μ-trans-1,2-Di-4-pyridylethene-κ²N:N′-bis­[(dimethyl­formamide-κO)bis­(tri-tert-butoxy­silanethiol­ato-κS)cadmium(II)]

In the centrosymmetric title complex, [Cd₂(C₁₂H₂₇O₃SSi)₄(C₃H₇NO)₂(C₁₂H₁₀N₂)], the Cd atom is four-coordinated in a CdNOS₂ core.

Key indicators

• Single-crystal X-ray study
• T = 299 K
• Mean [sigma](C-C) = 0.014 Å
• Disorder in main residue
• R factor = 0.056
• wR factor = 0.174
• Data-to-parameter ratio = 12.6

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       5.22 Ratio
PLAT222_ALERT_3_A Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       5.69 Ratio
PLAT242_ALERT_2_A Check Low       Ueq as Compared to Neighbors for        C13
PLAT242_ALERT_2_A Check Low       Ueq as Compared to Neighbors for        C21

Alert level B
PLAT029_ALERT_3_B _diffrn_measured_fraction_theta_full Low .......       0.95
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C32
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        Si2
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C5'
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C17
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for         C1
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for         C5
PLAT301_ALERT_3_B Main Residue  Disorder .........................      32.00 Perc.

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000)         700 Deg.
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         S2
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O5
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O6
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C31
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C33
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         N2
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C1'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C9'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C32'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C9
PLAT245_ALERT_2_C U(iso) H28     Smaller than U(eq) C28'    by ...       0.01 AngSq
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         14
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         18
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      22.00 Deg.
              O1   -SI1  -O1'     1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      35.30 Deg.
              O3'  -SI1  -O3      1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      37.60 Deg.
              O2   -SI1  -O2'     1.555   1.555   1.555

   4 ALERT level A = In general: serious problem
   8 ALERT level B = Potentially serious problem
  20 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  23 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: CrysAlis CCD (Oxford Diffraction, 2006); cell refinement: CrysAlis RED (Oxford Diffraction, 2006); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

µ-trans-1,2-Di-4-pyridylethene-κ²N:N'-bis[(dimethylformamide- κO)bis(tri-tert-butoxysilanethiolato-κS)cadmium(II)]

Crystal data

[Cd2(C12H27O3SSi)4(C3H7NO)2(C12H10N2)]	Z = 1
Mr = 1671.16	F(000) = 884
Triclinic, P1	Dx = 1.231 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.5922 (7) Å	Cell parameters from 3413 reflections
b = 15.3340 (11) Å	θ = 2.8–21.0°
c = 15.7451 (12) Å	µ = 0.67 mm^−1
α = 100.539 (7)°	T = 299 K
β = 94.205 (7)°	Block, colourless
γ = 96.145 (7)°	0.35 × 0.25 × 0.20 mm
V = 2253.5 (3) Å^3

Data collection

Kuma KM-4-CCD diffractometer	6028 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.046
Graphite monochromator	θmax = 25.0°, θmin = 2.7°
ω scans	h = −10→11
12228 measured reflections	k = −11→18
7558 independent reflections	l = −18→18

