4408 (2)0.6397 (3)0.0411 (8)
H5A0.46770.41060.57320.049*
H5B0.48040.50010.62850.049*
C60.52769 (19)0.4037 (2)0.7242 (3)0.0428 (8)
H6A0.52760.34210.71880.051*
H6B0.57170.42470.71580.051*
C70.2072 (2)0.3338 (4)0.8163 (4)0.0817 (17)
H7A0.21210.28890.76810.123*
H7B0.18750.38280.77650.123*
H7C0.17780.31510.86100.123*
C80.2643 (3)0.4418 (4)0.9745 (4)0.0879 (19)
H8A0.30430.46351.02320.132*
H8B0.23300.41921.01370.132*
H8C0.24240.48690.92900.132*
N10.40288 (14)0.43391 (17)0.6723 (2)0.0326 (6)
N20.42128 (15)0.29496 (17)0.7944 (2)0.0351 (6)
H2C0.46380.27450.82000.042*
H2D0.39240.26720.82680.042*
N30.40533 (15)0.53916 (18)0.8373 (2)0.0374 (6)
H3C0.36840.54850.86450.045*
H3D0.44210.56250.88160.045*
N40.51570 (14)0.43012 (18)0.8288 (2)0.0354 (6)
H4C0.52820.48480.84180.042*
H4D0.54100.39780.88080.042*
O10.32101 (12)0.40697 (16)0.81506 (18)0.0398 (6)
S10.28878 (5)0.36036 (7)0.89622 (7)0.0460 (2)
Co20.90425 (2)0.47537 (3)0.80758 (3)0.02916 (12)
Cl20.90154 (4)0.50517 (6)0.97645 (6)0.0403 (2)
C90.9334 (2)0.3643 (2)0.6580 (3)0.0459 (9)
H9A0.94730.35400.59190.055*
H9B0.89740.32430.66300.055*
C100.9940 (2)0.3534 (3)0.7517 (3)0.0490 (10)
H10A1.00620.29370.76150.059*
H10B1.03340.38440.73960.059*
C110.8368 (2)0.4649 (3)0.5963 (3)0.0524 (10)
H11A0.80800.41830.60910.063*
H11B0.83670.46580.52110.063*
C120.8097 (2)0.5480 (3)0.6284 (3)0.0561 (11)
H12A0.82990.59530.59810.067*
H12B0.76030.55050.60260.067*
C130.9575 (2)0.5150 (3)0.6277 (3)0.0492 (10)
H13A1.00150.48750.63300.059*
H13B0.93990.53170.55420.059*
C140.9667 (2)0.5927 (3)0.6976 (3)0.0513 (10)
H14A1.00800.62300.69240.062*
H14B0.92780.63060.67610.062*
C150.7205 (2)0.3111 (3)0.7826 (4)0.0580 (11)
H15A0.69680.34440.72320.087*
H15B0.68840.29110.82210.087*
H15C0.74210.26340.75730.087*
C160.8177 (3)0.2996 (3)0.9678 (3)0.0641 (12)
H16A0.85370.32531.02050.096*
H16B0.83570.25170.93680.096*
H16C0.78180.28091.00060.096*
N50.90814 (14)0.4532 (2)0.6607 (2)0.0373 (6)
N60.97329 (15)0.38707 (19)0.8475 (2)0.0391 (7)
H6C1.01030.40850.89330.047*
H6D0.95640.34450.88050.047*
N70.82847 (15)0.5530 (2)0.7481 (2)0.0398 (7)
H7D0.79170.53950.77370.048*
H7E0.84080.60670.76820.048*
