(Acetato-κO)[benzoyl­acetone (4-methoxy­benzoyl)­hydrazonato-κ³O,O′,N](quinoline-κN)­zinc(II)

In the title complex, [Zn(C₁₈H₁₇N₂O₃)(C₂H₃O₂)(C₉H₇N)], the Zn^II atom is coordinated by two O atoms and one N atom from the tridentate hydrazone ligand, the N atom from the quinoline mol­ecule and one O atom from the acetate group, leading to a distorted trigonal bipyramidal environment for the metal atom. The two O atoms of the deprotonated hydrazone ligand occupy the axial sites. A hydrogen-bonded dimer is formed through intermolecular hydrogen bonds across a center of inversion.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.045
• wR factor = 0.120
• Data-to-parameter ratio = 17.4

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Zn1    -   O5      ..      17.43 su

Alert level C
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O1     -   C7      ..       5.83 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Zn1    -   O4      ..       7.62 su
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....         O5
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C28

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

(Acetato-κO)[benzoylacetone (4-methoxybenzoyl)hydrazonato- κ³O,O',N](quinoline-κN)zinc(II)

Crystal data

[Zn(C18H17N2O3)(C2H3O2)(C9H7N)]	Z = 2
Mr = 562.93	F(000) = 584
Triclinic, P1	Dx = 1.402 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.529 (1) Å	Cell parameters from 6783 reflections
b = 11.471 (1) Å	θ = 3.0–27.3°
c = 12.633 (2) Å	µ = 0.97 mm^−1
α = 94.391 (9)°	T = 293 K
β = 95.409 (8)°	Prism, yellow
γ = 102.888 (5)°	0.37 × 0.24 × 0.19 mm
V = 1333.2 (3) Å^3

