[mu]-Acetato-O:O'-bis{[bis­(salicyl­idene)­ethyl­ene­diamin­ato]manganese(III)} per­chlorate

In the title complex, [Mn₂(C₁₆H₁₄N₂O₂)₂(C₂H₃O₂)]ClO₄, two [Mn(salen)] moieties [salen is bis­(salicyl­idene)­ethyl­enedi­amine] are connected through a [mu]-acetate bridge in a syn-anti fashion. The Mn...Mn distance is 5.365 (1) Å.

S1. Comment

The X-ray structure analysis of [Mn₂(7-Me-salen)₂(CH₃COO)]ClO₄ gave an unsatisfactory R value of 0.140 due to the poor crystalinity (Suzuki et al., 1997). The structure of [Mn₂(salen)₂(CH₃COO)]ClO₄, (I), is presented here.

S2. Experimental

The title compound, [Mn₂(salen)₂(CH₃COO)]ClO₄, was synthesized as described previously by Suzuki et al. (1997).

S3. Refinement

The positional parameters of all the H atoms were calculated geometrically and fixed with U(H) = 1.2U_eq(parent atom).

Computing details

Data collection: MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1993); cell refinement: MSC/AFC Diffractometer Control Software; data reduction: TEXSAN (Molecular Structure Corporation, 1999); program(s) used to solve structure: DIRDIF94 (Beurskens et al., 1994); program(s) used to refine structure: TEXSAN; software used to prepare material for publication: TEXSAN.

µ-acetato-O:O'-bis({2,2'[1,2-ethanediylbis(nitrilomethylidyne)]diphenolato}- manganese(III)) perchlorate

Crystal data

[Mn2(C16H14N2O2)2(C2H3O2)]ClO4	Z = 2
Mr = 800.97	Dx = 1.583 Mg m^−3
Triclinic, P1	Mo Kα radiation, λ = 0.71073 Å
a = 11.990 (4) Å	Cell parameters from 25 reflections
b = 12.988 (4) Å	θ = 10–15°
c = 11.296 (5) Å	µ = 0.90 mm^−1
α = 106.52 (3)°	T = 298 K
β = 94.31 (3)°	Prism, black
γ = 90.79 (3)°	0.5 × 0.5 × 0.3 mm
V = 1680.5 (9) Å^3

Data collection

Rigaku AFC-5S diffractometer	Rint = 0.011
θ–2θ scans	θmax = 27.5°
Absorption correction: integration (Coppens et al., 1965)	h = 0→16
Tmin = 0.670, Tmax = 0.789	k = −17→17
8092 measured reflections	l = −15→15
7723 independent reflections	3 standard reflections every 100 reflections
6237 reflections with I > 2σ(I)	intensity decay: none

Refinement

Refinement on F^2	H-atom parameters not refined
R[F^2 > 2σ(F^2)] = 0.039	w = 1/[σ^2(Fo^2) + (0.05(Fo^2 + 2Fc^2)/3)^2]
wR(F^2) = 0.106	(Δ/σ)max = 0.001
S = 1.37	Δρmax = 0.53 e Å^−3
7723 reflections	Δρmin = −0.66 e Å^−3
460 parameters

