cif-access (metal-organic compounds)
The title complex consists of infinite positively charged [Sc2(Gly)6]n (Gly = glycine, O2CCH2NH3) chains and ClO4- anions. In the [Sc2(Gly)6]n chain, each adjacent pair of Sc3+ ions is linked by three glycine molecules. The scandium ions are octahedrally coordinated by six oxygen atoms from six glycine. The coordination environment around Sc1 is nearly ideal while that around Sc2 is quite distorted. This work is a correction of space-group from P-1 (Yan et al., 1996) to R-3.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 130515