Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802019153/na6174sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802019153/na6174Isup2.hkl |
CCDC reference: 200741
Key indicators
- Single-crystal X-ray study
- T = 150 K
- Mean (C-C) = 0.018 Å
- R factor = 0.064
- wR factor = 0.127
- Data-to-parameter ratio = 14.2
checkCIF results
No syntax errors found ADDSYM reports no extra symmetry
Alert Level C:
RINTA_01 Alert C The value of Rint is greater than 0.10 Rint given 0.109 General Notes
REFLT_03 From the CIF: _diffrn_reflns_theta_max 25.00 From the CIF: _reflns_number_total 5652 From the CIF: _diffrn_reflns_limit_ max hkl 11. 12. 36. From the CIF: _diffrn_reflns_limit_ min hkl -11. -12. -37. TEST1: Expected hkl limits for theta max Calculated maximum hkl 11. 12. 40. Calculated minimum hkl -11. -12. -40. ALERT: Expected hkl max differ from CIF values REFLT_03 From the CIF: _diffrn_reflns_theta_max 25.00 From the CIF: _reflns_number_total 5652 Count of symmetry unique reflns 3412 Completeness (_total/calc) 165.65% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 2240 Fraction of Friedel pairs measured 0.657 Are heavy atom types Z>Si present yes Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF.
0 Alert Level A = Potentially serious problem
0 Alert Level B = Potential problem
1 Alert Level C = Please check
Data collection: COLLECT (Nonius, 1997-2001); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXTL (Sheldrick, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
[Co(C5H5)2]2[RuCl3(C12H10ClSi)(CO)2] | F(000) = 1720 |
Mr = 859.40 | Dx = 1.679 Mg m−3 |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 3060 reflections |
a = 9.7462 (5) Å | θ = 2.6–25.0° |
b = 10.2277 (6) Å | µ = 1.78 mm−1 |
c = 34.099 (2) Å | T = 150 K |
V = 3399.0 (3) Å3 | Plate, dark orange |
Z = 4 | 0.20 × 0.20 × 0.02 mm |
Nonius KappaCCD diffractometer | 5652 independent reflections |
Radiation source: fine-focus sealed tube | 3558 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.109 |
Detector resolution: 9 pixels mm-1 | θmax = 25.0°, θmin = 2.7° |
φ scans and ω scans with κ offsets | h = −11→11 |
Absorption correction: multi-scan (DENZO-SMN; Otwinowski & Minor, 1997) | k = −12→12 |
Tmin = 0.717, Tmax = 0.965 | l = −37→36 |
12795 measured reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.064 | H-atom parameters constrained |
wR(F2) = 0.128 | w = 1/[σ2(Fo2) + (0.0371P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.01 | (Δ/σ)max = 0.001 |
5652 reflections | Δρmax = 0.84 e Å−3 |
