Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806042851/ob2085sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806042851/ob2085Isup2.hkl |
CCDC reference: 628037
Key indicators
- Single-crystal X-ray study
- T = 273 K
- Mean (C-C) = 0.004 Å
- Disorder in main residue
- R factor = 0.041
- wR factor = 0.121
- Data-to-parameter ratio = 11.2
checkCIF/PLATON results
No syntax errors found
Alert level B PLAT411_ALERT_2_B Short Inter H...H Contact H20A .. H24A .. 2.07 Ang.
Alert level C PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C23' PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C23 PLAT301_ALERT_3_C Main Residue Disorder ......................... 15.00 Perc.
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 28.24 From the CIF: _reflns_number_total 3070 Count of symmetry unique reflns 3144 Completeness (_total/calc) 97.65% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 0 Fraction of Friedel pairs measured 0.000 Are heavy atom types Z>Si present no PLAT791_ALERT_1_G Confirm the Absolute Configuration of C3 = . R PLAT791_ALERT_1_G Confirm the Absolute Configuration of C14 = . S
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 3 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check
Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.
C25H29NO3 | Dx = 1.149 Mg m−3 |
Mr = 391.49 | Melting point: 384 K |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 5993 reflections |
a = 10.2911 (2) Å | θ = 2.0–28.2° |
b = 14.0805 (3) Å | µ = 0.08 mm−1 |
c = 15.6118 (3) Å | T = 273 K |
V = 2262.21 (8) Å3 | Block, colorless |
Z = 4 | 0.31 × 0.25 × 0.19 mm |
F(000) = 840 |
Bruker SMART APEX-2 CCD area-detector diffractometer | 3070 independent reflections |
Radiation source: fine-focus sealed tube | 2359 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.025 |
φ and ω scans | θmax = 28.2°, θmin = 2.0° |
Absorption correction: multi-scan (SADABS; Bruker, 1998) | h = −13→13 |
Tmin = 0.971, Tmax = 0.979 | k = −18→18 |
20251 measured reflections | l = −20→20 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.041 | H-atom parameters constrained |
wR(F2) = 0.121 | w = 1/[σ2(Fo2) + (0.0654P)2 + 0.1915P] where P = (Fo2 + 2Fc2)/3 |
S = 1.01 | (Δ/σ)max = 0.001 |
3070 reflections | Δρmax = 0.20 e Å−3 |
275 parameters | Δρmin = −0.19 e Å−3 |
