Isomorphism in monomeric 1:3 complexes of silver(I) salts with tri-p-tolylphosphine

Reaction of silver(I) salts with three equivalents of tri-p-tolylphosphine in CH₃CN resulted in a series of isomorphous complexes [AgX{P(4-MeC₆H₄)₃}₃] (X = Br, SCN, ClO₄). These complexes all crystallize in the orthorhombic space group Pna2₁. The complexes with X = Br, SCN are distorted tetrahedral around the silver(I) atom, whereas the ClO₄^- complex is distorted trigonal planar around the silver. The new complexes are compared with each other using r.m.s. overlay calculations as well as half-normal probability plot analysis and with the previously reported isomorphous chloride, bromide as well as the non-isomorphous iodide complexes.

Computing details

Data collection: Apex2 (Bruker, 2005) for (II); APEX2 (Bruker, 2005) for (III). For all compounds, cell refinement: SAINT-Plus (Bruker, 2004). Data reduction: SAINT-Plus and XPREP (Bruker, 2004) for (I), (III); SAINT-Plus and XPREP (Bruker 2004) for (II). Program(s) used to solve structure: SHELXL97 (Sheldrick, 1997) for (I), (III); SHELXS97 (Sheldrick, 1997) for (II). Program(s) used to refine structure: SIR97 (Altomare et al., 1999) for (I); SHELXL97 (Sheldrick, 1997) for (II); SHELXS97 (Sheldrick, 1997) for (III). For all compounds, molecular graphics: DIAMOND 3.0c (Brandenburg & Putz, 2004); software used to prepare material for publication: WinGX (Farrugia, 1999).

(I)

Crystal data

2(C63H63AgBrP3)·C3H6N	Dx = 1.345 Mg m^−3
Mr = 2257.72	Mo Kα radiation, λ = 0.71069 Å
Orthorhombic, Pna21	Cell parameters from 5664 reflections
a = 20.5740 (5) Å	θ = 1.3–28.4°
b = 25.5930 (8) Å	µ = 1.21 mm^−1
c = 10.5860 (7) Å	T = 100 K
V = 5574.1 (4) Å^3	Cuboid, colourless
Z = 2	0.44 × 0.21 × 0.18 mm
F(000) = 2360

Data collection

Bruker X8 ApexII 4K Kappa CCD diffractometer	9587 reflections with I > 2σ(I)
ω and φ scans	Rint = 0.066
Absorption correction: multi-scan SADABS (Bruker, 2004)	θmax = 28.4°, θmin = 1.3°
Tmin = 0.619, Tmax = 0.812	h = −27→25
42533 measured reflections	k = −34→34
12171 independent reflections	l = −11→14

Refinement

Refinement on F^2	H-atom parameters constrained
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0243P)^2 + 0.9591P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.043	(Δ/σ)max = 0.015
wR(F^2) = 0.095	Δρmax = 0.53 e Å^−3
S = 1.06	Δρmin = −0.59 e Å^−3
12171 reflections	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
650 parameters	Absolute structure parameter: 0.003 (7)
3 restraints

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
P1	0.77429 (5)	0.48169 (3)	0.70519 (10)	0.0157 (2)
P2	0.82915 (5)	0.32153 (4)	0.73369 (10)	0.0166 (2)
P3	0.63468 (5)	0.35400 (3)	0.69930 (10)	0.0152 (2)
Br1	0.74092 (2)	0.390378 (15)	0.39854 (4)	0.02529 (11)
N01	0.4641 (4)	0.1959 (3)	0.1851 (7)	0.034 (2)	0.5
C02	0.4052 (4)	0.1262 (3)	0.3200 (7)	0.091 (3)
H02A	0.4093	0.0922	0.278	0.136*
H02B	0.3591	0.1352	0.3284	0.136*
H02C	0.4251	0.1244	0.4039	0.136*
Ag1	0.748095 (15)	0.388351 (9)	0.65604 (3)	0.01535 (7)
C01	0.4388 (4)	0.1669 (3)	0.2432 (8)	0.0185 (17)	0.5
C111	0.72088 (19)	0.53008 (13)	0.6331 (4)	0.0159 (8)
C112	0.7432 (2)	0.57786 (15)	0.5871 (4)	0.0218 (9)
H112	0.7884	0.5854	0.5874	0.026*
C113	0.6992 (2)	0.61445 (14)	0.5407 (4)	0.0241 (9)
H113	0.715	0.6467	0.5083	0.029*
C114	0.6335 (2)	0.60498 (13)	0.5409 (4)	0.0227 (9)
C115	0.6118 (2)	0.55748 (15)	0.5869 (4)	0.0286 (11)
H115	0.5665	0.5501	0.5875	0.034*
C116	0.6549 (2)	0.52055 (15)	0.6318 (4)	0.0281 (11)
H116	0.6389	0.4881	0.6624	0.034*
C117	0.5871 (2)	0.64555 (16)	0.4937 (5)	0.0342 (12)
H11A	0.6045	0.6804	0.5116	0.051*
H11B	0.5451	0.6414	0.5364	0.051*
H11C	0.5812	0.6414	0.4024	0.051*
C121	0.85433 (18)	0.50313 (12)	0.6536 (4)	0.0183 (8)
C122	0.8972 (2)	0.53060 (14)	0.7295 (4)	0.0239 (9)
H122	0.8846	0.5396	0.813	0.029*
C123	0.9581 (2)	0.54517 (14)	0.6865 (4)	0.0244 (10)
H123	0.9866	0.5638	0.741	0.029*
C124	0.9781 (2)	0.53296 (15)	0.5647 (4)	0.0240 (10)
C125	0.9348 (2)	0.50619 (15)	0.4867 (4)	0.0253 (10)
H125	0.9471	0.4981	0.4025	0.03*
C126	0.87468 (19)	0.49142 (13)	0.5294 (4)	0.0211 (8)
H126	0.8462	0.473	0.4746	0.025*
C127	1.0449 (2)	0.54764 (16)	0.5194 (5)	0.0316 (10)
H12A	1.0545	0.5837	0.5444	0.047*
H12B	1.0468	0.5447	0.4272	0.047*
H12C	1.0771	0.5241	0.5571	0.047*
C131	0.77053 (19)	0.49982 (14)	0.8724 (4)	0.0169 (9)
C132	0.7781 (2)	0.46138 (15)	0.9633 (4)	0.0189 (9)
H132	0.789	0.4269	0.938	0.023*
C133	0.7701 (2)	0.47250 (16)	1.0906 (4)	0.0223 (10)
H133	0.7757	0.4455	1.1512	0.027*
C134	0.7538 (2)	0.52260 (15)	1.1309 (4)	0.0186 (9)
C135	0.7485 (2)	0.56142 (14)	1.0393 (5)	0.0228 (9)
H135	0.7391	0.5962	1.0646	0.027*
C136	0.75639 (19)	0.55054 (14)	0.9129 (4)	0.0217 (9)
H136	0.7522	0.5778	0.8525	0.026*
C137	0.7396 (2)	0.5345 (2)	1.2678 (4)	0.0319 (12)
H13A	0.7071	0.5098	1.2997	0.048*
H13B	0.7229	0.5702	1.2753	0.048*
H13C	0.7797	0.5311	1.3173	0.048*
C211	0.84400 (19)	0.26558 (14)	0.6306 (4)	0.0169 (9)
C212	0.86574 (19)	0.21784 (13)	0.6754 (4)	0.0217 (9)
H212	0.871	0.2126	0.7636	0.026*
C213	0.8798 (2)	0.17765 (16)	0.5916 (4)	0.0236 (10)
H213	0.8941	0.1449	0.6236	0.028*
C214	0.8734 (2)	0.18437 (15)	0.4620 (4)	0.0221 (10)
C215	0.8512 (2)	0.23208 (15)	0.4185 (4)	0.0245 (10)
H215	0.8457	0.2373	0.3303	0.029*
C216	0.8368 (2)	0.27245 (15)	0.5014 (4)	0.0246 (10)
H216	0.822	0.305	0.4694	0.03*
C217	0.8883 (2)	0.14074 (15)	0.3704 (4)	0.0282 (11)
H21A	0.8658	0.1473	0.2903	0.042*
H21B	0.8736	0.1074	0.4059	0.042*
H21C	0.9353	0.1392	0.3554	0.042*
C221	0.79925 (19)	0.29306 (13)	0.8807 (4)	0.0193 (9)
C222	0.8146 (2)	0.31365 (15)	0.9988 (4)	0.0261 (10)
H222	0.8461	0.3407	1.0053	0.031*
C223	0.7847 (3)	0.29509 (17)	1.1061 (4)	0.0324 (12)
H223	0.7959	0.3096	1.1858	0.039*
C224	0.7386 (2)	0.25576 (17)	1.1004 (4)	0.0282 (11)
C225	0.7226 (2)	0.23623 (16)	0.9832 (4)	0.0262 (10)
H225	0.6903	0.2098	0.9772	0.031*
C226	0.7519 (2)	0.25401 (14)	0.8745 (4)	0.0220 (9)
H226	0.74	0.2397	0.7951	0.026*
C227	0.7078 (3)	0.23477 (18)	1.2196 (5)	0.0429 (14)
H22A	0.6613	0.2289	1.2052	0.064*
H22B	0.7135	0.2601	1.2882	0.064*
H22C	0.7286	0.2017	1.2429	0.064*
C231	0.9128 (2)	0.34194 (14)	0.7674 (4)	0.0169 (9)
C232	0.9544 (2)	0.31648 (15)	0.8494 (4)	0.0234 (10)
H232	0.9389	0.2882	0.8991	0.028*
C233	1.0181 (2)	0.33188 (15)	0.8592 (4)	0.0257 (10)
H233	1.0456	0.3145	0.9178	0.031*
C234	1.0436 (2)	0.37201 (16)	0.7864 (4)	0.0230 (10)
C235	1.0014 (2)	0.39762 (14)	0.7055 (4)	0.0245 (10)
H235	1.0171	0.4257	0.6554	0.029*
C236	0.9367 (2)	0.38319 (13)	0.6960 (4)	0.0203 (9)
H236	0.9086	0.4016	0.6404	0.024*
C237	1.1137 (2)	0.38566 (18)	0.7925 (5)	0.0342 (12)
H23A	1.1395	0.3572	0.7561	0.051*
H23B	1.1264	0.391	0.8808	0.051*
H23C	1.1215	0.4178	0.7446	0.051*
C311	0.56772 (17)	0.39657 (12)	0.6519 (4)	0.0166 (8)
C312	0.5208 (2)	0.41489 (14)	0.7348 (4)	0.0204 (9)
H312	0.5218	0.4043	0.8208	0.025*
C313	0.47228 (19)	0.44853 (13)	0.6938 (4)	0.0234 (10)
H313	0.4405	0.4606	0.752	0.028*
C314	0.4697 (2)	0.46476 (14)	0.5690 (4)	0.0244 (11)
C315	0.5170 (2)	0.44651 (15)	0.4874 (4)	0.0264 (10)
H315	0.516	0.4573	0.4016	0.032*
C316	0.56573 (19)	0.41311 (13)	0.5263 (5)	0.0222 (8)
H316	0.5977	0.4014	0.468	0.027*
C317	0.4182 (2)	0.50179 (15)	0.5246 (6)	0.0406 (12)
H31A	0.4322	0.5378	0.5402	0.061*
H31B	0.3777	0.495	0.5705	0.061*
H31C	0.4109	0.4968	0.4339	0.061*
C321	0.61573 (19)	0.29391 (13)	0.6154 (3)	0.0154 (8)
C322	0.5523 (2)	0.27694 (15)	0.5915 (4)	0.0198 (9)
H322	0.5165	0.2981	0.6161	0.024*
C323	0.5413 (2)	0.22942 (14)	0.5320 (4)	0.0243 (9)
H323	0.498	0.2183	0.5165	0.029*
C324	0.5926 (2)	0.19803 (14)	0.4950 (4)	0.0241 (10)
C325	0.6551 (2)	0.21497 (13)	0.5187 (4)	0.0231 (9)
H325	0.6906	0.1933	0.4956	0.028*
C326	0.6672 (2)	0.26251 (14)	0.5752 (4)	0.0193 (9)
H326	0.7107	0.2739	0.5868	0.023*
C327	0.5819 (3)	0.14704 (16)	0.4266 (4)	0.0393 (13)
H32A	0.5375	0.1347	0.442	0.059*
H32B	0.613	0.121	0.4575	0.059*
H32C	0.5883	0.1523	0.3357	0.059*
C331	0.6165 (2)	0.33917 (13)	0.8646 (4)	0.0171 (9)
C332	0.57429 (18)	0.29970 (14)	0.9029 (4)	0.0196 (8)
H332	0.5545	0.2777	0.8416	0.024*
C333	0.56095 (19)	0.29229 (13)	1.0304 (4)	0.0213 (8)
H333	0.5321	0.2652	1.055	0.026*
C334	0.5889 (2)	0.32374 (15)	1.1225 (4)	0.0206 (9)
C335	0.6322 (2)	0.36221 (16)	1.0834 (4)	0.0240 (10)
H335	0.6529	0.3836	1.1448	0.029*
C336	0.6459 (2)	0.36987 (15)	0.9569 (4)	0.0200 (9)
H336	0.6756	0.3964	0.9326	0.024*
C337	0.5730 (3)	0.31681 (19)	1.2600 (4)	0.0335 (12)
H33A	0.6126	0.321	1.3103	0.05*
H33B	0.555	0.2818	1.2736	0.05*
H33C	0.541	0.3431	1.2856	0.05*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
P1	0.0202 (5)	0.0131 (4)	0.0139 (5)	−0.0007 (4)	0.0020 (4)	−0.0009 (4)
P2	0.0202 (6)	0.0155 (4)	0.0139 (6)	0.0032 (4)	−0.0022 (5)	0.0003 (4)
P3	0.0182 (5)	0.0138 (4)	0.0136 (5)	0.0005 (4)	−0.0013 (4)	0.0005 (4)
Br1	0.0394 (3)	0.0242 (2)	0.0123 (2)	0.00296 (18)	−0.0013 (2)	0.00124 (18)
N01	0.043 (5)	0.050 (5)	0.011 (4)	−0.018 (4)	0.000 (4)	0.007 (3)
C02	0.062 (6)	0.119 (7)	0.091 (6)	0.033 (5)	0.020 (4)	0.016 (5)
Ag1	0.01949 (13)	0.01283 (10)	0.01371 (15)	0.00060 (12)	−0.00083 (13)	0.00019 (14)
C01	0.014 (4)	0.028 (4)	0.014 (5)	−0.005 (3)	0.003 (4)	0.002 (3)
C111	0.022 (2)	0.0150 (16)	0.011 (2)	−0.0021 (14)	0.0021 (17)	−0.0026 (14)
C112	0.023 (2)	0.0205 (18)	0.022 (2)	0.0021 (17)	0.0023 (18)	0.0028 (16)
C113	0.031 (2)	0.0200 (17)	0.021 (2)	0.0009 (16)	0.005 (2)	0.0081 (18)
C114	0.034 (2)	0.0196 (17)	0.015 (2)	0.0038 (16)	−0.007 (2)	−0.0055 (17)
C115	0.021 (3)	0.023 (2)	0.042 (3)	−0.0018 (18)	−0.010 (2)	−0.0017 (19)
C116	0.030 (2)	0.0188 (19)	0.035 (3)	−0.0064 (17)	−0.003 (2)	0.0014 (18)
C117	0.037 (3)	0.030 (2)	0.036 (3)	0.004 (2)	−0.007 (2)	0.0056 (19)
C121	0.022 (2)	0.0139 (15)	0.019 (2)	0.0006 (14)	0.004 (2)	0.0019 (17)
C122	0.025 (2)	0.024 (2)	0.022 (3)	0.0018 (17)	0.006 (2)	−0.0029 (17)
C123	0.021 (2)	0.0262 (19)	0.026 (3)	−0.0024 (16)	0.0048 (19)	−0.0017 (17)
C124	0.021 (2)	0.023 (2)	0.029 (3)	0.0036 (17)	0.0056 (19)	0.0084 (16)
C125	0.032 (3)	0.028 (2)	0.016 (2)	0.0057 (19)	0.0076 (19)	0.0033 (17)
C126	0.025 (2)	0.0193 (17)	0.019 (2)	0.0002 (15)	0.001 (2)	0.0005 (19)
C127	0.025 (2)	0.038 (2)	0.032 (3)	0.0012 (18)	0.008 (2)	0.006 (2)
C131	0.017 (2)	0.0201 (18)	0.013 (2)	−0.0015 (15)	0.0005 (17)	−0.0030 (15)
C132	0.020 (2)	0.0188 (18)	0.018 (2)	−0.0033 (17)	−0.0002 (19)	−0.0002 (16)
C133	0.021 (2)	0.027 (2)	0.019 (3)	−0.0015 (17)	−0.0020 (19)	0.0048 (17)
C134	0.0145 (19)	0.0295 (19)	0.012 (3)	−0.0041 (17)	0.0040 (18)	−0.0051 (16)
C135	0.027 (2)	0.0219 (16)	0.020 (2)	−0.0013 (16)	0.001 (2)	−0.004 (2)
C136	0.029 (2)	0.0217 (18)	0.015 (2)	−0.0012 (16)	0.002 (2)	0.0032 (17)
C137	0.038 (3)	0.041 (3)	0.017 (3)	−0.006 (2)	0.000 (2)	−0.0028 (19)
C211	0.015 (2)	0.0210 (18)	0.015 (2)	−0.0001 (15)	0.0013 (17)	−0.0023 (15)
C212	0.023 (2)	0.0215 (18)	0.020 (3)	0.0064 (15)	−0.0026 (19)	0.0025 (16)
C213	0.029 (3)	0.018 (2)	0.024 (3)	0.0044 (18)	−0.002 (2)	0.0014 (17)
C214	0.016 (2)	0.022 (2)	0.028 (3)	0.0022 (17)	0.0013 (19)	−0.0075 (18)
C215	0.031 (3)	0.032 (2)	0.010 (2)	0.0060 (18)	−0.003 (2)	−0.0014 (17)
C216	0.040 (3)	0.0213 (19)	0.013 (3)	0.0099 (18)	0.000 (2)	0.0017 (16)
C217	0.026 (3)	0.029 (2)	0.029 (3)	0.0054 (19)	0.002 (2)	−0.0083 (19)
C221	0.023 (2)	0.0166 (17)	0.018 (2)	0.0095 (15)	0.0005 (19)	0.0016 (16)
C222	0.042 (3)	0.0203 (19)	0.016 (3)	0.0085 (18)	−0.001 (2)	−0.0013 (15)
C223	0.048 (3)	0.033 (2)	0.016 (3)	0.019 (2)	0.000 (2)	0.0005 (18)
C224	0.034 (3)	0.030 (2)	0.021 (3)	0.019 (2)	0.008 (2)	0.0072 (18)
C225	0.025 (2)	0.028 (2)	0.026 (3)	0.0096 (19)	0.005 (2)	0.0100 (18)
C226	0.024 (2)	0.0202 (18)	0.022 (3)	0.0047 (17)	0.000 (2)	0.0009 (16)
C227	0.056 (4)	0.046 (3)	0.027 (3)	0.018 (3)	0.008 (3)	0.014 (2)
C231	0.020 (2)	0.0170 (19)	0.014 (2)	0.0012 (16)	−0.0008 (17)	−0.0030 (15)
C232	0.027 (3)	0.0160 (19)	0.027 (3)	0.0023 (17)	−0.006 (2)	0.0049 (17)
C233	0.024 (3)	0.026 (2)	0.027 (3)	0.0035 (18)	−0.008 (2)	0.0001 (18)
C234	0.020 (2)	0.024 (2)	0.026 (3)	0.0044 (17)	0.0008 (18)	−0.0070 (17)
C235	0.026 (2)	0.0205 (18)	0.027 (3)	0.0013 (16)	0.006 (2)	0.0013 (17)
C236	0.024 (2)	0.0168 (17)	0.020 (2)	0.0038 (16)	0.0011 (18)	0.0012 (16)
C237	0.026 (3)	0.035 (3)	0.042 (3)	−0.002 (2)	−0.002 (2)	−0.006 (2)
C311	0.0139 (18)	0.0115 (15)	0.024 (2)	−0.0019 (12)	−0.002 (2)	−0.0004 (18)
C312	0.021 (2)	0.0192 (19)	0.021 (2)	−0.0027 (16)	−0.0023 (19)	0.0008 (17)
C313	0.019 (2)	0.0164 (17)	0.035 (3)	0.0000 (15)	0.0039 (19)	−0.0014 (17)
C314	0.019 (2)	0.0120 (17)	0.042 (3)	−0.0035 (16)	−0.005 (2)	0.0010 (16)
C315	0.032 (3)	0.024 (2)	0.022 (3)	−0.0041 (18)	−0.011 (2)	0.0044 (16)
C316	0.025 (2)	0.0201 (17)	0.022 (2)	0.0013 (15)	−0.003 (2)	−0.004 (2)
C317	0.027 (3)	0.028 (2)	0.067 (4)	0.0056 (18)	−0.013 (3)	0.018 (3)
C321	0.021 (2)	0.0161 (17)	0.009 (2)	−0.0008 (15)	−0.0039 (16)	0.0040 (13)
C322	0.020 (2)	0.0204 (19)	0.019 (2)	−0.0038 (16)	−0.0012 (18)	0.0030 (16)
C323	0.028 (2)	0.0285 (19)	0.016 (2)	−0.0115 (16)	−0.002 (2)	−0.001 (2)
C324	0.042 (3)	0.0205 (19)	0.010 (2)	−0.0066 (18)	0.0031 (19)	−0.0004 (15)
C325	0.038 (3)	0.0163 (16)	0.015 (2)	0.0077 (16)	0.008 (2)	−0.0023 (17)
C326	0.027 (2)	0.0191 (19)	0.012 (2)	0.0006 (17)	0.0010 (18)	0.0051 (15)
C327	0.065 (4)	0.027 (2)	0.026 (3)	−0.014 (2)	0.007 (3)	−0.0135 (19)
C331	0.023 (2)	0.0161 (17)	0.012 (2)	0.0031 (15)	−0.0016 (17)	−0.0019 (15)
C332	0.021 (2)	0.0207 (18)	0.018 (2)	−0.0014 (15)	−0.002 (2)	−0.0007 (17)
C333	0.026 (2)	0.0204 (17)	0.017 (2)	−0.0006 (15)	0.004 (2)	0.0044 (19)
C334	0.023 (2)	0.0216 (19)	0.017 (3)	0.0076 (16)	0.0033 (18)	0.0006 (16)
C335	0.025 (3)	0.025 (2)	0.022 (3)	0.0011 (19)	−0.005 (2)	−0.0062 (17)
C336	0.023 (2)	0.0177 (18)	0.019 (3)	0.0010 (16)	0.0007 (18)	0.0021 (16)
C337	0.041 (3)	0.041 (3)	0.018 (3)	0.005 (2)	0.003 (2)	−0.006 (2)