397 parameters | Δρmin = −0.54 e Å−3 |
0 restraints | Absolute structure: (Flack, 1983), 2319 Friedel pairs |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: 0.03 (3) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Ru1 | 0.76741 (8) | 0.48626 (7) | 0.34656 (2) | 0.0406 (2) | |
Cl1 | 0.7378 (3) | 0.4406 (2) | 0.27306 (6) | 0.0507 (7) | |
Cl2 | 0.9653 (3) | 0.6236 (2) | 0.32940 (7) | 0.0482 (7) | |
Cl3 | 0.6065 (3) | 0.6703 (2) | 0.33936 (8) | 0.0490 (7) | |
Cl4 | 0.6548 (3) | 0.4860 (3) | 0.45106 (7) | 0.0643 (8) | |
Si1 | 0.8154 (3) | 0.5437 (3) | 0.41222 (8) | 0.0445 (8) | |
O1 | 0.5304 (8) | 0.3205 (8) | 0.3724 (2) | 0.067 (3) | |
O2 | 0.9436 (8) | 0.2481 (7) | 0.3578 (2) | 0.065 (2) | |
C1 | 0.6202 (13) | 0.3830 (12) | 0.3629 (3) | 0.053 (3) | |
C2 | 0.8796 (11) | 0.3401 (11) | 0.3527 (3) | 0.045 (3) | |
C3 | 0.9706 (12) | 0.4584 (10) | 0.4331 (3) | 0.053 (3) | |
C4 | 0.9636 (15) | 0.3622 (11) | 0.4626 (3) | 0.071 (4) | |
H4A | 0.8769 | 0.3409 | 0.4737 | 0.085* | |
C5 | 1.0822 (17) | 0.2964 (12) | 0.4764 (4) | 0.078 (4) | |
H5A | 1.0754 | 0.2312 | 0.4962 | 0.093* | |
C6 | 1.2088 (18) | 0.3294 (12) | 0.4602 (4) | 0.082 (5) | |
H6A | 1.2897 | 0.2878 | 0.4696 | 0.098* | |
C7 | 1.2183 (13) | 0.4227 (11) | 0.4305 (3) | 0.067 (3) | |
H7A | 1.3048 | 0.4443 | 0.4195 | 0.080* | |
C8 | 1.0989 (12) | 0.4843 (11) | 0.4172 (3) | 0.060 (3) | |
H8A | 1.1058 | 0.5459 | 0.3964 | 0.072* | |
C9 | 0.8385 (10) | 0.7215 (9) | 0.4271 (3) | 0.041 (3) | |
C10 | 0.8681 (14) | 0.7513 (11) | 0.4654 (3) | 0.072 (4) | |
H10A | 0.8818 | 0.6814 | 0.4833 | 0.086* | |
C11 | 0.8784 (16) | 0.8725 (12) | 0.4786 (3) | 0.085 (5) | |
H11A | 0.8936 | 0.8878 | 0.5058 | 0.102* | |
C12 | 0.8668 (12) | 0.9786 (11) | 0.4528 (4) | 0.071 (4) | |
H12A | 0.8770 | 1.0655 | 0.4621 | 0.085* | |
C13 | 0.8411 (11) | 0.9562 (10) | 0.4143 (3) | 0.056 (3) | |
H13A | 0.8302 | 1.0269 | 0.3966 | 0.067* | |
C14 | 0.8308 (10) | 0.8255 (11) | 0.4012 (3) | 0.048 (3) | |
H14A | 0.8183 | 0.8087 | 0.3740 | 0.058* | |
Co1 | 0.23943 (15) | 0.44754 (11) | 0.24875 (4) | 0.0417 (4) | |
C15 | 0.3981 (16) | 0.3249 (14) | 0.2643 (3) | 0.076 (4) | |
H15A | 0.4816 | 0.3051 | 0.2484 | 0.091* | |
C16 | 0.3816 (14) | 0.4297 (12) | 0.2907 (3) | 0.065 (3) | |
H16A | 0.4530 | 0.4961 | 0.2975 | 0.078* | |
C17 | 0.2514 (15) | 0.4211 (11) | 0.3070 (3) | 0.062 (3) | |
H17A | 0.2126 | 0.4805 | 0.3275 | 0.074* | |
C18 | 0.1854 (14) | 0.3182 (14) | 0.2901 (4) | 0.074 (4) | |
H18A | 0.0892 | 0.2906 | 0.2960 | 0.089* | |
C19 | 0.2716 (17) | 0.2578 (11) | 0.2630 (3) | 0.065 (4) | |