17 restraints | Extinction correction: SHELXL97 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.043 (6) |
Experimental. Spectroscopic analysis: 1H NMR (CDCl3, δ, p.p.m.): 7.37–6.00 (8H, m, Ar), 5.01 (s, 1H, PhCH–), 3.49–3.44 (q, 1H), 3.23–3.13 (m, 2H), 1.61 (s, 3H), 1.67–1.64 (m, 2H), 0.97 (s, 3H), 0.82–0.79 (t, 3H); 13C NMR (CDCl3, δ, p.p.m.): 172.4, 158.0, 154.1, 141.85–106.20 (Ar), 83.3, 68.0, 40.4, 37.4, 29.8, 28.1, 24.5, 12.4; ESI-MS for C25H29O3N, Calcd. 414(M+Na+); Found: 414(M+Na+). |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
O1 | 0.44076 (19) | 0.93655 (14) | 0.04012 (15) | 0.0901 (6) | |
O2 | 0.37297 (16) | 0.79593 (12) | −0.00837 (12) | 0.0718 (5) | |
O3 | 0.06448 (18) | 0.92985 (11) | 0.14736 (11) | 0.0714 (5) | |
N1 | 0.23632 (17) | 0.87519 (12) | 0.07545 (12) | 0.0546 (4) | |
C1 | 0.3578 (2) | 0.87749 (18) | 0.03624 (17) | 0.0657 (6) | |
C2 | 0.2493 (2) | 0.74262 (18) | −0.01161 (15) | 0.0623 (6) | |
C3 | 0.1803 (2) | 0.77892 (14) | 0.06982 (13) | 0.0519 (5) | |
H3A | 0.0867 | 0.7837 | 0.0588 | 0.062* | |
C4 | 0.2836 (3) | 0.63844 (19) | −0.01243 (19) | 0.0784 (7) | |
H4A | 0.3256 | 0.6230 | −0.0656 | 0.118* | |
H4B | 0.2059 | 0.6013 | −0.0066 | 0.118* | |
H4C | 0.3413 | 0.6247 | 0.0343 | 0.118* | |
C5 | 0.1764 (3) | 0.7738 (3) | −0.09173 (17) | 0.0897 (9) | |
H5A | 0.2210 | 0.7507 | −0.1416 | 0.135* | |
H5B | 0.1725 | 0.8418 | −0.0936 | 0.135* | |
H5C | 0.0899 | 0.7484 | −0.0905 | 0.135* | |
C6 | 0.2025 (2) | 0.72197 (15) | 0.15048 (13) | 0.0555 (5) | |
C7 | 0.1146 (3) | 0.65228 (16) | 0.17310 (17) | 0.0698 (7) | |
H7A | 0.0411 | 0.6422 | 0.1396 | 0.084* | |
C8 | 0.1352 (4) | 0.59704 (19) | 0.2456 (2) | 0.0893 (10) | |
H8A | 0.0756 | 0.5500 | 0.2600 | 0.107* | |
C9 | 0.2415 (5) | 0.6110 (2) | 0.29565 (19) | 0.1001 (11) | |
H9A | 0.2543 | 0.5739 | 0.3442 | 0.120* | |
C10 | 0.3300 (4) | 0.6801 (3) | 0.27416 (18) | 0.0986 (10) | |
H10A | 0.4029 | 0.6895 | 0.3083 | 0.118* | |
C11 | 0.3112 (3) | 0.7359 (2) | 0.20190 (16) | 0.0756 (7) | |
H11A | 0.3714 | 0.7826 | 0.1879 | 0.091* | |
C12 | 0.1689 (2) | 0.94840 (15) | 0.11507 (13) | 0.0542 (5) | |
C13 | 0.2230 (3) | 1.04713 (15) | 0.11489 (14) | 0.0613 (6) | |
H13A | 0.3062 | 1.0474 | 0.0857 | 0.074* | |
H13B | 0.2369 | 1.0679 | 0.1734 | 0.074* | |
C14 | 0.1294 (2) | 1.11633 (14) | 0.06963 (13) | 0.0530 (5) | |
H14A | 0.0448 | 1.1112 | 0.0981 | 0.064* | |