Geometric parameters (Å, º)

P1—C121	1.820 (4)	C217—H21B	0.98
P1—C111	1.823 (4)	C217—H21C	0.98
P1—C131	1.832 (4)	C221—C222	1.393 (6)
P1—Ag1	2.5034 (9)	C221—C226	1.397 (5)
P2—C221	1.825 (4)	C222—C223	1.377 (6)
P2—C211	1.826 (4)	C222—H222	0.95
P2—C231	1.834 (4)	C223—C224	1.384 (7)
P2—Ag1	2.5261 (10)	C223—H223	0.95
P3—C321	1.818 (4)	C224—C225	1.378 (6)
P3—C311	1.826 (4)	C224—C227	1.511 (6)
P3—C331	1.829 (4)	C225—C226	1.376 (6)
P3—Ag1	2.5353 (11)	C225—H225	0.95
Br1—Ag1	2.7304 (5)	C226—H226	0.95
N01—C01	1.095 (9)	C227—H22A	0.98
C02—C01	1.492 (9)	C227—H22B	0.98
C02—H02A	0.98	C227—H22C	0.98
C02—H02B	0.98	C231—C232	1.382 (5)
C02—H02C	0.98	C231—C236	1.388 (5)
C111—C116	1.379 (5)	C232—C233	1.371 (6)
C111—C112	1.394 (5)	C232—H232	0.95
C112—C113	1.391 (5)	C233—C234	1.388 (6)
C112—H112	0.95	C233—H233	0.95
C113—C114	1.374 (6)	C234—C235	1.385 (6)
C113—H113	0.95	C234—C237	1.486 (6)
C114—C115	1.384 (5)	C235—C236	1.384 (6)
C114—C117	1.497 (5)	C235—H235	0.95
C115—C116	1.381 (6)	C236—H236	0.95
C115—H115	0.95	C237—H23A	0.98
C116—H116	0.95	C237—H23B	0.98
C117—H11A	0.98	C237—H23C	0.98
C117—H11B	0.98	C311—C312	1.386 (5)
C117—H11C	0.98	C311—C316	1.396 (6)
C121—C122	1.385 (6)	C312—C313	1.387 (5)
C121—C126	1.412 (6)	C312—H312	0.95
C122—C123	1.384 (6)	C313—C314	1.387 (6)
C122—H122	0.95	C313—H313	0.95
C123—C124	1.389 (6)	C314—C315	1.383 (6)
C123—H123	0.95	C314—C317	1.498 (6)
C124—C125	1.396 (6)	C315—C316	1.380 (5)
C124—C127	1.504 (6)	C315—H315	0.95
C125—C126	1.370 (6)	C316—H316	0.95
C125—H125	0.95	C317—H31A	0.98
C126—H126	0.95	C317—H31B	0.98
C127—H12A	0.98	C317—H31C	0.98
C127—H12B	0.98	C321—C326	1.395 (5)
C127—H12C	0.98	C321—C322	1.399 (5)
C131—C132	1.384 (5)	C322—C323	1.388 (5)
C131—C136	1.397 (5)	C322—H322	0.95
C132—C133	1.388 (5)	C323—C324	1.382 (6)
C132—H132	0.95	C323—H323	0.95
C133—C134	1.392 (5)	C324—C325	1.380 (6)
C133—H133	0.95	C324—C327	1.509 (5)
C134—C135	1.393 (6)	C325—C326	1.378 (5)
C134—C137	1.509 (6)	C325—H325	0.95
C135—C136	1.376 (6)	C326—H326	0.95
C135—H135	0.95	C327—H32A	0.98
C136—H136	0.95	C327—H32B	0.98
C137—H13A	0.98	C327—H32C	0.98
C137—H13B	0.98	C331—C336	1.391 (5)
C137—H13C	0.98	C331—C332	1.393 (5)
C211—C212	1.385 (5)	C332—C333	1.390 (6)
C211—C216	1.387 (6)	C332—H332	0.95
C212—C213	1.389 (5)	C333—C334	1.389 (6)
C212—H212	0.95	C333—H333	0.95
C213—C214	1.389 (5)	C334—C335	1.391 (6)
C213—H213	0.95	C334—C337	1.502 (6)
C214—C215	1.383 (6)	C335—C336	1.383 (6)
C214—C217	1.511 (5)	C335—H335	0.95
C215—C216	1.388 (5)	C336—H336	0.95
C215—H215	0.95	C337—H33A	0.98
C216—H216	0.95	C337—H33B	0.98
C217—H21A	0.98	C337—H33C	0.98
C121—P1—C111	102.41 (17)	C214—C217—H21C	109.5
C121—P1—C131	104.58 (19)	H21A—C217—H21C	109.5
C111—P1—C131	101.95 (17)	H21B—C217—H21C	109.5
C121—P1—Ag1	114.85 (12)	C222—C221—C226	118.1 (4)
C111—P1—Ag1	115.56 (12)	C222—C221—P2	122.5 (3)
C131—P1—Ag1	115.69 (12)	C226—C221—P2	118.7 (3)
C221—P2—C211	104.67 (17)	C223—C222—C221	120.5 (4)
C221—P2—C231	105.30 (19)	C223—C222—H222	119.7
C211—P2—C231	100.53 (17)	C221—C222—H222	119.7
C221—P2—Ag1	108.98 (12)	C222—C223—C224	121.4 (4)
C211—P2—Ag1	116.53 (13)	C222—C223—H223	119.3
C231—P2—Ag1	119.34 (13)	C224—C223—H223	119.3
C321—P3—C311	102.05 (17)	C225—C224—C223	117.9 (4)
C321—P3—C331	104.37 (17)	C225—C224—C227	121.5 (4)
C311—P3—C331	103.44 (19)	C223—C224—C227	120.6 (4)
C321—P3—Ag1	113.72 (14)	C226—C225—C224	121.8 (4)
C311—P3—Ag1	115.96 (12)	C226—C225—H225	119.1
C331—P3—Ag1	115.63 (13)	C224—C225—H225	119.1
C01—C02—H02A	109.5	C225—C226—C221	120.2 (4)
C01—C02—H02B	109.5	C225—C226—H226	119.9
H02A—C02—H02B	109.5	C221—C226—H226	119.9
C01—C02—H02C	109.5	C224—C227—H22A	109.5
H02A—C02—H02C	109.5	C224—C227—H22B	109.5
H02B—C02—H02C	109.5	H22A—C227—H22B	109.5
P1—Ag1—P2	115.87 (4)	C224—C227—H22C	109.5
P1—Ag1—P3	119.44 (3)	H22A—C227—H22C	109.5
P2—Ag1—P3	108.30 (3)	H22B—C227—H22C	109.5
P1—Ag1—Br1	101.59 (3)	C232—C231—C236	118.7 (4)
P2—Ag1—Br1	111.92 (3)	C232—C231—P2	124.7 (3)
P3—Ag1—Br1	97.88 (3)	C236—C231—P2	116.3 (3)
N01—C01—C02	178.3 (10)	C233—C232—C231	120.3 (4)
C116—C111—C112	118.4 (4)	C233—C232—H232	119.9
C116—C111—P1	118.5 (3)	C231—C232—H232	119.9
C112—C111—P1	122.9 (3)	C232—C233—C234	122.1 (4)
C113—C112—C111	120.0 (4)	C232—C233—H233	118.9
C113—C112—H112	120	C234—C233—H233	118.9
C111—C112—H112	120	C235—C234—C233	117.2 (4)
C114—C113—C112	121.4 (4)	C235—C234—C237	121.7 (4)
C114—C113—H113	119.3	C233—C234—C237	121.1 (4)
C112—C113—H113	119.3	C236—C235—C234	121.4 (4)
C113—C114—C115	118.2 (4)	C236—C235—H235	119.3
C113—C114—C117	120.4 (4)	C234—C235—H235	119.3
C115—C114—C117	121.4 (4)	C235—C236—C231	120.2 (4)
C116—C115—C114	121.0 (4)	C235—C236—H236	119.9
C116—C115—H115	119.5	C231—C236—H236	119.9
C114—C115—H115	119.5	C234—C237—H23A	109.5
C111—C116—C115	121.0 (4)	C234—C237—H23B	109.5
C111—C116—H116	119.5	H23A—C237—H23B	109.5
C115—C116—H116	119.5	C234—C237—H23C	109.5
C114—C117—H11A	109.5	H23A—C237—H23C	109.5
C114—C117—H11B	109.5	H23B—C237—H23C	109.5
H11A—C117—H11B	109.5	C312—C311—C316	118.7 (3)
C114—C117—H11C	109.5	C312—C311—P3	123.6 (3)
H11A—C117—H11C	109.5	C316—C311—P3	117.7 (3)
H11B—C117—H11C	109.5	C311—C312—C313	120.9 (4)
C122—C121—C126	117.3 (4)	C311—C312—H312	119.6
C122—C121—P1	123.8 (3)	C313—C312—H312	119.6
C126—C121—P1	118.9 (3)	C314—C313—C312	120.8 (4)
C123—C122—C121	121.5 (4)	C314—C313—H313	119.6
C123—C122—H122	119.2	C312—C313—H313	119.6
C121—C122—H122	119.2	C315—C314—C313	117.8 (4)
C122—C123—C124	120.8 (4)	C315—C314—C317	121.1 (4)
C122—C123—H123	119.6	C313—C314—C317	121.0 (4)
C124—C123—H123	119.6	C316—C315—C314	122.3 (4)
C123—C124—C125	118.1 (4)	C316—C315—H315	118.9
C123—C124—C127	120.7 (4)	C314—C315—H315	118.9
C125—C124—C127	121.2 (4)	C315—C316—C311	119.6 (4)
C126—C125—C124	121.1 (4)	C315—C316—H316	120.2
C126—C125—H125	119.5	C311—C316—H316	120.2
C124—C125—H125	119.5	C314—C317—H31A	109.5
C125—C126—C121	121.1 (4)	C314—C317—H31B	109.5
C125—C126—H126	119.4	H31A—C317—H31B	109.5
C121—C126—H126	119.4	C314—C317—H31C	109.5
C124—C127—H12A	109.5	H31A—C317—H31C	109.5
C124—C127—H12B	109.5	H31B—C317—H31C	109.5
H12A—C127—H12B	109.5	C326—C321—C322	118.3 (3)
C124—C127—H12C	109.5	C326—C321—P3	118.3 (3)
H12A—C127—H12C	109.5	C322—C321—P3	123.4 (3)
H12B—C127—H12C	109.5	C323—C322—C321	120.4 (4)
C132—C131—C136	118.1 (4)	C323—C322—H322	119.8
C132—C131—P1	119.1 (3)	C321—C322—H322	119.8
C136—C131—P1	122.7 (3)	C324—C323—C322	120.9 (4)
C131—C132—C133	121.0 (4)	C324—C323—H323	119.5
C131—C132—H132	119.5	C322—C323—H323	119.5
C133—C132—H132	119.5	C325—C324—C323	118.5 (3)
C132—C133—C134	121.0 (4)	C325—C324—C327	119.6 (4)
C132—C133—H133	119.5	C323—C324—C327	121.9 (4)
C134—C133—H133	119.5	C326—C325—C324	121.6 (4)
C133—C134—C135	117.5 (4)	C326—C325—H325	119.2
C133—C134—C137	121.7 (4)	C324—C325—H325	119.2
C135—C134—C137	120.7 (4)	C325—C326—C321	120.2 (4)
C136—C135—C134	121.6 (4)	C325—C326—H326	119.9
C136—C135—H135	119.2	C321—C326—H326	119.9
C134—C135—H135	119.2	C324—C327—H32A	109.5
C135—C136—C131	120.7 (4)	C324—C327—H32B	109.5
C135—C136—H136	119.7	H32A—C327—H32B	109.5
C131—C136—H136	119.7	C324—C327—H32C	109.5
C134—C137—H13A	109.5	H32A—C327—H32C	109.5
C134—C137—H13B	109.5	H32B—C327—H32C	109.5
H13A—C137—H13B	109.5	C336—C331—C332	118.4 (4)
C134—C137—H13C	109.5	C336—C331—P3	117.8 (3)
H13A—C137—H13C	109.5	C332—C331—P3	123.8 (3)
H13B—C137—H13C	109.5	C333—C332—C331	120.3 (4)
C212—C211—C216	119.0 (4)	C333—C332—H332	119.8
C212—C211—P2	122.7 (3)	C331—C332—H332	119.8
C216—C211—P2	118.2 (3)	C334—C333—C332	121.4 (4)
C211—C212—C213	120.1 (4)	C334—C333—H333	119.3
C211—C212—H212	119.9	C332—C333—H333	119.3
C213—C212—H212	119.9	C333—C334—C335	117.8 (4)
C214—C213—C212	121.3 (4)	C333—C334—C337	121.4 (4)
C214—C213—H213	119.4	C335—C334—C337	120.8 (4)
C212—C213—H213	119.4	C336—C335—C334	121.2 (4)
C215—C214—C213	118.1 (4)	C336—C335—H335	119.4
C215—C214—C217	120.4 (4)	C334—C335—H335	119.4
C213—C214—C217	121.6 (4)	C335—C336—C331	120.8 (4)
C214—C215—C216	121.1 (4)	C335—C336—H336	119.6
C214—C215—H215	119.4	C331—C336—H336	119.6
C216—C215—H215	119.4	C334—C337—H33A	109.5
C211—C216—C215	120.4 (4)	C334—C337—H33B	109.5
C211—C216—H216	119.8	H33A—C337—H33B	109.5
C215—C216—H216	119.8	C334—C337—H33C	109.5
C214—C217—H21A	109.5	H33A—C337—H33C	109.5
C214—C217—H21B	109.5	H33B—C337—H33C	109.5
H21A—C217—H21B	109.5
C121—P1—Ag1—P2	54.09 (16)	C213—C214—C215—C216	1.1 (7)
C111—P1—Ag1—P2	173.03 (14)	C217—C214—C215—C216	179.6 (4)
C131—P1—Ag1—P2	−67.97 (15)	C212—C211—C216—C215	0.0 (6)
C121—P1—Ag1—P3	−173.51 (15)	P2—C211—C216—C215	176.2 (3)
C111—P1—Ag1—P3	−54.56 (15)	C214—C215—C216—C211	−0.5 (7)
C131—P1—Ag1—P3	64.44 (15)	C211—P2—C221—C222	143.9 (3)
C121—P1—Ag1—Br1	−67.45 (15)	C231—P2—C221—C222	38.3 (4)
C111—P1—Ag1—Br1	51.49 (14)	Ag1—P2—C221—C222	−90.8 (3)
C131—P1—Ag1—Br1	170.49 (14)	C211—P2—C221—C226	−45.6 (3)
C221—P2—Ag1—P1	99.08 (14)	C231—P2—C221—C226	−151.1 (3)
C211—P2—Ag1—P1	−142.82 (14)	Ag1—P2—C221—C226	79.8 (3)
C231—P2—Ag1—P1	−21.82 (15)	C226—C221—C222—C223	1.2 (6)
C221—P2—Ag1—P3	−38.28 (14)	P2—C221—C222—C223	171.8 (3)
C211—P2—Ag1—P3	79.81 (14)	C221—C222—C223—C224	−0.1 (6)
C231—P2—Ag1—P3	−159.19 (14)	C222—C223—C224—C225	−1.2 (7)
C221—P2—Ag1—Br1	−145.07 (13)	C222—C223—C224—C227	178.1 (4)
C211—P2—Ag1—Br1	−26.98 (14)	C223—C224—C225—C226	1.4 (6)
C231—P2—Ag1—Br1	94.02 (15)	C227—C224—C225—C226	−177.9 (4)
C321—P3—Ag1—P1	161.70 (13)	C224—C225—C226—C221	−0.3 (6)
C311—P3—Ag1—P1	43.83 (17)	C222—C221—C226—C225	−1.0 (6)
C331—P3—Ag1—P1	−77.53 (13)	P2—C221—C226—C225	−172.0 (3)
C321—P3—Ag1—P2	−62.71 (14)	C221—P2—C231—C232	33.0 (4)
C311—P3—Ag1—P2	179.41 (16)	C211—P2—C231—C232	−75.5 (4)
C331—P3—Ag1—P2	58.06 (13)	Ag1—P2—C231—C232	155.7 (3)
C321—P3—Ag1—Br1	53.57 (13)	C221—P2—C231—C236	−153.0 (3)
C311—P3—Ag1—Br1	−64.30 (16)	C211—P2—C231—C236	98.5 (3)
C331—P3—Ag1—Br1	174.34 (13)	Ag1—P2—C231—C236	−30.2 (3)
C121—P1—C111—C116	167.7 (3)	C236—C231—C232—C233	−0.1 (6)
C131—P1—C111—C116	−84.2 (3)	P2—C231—C232—C233	173.8 (3)
Ag1—P1—C111—C116	42.1 (4)	C231—C232—C233—C234	−1.7 (6)
C121—P1—C111—C112	−16.9 (4)	C232—C233—C234—C235	2.3 (6)
C131—P1—C111—C112	91.2 (4)	C232—C233—C234—C237	−175.9 (4)
Ag1—P1—C111—C112	−142.5 (3)	C233—C234—C235—C236	−1.1 (6)
C116—C111—C112—C113	−0.4 (6)	C237—C234—C235—C236	177.1 (4)
P1—C111—C112—C113	−175.8 (3)	C234—C235—C236—C231	−0.6 (6)
C111—C112—C113—C114	1.0 (7)	C232—C231—C236—C235	1.2 (6)
C112—C113—C114—C115	−0.9 (7)	P2—C231—C236—C235	−173.2 (3)
C112—C113—C114—C117	178.3 (4)	C321—P3—C311—C312	113.9 (3)
C113—C114—C115—C116	0.2 (7)	C331—P3—C311—C312	5.8 (3)
C117—C114—C115—C116	−179.1 (4)	Ag1—P3—C311—C312	−121.9 (3)
C112—C111—C116—C115	−0.4 (6)	C321—P3—C311—C316	−68.9 (3)
P1—C111—C116—C115	175.2 (3)	C331—P3—C311—C316	−177.1 (3)
C114—C115—C116—C111	0.5 (7)	Ag1—P3—C311—C316	55.3 (3)
C111—P1—C121—C122	101.6 (3)	C316—C311—C312—C313	0.7 (5)
C131—P1—C121—C122	−4.5 (4)	P3—C311—C312—C313	177.9 (3)
Ag1—P1—C121—C122	−132.4 (3)	C311—C312—C313—C314	−0.2 (6)
C111—P1—C121—C126	−78.5 (3)	C312—C313—C314—C315	−0.2 (6)
C131—P1—C121—C126	175.5 (3)	C312—C313—C314—C317	−179.0 (4)
Ag1—P1—C121—C126	47.6 (3)	C313—C314—C315—C316	0.1 (6)
C126—C121—C122—C123	−1.2 (5)	C317—C314—C315—C316	178.9 (4)
P1—C121—C122—C123	178.8 (3)	C314—C315—C316—C311	0.4 (6)
C121—C122—C123—C124	0.5 (6)	C312—C311—C316—C315	−0.8 (5)
C122—C123—C124—C125	0.8 (6)	P3—C311—C316—C315	−178.1 (3)
C122—C123—C124—C127	−178.4 (4)	C311—P3—C321—C326	148.3 (3)
C123—C124—C125—C126	−1.2 (6)	C331—P3—C321—C326	−104.2 (3)
C127—C124—C125—C126	177.9 (4)	Ag1—P3—C321—C326	22.7 (3)
C124—C125—C126—C121	0.5 (6)	C311—P3—C321—C322	−33.1 (4)
C122—C121—C126—C125	0.7 (5)	C331—P3—C321—C322	74.3 (3)
P1—C121—C126—C125	−179.2 (3)	Ag1—P3—C321—C322	−158.8 (3)
C121—P1—C131—C132	−103.5 (3)	C326—C321—C322—C323	1.6 (6)
C111—P1—C131—C132	150.1 (3)	P3—C321—C322—C323	−177.0 (3)
Ag1—P1—C131—C132	23.8 (4)	C321—C322—C323—C324	−0.2 (6)
C121—P1—C131—C136	80.4 (4)	C322—C323—C324—C325	0.1 (6)
C111—P1—C131—C136	−26.0 (4)	C322—C323—C324—C327	−178.0 (4)
Ag1—P1—C131—C136	−152.2 (3)	C323—C324—C325—C326	−1.5 (6)
C136—C131—C132—C133	1.9 (6)	C327—C324—C325—C326	176.6 (4)
P1—C131—C132—C133	−174.4 (3)	C324—C325—C326—C321	3.0 (6)
C131—C132—C133—C134	0.3 (7)	C322—C321—C326—C325	−2.9 (5)
C132—C133—C134—C135	−2.4 (7)	P3—C321—C326—C325	175.7 (3)
C132—C133—C134—C137	175.1 (4)	C321—P3—C331—C336	158.6 (3)
C133—C134—C135—C136	2.5 (6)	C311—P3—C331—C336	−95.0 (3)
C137—C134—C135—C136	−175.0 (4)	Ag1—P3—C331—C336	32.9 (3)
C134—C135—C136—C131	−0.4 (6)	C321—P3—C331—C332	−22.6 (4)
C132—C131—C136—C135	−1.8 (6)	C311—P3—C331—C332	83.8 (3)
P1—C131—C136—C135	174.3 (3)	Ag1—P3—C331—C332	−148.3 (3)
C221—P2—C211—C212	−34.3 (4)	C336—C331—C332—C333	1.5 (6)
C231—P2—C211—C212	74.8 (4)	P3—C331—C332—C333	−177.3 (3)
Ag1—P2—C211—C212	−154.7 (3)	C331—C332—C333—C334	0.1 (6)
C221—P2—C211—C216	149.7 (3)	C332—C333—C334—C335	−1.7 (6)
C231—P2—C211—C216	−101.3 (3)	C332—C333—C334—C337	178.2 (4)
Ag1—P2—C211—C216	29.3 (4)	C333—C334—C335—C336	1.6 (6)
C216—C211—C212—C213	−0.2 (6)	C337—C334—C335—C336	−178.2 (4)
P2—C211—C212—C213	−176.2 (3)	C334—C335—C336—C331	−0.1 (7)
C211—C212—C213—C214	0.9 (7)	C332—C331—C336—C335	−1.5 (6)
C212—C213—C214—C215	−1.3 (7)	P3—C331—C336—C335	177.3 (3)
C212—C213—C214—C217	−179.7 (4)