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.056	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.174	H-atom parameters constrained
S = 1.07	w = 1/[σ^2(Fo^2) + (0.117P)^2 + 0.2921P] where P = (Fo^2 + 2Fc^2)/3
7558 reflections	(Δ/σ)max = 0.001
601 parameters	Δρmax = 1.05 e Å^−3
573 restraints	Δρmin = −0.70 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cd1	0.65692 (4)	0.65667 (2)	0.73992 (2)	0.04930 (18)
S1	0.80318 (16)	0.71637 (10)	0.64086 (10)	0.0631 (4)
S2	0.56972 (16)	0.65531 (12)	0.88081 (9)	0.0671 (4)
Si1	0.68545 (15)	0.81089 (9)	0.60255 (9)	0.0465 (3)
Si2	0.75107 (14)	0.71105 (9)	0.96091 (9)	0.0450 (3)
O1	0.5257 (5)	0.7854 (4)	0.6198 (6)	0.059 (3)	0.490 (8)
O2	0.7062 (8)	0.8249 (5)	0.5074 (4)	0.063 (3)	0.490 (8)
O3	0.7297 (7)	0.9136 (3)	0.6636 (5)	0.065 (3)	0.490 (8)
C1	0.4101 (11)	0.8384 (8)	0.6281 (9)	0.070 (6)	0.490 (8)
C2	0.2747 (9)	0.7761 (10)	0.6081 (13)	0.105 (6)	0.490 (8)
H2A	0.2682	0.7447	0.5490	0.158*	0.490 (8)
H2B	0.1965	0.8099	0.6161	0.158*	0.490 (8)
H2C	0.2731	0.7339	0.6463	0.158*	0.490 (8)
C3	0.4161 (18)	0.8893 (11)	0.7190 (9)	0.119 (7)	0.490 (8)
H3A	0.5026	0.9289	0.7327	0.178*	0.490 (8)
H3B	0.4117	0.8482	0.7583	0.178*	0.490 (8)
H3C	0.3379	0.9234	0.7245	0.178*	0.490 (8)
C4	0.4166 (19)	0.9015 (11)	0.5661 (12)	0.124 (7)	0.490 (8)
H4A	0.5022	0.9419	0.5800	0.186*	0.490 (8)
H4B	0.3374	0.9348	0.5705	0.186*	0.490 (8)
H4C	0.4145	0.8683	0.5080	0.186*	0.490 (8)
C5	0.7123 (13)	0.7689 (7)	0.4241 (6)	0.049 (4)	0.490 (8)
C6	0.688 (2)	0.8245 (11)	0.3567 (7)	0.108 (7)	0.490 (8)
H6A	0.7597	0.8749	0.3662	0.163*	0.490 (8)
H6B	0.5972	0.8452	0.3607	0.163*	0.490 (8)
H6C	0.6913	0.7892	0.3001	0.163*	0.490 (8)
C7	0.8532 (12)	0.7365 (10)	0.4196 (10)	0.090 (5)	0.490 (8)
H7A	0.9251	0.7867	0.4279	0.136*	0.490 (8)
H7B	0.8570	0.6995	0.3638	0.136*	0.490 (8)
H7C	0.8683	0.7024	0.4642	0.136*	0.490 (8)
C8	0.6005 (15)	0.6905 (8)	0.4126 (10)	0.094 (5)	0.490 (8)
H8A	0.5097	0.7112	0.4150	0.141*	0.490 (8)
H8B	0.6159	0.6575	0.4580	0.141*	0.490 (8)
H8C	0.6043	0.6524	0.3574	0.141*	0.490 (8)
C9	0.8463 (13)	0.9822 (8)	0.6675 (8)	0.076 (9)	0.490 (8)
C10	0.9766 (11)	0.9410 (13)	0.6471 (14)	0.098 (7)	0.490 (8)
H10A	0.9640	0.9072	0.5888	0.148*	0.490 (8)
H10B	0.9954	0.9021	0.6868	0.148*	0.490 (8)
H10C	1.0545	0.9871	0.6525	0.148*	0.490 (8)
C11	0.812 (2)	1.0401 (10)	0.6042 (11)	0.101 (6)	0.490 (8)
H11A	0.8006	1.0051	0.5464	0.151*	0.490 (8)
H11B	0.8871	1.0879	0.6086	0.151*	0.490 (8)
H11C	0.7261	1.0646	0.6168	0.151*	0.490 (8)
C12	0.8659 (19)	1.0355 (10)	0.7590 (8)	0.125 (7)	0.490 (8)
H12A	0.7818	1.0620	0.7720	0.187*	0.490 (8)
H12B	0.9437	1.0816	0.7643	0.187*	0.490 (8)
H12C	0.8846	0.9967	0.7988	0.187*	0.490 (8)
O1'	0.5459 (6)	0.8123 (4)	0.6532 (4)	0.046 (2)	0.510 (8)
O2'	0.6193 (7)	0.7748 (4)	0.4985 (3)	0.062 (2)	0.510 (8)
O3'	0.7671 (6)	0.9055 (3)	0.6060 (5)	0.062 (2)	0.510 (8)
C1'	0.4142 (10)	0.8489 (7)	0.6483 (8)	0.059 (5)	0.510 (8)
C2'	0.3160 (12)	0.7910 (10)	0.5754 (9)	0.097 (6)	0.510 (8)
H2'A	0.3565	0.7908	0.5214	0.146*	0.510 (8)
H2'B	0.2271	0.8143	0.5727	0.146*	0.510 (8)
H2'C	0.3019	0.7310	0.5858	0.146*	0.510 (8)
C3'	0.3520 (14)	0.8487 (11)	0.7319 (8)	0.105 (6)	0.510 (8)
H3'A	0.4138	0.8862	0.7781	0.157*	0.510 (8)
H3'B	0.3396	0.7888	0.7426	0.157*	0.510 (8)
H3'C	0.2623	0.8710	0.7291	0.157*	0.510 (8)
C4'	0.4397 (14)	0.9411 (6)	0.6304 (11)	0.096 (5)	0.510 (8)
H4'A	0.5018	0.9781	0.6768	0.145*	0.510 (8)
H4'B	0.3518	0.9653	0.6262	0.145*	0.510 (8)
H4'C	0.4819	0.9393	0.5768	0.145*	0.510 (8)
C5'	0.6748 (14)	0.7625 (9)	0.4153 (6)	0.071 (5)	0.510 (8)
C6'	0.621 (2)	0.8301 (13)	0.3671 (9)	0.124 (7)	0.510 (8)
H6'A	0.6542	0.8892	0.3988	0.186*	0.510 (8)
H6'B	0.5202	0.8217	0.3608	0.186*	0.510 (8)
H6'C	0.6555	0.8226	0.3107	0.186*	0.510 (8)
C7'	0.8318 (12)	0.7753 (14)	0.4264 (11)	0.128 (8)	0.510 (8)
H7'A	0.8644	0.8349	0.4570	0.193*	0.510 (8)
H7'B	0.8673	0.7662	0.3704	0.193*	0.510 (8)
H7'C	0.8648	0.7331	0.4588	0.193*	0.510 (8)
C8'	0.623 (2)	0.6702 (9)	0.3672 (10)	0.130 (8)	0.510 (8)
H8'A	0.6579	0.6274	0.3981	0.195*	0.510 (8)
H8'B	0.6548	0.6619	0.3103	0.195*	0.510 (8)
H8'C	0.5215	0.6618	0.3622	0.195*	0.510 (8)
C9'	0.8571 (11)	0.9726 (8)	0.6674 (7)	0.067 (7)	0.510 (8)
C10'	1.0061 (9)	0.9560 (12)	0.6608 (11)	0.083 (5)	0.510 (8)