Special details

Refinement. Refinement using reflections with F² > 0.0 σ(F²). The weighted R-factor (wR) and goodness of fit (S) are based on F². R-factor (gt) are based on F. The threshold expression of F² > 2.0 σ(F²) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mn1	0.00387 (3)	0.46031 (3)	0.34269 (3)	0.02548 (8)
Mn2	−0.35940 (3)	0.48464 (3)	0.04533 (3)	0.02727 (8)
Cl1	−0.48912 (7)	0.22137 (7)	0.40514 (6)	0.0617 (2)
O1	−0.0807 (1)	0.5607 (1)	0.4584 (1)	0.0293 (4)
O2	−0.0884 (1)	0.3388 (1)	0.3269 (1)	0.0345 (4)
O3	−0.4264 (1)	0.5849 (1)	−0.0291 (1)	0.0324 (4)
O4	−0.3411 (1)	0.3819 (1)	−0.1063 (1)	0.0355 (4)
O5	−0.0808 (1)	0.5022 (1)	0.1913 (2)	0.0425 (5)
O6	−0.1991 (1)	0.5607 (1)	0.0677 (2)	0.0425 (5)
O7	−0.4440 (3)	0.1738 (2)	0.2936 (2)	0.0923 (10)
O8	−0.5757 (4)	0.2880 (5)	0.3794 (4)	0.190 (2)
O9	−0.4076 (4)	0.2916 (3)	0.4854 (3)	0.148 (2)
O10	−0.5290 (3)	0.1514 (3)	0.4684 (3)	0.110 (1)
N1	0.1250 (1)	0.5727 (2)	0.3706 (2)	0.0330 (5)
N2	0.1189 (2)	0.3699 (2)	0.2491 (2)	0.0364 (5)
N3	−0.4018 (1)	0.5736 (2)	0.2085 (2)	0.0326 (5)
N4	−0.3272 (1)	0.3801 (2)	0.1395 (2)	0.0317 (5)
C1	−0.0882 (2)	0.6631 (2)	0.4546 (2)	0.0314 (5)
C2	−0.1864 (2)	0.7167 (2)	0.4857 (2)	0.0405 (6)
C3	−0.1958 (2)	0.8229 (2)	0.4866 (3)	0.0528 (8)
C4	−0.1075 (3)	0.8786 (2)	0.4567 (3)	0.0585 (9)
C5	−0.0101 (3)	0.8282 (2)	0.4288 (3)	0.0509 (8)
C6	0.0022 (2)	0.7203 (2)	0.4263 (2)	0.0365 (6)
C7	0.1095 (2)	0.6734 (2)	0.4004 (2)	0.0391 (6)
C8	0.2356 (2)	0.5272 (2)	0.3464 (2)	0.0432 (7)
C9	0.2178 (2)	0.4318 (2)	0.2334 (3)	0.0487 (7)
C10	0.1129 (2)	0.2674 (2)	0.2032 (2)	0.0482 (7)
C11	0.0238 (2)	0.1974 (2)	0.2134 (3)	0.0488 (7)
C12	0.0337 (3)	0.0850 (3)	0.1621 (4)	0.075 (1)
C13	−0.0447 (4)	0.0134 (3)	0.1752 (4)	0.085 (1)
C14	−0.1366 (3)	0.0506 (2)	0.2390 (3)	0.070 (1)
C15	−0.1508 (2)	0.1593 (2)	0.2898 (3)	0.0491 (7)
C16	−0.0712 (2)	0.2352 (2)	0.2775 (2)	0.0383 (6)
C17	−0.4148 (2)	0.6914 (2)	0.0230 (2)	0.0305 (5)
C18	−0.4189 (2)	0.7586 (2)	−0.0542 (2)	0.0376 (6)
C19	−0.4140 (2)	0.8693 (2)	−0.0050 (3)	0.0482 (7)
C20	−0.4067 (2)	0.9162 (2)	0.1230 (3)	0.0550 (8)
C21	−0.4041 (2)	0.8516 (2)	0.2000 (2)	0.0465 (7)
C22	−0.4062 (2)	0.7390 (2)	0.1526 (2)	0.0356 (6)
C23	−0.4120 (2)	0.6756 (2)	0.2382 (2)	0.0365 (6)
C24	−0.4181 (2)	0.5103 (2)	0.2957 (2)	0.0380 (6)
C25	−0.3295 (2)	0.4267 (2)	0.2750 (2)	0.0383 (6)
C26	−0.3056 (2)	0.2812 (2)	0.0936 (2)	0.0382 (6)
C27	−0.3007 (2)	0.2270 (2)	−0.0354 (2)	0.0387 (6)
