Buy article online - an online subscription or single-article purchase is required to access this article.
Download citation
Download citation
link to html
The title compound, [RuCl(C24H16N2)(C15H11N3)]PF6, consists of a monomeric RuII complex cation and a hexa­fluoro­phosphate anion. The coordination environment about the RuII atom is distorted octa­hedral, where the 2,2':6',2''-terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,7-diphen­yl-1,10-phenanthroline (dpphen) ligand is coordinated in a cis fashion and the Cl atom is trans to one of the dpphen N atoms. The Ru-N bond distances are in the range 1.956 (5)-2.096 (5) Å and the Ru-Cl distance is 2.403 (2) Å.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805004691/ob6477sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805004691/ob6477Isup2.hkl
Contains datablock I

CCDC reference: 269838

Key indicators

  • Single-crystal X-ray study
  • T = 296 K
  • Mean [sigma](C-C) = 0.010 Å
  • R factor = 0.083
  • wR factor = 0.201
  • Data-to-parameter ratio = 12.4

checkCIF/PLATON results

No syntax errors found



Alert level B ABSTM02_ALERT_3_B The ratio of expected to reported Tmax/Tmin(RR') is < 0.75 Tmin and Tmax reported: 0.590 0.939 Tmin' and Tmax expected: 0.828 0.939 RR' = 0.713 Please check that your absorption correction is appropriate. PLAT061_ALERT_3_B Tmax/Tmin Range Test RR' too Large ............. 0.71 PLAT601_ALERT_2_B Structure Contains Solvent Accessible VOIDS of . 103.00 A   3
Alert level C RINTA01_ALERT_3_C The value of Rint is greater than 0.10 Rint given 0.105 PLAT020_ALERT_3_C The value of Rint is greater than 0.10 ......... 0.10 PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)... ? PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 3.07 PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT143_ALERT_4_C su on c - Axis Small or Missing (x 100000) ..... 10 Ang. PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.10 Ratio PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for P1 PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 11
0 ALERT level A = In general: serious problem 3 ALERT level B = Potentially serious problem 10 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 5 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: TEXSAN (Molecular Structure Corporation, 2000); program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: SHELXL97 (Sheldrick,1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: TEXSAN.

Chloro(4,7-diphenyl-1,10-phenanthroline)(2,2':6',2''-terpyridine)ruthenium(II) hexafluorophosphate top
Crystal data top
[RuCl(C24H16N2)(C15H11N3)]PF6F(000) = 3408
Mr = 847.16Dx = 1.570 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.7107 Å
a = 42.071 (1) ÅCell parameters from 38559 reflections
b = 8.6042 (1) Åθ = 1.0–27.5°
c = 19.9088 (1) ŵ = 0.63 mm1
β = 96.096 (2)°T = 296 K
V = 7165.9 (2) Å3Needle, red–black
Z = 80.3 × 0.1 × 0.1 mm
Data collection top
Rigaku R-AXIS RAPID imaging-plate
diffractometer
5940 reflections with I > 2σ(I)
Detector resolution: 10.00 pixels mm-1Rint = 0.105
ω scansθmax = 27.5°, θmin = 1.0°
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
h = 5454
Tmin = 0.590, Tmax = 0.939k = 1110
28548 measured reflectionsl = 2525
8145 independent reflections
Refinement top
Refinement on F2H-atom parameters not refined
R[F2 > 2σ(F2)] = 0.083 w = 1/[σ2(Fo2) + (0.1P)2]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.201(Δ/σ)max = 0.045
S = 1.74Δρmax = 2.61 e Å3
5940 reflectionsΔρmin = 0.85 e Å3
478 parameters
Special details top