C15 | 0.1107 (2) | 1.08751 (15) | −0.02319 (13) | 0.0532 (5) | |
C16 | −0.0090 (3) | 1.0616 (2) | −0.05399 (16) | 0.0715 (7) | |
H16A | −0.0805 | 1.0625 | −0.0176 | 0.086* | |
C17 | −0.0251 (3) | 1.0341 (3) | −0.13893 (19) | 0.0907 (9) | |
H17A | −0.1069 | 1.0166 | −0.1587 | 0.109* | |
C18 | 0.0779 (4) | 1.0325 (2) | −0.19304 (17) | 0.0877 (9) | |
H18A | 0.0669 | 1.0141 | −0.2498 | 0.105* | |
C19 | 0.1976 (3) | 1.0580 (2) | −0.16365 (16) | 0.0868 (9) | |
H19A | 0.2683 | 1.0575 | −0.2007 | 0.104* | |
C20 | 0.2145 (3) | 1.0845 (2) | −0.07952 (16) | 0.0739 (7) | |
H20A | 0.2971 | 1.1007 | −0.0602 | 0.089* | |
C21 | 0.1760 (3) | 1.21898 (14) | 0.07973 (14) | 0.0623 (6) | 0.196 (11) |
H21B | 0.2703 | 1.2188 | 0.0713 | 0.075* | 0.196 (11) |
C22 | 0.151 (3) | 1.2576 (15) | 0.1696 (6) | 0.0766 (13) | 0.196 (11) |
H22A | 0.2300 | 1.2823 | 0.1946 | 0.092* | 0.196 (11) |
H22B | 0.1166 | 1.2082 | 0.2066 | 0.092* | 0.196 (11) |
C23 | 0.051 (3) | 1.3370 (13) | 0.1578 (13) | 0.110 (2) | 0.196 (11) |
H23A | −0.0371 | 1.3123 | 0.1627 | 0.132* | 0.196 (11) |
H23B | 0.0627 | 1.3864 | 0.2004 | 0.132* | 0.196 (11) |
C24 | 0.075 (3) | 1.3752 (10) | 0.0682 (13) | 0.1048 (17) | 0.196 (11) |
H24A | −0.0035 | 1.4017 | 0.0439 | 0.126* | 0.196 (11) |
H24B | 0.1419 | 1.4240 | 0.0691 | 0.126* | 0.196 (11) |
C25 | 0.120 (3) | 1.2897 (12) | 0.0173 (8) | 0.0820 (13) | 0.196 (11) |
H25A | 0.0475 | 1.2619 | −0.0133 | 0.098* | 0.196 (11) |
H25B | 0.1856 | 1.3084 | −0.0241 | 0.098* | 0.196 (11) |
C21' | 0.1760 (3) | 1.21898 (14) | 0.07973 (14) | 0.0623 (6) | 0.804 (11) |
H21A | 0.2594 | 1.2263 | 0.0501 | 0.075* | 0.804 (11) |
C22' | 0.1923 (6) | 1.2500 (4) | 0.1744 (2) | 0.0766 (13) | 0.804 (11) |
H22C | 0.1481 | 1.2059 | 0.2122 | 0.092* | 0.804 (11) |
H22D | 0.2836 | 1.2518 | 0.1898 | 0.092* | 0.804 (11) |
C23' | 0.1331 (9) | 1.3477 (3) | 0.1814 (3) | 0.110 (2) | 0.804 (11) |
H23C | 0.0542 | 1.3452 | 0.2154 | 0.132* | 0.804 (11) |
H23D | 0.1935 | 1.3908 | 0.2090 | 0.132* | 0.804 (11) |
C24' | 0.1033 (6) | 1.3812 (3) | 0.0940 (4) | 0.1048 (17) | 0.804 (11) |
H24C | 0.1763 | 1.4160 | 0.0704 | 0.126* | 0.804 (11) |
H24D | 0.0277 | 1.4224 | 0.0944 | 0.126* | 0.804 (11) |
C25' | 0.0769 (5) | 1.2923 (3) | 0.0422 (4) | 0.0820 (13) | 0.804 (11) |
H25C | 0.0925 | 1.3032 | −0.0183 | 0.098* | 0.804 (11) |
H25D | −0.0119 | 1.2708 | 0.0500 | 0.098* | 0.804 (11) |