C28	−0.2831 (3)	0.1148 (2)	−0.0706 (3)	0.0575 (9)
C29	−0.2870 (3)	0.0560 (2)	−0.1917 (3)	0.0661 (10)
C30	−0.3101 (3)	0.1060 (2)	−0.2840 (3)	0.0560 (8)
C31	−0.3267 (2)	0.2153 (2)	−0.2537 (2)	0.0426 (7)
C32	−0.3218 (2)	0.2782 (2)	−0.1295 (2)	0.0330 (5)
C33	−0.1049 (2)	0.5608 (2)	0.1233 (2)	0.0323 (5)
C34	−0.0168 (2)	0.6367 (2)	0.1026 (2)	0.0514 (8)
H1	−0.2483	0.6795	0.5068	0.0487*
H2	−0.2642	0.8586	0.5080	0.0634*
H3	−0.1151	0.9518	0.4557	0.0703*
H4	0.0516	0.8674	0.4104	0.0611*
H5	0.1729	0.7210	0.4059	0.0470*
H6	0.2857	0.5795	0.3313	0.0519*
H7	0.2661	0.5050	0.4159	0.0519*
H8	0.2823	0.3881	0.2260	0.0585*
H9	0.2051	0.4555	0.1605	0.0585*
H10	0.1740	0.2348	0.1577	0.0579*
H11	0.0972	0.0590	0.1170	0.0897*
H12	−0.0363	−0.0624	0.1405	0.1022*
H13	−0.1919	−0.0001	0.2484	0.0839*
H14	−0.2155	0.1830	0.3338	0.0589*
H15	−0.4252	0.7277	−0.1425	0.0451*
H16	−0.4157	0.9142	−0.0595	0.0579*
H17	−0.4036	0.9930	0.1567	0.0660*
H18	−0.4007	0.8838	0.2880	0.0559*
H19	−0.4243	0.7121	0.3227	0.0438*
H20	−0.4093	0.5560	0.3795	0.0456*
H21	−0.4914	0.4761	0.2795	0.0456*
H22	−0.3478	0.3716	0.3124	0.0459*
H23	−0.2578	0.4596	0.3103	0.0459*
H24	−0.2914	0.2396	0.1507	0.0458*
H25	−0.2680	0.0796	−0.0073	0.0690*
H26	−0.2739	−0.0196	−0.2132	0.0794*
H27	−0.3144	0.0644	−0.3695	0.0672*
H28	−0.3419	0.2487	−0.3186	0.0511*
H29	0.0521	0.6307	0.1489	0.0617*
H30	−0.0053	0.6186	0.0160	0.0617*
H31	−0.0412	0.7092	0.1298	0.0617*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mn1	0.0234 (2)	0.0286 (2)	0.0259 (2)	0.0013 (1)	0.0031 (1)	0.0099 (1)
Mn2	0.0327 (2)	0.0273 (2)	0.0237 (2)	0.0053 (1)	0.0002 (1)	0.0106 (1)
Cl1	0.0737 (5)	0.0704 (5)	0.0372 (3)	−0.0129 (4)	0.0143 (3)	0.0074 (3)
O1	0.0302 (7)	0.0295 (7)	0.0306 (7)	0.0027 (6)	0.0050 (6)	0.0120 (6)
O2	0.0329 (8)	0.0306 (8)	0.0409 (9)	0.0006 (6)	0.0013 (6)	0.0122 (7)
O3	0.0395 (8)	0.0274 (7)	0.0295 (7)	0.0048 (6)	−0.0044 (6)	0.0087 (6)
O4	0.0473 (9)	0.0299 (8)	0.0316 (8)	0.0083 (7)	0.0070 (7)	0.0114 (6)
O5	0.0449 (9)	0.052 (1)	0.0351 (8)	−0.0001 (8)	−0.0063 (7)	0.0216 (8)
O6	0.0352 (8)	0.054 (1)	0.0430 (9)	−0.0018 (7)	−0.0059 (7)	0.0250 (8)
O7	0.122 (2)	0.086 (2)	0.062 (2)	0.018 (2)	0.032 (2)	0.004 (1)
O8	0.159 (4)	0.303 (6)	0.173 (4)	0.148 (4)	0.097 (3)	0.146 (4)
O9	0.224 (4)	0.148 (3)	0.061 (2)	−0.105 (3)	−0.036 (2)	0.029 (2)
O10	0.117 (2)	0.122 (3)	0.105 (2)	−0.033 (2)	0.018 (2)	0.055 (2)
N1	0.0286 (9)	0.041 (1)	0.0330 (9)	−0.0030 (7)	0.0019 (7)	0.0164 (8)
N2	0.0308 (9)	0.048 (1)	0.0303 (9)	0.0068 (8)	0.0045 (7)	0.0096 (8)