Refinement. Refinement using reflections with F2 > -10.0 σ(F2). The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.16822 (1)0.07393 (6)0.04791 (2)0.0346 (2)
Cl10.21525 (4)0.0291 (2)0.11157 (9)0.0505 (4)
P10.12598 (6)0.5858 (3)0.2363 (1)0.0677 (6)
F10.1360 (2)0.675 (1)0.3028 (3)0.162 (4)
F20.1545 (1)0.6629 (8)0.2044 (3)0.111 (2)
F30.1463 (2)0.4425 (9)0.2583 (5)0.150 (3)
F40.1167 (2)0.4996 (9)0.1680 (3)0.126 (2)
F50.0956 (2)0.506 (1)0.2628 (4)0.155 (3)
F60.1044 (2)0.7230 (8)0.2102 (5)0.153 (3)
N10.1420 (1)0.0807 (6)0.1317 (2)0.036 (1)
N20.1255 (1)0.1538 (6)0.0047 (2)0.033 (1)
N30.1561 (1)0.1428 (6)0.0121 (3)0.039 (1)
N40.1897 (1)0.0758 (6)0.0345 (3)0.041 (1)
N50.1887 (1)0.2912 (6)0.0543 (3)0.038 (1)
C10.1511 (1)0.0461 (8)0.1956 (3)0.042 (1)
C20.1306 (1)0.0549 (8)0.2460 (3)0.043 (2)
C30.0996 (1)0.0996 (8)0.2315 (3)0.040 (1)
C40.0772 (1)0.1029 (8)0.2851 (3)0.045 (2)
C50.0839 (2)0.189 (1)0.3422 (4)0.065 (2)
C60.0632 (3)0.191 (1)0.3920 (4)0.089 (3)
C70.0349 (2)0.107 (1)0.3831 (5)0.086 (3)
C80.0289 (2)0.020 (1)0.3279 (4)0.078 (3)
C90.0496 (2)0.014 (1)0.2779 (4)0.067 (2)
C100.0894 (1)0.1456 (8)0.1642 (3)0.041 (1)
C110.0587 (2)0.2092 (9)0.1425 (3)0.049 (2)
C120.0506 (1)0.2493 (8)0.0777 (3)0.046 (2)
C130.0713 (1)0.2247 (8)0.0267 (3)0.039 (1)
C140.1024 (1)0.1718 (8)0.0478 (3)0.038 (1)
C150.1112 (1)0.1311 (7)0.1160 (3)0.033 (1)
C160.1174 (1)0.1875 (8)0.0611 (3)0.040 (1)
C170.0872 (1)0.2377 (8)0.0854 (3)0.043 (1)
C180.0632 (1)0.2545 (8)0.0441 (3)0.042 (1)
C190.0307 (2)0.3036 (9)0.0729 (3)0.049 (2)
C200.0037 (2)0.230 (1)0.0554 (4)0.067 (2)
C210.0262 (2)0.266 (2)0.0874 (6)0.092 (3)
C220.0291 (3)0.378 (2)0.1359 (6)0.102 (4)
C230.0031 (3)0.454 (2)0.1527 (5)0.101 (4)
C240.0276 (2)0.418 (1)0.1217 (4)0.073 (3)
C250.1386 (2)0.2482 (9)0.0380 (4)0.054 (2)
C260.1311 (2)0.3902 (10)0.0063 (5)0.072 (2)
C270.1431 (2)0.4184 (9)0.0541 (4)0.067 (2)
C280.1619 (2)0.3149 (9)0.0814 (4)0.062 (2)
C290.1683 (2)0.1733 (8)0.0490 (3)0.046 (2)
C300.1872 (2)0.0508 (8)0.0752 (3)0.043 (1)
C310.2017 (2)0.0504 (9)0.1346 (3)0.054 (2)
C320.2175 (2)0.081 (1)0.1526 (4)0.061 (2)
C330.2200 (2)0.2091 (10)0.1108 (4)0.055 (2)
C340.2055 (1)0.2026 (8)0.0503 (3)0.042 (1)
C350.2057 (1)0.3247 (8)0.0009 (3)0.041 (1)
C360.2212 (2)0.4635 (9)0.0033 (4)0.053 (2)
C370.2199 (2)0.5704 (9)0.0489 (4)0.060 (2)
C380.2032 (2)0.5383 (8)0.1016 (4)0.058 (2)
C390.1881 (2)0.3958 (8)0.1037 (4)0.050 (2)