U11 | U22 | U33 | U12 | U13 | U23 | |
O1 | 0.0665 (10) | 0.0701 (11) | 0.1337 (18) | −0.0101 (10) | 0.0223 (11) | 0.0069 (11) |
O2 | 0.0618 (9) | 0.0691 (10) | 0.0847 (11) | 0.0037 (8) | 0.0266 (9) | −0.0014 (9) |
O3 | 0.0817 (11) | 0.0600 (9) | 0.0726 (10) | 0.0062 (9) | 0.0290 (9) | 0.0003 (8) |
N1 | 0.0552 (9) | 0.0472 (9) | 0.0615 (10) | 0.0012 (8) | 0.0116 (8) | 0.0059 (8) |
C1 | 0.0586 (13) | 0.0582 (13) | 0.0804 (16) | 0.0052 (11) | 0.0156 (12) | 0.0120 (12) |
C2 | 0.0652 (13) | 0.0654 (13) | 0.0562 (11) | 0.0001 (11) | 0.0122 (11) | −0.0026 (10) |
C3 | 0.0543 (11) | 0.0470 (10) | 0.0545 (11) | −0.0001 (9) | 0.0101 (9) | −0.0002 (9) |
C4 | 0.0903 (18) | 0.0676 (15) | 0.0773 (15) | 0.0069 (14) | 0.0212 (15) | −0.0144 (13) |
C5 | 0.099 (2) | 0.114 (2) | 0.0559 (13) | 0.009 (2) | 0.0052 (14) | 0.0030 (15) |
C6 | 0.0707 (13) | 0.0446 (10) | 0.0513 (10) | 0.0032 (10) | 0.0128 (10) | −0.0024 (9) |
C7 | 0.0856 (17) | 0.0540 (12) | 0.0698 (14) | −0.0047 (12) | 0.0226 (13) | −0.0023 (11) |
C8 | 0.133 (3) | 0.0532 (14) | 0.0812 (19) | −0.0048 (16) | 0.045 (2) | 0.0041 (13) |
C9 | 0.167 (4) | 0.0748 (19) | 0.0586 (15) | 0.018 (2) | 0.021 (2) | 0.0149 (14) |
C10 | 0.136 (3) | 0.100 (2) | 0.0598 (14) | 0.011 (2) | −0.0135 (18) | 0.0079 (16) |
C11 | 0.0961 (19) | 0.0694 (15) | 0.0613 (13) | −0.0067 (15) | −0.0014 (13) | 0.0041 (12) |
C12 | 0.0663 (13) | 0.0497 (11) | 0.0467 (10) | 0.0061 (10) | 0.0010 (10) | 0.0049 (9) |
C13 | 0.0756 (14) | 0.0515 (12) | 0.0567 (11) | 0.0011 (11) | −0.0071 (11) | 0.0024 (10) |
C14 | 0.0629 (12) | 0.0485 (10) | 0.0477 (10) | 0.0047 (10) | 0.0050 (10) | 0.0026 (9) |
C15 | 0.0649 (12) | 0.0485 (11) | 0.0462 (10) | 0.0007 (9) | 0.0011 (9) | 0.0041 (9) |
C16 | 0.0653 (14) | 0.0866 (18) | 0.0627 (13) | −0.0051 (13) | −0.0003 (12) | −0.0058 (13) |
C17 | 0.0868 (18) | 0.112 (2) | 0.0735 (17) | −0.0086 (18) | −0.0163 (16) | −0.0139 (17) |
C18 | 0.121 (2) | 0.094 (2) | 0.0478 (12) | 0.0019 (19) | −0.0050 (16) | −0.0064 (13) |
C19 | 0.103 (2) | 0.103 (2) | 0.0546 (13) | −0.0093 (19) | 0.0192 (15) | −0.0070 (14) |
C20 | 0.0745 (15) | 0.0870 (18) | 0.0600 (13) | −0.0106 (14) | 0.0095 (13) | −0.0055 (13) |
C21 | 0.0833 (16) | 0.0481 (11) | 0.0556 (11) | 0.0031 (11) | 0.0008 (12) | 0.0007 (10) |
C22 | 0.101 (4) | 0.0645 (17) | 0.0642 (15) | 0.002 (2) | −0.0116 (18) | −0.0112 (13) |