N3	0.0321 (9)	0.038 (1)	0.0273 (9)	0.0005 (7)	−0.0002 (7)	0.0100 (8)
N4	0.0285 (9)	0.039 (1)	0.0319 (9)	0.0018 (7)	−0.0006 (7)	0.0172 (8)
C1	0.038 (1)	0.030 (1)	0.0251 (10)	0.0019 (9)	−0.0020 (8)	0.0086 (8)
C2	0.042 (1)	0.036 (1)	0.042 (1)	0.0057 (10)	−0.0033 (10)	0.0097 (10)
C3	0.055 (2)	0.039 (1)	0.060 (2)	0.015 (1)	−0.007 (1)	0.009 (1)
C4	0.079 (2)	0.029 (1)	0.068 (2)	0.005 (1)	−0.005 (2)	0.015 (1)
C5	0.065 (2)	0.035 (1)	0.054 (2)	−0.008 (1)	0.000 (1)	0.017 (1)
C6	0.044 (1)	0.034 (1)	0.033 (1)	−0.0031 (9)	−0.0024 (9)	0.0128 (9)
C7	0.039 (1)	0.043 (1)	0.038 (1)	−0.0101 (10)	0.0031 (10)	0.017 (1)
C8	0.027 (1)	0.056 (2)	0.051 (1)	−0.003 (1)	0.0028 (10)	0.023 (1)
C9	0.035 (1)	0.067 (2)	0.047 (1)	0.007 (1)	0.016 (1)	0.019 (1)
C10	0.044 (1)	0.051 (2)	0.042 (1)	0.014 (1)	0.004 (1)	0.001 (1)
C11	0.049 (1)	0.038 (1)	0.050 (1)	0.008 (1)	−0.008 (1)	0.000 (1)
C12	0.076 (2)	0.045 (2)	0.084 (2)	0.017 (2)	−0.005 (2)	−0.010 (2)
C13	0.090 (3)	0.035 (2)	0.113 (3)	0.003 (2)	−0.022 (2)	0.000 (2)
C14	0.082 (2)	0.040 (2)	0.084 (2)	−0.016 (2)	−0.037 (2)	0.025 (2)
C15	0.051 (1)	0.040 (1)	0.057 (2)	−0.008 (1)	−0.018 (1)	0.022 (1)
C16	0.042 (1)	0.034 (1)	0.038 (1)	−0.0002 (9)	−0.0136 (10)	0.0116 (9)
C17	0.0251 (10)	0.028 (1)	0.038 (1)	0.0014 (8)	−0.0025 (8)	0.0095 (9)
C18	0.036 (1)	0.035 (1)	0.044 (1)	0.0033 (9)	0.0012 (10)	0.0155 (10)
C19	0.050 (1)	0.033 (1)	0.065 (2)	0.000 (1)	−0.002 (1)	0.021 (1)
C20	0.058 (2)	0.027 (1)	0.074 (2)	0.000 (1)	−0.010 (1)	0.008 (1)
C21	0.048 (1)	0.035 (1)	0.048 (1)	0.001 (1)	−0.006 (1)	0.001 (1)
C22	0.033 (1)	0.031 (1)	0.038 (1)	0.0006 (9)	−0.0028 (9)	0.0057 (9)
C23	0.036 (1)	0.040 (1)	0.028 (1)	0.0027 (9)	0.0004 (9)	0.0020 (9)
C24	0.039 (1)	0.049 (1)	0.028 (1)	−0.0024 (10)	0.0027 (9)	0.0141 (10)
C25	0.041 (1)	0.048 (1)	0.031 (1)	−0.001 (1)	−0.0028 (9)	0.021 (1)
C26	0.036 (1)	0.041 (1)	0.044 (1)	0.0056 (9)	−0.0029 (10)	0.024 (1)
C27	0.037 (1)	0.035 (1)	0.046 (1)	0.0086 (9)	0.0031 (10)	0.017 (1)
C28	0.073 (2)	0.039 (1)	0.065 (2)	0.020 (1)	0.004 (1)	0.022 (1)
C29	0.089 (2)	0.032 (1)	0.075 (2)	0.020 (1)	0.011 (2)	0.010 (1)
C30	0.068 (2)	0.041 (1)	0.055 (2)	0.010 (1)	0.017 (1)	0.004 (1)
C31	0.047 (1)	0.038 (1)	0.043 (1)	0.004 (1)	0.011 (1)	0.011 (1)
C32	0.030 (1)	0.031 (1)	0.040 (1)	0.0043 (8)	0.0058 (9)	0.0115 (9)
C33	0.034 (1)	0.039 (1)	0.0237 (10)	0.0016 (9)	0.0033 (8)	0.0084 (9)
C34	0.052 (2)	0.063 (2)	0.042 (1)	−0.016 (1)	−0.003 (1)	0.022 (1)