(II)

Crystal data

2(C64H63AgNP3S)·O	Dx = 1.302 Mg m^−3
Mr = 2174.02	Mo Kα radiation, λ = 0.71069 Å
Orthorhombic, Pna21	Cell parameters from 9550 reflections
a = 20.134 (5) Å	θ = 1.3–28.3°
b = 25.8990 (6) Å	µ = 0.53 mm^−1
c = 10.6360 (2) Å	T = 100 K
V = 5546.1 (14) Å^3	Cuboid, colourless
Z = 2	0.36 × 0.16 × 0.13 mm
F(000) = 2264

Data collection

Bruker X8 ApexII 4K Kappa CCD diffractometer	11753 reflections with I > 2σ(I)
ω and φ scans	Rint = 0.051
Absorption correction: multi-scan SADABS (Bruker, 2004)	θmax = 28.3°, θmin = 1.3°
Tmin = 0.832, Tmax = 0.934	h = −26→26
77821 measured reflections	k = −34→34
13669 independent reflections	l = −13→14

Refinement

Refinement on F^2	H-atom parameters constrained
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0342P)^2 + 0.7575P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.034	(Δ/σ)max = 0.003
wR(F^2) = 0.074	Δρmax = 0.75 e Å^−3
S = 1.04	Δρmin = −0.55 e Å^−3
13669 reflections	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
649 parameters	Absolute structure parameter: −0.029 (14)
1 restraint