H10.17250.01130.20770.0510*
H20.13840.02630.29120.0540*
H30.10350.24660.34900.0788*
H40.06830.25220.43150.1041*
H50.02040.11830.41770.1008*
H60.00920.03930.32160.0961*
H70.04510.05150.23940.0792*
H80.04350.22380.17500.0589*
H90.02990.29450.06590.0574*
H100.13340.17610.09200.0485*
H110.08270.25940.13270.0509*
H120.00600.15110.01990.0836*
H130.04550.21660.07480.1123*
H140.04910.40230.16140.1223*
H150.00450.54200.18490.1154*
H160.04640.46670.13500.0878*
H170.13060.22800.08080.0662*
H180.11810.46500.02580.0846*
H190.13840.51560.07700.0810*
H200.17050.33420.12370.0727*
H210.20080.13900.16300.0628*
H220.22670.08460.19460.0728*
H230.23180.30020.12190.0675*
H240.23260.48750.04210.0640*
H250.23140.66700.04720.0698*
H260.20120.61560.13550.0699*
H270.17700.37020.14190.0607*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0297 (2)0.0341 (3)0.0409 (3)0.0017 (2)0.0087 (2)0.0019 (2)
Cl10.0345 (8)0.0511 (10)0.066 (1)0.0025 (7)0.0068 (7)0.0065 (8)
P10.086 (2)0.059 (1)0.063 (1)0.000 (1)0.031 (1)0.001 (1)
F10.220 (8)0.184 (8)0.093 (5)0.075 (7)0.066 (5)0.062 (5)
F20.109 (4)0.117 (5)0.117 (5)0.020 (4)0.060 (4)0.003 (4)
F30.158 (7)0.107 (6)0.181 (8)0.030 (5)0.005 (6)0.049 (5)
F40.170 (7)0.114 (5)0.093 (4)0.009 (5)0.016 (4)0.027 (4)
F50.147 (6)0.152 (7)0.182 (7)0.040 (6)0.089 (6)0.013 (6)
F60.117 (5)0.073 (4)0.262 (9)0.017 (4)0.011 (6)0.004 (5)
N10.033 (2)0.037 (3)0.040 (3)0.005 (2)0.008 (2)0.007 (2)
N20.034 (2)0.029 (3)0.039 (2)0.002 (2)0.009 (2)0.005 (2)
N30.037 (3)0.032 (3)0.047 (3)0.002 (2)0.001 (2)0.004 (2)
N40.032 (2)0.041 (3)0.050 (3)0.003 (2)0.006 (2)0.006 (3)
N50.028 (2)0.033 (3)0.053 (3)0.003 (2)0.008 (2)0.000 (2)
C10.032 (3)0.056 (4)0.038 (3)0.005 (3)0.001 (2)0.002 (3)
C20.039 (3)0.058 (4)0.032 (3)0.002 (3)0.000 (2)0.007 (3)
C30.039 (3)0.044 (4)0.038 (3)0.005 (3)0.010 (2)0.001 (3)
C40.038 (3)0.057 (4)0.041 (3)0.004 (3)0.007 (3)0.011 (3)
C50.073 (5)0.071 (6)0.053 (4)0.006 (4)0.020 (4)0.002 (4)
C60.136 (9)0.082 (7)0.054 (5)0.002 (7)0.034 (6)0.004 (5)
C70.072 (6)0.121 (9)0.070 (6)0.029 (6)0.035 (5)0.024 (6)
C80.038 (4)0.135 (9)0.061 (5)0.001 (5)0.005 (3)0.034 (6)
C90.046 (4)0.106 (7)0.048 (4)0.010 (4)0.006 (3)0.016 (4)
C100.030 (3)0.052 (4)0.042 (3)0.001 (3)0.006 (2)0.004 (3)
C110.041 (3)0.070 (5)0.039 (3)0.016 (3)0.013 (3)0.005 (3)
C120.038 (3)0.055 (4)0.046 (4)0.011 (3)0.008 (3)0.006 (3)
C130.032 (3)0.047 (4)0.039 (3)0.002 (3)0.006 (2)0.003 (3)