C23 | 0.164 (6) | 0.071 (2) | 0.095 (3) | 0.009 (3) | 0.022 (4) | −0.023 (2) |
C24 | 0.109 (4) | 0.0638 (18) | 0.142 (5) | 0.014 (2) | −0.031 (3) | −0.015 (2) |
C25 | 0.103 (3) | 0.0579 (16) | 0.085 (3) | 0.019 (2) | −0.008 (2) | 0.0039 (18) |
C21' | 0.0833 (16) | 0.0481 (11) | 0.0556 (11) | 0.0031 (11) | 0.0008 (12) | 0.0007 (10) |
C22' | 0.101 (4) | 0.0645 (17) | 0.0642 (15) | 0.002 (2) | −0.0116 (18) | −0.0112 (13) |
C23' | 0.164 (6) | 0.071 (2) | 0.095 (3) | 0.009 (3) | 0.022 (4) | −0.023 (2) |
C24' | 0.109 (4) | 0.0638 (18) | 0.142 (5) | 0.014 (2) | −0.031 (3) | −0.015 (2) |
C25' | 0.103 (3) | 0.0579 (16) | 0.085 (3) | 0.019 (2) | −0.008 (2) | 0.0039 (18) |
O1—C1 | 1.193 (3) | C15—C16 | 1.372 (3) |
O2—C1 | 1.352 (3) | C15—C20 | 1.384 (3) |
O2—C2 | 1.478 (3) | C16—C17 | 1.392 (4) |
O3—C12 | 1.215 (3) | C16—H16A | 0.9300 |
N1—C12 | 1.388 (3) | C17—C18 | 1.355 (4) |
N1—C1 | 1.393 (3) | C17—H17A | 0.9300 |
N1—C3 | 1.476 (3) | C18—C19 | 1.362 (5) |
C2—C4 | 1.509 (4) | C18—H18A | 0.9300 |
C2—C5 | 1.523 (4) | C19—C20 | 1.377 (4) |
C2—C3 | 1.544 (3) | C19—H19A | 0.9300 |
C3—C6 | 1.510 (3) | C20—H20A | 0.9300 |
C3—H3A | 0.9800 | C21—C25 | 1.507 (8) |
C4—H4A | 0.9600 | C21—C22 | 1.527 (9) |
C4—H4B | 0.9600 | C21—H21B | 0.9800 |
C4—H4C | 0.9600 | C22—C23 | 1.531 (9) |
C5—H5A | 0.9600 | C22—H22A | 0.9700 |
C5—H5B | 0.9600 | C22—H22B | 0.9700 |
C5—H5C | 0.9600 | C23—C24 | 1.521 (10) |
C6—C7 | 1.380 (3) | C23—H23A | 0.9700 |
C6—C11 | 1.391 (4) | C23—H23B | 0.9700 |
C7—C8 | 1.390 (4) | C24—C25 | 1.514 (9) |
C7—H7A | 0.9300 | C24—H24A | 0.9700 |
C8—C9 | 1.358 (5) | C24—H24B | 0.9700 |
C8—H8A | 0.9300 | C25—H25A | 0.9700 |
C9—C10 | 1.375 (5) | C25—H25B | 0.9700 |
C9—H9A | 0.9300 | C22'—C23' | 1.509 (6) |
C10—C11 | 1.388 (4) | C22'—H22C | 0.9700 |
C10—H10A | 0.9300 | C22'—H22D | 0.9700 |
C11—H11A | 0.9300 | C23'—C24' | 1.475 (7) |
C12—C13 | 1.497 (3) | C23'—H23C | 0.9700 |
C13—C14 | 1.541 (3) | C23'—H23D | 0.9700 |
C13—H13A | 0.9700 | C24'—C25' | 1.515 (6) |
C13—H13B | 0.9700 | C24'—H24C | 0.9700 |
C14—C15 | 1.517 (3) | C24'—H24D | 0.9700 |
C14—C21 | 1.531 (3) | C25'—H25C | 0.9700 |
C14—H14A | 0.9800 | C25'—H25D | 0.9700 |
C1—O2—C2 | 110.48 (17) | C16—C15—C14 | 121.3 (2) |
C12—N1—C1 | 128.9 (2) | C20—C15—C14 | 121.1 (2) |
C12—N1—C3 | 120.87 (17) | C15—C16—C17 | 121.0 (3) |
C1—N1—C3 | 110.26 (18) | C15—C16—H16A | 119.5 |