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.82666 (15)	0.38881 (9)	−0.2726 (2)	0.0225 (6)
C111	0.72597 (12)	0.52851 (9)	0.0076 (2)	0.0151 (5)
C112	0.74924 (13)	0.57576 (10)	−0.0376 (3)	0.0199 (6)
H112	0.7955	0.5829	−0.0366	0.024*
C113	0.70515 (15)	0.61235 (9)	−0.0839 (2)	0.0229 (6)
H113	0.7219	0.6443	−0.1144	0.028*
C114	0.63778 (14)	0.60352 (10)	−0.0867 (2)	0.0223 (6)
C115	0.61492 (14)	0.55643 (10)	−0.0423 (3)	0.0273 (6)
H115	0.5686	0.5494	−0.0437	0.033*
C116	0.65796 (13)	0.51948 (10)	0.0039 (3)	0.0223 (6)
H116	0.6409	0.4875	0.0335	0.027*
C117	0.59034 (16)	0.64380 (11)	−0.1362 (3)	0.0343 (7)
H11A	0.6068	0.6783	−0.1144	0.051*
H11B	0.5464	0.6386	−0.0986	0.051*
H11C	0.587	0.6407	−0.2279	0.051*
C121	0.77218 (12)	0.49609 (9)	0.2455 (2)	0.0160 (5)
C122	0.77769 (13)	0.45696 (10)	0.3349 (2)	0.0165 (5)
H122	0.7891	0.423	0.3086	0.02*
C123	0.76686 (13)	0.46661 (11)	0.4617 (2)	0.0200 (6)
H123	0.7705	0.4392	0.5207	0.024*
C124	0.75077 (12)	0.51614 (11)	0.5034 (2)	0.0198 (6)
C125	0.74790 (13)	0.55560 (11)	0.4149 (3)	0.0235 (6)
H125	0.7387	0.5898	0.4418	0.028*
C126	0.75820 (12)	0.54602 (10)	0.2882 (2)	0.0197 (6)
H126	0.7557	0.5737	0.2297	0.024*
C127	0.73460 (15)	0.52616 (13)	0.6395 (2)	0.0293 (7)
H12A	0.6947	0.5068	0.663	0.044*
H12B	0.7267	0.5631	0.652	0.044*
H12C	0.7719	0.5151	0.6922	0.044*
C131	0.86211 (11)	0.50318 (8)	0.0351 (2)	0.0144 (5)
C132	0.90536 (13)	0.52863 (9)	0.1158 (2)	0.0178 (5)
H132	0.8926	0.5344	0.2007	0.021*
C133	0.96691 (12)	0.54569 (9)	0.0744 (2)	0.0182 (5)
H133	0.9957	0.563	0.1312	0.022*
C134	0.98702 (13)	0.53785 (10)	−0.0493 (2)	0.0178 (5)
C135	0.94334 (13)	0.51229 (9)	−0.1308 (2)	0.0198 (5)
H135	0.9561	0.5066	−0.2157	0.024*
C136	0.88235 (12)	0.49525 (9)	−0.0901 (2)	0.0178 (5)
H136	0.8536	0.4779	−0.147	0.021*
C137	1.05404 (13)	0.55513 (11)	−0.0941 (3)	0.0285 (6)
H13A	1.0758	0.5753	−0.0279	0.043*
H13B	1.0489	0.5765	−0.1695	0.043*
H13C	1.0812	0.5249	−0.1141	0.043*
C211	0.92000 (13)	0.34120 (9)	0.1298 (2)	0.0162 (5)
C212	0.96510 (13)	0.31515 (10)	0.2066 (2)	0.0226 (6)
H212	0.9511	0.2858	0.2529	0.027*
C213	1.03002 (13)	0.33189 (10)	0.2156 (3)	0.0234 (6)
H213	1.0599	0.3141	0.2695	0.028*
C214	1.05247 (14)	0.37383 (11)	0.1481 (2)	0.0223 (6)
C215	1.00779 (13)	0.39982 (10)	0.0718 (3)	0.0226 (6)
H215	1.0223	0.429	0.0251	0.027*
C216	0.94244 (13)	0.38387 (9)	0.0629 (2)	0.0190 (6)
H216	0.9125	0.4023	0.0104	0.023*
C217	1.12462 (14)	0.39040 (11)	0.1567 (3)	0.0296 (7)
H21A	1.1363	0.3965	0.2449	0.044*
H21B	1.1311	0.4223	0.1085	0.044*
H21C	1.1531	0.3632	0.1222	0.044*
C221	0.80568 (12)	0.29368 (9)	0.2505 (2)	0.0162 (5)
C222	0.82792 (13)	0.31205 (9)	0.3667 (2)	0.0195 (5)
H222	0.8625	0.337	0.3699	0.023*
C223	0.79976 (14)	0.29406 (10)	0.4775 (2)	0.0231 (6)
H223	0.8155	0.3069	0.5557	0.028*
C224	0.74910 (13)	0.25770 (11)	0.4768 (3)	0.0220 (6)
C225	0.72542 (13)	0.24073 (10)	0.3611 (2)	0.0192 (5)
H225	0.6895	0.217	0.3584	0.023*
C226	0.75344 (12)	0.25799 (10)	0.2493 (2)	0.0183 (5)
H226	0.737	0.2455	0.1713	0.022*
C227	0.72026 (16)	0.23703 (12)	0.5970 (3)	0.0325 (7)
H22A	0.6732	0.229	0.5844	0.049*
H22B	0.7247	0.263	0.6634	0.049*
H22C	0.7441	0.2056	0.6215	0.049*
C231	0.84905 (11)	0.26322 (9)	0.0028 (2)	0.0154 (5)
C232	0.85843 (13)	0.21346 (9)	0.0481 (2)	0.0218 (6)
H232	0.8564	0.2071	0.136	0.026*
C233	0.87080 (14)	0.17288 (10)	−0.0344 (2)	0.0227 (6)
H233	0.8765	0.139	−0.002	0.027*
C234	0.87502 (13)	0.18112 (10)	−0.1642 (2)	0.0204 (6)
C235	0.86686 (14)	0.23114 (11)	−0.2074 (2)	0.0251 (6)
H235	0.8705	0.2379	−0.2949	0.03*
C236	0.85353 (13)	0.27152 (10)	−0.1261 (2)	0.0218 (6)
H236	0.8474	0.3053	−0.1587	0.026*
C237	0.88761 (15)	0.13749 (11)	−0.2540 (3)	0.0300 (7)
H23A	0.8619	0.143	−0.331	0.045*
H23B	0.8741	0.1048	−0.2149	0.045*
H23C	0.935	0.1361	−0.2745	0.045*
C311	0.56914 (12)	0.39578 (8)	0.0072 (3)	0.0164 (5)
C312	0.51979 (13)	0.41423 (9)	0.0865 (3)	0.0215 (6)
H312	0.5183	0.403	0.1715	0.026*
C313	0.47240 (12)	0.44910 (9)	0.0428 (3)	0.0260 (6)
H313	0.439	0.4613	0.0985	0.031*
C314	0.47316 (13)	0.46629 (10)	−0.0807 (3)	0.0253 (6)
C315	0.52222 (14)	0.44719 (10)	−0.1604 (3)	0.0258 (6)
H315	0.523	0.458	−0.2457	0.031*
C316	0.56972 (13)	0.41285 (9)	−0.1179 (2)	0.0211 (6)
H316	0.603	0.4007	−0.1739	0.025*
C317	0.42261 (15)	0.50488 (11)	−0.1269 (3)	0.0375 (8)
H31A	0.3845	0.5053	−0.0696	0.056*
H31B	0.4078	0.4951	−0.2114	0.056*
H31C	0.4428	0.5393	−0.1297	0.056*
C321	0.61768 (12)	0.29358 (9)	−0.0258 (2)	0.0138 (5)
C322	0.55334 (12)	0.27673 (10)	−0.0515 (2)	0.0186 (5)
H322	0.5165	0.298	−0.0303	0.022*
C323	0.54268 (14)	0.22885 (10)	−0.1080 (2)	0.0230 (6)
H323	0.4985	0.218	−0.1251	0.028*
C324	0.59522 (14)	0.19693 (10)	−0.1395 (2)	0.0227 (6)
C325	0.65988 (13)	0.21378 (10)	−0.1143 (2)	0.0207 (6)
H325	0.6966	0.1922	−0.1343	0.025*
C326	0.67059 (13)	0.26162 (9)	−0.0604 (2)	0.0166 (5)
H326	0.7148	0.273	−0.0465	0.02*
C327	0.58443 (17)	0.14573 (11)	−0.2035 (3)	0.0375 (8)
H32A	0.5368	0.1381	−0.2065	0.056*
H32B	0.6074	0.1185	−0.1564	0.056*
H32C	0.6021	0.1472	−0.2893	0.056*
C331	0.61564 (12)	0.33890 (9)	0.2214 (2)	0.0141 (5)
C332	0.57251 (12)	0.30001 (10)	0.2582 (2)	0.0185 (5)
H332	0.5521	0.2788	0.1964	0.022*
C333	0.55887 (13)	0.29172 (10)	0.3855 (2)	0.0223 (6)
H333	0.5289	0.2651	0.4092	0.027*
C334	0.58834 (13)	0.32177 (10)	0.4774 (2)	0.0211 (6)
C335	0.63181 (14)	0.36022 (10)	0.4403 (2)	0.0233 (6)
H335	0.6525	0.3812	0.5022	0.028*
C336	0.64564 (13)	0.36863 (10)	0.3149 (2)	0.0205 (6)
H336	0.676	0.395	0.2919	0.025*
C337	0.57194 (16)	0.31345 (12)	0.6150 (3)	0.0318 (7)
H33A	0.6121	0.3183	0.6657	0.048*
H33B	0.5551	0.2783	0.627	0.048*
H33C	0.538	0.3383	0.6412	0.048*
N1	0.88128 (14)	0.38966 (10)	−0.3059 (2)	0.0366 (7)
P1	0.77988 (3)	0.48013 (2)	0.07936 (6)	0.01335 (13)
P2	0.83497 (3)	0.32014 (2)	0.10202 (6)	0.01494 (13)
P3	0.63627 (3)	0.35311 (2)	0.05782 (5)	0.01406 (13)
S2	0.74797 (3)	0.38711 (3)	−0.22632 (7)	0.02514 (16)
Ag1	0.753625 (8)	0.387431 (6)	0.02367 (2)	0.01341 (4)
O1	0.4774 (2)	0.18288 (18)	0.5551 (5)	0.0559 (13)	0.5

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.0368 (18)	0.0178 (14)	0.0130 (13)	−0.0061 (12)	−0.0017 (11)	0.0035 (10)
C111	0.0178 (12)	0.0154 (11)	0.0122 (12)	−0.0003 (9)	−0.0004 (10)	−0.0001 (10)
C112	0.0202 (15)	0.0157 (13)	0.0238 (14)	−0.0024 (11)	0.0011 (10)	0.0016 (11)
C113	0.0337 (17)	0.0159 (13)	0.0192 (14)	0.0001 (11)	0.0029 (11)	0.0038 (10)
C114	0.0265 (15)	0.0225 (14)	0.0181 (14)	0.0061 (11)	−0.0046 (11)	−0.0021 (10)
C115	0.0188 (15)	0.0258 (15)	0.0372 (16)	−0.0018 (12)	−0.0056 (12)	−0.0010 (12)
C116	0.0214 (13)	0.0151 (12)	0.0304 (16)	−0.0042 (10)	−0.0036 (11)	−0.0002 (11)
C117	0.0336 (19)	0.0292 (16)	0.0400 (18)	0.0098 (14)	−0.0084 (14)	0.0053 (13)
C121	0.0139 (12)	0.0185 (13)	0.0156 (12)	−0.0021 (10)	0.0015 (10)	−0.0023 (10)
C122	0.0135 (13)	0.0180 (13)	0.0181 (13)	−0.0016 (10)	−0.0010 (10)	0.0023 (10)
C123	0.0171 (13)	0.0236 (15)	0.0193 (13)	−0.0013 (11)	−0.0026 (10)	0.0043 (11)
C124	0.0157 (12)	0.0307 (14)	0.0131 (17)	−0.0067 (11)	−0.0001 (10)	−0.0036 (11)
C125	0.0256 (15)	0.0213 (14)	0.0237 (16)	0.0002 (12)	0.0008 (11)	−0.0073 (12)
C126	0.0229 (15)	0.0176 (13)	0.0187 (14)	−0.0028 (11)	0.0002 (10)	−0.0004 (10)
C127	0.0295 (17)	0.042 (2)	0.0166 (15)	−0.0070 (14)	0.0022 (11)	−0.0036 (12)
C131	0.0145 (11)	0.0102 (10)	0.0185 (13)	−0.0008 (8)	−0.0005 (11)	0.0027 (10)
C132	0.0215 (14)	0.0151 (12)	0.0169 (12)	−0.0003 (10)	0.0017 (10)	−0.0026 (10)
C133	0.0157 (13)	0.0188 (13)	0.0202 (13)	−0.0037 (10)	−0.0029 (10)	−0.0022 (10)
C134	0.0165 (14)	0.0208 (13)	0.0163 (13)	0.0007 (11)	0.0023 (10)	0.0017 (10)
C135	0.0197 (14)	0.0216 (13)	0.0181 (13)	0.0016 (11)	0.0022 (10)	0.0009 (10)
C136	0.0196 (14)	0.0162 (12)	0.0177 (13)	−0.0018 (10)	−0.0016 (10)	−0.0020 (10)
C137	0.0211 (15)	0.0384 (17)	0.0259 (15)	−0.0073 (13)	0.0034 (12)	−0.0025 (13)
C211	0.0157 (13)	0.0143 (12)	0.0186 (13)	0.0018 (10)	0.0006 (10)	−0.0023 (9)
C212	0.0209 (15)	0.0198 (14)	0.0271 (15)	0.0007 (11)	−0.0025 (11)	0.0051 (11)
C213	0.0188 (14)	0.0229 (14)	0.0284 (15)	0.0023 (12)	−0.0052 (11)	0.0017 (11)
C214	0.0179 (14)	0.0209 (14)	0.0282 (15)	−0.0003 (11)	0.0022 (11)	−0.0095 (11)
C215	0.0222 (14)	0.0168 (13)	0.0289 (14)	−0.0025 (11)	0.0036 (11)	0.0017 (11)
C216	0.0182 (13)	0.0144 (12)	0.0243 (15)	0.0030 (10)	−0.0006 (10)	0.0020 (10)
C217	0.0176 (16)	0.0324 (18)	0.0388 (18)	−0.0028 (12)	0.0024 (12)	−0.0051 (13)
C221	0.0162 (13)	0.0166 (13)	0.0158 (12)	0.0038 (10)	−0.0012 (10)	0.0021 (9)
C222	0.0223 (14)	0.0161 (13)	0.0202 (14)	0.0035 (11)	−0.0017 (10)	−0.0033 (10)
C223	0.0282 (16)	0.0238 (14)	0.0173 (13)	0.0057 (12)	−0.0013 (10)	−0.0028 (10)
C224	0.0240 (15)	0.0222 (15)	0.0197 (13)	0.0101 (12)	0.0039 (10)	0.0016 (10)
C225	0.0166 (13)	0.0176 (13)	0.0233 (14)	0.0023 (11)	0.0013 (11)	0.0056 (10)
C226	0.0181 (14)	0.0183 (13)	0.0185 (14)	0.0047 (10)	−0.0029 (10)	0.0009 (10)
C227	0.0353 (18)	0.0426 (18)	0.0197 (15)	0.0053 (15)	0.0066 (13)	0.0074 (13)
C231	0.0116 (11)	0.0166 (12)	0.0181 (14)	0.0001 (9)	0.0009 (9)	−0.0020 (10)
C232	0.0241 (14)	0.0212 (13)	0.0201 (14)	0.0016 (11)	−0.0015 (10)	0.0002 (10)
C233	0.0270 (16)	0.0137 (13)	0.0275 (15)	0.0030 (11)	0.0016 (12)	0.0001 (10)
C234	0.0155 (14)	0.0209 (14)	0.0248 (14)	0.0030 (11)	−0.0030 (10)	−0.0051 (11)
C235	0.0289 (17)	0.0298 (16)	0.0166 (13)	0.0039 (12)	0.0011 (11)	0.0026 (11)
C236	0.0291 (16)	0.0180 (13)	0.0183 (14)	0.0063 (11)	0.0026 (11)	0.0028 (10)
C237	0.0297 (17)	0.0309 (16)	0.0293 (16)	0.0031 (13)	0.0013 (13)	−0.0082 (13)
C311	0.0133 (11)	0.0120 (11)	0.0239 (15)	−0.0028 (9)	−0.0028 (11)	−0.0005 (11)
C312	0.0196 (14)	0.0183 (13)	0.0267 (14)	−0.0018 (11)	0.0001 (11)	−0.0014 (11)
C313	0.0170 (13)	0.0174 (13)	0.0435 (19)	0.0027 (10)	0.0024 (12)	−0.0002 (12)
C314	0.0175 (14)	0.0170 (13)	0.0414 (17)	0.0002 (11)	−0.0058 (12)	0.0051 (12)
C315	0.0271 (16)	0.0245 (15)	0.0257 (15)	0.0012 (12)	−0.0092 (12)	0.0050 (11)
C316	0.0221 (14)	0.0200 (13)	0.0213 (14)	0.0003 (11)	−0.0034 (11)	−0.0008 (11)
C317	0.0274 (17)	0.0265 (16)	0.059 (2)	0.0014 (13)	−0.0056 (15)	0.0129 (15)
C321	0.0157 (13)	0.0140 (12)	0.0119 (11)	−0.0015 (10)	0.0003 (9)	0.0011 (9)
C322	0.0132 (13)	0.0224 (14)	0.0202 (13)	−0.0008 (11)	−0.0005 (10)	−0.0003 (10)
C323	0.0226 (14)	0.0288 (14)	0.0176 (13)	−0.0101 (12)	0.0012 (11)	−0.0020 (11)
C324	0.0335 (17)	0.0198 (14)	0.0149 (13)	−0.0081 (12)	0.0048 (11)	−0.0029 (10)
C325	0.0275 (15)	0.0204 (13)	0.0142 (13)	0.0030 (11)	0.0053 (11)	−0.0002 (10)
C326	0.0163 (13)	0.0214 (13)	0.0120 (12)	−0.0014 (11)	−0.0003 (9)	0.0018 (9)
C327	0.046 (2)	0.0283 (17)	0.0378 (19)	−0.0133 (15)	0.0094 (15)	−0.0153 (13)
C331	0.0122 (12)	0.0155 (12)	0.0148 (12)	0.0028 (10)	−0.0003 (9)	−0.0010 (9)
C332	0.0191 (14)	0.0211 (14)	0.0153 (13)	−0.0016 (11)	−0.0023 (10)	−0.0032 (10)
C333	0.0215 (15)	0.0234 (14)	0.0219 (14)	0.0009 (11)	0.0035 (11)	0.0007 (11)
C334	0.0198 (15)	0.0251 (14)	0.0185 (13)	0.0086 (12)	0.0013 (10)	−0.0012 (10)
C335	0.0281 (16)	0.0216 (14)	0.0203 (14)	0.0035 (12)	−0.0044 (11)	−0.0074 (11)
C336	0.0201 (14)	0.0200 (14)	0.0212 (14)	−0.0010 (11)	−0.0024 (10)	−0.0021 (11)
C337	0.0340 (18)	0.0415 (18)	0.0198 (15)	0.0062 (14)	0.0017 (13)	−0.0032 (12)
N1	0.0367 (17)	0.0470 (17)	0.0262 (14)	−0.0089 (13)	0.0059 (12)	0.0056 (11)
P1	0.0145 (3)	0.0119 (3)	0.0136 (3)	−0.0006 (3)	0.0002 (2)	0.0001 (2)
P2	0.0151 (3)	0.0138 (3)	0.0159 (3)	0.0014 (3)	−0.0013 (2)	0.0002 (2)
P3	0.0134 (3)	0.0137 (3)	0.0151 (3)	−0.0007 (2)	−0.0003 (2)	−0.0007 (2)
S2	0.0269 (4)	0.0354 (4)	0.0131 (3)	0.0023 (3)	−0.0014 (3)	0.0012 (3)
Ag1	0.01428 (8)	0.01216 (8)	0.01380 (8)	−0.00035 (7)	−0.00021 (8)	−0.00003 (8)
O1	0.052 (3)	0.059 (3)	0.057 (3)	−0.015 (2)	−0.010 (2)	0.015 (2)

Geometric parameters (Å, º)