Data collection

Rigaku R-AXIS RAPID diffractometer	6036 independent reflections
Radiation source: fine-focus sealed tube	4880 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.026
Detector resolution: 10 pixels mm^-1	θmax = 27.5°, θmin = 3.0°
ω scans	h = −11→12
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	k = −14→14
Tmin = 0.717, Tmax = 0.838	l = −16→16
12738 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.045	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.120	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0716P)^2 + 0.2421P] where P = (Fo^2 + 2Fc^2)/3
6036 reflections	(Δ/σ)max = 0.001
346 parameters	Δρmax = 0.67 e Å^−3
0 restraints	Δρmin = −0.34 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Zn1	0.73388 (3)	0.34612 (2)	0.81804 (2)	0.0476 (1)
N1	0.7654 (2)	0.4481 (2)	0.9632 (1)	0.0449 (4)
N2	0.8512 (2)	0.4087 (2)	1.0422 (1)	0.0448 (4)
N3	0.5382 (2)	0.2068 (2)	0.8222 (2)	0.0474 (4)
O1	0.6322 (2)	0.4614 (2)	0.7532 (1)	0.0573 (4)
O2	0.8472 (2)	0.2489 (2)	0.9249 (1)	0.0547 (4)
O3	1.2088 (2)	0.0924 (2)	1.3093 (1)	0.0670 (5)
O4	0.8153 (2)	0.2915 (2)	0.6853 (1)	0.0544 (4)
O5	0.9814 (2)	0.4380 (2)	0.7739 (2)	0.0688 (5)
C1	0.4432 (3)	0.5572 (3)	0.6309 (2)	0.0617 (6)
C2	0.3579 (3)	0.6098 (3)	0.5638 (2)	0.0715 (8)
C3	0.3282 (3)	0.7172 (3)	0.5965 (3)	0.0745 (8)
C4	0.3826 (4)	0.7708 (3)	0.6963 (3)	0.090 (1)
C5	0.4685 (4)	0.7187 (3)	0.7644 (2)	0.0752 (8)
C6	0.5005 (2)	0.6104 (2)	0.7330 (2)	0.0492 (5)
C7	0.5926 (2)	0.5489 (2)	0.8020 (2)	0.0456 (5)
C8	0.6260 (2)	0.5867 (2)	0.9105 (2)	0.0481 (5)
C9	0.7106 (2)	0.5413 (2)	0.9887 (2)	0.0449 (5)
C10	0.7356 (3)	0.6038 (2)	1.0998 (2)	0.0551 (6)
C11	0.8901 (2)	0.3057 (2)	1.0150 (2)	0.0440 (5)
C12	0.9798 (2)	0.2563 (2)	1.0946 (2)	0.0426 (5)
C13	0.9989 (3)	0.2913 (2)	1.2035 (2)	0.0531 (6)
C14	1.0784 (3)	0.2366 (2)	1.2729 (2)	0.0579 (6)
C15	1.1380 (3)	0.1439 (2)	1.2344 (2)	0.0491 (5)
C16	1.1203 (3)	0.1085 (2)	1.1257 (2)	0.0485 (5)
C17	1.0426 (2)	0.1650 (2)	1.0571 (2)	0.0455 (5)
C18	1.2650 (4)	−0.0078 (3)	1.2756 (3)	0.088 (1)
C19	0.5142 (3)	0.1664 (2)	0.9152 (2)	0.0555 (6)
C20	0.3878 (3)	0.0849 (3)	0.9333 (2)	0.0650 (7)
C21	0.2810 (3)	0.0444 (3)	0.8508 (2)	0.0651 (7)
C22	0.3002 (3)	0.0846 (2)	0.7498 (2)	0.0546 (6)
C23	0.1954 (3)	0.0456 (3)	0.6589 (3)	0.0739 (8)
C24	0.2209 (3)	0.0848 (3)	0.5634 (2)	0.0809 (9)
C25	0.3514 (3)	0.1653 (3)	0.5518 (2)	0.0702 (8)
C26	0.4555 (3)	0.2058 (2)	0.6363 (2)	0.0557 (6)
C27	0.4321 (2)	0.1660 (2)	0.7376 (2)	0.0457 (5)
C28	0.9393 (3)	0.3615 (2)	0.6957 (2)	0.0537 (6)
C29	1.0360 (4)	0.3497 (4)	0.6095 (3)	0.103 (1)
H1	0.4628	0.4843	0.6071	0.074*
H2	0.3204	0.5719	0.4960	0.086*
H3	0.2716	0.7531	0.5512	0.089*
H4	0.3619	0.8435	0.7193	0.108*
H5	0.5051	0.7573	0.8321	0.090*
H8	0.5877	0.6502	0.9350	0.058*
H10A	0.7230	0.5451	1.1504	0.066*
H10B	0.6675	0.6534	1.1075	0.066*
H10C	0.8324	0.6531	1.1126	0.066*
H13	0.9578	0.3521	1.2301	0.064*
H14	1.0920	0.2618	1.3456	0.070*
H16	1.1607	0.0471	1.0992	0.058*
H17	1.0318	0.1415	0.9841	0.055*
H18A	1.1872	−0.0718	1.2417	0.106*