N80.97208 (15)0.56278 (19)0.8081 (2)0.0400 (7)
H8D0.96500.60650.84930.048*
H8E1.01440.54180.83480.048*
O20.83867 (13)0.38252 (17)0.79914 (19)0.0428 (6)
S20.78427 (5)0.37518 (6)0.86688 (7)0.0412 (2)
Cl30.63998 (4)0.57897 (5)0.69409 (7)0.0394 (2)
O30.57936 (18)0.5972 (2)0.7279 (4)0.0917 (13)
O40.6244 (3)0.5306 (3)0.5990 (3)0.1090 (16)
O50.67627 (18)0.6541 (2)0.6797 (4)0.0849 (12)
O60.6813 (2)0.5265 (3)0.7703 (3)0.1044 (15)
Cl40.60941 (5)0.25236 (7)0.50364 (8)0.0533 (3)
O70.66763 (17)0.3058 (2)0.5081 (3)0.0751 (10)
O80.5887 (2)0.2502 (3)0.6005 (3)0.0995 (14)
O90.6279 (2)0.1649 (3)0.4860 (4)0.1038 (14)
O100.5582 (2)0.2712 (4)0.4144 (4)0.141 (2)
Cl50.15410 (7)0.59792 (9)0.72736 (11)0.0735 (4)
O110.1238 (2)0.5341 (3)0.7779 (4)0.1129 (16)
O120.1346 (3)0.6767 (3)0.7586 (5)0.139 (2)
O130.1225 (5)0.5972 (6)0.6194 (4)0.212 (4)
O14A0.2292 (5)0.6009 (7)0.7868 (9)0.116 (3)*0.50
O14B0.2160 (5)0.5861 (6)0.7149 (9)0.110 (3)*0.50
Cl60.09721 (9)0.26153 (7)0.55487 (9)0.0785 (4)
O150.0967 (2)0.3497 (2)0.5750 (3)0.0935 (13)
O160.0947 (3)0.2385 (3)0.4540 (4)0.136 (2)
O18A0.1324 (5)0.2133 (6)0.6380 (8)0.101 (3)*0.50
O17B0.0953 (3)0.2205 (4)0.6478 (5)0.0554 (15)*0.50
O18B0.1790 (6)0.2393 (8)0.5681 (10)0.139 (4)*0.50
O17A0.0192 (4)0.2251 (5)0.5427 (6)0.089 (2)*0.50
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0336 (2)0.0256 (2)0.0221 (2)0.00252 (16)0.00670 (16)0.00156 (16)
Cl10.0451 (5)0.0443 (5)0.0240 (4)0.0050 (4)0.0043 (3)0.0005 (3)
C10.076 (3)0.0323 (19)0.0350 (19)0.0116 (18)0.0154 (18)0.0083 (15)
C20.059 (2)0.044 (2)0.0251 (16)0.0161 (17)0.0067 (15)0.0051 (15)
C30.049 (2)0.042 (2)0.0331 (18)0.0040 (16)0.0056 (15)0.0089 (15)
C40.065 (2)0.0305 (18)0.0396 (19)0.0058 (16)0.0120 (17)0.0069 (15)
C50.053 (2)0.043 (2)0.0321 (17)0.0031 (16)0.0199 (16)0.0014 (15)
C60.047 (2)0.041 (2)0.047 (2)0.0001 (16)0.0246 (17)0.0005 (16)
C70.047 (3)0.126 (5)0.068 (3)0.036 (3)0.005 (2)0.000 (3)
C80.068 (3)0.145 (5)0.056 (3)0.026 (3)0.023 (2)0.028 (3)
N10.0416 (15)0.0331 (15)0.0236 (13)0.0044 (12)0.0084 (11)0.0001 (11)
N20.0474 (16)0.0270 (14)0.0315 (14)0.0056 (12)0.0102 (12)0.0034 (11)