C1—N1	1.155 (4)	C225—C226	1.390 (4)
C1—S2	1.660 (3)	C225—H225	0.95
C111—C116	1.390 (3)	C226—H226	0.95
C111—C112	1.396 (3)	C227—H22A	0.98
C111—P1	1.825 (2)	C227—H22B	0.98
C112—C113	1.389 (4)	C227—H22C	0.98
C112—H112	0.95	C231—C232	1.389 (3)
C113—C114	1.376 (4)	C231—C236	1.391 (3)
C113—H113	0.95	C231—P2	1.835 (2)
C114—C115	1.386 (4)	C232—C233	1.392 (3)
C114—C117	1.510 (4)	C232—H232	0.95
C115—C116	1.381 (4)	C233—C234	1.400 (4)
C115—H115	0.95	C233—H233	0.95
C116—H116	0.95	C234—C235	1.384 (4)
C117—H11A	0.98	C234—C237	1.501 (4)
C117—H11B	0.98	C235—C236	1.383 (4)
C117—H11C	0.98	C235—H235	0.95
C121—C122	1.394 (3)	C236—H236	0.95
C121—C126	1.399 (3)	C237—H23A	0.98
C121—P1	1.821 (2)	C237—H23B	0.98
C122—C123	1.389 (3)	C237—H23C	0.98
C122—H122	0.95	C311—C312	1.388 (4)
C123—C124	1.396 (4)	C311—C316	1.402 (4)
C123—H123	0.95	C311—P3	1.827 (2)
C124—C125	1.391 (4)	C312—C313	1.394 (3)
C124—C127	1.507 (4)	C312—H312	0.95
C125—C126	1.386 (4)	C313—C314	1.387 (4)
C125—H125	0.95	C313—H313	0.95
C126—H126	0.95	C314—C315	1.392 (4)
C127—H12A	0.98	C314—C317	1.509 (4)
C127—H12B	0.98	C315—C316	1.382 (4)
C127—H12C	0.98	C315—H315	0.95
C131—C132	1.390 (3)	C316—H316	0.95
C131—C136	1.407 (4)	C317—H31A	0.98
C131—P1	1.822 (2)	C317—H31B	0.98
C132—C133	1.388 (3)	C317—H31C	0.98
C132—H132	0.95	C321—C322	1.394 (3)
C133—C134	1.391 (3)	C321—C326	1.398 (3)
C133—H133	0.95	C321—P3	1.819 (2)
C134—C135	1.401 (4)	C322—C323	1.394 (4)
C134—C137	1.500 (4)	C322—H322	0.95
C135—C136	1.375 (3)	C323—C324	1.384 (4)
C135—H135	0.95	C323—H323	0.95
C136—H136	0.95	C324—C325	1.399 (4)
C137—H13A	0.98	C324—C327	1.506 (4)
C137—H13B	0.98	C325—C326	1.382 (3)
C137—H13C	0.98	C325—H325	0.95
C211—C216	1.390 (3)	C326—H326	0.95
C211—C212	1.396 (3)	C327—H32A	0.98
C211—P2	1.821 (3)	C327—H32B	0.98
C212—C213	1.380 (4)	C327—H32C	0.98
C212—H212	0.95	C331—C332	1.386 (3)
C213—C214	1.379 (4)	C331—C336	1.395 (3)
C213—H213	0.95	C331—P3	1.827 (2)
C214—C215	1.386 (4)	C332—C333	1.399 (4)
C214—C217	1.517 (4)	C332—H332	0.95
C215—C216	1.382 (4)	C333—C334	1.383 (4)
C215—H215	0.95	C333—H333	0.95
C216—H216	0.95	C334—C335	1.383 (4)
C217—H21A	0.98	C334—C337	1.516 (4)
C217—H21B	0.98	C335—C336	1.379 (4)
C217—H21C	0.98	C335—H335	0.95
C221—C222	1.399 (3)	C336—H336	0.95
C221—C226	1.400 (3)	C337—H33A	0.98
C221—P2	1.819 (2)	C337—H33B	0.98
C222—C223	1.388 (4)	C337—H33C	0.98
C222—H222	0.95	P1—Ag1	2.5287 (6)
C223—C224	1.388 (4)	P2—Ag1	2.5325 (7)
C223—H223	0.95	P3—Ag1	2.5504 (8)
C224—C225	1.391 (4)	S2—Ag1	2.6613 (7)
C224—C227	1.502 (4)
N1—C1—S2	179.3 (3)	C232—C231—C236	118.4 (2)
C116—C111—C112	118.0 (2)	C232—C231—P2	124.57 (18)
C116—C111—P1	118.82 (18)	C236—C231—P2	116.91 (18)
C112—C111—P1	123.11 (19)	C231—C232—C233	120.4 (2)
C113—C112—C111	120.4 (2)	C231—C232—H232	119.8
C113—C112—H112	119.8	C233—C232—H232	119.8
C111—C112—H112	119.8	C232—C233—C234	121.2 (2)
C114—C113—C112	121.6 (2)	C232—C233—H233	119.4
C114—C113—H113	119.2	C234—C233—H233	119.4
C112—C113—H113	119.2	C235—C234—C233	117.6 (2)
C113—C114—C115	117.8 (2)	C235—C234—C237	120.9 (2)
C113—C114—C117	121.1 (2)	C233—C234—C237	121.5 (2)
C115—C114—C117	121.1 (3)	C236—C235—C234	121.6 (2)
C116—C115—C114	121.5 (3)	C236—C235—H235	119.2
C116—C115—H115	119.3	C234—C235—H235	119.2
C114—C115—H115	119.3	C235—C236—C231	120.8 (2)
C115—C116—C111	120.8 (2)	C235—C236—H236	119.6
C115—C116—H116	119.6	C231—C236—H236	119.6
C111—C116—H116	119.6	C234—C237—H23A	109.5
C114—C117—H11A	109.5	C234—C237—H23B	109.5
C114—C117—H11B	109.5	H23A—C237—H23B	109.5
H11A—C117—H11B	109.5	C234—C237—H23C	109.5
C114—C117—H11C	109.5	H23A—C237—H23C	109.5
H11A—C117—H11C	109.5	H23B—C237—H23C	109.5
H11B—C117—H11C	109.5	C312—C311—C316	118.3 (2)
C122—C121—C126	117.8 (2)	C312—C311—P3	123.9 (2)
C122—C121—P1	119.36 (19)	C316—C311—P3	117.67 (19)
C126—C121—P1	122.82 (19)	C311—C312—C313	120.7 (3)
C123—C122—C121	121.3 (2)	C311—C312—H312	119.7
C123—C122—H122	119.4	C313—C312—H312	119.7
C121—C122—H122	119.4	C314—C313—C312	121.1 (3)
C122—C123—C124	120.7 (2)	C314—C313—H313	119.5
C122—C123—H123	119.7	C312—C313—H313	119.5
C124—C123—H123	119.7	C313—C314—C315	118.1 (2)
C125—C124—C123	118.0 (2)	C313—C314—C317	120.9 (3)
C125—C124—C127	121.0 (3)	C315—C314—C317	121.0 (3)
C123—C124—C127	120.9 (3)	C316—C315—C314	121.4 (3)
C126—C125—C124	121.4 (3)	C316—C315—H315	119.3
C126—C125—H125	119.3	C314—C315—H315	119.3
C124—C125—H125	119.3	C315—C316—C311	120.5 (2)
C125—C126—C121	120.8 (3)	C315—C316—H316	119.8
C125—C126—H126	119.6	C311—C316—H316	119.8
C121—C126—H126	119.6	C314—C317—H31A	109.5
C124—C127—H12A	109.5	C314—C317—H31B	109.5
C124—C127—H12B	109.5	H31A—C317—H31B	109.5
H12A—C127—H12B	109.5	C314—C317—H31C	109.5
C124—C127—H12C	109.5	H31A—C317—H31C	109.5
H12A—C127—H12C	109.5	H31B—C317—H31C	109.5
H12B—C127—H12C	109.5	C322—C321—C326	118.1 (2)
C132—C131—C136	118.2 (2)	C322—C321—P3	123.52 (19)
C132—C131—P1	124.4 (2)	C326—C321—P3	118.26 (18)
C136—C131—P1	117.39 (18)	C321—C322—C323	120.4 (2)
C133—C132—C131	121.0 (2)	C321—C322—H322	119.8
C133—C132—H132	119.5	C323—C322—H322	119.8
C131—C132—H132	119.5	C324—C323—C322	121.2 (2)
C132—C133—C134	120.9 (2)	C324—C323—H323	119.4
C132—C133—H133	119.5	C322—C323—H323	119.4
C134—C133—H133	119.5	C323—C324—C325	118.6 (2)
C133—C134—C135	118.1 (2)	C323—C324—C327	121.7 (3)
C133—C134—C137	121.2 (2)	C325—C324—C327	119.7 (3)
C135—C134—C137	120.6 (2)	C326—C325—C324	120.3 (2)
C136—C135—C134	121.2 (2)	C326—C325—H325	119.9
C136—C135—H135	119.4	C324—C325—H325	119.9
C134—C135—H135	119.4	C325—C326—C321	121.4 (2)
C135—C136—C131	120.6 (2)	C325—C326—H326	119.3
C135—C136—H136	119.7	C321—C326—H326	119.3
C131—C136—H136	119.7	C324—C327—H32A	109.5
C134—C137—H13A	109.5	C324—C327—H32B	109.5
C134—C137—H13B	109.5	H32A—C327—H32B	109.5
H13A—C137—H13B	109.5	C324—C327—H32C	109.5
C134—C137—H13C	109.5	H32A—C327—H32C	109.5
H13A—C137—H13C	109.5	H32B—C327—H32C	109.5
H13B—C137—H13C	109.5	C332—C331—C336	118.1 (2)
C216—C211—C212	118.2 (2)	C332—C331—P3	123.88 (18)
C216—C211—P2	117.44 (19)	C336—C331—P3	117.99 (19)
C212—C211—P2	124.2 (2)	C331—C332—C333	120.5 (2)
C213—C212—C211	120.3 (2)	C331—C332—H332	119.8
C213—C212—H212	119.8	C333—C332—H332	119.8
C211—C212—H212	119.8	C334—C333—C332	120.9 (2)
C214—C213—C212	121.4 (2)	C334—C333—H333	119.5
C214—C213—H213	119.3	C332—C333—H333	119.5
C212—C213—H213	119.3	C333—C334—C335	118.3 (2)
C213—C214—C215	118.4 (3)	C333—C334—C337	120.6 (3)
C213—C214—C217	120.4 (3)	C335—C334—C337	121.1 (2)
C215—C214—C217	121.3 (3)	C336—C335—C334	121.2 (2)
C216—C215—C214	120.9 (2)	C336—C335—H335	119.4
C216—C215—H215	119.6	C334—C335—H335	119.4
C214—C215—H215	119.6	C335—C336—C331	120.9 (3)
C215—C216—C211	120.8 (2)	C335—C336—H336	119.5
C215—C216—H216	119.6	C331—C336—H336	119.5
C211—C216—H216	119.6	C334—C337—H33A	109.5
C214—C217—H21A	109.5	C334—C337—H33B	109.5
C214—C217—H21B	109.5	H33A—C337—H33B	109.5
H21A—C217—H21B	109.5	C334—C337—H33C	109.5
C214—C217—H21C	109.5	H33A—C337—H33C	109.5
H21A—C217—H21C	109.5	H33B—C337—H33C	109.5
H21B—C217—H21C	109.5	C121—P1—C131	104.71 (12)
C222—C221—C226	118.2 (2)	C121—P1—C111	101.50 (11)
C222—C221—P2	122.37 (19)	C131—P1—C111	101.96 (11)
C226—C221—P2	118.96 (19)	C121—P1—Ag1	115.15 (8)
C223—C222—C221	120.4 (2)	C131—P1—Ag1	116.14 (8)
C223—C222—H222	119.8	C111—P1—Ag1	115.43 (8)
C221—C222—H222	119.8	C221—P2—C211	106.08 (11)
C224—C223—C222	121.5 (2)	C221—P2—C231	104.26 (11)
C224—C223—H223	119.2	C211—P2—C231	100.86 (11)
C222—C223—H223	119.2	C221—P2—Ag1	109.58 (8)
C223—C224—C225	118.1 (2)	C211—P2—Ag1	117.08 (8)
C223—C224—C227	121.4 (2)	C231—P2—Ag1	117.63 (8)
C225—C224—C227	120.5 (3)	C321—P3—C331	104.39 (11)
C226—C225—C224	121.1 (3)	C321—P3—C311	102.48 (11)
C226—C225—H225	119.5	C331—P3—C311	103.56 (12)
C224—C225—H225	119.5	C321—P3—Ag1	114.61 (8)
C225—C226—C221	120.6 (2)	C331—P3—Ag1	114.62 (8)
C225—C226—H226	119.7	C311—P3—Ag1	115.63 (8)
C221—C226—H226	119.7	C1—S2—Ag1	104.81 (10)
C224—C227—H22A	109.5	P1—Ag1—P2	116.17 (2)
C224—C227—H22B	109.5	P1—Ag1—P3	119.42 (2)
H22A—C227—H22B	109.5	P2—Ag1—P3	108.20 (2)
C224—C227—H22C	109.5	P1—Ag1—S2	104.24 (2)
H22A—C227—H22C	109.5	P2—Ag1—S2	110.75 (2)
H22B—C227—H22C	109.5	P3—Ag1—S2	95.83 (2)
C116—C111—C112—C113	0.3 (4)	C332—C331—C336—C335	−1.2 (4)
P1—C111—C112—C113	−175.8 (2)	P3—C331—C336—C335	179.4 (2)
C111—C112—C113—C114	0.1 (4)	C122—C121—P1—C131	−105.0 (2)
C112—C113—C114—C115	−0.4 (4)	C126—C121—P1—C131	77.7 (2)
C112—C113—C114—C117	179.5 (3)	C122—C121—P1—C111	149.2 (2)
C113—C114—C115—C116	0.3 (4)	C126—C121—P1—C111	−28.1 (2)
C117—C114—C115—C116	−179.6 (3)	C122—C121—P1—Ag1	23.8 (2)
C114—C115—C116—C111	0.1 (4)	C126—C121—P1—Ag1	−153.55 (19)
C112—C111—C116—C115	−0.4 (4)	C132—C131—P1—C121	−1.9 (2)
P1—C111—C116—C115	175.9 (2)	C136—C131—P1—C121	179.13 (18)
C126—C121—C122—C123	2.7 (4)	C132—C131—P1—C111	103.5 (2)
P1—C121—C122—C123	−174.8 (2)	C136—C131—P1—C111	−75.42 (19)
C121—C122—C123—C124	−0.7 (4)	C132—C131—P1—Ag1	−130.13 (18)
C122—C123—C124—C125	−1.9 (4)	C136—C131—P1—Ag1	50.94 (19)
C122—C123—C124—C127	176.0 (2)	C116—C111—P1—C121	−82.3 (2)
C123—C124—C125—C126	2.4 (4)	C112—C111—P1—C121	93.8 (2)
C127—C124—C125—C126	−175.5 (2)	C116—C111—P1—C131	169.7 (2)
C124—C125—C126—C121	−0.3 (4)	C112—C111—P1—C131	−14.1 (2)
C122—C121—C126—C125	−2.2 (4)	C116—C111—P1—Ag1	42.9 (2)
P1—C121—C126—C125	175.2 (2)	C112—C111—P1—Ag1	−140.96 (19)
C136—C131—C132—C133	−0.1 (4)	C222—C221—P2—C211	31.2 (2)
P1—C131—C132—C133	−179.06 (18)	C226—C221—P2—C211	−156.55 (19)
C131—C132—C133—C134	0.1 (4)	C222—C221—P2—C231	137.2 (2)
C132—C133—C134—C135	0.0 (4)	C226—C221—P2—C231	−50.6 (2)
C132—C133—C134—C137	−178.6 (2)	C222—C221—P2—Ag1	−96.1 (2)
C133—C134—C135—C136	−0.1 (4)	C226—C221—P2—Ag1	76.2 (2)
C137—C134—C135—C136	178.6 (2)	C216—C211—P2—C221	−147.78 (19)
C134—C135—C136—C131	0.1 (4)	C212—C211—P2—C221	37.0 (2)
C132—C131—C136—C135	0.0 (3)	C216—C211—P2—C231	103.8 (2)
P1—C131—C136—C135	179.03 (19)	C212—C211—P2—C231	−71.5 (2)
C216—C211—C212—C213	0.3 (4)	C216—C211—P2—Ag1	−25.2 (2)
P2—C211—C212—C213	175.6 (2)	C212—C211—P2—Ag1	159.60 (19)
C211—C212—C213—C214	−1.2 (4)	C232—C231—P2—C221	−20.8 (2)
C212—C213—C214—C215	1.2 (4)	C236—C231—P2—C221	162.3 (2)
C212—C213—C214—C217	−178.1 (2)	C232—C231—P2—C211	89.1 (2)
C213—C214—C215—C216	−0.5 (4)	C236—C231—P2—C211	−87.9 (2)
C217—C214—C215—C216	178.8 (2)	C232—C231—P2—Ag1	−142.33 (19)
C214—C215—C216—C211	−0.3 (4)	C236—C231—P2—Ag1	40.7 (2)
C212—C211—C216—C215	0.4 (4)	C322—C321—P3—C331	73.8 (2)
P2—C211—C216—C215	−175.17 (19)	C326—C321—P3—C331	−102.64 (19)
C226—C221—C222—C223	1.7 (4)	C322—C321—P3—C311	−34.0 (2)
P2—C221—C222—C223	174.03 (19)	C326—C321—P3—C311	149.62 (19)
C221—C222—C223—C224	−0.1 (4)	C322—C321—P3—Ag1	−160.02 (18)
C222—C223—C224—C225	−2.1 (4)	C326—C321—P3—Ag1	23.6 (2)
C222—C223—C224—C227	178.0 (3)	C332—C331—P3—C321	−22.0 (2)
C223—C224—C225—C226	2.6 (4)	C336—C331—P3—C321	157.3 (2)
C227—C224—C225—C226	−177.4 (2)	C332—C331—P3—C311	84.9 (2)
C224—C225—C226—C221	−1.1 (4)	C336—C331—P3—C311	−95.8 (2)
C222—C221—C226—C225	−1.1 (4)	C332—C331—P3—Ag1	−148.21 (19)
P2—C221—C226—C225	−173.72 (19)	C336—C331—P3—Ag1	31.1 (2)
C236—C231—C232—C233	−1.1 (4)	C312—C311—P3—C321	113.4 (2)
P2—C231—C232—C233	−178.0 (2)	C316—C311—P3—C321	−70.0 (2)
C231—C232—C233—C234	0.9 (4)	C312—C311—P3—C331	5.0 (2)
C232—C233—C234—C235	0.4 (4)	C316—C311—P3—C331	−178.39 (19)
C232—C233—C234—C237	−179.3 (2)	C312—C311—P3—Ag1	−121.25 (19)
C233—C234—C235—C236	−1.4 (4)	C316—C311—P3—Ag1	55.4 (2)
C237—C234—C235—C236	178.3 (3)	N1—C1—S2—Ag1	14E1 (10)
C234—C235—C236—C231	1.2 (4)	C121—P1—Ag1—P2	−68.68 (10)
C232—C231—C236—C235	0.1 (4)	C131—P1—Ag1—P2	54.20 (10)
P2—C231—C236—C235	177.3 (2)	C111—P1—Ag1—P2	173.47 (9)
C316—C311—C312—C313	−0.4 (4)	C121—P1—Ag1—P3	63.91 (10)
P3—C311—C312—C313	176.18 (19)	C131—P1—Ag1—P3	−173.21 (9)
C311—C312—C313—C314	0.0 (4)	C111—P1—Ag1—P3	−53.94 (9)
C312—C313—C314—C315	0.8 (4)	C121—P1—Ag1—S2	169.18 (9)
C312—C313—C314—C317	−178.7 (2)	C131—P1—Ag1—S2	−67.94 (9)
C313—C314—C315—C316	−1.2 (4)	C111—P1—Ag1—S2	51.33 (9)
C317—C314—C315—C316	178.3 (3)	C221—P2—Ag1—P1	95.04 (9)
C314—C315—C316—C311	0.8 (4)	C211—P2—Ag1—P1	−25.76 (9)
C312—C311—C316—C315	0.0 (4)	C231—P2—Ag1—P1	−146.19 (9)
P3—C311—C316—C315	−176.8 (2)	C221—P2—Ag1—P3	−42.50 (9)
C326—C321—C322—C323	1.1 (3)	C211—P2—Ag1—P3	−163.30 (9)
P3—C321—C322—C323	−175.33 (18)	C231—P2—Ag1—P3	76.27 (9)
C321—C322—C323—C324	0.2 (4)	C221—P2—Ag1—S2	−146.32 (9)
C322—C323—C324—C325	−0.4 (4)	C211—P2—Ag1—S2	92.87 (9)
C322—C323—C324—C327	−178.5 (2)	C231—P2—Ag1—S2	−27.56 (9)
C323—C324—C325—C326	−0.8 (4)	C321—P3—Ag1—P1	163.11 (8)
C327—C324—C325—C326	177.3 (2)	C331—P3—Ag1—P1	−76.18 (9)
C324—C325—C326—C321	2.2 (4)	C311—P3—Ag1—P1	44.21 (10)
C322—C321—C326—C325	−2.3 (3)	C321—P3—Ag1—P2	−60.96 (9)
P3—C321—C326—C325	174.31 (18)	C331—P3—Ag1—P2	59.74 (9)
C336—C331—C332—C333	1.1 (4)	C311—P3—Ag1—P2	−179.87 (10)
P3—C331—C332—C333	−179.58 (19)	C321—P3—Ag1—S2	53.15 (9)
C331—C332—C333—C334	−0.5 (4)	C331—P3—Ag1—S2	173.85 (9)
C332—C333—C334—C335	−0.1 (4)	C311—P3—Ag1—S2	−65.76 (10)
C332—C333—C334—C337	178.4 (2)	C1—S2—Ag1—P1	76.54 (9)
C333—C334—C335—C336	0.0 (4)	C1—S2—Ag1—P2	−49.10 (10)
C337—C334—C335—C336	−178.5 (3)	C1—S2—Ag1—P3	−161.09 (9)
C334—C335—C336—C331	0.7 (4)