H18B	1.3120	−0.0348	1.3365	0.106*
H18C	1.3338	0.0156	1.2259	0.106*
H19	0.5858	0.1938	0.9725	0.067*
H20	0.3769	0.0588	1.0006	0.078*
H21	0.1960	−0.0095	0.8612	0.078*
H23	0.1083	−0.0077	0.6657	0.089*
H24	0.1514	0.0583	0.5046	0.097*
H25	0.3673	0.1916	0.4851	0.084*
H26	0.5414	0.2594	0.6273	0.067*
H29A	1.0453	0.4181	0.5693	0.123*
H29B	0.9944	0.2778	0.5627	0.123*
H29C	1.1300	0.3456	0.6416	0.123*
H30	0.8775	0.4478	1.1043	0.054*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Zn1	0.0548 (2)	0.0449 (2)	0.0423 (2)	0.0150 (1)	−0.0033 (1)	−0.0010 (1)
N1	0.048 (1)	0.044 (1)	0.0417 (9)	0.0117 (8)	−0.0032 (8)	0.0021 (8)
N2	0.049 (1)	0.044 (1)	0.0398 (9)	0.0110 (8)	−0.0039 (8)	0.0015 (7)
N3	0.051 (1)	0.050 (1)	0.042 (1)	0.0131 (9)	0.0036 (8)	0.0051 (8)
O1	0.072 (1)	0.055 (1)	0.0497 (9)	0.0302 (9)	−0.0023 (8)	−0.0013 (7)
O2	0.067 (1)	0.0512 (9)	0.0455 (9)	0.0232 (8)	−0.0110 (7)	−0.0050 (7)
O3	0.093 (1)	0.060 (1)	0.051 (1)	0.034 (1)	−0.0138 (9)	0.0040 (8)
O4	0.0507 (9)	0.0543 (9)	0.054 (1)	0.0055 (8)	0.0023 (7)	0.0007 (8)
O5	0.065 (1)	0.056 (1)	0.077 (1)	0.0108 (9)	−0.011 (1)	−0.0086 (9)
C1	0.070 (2)	0.062 (2)	0.056 (2)	0.025 (1)	−0.002 (1)	0.007 (1)
C2	0.074 (2)	0.083 (2)	0.056 (2)	0.021 (2)	−0.008 (1)	0.011 (1)
C3	0.066 (2)	0.088 (2)	0.076 (2)	0.030 (2)	−0.003 (1)	0.027 (2)
C4	0.118 (3)	0.080 (2)	0.086 (2)	0.059 (2)	−0.005 (2)	0.008 (2)
C5	0.099 (2)	0.070 (2)	0.063 (2)	0.042 (2)	−0.011 (2)	−0.000 (1)
C6	0.045 (1)	0.050 (1)	0.052 (1)	0.009 (1)	0.007 (1)	0.011 (1)
C7	0.043 (1)	0.042 (1)	0.050 (1)	0.0072 (9)	0.0030 (9)	0.0086 (9)
C8	0.049 (1)	0.0455 (1)	0.050 (1)	0.013 (1)	0.004 (1)	0.003 (1)
C9	0.041 (1)	0.045 (1)	0.047 (1)	0.0073 (9)	0.0042 (9)	0.0018 (9)
C10	0.059 (1)	0.059 (1)	0.049 (1)	0.022 (1)	−0.002 (1)	−0.003 (1)
C11	0.044 (1)	0.043 (1)	0.043 (1)	0.0062 (9)	−0.0005 (9)	0.0032 (9)
C12	0.040 (1)	0.041 (1)	0.042 (1)	0.0035 (9)	0.0004 (8)	0.0040 (9)
C13	0.069 (2)	0.046 (1)	0.047 (1)	0.021 (1)	0.002 (1)	0.001 (1)
C14	0.082 (2)	0.054 (1)	0.038 (1)	0.022 (1)	−0.005 (1)	−0.002 (1)
C15	0.056 (1)	0.044 (1)	0.046 (1)	0.011 (1)	−0.004 (1)	0.0062 (9)
C16	0.051 (1)	0.046 (1)	0.048 (1)	0.013 (1)	0.003 (1)	0.001 (1)
C17	0.047 (1)	0.048 (1)	0.040 (1)	0.010 (1)	0.0010 (9)	0.0008 (9)
C18	0.126 (3)	0.069 (2)	0.077 (2)	0.055 (2)	−0.018 (2)	0.005 (2)
C19	0.057 (1)	0.065 (2)	0.046 (1)	0.018 (1)	0.005 (1)	0.008 (1)
C20	0.074 (2)	0.075 (2)	0.055 (2)	0.024 (2)	0.020 (1)	0.022 (1)
C21	0.059 (2)	0.066 (2)	0.072 (2)	0.008 (1)	0.021 (1)	0.015 (1)
C22	0.051 (1)	0.054 (1)	0.058 (1)	0.008 (1)	0.009 (1)	0.006 (1)
C23	0.053 (2)	0.081 (2)	0.075 (2)	−0.008 (1)	0.000 (1)	0.005 (2)
C24	0.061 (2)	0.103 (2)	0.060 (2)	−0.010 (2)	−0.011 (1)	0.003 (2)
C25	0.066 (2)	0.088 (2)	0.046 (1)	−0.002 (2)	−0.005 (1)	0.007 (1)
C26	0.052 (1)	0.062 (2)	0.046 (1)	0.001 (1)	0.001 (1)	0.008 (1)
C27	0.046 (1)	0.044 (1)	0.046 (1)	0.011 (1)	0.0030 (9)	0.0019 (9)
C28	0.050 (1)	0.054 (1)	0.056 (1)	0.012 (1)	−0.000 (1)	0.006 (1)
C29	0.071 (2)	0.137 (4)	0.095 (3)	0.009 (2)	0.0270 (19)	−0.004 (2)