H19A | 0.2494 | 0.1798 | 0.2464 | 0.079* | |
C20 | 0.2555 (11) | 0.4925 (9) | 0.1914 (3) | 0.049 (3) | |
H20A | 0.3223 | 0.4541 | 0.1723 | 0.059* | |
C21 | 0.2756 (13) | 0.6051 (10) | 0.2143 (3) | 0.054 (3) | |
H21A | 0.3604 | 0.6601 | 0.2147 | 0.065* | |
C22 | 0.1573 (12) | 0.6259 (10) | 0.2372 (3) | 0.049 (3) | |
H22A | 0.1433 | 0.6982 | 0.2565 | 0.058* | |
C23 | 0.0628 (11) | 0.5258 (10) | 0.2282 (3) | 0.049 (3) | |
H23A | −0.0307 | 0.5146 | 0.2398 | 0.058* | |
C24 | 0.1243 (11) | 0.4445 (11) | 0.1999 (3) | 0.053 (3) | |
H24A | 0.0816 | 0.3649 | 0.1881 | 0.063* | |
Co2 | 0.68687 (14) | 0.43589 (13) | 0.11062 (4) | 0.0463 (4) | |
C25 | 0.639 (2) | 0.2732 (14) | 0.0810 (4) | 0.090 (5) | |
H25A | 0.6280 | 0.1837 | 0.0925 | 0.108* | |
C26 | 0.7599 (16) | 0.3266 (14) | 0.0659 (3) | 0.080 (4) | |
H26A | 0.8516 | 0.2830 | 0.0645 | 0.096* | |
C27 | 0.7272 (17) | 0.4549 (14) | 0.0524 (3) | 0.074 (4) | |
H27A | 0.7918 | 0.5187 | 0.0401 | 0.088* | |
C28 | 0.5907 (17) | 0.4742 (15) | 0.0597 (4) | 0.080 (4) | |
H28A | 0.5399 | 0.5569 | 0.0539 | 0.096* | |
C29 | 0.5339 (15) | 0.3665 (19) | 0.0766 (4) | 0.084 (5) | |
H29A | 0.4357 | 0.3558 | 0.0845 | 0.101* | |
C30 | 0.7802 (16) | 0.3932 (13) | 0.1612 (3) | 0.078 (4) | |
H30A | 0.8282 | 0.3096 | 0.1677 | 0.094* | |
C31 | 0.8419 (12) | 0.5088 (15) | 0.1435 (3) | 0.070 (4) | |
H31A | 0.9398 | 0.5194 | 0.1353 | 0.083* | |
C32 | 0.7377 (17) | 0.6016 (12) | 0.1401 (3) | 0.077 (4) | |
H32A | 0.7462 | 0.6915 | 0.1288 | 0.092* | |
C33 | 0.6194 (14) | 0.5451 (14) | 0.1561 (4) | 0.077 (4) | |
H33A | 0.5278 | 0.5889 | 0.1571 | 0.093* | |
C34 | 0.6436 (13) | 0.4221 (14) | 0.1683 (3) | 0.065 (4) | |
H34A | 0.5748 | 0.3619 | 0.1804 | 0.078* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ru1 | 0.0454 (5) | 0.0299 (4) | 0.0465 (5) | 0.0018 (4) | 0.0005 (4) | 0.0016 (4) |
Cl1 | 0.0658 (19) | 0.0370 (14) | 0.0494 (15) | 0.0010 (17) | 0.0028 (14) | −0.0035 (11) |
Cl2 | 0.0481 (17) | 0.0347 (15) | 0.0618 (18) | −0.0030 (13) | 0.0038 (14) | 0.0021 (13) |
Cl3 | 0.0521 (17) | 0.0340 (15) | 0.0609 (19) | 0.0088 (13) | −0.0033 (15) | −0.0015 (14) |
Cl4 | 0.078 (2) | 0.062 (2) | 0.0526 (17) | −0.0130 (18) | 0.0139 (15) | 0.0029 (15) |
Si1 | 0.0557 (19) | 0.0346 (18) | 0.0432 (18) | −0.0024 (16) | −0.0025 (14) | 0.0023 (13) |
O1 | 0.059 (6) | 0.056 (6) | 0.086 (6) | −0.019 (5) | −0.006 (5) | −0.002 (4) |
O2 | 0.067 (6) | 0.040 (5) | 0.087 (6) | 0.021 (4) | 0.000 (5) | 0.004 (4) |
C1 | 0.052 (8) | 0.052 (8) | 0.056 (8) | 0.010 (7) | −0.016 (6) | −0.011 (6) |