(III)

Crystal data

C63H63AgP3^+·C3H6O·ClO4^−	Dx = 1.329 Mg m^−3
Mr = 1178.44	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pna21	Cell parameters from 7165 reflections
a = 19.8625 (8) Å	θ = 1.3–28.4°
b = 25.3785 (9) Å	µ = 0.52 mm^−1
c = 11.6858 (5) Å	T = 100 K
V = 5890.6 (4) Å^3	Cuboid, white
Z = 4	0.31 × 0.26 × 0.24 mm
F(000) = 2456

Data collection

CCD area detector diffractometer	6860 reflections with I > 2σ(I)
phi and ω scans	Rint = 0.045
Absorption correction: multi-scan SADABS (Bruker, 2004)	θmax = 28.4°, θmin = 1.3°
Tmin = 0.856, Tmax = 0.886	h = −26→19
27027 measured reflections	k = −16→33
7691 independent reflections	l = −11→15

Refinement

Refinement on F^2	H-atom parameters constrained
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0647P)^2 + 2.2152P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.040	(Δ/σ)max = 0.002
wR(F^2) = 0.109	Δρmax = 1.10 e Å^−3
S = 1.04	Δρmin = −0.95 e Å^−3
7691 reflections	Absolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
704 parameters	Absolute structure parameter: 0.08 (3)
30 restraints

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.770722 (13)	0.128536 (10)	0.80882 (3)	0.01687 (8)
P1	0.68328 (6)	0.19361 (4)	0.75282 (10)	0.0189 (2)
P2	0.88769 (5)	0.15764 (4)	0.84181 (10)	0.0176 (2)
P3	0.73376 (5)	0.03615 (4)	0.79733 (12)	0.0158 (2)
Cl1	0.61125 (10)	0.13702 (7)	0.27416 (13)	0.0529 (4)
O01	0.5983 (4)	0.1914 (2)	0.3025 (6)	0.097 (2)
O02A	0.5599 (16)	0.1094 (9)	0.326 (3)	0.276 (10)	0.25
O03A	0.6685 (18)	0.1280 (10)	0.356 (4)	0.099 (4)	0.45
O04A	0.601 (2)	0.1331 (14)	0.1553 (12)	0.081 (4)	0.25
O02B	0.5557 (7)	0.1097 (6)	0.2960 (9)	0.276 (10)	0.75
O03B	0.6677 (14)	0.1250 (9)	0.337 (3)	0.099 (4)	0.55
O04B	0.6302 (6)	0.1408 (4)	0.1569 (6)	0.081 (4)	0.75
O002	0.8646 (2)	0.09024 (18)	0.2722 (4)	0.0477 (11)
C001	0.7852 (4)	0.0803 (4)	0.1257 (6)	0.065 (2)
H01A	0.8062	0.0455	0.118	0.097*
H01B	0.7873	0.0988	0.0522	0.097*
H01C	0.738	0.0761	0.1487	0.097*
C002	0.8221 (3)	0.1117 (3)	0.2152 (5)	0.0439 (15)
C003	0.8067 (4)	0.1688 (3)	0.2271 (8)	0.067 (2)
H03A	0.8393	0.1851	0.2791	0.1*
H03B	0.7612	0.1731	0.2582	0.1*
H03C	0.8094	0.1858	0.152	0.1*
C111	0.6645 (2)	0.24153 (17)	0.8646 (4)	0.0197 (9)
C112	0.6484 (2)	0.29421 (16)	0.8418 (4)	0.0207 (9)
H112	0.6469	0.3064	0.765	0.025*
C113	0.6345 (2)	0.32867 (18)	0.9308 (4)	0.0226 (9)
H113	0.6238	0.3643	0.9141	0.027*
C114	0.6360 (2)	0.31173 (18)	1.0452 (4)	0.0192 (9)
C115	0.6516 (2)	0.25909 (19)	1.0665 (4)	0.0235 (10)
H115	0.6522	0.2466	1.1431	0.028*
C116	0.6663 (2)	0.22468 (19)	0.9775 (4)	0.0251 (10)
H116	0.6777	0.1892	0.9942	0.03*
C117	0.6187 (3)	0.3491 (2)	1.1413 (5)	0.0315 (11)
H11A	0.5707	0.3461	1.1596	0.047*
H11B	0.6287	0.3854	1.1176	0.047*
H11C	0.6455	0.3403	1.209	0.047*
C121	0.7123 (2)	0.23286 (18)	0.6316 (4)	0.0215 (9)
C122	0.7756 (2)	0.25563 (19)	0.6419 (5)	0.0272 (11)
H122	0.8	0.2522	0.7115	0.033*
C123	0.8034 (3)	0.2833 (2)	0.5515 (5)	0.0327 (12)
H123	0.8464	0.2991	0.5605	0.039*
C124	0.7700 (3)	0.2884 (2)	0.4483 (5)	0.0346 (13)
C125	0.7070 (3)	0.2665 (2)	0.4384 (5)	0.0359 (12)
H125	0.6829	0.2703	0.3686	0.043*
C126	0.6776 (3)	0.2389 (2)	0.5290 (5)	0.0293 (11)
H126	0.6339	0.2242	0.5206	0.035*
C127	0.8015 (4)	0.3174 (2)	0.3483 (6)	0.0473 (16)
H12A	0.8183	0.2919	0.2923	0.071*
H12B	0.839	0.3392	0.3758	0.071*
H12C	0.7677	0.34	0.3121	0.071*
C131	0.6018 (2)	0.16513 (17)	0.7151 (4)	0.0217 (9)
C132	0.5478 (2)	0.16802 (17)	0.7900 (4)	0.0232 (10)
H132	0.5521	0.1873	0.8593	0.028*
C133	0.4873 (3)	0.14277 (19)	0.7641 (5)	0.0275 (10)
H133	0.4508	0.1446	0.8166	0.033*
C134	0.4798 (2)	0.11505 (19)	0.6630 (5)	0.0278 (11)
C135	0.5334 (2)	0.1125 (2)	0.5873 (5)	0.0272 (10)
H135	0.5284	0.0943	0.5168	0.033*
C136	0.5949 (2)	0.13659 (18)	0.6143 (5)	0.0249 (10)
H136	0.632	0.1334	0.5634	0.03*
C137	0.4146 (3)	0.0869 (2)	0.6349 (6)	0.0389 (13)
H13A	0.415	0.0517	0.6694	0.058*
H13B	0.41	0.0836	0.5516	0.058*
H13C	0.3765	0.1071	0.6653	0.058*
C211	0.9184 (2)	0.17807 (17)	0.7017 (4)	0.0187 (9)
C212	0.9609 (2)	0.22019 (19)	0.6857 (4)	0.0235 (10)
H212	0.977	0.2392	0.7501	0.028*
C213	0.9805 (2)	0.2352 (2)	0.5767 (5)	0.0262 (10)
H213	1.0087	0.265	0.5671	0.031*
C214	0.9591 (3)	0.2068 (2)	0.4806 (4)	0.0283 (11)
C215	0.9176 (2)	0.1640 (2)	0.4973 (4)	0.0275 (10)
H215	0.9033	0.1438	0.4333	0.033*
C216	0.8964 (2)	0.14999 (18)	0.6059 (4)	0.0222 (9)
H216	0.8667	0.121	0.6155	0.027*
C217	0.9812 (3)	0.2222 (3)	0.3624 (5)	0.0462 (15)
H21A	0.9699	0.1939	0.3086	0.069*
H21B	1.0299	0.2281	0.3619	0.069*
H21C	0.9581	0.2546	0.3394	0.069*
C221	0.9494 (2)	0.10948 (17)	0.8932 (4)	0.0183 (8)
C222	0.99060 (18)	0.08134 (15)	0.8180 (5)	0.0193 (8)
H222	0.9898	0.0891	0.7385	0.023*
C223	1.0329 (2)	0.04185 (17)	0.8596 (4)	0.0228 (9)
H223	1.0612	0.0233	0.808	0.027*
C224	1.0344 (2)	0.02942 (17)	0.9738 (5)	0.0229 (10)
C225	0.9937 (2)	0.05766 (19)	1.0488 (4)	0.0263 (10)
H225	0.9949	0.0498	1.1283	0.032*
C226	0.9514 (2)	0.0972 (2)	1.0091 (4)	0.0258 (10)
H226	0.9236	0.1159	1.0613	0.031*
C227	1.0801 (3)	−0.0135 (2)	1.0193 (5)	0.0330 (12)
H22A	1.0986	−0.0337	0.9551	0.049*
H22B	1.0542	−0.0371	1.0692	0.049*
H22C	1.117	0.0024	1.0629	0.049*
C231	0.8995 (2)	0.21398 (17)	0.9351 (4)	0.0194 (9)
C232	0.9614 (2)	0.22777 (19)	0.9834 (4)	0.0225 (10)
H232	0.9997	0.2061	0.9706	0.027*
C233	0.9675 (2)	0.27307 (19)	1.0501 (4)	0.0251 (10)
H233	1.0098	0.2814	1.0836	0.03*
C234	0.9123 (3)	0.30655 (19)	1.0685 (5)	0.0286 (11)
C235	0.8506 (3)	0.29210 (18)	1.0211 (5)	0.0282 (11)
H235	0.8124	0.3138	1.0334	0.034*
C236	0.8440 (2)	0.24688 (18)	0.9567 (4)	0.0240 (10)
H236	0.8012	0.2378	0.9263	0.029*
C237	0.9203 (3)	0.3562 (2)	1.1368 (6)	0.0418 (15)
H23A	0.9671	0.3594	1.1626	0.063*
H23B	0.8904	0.3551	1.2035	0.063*
H23C	0.9087	0.3866	1.089	0.063*
C311	0.7805 (2)	−0.01189 (16)	0.8820 (4)	0.0161 (8)
C312	0.7494 (3)	−0.04657 (19)	0.9584 (4)	0.0191 (9)
H312	0.702	−0.0455	0.969	0.023*
C313	0.7883 (2)	−0.08271 (18)	1.0189 (4)	0.0233 (9)
H313	0.7669	−0.1063	1.0706	0.028*
C314	0.8576 (2)	−0.08507 (17)	1.0053 (4)	0.0217 (9)
C315	0.8877 (2)	−0.05049 (18)	0.9285 (5)	0.0260 (10)
H315	0.935	−0.0519	0.9173	0.031*
C316	0.8499 (2)	−0.01392 (17)	0.8679 (4)	0.0227 (9)
H316	0.8715	0.0098	0.8168	0.027*
C317	0.8987 (3)	−0.1239 (2)	1.0733 (5)	0.0339 (12)
H31A	0.8937	−0.1164	1.1551	0.051*
H31B	0.9462	−0.1207	1.0517	0.051*
H31C	0.883	−0.1597	1.0573	0.051*
C321	0.6463 (2)	0.02764 (16)	0.8391 (4)	0.0181 (9)
C322	0.6021 (2)	−0.00361 (19)	0.7785 (4)	0.0241 (10)
H322	0.6173	−0.0224	0.7131	0.029*
C323	0.5347 (2)	−0.00778 (18)	0.8130 (5)	0.0268 (9)
H323	0.5045	−0.0291	0.7701	0.032*
C324	0.5114 (2)	0.01883 (18)	0.9087 (4)	0.0236 (10)
C325	0.5571 (2)	0.04928 (19)	0.9704 (4)	0.0265 (10)
H325	0.5423	0.067	1.0375	0.032*
C326	0.6238 (2)	0.05433 (18)	0.9360 (4)	0.0221 (9)
H326	0.654	0.0759	0.9784	0.027*
C327	0.4383 (3)	0.0164 (2)	0.9431 (6)	0.0366 (13)
H32A	0.435	0.0097	1.0255	0.055*
H32B	0.4159	−0.0121	0.9012	0.055*
H32C	0.4164	0.05	0.9249	0.055*
C331	0.7400 (2)	0.00972 (18)	0.6533 (4)	0.0192 (9)
C332	0.7468 (3)	−0.0444 (2)	0.6325 (4)	0.0227 (10)
H332	0.7489	−0.0684	0.6947	0.027*
C333	0.7506 (3)	−0.0628 (2)	0.5203 (5)	0.0292 (11)
H333	0.7553	−0.0996	0.5073	0.035*
C334	0.7475 (3)	−0.0292 (2)	0.4280 (4)	0.0293 (11)
C335	0.7400 (2)	0.0243 (2)	0.4486 (5)	0.0290 (11)
H335	0.7366	0.048	0.3859	0.035*
C336	0.7371 (2)	0.0438 (2)	0.5596 (4)	0.0236 (10)
H336	0.7332	0.0807	0.5719	0.028*
C337	0.7528 (3)	−0.0497 (3)	0.3073 (6)	0.0450 (14)
H33A	0.7972	−0.0411	0.276	0.067*
H33B	0.7178	−0.0334	0.2599	0.067*
H33C	0.7466	−0.088	0.3074	0.067*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.01589 (13)	0.01270 (13)	0.02203 (15)	0.00105 (10)	−0.00106 (15)	0.00151 (14)
P1	0.0171 (5)	0.0161 (5)	0.0236 (6)	0.0036 (4)	0.0002 (4)	0.0035 (5)
P2	0.0160 (5)	0.0155 (5)	0.0213 (6)	0.0013 (4)	−0.0011 (4)	0.0000 (4)
P3	0.0158 (4)	0.0129 (4)	0.0187 (6)	0.0002 (3)	0.0014 (4)	−0.0004 (5)
Cl1	0.0749 (11)	0.0613 (10)	0.0225 (7)	−0.0194 (8)	−0.0054 (7)	0.0083 (6)
O01	0.168 (6)	0.064 (3)	0.060 (4)	0.043 (4)	0.024 (5)	−0.002 (4)
O02A	0.358 (15)	0.409 (16)	0.062 (7)	−0.353 (15)	−0.124 (9)	0.144 (10)
O03A	0.132 (6)	0.134 (6)	0.029 (12)	0.083 (5)	0.002 (5)	0.007 (5)
O04A	0.169 (13)	0.048 (4)	0.026 (3)	−0.043 (5)	0.009 (4)	0.006 (2)
O02B	0.358 (15)	0.409 (16)	0.062 (7)	−0.353 (15)	−0.124 (9)	0.144 (10)
O03B	0.132 (6)	0.134 (6)	0.029 (12)	0.083 (5)	0.002 (5)	0.007 (5)
O04B	0.169 (13)	0.048 (4)	0.026 (3)	−0.043 (5)	0.009 (4)	0.006 (2)
O002	0.060 (3)	0.053 (3)	0.031 (2)	−0.008 (2)	−0.007 (2)	−0.0053 (19)
C001	0.062 (4)	0.101 (7)	0.031 (3)	−0.046 (4)	−0.002 (3)	−0.006 (4)
C002	0.051 (4)	0.060 (4)	0.021 (3)	−0.023 (3)	−0.001 (3)	0.006 (3)
C003	0.080 (6)	0.048 (4)	0.073 (5)	−0.021 (4)	−0.038 (5)	0.015 (4)
C111	0.0160 (19)	0.021 (2)	0.022 (2)	0.0024 (16)	0.0003 (17)	0.0053 (18)
C112	0.023 (2)	0.0169 (19)	0.022 (2)	0.0014 (15)	0.0013 (17)	0.0066 (16)
C113	0.023 (2)	0.019 (2)	0.026 (2)	0.0018 (17)	−0.0028 (19)	0.0046 (18)
C114	0.0145 (19)	0.022 (2)	0.021 (2)	−0.0021 (16)	0.0000 (16)	0.0001 (17)
C115	0.025 (2)	0.025 (2)	0.020 (2)	0.0008 (18)	−0.0037 (18)	0.0079 (19)
C116	0.025 (2)	0.022 (2)	0.028 (3)	0.0011 (18)	−0.003 (2)	0.0085 (19)
C117	0.037 (3)	0.029 (3)	0.028 (3)	0.000 (2)	0.000 (2)	−0.006 (2)
C121	0.020 (2)	0.021 (2)	0.024 (2)	0.0081 (17)	0.0081 (18)	0.0030 (18)
C122	0.026 (2)	0.021 (2)	0.034 (3)	0.0038 (18)	0.003 (2)	0.008 (2)
C123	0.028 (3)	0.024 (2)	0.047 (3)	0.0012 (19)	0.012 (2)	0.010 (2)
C124	0.040 (3)	0.025 (3)	0.039 (3)	0.011 (2)	0.017 (2)	0.007 (2)
C125	0.042 (3)	0.037 (3)	0.028 (3)	0.003 (2)	0.005 (2)	0.008 (2)
C126	0.029 (3)	0.032 (3)	0.027 (3)	0.004 (2)	0.006 (2)	0.005 (2)
C127	0.059 (4)	0.043 (3)	0.040 (3)	0.005 (3)	0.024 (3)	0.015 (3)
C131	0.020 (2)	0.018 (2)	0.027 (2)	0.0060 (16)	−0.0026 (18)	0.0045 (18)
C132	0.025 (2)	0.020 (2)	0.025 (3)	0.0017 (15)	−0.0001 (19)	0.0044 (18)
C133	0.026 (2)	0.023 (2)	0.033 (3)	−0.0020 (18)	0.003 (2)	0.003 (2)
C134	0.025 (2)	0.020 (2)	0.039 (3)	0.0005 (18)	−0.005 (2)	0.006 (2)
C135	0.022 (2)	0.025 (2)	0.035 (3)	0.0041 (18)	0.000 (2)	−0.003 (2)
C136	0.025 (2)	0.024 (2)	0.026 (3)	0.0037 (18)	0.002 (2)	0.0002 (19)
C137	0.028 (3)	0.032 (3)	0.056 (4)	−0.009 (2)	0.000 (3)	−0.002 (3)
C211	0.019 (2)	0.017 (2)	0.020 (2)	0.0006 (16)	−0.0018 (17)	0.0012 (17)
C212	0.023 (2)	0.021 (2)	0.027 (3)	−0.0008 (18)	−0.0018 (19)	−0.0041 (19)
C213	0.021 (2)	0.027 (2)	0.030 (3)	−0.0006 (18)	0.001 (2)	0.000 (2)
C214	0.027 (2)	0.035 (3)	0.023 (2)	0.006 (2)	0.007 (2)	0.000 (2)
C215	0.027 (2)	0.031 (3)	0.024 (3)	0.0028 (19)	−0.002 (2)	−0.007 (2)
C216	0.020 (2)	0.021 (2)	0.026 (2)	−0.0002 (17)	−0.0038 (18)	−0.0022 (19)
C217	0.053 (4)	0.058 (4)	0.028 (3)	0.002 (3)	0.013 (3)	0.003 (3)
C221	0.0156 (19)	0.0155 (19)	0.024 (2)	0.0035 (15)	−0.0022 (17)	−0.0016 (17)
C222	0.0171 (17)	0.0186 (17)	0.022 (2)	−0.0010 (13)	−0.001 (2)	0.000 (2)
C223	0.018 (2)	0.019 (2)	0.031 (3)	0.0010 (16)	0.0009 (18)	−0.0047 (19)
C224	0.016 (2)	0.015 (2)	0.038 (3)	−0.0022 (16)	−0.0059 (19)	0.0034 (19)
C225	0.029 (2)	0.030 (3)	0.020 (2)	0.0019 (19)	−0.0029 (19)	0.0028 (19)
C226	0.026 (2)	0.028 (2)	0.024 (2)	0.0047 (18)	0.0000 (19)	0.000 (2)
C227	0.024 (2)	0.026 (3)	0.049 (3)	0.0017 (19)	−0.005 (2)	0.010 (2)
C231	0.024 (2)	0.018 (2)	0.017 (2)	0.0000 (16)	0.0026 (17)	−0.0020 (17)
C232	0.023 (2)	0.020 (2)	0.025 (2)	0.0023 (18)	−0.0010 (19)	−0.0019 (19)
C233	0.027 (2)	0.026 (2)	0.022 (2)	−0.0033 (18)	0.0060 (19)	−0.0060 (19)
C234	0.039 (3)	0.020 (2)	0.027 (3)	−0.005 (2)	0.015 (2)	−0.007 (2)
C235	0.033 (3)	0.017 (2)	0.035 (3)	0.0073 (18)	0.012 (2)	−0.001 (2)
C236	0.021 (2)	0.019 (2)	0.032 (3)	0.0033 (17)	0.0018 (19)	0.0000 (19)
C237	0.052 (4)	0.022 (2)	0.051 (4)	−0.011 (2)	0.030 (3)	−0.012 (2)
C311	0.0167 (19)	0.0110 (18)	0.021 (2)	−0.0004 (14)	−0.0007 (16)	−0.0010 (16)
C312	0.020 (2)	0.020 (2)	0.018 (2)	−0.0033 (18)	0.0002 (18)	0.0005 (18)
C313	0.030 (2)	0.018 (2)	0.021 (2)	−0.0036 (18)	0.0022 (19)	0.0035 (18)
C314	0.024 (2)	0.017 (2)	0.025 (2)	0.0032 (16)	−0.0070 (19)	−0.0019 (18)
C315	0.016 (2)	0.021 (2)	0.041 (3)	0.0018 (17)	−0.007 (2)	0.005 (2)
C316	0.023 (2)	0.018 (2)	0.027 (3)	0.0008 (16)	0.0021 (19)	0.0065 (18)
C317	0.035 (3)	0.025 (3)	0.042 (3)	0.001 (2)	−0.013 (2)	0.007 (2)
C321	0.0190 (19)	0.0157 (18)	0.020 (2)	−0.0002 (14)	0.0014 (16)	0.0021 (16)
C322	0.024 (2)	0.027 (2)	0.022 (2)	−0.0028 (17)	0.0017 (17)	−0.0079 (18)
C323	0.0179 (18)	0.031 (2)	0.031 (2)	−0.0016 (15)	0.002 (2)	−0.001 (3)
C324	0.019 (2)	0.022 (2)	0.030 (3)	0.0044 (17)	0.0051 (19)	0.0056 (19)
C325	0.030 (2)	0.025 (2)	0.025 (2)	0.0046 (19)	0.008 (2)	−0.004 (2)
C326	0.019 (2)	0.020 (2)	0.027 (2)	0.0013 (16)	0.0023 (18)	−0.0046 (18)
C327	0.023 (3)	0.040 (3)	0.047 (3)	0.005 (2)	0.013 (2)	0.002 (3)
C331	0.014 (2)	0.022 (2)	0.022 (2)	−0.0023 (15)	0.0016 (17)	0.0002 (18)
C332	0.022 (2)	0.023 (2)	0.022 (2)	−0.0015 (19)	0.0032 (19)	0.0016 (19)
C333	0.025 (2)	0.033 (3)	0.029 (3)	0.000 (2)	0.003 (2)	−0.012 (2)
C334	0.020 (2)	0.047 (3)	0.022 (3)	0.003 (2)	0.0008 (19)	−0.007 (2)
C335	0.019 (2)	0.044 (3)	0.024 (3)	0.002 (2)	−0.0001 (19)	0.006 (2)
C336	0.019 (2)	0.026 (2)	0.025 (3)	0.0028 (17)	0.0005 (18)	0.0073 (19)
C337	0.037 (3)	0.072 (4)	0.025 (3)	0.001 (3)	0.005 (3)	−0.015 (4)