Geometric parameters (Å, º)

Zn1—N1	2.058 (2)	C10—H10C	0.9600
Zn1—N3	2.176 (2)	C11—C12	1.485 (3)
Zn1—O1	1.987 (2)	C12—c13	1.387 (3)
Zn1—O2	2.174 (2)	C12—C17	1.393 (3)
Zn1—O4	2.027 (2)	C13—C14	1.380 (3)
N1—C9	1.322 (3)	C13—H13	0.9300
O2—C11	1.252 (3)	C14—C15	1.390 (3)
C7—C8	1.390 (3)	C14—H14	0.9300
N1—N2	1.395 (2)	C15—C16	1.386 (3)
N2—C11	1.344 (3)	C16—C17	1.378 (3)
O1—C7	1.283 (3)	C16—H16	0.9300
C8—C9	1.419 (3)	C17—H17	0.9300
Zn1—C28	2.591 (3)	C18—H18A	0.9600
N2—H30	0.8600	C18—H18B	0.9600
N3—C19	1.318 (3)	C18—H18C	0.9600
N3—C27	1.376 (3)	C19—C20	1.400 (4)
O3—C15	1.357 (3)	C19—H19	0.9300
O3—C18	1.425 (3)	C20—C21	1.361 (4)
O4—C28	1.261 (3)	C20—H20	0.9300
O5—C28	1.242 (3)	C21—C22	1.404 (4)
C1—C2	1.383 (4)	C21—H21	0.9300
C1—C6	1.390 (4)	C22—C27	1.417 (3)
C1—H1	0.9300	C22—C23	1.422 (4)
C2—C3	1.367 (5)	C23—C24	1.344 (4)
C2—H2	0.9300	C23—H23	0.9300
C3—C4	1.361 (5)	C24—C25	1.402 (4)
C3—H3	0.9300	C24—H24	0.9300
C4—C5	1.390 (4)	C25—C26	1.363 (3)
C4—H4	0.9300	C25—H25	0.9300
C5—C6	1.382 (4)	C26—C27	1.412 (3)
C5—H5	0.9300	C26—H26	0.9300
C6—C7	1.502 (3)	C28—C29	1.508 (4)
C8—H8	0.9300	C29—H29A	0.9600
C9—C10	1.499 (3)	C29—H29B	0.9600
C10—H10A	0.9600	C29—H29C	0.9600
C10—H10B	0.9600
N1—Zn1—N3	105.54 (8)	C9—C10—H10A	109.5
N1—Zn1—O2	75.77 (7)	C9—C10—H10B	109.5
O1—Zn1—N1	90.07 (7)	C9—C10—H10C	109.5
O1—Zn1—N3	95.17 (8)	C11—N2—N1	115.8 (2)
O1—Zn1—O2	165.82 (7)	C11—N2—H30	122.1
O1—Zn1—O4	97.59 (7)	C11—O2—Zn1	112.9 (1)
O2—Zn1—N3	88.04 (7)	C12—C13—H13	119.7
O4—Zn1—N1	149.27 (8)	C12—C17—H17	119.3
O4—Zn1—N3	103.35 (7)	C13—C12—C11	124.3 (2)
O4—Zn1—O2	95.08 (7)	C13—C12—C17	118.4 (2)
N1—Zn1—C28	120.99 (8)	C13—C14—C15	120.3 (2)
N1—N2—H30	122.1	C13—C14—H14	119.9
N1—C9—C8	120.7 (2)	C14—C13—C12	120.6 (2)
N1—C9—C10	122.0 (2)	C14—C13—H13	119.7
N2—N1—Zn1	114.0 (1)	C15—O3—C18	118.6 (2)
N2—C11—C12	119.5 (2)	C15—C14—H14	119.9
N3—Zn1—C28	131.19 (8)	C15—C16—H16	120.2
N3—C19—C20	124.2 (2)	C16—C15—C14	119.7 (2)
N3—C19—H19	117.9	C16—C17—C12	121.4 (2)
N3—C27—C22	121.5 (2)	C16—C17—H17	119.3
N3—C27—C26	119.1 (2)	C17—C12—C11	117.2 (2)
O1—Zn1—C28	98.48 (8)	C17—C16—C15	119.6 (2)
O1—C7—C6	114.9 (2)	C17—C16—H16	120.2
O1—C7—C8	125.3 (2)	C19—N3—Zn1	117.2 (2)