N30.0473 (17)0.0297 (15)0.0347 (15)0.0013 (12)0.0085 (13)0.0031 (12)
N40.0367 (15)0.0334 (15)0.0349 (15)0.0003 (12)0.0062 (12)0.0010 (12)
O10.0353 (12)0.0535 (16)0.0313 (12)0.0054 (11)0.0092 (10)0.0009 (11)
S10.0371 (5)0.0663 (7)0.0361 (5)0.0060 (4)0.0112 (4)0.0044 (4)
Co20.0309 (2)0.0324 (2)0.0241 (2)0.00308 (17)0.00624 (16)0.00085 (17)
Cl20.0405 (4)0.0530 (5)0.0274 (4)0.0001 (4)0.0081 (3)0.0078 (3)
C90.062 (2)0.042 (2)0.0378 (19)0.0069 (17)0.0180 (17)0.0091 (16)
C100.061 (2)0.047 (2)0.042 (2)0.0207 (18)0.0184 (18)0.0010 (17)
C110.045 (2)0.084 (3)0.0251 (17)0.010 (2)0.0034 (15)0.0011 (18)
C120.048 (2)0.085 (3)0.035 (2)0.026 (2)0.0081 (17)0.013 (2)
C130.056 (2)0.057 (2)0.041 (2)0.0089 (19)0.0237 (18)0.0117 (18)
C140.058 (2)0.045 (2)0.058 (2)0.0021 (18)0.027 (2)0.0109 (19)
C150.049 (2)0.065 (3)0.058 (3)0.020 (2)0.010 (2)0.012 (2)
C160.081 (3)0.066 (3)0.044 (2)0.008 (2)0.012 (2)0.012 (2)
N50.0401 (16)0.0472 (17)0.0254 (13)0.0075 (13)0.0094 (12)0.0002 (12)
N60.0457 (17)0.0368 (16)0.0333 (15)0.0096 (13)0.0058 (13)0.0008 (12)
N70.0371 (15)0.0470 (17)0.0355 (15)0.0110 (13)0.0086 (12)0.0012 (13)
N80.0406 (16)0.0358 (16)0.0452 (17)0.0003 (12)0.0130 (13)0.0016 (13)
O20.0490 (15)0.0455 (15)0.0370 (13)0.0116 (11)0.0159 (11)0.0091 (11)
S20.0431 (5)0.0446 (5)0.0374 (5)0.0059 (4)0.0127 (4)0.0045 (4)
Cl30.0411 (5)0.0369 (5)0.0416 (5)0.0051 (3)0.0121 (4)0.0007 (4)
O30.067 (2)0.057 (2)0.171 (4)0.0099 (16)0.068 (3)0.027 (2)
O40.156 (4)0.125 (4)0.057 (2)0.053 (3)0.048 (2)0.030 (2)
O50.072 (2)0.0446 (18)0.157 (4)0.0041 (15)0.065 (2)0.005 (2)
O60.071 (2)0.143 (4)0.091 (3)0.013 (2)0.002 (2)0.061 (3)
Cl40.0612 (6)0.0568 (6)0.0400 (5)0.0162 (5)0.0077 (4)0.0032 (4)
O70.071 (2)0.072 (2)0.078 (2)0.0262 (17)0.0068 (17)0.0026 (18)
O80.111 (3)0.125 (4)0.075 (3)0.034 (3)0.045 (2)0.034 (2)
O90.128 (4)0.068 (3)0.130 (4)0.020 (2)0.061 (3)0.028 (2)
O100.108 (3)0.169 (5)0.111 (4)0.067 (3)0.049 (3)0.076 (3)
Cl50.0898 (9)0.0703 (8)0.0717 (8)0.0073 (6)0.0420 (7)0.0020 (6)
O110.094 (3)0.121 (4)0.130 (4)0.000 (3)0.039 (3)0.058 (3)
O120.153 (5)0.088 (3)0.177 (5)0.006 (3)0.038 (4)0.047 (3)
O130.303 (10)0.285 (10)0.066 (3)0.061 (8)0.078 (5)0.017 (4)