Geometric parameters (Å, º)

Ag1—P3	2.4607 (10)	C214—C217	1.501 (7)
Ag1—P2	2.4681 (11)	C215—C216	1.384 (7)
Ag1—P1	2.4844 (11)	C215—H215	0.95
P1—C111	1.823 (5)	C216—H216	0.95
P1—C121	1.825 (5)	C217—H21A	0.98
P1—C131	1.827 (5)	C217—H21B	0.98
P2—C231	1.813 (5)	C217—H21C	0.98
P2—C211	1.823 (5)	C221—C226	1.390 (7)
P2—C221	1.831 (4)	C221—C222	1.397 (6)
P3—C331	1.816 (5)	C222—C223	1.396 (6)
P3—C321	1.817 (4)	C222—H222	0.95
P3—C311	1.824 (4)	C223—C224	1.371 (7)
Cl1—O02B	1.328 (9)	C223—H223	0.95
Cl1—O03B	1.376 (14)	C224—C225	1.392 (7)
Cl1—O02A	1.376 (15)	C224—C227	1.515 (6)
Cl1—O04A	1.407 (15)	C225—C226	1.389 (7)
Cl1—O04B	1.424 (7)	C225—H225	0.95
Cl1—O01	1.443 (5)	C226—H226	0.95
Cl1—O03A	1.50 (2)	C227—H22A	0.98
O002—C002	1.205 (8)	C227—H22B	0.98
C001—C002	1.505 (9)	C227—H22C	0.98
C001—H01A	0.98	C231—C232	1.397 (7)
C001—H01B	0.98	C231—C236	1.406 (6)
C001—H01C	0.98	C232—C233	1.394 (7)
C002—C003	1.489 (11)	C232—H232	0.95
C003—H03A	0.98	C233—C234	1.404 (7)
C003—H03B	0.98	C233—H233	0.95
C003—H03C	0.98	C234—C235	1.394 (8)
C111—C116	1.388 (7)	C234—C237	1.501 (7)
C111—C112	1.400 (6)	C235—C236	1.379 (7)
C112—C113	1.387 (7)	C235—H235	0.95
C112—H112	0.95	C236—H236	0.95
C113—C114	1.404 (7)	C237—H23A	0.98
C113—H113	0.95	C237—H23B	0.98
C114—C115	1.394 (6)	C237—H23C	0.98
C114—C117	1.510 (7)	C311—C316	1.388 (6)
C115—C116	1.389 (7)	C311—C312	1.399 (6)
C115—H115	0.95	C312—C313	1.392 (7)
C116—H116	0.95	C312—H312	0.95
C117—H11A	0.98	C313—C314	1.386 (7)
C117—H11B	0.98	C313—H313	0.95
C117—H11C	0.98	C314—C315	1.390 (7)
C121—C126	1.391 (7)	C314—C317	1.507 (7)
C121—C122	1.389 (7)	C315—C316	1.387 (6)
C122—C123	1.383 (7)	C315—H315	0.95
C122—H122	0.95	C316—H316	0.95
C123—C124	1.382 (9)	C317—H31A	0.98
C123—H123	0.95	C317—H31B	0.98
C124—C125	1.375 (9)	C317—H31C	0.98
C124—C127	1.517 (8)	C321—C322	1.379 (6)
C125—C126	1.398 (7)	C321—C326	1.393 (6)
C125—H125	0.95	C322—C323	1.402 (6)
C126—H126	0.95	C322—H322	0.95
C127—H12A	0.98	C323—C324	1.385 (7)
C127—H12B	0.98	C323—H323	0.95
C127—H12C	0.98	C324—C325	1.393 (7)
C131—C132	1.386 (7)	C324—C327	1.509 (7)
C131—C136	1.390 (7)	C325—C326	1.391 (7)
C132—C133	1.396 (7)	C325—H325	0.95
C132—H132	0.95	C326—H326	0.95
C133—C134	1.384 (8)	C327—H32A	0.98
C133—H133	0.95	C327—H32B	0.98
C134—C135	1.386 (7)	C327—H32C	0.98
C134—C137	1.515 (7)	C331—C336	1.397 (6)
C135—C136	1.402 (7)	C331—C332	1.401 (7)
C135—H135	0.95	C332—C333	1.394 (7)
C136—H136	0.95	C332—H332	0.95
C137—H13A	0.98	C333—C334	1.378 (8)
C137—H13B	0.98	C333—H333	0.95
C137—H13C	0.98	C334—C335	1.387 (8)
C211—C212	1.375 (7)	C334—C337	1.507 (8)
C211—C216	1.396 (6)	C335—C336	1.390 (7)
C212—C213	1.385 (7)	C335—H335	0.95
C212—H212	0.95	C336—H336	0.95
C213—C214	1.399 (7)	C337—H33A	0.98
C213—H213	0.95	C337—H33B	0.98
C214—C215	1.378 (7)	C337—H33C	0.98
P3—Ag1—P2	125.07 (4)	C214—C213—H213	119.6
P3—Ag1—P1	114.24 (4)	C215—C214—C213	118.3 (5)
P2—Ag1—P1	120.01 (4)	C215—C214—C217	120.6 (5)
C111—P1—C121	104.9 (2)	C213—C214—C217	121.1 (5)
C111—P1—C131	104.8 (2)	C214—C215—C216	120.9 (5)
C121—P1—C131	108.0 (2)	C214—C215—H215	119.5
C111—P1—Ag1	113.45 (15)	C216—C215—H215	119.5
C121—P1—Ag1	110.26 (14)	C215—C216—C211	120.6 (4)
C131—P1—Ag1	114.83 (14)	C215—C216—H216	119.7
C231—P2—C211	105.8 (2)	C211—C216—H216	119.7
C231—P2—C221	104.0 (2)	C214—C217—H21A	109.5
C211—P2—C221	105.1 (2)	C214—C217—H21B	109.5
C231—P2—Ag1	116.88 (15)	H21A—C217—H21B	109.5
C211—P2—Ag1	105.05 (15)	C214—C217—H21C	109.5
C221—P2—Ag1	118.75 (14)	H21A—C217—H21C	109.5
C331—P3—C321	105.7 (2)	H21B—C217—H21C	109.5
C331—P3—C311	102.8 (2)	C226—C221—C222	118.7 (4)
C321—P3—C311	105.19 (19)	C226—C221—P2	119.2 (3)
C331—P3—Ag1	112.46 (15)	C222—C221—P2	121.8 (4)
C321—P3—Ag1	112.57 (14)	C221—C222—C223	120.1 (5)
C311—P3—Ag1	117.08 (14)	C221—C222—H222	119.9
O02B—Cl1—O03B	117.2 (16)	C223—C222—H222	119.9
O02B—Cl1—O02A	15.1 (17)	C224—C223—C222	121.1 (4)
O03B—Cl1—O02A	105 (3)	C224—C223—H223	119.4
O02B—Cl1—O04A	91.8 (14)	C222—C223—H223	119.4
O03B—Cl1—O04A	129 (3)	C223—C224—C225	118.8 (4)
O02A—Cl1—O04A	106.9 (17)	C223—C224—C227	121.3 (5)
O02B—Cl1—O04B	116.1 (6)	C225—C224—C227	119.8 (5)
O03B—Cl1—O04B	108.4 (19)	C226—C225—C224	120.8 (5)
O02A—Cl1—O04B	130.7 (14)	C226—C225—H225	119.6
O04A—Cl1—O04B	25.0 (17)	C224—C225—H225	119.6
O02B—Cl1—O01	107.9 (9)	C225—C226—C221	120.4 (5)
O03B—Cl1—O01	103.6 (10)	C225—C226—H226	119.8
O02A—Cl1—O01	104.7 (13)	C221—C226—H226	119.8
O04A—Cl1—O01	105.5 (16)	C224—C227—H22A	109.5
O04B—Cl1—O01	101.8 (5)	C224—C227—H22B	109.5
O02B—Cl1—O03A	115 (2)	H22A—C227—H22B	109.5
O03B—Cl1—O03A	8 (3)	C224—C227—H22C	109.5
O02A—Cl1—O03A	102 (2)	H22A—C227—H22C	109.5
O04A—Cl1—O03A	136 (3)	H22B—C227—H22C	109.5
O04B—Cl1—O03A	115 (2)	C232—C231—C236	117.9 (4)
O01—Cl1—O03A	97.8 (12)	C232—C231—P2	123.7 (3)
C002—C001—H01A	109.5	C236—C231—P2	118.3 (4)
C002—C001—H01B	109.5	C233—C232—C231	120.6 (4)
H01A—C001—H01B	109.5	C233—C232—H232	119.7
C002—C001—H01C	109.5	C231—C232—H232	119.7
H01A—C001—H01C	109.5	C232—C233—C234	121.1 (5)
H01B—C001—H01C	109.5	C232—C233—H233	119.4
O002—C002—C003	122.1 (6)	C234—C233—H233	119.4
O002—C002—C001	119.1 (7)	C235—C234—C233	117.8 (4)
C003—C002—C001	118.7 (7)	C235—C234—C237	121.7 (5)
C002—C003—H03A	109.5	C233—C234—C237	120.5 (5)
C002—C003—H03B	109.5	C236—C235—C234	121.3 (4)
H03A—C003—H03B	109.5	C236—C235—H235	119.4
C002—C003—H03C	109.5	C234—C235—H235	119.4
H03A—C003—H03C	109.5	C235—C236—C231	121.2 (5)
H03B—C003—H03C	109.5	C235—C236—H236	119.4
C116—C111—C112	118.7 (4)	C231—C236—H236	119.4
C116—C111—P1	118.1 (3)	C234—C237—H23A	109.5
C112—C111—P1	123.2 (4)	C234—C237—H23B	109.5
C113—C112—C111	120.3 (4)	H23A—C237—H23B	109.5
C113—C112—H112	119.8	C234—C237—H23C	109.5
C111—C112—H112	119.8	H23A—C237—H23C	109.5
C112—C113—C114	121.1 (4)	H23B—C237—H23C	109.5
C112—C113—H113	119.4	C316—C311—C312	119.4 (4)
C114—C113—H113	119.4	C316—C311—P3	117.8 (3)
C115—C114—C113	117.9 (4)	C312—C311—P3	122.8 (3)
C115—C114—C117	121.3 (4)	C313—C312—C311	119.6 (5)
C113—C114—C117	120.7 (4)	C313—C312—H312	120.2
C116—C115—C114	121.0 (4)	C311—C312—H312	120.2
C116—C115—H115	119.5	C314—C313—C312	121.4 (4)
C114—C115—H115	119.5	C314—C313—H313	119.3
C115—C116—C111	120.8 (4)	C312—C313—H313	119.3
C115—C116—H116	119.6	C313—C314—C315	118.3 (4)
C111—C116—H116	119.6	C313—C314—C317	120.4 (4)
C114—C117—H11A	109.5	C315—C314—C317	121.3 (4)
C114—C117—H11B	109.5	C316—C315—C314	121.3 (4)
H11A—C117—H11B	109.5	C316—C315—H315	119.4
C114—C117—H11C	109.5	C314—C315—H315	119.4
H11A—C117—H11C	109.5	C315—C316—C311	120.1 (4)
H11B—C117—H11C	109.5	C315—C316—H316	120
C126—C121—C122	118.5 (5)	C311—C316—H316	120
C126—C121—P1	124.9 (4)	C314—C317—H31A	109.5
C122—C121—P1	116.5 (4)	C314—C317—H31B	109.5
C123—C122—C121	120.4 (5)	H31A—C317—H31B	109.5
C123—C122—H122	119.8	C314—C317—H31C	109.5
C121—C122—H122	119.8	H31A—C317—H31C	109.5
C124—C123—C122	121.5 (5)	H31B—C317—H31C	109.5
C124—C123—H123	119.2	C322—C321—C326	119.5 (4)
C122—C123—H123	119.2	C322—C321—P3	122.7 (3)
C125—C124—C123	118.2 (5)	C326—C321—P3	117.8 (3)
C125—C124—C127	120.4 (6)	C321—C322—C323	120.3 (4)
C123—C124—C127	121.4 (5)	C321—C322—H322	119.9