C140.030 (3)0.046 (4)0.036 (3)0.001 (3)0.003 (2)0.002 (3)
C150.028 (3)0.034 (3)0.036 (3)0.002 (2)0.005 (2)0.006 (3)
C160.042 (3)0.044 (4)0.036 (3)0.006 (3)0.010 (3)0.005 (3)
C170.042 (3)0.047 (4)0.039 (3)0.001 (3)0.005 (3)0.004 (3)
C180.040 (3)0.046 (4)0.039 (3)0.000 (3)0.003 (3)0.008 (3)
C190.046 (4)0.062 (5)0.040 (3)0.011 (3)0.003 (3)0.005 (3)
C200.045 (4)0.087 (6)0.070 (5)0.009 (4)0.003 (4)0.009 (5)
C210.049 (5)0.127 (10)0.100 (7)0.011 (6)0.008 (5)0.029 (7)
C220.065 (6)0.14 (1)0.090 (7)0.046 (7)0.028 (5)0.017 (7)
C230.099 (7)0.13 (1)0.068 (6)0.066 (7)0.010 (5)0.014 (6)
C240.076 (6)0.084 (7)0.058 (4)0.037 (5)0.001 (4)0.005 (4)
C250.052 (4)0.043 (4)0.065 (4)0.011 (3)0.004 (3)0.011 (3)
C260.082 (6)0.048 (4)0.078 (6)0.023 (4)0.021 (5)0.012 (4)
C270.095 (6)0.036 (4)0.067 (5)0.014 (4)0.011 (4)0.005 (4)
C280.084 (5)0.043 (4)0.057 (4)0.001 (4)0.008 (4)0.009 (4)
C290.045 (4)0.043 (4)0.047 (4)0.006 (3)0.007 (3)0.001 (3)
C300.041 (3)0.041 (4)0.047 (3)0.010 (3)0.001 (3)0.005 (3)
C310.053 (4)0.063 (5)0.046 (4)0.005 (3)0.006 (3)0.014 (3)
C320.051 (4)0.081 (6)0.055 (4)0.001 (4)0.021 (3)0.006 (4)
C330.045 (4)0.064 (5)0.058 (4)0.000 (3)0.016 (3)0.012 (4)
C340.028 (3)0.050 (4)0.050 (3)0.001 (3)0.009 (3)0.006 (3)
C350.025 (3)0.046 (4)0.053 (4)0.002 (3)0.009 (3)0.004 (3)
C360.038 (3)0.045 (4)0.076 (5)0.001 (3)0.009 (3)0.012 (4)
C370.049 (4)0.042 (4)0.090 (5)0.012 (3)0.006 (4)0.004 (4)
C380.050 (4)0.036 (4)0.088 (6)0.007 (3)0.010 (4)0.014 (4)
C390.045 (4)0.043 (4)0.062 (4)0.003 (3)0.015 (3)0.004 (3)
Geometric parameters (Å, º) top
Ru1—Cl12.403 (2)C13—C141.408 (8)
Ru1—N12.096 (5)C13—C181.437 (8)
Ru1—N22.028 (4)C14—C151.412 (8)
Ru1—N32.042 (5)C16—C171.382 (8)
Ru1—N41.956 (5)C16—H100.964
Ru1—N52.057 (5)C17—C181.375 (9)
P1—F11.550 (8)C17—H110.958
P1—F21.565 (7)C18—C191.487 (9)
P1—F31.538 (8)C19—C201.38 (1)
P1—F41.561 (7)C19—C241.38 (1)
P1—F51.589 (9)C20—C211.38 (1)
P1—F61.546 (7)C20—H120.978
N1—C11.324 (8)C21—C221.36 (2)
N1—C151.368 (7)C21—H130.972
N2—C141.372 (8)C22—C231.35 (2)
N2—C161.349 (7)C22—H140.960
N3—C251.309 (9)C23—C241.40 (1)
N3—C291.392 (9)C23—H150.989
N4—C301.355 (8)C24—H160.957
N4—C341.333 (8)C25—C261.39 (1)
N5—C351.373 (8)C25—H170.964
N5—C391.334 (9)C26—C271.37 (1)
C1—C21.395 (9)C26—H180.954
C1—H10.956C27—C281.34 (1)
C2—C31.361 (8)C27—H190.964
C2—H20.956C28—C291.39 (1)
C3—C41.497 (9)C28—H200.966
C3—C101.419 (8)C29—C301.452 (9)