Cl60.1522 (13)0.0433 (6)0.0406 (6)0.0138 (7)0.0233 (7)0.0044 (5)
O150.162 (4)0.0413 (18)0.073 (2)0.007 (2)0.019 (2)0.0079 (17)
O160.241 (7)0.094 (3)0.073 (3)0.004 (4)0.038 (3)0.009 (2)
Geometric parameters (Å, º) top
Co1—N41.927 (3)C11—C121.508 (6)
Co1—O11.952 (2)C12—N71.506 (4)
Co1—N31.952 (3)C13—C141.504 (6)
Co1—N11.956 (3)C13—N51.515 (5)
Co1—N21.963 (3)C14—N81.482 (5)
Co1—Cl12.2500 (9)C15—S21.786 (4)
C1—C21.505 (5)C16—S21.777 (4)
C1—N21.506 (4)O2—S21.549 (3)
C2—N11.497 (4)Cl3—O61.400 (4)
C3—N11.494 (4)Cl3—O31.410 (3)
C3—C41.510 (5)Cl3—O41.416 (4)
C4—N31.493 (4)Cl3—O51.421 (3)
C5—C61.505 (5)Cl4—O101.386 (4)
C5—N11.513 (4)Cl4—O81.406 (4)
C6—N41.484 (4)Cl4—O71.427 (3)
C7—S11.770 (4)Cl4—O91.455 (4)
C8—S11.768 (5)Cl5—O14B1.299 (10)
O1—S11.536 (2)Cl5—O121.386 (5)
Co2—N81.931 (3)Cl5—O131.393 (6)
Co2—N61.943 (3)Cl5—O111.407 (4)
Co2—N51.947 (3)Cl5—O14A1.523 (11)
Co2—O21.949 (2)Cl6—O161.341 (4)
Co2—N71.962 (3)Cl6—O17B1.370 (6)
Co2—Cl22.2422 (9)Cl6—O18A1.370 (10)
C9—N51.489 (5)Cl6—O151.411 (4)
C9—C101.514 (5)Cl6—O17A1.637 (8)
C10—N61.489 (4)Cl6—O18B1.644 (12)
C11—N51.490 (5)
N4—Co1—O1176.48 (11)C14—C13—N5110.5 (3)
N4—Co1—N393.17 (12)N8—C14—C13107.0 (3)
O1—Co1—N385.52 (12)C9—N5—C11113.0 (3)
N4—Co1—N186.61 (11)C9—N5—C13110.4 (3)
O1—Co1—N190.05 (11)C11—N5—C13111.5 (3)
N3—Co1—N186.93 (11)C9—N5—Co2106.3 (2)
N4—Co1—N292.51 (12)C11—N5—Co2105.9 (2)
O1—Co1—N288.37 (12)C13—N5—Co2109.4 (2)
N3—Co1—N2170.55 (12)C10—N6—Co2110.5 (2)
N1—Co1—N285.87 (11)C12—N7—Co2111.0 (2)
N4—Co1—Cl191.06 (8)C14—N8—Co2109.1 (2)
O1—Co1—Cl192.29 (7)S2—O2—Co2125.15 (15)
N3—Co1—Cl193.87 (9)O2—S2—C16105.5 (2)
N1—Co1—Cl1177.57 (9)O2—S2—C15101.25 (18)
N2—Co1—Cl193.57 (8)C16—S2—C1599.5 (2)
C2—C1—N2108.2 (3)O6—Cl3—O3108.4 (3)
N1—C2—C1108.2 (3)O6—Cl3—O4105.7 (3)
N1—C3—C4107.9 (3)O3—Cl3—O4110.1 (3)
N3—C4—C3107.6 (3)O6—Cl3—O5110.1 (3)
C6—C5—N1110.6 (3)O3—Cl3—O5111.9 (2)
N4—C6—C5107.2 (3)O4—Cl3—O5110.5 (2)
C3—N1—C2112.7 (3)O10—Cl4—O8115.6 (3)
C3—N1—C5111.2 (3)O10—Cl4—O7110.4 (2)
C2—N1—C5111.4 (3)O8—Cl4—O7112.6 (2)
C3—N1—Co1106.4 (2)O10—Cl4—O9103.8 (3)
C2—N1—Co1105.16 (19)O8—Cl4—O9104.7 (3)