O2—Zn1—C28	89.66 (7)	C19—N3—C27	117.7 (2)
O2—C11—N2	120.8 (2)	C19—C20—H20	120.5
O2—C11—C12	119.7 (2)	C20—C19—H19	117.9
O3—C15—C14	115.9 (2)	C20—C21—C22	119.5 (3)
O3—C15—C16	124.5 (2)	C20—C21—H21	120.3
O3—C18—H18A	109.5	C21—C20—C19	118.9 (2)
O3—C18—H18B	109.5	C21—C20—H20	120.5
O3—C18—H18C	109.5	C21—C22—C23	123.2 (3)
O4—Zn1—C28	28.49 (7)	C21—C22—C27	118.2 (2)
O4—C28—Zn1	50.1 (1)	C22—C21—H21	120.3
O4—C28—C29	117.8 (3)	C22—C23—H23	119.6
O5—C28—Zn1	71.5 (2)	C23—C24—C25	120.5 (3)
O5—C28—O4	121.6 (2)	C23—C24—H24	119.8
O5—C28—C29	120.6 (3)	C24—C23—C22	120.7 (3)
C1—C2—H2	119.8	C24—C23—H23	119.6
C1—C6—C7	119.1 (2)	C24—C25—H25	119.4
C2—C1—C6	121.7 (3)	C25—C24—H24	119.8
C2—C1—H1	119.2	C25—C26—C27	119.6 (2)
C2—C3—H3	120.4	C25—C26—H26	120.2
C3—C2—C1	120.3 (3)	C26—C25—C24	121.2 (3)
C3—C2—H2	119.8	C26—C25—H25	119.4
C3—C4—C5	121.0 (3)	C26—C27—C22	119.4 (2)
C3—C4—H4	119.5	C27—N3—Zn1	124.9 (2)
C4—C3—C2	119.1 (3)	C27—C22—C23	118.6 (2)
C4—C3—H3	120.4	C27—C26—H26	120.2
C4—C5—H5	119.5	C28—O4—Zn1	101.4 (2)
C5—C4—H4	119.5	C28—C29—H29A	109.5
C5—C6—C1	116.9 (2)	C28—C29—H29B	109.5
C5—C6—C7	123.9 (2)	C28—C29—H29C	109.5
C6—C1—H1	119.2	C29—C28—Zn1	167.8 (2)
C6—C5—C4	120.9 (3)	H10A—C10—H10B	109.5
C6—C5—H5	119.5	H10A—C10—H10C	109.5
C7—O1—Zn1	127.2 (2)	H10B—C10—H10C	109.5
C7—C8—C9	128.6 (2)	H18A—C18—H18B	109.5
C7—C8—H8	115.7	H18A—C18—H18C	109.5
C8—C7—C6	119.8 (2)	H18B—C18—H18C	109.5
C8—C9—C10	117.3 (2)	H29A—C29—H29B	109.5
C9—N1—Zn1	127.3 (2)	H29A—C29—H29C	109.5
C9—N1—N2	118.6 (2)	H29B—C29—H29C	109.5
C9—C8—H8	115.7
Zn1—N1—N2—C11	−5.3 (2)	O4—Zn1—N1—N2	−69.1 (2)
Zn1—N1—C9—C8	−4.0 (3)	O4—Zn1—N1—C9	113.2 (2)
Zn1—N1—C9—C10	176.5 (2)	O4—Zn1—N3—C19	135.7 (2)
Zn1—N3—C19—C20	174.2 (2)	O4—Zn1—N3—C27	−50.5 (2)
Zn1—N3—C27—C22	−172.8 (2)	O4—Zn1—O1—C7	−159.3 (2)
Zn1—N3—C27—C26	7.3 (3)	O4—Zn1—O2—C11	142.6 (2)
Zn1—O1—C7—C6	−172.3 (2)	O4—Zn1—C28—O5	−179.6 (2)
Zn1—O1—C7—C8	6.4 (3)	O4—Zn1—C28—C29	3 (1)
Zn1—O2—C11—N2	7.6 (3)	C1—C2—C3—C4	−0.7 (5)
Zn1—O2—C11—C12	−175.1 (2)	C1—C6—C7—O1	11.9 (3)
Zn1—O4—C28—O5	0.5 (3)	C1—C6—C7—C8	−166.8 (2)
Zn1—O4—C28—C29	−179.4 (3)	C2—C1—C6—C5	−0.2 (4)
N1—Zn1—N3—C19	−33.7 (2)	C2—C1—C6—C7	−179.9 (3)
N1—Zn1—N3—C27	140.1 (2)	C2—C3—C4—C5	0.7 (6)