C2 | 0.050 (7) | 0.044 (8) | 0.040 (6) | −0.017 (6) | 0.009 (5) | −0.003 (6) |
C3 | 0.060 (8) | 0.034 (7) | 0.065 (8) | 0.011 (6) | −0.013 (6) | 0.001 (6) |
C4 | 0.102 (11) | 0.040 (8) | 0.069 (9) | 0.015 (8) | −0.013 (8) | 0.000 (7) |
C5 | 0.115 (13) | 0.050 (9) | 0.068 (10) | 0.007 (10) | −0.007 (9) | 0.019 (7) |
C6 | 0.124 (14) | 0.046 (8) | 0.076 (10) | 0.022 (9) | −0.052 (10) | −0.005 (7) |
C7 | 0.057 (9) | 0.061 (8) | 0.082 (9) | −0.001 (8) | −0.016 (7) | −0.004 (7) |
C8 | 0.047 (7) | 0.054 (8) | 0.080 (8) | 0.011 (7) | −0.014 (6) | 0.011 (7) |
C9 | 0.048 (7) | 0.036 (7) | 0.040 (7) | −0.006 (5) | 0.008 (5) | 0.001 (5) |
C10 | 0.139 (13) | 0.031 (7) | 0.044 (7) | 0.002 (7) | −0.013 (8) | 0.007 (6) |
C11 | 0.166 (15) | 0.037 (8) | 0.051 (8) | −0.023 (9) | −0.014 (8) | −0.006 (6) |
C12 | 0.104 (10) | 0.038 (7) | 0.069 (9) | −0.005 (7) | 0.014 (7) | −0.016 (7) |
C13 | 0.076 (8) | 0.036 (7) | 0.056 (8) | −0.002 (6) | 0.007 (6) | −0.012 (6) |
C14 | 0.048 (7) | 0.061 (8) | 0.037 (6) | 0.007 (6) | 0.002 (5) | 0.001 (6) |
Co1 | 0.0433 (9) | 0.0321 (7) | 0.0498 (8) | −0.0007 (8) | −0.0021 (8) | −0.0014 (6) |
C15 | 0.088 (11) | 0.077 (10) | 0.063 (9) | 0.052 (9) | 0.011 (8) | 0.002 (8) |
C16 | 0.066 (9) | 0.057 (9) | 0.071 (9) | 0.001 (7) | −0.034 (7) | −0.003 (7) |
C17 | 0.067 (9) | 0.061 (8) | 0.056 (7) | 0.023 (9) | 0.000 (7) | 0.005 (6) |
C18 | 0.059 (9) | 0.079 (10) | 0.084 (10) | −0.027 (8) | −0.008 (8) | 0.025 (8) |
C19 | 0.098 (12) | 0.040 (7) | 0.059 (8) | −0.003 (9) | −0.007 (8) | 0.008 (6) |
C20 | 0.053 (7) | 0.040 (6) | 0.055 (6) | 0.014 (7) | 0.005 (6) | −0.001 (5) |
C21 | 0.073 (9) | 0.042 (7) | 0.047 (7) | −0.004 (7) | 0.014 (7) | 0.007 (5) |
C22 | 0.070 (9) | 0.023 (6) | 0.053 (7) | 0.001 (6) | 0.002 (6) | 0.004 (5) |
C23 | 0.047 (7) | 0.039 (7) | 0.060 (7) | 0.007 (6) | 0.003 (5) | 0.007 (6) |
C24 | 0.055 (8) | 0.053 (8) | 0.051 (7) | 0.003 (6) | −0.010 (6) | −0.007 (6) |
Co2 | 0.0467 (9) | 0.0427 (9) | 0.0496 (9) | −0.0025 (7) | 0.0008 (7) | 0.0001 (7) |
C25 | 0.135 (15) | 0.061 (10) | 0.076 (10) | −0.036 (11) | 0.014 (10) | −0.030 (8) |
C26 | 0.085 (11) | 0.067 (9) | 0.087 (9) | −0.001 (10) | 0.024 (9) | −0.022 (7) |
C27 | 0.084 (11) | 0.088 (11) | 0.049 (7) | −0.049 (10) | −0.017 (7) | 0.000 (6) |
C28 | 0.084 (11) | 0.084 (12) | 0.071 (9) | −0.016 (10) | −0.044 (8) | 0.010 (8) |
C29 | 0.066 (10) | 0.135 (15) | 0.052 (9) | −0.026 (12) | −0.007 (7) | −0.027 (10) |
C30 | 0.105 (12) | 0.063 (9) | 0.068 (9) | 0.028 (9) | −0.023 (9) | 0.008 (7) |