C5—N1—Co1109.7 (2)O7—Cl4—O9109.1 (2)
C1—N2—Co1110.9 (2)O14B—Cl5—O12120.2 (5)
C4—N3—Co1110.2 (2)O14B—Cl5—O1395.9 (6)
C6—N4—Co1108.8 (2)O12—Cl5—O13101.8 (5)
S1—O1—Co1124.29 (15)O14B—Cl5—O11118.7 (5)
O1—S1—C8105.0 (2)O12—Cl5—O11108.8 (3)
O1—S1—C7101.0 (2)O13—Cl5—O11108.2 (4)
C8—S1—C799.5 (3)O14B—Cl5—O14A37.6 (5)
N8—Co2—N692.90 (13)O12—Cl5—O14A97.9 (5)
N8—Co2—N586.89 (13)O13—Cl5—O14A132.4 (5)
N6—Co2—N586.90 (12)O11—Cl5—O14A105.6 (5)
N8—Co2—O2175.66 (11)O16—Cl6—O17B136.1 (4)
N6—Co2—O284.78 (13)O16—Cl6—O18A120.6 (5)
N5—Co2—O289.32 (12)O17B—Cl6—O18A33.4 (4)
N8—Co2—N792.21 (13)O16—Cl6—O15116.3 (3)
N6—Co2—N7170.99 (13)O17B—Cl6—O15107.4 (3)
N5—Co2—N785.97 (12)O18A—Cl6—O15115.1 (4)
O2—Co2—N789.63 (12)O16—Cl6—O17A89.5 (4)
N8—Co2—Cl291.24 (9)O17B—Cl6—O17A72.7 (4)
N6—Co2—Cl293.75 (9)O18A—Cl6—O17A100.9 (5)
N5—Co2—Cl2178.05 (10)O15—Cl6—O17A108.3 (4)
O2—Co2—Cl292.57 (7)O16—Cl6—O18B81.8 (5)
N7—Co2—Cl293.56 (9)O17B—Cl6—O18B92.0 (5)
N5—C9—C10107.6 (3)O18A—Cl6—O18B58.7 (6)
N6—C10—C9107.4 (3)O15—Cl6—O18B103.8 (5)
N5—C11—C12108.2 (3)O17A—Cl6—O18B147.3 (5)
N7—C12—C11107.8 (3)
N2—C1—C2—N144.4 (4)N5—C9—C10—N648.4 (4)
N1—C3—C4—N348.6 (4)N5—C11—C12—N744.7 (4)
N1—C5—C6—N440.6 (4)N5—C13—C14—N841.8 (4)
C4—C3—N1—C2159.4 (3)C10—C9—N5—C11161.4 (3)
C4—C3—N1—C574.7 (3)C10—C9—N5—C1372.9 (4)
C4—C3—N1—Co144.6 (3)C10—C9—N5—Co245.7 (3)
C1—C2—N1—C3165.0 (3)C12—C11—N5—C9164.4 (3)
C1—C2—N1—C569.3 (3)C12—C11—N5—C1370.5 (4)
C1—C2—N1—Co149.4 (3)C12—C11—N5—Co248.5 (4)
C6—C5—N1—C3136.8 (3)C14—C13—N5—C9138.5 (3)
C6—C5—N1—C296.6 (3)C14—C13—N5—C1195.0 (4)
C6—C5—N1—Co119.3 (3)C14—C13—N5—Co221.9 (4)
N4—Co1—N1—C3116.1 (2)N8—Co2—N5—C9117.4 (2)
O1—Co1—N1—C362.7 (2)N6—Co2—N5—C924.3 (2)
N3—Co1—N1—C322.8 (2)O2—Co2—N5—C960.5 (2)
N2—Co1—N1—C3151.1 (2)N7—Co2—N5—C9150.2 (2)
Cl1—Co1—N1—C3132.2 (19)Cl2—Co2—N5—C9134 (3)
N4—Co1—N1—C2124.0 (2)N8—Co2—N5—C11122.2 (3)
O1—Co1—N1—C257.1 (2)N6—Co2—N5—C11144.7 (3)
N3—Co1—N1—C2142.6 (2)O2—Co2—N5—C1159.9 (3)
N2—Co1—N1—C231.3 (2)N7—Co2—N5—C1129.8 (3)
Cl1—Co1—N1—C2108 (2)Cl2—Co2—N5—C11106 (3)
N4—Co1—N1—C54.2 (2)N8—Co2—N5—C131.9 (2)
O1—Co1—N1—C5176.9 (2)N6—Co2—N5—C1394.9 (2)
N3—Co1—N1—C597.6 (2)O2—Co2—N5—C13179.7 (2)