H10D	1.0310	0.9595	0.6034	0.125*	0.510 (8)
H10E	1.0172	0.8975	0.6721	0.125*	0.510 (8)
H10F	1.0662	1.0001	0.7025	0.125*	0.510 (8)
C11'	0.834 (2)	1.0624 (6)	0.6484 (10)	0.107 (6)	0.510 (8)
H11D	0.8590	1.0660	0.5911	0.161*	0.510 (8)
H11E	0.8913	1.1081	0.6900	0.161*	0.510 (8)
H11F	0.7365	1.0706	0.6519	0.161*	0.510 (8)
C12'	0.8164 (14)	0.9668 (9)	0.7572 (6)	0.085 (4)	0.510 (8)
H12D	0.7200	0.9773	0.7609	0.128*	0.510 (8)
H12E	0.8759	1.0110	0.7993	0.128*	0.510 (8)
H12F	0.8275	0.9084	0.7686	0.128*	0.510 (8)
O4	0.8714 (4)	0.7347 (4)	0.9006 (3)	0.0787 (14)
O5	0.8141 (5)	0.6416 (3)	1.0155 (3)	0.0854 (14)
O6	0.7266 (5)	0.7919 (3)	1.0351 (3)	0.0902 (15)
C13	1.0216 (7)	0.7565 (6)	0.9126 (5)	0.082 (2)
C14	1.0747 (12)	0.7846 (10)	1.0059 (8)	0.160 (4)
H14A	1.0330	0.8363	1.0310	0.240*
H14B	1.1753	0.7988	1.0111	0.240*
H14C	1.0502	0.7368	1.0359	0.240*
C15	1.0476 (13)	0.8320 (8)	0.8658 (8)	0.157 (5)
H15A	1.0108	0.8130	0.8061	0.235*
H15B	1.1470	0.8503	0.8690	0.235*
H15C	1.0016	0.8813	0.8922	0.235*
C16	1.0766 (15)	0.6780 (10)	0.8672 (11)	0.193 (6)
H16A	1.0384	0.6651	0.8076	0.290*
H16B	1.0503	0.6279	0.8938	0.290*
H16C	1.1774	0.6893	0.8703	0.290*
C17	0.7669 (7)	0.5892 (5)	1.0747 (4)	0.0692 (16)
C18	0.6301 (9)	0.6082 (6)	1.1069 (6)	0.102 (3)
H18A	0.6392	0.6682	1.1395	0.153*
H18B	0.6022	0.5670	1.1436	0.153*
H18C	0.5602	0.6016	1.0586	0.153*
C19	0.8797 (12)	0.5996 (8)	1.1457 (6)	0.138 (4)
H19A	0.8921	0.6601	1.1773	0.207*
H19B	0.9659	0.5859	1.1220	0.207*
H19C	0.8547	0.5597	1.1840	0.207*
C20	0.7451 (14)	0.4938 (7)	1.0226 (8)	0.147 (4)
H20A	0.6693	0.4880	0.9778	0.220*
H20B	0.7223	0.4529	1.0604	0.220*
H20C	0.8299	0.4805	0.9968	0.220*
C21	0.6575 (9)	0.8700 (4)	1.0408 (5)	0.086 (2)
C22	0.6728 (16)	0.9066 (8)	0.9616 (9)	0.163 (5)
H22A	0.7710	0.9212	0.9556	0.245*
H22B	0.6268	0.9596	0.9654	0.245*
H22C	0.6307	0.8631	0.9122	0.245*
C23	0.5090 (12)	0.8449 (8)	1.0570 (9)	0.152 (4)
H23A	0.4613	0.8045	1.0070	0.228*
H23B	0.4624	0.8976	1.0680	0.228*
H23C	0.5075	0.8164	1.1064	0.228*
C24	0.7355 (16)	0.9323 (8)	1.1168 (9)	0.182 (5)
H24A	0.8318	0.9454	1.1055	0.273*
H24B	0.7324	0.9052	1.1671	0.273*
H24C	0.6929	0.9867	1.1271	0.273*
O7	0.7443 (5)	0.5108 (3)	0.7116 (3)	0.0715 (11)
N2	0.7519 (5)	0.3743 (3)	0.7467 (3)	0.0661 (13)
C25	0.7198 (7)	0.4561 (4)	0.7586 (4)	0.0673 (15)
H25A	0.6739	0.4749	0.8075	0.081*
C26	0.8238 (9)	0.3412 (5)	0.6725 (5)	0.093 (2)
H26A	0.8560	0.3900	0.6454	0.139*
H26B	0.7604	0.2980	0.6317	0.139*
H26C	0.9030	0.3136	0.6908	0.139*
C27	0.7149 (10)	0.3139 (5)	0.8030 (6)	0.099 (2)
H27A	0.6435	0.3360	0.8379	0.148*
H27B	0.7966	0.3090	0.8400	0.148*
H27C	0.6796	0.2562	0.7689	0.148*
N1	0.4323 (9)	0.5924 (9)	0.6677 (7)	0.055 (5)	0.50
C28	0.4136 (8)	0.5709 (9)	0.5776 (7)	0.042 (3)	0.50
H28	0.4911	0.5737	0.5456	0.051*	0.50
C29	0.2791 (9)	0.5450 (8)	0.5354 (5)	0.049 (3)	0.50
H29	0.2666	0.5306	0.4751	0.059*	0.50
C30	0.1633 (8)	0.5408 (5)	0.5833 (4)	0.053 (3)	0.50
C31	0.1820 (10)	0.5623 (8)	0.6734 (4)	0.081 (5)	0.50
H31	0.1045	0.5595	0.7054	0.098*	0.50
C32	0.3165 (11)	0.5881 (10)	0.7156 (5)	0.087 (6)	0.50
H32	0.3290	0.6026	0.7759	0.105*	0.50
C33	0.0178 (10)	0.5147 (7)	0.5411 (4)	0.061 (3)	0.50
H33	−0.0549	0.5198	0.5770	0.073*	0.50
N1'	0.4453 (7)	0.5871 (9)	0.6562 (6)	0.050 (5)	0.50
C28'	0.4480 (6)	0.5741 (10)	0.5667 (7)	0.065 (5)	0.50
H28'	0.5324	0.5855	0.5429	0.077*	0.50
C29'	0.3244 (7)	0.5439 (8)	0.5127 (5)	0.046 (3)	0.50
H29'	0.3262	0.5352	0.4527	0.055*	0.50
C30'	0.1983 (6)	0.5268 (4)	0.5482 (4)	0.037 (2)	0.50
C31'	0.1956 (7)	0.5398 (6)	0.6378 (4)	0.051 (3)	0.50
H31'	0.1112	0.5283	0.6616	0.061*	0.50
C32'	0.3192 (9)	0.5700 (8)	0.6918 (4)	0.045 (3)	0.50
H32'	0.3174	0.5787	0.7517	0.053*	0.50
C33'	0.0662 (5)	0.4951 (6)	0.4900 (5)	0.042 (2)	0.50
H33'	0.0760	0.4656	0.4341	0.051*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cd1	0.0494 (3)	0.0535 (3)	0.0418 (3)	0.00215 (17)	−0.00036 (16)	0.00513 (16)
S1	0.0621 (9)	0.0715 (9)	0.0692 (9)	0.0282 (7)	0.0222 (7)	0.0305 (8)
S2	0.0573 (8)	0.0909 (11)	0.0414 (8)	−0.0184 (8)	−0.0010 (6)	0.0006 (7)
Si1	0.0477 (8)	0.0460 (7)	0.0484 (8)	0.0086 (6)	0.0116 (6)	0.0117 (6)
Si2	0.0442 (7)	0.0490 (7)	0.0390 (7)	0.0015 (6)	0.0027 (5)	0.0042 (6)