C124—C125—C126	121.2 (6)	C323—C322—H322	119.9
C124—C125—H125	119.4	C324—C323—C322	120.9 (5)
C126—C125—H125	119.4	C324—C323—H323	119.6
C121—C126—C125	120.1 (5)	C322—C323—H323	119.6
C121—C126—H126	119.9	C323—C324—C325	118.1 (4)
C125—C126—H126	119.9	C323—C324—C327	121.1 (5)
C124—C127—H12A	109.5	C325—C324—C327	120.8 (5)
C124—C127—H12B	109.5	C324—C325—C326	121.4 (5)
H12A—C127—H12B	109.5	C324—C325—H325	119.3
C124—C127—H12C	109.5	C326—C325—H325	119.3
H12A—C127—H12C	109.5	C325—C326—C321	119.7 (4)
H12B—C127—H12C	109.5	C325—C326—H326	120.1
C132—C131—C136	119.1 (4)	C321—C326—H326	120.1
C132—C131—P1	120.8 (4)	C324—C327—H32A	109.5
C136—C131—P1	119.9 (4)	C324—C327—H32B	109.5
C131—C132—C133	120.4 (5)	H32A—C327—H32B	109.5
C131—C132—H132	119.8	C324—C327—H32C	109.5
C133—C132—H132	119.8	H32A—C327—H32C	109.5
C134—C133—C132	120.8 (5)	H32B—C327—H32C	109.5
C134—C133—H133	119.6	C336—C331—C332	118.4 (5)
C132—C133—H133	119.6	C336—C331—P3	119.6 (4)
C133—C134—C135	119.1 (5)	C332—C331—P3	121.9 (4)
C133—C134—C137	121.2 (5)	C333—C332—C331	119.8 (5)
C135—C134—C137	119.7 (5)	C333—C332—H332	120.1
C134—C135—C136	120.4 (5)	C331—C332—H332	120.1
C134—C135—H135	119.8	C334—C333—C332	121.7 (5)
C136—C135—H135	119.8	C334—C333—H333	119.1
C131—C136—C135	120.2 (5)	C332—C333—H333	119.1
C131—C136—H136	119.9	C333—C334—C335	118.4 (5)
C135—C136—H136	119.9	C333—C334—C337	121.1 (5)
C134—C137—H13A	109.5	C335—C334—C337	120.6 (5)
C134—C137—H13B	109.5	C336—C335—C334	121.1 (5)
H13A—C137—H13B	109.5	C336—C335—H335	119.5
C134—C137—H13C	109.5	C334—C335—H335	119.5
H13A—C137—H13C	109.5	C335—C336—C331	120.6 (5)
H13B—C137—H13C	109.5	C335—C336—H336	119.7
C212—C211—C216	118.6 (4)	C331—C336—H336	119.7
C212—C211—P2	123.3 (4)	C334—C337—H33A	109.5
C216—C211—P2	118.1 (3)	C334—C337—H33B	109.5
C211—C212—C213	120.7 (5)	H33A—C337—H33B	109.5
C211—C212—H212	119.6	C334—C337—H33C	109.5
C213—C212—H212	119.6	H33A—C337—H33C	109.5
C212—C213—C214	120.7 (5)	H33B—C337—H33C	109.5
C212—C213—H213	119.6
P3—Ag1—P1—C111	122.57 (16)	P2—C211—C216—C215	179.4 (4)
P2—Ag1—P1—C111	−66.41 (16)	C231—P2—C221—C226	51.2 (4)
P3—Ag1—P1—C121	−120.16 (18)	C211—P2—C221—C226	162.2 (4)
P2—Ag1—P1—C121	50.86 (19)	Ag1—P2—C221—C226	−80.7 (4)
P3—Ag1—P1—C131	2.06 (19)	C231—P2—C221—C222	−134.4 (4)
P2—Ag1—P1—C131	173.08 (18)	C211—P2—C221—C222	−23.4 (4)
P3—Ag1—P2—C231	−140.49 (17)	Ag1—P2—C221—C222	93.6 (4)
P1—Ag1—P2—C231	49.53 (18)	C226—C221—C222—C223	−0.2 (6)
P3—Ag1—P2—C211	102.62 (15)	P2—C221—C222—C223	−174.6 (3)
P1—Ag1—P2—C211	−67.37 (15)	C221—C222—C223—C224	0.9 (6)
P3—Ag1—P2—C221	−14.47 (19)	C222—C223—C224—C225	−1.3 (7)
P1—Ag1—P2—C221	175.55 (17)	C222—C223—C224—C227	179.8 (4)
P2—Ag1—P3—C331	−87.84 (16)	C223—C224—C225—C226	1.1 (7)
P1—Ag1—P3—C331	82.65 (15)	C227—C224—C225—C226	−180.0 (5)
P2—Ag1—P3—C321	152.92 (16)	C224—C225—C226—C221	−0.5 (8)
P1—Ag1—P3—C321	−36.58 (17)	C222—C221—C226—C225	0.0 (7)
P2—Ag1—P3—C311	30.84 (18)	P2—C221—C226—C225	174.6 (4)
P1—Ag1—P3—C311	−158.67 (16)	C211—P2—C231—C232	−78.9 (4)
C121—P1—C111—C116	−155.7 (4)	C221—P2—C231—C232	31.5 (5)
C131—P1—C111—C116	90.7 (4)	Ag1—P2—C231—C232	164.6 (4)
Ag1—P1—C111—C116	−35.3 (4)	C211—P2—C231—C236	98.5 (4)
C121—P1—C111—C112	24.3 (4)	C221—P2—C231—C236	−151.0 (4)
C131—P1—C111—C112	−89.3 (4)	Ag1—P2—C231—C236	−18.0 (4)
Ag1—P1—C111—C112	144.7 (3)	C236—C231—C232—C233	−0.5 (7)
C116—C111—C112—C113	0.0 (7)	P2—C231—C232—C233	177.0 (4)
P1—C111—C112—C113	179.9 (3)	C231—C232—C233—C234	−1.4 (8)
C111—C112—C113—C114	−0.2 (7)	C232—C233—C234—C235	2.1 (8)
C112—C113—C114—C115	−0.2 (7)	C232—C233—C234—C237	−177.7 (5)
C112—C113—C114—C117	−178.1 (4)	C233—C234—C235—C236	−1.0 (8)
C113—C114—C115—C116	1.0 (7)	C237—C234—C235—C236	178.8 (5)
C117—C114—C115—C116	178.9 (4)	C234—C235—C236—C231	−0.9 (8)
C114—C115—C116—C111	−1.3 (7)	C232—C231—C236—C235	1.6 (7)
C112—C111—C116—C115	0.8 (7)	P2—C231—C236—C235	−176.0 (4)
P1—C111—C116—C115	−179.2 (4)	C331—P3—C311—C316	70.1 (4)
C111—P1—C121—C126	−111.9 (4)	C321—P3—C311—C316	−179.5 (4)
C131—P1—C121—C126	−0.6 (5)	Ag1—P3—C311—C316	−53.7 (4)
Ag1—P1—C121—C126	125.6 (4)	C331—P3—C311—C312	−109.2 (4)
C111—P1—C121—C122	71.9 (4)	C321—P3—C311—C312	1.2 (4)
C131—P1—C121—C122	−176.7 (4)	Ag1—P3—C311—C312	127.0 (4)
Ag1—P1—C121—C122	−50.6 (4)	C316—C311—C312—C313	−0.3 (7)
C126—C121—C122—C123	−0.5 (7)	P3—C311—C312—C313	179.0 (4)
P1—C121—C122—C123	176.0 (4)	C311—C312—C313—C314	0.2 (7)
C121—C122—C123—C124	−1.1 (8)	C312—C313—C314—C315	−0.5 (7)
C122—C123—C124—C125	1.9 (8)	C312—C313—C314—C317	178.9 (5)
C122—C123—C124—C127	−178.3 (5)	C313—C314—C315—C316	0.9 (7)
C123—C124—C125—C126	−1.3 (8)	C317—C314—C315—C316	−178.4 (5)
C127—C124—C125—C126	178.9 (5)	C314—C315—C316—C311	−1.0 (8)
C122—C121—C126—C125	1.1 (7)	C312—C311—C316—C315	0.7 (7)
P1—C121—C126—C125	−175.0 (4)	P3—C311—C316—C315	−178.7 (4)
C124—C125—C126—C121	−0.3 (8)	C331—P3—C321—C322	12.9 (4)
C111—P1—C131—C132	−20.7 (4)	C311—P3—C321—C322	−95.4 (4)
C121—P1—C131—C132	−132.1 (4)	Ag1—P3—C321—C322	136.0 (4)
Ag1—P1—C131—C132	104.4 (3)	C331—P3—C321—C326	−166.7 (3)
C111—P1—C131—C136	164.4 (4)	C311—P3—C321—C326	85.0 (4)
C121—P1—C131—C136	53.0 (4)	Ag1—P3—C321—C326	−43.6 (4)
Ag1—P1—C131—C136	−70.4 (4)	C326—C321—C322—C323	1.1 (7)
C136—C131—C132—C133	−0.3 (7)	P3—C321—C322—C323	−178.5 (4)
P1—C131—C132—C133	−175.2 (4)	C321—C322—C323—C324	−0.6 (7)
C131—C132—C133—C134	−0.8 (7)	C322—C323—C324—C325	−0.8 (7)
C132—C133—C134—C135	0.2 (7)	C322—C323—C324—C327	177.3 (5)
C132—C133—C134—C137	179.1 (5)	C323—C324—C325—C326	1.8 (7)
C133—C134—C135—C136	1.5 (7)	C327—C324—C325—C326	−176.3 (5)
C137—C134—C135—C136	−177.4 (5)	C324—C325—C326—C321	−1.3 (7)
C132—C131—C136—C135	2.0 (7)	C322—C321—C326—C325	−0.1 (7)
P1—C131—C136—C135	177.0 (4)	P3—C321—C326—C325	179.5 (4)
C134—C135—C136—C131	−2.7 (7)	C321—P3—C331—C336	97.6 (4)
C231—P2—C211—C212	19.0 (5)	C311—P3—C331—C336	−152.3 (3)
C221—P2—C211—C212	−90.7 (4)	Ag1—P3—C331—C336	−25.6 (4)
Ag1—P2—C211—C212	143.3 (4)	C321—P3—C331—C332	−81.5 (4)
C231—P2—C211—C216	−159.7 (4)	C311—P3—C331—C332	28.5 (4)
C221—P2—C211—C216	90.6 (4)	Ag1—P3—C331—C332	155.3 (4)
Ag1—P2—C211—C216	−35.5 (4)	C336—C331—C332—C333	0.0 (7)
C216—C211—C212—C213	1.3 (7)	P3—C331—C332—C333	179.2 (4)
P2—C211—C212—C213	−177.4 (4)	C331—C332—C333—C334	−0.1 (8)
C211—C212—C213—C214	−2.0 (8)	C332—C333—C334—C335	−0.6 (8)
C212—C213—C214—C215	0.6 (7)	C332—C333—C334—C337	179.0 (5)
C212—C213—C214—C217	−178.8 (5)	C333—C334—C335—C336	1.6 (8)
C213—C214—C215—C216	1.3 (8)	C337—C334—C335—C336	−178.1 (5)
C217—C214—C215—C216	−179.3 (5)	C334—C335—C336—C331	−1.8 (7)
C214—C215—C216—C211	−1.9 (7)	C332—C331—C336—C335	1.0 (7)
C212—C211—C216—C215	0.6 (7)	P3—C331—C336—C335	−178.3 (4)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C003—H03B···O03B	0.98	2.41	3.24 (4)	143
C215—H215···O002	0.95	2.45	3.396 (7)	178
C335—H335···O03B	0.95	2.45	3.206 (15)	136
C217—H21B···O01^i	0.98	2.55	3.272 (9)	131
C116—H116···O04B^ii	0.95	2.45	3.073 (9)	123
C115—H115···O01^ii	0.95	2.56	3.417 (8)	150
C323—H323···O02B^iii	0.95	2.39	3.155 (8)	138

Symmetry codes: (i) x+1/2, −y+1/2, z; (ii) x, y, z+1; (iii) −x+1, −y, z+1/2.