N2—Co1—N1—C588.6 (2)N7—Co2—N5—C1390.6 (2)
Cl1—Co1—N1—C512 (2)Cl2—Co2—N5—C1315 (3)
C2—C1—N2—Co118.4 (4)C9—C10—N6—Co228.1 (4)
N4—Co1—N2—C193.9 (2)N8—Co2—N6—C1084.4 (3)
O1—Co1—N2—C182.7 (2)N5—Co2—N6—C102.3 (3)
N3—Co1—N2—C133.0 (9)O2—Co2—N6—C1091.9 (3)
N1—Co1—N2—C17.5 (2)N7—Co2—N6—C1040.0 (9)
Cl1—Co1—N2—C1174.9 (2)Cl2—Co2—N6—C10175.9 (2)
C3—C4—N3—Co129.3 (4)C11—C12—N7—Co220.0 (4)
N4—Co1—N3—C482.7 (2)N8—Co2—N7—C1292.3 (3)
O1—Co1—N3—C494.1 (2)N6—Co2—N7—C1232.2 (9)
N1—Co1—N3—C43.8 (2)N5—Co2—N7—C125.5 (3)
N2—Co1—N3—C444.2 (9)O2—Co2—N7—C1283.8 (3)
Cl1—Co1—N3—C4173.9 (2)Cl2—Co2—N7—C12176.4 (3)
C5—C6—N4—Co143.5 (3)C13—C14—N8—Co242.7 (3)
O1—Co1—N4—C646 (2)N6—Co2—N8—C14112.1 (2)
N3—Co1—N4—C6113.8 (2)N5—Co2—N8—C1425.4 (2)
N1—Co1—N4—C627.1 (2)O2—Co2—N8—C1454.6 (17)
N2—Co1—N4—C658.6 (2)N7—Co2—N8—C1460.4 (2)
Cl1—Co1—N4—C6152.2 (2)Cl2—Co2—N8—C14154.0 (2)
N4—Co1—O1—S1174.9 (18)N8—Co2—O2—S2177.1 (15)
N3—Co1—O1—S1116.83 (19)N6—Co2—O2—S2119.3 (2)
N1—Co1—O1—S1156.25 (19)N5—Co2—O2—S2153.7 (2)
N2—Co1—O1—S170.39 (19)N7—Co2—O2—S267.8 (2)
Cl1—Co1—O1—S123.13 (18)Cl2—Co2—O2—S225.78 (19)
Co1—O1—S1—C8101.7 (2)Co2—O2—S2—C16102.4 (2)
Co1—O1—S1—C7155.3 (3)Co2—O2—S2—C15154.2 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N2—H2C···O10i0.902.133.009 (5)167
N2—H2D···O5ii0.902.243.021 (4)145
N2—H2D···S10.902.853.379 (3)119
N3—H3C···O9iii0.902.653.201 (5)121
N3—H3D···Cl1iv0.902.513.399 (3)169
N4—H4C···O30.902.653.314 (5)131
N4—H4C···Cl1iv0.902.703.462 (3)143
N4—H4D···O9i0.902.183.051 (5)162
N6—H6C···Cl2v0.902.533.421 (3)168
N6—H6D···O17Avi0.902.443.040 (9)124
N7—H7D···O60.902.213.052 (5)156
N7—H7D···S20.902.873.402 (3)120
N7—H7E···O18Aiii0.902.072.932 (10)161
N8—H8D···O17Biii0.902.172.940 (7)144
N8—H8D···O17Biii0.902.172.940 (7)144
N8—H8D···O17Aiii0.902.313.178 (9)163
N8—H8D···O18Aiii0.902.613.334 (10)139
N8—H8E···O11vii0.902.473.181 (5)136
N8—H8E···Cl2v0.902.733.472 (3)141
Symmetry codes: (i) x, y+1/2, z+1/2; (ii) x+1, y1/2, z+3/2; (iii) x+1, y+1/2, z+3/2; (iv) x+1, y+1, z+2; (v) x+2, y+1, z+2; (vi) x+1, y+1/2, z+1/2; (vii) x+1, y, z.
 

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