O1	0.053 (5)	0.025 (4)	0.095 (8)	0.004 (3)	0.026 (5)	−0.006 (5)
O2	0.081 (7)	0.059 (5)	0.058 (5)	0.016 (5)	0.018 (4)	0.023 (4)
O3	0.068 (5)	0.051 (4)	0.071 (6)	0.005 (4)	0.020 (5)	−0.003 (4)
C1	0.063 (9)	0.063 (9)	0.084 (9)	0.015 (7)	0.009 (7)	0.006 (7)
C2	0.080 (9)	0.096 (9)	0.139 (12)	0.016 (7)	0.024 (9)	0.012 (8)
C3	0.101 (10)	0.138 (11)	0.114 (11)	0.034 (9)	0.025 (9)	−0.003 (9)
C4	0.120 (11)	0.120 (10)	0.143 (12)	0.050 (9)	0.011 (9)	0.033 (9)
C5	0.048 (6)	0.065 (7)	0.036 (6)	0.008 (5)	0.009 (5)	0.014 (5)
C6	0.123 (11)	0.105 (10)	0.110 (10)	0.025 (8)	0.014 (8)	0.048 (8)
C7	0.092 (9)	0.098 (9)	0.091 (9)	0.036 (7)	0.034 (7)	0.019 (7)
C8	0.104 (9)	0.079 (8)	0.091 (9)	−0.006 (7)	0.013 (8)	0.004 (7)
C9	0.083 (13)	0.054 (10)	0.088 (13)	−0.006 (8)	−0.008 (8)	0.020 (8)
C10	0.079 (9)	0.089 (10)	0.115 (11)	−0.026 (8)	−0.007 (8)	0.016 (8)
C11	0.106 (10)	0.092 (9)	0.107 (10)	0.002 (8)	0.000 (8)	0.035 (8)
C12	0.127 (11)	0.107 (10)	0.129 (11)	0.006 (9)	0.004 (9)	0.001 (9)
O1'	0.054 (5)	0.031 (4)	0.052 (5)	0.011 (3)	0.018 (3)	−0.003 (4)
O2'	0.058 (5)	0.074 (5)	0.049 (4)	0.003 (4)	0.013 (4)	0.001 (4)
O3'	0.054 (5)	0.060 (4)	0.072 (6)	−0.001 (4)	0.011 (4)	0.012 (4)
C1'	0.055 (8)	0.050 (7)	0.073 (8)	0.022 (6)	0.024 (6)	−0.007 (6)
C2'	0.086 (9)	0.097 (9)	0.111 (10)	0.036 (8)	0.014 (8)	0.010 (8)
C3'	0.100 (9)	0.125 (10)	0.096 (9)	0.034 (8)	0.037 (8)	0.017 (8)
C4'	0.088 (8)	0.069 (7)	0.137 (10)	0.027 (6)	0.019 (8)	0.018 (7)
C5'	0.071 (9)	0.084 (9)	0.055 (8)	0.000 (7)	0.004 (6)	0.009 (7)
C6'	0.160 (13)	0.122 (11)	0.111 (11)	0.043 (9)	0.020 (9)	0.061 (9)
C7'	0.129 (12)	0.151 (13)	0.112 (11)	0.017 (10)	0.049 (9)	0.028 (9)
C8'	0.145 (12)	0.114 (11)	0.125 (11)	0.010 (9)	0.044 (9)	−0.002 (9)
C9'	0.059 (10)	0.055 (9)	0.082 (11)	0.001 (7)	−0.002 (7)	0.007 (7)
C10'	0.053 (7)	0.078 (9)	0.108 (10)	−0.008 (7)	0.003 (7)	0.005 (7)
C11'	0.115 (10)	0.083 (9)	0.120 (11)	0.002 (8)	−0.002 (9)	0.021 (8)
C12'	0.079 (8)	0.079 (7)	0.093 (8)	0.010 (6)	0.004 (7)	0.006 (6)
O4	0.049 (2)	0.130 (4)	0.063 (3)	0.000 (2)	0.0094 (19)	0.038 (3)
O5	0.075 (3)	0.103 (3)	0.093 (3)	0.009 (3)	0.012 (3)	0.058 (3)
O6	0.087 (3)	0.077 (3)	0.088 (3)	0.016 (3)	−0.013 (3)	−0.027 (3)
C13	0.049 (3)	0.110 (5)	0.096 (5)	0.004 (3)	0.017 (3)	0.041 (4)
C14	0.101 (6)	0.241 (10)	0.134 (8)	−0.028 (7)	−0.015 (6)	0.063 (7)
C15	0.147 (8)	0.157 (8)	0.169 (9)	−0.037 (7)	0.013 (7)	0.074 (7)
C16	0.147 (9)	0.187 (10)	0.245 (11)	0.060 (8)	0.025 (8)	0.017 (9)
C17	0.064 (4)	0.088 (4)	0.061 (4)	0.008 (3)	0.010 (3)	0.028 (3)
C18	0.096 (5)	0.130 (6)	0.094 (5)	0.021 (5)	0.034 (4)	0.042 (5)
C19	0.130 (7)	0.192 (8)	0.096 (6)	−0.010 (6)	−0.020 (5)	0.067 (6)
C20	0.153 (8)	0.122 (7)	0.165 (8)	0.002 (6)	0.029 (7)	0.029 (6)
C21	0.103 (5)	0.058 (3)	0.096 (5)	0.021 (3)	0.019 (4)	0.001 (3)
C22	0.201 (10)	0.138 (8)	0.172 (9)	0.072 (7)	0.024 (8)	0.052 (7)
C23	0.124 (7)	0.133 (7)	0.203 (9)	0.043 (6)	0.047 (7)	0.014 (7)
C24	0.206 (10)	0.136 (8)	0.172 (9)	0.006 (7)	0.022 (8)	−0.050 (7)
O7	0.096 (3)	0.060 (2)	0.066 (3)	0.023 (2)	0.015 (2)	0.020 (2)
N2	0.068 (3)	0.059 (3)	0.074 (3)	0.016 (2)	0.006 (2)	0.019 (2)
C25	0.067 (4)	0.066 (3)	0.068 (4)	0.013 (3)	0.009 (3)	0.007 (3)
C26	0.111 (5)	0.088 (4)	0.086 (5)	0.041 (4)	0.015 (4)	0.016 (4)
C27	0.109 (5)	0.083 (4)	0.117 (6)	0.020 (4)	0.030 (5)	0.041 (4)
N1	0.052 (8)	0.063 (8)	0.050 (7)	0.016 (6)	−0.013 (6)	0.009 (6)
C28	0.038 (5)	0.051 (6)	0.037 (6)	0.007 (5)	0.002 (5)	0.008 (5)
C29	0.044 (7)	0.057 (6)	0.043 (6)	−0.007 (6)	0.001 (6)	0.010 (5)
C30	0.044 (6)	0.063 (6)	0.049 (7)	0.001 (5)	−0.003 (5)	0.009 (6)
C31	0.071 (8)	0.091 (9)	0.076 (9)	−0.004 (7)	0.009 (7)	0.007 (7)
C32	0.078 (9)	0.087 (9)	0.083 (9)	−0.021 (7)	−0.014 (7)	0.007 (8)
C33	0.063 (7)	0.067 (6)	0.054 (6)	0.007 (5)	0.005 (6)	0.015 (5)
N1'	0.048 (7)	0.048 (7)	0.045 (7)	−0.008 (5)	0.002 (6)	−0.004 (5)
C28'	0.048 (6)	0.067 (8)	0.070 (9)	−0.007 (6)	−0.012 (6)	0.007 (6)
C29'	0.032 (6)	0.064 (6)	0.043 (6)	0.012 (5)	0.002 (5)	0.008 (5)
C30'	0.039 (6)	0.038 (5)	0.027 (5)	−0.003 (4)	−0.003 (4)	−0.003 (4)
C31'	0.038 (5)	0.059 (6)	0.049 (7)	−0.002 (4)	−0.005 (5)	0.006 (6)
C32'	0.038 (6)	0.056 (6)	0.032 (5)	−0.006 (4)	−0.006 (4)	−0.004 (4)
C33'	0.041 (5)	0.053 (5)	0.028 (5)	0.008 (4)	−0.007 (4)	−0.004 (4)