O1—C1—O2 | 122.4 (2) | C17—C16—H16A | 119.5 |
O1—C1—N1 | 129.5 (2) | C18—C17—C16 | 120.4 (3) |
O2—C1—N1 | 108.1 (2) | C18—C17—H17A | 119.8 |
O2—C2—C4 | 107.0 (2) | C16—C17—H17A | 119.8 |
O2—C2—C5 | 107.8 (2) | C17—C18—C19 | 119.5 (2) |
C4—C2—C5 | 112.8 (2) | C17—C18—H18A | 120.2 |
O2—C2—C3 | 101.54 (17) | C19—C18—H18A | 120.2 |
C4—C2—C3 | 115.9 (2) | C18—C19—C20 | 120.5 (3) |
C5—C2—C3 | 110.7 (2) | C18—C19—H19A | 119.8 |
N1—C3—C6 | 112.27 (18) | C20—C19—H19A | 119.8 |
N1—C3—C2 | 99.97 (17) | C19—C20—C15 | 121.1 (3) |
C6—C3—C2 | 116.19 (17) | C19—C20—H20A | 119.4 |
N1—C3—H3A | 109.3 | C15—C20—H20A | 119.4 |
C6—C3—H3A | 109.3 | C25—C21—C22 | 107.0 (5) |
C2—C3—H3A | 109.3 | C25—C21—C14 | 116.0 (9) |
C2—C4—H4A | 109.5 | C22—C21—C14 | 112.2 (11) |
C2—C4—H4B | 109.5 | C25—C21—H21B | 107.1 |
H4A—C4—H4B | 109.5 | C22—C21—H21B | 107.1 |
C2—C4—H4C | 109.5 | C14—C21—H21B | 107.1 |
H4A—C4—H4C | 109.5 | C21—C22—C23 | 105.4 (6) |
H4B—C4—H4C | 109.5 | C21—C22—H22A | 110.7 |
C2—C5—H5A | 109.5 | C23—C22—H22A | 110.7 |
C2—C5—H5B | 109.5 | C21—C22—H22B | 110.7 |
H5A—C5—H5B | 109.5 | C23—C22—H22B | 110.7 |
C2—C5—H5C | 109.5 | H22A—C22—H22B | 108.8 |
H5A—C5—H5C | 109.5 | C24—C23—C22 | 104.8 (7) |
H5B—C5—H5C | 109.5 | C24—C23—H23A | 110.8 |
C7—C6—C11 | 118.7 (2) | C22—C23—H23A | 110.8 |
C7—C6—C3 | 119.4 (2) | C24—C23—H23B | 110.8 |
C11—C6—C3 | 121.9 (2) | C22—C23—H23B | 110.8 |
C6—C7—C8 | 120.4 (3) | H23A—C23—H23B | 108.9 |
C6—C7—H7A | 119.8 | C25—C24—C23 | 104.6 (7) |
C8—C7—H7A | 119.8 | C25—C24—H24A | 110.8 |
C9—C8—C7 | 120.7 (3) | C23—C24—H24A | 110.8 |
C9—C8—H8A | 119.6 | C25—C24—H24B | 110.8 |
C7—C8—H8A | 119.6 | C23—C24—H24B | 110.8 |
C8—C9—C10 | 119.7 (3) | H24A—C24—H24B | 108.9 |
C8—C9—H9A | 120.2 | C21—C25—C24 | 107.6 (6) |
C10—C9—H9A | 120.2 | C21—C25—H25A | 110.2 |
C9—C10—C11 | 120.5 (3) | C24—C25—H25A | 110.2 |
C9—C10—H10A | 119.8 | C21—C25—H25B | 110.2 |
C11—C10—H10A | 119.8 | C24—C25—H25B | 110.2 |
C10—C11—C6 | 120.1 (3) | H25A—C25—H25B | 108.5 |
C10—C11—H11A | 120.0 | C23'—C22'—H22C | 110.5 |
C6—C11—H11A | 120.0 | C23'—C22'—H22D | 110.5 |
O3—C12—N1 | 117.9 (2) | H22C—C22'—H22D | 108.6 |
O3—C12—C13 | 121.9 (2) | C24'—C23'—C22' | 108.0 (3) |
N1—C12—C13 | 120.2 (2) | C24'—C23'—H23C | 110.1 |
C12—C13—C14 | 110.8 (2) | C22'—C23'—H23C | 110.1 |
C12—C13—H13A | 109.5 | C24'—C23'—H23D | 110.1 |