Geometric parameters (Å, º)

Mn1—O1	1.924 (2)	C10—C11	1.425 (4)
Mn1—O2	1.873 (2)	C10—H10	0.960
Mn1—O5	2.129 (2)	C11—C12	1.419 (4)
Mn1—N1	1.987 (2)	C11—C16	1.414 (4)
Mn1—N2	1.989 (2)	C12—C13	1.359 (6)
Mn2—O3	1.897 (1)	C12—H11	0.960
Mn2—O4	1.878 (2)	C13—C14	1.380 (6)
Mn2—O6	2.113 (2)	C13—H12	0.960
Mn2—N3	1.984 (2)	C14—C15	1.383 (4)
Mn2—N4	1.975 (2)	C14—H13	0.960
Cl1—O7	1.389 (2)	C15—C16	1.406 (4)
Cl1—O8	1.426 (4)	C15—H14	0.960
Cl1—O9	1.407 (3)	C17—C18	1.397 (3)
Cl1—O10	1.405 (3)	C17—C22	1.413 (3)
O1—C1	1.348 (3)	C18—C19	1.384 (3)
O2—C16	1.328 (3)	C18—H15	0.960
O3—C17	1.340 (3)	C19—C20	1.396 (4)
O4—C32	1.323 (3)	C19—H16	0.960
O5—C33	1.248 (3)	C20—C21	1.369 (4)
O6—C33	1.250 (3)	C20—H17	0.960
N1—C7	1.274 (3)	C21—C22	1.407 (3)
N1—C8	1.473 (3)	C21—H18	0.960
N2—C9	1.474 (3)	C22—C23	1.442 (3)
N2—C10	1.283 (3)	C23—H19	0.960
N3—C23	1.280 (3)	C24—C25	1.512 (4)
N3—C24	1.473 (3)	C24—H20	0.960
N4—C25	1.480 (3)	C24—H21	0.960
N4—C26	1.279 (3)	C25—H22	0.960
C1—C2	1.393 (3)	C25—H23	0.960
C1—C6	1.411 (3)	C26—C27	1.433 (4)
C2—C3	1.384 (4)	C26—H24	0.960
C2—H1	0.960	C27—C28	1.421 (3)
C3—C4	1.388 (4)	C27—C32	1.414 (3)
C3—H2	0.960	C28—C29	1.361 (4)
C4—C5	1.360 (4)	C28—H25	0.960
C4—H3	0.960	C29—C30	1.391 (4)
C5—C6	1.404 (3)	C29—H26	0.960
C5—H4	0.960	C30—C31	1.384 (4)
C6—C7	1.445 (4)	C30—H27	0.960
C7—H5	0.960	C31—C32	1.405 (3)
C8—C9	1.503 (4)	C31—H28	0.960
C8—H6	0.960	C33—C34	1.510 (3)
C8—H7	0.960	C34—H29	0.960
C9—H8	0.960	C34—H30	0.960
C9—H9	0.960	C34—H31	0.960
Mn1···C1^i	3.259 (2)	O7···C26	3.477 (4)
Mn1···Mn1^i	3.4161 (6)	O7···C15	3.526 (4)
Mn2···O3^ii	2.686 (2)	O8···C2^v	3.341 (5)
Mn2···C17^ii	3.414 (2)	O8···C18^ii	3.544 (5)
Mn2···Mn2^ii	3.510 (1)	O9···C8^i	3.183 (4)
O1···O1^i	2.786 (3)	O9···C31^vi	3.445 (4)
O1···N1^i	3.008 (2)	O9···C25	3.503 (4)
O1···O2^i	3.013 (2)	O10···C3^v	3.383 (5)
O1···N2^i	3.239 (2)	O10···C23^v	3.563 (4)
O1···C8^i	3.407 (3)	N2···C2^i	3.531 (3)
O2···C1^i	3.134 (3)	N2···C1^i	3.538 (3)
O2···C7^i	3.158 (3)	N4···C18^ii	3.443 (3)
O2···C6^i	3.199 (3)	N4···C17^ii	3.448 (3)