Geometric parameters (Å, º)

Cd1—N1'	2.371 (6)	C10'—H10D	0.9600
Cd1—N1	2.384 (7)	C10'—H10E	0.9600
Cd1—S1	2.4098 (15)	C10'—H10F	0.9600
Cd1—S2	2.4304 (15)	C11'—H11D	0.9600
Cd1—O7	2.449 (4)	C11'—H11E	0.9600
S1—Si1	2.076 (2)	C11'—H11F	0.9600
S2—Si2	2.0768 (19)	C12'—H12D	0.9600
Si1—O3'	1.563 (5)	C12'—H12E	0.9600
Si1—O2	1.576 (5)	C12'—H12F	0.9600
Si1—O1	1.595 (5)	O4—C13	1.434 (8)
Si1—O1'	1.607 (5)	O5—C17	1.406 (7)
Si1—O3	1.682 (5)	O6—C21	1.422 (9)
Si1—O2'	1.684 (5)	C13—C16	1.454 (15)
Si2—O6	1.590 (4)	C13—C14	1.488 (13)
Si2—O4	1.601 (4)	C13—C15	1.491 (12)
Si2—O5	1.623 (5)	C14—H14A	0.9600
O1—C1	1.443 (8)	C14—H14B	0.9600
O2—C5	1.439 (8)	C14—H14C	0.9600
O3—C9	1.439 (9)	C15—H15A	0.9600
C1—C3	1.493 (10)	C15—H15B	0.9600
C1—C4	1.495 (10)	C15—H15C	0.9600
C1—C2	1.505 (10)	C16—H16A	0.9600
C2—H2A	0.9600	C16—H16B	0.9600
C2—H2B	0.9600	C16—H16C	0.9600
C2—H2C	0.9600	C17—C19	1.471 (11)
C3—H3A	0.9600	C17—C18	1.479 (10)
C3—H3B	0.9600	C17—C20	1.526 (13)
C3—H3C	0.9600	C18—H18A	0.9600
C4—H4A	0.9600	C18—H18B	0.9600
C4—H4B	0.9600	C18—H18C	0.9600
C4—H4C	0.9600	C19—H19A	0.9600
C5—C7	1.491 (10)	C19—H19B	0.9600
C5—C8	1.498 (10)	C19—H19C	0.9600
C5—C6	1.500 (9)	C20—H20A	0.9600
C6—H6A	0.9600	C20—H20B	0.9600
C6—H6B	0.9600	C20—H20C	0.9600
C6—H6C	0.9600	C21—C22	1.469 (14)
C7—H7A	0.9600	C21—C24	1.485 (14)
C7—H7B	0.9600	C21—C23	1.488 (13)
C7—H7C	0.9600	C22—H22A	0.9600
C8—H8A	0.9600	C22—H22B	0.9600
C8—H8B	0.9600	C22—H22C	0.9600
C8—H8C	0.9600	C23—H23A	0.9600
C9—C10	1.490 (10)	C23—H23B	0.9600
C9—C11	1.494 (10)	C23—H23C	0.9600
C9—C12	1.507 (10)	C24—H24A	0.9600
C10—H10A	0.9600	C24—H24B	0.9600
C10—H10B	0.9600	C24—H24C	0.9600
C10—H10C	0.9600	O7—C25	1.230 (7)
C11—H11A	0.9600	N2—C25	1.307 (8)
C11—H11B	0.9600	N2—C27	1.431 (8)
C11—H11C	0.9600	N2—C26	1.441 (9)
C12—H12A	0.9600	C25—H25A	0.9300
C12—H12B	0.9600	C26—H26A	0.9600
C12—H12C	0.9600	C26—H26B	0.9600
O1'—C1'	1.438 (8)	C26—H26C	0.9600
O2'—C5'	1.438 (9)	C27—H27A	0.9600
O3'—C9'	1.436 (8)	C27—H27B	0.9600
C1'—C3'	1.485 (10)	C27—H27C	0.9600
C1'—C4'	1.490 (9)	N1—C28	1.3900
C1'—C2'	1.511 (10)	N1—C32	1.3900
C2'—H2'A	0.9600	C28—C29	1.3900
C2'—H2'B	0.9600	C28—H28	0.9300
C2'—H2'C	0.9600	C29—C30	1.3900
C3'—H3'A	0.9600	C29—H29	0.9300
C3'—H3'B	0.9600	C30—C31	1.3900
C3'—H3'C	0.9600	C30—C33	1.482 (7)
C4'—H4'A	0.9600	C31—C32	1.3900
C4'—H4'B	0.9600	C31—H31	0.9300
C4'—H4'C	0.9600	C32—H32	0.9300
C5'—C7'	1.491 (10)	C33—C33^i	1.297 (10)
C5'—C8'	1.493 (10)	C33—H33	0.9300
C5'—C6'	1.504 (10)	N1'—C28'	1.3900
C6'—H6'A	0.9600	N1'—C32'	1.3900
C6'—H6'B	0.9600	C28'—C29'	1.3900
C6'—H6'C	0.9600	C28'—H28'	0.9300
C7'—H7'A	0.9600	C29'—C30'	1.3900
C7'—H7'B	0.9600	C29'—H29'	0.9300
C7'—H7'C	0.9600	C30'—C31'	1.3900
C8'—H8'A	0.9600	C30'—C33'	1.489 (6)
C8'—H8'B	0.9600	C31'—C32'	1.3900
C8'—H8'C	0.9600	C31'—H31'	0.9300
C9'—C10'	1.485 (10)	C32'—H32'	0.9300
C9'—C11'	1.497 (10)	C33'—C33'^i	1.347 (10)
C9'—C12'	1.511 (10)	C33'—H33'	0.9300
N1'—Cd1—N1	5.7 (5)	H8'A—C8'—H8'C	109.5
N1'—Cd1—S1	106.2 (3)	H8'B—C8'—H8'C	109.5
N1—Cd1—S1	110.5 (3)	O3'—C9'—C10'	109.4 (8)
N1'—Cd1—S2	96.2 (3)	O3'—C9'—C11'	108.4 (8)
N1—Cd1—S2	91.1 (3)	C10'—C9'—C11'	111.4 (8)
S1—Cd1—S2	154.11 (6)	O3'—C9'—C12'	108.2 (7)
N1'—Cd1—O7	87.3 (3)	C10'—C9'—C12'	110.0 (8)
N1—Cd1—O7	90.7 (3)	C11'—C9'—C12'	109.3 (8)