N1—Zn1—O1—C7	−9.1 (2)	C3—C4—C5—C6	−0.5 (6)
N1—Zn1—O2—C11	−7.7 (2)	C4—C5—C6—C1	0.2 (5)
N1—Zn1—O4—C28	−9.3 (2)	C4—C5—C6—C7	179.9 (3)
N1—Zn1—C28—O4	174.5 (1)	C5—C6—C7—O1	−167.8 (3)
N1—Zn1—C28—O5	−5.1 (2)	C5—C6—C7—C8	13.5 (4)
N1—Zn1—C28—C29	177 (1)	C6—C1—C2—C3	0.4 (5)
N1—N2—C11—O2	−1.9 (3)	C6—C7—C8—C9	−179.9 (2)
N1—N2—C11—C12	−179.2 (2)	C7—C8—C9—N1	−2.6 (4)
N2—N1—C9—C8	178.3 (2)	C7—C8—C9—C10	176.9 (2)
N2—N1—C9—C10	−1.2 (3)	C9—N1—N2—C11	172.7 (2)
N2—C11—C12—C13	16.4 (3)	C11—C12—C13—C14	176.8 (2)
N2—C11—C12—C17	−166.8 (2)	C11—C12—C17—C16	−176.0 (2)
N3—Zn1—N1—N2	90.4 (2)	C12—C13—C14—C15	−1.2 (4)
N3—Zn1—N1—C9	−87.3 (2)	C13—C12—C17—C16	1.0 (3)
N3—Zn1—O1—C7	96.5 (2)	C13—C14—C15—O3	−177.2 (2)
N3—Zn1—O2—C11	−114.2 (2)	C13—C14—C15—C16	1.5 (4)
N3—Zn1—O4—C28	−169.0 (1)	C14—C15—C16—C17	−0.6 (4)
N3—Zn1—C28—O4	14.3 (2)	C15—C16—C17—C12	−0.7 (4)
N3—Zn1—C28—O5	−165.3 (1)	C17—C12—C13—C14	0.0 (4)
N3—Zn1—C28—C29	16 (1)	C18—O3—C15—C14	176.3 (3)
N3—C19—C20—C21	−0.6 (4)	C18—O3—C15—C16	−2.3 (4)
O1—Zn1—N1—N2	−174.2 (2)	C19—N3—C27—C22	1.0 (3)
O1—Zn1—N1—C9	8.1 (2)	C19—N3—C27—C26	−178.9 (2)
O1—Zn1—N3—C19	−125.2 (2)	C19—C20—C21—C22	0.3 (4)
O1—Zn1—N3—C27	48.6 (2)	C20—C21—C22—C23	179.0 (3)
O1—Zn1—O2—C11	−10.8 (4)	C21—C22—C23—C24	−178.3 (3)
O1—Zn1—O4—C28	93.8 (2)	C21—C22—C27—N3	−1.2 (4)
O1—Zn1—C28—O4	−90.3 (2)	C21—C22—C27—C26	178.6 (2)
O1—Zn1—C28—O5	90.1 (2)	C22—C23—C24—C25	−0.2 (6)
O1—Zn1—C28—C29	−88 (1)	C23—C22—C27—N3	−179.7 (2)
O1—C7—C8—C9	1.5 (4)	C23—C22—C27—C26	0.1 (4)
O2—Zn1—N1—N2	6.6 (1)	C23—C24—C25—C26	0.0 (6)
O2—Zn1—N1—C9	−171.2 (2)	C24—C25—C26—C27	0.2 (5)
O2—Zn1—N3—C19	40.9 (2)	C25—C26—C27—N3	179.6 (3)
O2—Zn1—N3—C27	−145.2 (2)	C25—C26—C27—C22	−0.2 (4)
O2—Zn1—O1—C7	−6.1 (4)	C27—N3—C19—C20	−0.1 (4)
O2—Zn1—O4—C28	−79.8 (2)	C27—C22—C23—C24	0.1 (5)
O2—Zn1—C28—O4	101.3 (2)	C28—Zn1—N1—N2	−74.2 (2)
O2—Zn1—C28—O5	−78.2 (2)	C28—Zn1—N1—C9	108.0 (2)
O2—Zn1—C28—C29	104 (1)	C28—Zn1—N3—C19	128.8 (2)
O2—C11—C12—C13	−161.0 (2)	C28—Zn1—N3—C27	−57.4 (2)
O2—C11—C12—C17	15.8 (3)	C28—Zn1—O1—C7	−130.5 (2)
O3—C15—C16—C17	178.1 (2)	C28—Zn1—O2—C11	114.5 (2)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N2—H30···O5^i	0.86	2.10	2.909 (3)	157

Symmetry code: (i) −x+2, −y+1, −z+2.