O2···N1^i	3.345 (2)	C1···C16^i	3.366 (3)
O3···O3^ii	3.050 (3)	C2···C10^i	3.505 (4)
O3···N3^ii	3.077 (2)	C5···C15^i	3.553 (4)
O3···N4^ii	3.209 (2)	C6···C16^i	3.268 (3)
O3···O4^ii	3.256 (2)	C6···C15^i	3.480 (3)
O3···C24^ii	3.324 (3)	C7···C15^i	3.549 (4)
O3···C9^iii	3.496 (3)	C7···C16^i	3.559 (3)
O4···C23^ii	3.191 (3)	C17···C32^ii	3.452 (3)
O4···N3^ii	3.326 (3)	C17···C26^ii	3.568 (3)
O4···C22^ii	3.328 (3)	C17···C27^ii	3.586 (3)
O4···C17^ii	3.347 (3)	C18···C26^ii	3.312 (3)
O4···C9^iii	3.507 (3)	C18···C27^ii	3.575 (4)
O4···C8^iii	3.556 (3)	C21···C31^ii	3.472 (4)
O5···C34^iii	3.590 (3)	C22···C32^ii	3.251 (3)
O6···C9^iii	3.421 (3)	C22···C31^ii	3.483 (4)
O7···C18^ii	3.392 (4)	C23···C31^ii	3.452 (4)
O7···C20^iv	3.407 (4)	C23···C32^ii	3.455 (3)
O7···C19^ii	3.455 (4)	C33···C34^iii	3.489 (4)
O1—Mn1—O2	96.7 (1)	C10—C11—C16	122.6 (2)
O1—Mn1—O5	91.0 (1)	C12—C11—C16	118.9 (3)
O1—Mn1—N1	89.1 (1)	C11—C12—C13	121.5 (3)
O1—Mn1—N2	167.7 (1)	C11—C12—H11	119.2
O2—Mn1—O5	94.9 (1)	C13—C12—H11	119.2
O2—Mn1—N1	168.8 (1)	C12—C13—C14	119.3 (3)
O2—Mn1—N2	91.2 (1)	C12—C13—H12	120.3
O5—Mn1—N1	94.6 (1)	C14—C13—H12	120.3
O5—Mn1—N2	97.7 (1)	C13—C14—C15	121.4 (3)
N1—Mn1—N2	81.6 (1)	C13—C14—H13	119.3
O3—Mn2—O4	94.3 (1)	C15—C14—H13	119.3
O3—Mn2—O6	93.1 (1)	C14—C15—C16	120.5 (3)
O3—Mn2—N3	89.1 (1)	C14—C15—H14	119.8
O3—Mn2—N4	165.4 (1)	C16—C15—H14	119.8
O4—Mn2—O6	96.9 (1)	O2—C16—C11	123.2 (2)
O4—Mn2—N3	168.9 (1)	O2—C16—C15	118.5 (2)
O4—Mn2—N4	92.1 (1)	C11—C16—C15	118.3 (2)
O6—Mn2—N3	93.5 (1)	O3—C17—C18	118.6 (2)
O6—Mn2—N4	99.1 (1)	O3—C17—C22	122.8 (2)
N3—Mn2—N4	82.3 (1)	C18—C17—C22	118.5 (2)
O7—Cl1—O8	106.8 (2)	C17—C18—C19	120.9 (2)
O7—Cl1—O9	108.9 (2)	C17—C18—H15	119.6
O7—Cl1—O10	116.4 (2)	C19—C18—H15	119.6
O8—Cl1—O9	105.7 (3)	C18—C19—C20	120.7 (2)
O8—Cl1—O10	110.8 (3)	C18—C19—H16	119.7
O9—Cl1—O10	107.7 (2)	C20—C19—H16	119.7
Mn1—O1—C1	120.6 (1)	C19—C20—C21	119.3 (2)
Mn1—O2—C16	130.5 (2)	C19—C20—H17	120.4
Mn2—O3—C17	122.5 (1)	C21—C20—H17	120.4
Mn2—O4—C32	129.6 (1)	C20—C21—C22	121.2 (2)
Mn1—O5—C33	155.9 (2)	C20—C21—H18	119.4