S1—Cd1—O7	93.35 (11)	C9'—C10'—H10D	109.5
S2—Cd1—O7	100.64 (11)	C9'—C10'—H10E	109.5
Si1—S1—Cd1	101.80 (7)	H10D—C10'—H10E	109.5
Si2—S2—Cd1	99.78 (7)	C9'—C10'—H10F	109.5
O3'—Si1—O2	70.6 (3)	H10D—C10'—H10F	109.5
O3'—Si1—O1	128.7 (3)	H10E—C10'—H10F	109.5
O2—Si1—O1	114.5 (3)	C9'—C11'—H11D	109.5
O3'—Si1—O1'	114.0 (3)	C9'—C11'—H11E	109.5
O2—Si1—O1'	129.5 (3)	H11D—C11'—H11E	109.5
O1—Si1—O1'	22.0 (3)	C9'—C11'—H11F	109.5
O3'—Si1—O3	35.3 (3)	H11D—C11'—H11F	109.5
O2—Si1—O3	103.8 (3)	H11E—C11'—H11F	109.5
O1—Si1—O3	103.8 (3)	C9'—C12'—H12D	109.5
O1'—Si1—O3	83.8 (3)	C9'—C12'—H12E	109.5
O3'—Si1—O2'	105.6 (3)	H12D—C12'—H12E	109.5
O2—Si1—O2'	37.6 (3)	C9'—C12'—H12F	109.5
O1—Si1—O2'	82.2 (4)	H12D—C12'—H12F	109.5
O1'—Si1—O2'	102.5 (3)	H12E—C12'—H12F	109.5
O3—Si1—O2'	132.7 (3)	C13—O4—Si2	135.4 (4)
O3'—Si1—S1	116.0 (2)	C17—O5—Si2	137.3 (4)
O2—Si1—S1	113.2 (2)	C21—O6—Si2	136.7 (5)
O1—Si1—S1	108.12 (19)	O4—C13—C16	105.0 (8)
O1'—Si1—S1	108.70 (18)	O4—C13—C14	112.2 (7)
O3—Si1—S1	113.0 (2)	C16—C13—C14	114.8 (10)
O2'—Si1—S1	109.1 (2)	O4—C13—C15	103.5 (7)
O6—Si2—O4	114.4 (3)	C16—C13—C15	109.9 (10)
O6—Si2—O5	102.7 (3)	C14—C13—C15	110.7 (9)
O4—Si2—O5	104.9 (2)	C13—C14—H14A	109.5
O6—Si2—S2	113.5 (2)	C13—C14—H14B	109.5
O4—Si2—S2	107.96 (18)	H14A—C14—H14B	109.5
O5—Si2—S2	112.9 (2)	C13—C14—H14C	109.5
C1—O1—Si1	131.0 (6)	H14A—C14—H14C	109.5
C5—O2—Si1	136.7 (6)	H14B—C14—H14C	109.5
C9—O3—Si1	133.6 (7)	C13—C15—H15A	109.5
O1—C1—C3	109.8 (8)	C13—C15—H15B	109.5
O1—C1—C4	110.0 (8)	H15A—C15—H15B	109.5
C3—C1—C4	110.1 (9)	C13—C15—H15C	109.5
O1—C1—C2	108.2 (7)	H15A—C15—H15C	109.5
C3—C1—C2	108.8 (8)	H15B—C15—H15C	109.5
C4—C1—C2	109.8 (9)	C13—C16—H16A	109.5
C1—C2—H2A	109.5	C13—C16—H16B	109.5
C1—C2—H2B	109.5	H16A—C16—H16B	109.5
H2A—C2—H2B	109.5	C13—C16—H16C	109.5
C1—C2—H2C	109.5	H16A—C16—H16C	109.5
H2A—C2—H2C	109.5	H16B—C16—H16C	109.5
H2B—C2—H2C	109.5	O5—C17—C19	107.6 (6)
C1—C3—H3A	109.5	O5—C17—C18	114.6 (6)
C1—C3—H3B	109.5	C19—C17—C18	112.3 (7)
H3A—C3—H3B	109.5	O5—C17—C20	104.3 (7)
C1—C3—H3C	109.5	C19—C17—C20	110.8 (9)
H3A—C3—H3C	109.5	C18—C17—C20	107.0 (8)
H3B—C3—H3C	109.5	C17—C18—H18A	109.5
C1—C4—H4A	109.5	C17—C18—H18B	109.5
C1—C4—H4B	109.5	H18A—C18—H18B	109.5
H4A—C4—H4B	109.5	C17—C18—H18C	109.5
C1—C4—H4C	109.5	H18A—C18—H18C	109.5
H4A—C4—H4C	109.5	H18B—C18—H18C	109.5
H4B—C4—H4C	109.5	C17—C19—H19A	109.5
O2—C5—C7	109.8 (8)	C17—C19—H19B	109.5
O2—C5—C8	108.9 (7)	H19A—C19—H19B	109.5
C7—C5—C8	109.4 (8)	C17—C19—H19C	109.5
O2—C5—C6	107.2 (7)	H19A—C19—H19C	109.5
C7—C5—C6	110.5 (8)	H19B—C19—H19C	109.5
C8—C5—C6	111.0 (8)	C17—C20—H20A	109.5
C5—C6—H6A	109.5	C17—C20—H20B	109.5
C5—C6—H6B	109.5	H20A—C20—H20B	109.5
H6A—C6—H6B	109.5	C17—C20—H20C	109.5
C5—C6—H6C	109.5	H20A—C20—H20C	109.5
H6A—C6—H6C	109.5	H20B—C20—H20C	109.5
H6B—C6—H6C	109.5	O6—C21—C22	109.2 (7)
C5—C7—H7A	109.5	O6—C21—C24	103.8 (8)
C5—C7—H7B	109.5	C22—C21—C24	110.2 (10)
H7A—C7—H7B	109.5	O6—C21—C23	107.5 (7)
C5—C7—H7C	109.5	C22—C21—C23	114.3 (10)
H7A—C7—H7C	109.5	C24—C21—C23	111.3 (10)
H7B—C7—H7C	109.5	C21—C22—H22A	109.5
C5—C8—H8A	109.5	C21—C22—H22B	109.5
C5—C8—H8B	109.5	H22A—C22—H22B	109.5
H8A—C8—H8B	109.5	C21—C22—H22C	109.5
C5—C8—H8C	109.5	H22A—C22—H22C	109.5
H8A—C8—H8C	109.5	H22B—C22—H22C	109.5