C4—C51.36 (1)C30—C311.385 (10)
C4—C91.38 (1)C31—C321.38 (1)
C5—C61.39 (1)C31—H210.948
C5—H30.959C32—C331.38 (1)
C6—C71.39 (2)C32—H220.957
C6—H40.951C33—C341.406 (10)
C7—C81.33 (1)C33—H230.967
C7—H50.971C34—C351.463 (9)
C8—C91.39 (1)C35—C361.368 (10)
C8—H60.968C36—C371.39 (1)
C9—H70.955C36—H240.975
C10—C111.426 (9)C37—C381.35 (1)
C10—C151.402 (8)C37—H250.962
C11—C121.344 (9)C38—C391.38 (1)
C11—H80.964C38—H260.957
C12—C131.422 (9)C39—H270.961
C12—H90.961
F(1)···C(16)i3.132 (10)C(8)···C(20)iii3.42 (1)
F(1)···C(17)i3.27 (1)C(12)···C(22)iv3.56 (2)
F(1)···C(2)ii3.46 (1)C(16)···C(27)ii3.56 (1)
F(1)···C(27)iii3.59 (1)C(25)···C(38)v3.41 (1)
F(2)···C(1)ii3.304 (10)C(26)···C(39)v3.45 (1)
F(2)···C(25)ii3.397 (10)C(26)···C(38)v3.45 (1)
F(3)···C(28)iii3.37 (1)C(27)···C(36)v3.48 (1)
F(4)···C(26)ii3.47 (1)C(27)···C(35)v3.52 (1)
F(4)···C(25)ii3.57 (1)C(28)···C(36)v3.38 (1)
F(6)···C(2)ii3.117 (10)C(28)···C(37)v3.51 (1)
F(6)···C(3)ii3.277 (9)C(29)···C(37)v3.533 (10)
F(6)···C(1)ii3.436 (10)C(31)···C(37)vi3.554 (10)
F(6)···C(22)iv3.46 (1)C(32)···C(37)vi3.43 (1)
C(7)···C(20)iii3.46 (2)C(32)···C(38)vi3.54 (1)
C(7)···C(18)iii3.58 (1)C(33)···C(36)vi3.507 (10)
C(8)···C(19)iii3.41 (1)C(34)···C(36)vi3.463 (9)
Cl1—Ru1—N193.7 (1)C12—C13—C14117.0 (5)
Cl1—Ru1—N2172.6 (1)C12—C13—C18125.1 (5)
Cl1—Ru1—N390.5 (1)C14—C13—C18117.8 (5)
Cl1—Ru1—N491.0 (1)N2—C14—C13123.2 (5)
Cl1—Ru1—N589.2 (1)N2—C14—C15116.2 (5)
N1—Ru1—N279.1 (2)C13—C14—C15120.6 (5)
N1—Ru1—N399.8 (2)N1—C15—C10122.8 (5)
N1—Ru1—N4175.3 (2)N1—C15—C14116.4 (5)
N1—Ru1—N5100.2 (2)C10—C15—C14120.8 (5)
N2—Ru1—N389.1 (2)N2—C16—C17122.4 (6)
N2—Ru1—N496.2 (2)N2—C16—H10118.4
N2—Ru1—N593.7 (2)C17—C16—H10119.2
N3—Ru1—N480.5 (2)C16—C17—C18122.0 (6)
N3—Ru1—N5159.9 (2)C16—C17—H11118.8
N4—Ru1—N579.4 (2)C18—C17—H11119.2
F1—P1—F289.2 (4)C13—C18—C17117.1 (5)
F1—P1—F393.5 (5)C13—C18—C19122.7 (5)
F1—P1—F4178.0 (5)C17—C18—C19120.2 (5)
F1—P1—F594.9 (5)C18—C19—C20121.5 (7)
F1—P1—F690.4 (5)C18—C19—C24119.3 (7)
F2—P1—F391.6 (4)C20—C19—C24119.1 (7)
F2—P1—F488.9 (4)C19—C20—C21121.0 (9)
F2—P1—F5175.5 (4)C19—C20—H12118.7
F2—P1—F689.4 (4)C21—C20—H12120.3
F3—P1—F487.0 (4)C20—C21—C22119.6 (10)
F3—P1—F590.2 (5)C20—C21—H13121.8
F3—P1—F6176.1 (5)C22—C21—H13118.6
F4—P1—F587.1 (4)C21—C22—C23120.5 (10)
F4—P1—F689.2 (4)C21—C22—H14122.6
F5—P1—F688.6 (4)C23—C22—H14116.8
Ru1—N1—C1129.4 (4)C22—C23—C24120 (1)
Ru1—N1—C15113.0 (4)C22—C23—H15122.7