Mn2—O6—C33	140.1 (1)	C22—C21—H18	119.4
Mn1—N1—C7	124.5 (2)	C17—C22—C21	119.5 (2)
Mn1—N1—C8	112.6 (2)	C17—C22—C23	121.9 (2)
C7—N1—C8	122.8 (2)	C21—C22—C23	118.3 (2)
Mn1—N2—C9	113.7 (2)	N3—C23—C22	124.0 (2)
Mn1—N2—C10	126.3 (2)	N3—C23—H19	118.0
C9—N2—C10	119.9 (2)	C22—C23—H19	118.0
Mn2—N3—C23	124.8 (2)	N3—C24—C25	106.4 (2)
Mn2—N3—C24	112.9 (1)	N3—C24—H20	110.2
C23—N3—C24	122.4 (2)	N3—C24—H21	110.2
Mn2—N4—C25	113.3 (1)	C25—C24—H20	110.2
Mn2—N4—C26	126.1 (2)	C25—C24—H21	110.2
C25—N4—C26	120.6 (2)	H20—C24—H21	109.5
O1—C1—C2	119.1 (2)	N4—C25—C24	107.3 (2)
O1—C1—C6	122.3 (2)	N4—C25—H22	110.0
C2—C1—C6	118.5 (2)	N4—C25—H23	110.0
C1—C2—C3	120.7 (2)	C24—C25—H22	110.0
C1—C2—H1	119.7	C24—C25—H23	110.0
C3—C2—H1	119.7	H22—C25—H23	109.5
C2—C3—C4	120.7 (3)	N4—C26—C27	125.8 (2)
C2—C3—H2	119.6	N4—C26—H24	117.1
C4—C3—H2	119.6	C27—C26—H24	117.1
C3—C4—C5	119.4 (2)	C26—C27—C28	118.2 (2)
C3—C4—H3	120.3	C26—C27—C32	123.0 (2)
C5—C4—H3	120.3	C28—C27—C32	118.6 (2)
C4—C5—C6	121.4 (3)	C27—C28—C29	121.7 (3)
C4—C5—H4	119.3	C27—C28—H25	119.1
C6—C5—H4	119.3	C29—C28—H25	119.1
C1—C6—C5	119.2 (2)	C28—C29—C30	119.6 (3)
C1—C6—C7	122.4 (2)	C28—C29—H26	120.2
C5—C6—C7	118.3 (2)	C30—C29—H26	120.2
N1—C7—C6	124.0 (2)	C29—C30—C31	120.5 (3)
N1—C7—H5	118.0	C29—C30—H27	119.8
C6—C7—H5	118.0	C31—C30—H27	119.7
N1—C8—C9	106.6 (2)	C30—C31—C32	121.1 (2)
N1—C8—H6	110.2	C30—C31—H28	119.5
N1—C8—H7	110.2	C32—C31—H28	119.5
C9—C8—H6	110.2	O4—C32—C27	123.2 (2)
C9—C8—H7	110.2	O4—C32—C31	118.2 (2)
H6—C8—H7	109.5	C27—C32—C31	118.5 (2)
N2—C9—C8	107.3 (2)	O5—C33—O6	124.1 (2)
N2—C9—H8	110.0	O5—C33—C34	119.9 (2)
N2—C9—H9	110.0	O6—C33—C34	116.0 (2)
C8—C9—H8	110.0	C33—C34—H29	109.5
C8—C9—H9	110.0	C33—C34—H30	109.5
H8—C9—H9	109.5	C33—C34—H31	109.5
N2—C10—C11	126.0 (2)	H29—C34—H30	109.5
N2—C10—H10	117.0	H29—C34—H31	109.5
C11—C10—H10	117.0	H30—C34—H31	109.5
C10—C11—C12	118.4 (3)
Mn1—O5—C33—O6	−148.6 (3)	Mn2—O6—C33—O5	0.9 (4)

Symmetry codes: (i) −x, −y+1, −z+1; (ii) −x−1, −y+1, −z; (iii) −x, −y+1, −z; (iv) x, y−1, z; (v) −x−1, −y+1, −z+1; (vi) x, y, z+1.