H8B—C8—H8C	109.5	C21—C23—H23A	109.5
O3—C9—C10	110.2 (8)	C21—C23—H23B	109.5
O3—C9—C11	109.0 (7)	H23A—C23—H23B	109.5
C10—C9—C11	110.3 (9)	C21—C23—H23C	109.5
O3—C9—C12	107.0 (7)	H23A—C23—H23C	109.5
C10—C9—C12	109.6 (8)	H23B—C23—H23C	109.5
C11—C9—C12	110.7 (9)	C21—C24—H24A	109.5
C9—C10—H10A	109.5	C21—C24—H24B	109.5
C9—C10—H10B	109.5	H24A—C24—H24B	109.5
H10A—C10—H10B	109.5	C21—C24—H24C	109.5
C9—C10—H10C	109.5	H24A—C24—H24C	109.5
H10A—C10—H10C	109.5	H24B—C24—H24C	109.5
H10B—C10—H10C	109.5	C25—O7—Cd1	120.9 (4)
C9—C11—H11A	109.5	C25—N2—C27	122.9 (6)
C9—C11—H11B	109.5	C25—N2—C26	119.5 (6)
H11A—C11—H11B	109.5	C27—N2—C26	117.5 (6)
C9—C11—H11C	109.5	O7—C25—N2	126.5 (6)
H11A—C11—H11C	109.5	O7—C25—H25A	116.7
H11B—C11—H11C	109.5	N2—C25—H25A	116.7
C9—C12—H12A	109.5	N2—C26—H26A	109.5
C9—C12—H12B	109.5	N2—C26—H26B	109.5
H12A—C12—H12B	109.5	H26A—C26—H26B	109.5
C9—C12—H12C	109.5	N2—C26—H26C	109.5
H12A—C12—H12C	109.5	H26A—C26—H26C	109.5
H12B—C12—H12C	109.5	H26B—C26—H26C	109.5
C1'—O1'—Si1	137.7 (6)	N2—C27—H27A	109.5
C5'—O2'—Si1	136.1 (7)	N2—C27—H27B	109.5
C9'—O3'—Si1	138.3 (7)	H27A—C27—H27B	109.5
O1'—C1'—C3'	108.3 (7)	N2—C27—H27C	109.5
O1'—C1'—C4'	109.3 (7)	H27A—C27—H27C	109.5
C3'—C1'—C4'	111.4 (8)	H27B—C27—H27C	109.5
O1'—C1'—C2'	109.1 (7)	C28—N1—C32	120.0
C3'—C1'—C2'	109.5 (8)	C28—N1—Cd1	120.2 (5)
C4'—C1'—C2'	109.3 (8)	C32—N1—Cd1	119.2 (5)
C1'—C2'—H2'A	109.5	C29—C28—N1	120.0
C1'—C2'—H2'B	109.5	C29—C28—H28	120.0
H2'A—C2'—H2'B	109.5	N1—C28—H28	120.0
C1'—C2'—H2'C	109.5	C30—C29—C28	120.0
H2'A—C2'—H2'C	109.5	C30—C29—H29	120.0
H2'B—C2'—H2'C	109.5	C28—C29—H29	120.0
C1'—C3'—H3'A	109.5	C31—C30—C29	120.0
C1'—C3'—H3'B	109.5	C31—C30—C33	118.1 (4)
H3'A—C3'—H3'B	109.5	C29—C30—C33	121.9 (4)
C1'—C3'—H3'C	109.5	C30—C31—C32	120.0
H3'A—C3'—H3'C	109.5	C30—C31—H31	120.0
H3'B—C3'—H3'C	109.5	C32—C31—H31	120.0
C1'—C4'—H4'A	109.5	C31—C32—N1	120.0
C1'—C4'—H4'B	109.5	C31—C32—H32	120.0
H4'A—C4'—H4'B	109.5	N1—C32—H32	120.0
C1'—C4'—H4'C	109.5	C33^i—C33—C30	126.2 (11)
H4'A—C4'—H4'C	109.5	C33^i—C33—H33	116.9
H4'B—C4'—H4'C	109.5	C30—C33—H33	116.9
O2'—C5'—C7'	110.4 (8)	C28'—N1'—C32'	120.0
O2'—C5'—C8'	108.5 (8)	C28'—N1'—Cd1	116.1 (5)
C7'—C5'—C8'	110.1 (9)	C32'—N1'—Cd1	123.4 (5)
O2'—C5'—C6'	107.7 (7)	N1'—C28'—C29'	120.0
C7'—C5'—C6'	110.1 (9)	N1'—C28'—H28'	120.0
C8'—C5'—C6'	110.0 (9)	C29'—C28'—H28'	120.0
C5'—C6'—H6'A	109.5	C28'—C29'—C30'	120.0
C5'—C6'—H6'B	109.5	C28'—C29'—H29'	120.0
H6'A—C6'—H6'B	109.5	C30'—C29'—H29'	120.0
C5'—C6'—H6'C	109.5	C29'—C30'—C31'	120.0
H6'A—C6'—H6'C	109.5	C29'—C30'—C33'	119.7 (4)
H6'B—C6'—H6'C	109.5	C31'—C30'—C33'	120.3 (4)
C5'—C7'—H7'A	109.5	C32'—C31'—C30'	120.0
C5'—C7'—H7'B	109.5	C32'—C31'—H31'	120.0
H7'A—C7'—H7'B	109.5	C30'—C31'—H31'	120.0
C5'—C7'—H7'C	109.5	C31'—C32'—N1'	120.0
H7'A—C7'—H7'C	109.5	C31'—C32'—H32'	120.0
H7'B—C7'—H7'C	109.5	N1'—C32'—H32'	120.0
C5'—C8'—H8'A	109.5	C33'^i—C33'—C30'	126.7 (9)
C5'—C8'—H8'B	109.5	C33'^i—C33'—H33'	116.7
H8'A—C8'—H8'B	109.5	C30'—C33'—H33'	116.7
C5'—C8'—H8'C	109.5
N1'—Cd1—S1—Si1	63.9 (3)	Si1—O3'—C9'—C10'	90.0 (12)
N1—Cd1—S1—Si1	60.1 (4)	Si1—O3'—C9'—C11'	−148.3 (10)
S2—Cd1—S1—Si1	−84.99 (15)	Si1—O3'—C9'—C12'	−29.8 (14)
O7—Cd1—S1—Si1	152.05 (13)	O6—Si2—O4—C13	67.6 (8)
N1'—Cd1—S2—Si2	177.9 (3)	O5—Si2—O4—C13	−44.2 (8)
