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The title compound shows significant conformational distortion in the vicinity of the [beta]-nitro group. This is attributed to steric interaction between a meso-phenyl and the [beta]-nitro group. The overall degree of conformation distortion is moderate, the average deviation of the 24 macrocycle atoms from their least-squares plane being 0.08 Å. The largest displacements (0.33 Å from the plane of the four pyrrole nitrogen atoms) were found for the Cb-positions of the nitrated pyrrole ring.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks MS133, paper

hkl

Structure factor file (CIF format)
Contains datablock ms133

CCDC reference: 130114

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