C14—C13—H13A | 109.5 | C22'—C23'—H23D | 110.1 |
C12—C13—H13B | 109.5 | H23C—C23'—H23D | 108.4 |
C14—C13—H13B | 109.5 | C23'—C24'—C25' | 105.5 (3) |
H13A—C13—H13B | 108.1 | C23'—C24'—H24C | 110.6 |
C15—C14—C21 | 112.99 (17) | C25'—C24'—H24C | 110.6 |
C15—C14—C13 | 110.38 (18) | C23'—C24'—H24D | 110.6 |
C21—C14—C13 | 110.76 (19) | C25'—C24'—H24D | 110.6 |
C15—C14—H14A | 107.5 | H24C—C24'—H24D | 108.8 |
C21—C14—H14A | 107.5 | C24'—C25'—H25C | 111.1 |
C13—C14—H14A | 107.5 | C24'—C25'—H25D | 111.1 |
C16—C15—C20 | 117.5 (2) | H25C—C25'—H25D | 109.1 |
C2—O2—C1—O1 | −172.3 (2) | C3—N1—C12—O3 | 2.4 (3) |
C2—O2—C1—N1 | 9.6 (3) | C1—N1—C12—C13 | 3.7 (3) |
C12—N1—C1—O1 | 14.4 (4) | C3—N1—C12—C13 | −175.75 (19) |
C3—N1—C1—O1 | −166.1 (3) | O3—C12—C13—C14 | −58.5 (3) |
C12—N1—C1—O2 | −167.7 (2) | N1—C12—C13—C14 | 119.6 (2) |
C3—N1—C1—O2 | 11.8 (3) | C12—C13—C14—C15 | −61.5 (2) |
C1—O2—C2—C4 | −147.4 (2) | C12—C13—C14—C21 | 172.56 (18) |
C1—O2—C2—C5 | 90.9 (2) | C21—C14—C15—C16 | −117.6 (3) |
C1—O2—C2—C3 | −25.5 (2) | C13—C14—C15—C16 | 117.7 (3) |
C12—N1—C3—C6 | −83.1 (2) | C21—C14—C15—C20 | 63.7 (3) |
C1—N1—C3—C6 | 97.4 (2) | C13—C14—C15—C20 | −60.9 (3) |
C12—N1—C3—C2 | 153.16 (19) | C20—C15—C16—C17 | −0.4 (4) |
C1—N1—C3—C2 | −26.4 (2) | C14—C15—C16—C17 | −179.1 (3) |
O2—C2—C3—N1 | 29.5 (2) | C15—C16—C17—C18 | −0.1 (5) |
C4—C2—C3—N1 | 145.1 (2) | C16—C17—C18—C19 | 0.1 (5) |
C5—C2—C3—N1 | −84.7 (2) | C17—C18—C19—C20 | 0.5 (5) |
O2—C2—C3—C6 | −91.5 (2) | C18—C19—C20—C15 | −1.1 (5) |
C4—C2—C3—C6 | 24.1 (3) | C16—C15—C20—C19 | 1.0 (4) |
C5—C2—C3—C6 | 154.2 (2) | C14—C15—C20—C19 | 179.7 (3) |
N1—C3—C6—C7 | 151.4 (2) | C15—C14—C21—C25 | 37.1 (10) |
C2—C3—C6—C7 | −94.4 (2) | C13—C14—C21—C25 | 161.5 (9) |
N1—C3—C6—C11 | −30.3 (3) | C15—C14—C21—C22 | 160.5 (9) |
C2—C3—C6—C11 | 83.9 (3) | C13—C14—C21—C22 | −75.1 (10) |
C11—C6—C7—C8 | −0.3 (3) | C25—C21—C22—C23 | 14 (2) |
C3—C6—C7—C8 | 178.0 (2) | C14—C21—C22—C23 | −114.2 (16) |
C6—C7—C8—C9 | 0.4 (4) | C21—C22—C23—C24 | −29 (2) |
C7—C8—C9—C10 | −0.3 (5) | C22—C23—C24—C25 | 33 (2) |
C8—C9—C10—C11 | 0.2 (5) | C22—C21—C25—C24 | 6 (2) |
C9—C10—C11—C6 | −0.2 (5) | C14—C21—C25—C24 | 132.3 (17) |
C7—C6—C11—C10 | 0.2 (4) | C23—C24—C25—C21 | −24 (2) |
C3—C6—C11—C10 | −178.1 (2) | C22'—C23'—C24'—C25' | 29.0 (6) |
C1—N1—C12—O3 | −178.1 (2) |
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