N1—Cd1—S2—Si2	−179.7 (3)	S2—Si2—O4—C13	−164.9 (7)
S1—Cd1—S2—Si2	−32.12 (17)	O6—Si2—O5—C17	65.3 (8)
O7—Cd1—S2—Si2	89.43 (13)	O4—Si2—O5—C17	−174.8 (7)
Cd1—S1—Si1—O3'	131.6 (3)	S2—Si2—O5—C17	−57.4 (8)
Cd1—S1—Si1—O2	−149.5 (3)	O4—Si2—O6—C21	78.1 (7)
Cd1—S1—Si1—O1	−21.6 (4)	O5—Si2—O6—C21	−168.8 (7)
Cd1—S1—Si1—O1'	1.6 (3)	S2—Si2—O6—C21	−46.5 (8)
Cd1—S1—Si1—O3	92.7 (3)	Si2—O4—C13—C16	108.0 (10)
Cd1—S1—Si1—O2'	−109.4 (3)	Si2—O4—C13—C14	−17.4 (12)
Cd1—S2—Si2—O6	129.5 (2)	Si2—O4—C13—C15	−136.8 (8)
Cd1—S2—Si2—O4	1.5 (2)	Si2—O5—C17—C19	−135.6 (8)
Cd1—S2—Si2—O5	−114.0 (2)	Si2—O5—C17—C18	−9.9 (11)
O3'—Si1—O1—C1	11.8 (11)	Si2—O5—C17—C20	106.7 (9)
O2—Si1—O1—C1	−72.3 (10)	Si2—O6—C21—C22	−35.6 (12)
O1'—Si1—O1—C1	65.3 (9)	Si2—O6—C21—C24	−153.2 (8)
O3—Si1—O1—C1	40.2 (10)	Si2—O6—C21—C23	88.8 (10)
O2'—Si1—O1—C1	−91.9 (9)	N1'—Cd1—O7—C25	−86.6 (5)
S1—Si1—O1—C1	160.5 (8)	N1—Cd1—O7—C25	−82.1 (6)
O3'—Si1—O2—C5	155.2 (9)	S1—Cd1—O7—C25	167.3 (5)
O1—Si1—O2—C5	−80.2 (10)	S2—Cd1—O7—C25	9.2 (5)
O1'—Si1—O2—C5	−99.3 (9)	Cd1—O7—C25—N2	174.8 (5)
O3—Si1—O2—C5	167.4 (9)	C27—N2—C25—O7	−177.6 (7)
O2'—Si1—O2—C5	−47.1 (9)	C26—N2—C25—O7	0.4 (10)
S1—Si1—O2—C5	44.4 (10)	N1'—Cd1—N1—C28	−22 (6)
O3'—Si1—O3—C9	−26.8 (9)	S1—Cd1—N1—C28	17.6 (7)
O2—Si1—O3—C9	−46.9 (10)	S2—Cd1—N1—C28	−176.9 (6)
O1—Si1—O3—C9	−166.9 (9)	O7—Cd1—N1—C28	−76.2 (6)
O1'—Si1—O3—C9	−176.1 (9)	N1'—Cd1—N1—C32	166 (7)
O2'—Si1—O3—C9	−74.9 (10)	S1—Cd1—N1—C32	−153.6 (5)
S1—Si1—O3—C9	76.2 (9)	S2—Cd1—N1—C32	11.9 (5)
Si1—O1—C1—C3	−83.9 (13)	O7—Cd1—N1—C32	112.6 (5)
Si1—O1—C1—C4	37.5 (14)	C32—N1—C28—C29	0.0
Si1—O1—C1—C2	157.5 (11)	Cd1—N1—C28—C29	−171.1 (7)
Si1—O2—C5—C7	−78.0 (12)	N1—C28—C29—C30	0.0
Si1—O2—C5—C8	41.7 (13)	C28—C29—C30—C31	0.0
Si1—O2—C5—C6	161.9 (9)	C28—C29—C30—C33	179.3 (3)
Si1—O3—C9—C10	−33.2 (13)	C29—C30—C31—C32	0.0
Si1—O3—C9—C11	87.9 (11)	C33—C30—C31—C32	−179.3 (3)
Si1—O3—C9—C12	−152.3 (9)	C30—C31—C32—N1	0.0
O3'—Si1—O1'—C1'	61.2 (10)	C28—N1—C32—C31	0.0
O2—Si1—O1'—C1'	−22.8 (11)	Cd1—N1—C32—C31	171.2 (7)
O1—Si1—O1'—C1'	−75.5 (9)	C31—C30—C33—C33^i	−173.7 (13)
O3—Si1—O1'—C1'	80.0 (10)	C29—C30—C33—C33^i	7.0 (14)
O2'—Si1—O1'—C1'	−52.4 (10)	N1—Cd1—N1'—C28'	154 (7)
S1—Si1—O1'—C1'	−167.7 (9)	S1—Cd1—N1'—C28'	13.0 (5)
O3'—Si1—O2'—C5'	54.9 (10)	S2—Cd1—N1'—C28'	179.9 (4)
O2—Si1—O2'—C5'	33.1 (10)	O7—Cd1—N1'—C28'	−79.7 (4)
O1—Si1—O2'—C5'	−177.0 (9)	N1—Cd1—N1'—C32'	−18 (6)
O1'—Si1—O2'—C5'	174.4 (9)	S1—Cd1—N1'—C32'	−158.9 (6)
O3—Si1—O2'—C5'	81.4 (10)	S2—Cd1—N1'—C32'	8.0 (7)
S1—Si1—O2'—C5'	−70.5 (10)	O7—Cd1—N1'—C32'	108.4 (7)
O2—Si1—O3'—C9'	−159.9 (10)	C32'—N1'—C28'—C29'	0.0
O1—Si1—O3'—C9'	93.9 (10)	Cd1—N1'—C28'—C29'	−172.2 (7)
O1'—Si1—O3'—C9'	74.6 (10)	N1'—C28'—C29'—C30'	0.0
O3—Si1—O3'—C9'	40.9 (10)	C28'—C29'—C30'—C31'	0.0
O2'—Si1—O3'—C9'	−173.7 (9)	C28'—C29'—C30'—C33'	179.5 (3)
S1—Si1—O3'—C9'	−52.8 (10)	C29'—C30'—C31'—C32'	0.0
Si1—O1'—C1'—C3'	−162.5 (10)	C33'—C30'—C31'—C32'	−179.5 (3)
Si1—O1'—C1'—C4'	−41.0 (14)	C30'—C31'—C32'—N1'	0.0
Si1—O1'—C1'—C2'	78.4 (13)	C28'—N1'—C32'—C31'	0.0
Si1—O2'—C5'—C7'	8.6 (14)	Cd1—N1'—C32'—C31'	171.6 (7)
Si1—O2'—C5'—C8'	129.3 (11)	C29'—C30'—C33'—C33'^i	−155.1 (12)
Si1—O2'—C5'—C6'	−111.6 (12)	C31'—C30'—C33'—C33'^i	24.5 (13)

Symmetry code: (i) −x, −y+1, −z+1.