C1—N1—C15117.6 (5)C24—C23—H15116.3
Ru1—N2—C14115.3 (3)C19—C24—C23118.8 (9)
Ru1—N2—C16127.3 (4)C19—C24—H16119.1
C14—N2—C16117.4 (5)C23—C24—H16122.0
Ru1—N3—C25128.7 (5)N3—C25—C26122.5 (7)
Ru1—N3—C29112.1 (4)N3—C25—H17119.1
C25—N3—C29119.2 (6)C26—C25—H17118.3
Ru1—N4—C30118.8 (4)C25—C26—C27117.7 (8)
Ru1—N4—C34119.4 (4)C25—C26—H18121.2
C30—N4—C34121.8 (6)C27—C26—H18121.1
Ru1—N5—C35113.0 (4)C26—C27—C28121.5 (7)
Ru1—N5—C39128.2 (5)C26—C27—H19119.5
C35—N5—C39118.7 (5)C28—C27—H19119.0
N1—C1—C2122.7 (5)C27—C28—C29119.1 (7)
N1—C1—H1118.9C27—C28—H20122.0
C2—C1—H1118.4C29—C28—H20118.9
C1—C2—C3121.0 (5)N3—C29—C28119.9 (6)
C1—C2—H2119.1N3—C29—C30116.4 (6)
C3—C2—H2119.9C28—C29—C30123.7 (6)
C2—C3—C4121.0 (5)N4—C30—C29112.2 (6)
C2—C3—C10117.7 (6)N4—C30—C31119.6 (6)
C4—C3—C10121.3 (5)C29—C30—C31128.1 (6)
C3—C4—C5121.0 (6)C30—C31—C32119.5 (7)
C3—C4—C9120.0 (6)C30—C31—H21121.0
C5—C4—C9119.0 (7)C32—C31—H21119.5
C4—C5—C6120.9 (8)C31—C32—C33120.4 (7)
C4—C5—H3119.9C31—C32—H22120.5
C6—C5—H3119.2C33—C32—H22119.1
C5—C6—C7119.8 (8)C32—C33—C34118.2 (7)
C5—C6—H4119.8C32—C33—H23121.2
C7—C6—H4120.4C34—C33—H23120.6
C6—C7—C8118.9 (9)N4—C34—C33120.4 (6)
C6—C7—H5116.9N4—C34—C35112.8 (5)
C8—C7—H5124.2C33—C34—C35126.8 (6)
C7—C8—C9122.2 (9)N5—C35—C34115.2 (5)
C7—C8—H6119.2N5—C35—C36121.4 (6)
C9—C8—H6118.6C34—C35—C36123.4 (6)
C4—C9—C8119.2 (8)C35—C36—C37118.4 (7)
C4—C9—H7120.2C35—C36—H24120.8
C8—C9—H7120.7C37—C36—H24120.7
C3—C10—C11124.4 (6)C36—C37—C38120.4 (7)
C3—C10—C15117.9 (5)C36—C37—H25119.1
C11—C10—C15117.7 (5)C38—C37—H25120.4
C10—C11—C12121.2 (6)C37—C38—C39118.8 (7)
C10—C11—H8119.4C37—C38—H26119.7
C12—C11—H8119.4C39—C38—H26121.4
C11—C12—C13122.4 (6)N5—C39—C38122.1 (7)
C11—C12—H9118.1N5—C39—H27118.6
C13—C12—H9119.5C38—C39—H27119.3
Symmetry codes: (i) x, y+1, z+1/2; (ii) x, y+1, z; (iii) x, y, z+1/2; (iv) x, y+1, z; (v) x, y1, z; (vi) x+1/2, y+1/2, z.
 

Subscribe to Acta Crystallographica Section E: Crystallographic Communications

The full text of this article is available to subscribers to the journal.

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.
E-mail address* 
Repeat e-mail address* 
(for error checking) 

Format*   PDF (US $40)
   HTML (US $40)
   PDF+HTML (US $50)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number 
(non-UK EC countries only) 
Country* 
 

Terms and conditions of use
Contact us

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds