Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806004958/ng2002sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806004958/ng2002Isup2.hkl |
CCDC reference: 601797
Data collection: CrystalClear (Rigaku, 2004); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Burnett & Johnson, 1996); software used to prepare material for publication: SHELXL97 and Yadokari-XG (Wakita, 2005).
[PdCl2(C30H37PSi)2] | Z = 1 |
Mr = 1090.61 | F(000) = 572 |
Triclinic, P1 | Dx = 1.345 Mg m−3 |
Hall symbol: -P 1 | Melting point = 505–507 K |
a = 9.253 (6) Å | Mo Kα radiation, λ = 0.71070 Å |
b = 10.897 (7) Å | Cell parameters from 3738 reflections |
c = 14.311 (9) Å | θ = 3.1–25.5° |
α = 106.403 (10)° | µ = 0.59 mm−1 |
β = 92.296 (10)° | T = 103 K |
γ = 102.087 (9)° | Prism, yellow |
V = 1346.0 (15) Å3 | 0.20 × 0.15 × 0.05 mm |
Saturn70 CCD (4 × 4 bin mode) diffractometer | 4993 independent reflections |
Radiation source: fine-focus sealed tube | 4405 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.041 |
Detector resolution: 28.5714 pixels mm-1 | θmax = 25.5°, θmin = 3.1° |
ω scans | h = −11→11 |
Absorption correction: multi-scan (Jacobson, 1998) | k = −13→13 |
Tmin = 0.892, Tmax = 0.971 | l = −17→17 |
14206 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.034 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.080 | H-atom parameters constrained |
S = 1.09 | w = 1/[σ2(Fo2) + (0.0324P)2 + 0.108P] where P = (Fo2 + 2Fc2)/3 |
4993 reflections | (Δ/σ)max = 0.001 |
304 parameters | Δρmax = 0.50 e Å−3 |
0 restraints | Δρmin = −0.28 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Pd1 | 1.0000 | 0.0000 | 1.0000 | 0.01254 (9) | |
Cl1 | 1.04901 (7) | 0.20253 (6) | 1.11644 (4) | 0.01873 (15) | |
P1 | 0.85897 (7) | 0.10117 (6) | 0.91651 (4) | 0.01184 (14) | |
C1 | 0.9595 (3) | 0.2597 (2) | 0.90420 (17) | 0.0129 (5) | |
C2 | 1.1127 (3) | 0.3012 (2) | 0.92416 (17) | 0.0152 (5) | |
H1 | 1.1682 | 0.2484 | 0.9458 | 0.018* | |
C3 | 1.1848 (3) | 0.4204 (2) | 0.91233 (18) | 0.0169 (5) | |
H2 | 1.2898 | 0.4491 | 0.9261 | 0.020* | |
C4 | 1.1042 (3) | 0.4979 (2) | 0.88052 (17) | 0.0185 (6) | |
H3 | 1.1538 | 0.5793 | 0.8725 | 0.022* | |
C5 | 0.9510 (3) | 0.4559 (2) | 0.86055 (17) | 0.0155 (5) | |
H4 | 0.8963 | 0.5095 | 0.8392 | 0.019* | |
C6 | 0.8761 (3) | 0.3369 (2) | 0.87115 (17) | 0.0137 (5) | |
C7 | 0.7587 (2) | 0.0275 (2) | 0.79142 (17) | 0.0134 (5) | |
C8 | 0.7703 (3) | −0.0938 (2) | 0.73049 (17) | 0.0162 (5) | |
H5 | 0.8310 | −0.1425 | 0.7527 | 0.019* | |
C9 | 0.6937 (3) | −0.1439 (2) | 0.63749 (18) | 0.0207 (6) | |
H6 | 0.7025 | −0.2267 | 0.5963 | 0.025* | |
C10 | 0.6049 (3) | −0.0745 (3) | 0.60431 (19) | 0.0221 (6) | |
H7 | 0.5517 | −0.1098 | 0.5408 | 0.026* | |
C11 | 0.5937 (3) | 0.0471 (2) | 0.66434 (18) | 0.0188 (6) | |
H8 | 0.5330 | 0.0949 | 0.6411 | 0.023* | |
C12 | 0.6695 (3) | 0.1006 (2) | 0.75775 (17) | 0.0143 (5) | |
C13 | 0.7068 (2) | 0.1452 (2) | 0.98899 (17) | 0.0117 (5) | |
C14 | 0.6768 (3) | 0.1027 (2) | 1.07065 (18) | 0.0162 (5) | |
H9 | 0.7360 | 0.0514 | 1.0908 | 0.019* | |
C15 | 0.5594 (3) | 0.1357 (2) | 1.12288 (18) | 0.0173 (5) | |
H10 | 0.5395 | 0.1073 | 1.1790 | 0.021* | |
C16 | 0.4718 (3) | 0.2095 (2) | 1.09369 (18) | 0.0180 (5) | |
H11 | 0.3914 | 0.2307 | 1.1292 | 0.022* | |
C17 | 0.5017 (3) | 0.2525 (2) | 1.01224 (18) | 0.0157 (5) | |
H12 | 0.4419 | 0.3038 | 0.9928 | 0.019* | |
C18 | 0.6196 (2) | 0.2208 (2) | 0.95827 (17) | 0.0138 (5) | |
Si1 | 0.67096 (7) | 0.26560 (6) | 0.84529 (5) | 0.01366 (15) | |
C19 | 0.5457 (3) | 0.3639 (2) | 0.81364 (19) | 0.0192 (6) | |
H13 | 0.4429 | 0.3135 | 0.8124 | 0.023* | |
H14 | 0.5603 | 0.4449 | 0.8696 | 0.023* | |
C20 | 0.5498 (3) | 0.4074 (3) | 0.72104 (19) | 0.0215 (6) | |
H15 | 0.5443 | 0.3306 | 0.6630 | 0.026* | |
H16 | 0.6444 | 0.4717 | 0.7245 | 0.026* | |
C21 | 0.4185 (3) | 0.4701 (2) | 0.71110 (19) | 0.0203 (6) | |
H17 | 0.3254 | 0.4055 | 0.7105 | 0.024* | |
H18 | 0.4260 | 0.5465 | 0.7699 | 0.024* | |
C22 | 0.4070 (3) | 0.5161 (3) | 0.6207 (2) | 0.0243 (6) | |
H19 | 0.3946 | 0.4400 | 0.5612 | 0.029* | |
H20 | 0.5002 | 0.5797 | 0.6197 | 0.029* | |
C23 | 0.2759 (3) | 0.5811 (3) | 0.6193 (2) | 0.0259 (6) | |
H21 | 0.1846 | 0.5197 | 0.6264 | 0.031* | |
H22 | 0.2929 | 0.6606 | 0.6767 | 0.031* | |
C24 | 0.2501 (3) | 0.6204 (3) | 0.5268 (2) | 0.0249 (6) | |
H23 | 0.3405 | 0.6828 | 0.5197 | 0.030* | |
H24 | 0.2330 | 0.5413 | 0.4691 | 0.030* | |
C25 | 0.1177 (3) | 0.6840 (3) | 0.52855 (19) | 0.0243 (6) | |
H25 | 0.0268 | 0.6200 | 0.5329 | 0.029* | |
H26 | 0.1330 | 0.7605 | 0.5881 | 0.029* | |
C26 | 0.0934 (3) | 0.7298 (3) | 0.4390 (2) | 0.0239 (6) | |
H27 | 0.0798 | 0.6538 | 0.3792 | 0.029* | |
H28 | 0.1831 | 0.7954 | 0.4353 | 0.029* | |
C27 | −0.0425 (3) | 0.7910 (3) | 0.44145 (19) | 0.0211 (6) | |
H29 | −0.1332 | 0.7232 | 0.4399 | 0.025* | |
H30 | −0.0326 | 0.8623 | 0.5038 | 0.025* | |
C28 | −0.0604 (3) | 0.8466 (3) | 0.35599 (19) | 0.0209 (6) | |
H31 | 0.0304 | 0.9143 | 0.3576 | 0.025* | |
H32 | −0.0701 | 0.7752 | 0.2937 | 0.025* | |
C29 | −0.1948 (3) | 0.9074 (3) | 0.35764 (19) | 0.0216 (6) | |
H33 | −0.1868 | 0.9773 | 0.4206 | 0.026* | |
H34 | −0.2861 | 0.8392 | 0.3538 | 0.026* | |
C30 | −0.2078 (3) | 0.9659 (3) | 0.2735 (2) | 0.0255 (6) | |
H35 | −0.2955 | 1.0037 | 0.2776 | 0.038* | |
H36 | −0.2179 | 0.8967 | 0.2109 | 0.038* | |
H37 | −0.1186 | 1.0348 | 0.2777 | 0.038* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pd1 | 0.01289 (15) | 0.01024 (14) | 0.01518 (15) | 0.00336 (10) | 0.00008 (11) | 0.00458 (11) |
Cl1 | 0.0242 (3) | 0.0123 (3) | 0.0185 (3) | 0.0057 (3) | −0.0030 (3) | 0.0025 (2) |
P1 | 0.0120 (3) | 0.0106 (3) | 0.0133 (3) | 0.0025 (2) | 0.0008 (3) | 0.0041 (2) |
C1 | 0.0164 (13) | 0.0106 (12) | 0.0108 (12) | 0.0024 (10) | 0.0031 (10) | 0.0021 (10) |
C2 | 0.0165 (13) | 0.0141 (12) | 0.0151 (13) | 0.0056 (10) | 0.0024 (10) | 0.0028 (10) |
C3 | 0.0118 (12) | 0.0198 (13) | 0.0179 (13) | 0.0029 (10) | 0.0036 (10) | 0.0039 (11) |
C4 | 0.0250 (14) | 0.0126 (12) | 0.0161 (13) | 0.0001 (11) | 0.0058 (11) | 0.0040 (10) |
C5 | 0.0193 (13) | 0.0156 (12) | 0.0137 (12) | 0.0062 (10) | 0.0022 (10) | 0.0058 (10) |
C6 | 0.0150 (12) | 0.0149 (12) | 0.0121 (12) | 0.0046 (10) | 0.0033 (10) | 0.0040 (10) |
C7 | 0.0115 (12) | 0.0151 (12) | 0.0121 (12) | −0.0015 (10) | 0.0025 (10) | 0.0050 (10) |
C8 | 0.0162 (13) | 0.0158 (13) | 0.0174 (13) | 0.0020 (10) | 0.0026 (11) | 0.0070 (10) |
C9 | 0.0252 (14) | 0.0159 (13) | 0.0176 (13) | 0.0012 (11) | 0.0050 (11) | 0.0018 (11) |
C10 | 0.0224 (14) | 0.0217 (14) | 0.0151 (13) | −0.0046 (11) | −0.0031 (11) | 0.0022 (11) |
C11 | 0.0155 (13) | 0.0232 (14) | 0.0190 (13) | 0.0026 (11) | 0.0005 (11) | 0.0100 (11) |
C12 | 0.0141 (12) | 0.0158 (12) | 0.0151 (13) | 0.0028 (10) | 0.0061 (10) | 0.0079 (10) |
C13 | 0.0094 (11) | 0.0103 (11) | 0.0143 (12) | 0.0012 (9) | 0.0013 (10) | 0.0025 (10) |
C14 | 0.0158 (13) | 0.0111 (12) | 0.0193 (13) | −0.0003 (10) | −0.0020 (10) | 0.0037 (10) |
C15 | 0.0162 (13) | 0.0174 (13) | 0.0156 (13) | −0.0027 (10) | 0.0009 (11) | 0.0055 (10) |
C16 | 0.0138 (13) | 0.0188 (13) | 0.0183 (13) | 0.0009 (10) | 0.0046 (11) | 0.0023 (11) |
C17 | 0.0114 (12) | 0.0134 (12) | 0.0209 (13) | 0.0018 (10) | −0.0010 (10) | 0.0039 (10) |
C18 | 0.0112 (12) | 0.0124 (12) | 0.0148 (13) | −0.0016 (10) | −0.0017 (10) | 0.0028 (10) |
Si1 | 0.0129 (3) | 0.0146 (3) | 0.0153 (4) | 0.0041 (3) | 0.0007 (3) | 0.0067 (3) |
C19 | 0.0171 (13) | 0.0197 (13) | 0.0227 (14) | 0.0061 (11) | 0.0001 (11) | 0.0083 (11) |
C20 | 0.0197 (14) | 0.0227 (14) | 0.0238 (14) | 0.0048 (11) | −0.0001 (11) | 0.0100 (12) |
C21 | 0.0203 (14) | 0.0177 (13) | 0.0221 (14) | 0.0039 (11) | −0.0035 (11) | 0.0059 (11) |
C22 | 0.0219 (14) | 0.0255 (15) | 0.0279 (15) | 0.0021 (12) | −0.0020 (12) | 0.0147 (12) |
C23 | 0.0309 (16) | 0.0219 (14) | 0.0254 (15) | 0.0052 (12) | −0.0022 (12) | 0.0092 (12) |
C24 | 0.0256 (15) | 0.0241 (15) | 0.0277 (15) | 0.0029 (12) | −0.0024 (12) | 0.0147 (12) |
C25 | 0.0267 (15) | 0.0226 (14) | 0.0250 (15) | 0.0053 (12) | −0.0014 (12) | 0.0103 (12) |
C26 | 0.0223 (14) | 0.0249 (15) | 0.0259 (15) | 0.0036 (12) | 0.0001 (12) | 0.0115 (12) |
C27 | 0.0231 (14) | 0.0200 (14) | 0.0197 (14) | 0.0011 (11) | −0.0004 (11) | 0.0083 (11) |
C28 | 0.0205 (14) | 0.0224 (14) | 0.0215 (14) | 0.0058 (11) | 0.0022 (11) | 0.0088 (11) |
C29 | 0.0187 (14) | 0.0215 (14) | 0.0243 (14) | 0.0036 (11) | 0.0024 (11) | 0.0071 (12) |
C30 | 0.0263 (15) | 0.0282 (15) | 0.0266 (15) | 0.0100 (12) | 0.0026 (12) | 0.0130 (13) |
Pd1—Cl1 | 2.3014 (13) | C17—H12 | 0.9500 |
Pd1—Cl1i | 2.3014 (13) | C18—Si1 | 1.868 (3) |
Pd1—P1 | 2.3596 (11) | Si1—C19 | 1.857 (3) |
Pd1—P1i | 2.3596 (11) | C19—C20 | 1.528 (3) |
P1—C1 | 1.842 (3) | C19—H13 | 0.9900 |
P1—C13 | 1.846 (2) | C19—H14 | 0.9900 |
P1—C7 | 1.858 (3) | C20—C21 | 1.534 (4) |
P1—Si1 | 3.0774 (15) | C20—H15 | 0.9900 |
C1—C2 | 1.386 (3) | C20—H16 | 0.9900 |
C1—C6 | 1.413 (3) | C21—C22 | 1.521 (4) |
C2—C3 | 1.390 (3) | C21—H17 | 0.9900 |
C2—H1 | 0.9500 | C21—H18 | 0.9900 |
C3—C4 | 1.389 (4) | C22—C23 | 1.529 (4) |
C3—H2 | 0.9500 | C22—H19 | 0.9900 |
C4—C5 | 1.386 (3) | C22—H20 | 0.9900 |
C4—H3 | 0.9500 | C23—C24 | 1.527 (4) |
C5—C6 | 1.388 (3) | C23—H21 | 0.9900 |
C5—H4 | 0.9500 | C23—H22 | 0.9900 |
C6—Si1 | 1.873 (3) | C24—C25 | 1.527 (4) |
C7—C8 | 1.391 (3) | C24—H23 | 0.9900 |
C7—C12 | 1.417 (3) | C24—H24 | 0.9900 |
C8—C9 | 1.387 (3) | C25—C26 | 1.526 (4) |
C8—H5 | 0.9500 | C25—H25 | 0.9900 |
C9—C10 | 1.380 (4) | C25—H26 | 0.9900 |
C9—H6 | 0.9500 | C26—C27 | 1.539 (4) |
C10—C11 | 1.388 (4) | C26—H27 | 0.9900 |
C10—H7 | 0.9500 | C26—H28 | 0.9900 |
C11—C12 | 1.390 (3) | C27—C28 | 1.529 (3) |
C11—H8 | 0.9500 | C27—H29 | 0.9900 |
C12—Si1 | 1.876 (3) | C27—H30 | 0.9900 |
C13—C14 | 1.391 (3) | C28—C29 | 1.524 (4) |
C13—C18 | 1.406 (3) | C28—H31 | 0.9900 |
C14—C15 | 1.394 (3) | C28—H32 | 0.9900 |
C14—H9 | 0.9500 | C29—C30 | 1.525 (4) |
C15—C16 | 1.383 (4) | C29—H33 | 0.9900 |
C15—H10 | 0.9500 | C29—H34 | 0.9900 |
C16—C17 | 1.391 (3) | C30—H35 | 0.9800 |
C16—H11 | 0.9500 | C30—H36 | 0.9800 |
C17—C18 | 1.407 (3) | C30—H37 | 0.9800 |
Cl1—Pd1—Cl1i | 180.0 | C20—C19—Si1 | 123.62 (18) |
Cl1—Pd1—P1 | 82.77 (5) | C20—C19—H13 | 106.4 |
Cl1i—Pd1—P1 | 97.23 (5) | Si1—C19—H13 | 106.4 |
Cl1—Pd1—P1i | 97.23 (5) | C20—C19—H14 | 106.4 |
Cl1i—Pd1—P1i | 82.77 (5) | Si1—C19—H14 | 106.4 |
P1—Pd1—P1i | 180.00 (2) | H13—C19—H14 | 106.5 |
C1—P1—C13 | 103.27 (11) | C19—C20—C21 | 109.7 (2) |
C1—P1—C7 | 99.25 (11) | C19—C20—H15 | 109.7 |
C13—P1—C7 | 101.15 (11) | C21—C20—H15 | 109.7 |
C1—P1—Pd1 | 114.90 (9) | C19—C20—H16 | 109.7 |
C13—P1—Pd1 | 108.86 (9) | C21—C20—H16 | 109.7 |
C7—P1—Pd1 | 126.49 (9) | H15—C20—H16 | 108.2 |
C2—C1—C6 | 120.6 (2) | C22—C21—C20 | 115.5 (2) |
C2—C1—P1 | 121.47 (18) | C22—C21—H17 | 108.4 |
C6—C1—P1 | 117.92 (18) | C20—C21—H17 | 108.4 |
C1—C2—C3 | 119.7 (2) | C22—C21—H18 | 108.4 |
C1—C2—H1 | 120.1 | C20—C21—H18 | 108.4 |
C3—C2—H1 | 120.1 | H17—C21—H18 | 107.5 |
C4—C3—C2 | 120.4 (2) | C21—C22—C23 | 111.5 (2) |
C4—C3—H2 | 119.8 | C21—C22—H19 | 109.3 |
C2—C3—H2 | 119.8 | C23—C22—H19 | 109.3 |
C5—C4—C3 | 119.7 (2) | C21—C22—H20 | 109.3 |
C5—C4—H3 | 120.2 | C23—C22—H20 | 109.3 |
C3—C4—H3 | 120.2 | H19—C22—H20 | 108.0 |
C4—C5—C6 | 121.2 (2) | C24—C23—C22 | 114.4 (2) |
C4—C5—H4 | 119.4 | C24—C23—H21 | 108.7 |
C6—C5—H4 | 119.4 | C22—C23—H21 | 108.7 |
C5—C6—C1 | 118.4 (2) | C24—C23—H22 | 108.7 |
C5—C6—Si1 | 126.29 (18) | C22—C23—H22 | 108.7 |
C1—C6—Si1 | 115.34 (18) | H21—C23—H22 | 107.6 |
C8—C7—C12 | 119.8 (2) | C25—C24—C23 | 112.5 (2) |
C8—C7—P1 | 122.62 (18) | C25—C24—H23 | 109.1 |
C12—C7—P1 | 117.62 (18) | C23—C24—H23 | 109.1 |
C9—C8—C7 | 120.3 (2) | C25—C24—H24 | 109.1 |
C9—C8—H5 | 119.9 | C23—C24—H24 | 109.1 |
C7—C8—H5 | 119.9 | H23—C24—H24 | 107.8 |
C10—C9—C8 | 120.6 (2) | C26—C25—C24 | 113.6 (2) |
C10—C9—H6 | 119.7 | C26—C25—H25 | 108.8 |
C8—C9—H6 | 119.7 | C24—C25—H25 | 108.8 |
C9—C10—C11 | 119.5 (2) | C26—C25—H26 | 108.8 |
C9—C10—H7 | 120.2 | C24—C25—H26 | 108.8 |
C11—C10—H7 | 120.2 | H25—C25—H26 | 107.7 |
C10—C11—C12 | 121.4 (2) | C25—C26—C27 | 112.7 (2) |
C10—C11—H8 | 119.3 | C25—C26—H27 | 109.1 |
C12—C11—H8 | 119.3 | C27—C26—H27 | 109.1 |
C11—C12—C7 | 118.5 (2) | C25—C26—H28 | 109.1 |
C11—C12—Si1 | 126.34 (19) | C27—C26—H28 | 109.1 |
C7—C12—Si1 | 115.17 (18) | H27—C26—H28 | 107.8 |
C14—C13—C18 | 120.7 (2) | C28—C27—C26 | 112.9 (2) |
C14—C13—P1 | 121.15 (18) | C28—C27—H29 | 109.0 |
C18—C13—P1 | 118.17 (18) | C26—C27—H29 | 109.0 |
C13—C14—C15 | 119.8 (2) | C28—C27—H30 | 109.0 |
C13—C14—H9 | 120.1 | C26—C27—H30 | 109.0 |
C15—C14—H9 | 120.1 | H29—C27—H30 | 107.8 |
C16—C15—C14 | 120.5 (2) | C29—C28—C27 | 113.4 (2) |
C16—C15—H10 | 119.7 | C29—C28—H31 | 108.9 |
C14—C15—H10 | 119.7 | C27—C28—H31 | 108.9 |
C15—C16—C17 | 119.9 (2) | C29—C28—H32 | 108.9 |
C15—C16—H11 | 120.0 | C27—C28—H32 | 108.9 |
C17—C16—H11 | 120.0 | H31—C28—H32 | 107.7 |
C16—C17—C18 | 120.8 (2) | C28—C29—C30 | 112.4 (2) |
C16—C17—H12 | 119.6 | C28—C29—H33 | 109.1 |
C18—C17—H12 | 119.6 | C30—C29—H33 | 109.1 |
C13—C18—C17 | 118.4 (2) | C28—C29—H34 | 109.1 |
C13—C18—Si1 | 115.32 (17) | C30—C29—H34 | 109.1 |
C17—C18—Si1 | 126.28 (18) | H33—C29—H34 | 107.8 |
C19—Si1—C18 | 110.26 (11) | C29—C30—H35 | 109.5 |
C19—Si1—C6 | 119.91 (12) | C29—C30—H36 | 109.5 |
C18—Si1—C6 | 103.75 (11) | H35—C30—H36 | 109.5 |
C19—Si1—C12 | 118.94 (12) | C29—C30—H37 | 109.5 |
C18—Si1—C12 | 101.45 (11) | H35—C30—H37 | 109.5 |
C6—Si1—C12 | 100.03 (11) | H36—C30—H37 | 109.5 |
Cl1—Pd1—P1—C1 | 51.78 (9) | C1—P1—C13—C18 | 50.0 (2) |
Cl1i—Pd1—P1—C1 | −128.22 (9) | C7—P1—C13—C18 | −52.4 (2) |
P1i—Pd1—P1—C1 | 145 (100) | Pd1—P1—C13—C18 | 172.55 (16) |
Cl1—Pd1—P1—C13 | −63.44 (8) | C18—C13—C14—C15 | −0.2 (3) |
Cl1i—Pd1—P1—C13 | 116.56 (8) | P1—C13—C14—C15 | −178.91 (18) |
P1i—Pd1—P1—C13 | 30 (100) | C13—C14—C15—C16 | 0.5 (4) |
Cl1—Pd1—P1—C7 | 176.11 (9) | C14—C15—C16—C17 | −0.7 (4) |
Cl1i—Pd1—P1—C7 | −3.89 (9) | C15—C16—C17—C18 | 0.6 (4) |
P1i—Pd1—P1—C7 | −91 (100) | C14—C13—C18—C17 | 0.1 (3) |
C13—P1—C1—C2 | 131.2 (2) | P1—C13—C18—C17 | 178.83 (17) |
C7—P1—C1—C2 | −124.9 (2) | C14—C13—C18—Si1 | −178.27 (18) |
Pd1—P1—C1—C2 | 12.8 (2) | P1—C13—C18—Si1 | 0.5 (2) |
C13—P1—C1—C6 | −50.4 (2) | C16—C17—C18—C13 | −0.3 (3) |
C7—P1—C1—C6 | 53.4 (2) | C16—C17—C18—Si1 | 177.87 (18) |
Pd1—P1—C1—C6 | −168.83 (15) | C13—C18—Si1—C19 | 179.59 (17) |
C6—C1—C2—C3 | 0.5 (4) | C17—C18—Si1—C19 | 1.4 (2) |
P1—C1—C2—C3 | 178.87 (18) | C13—C18—Si1—C6 | −50.8 (2) |
C1—C2—C3—C4 | −0.1 (4) | C17—C18—Si1—C6 | 131.0 (2) |
C2—C3—C4—C5 | 0.0 (4) | C13—C18—Si1—C12 | 52.6 (2) |
C3—C4—C5—C6 | −0.4 (4) | C17—C18—Si1—C12 | −125.6 (2) |
C4—C5—C6—C1 | 0.8 (4) | C5—C6—Si1—C19 | −6.5 (3) |
C4—C5—C6—Si1 | −178.96 (18) | C1—C6—Si1—C19 | 173.78 (17) |
C2—C1—C6—C5 | −0.9 (3) | C5—C6—Si1—C18 | −130.0 (2) |
P1—C1—C6—C5 | −179.27 (17) | C1—C6—Si1—C18 | 50.3 (2) |
C2—C1—C6—Si1 | 178.91 (17) | C5—C6—Si1—C12 | 125.5 (2) |
P1—C1—C6—Si1 | 0.5 (2) | C1—C6—Si1—C12 | −54.3 (2) |
C1—P1—C7—C8 | 124.1 (2) | C11—C12—Si1—C19 | 7.1 (3) |
C13—P1—C7—C8 | −130.3 (2) | C7—C12—Si1—C19 | −174.72 (17) |
Pd1—P1—C7—C8 | −6.5 (2) | C11—C12—Si1—C18 | 128.2 (2) |
C1—P1—C7—C12 | −54.7 (2) | C7—C12—Si1—C18 | −53.67 (19) |
C13—P1—C7—C12 | 50.9 (2) | C11—C12—Si1—C6 | −125.4 (2) |
Pd1—P1—C7—C12 | 174.62 (14) | C7—C12—Si1—C6 | 52.71 (19) |
C12—C7—C8—C9 | −0.7 (3) | C18—Si1—C19—C20 | −175.2 (2) |
P1—C7—C8—C9 | −179.58 (18) | C6—Si1—C19—C20 | 64.5 (2) |
C7—C8—C9—C10 | −0.2 (4) | C12—Si1—C19—C20 | −58.7 (3) |
C8—C9—C10—C11 | 0.8 (4) | Si1—C19—C20—C21 | 172.38 (18) |
C9—C10—C11—C12 | −0.4 (4) | C19—C20—C21—C22 | −178.9 (2) |
C10—C11—C12—C7 | −0.4 (4) | C20—C21—C22—C23 | −178.1 (2) |
C10—C11—C12—Si1 | 177.66 (19) | C21—C22—C23—C24 | −175.5 (2) |
C8—C7—C12—C11 | 1.0 (3) | C22—C23—C24—C25 | 179.7 (2) |
P1—C7—C12—C11 | 179.92 (17) | C23—C24—C25—C26 | 177.5 (2) |
C8—C7—C12—Si1 | −177.29 (17) | C24—C25—C26—C27 | 178.8 (2) |
P1—C7—C12—Si1 | 1.6 (2) | C25—C26—C27—C28 | 175.5 (2) |
C1—P1—C13—C14 | −131.2 (2) | C26—C27—C28—C29 | 180.0 (2) |
C7—P1—C13—C14 | 126.3 (2) | C27—C28—C29—C30 | 178.3 (2) |
Pd1—P1—C13—C14 | −8.7 (2) |
Symmetry code: (i) −x+2, −y, −z+2. |