C31 | 0.046 (7) | 0.098 (12) | 0.065 (8) | 0.003 (9) | −0.014 (6) | 0.007 (8) |
C32 | 0.109 (12) | 0.048 (7) | 0.074 (8) | −0.021 (10) | −0.005 (10) | 0.005 (6) |
C33 | 0.079 (10) | 0.064 (9) | 0.089 (10) | −0.007 (8) | 0.008 (8) | 0.003 (9) |
C34 | 0.069 (10) | 0.059 (9) | 0.066 (9) | −0.023 (8) | 0.007 (7) | 0.010 (7) |
Ru1—C2 | 1.864 (12) | C16—H16A | 1.0000 |
Ru1—C1 | 1.867 (14) | C17—C18 | 1.362 (15) |
Ru1—Si1 | 2.362 (3) | C17—H17A | 1.0000 |
Ru1—Cl2 | 2.456 (3) | C18—C19 | 1.395 (16) |
Ru1—Cl3 | 2.462 (3) | C18—H18A | 1.0000 |
Ru1—Cl1 | 2.566 (2) | C19—H19A | 1.0000 |
Cl4—Si1 | 2.134 (4) | C20—C24 | 1.400 (13) |
Si1—C3 | 1.886 (11) | C20—C21 | 1.405 (12) |
Si1—C9 | 1.901 (10) | C20—H20A | 1.0000 |
O1—C1 | 1.131 (12) | C21—C22 | 1.408 (14) |
O2—C2 | 1.143 (11) | C21—H21A | 1.0000 |
C3—C8 | 1.389 (14) | C22—C23 | 1.411 (13) |
C3—C4 | 1.409 (13) | C22—H22A | 1.0000 |
C4—C5 | 1.417 (16) | C23—C24 | 1.408 (13) |
C4—H4A | 0.9500 | C23—H23A | 1.0000 |
C5—C6 | 1.393 (18) | C24—H24A | 1.0000 |
C5—H5A | 0.9500 | Co2—C30 | 1.997 (11) |
C6—C7 | 1.395 (15) | Co2—C25 | 2.002 (12) |
C6—H6A | 0.9500 | Co2—C28 | 2.011 (11) |
C7—C8 | 1.399 (14) | Co2—C34 | 2.017 (11) |
C7—H7A | 0.9500 | Co2—C29 | 2.017 (12) |
C8—H8A | 0.9500 | Co2—C26 | 2.021 (11) |
C9—C10 | 1.373 (13) | Co2—C33 | 2.021 (13) |
C9—C14 | 1.384 (12) | Co2—C31 | 2.024 (11) |
C10—C11 | 1.323 (14) | Co2—C27 | 2.032 (11) |
C10—H10A | 0.9500 | Co2—C32 | 2.032 (11) |
C11—C12 | 1.403 (15) | C25—C26 | 1.402 (18) |
C11—H11A | 0.9500 | C25—C29 | 1.405 (19) |
C12—C13 | 1.353 (13) | C25—H25A | 1.0000 |
C12—H12A | 0.9500 | C26—C27 | 1.425 (16) |
C13—C14 | 1.413 (13) | C26—H26A | 1.0000 |
C13—H13A | 0.9500 | C27—C28 | 1.367 (18) |
C14—H14A | 0.9500 | C27—H27A | 1.0000 |
Co1—C16 | 2.001 (11) | C28—C29 | 1.361 (17) |
Co1—C18 | 2.004 (12) | C28—H28A | 1.0000 |
Co1—C24 | 2.007 (10) | C29—H29A | 1.0000 |
Co1—C17 | 2.009 (10) | C30—C34 | 1.386 (16) |
Co1—C20 | 2.015 (9) | C30—C31 | 1.456 (16) |
Co1—C23 | 2.024 (10) | C30—H30A | 1.0000 |
Co1—C21 | 2.025 (10) | C31—C32 | 1.395 (15) |
Co1—C19 | 2.025 (11) | C31—H31A | 1.0000 |
Co1—C22 | 2.031 (10) | C32—C33 | 1.400 (16) |
Co1—C15 | 2.061 (12) | C32—H32A | 1.0000 |
C15—C16 | 1.409 (15) | C33—C34 | 1.346 (16) |
C15—C19 | 1.411 (17) | C33—H33A | 1.0000 |
C15—H15A | 1.0000 | C34—H34A | 1.0000 |
C16—C17 | 1.389 (15) | ||
C2—Ru1—C1 | 87.9 (4) | C24—C20—Co1 | 69.3 (6) |
C2—Ru1—Si1 | 88.7 (3) | C21—C20—Co1 | 70.0 (5) |
C1—Ru1—Si1 | 90.5 (3) | C24—C20—H20A | 126.3 |
C2—Ru1—Cl2 | 91.4 (3) | C21—C20—H20A | 126.3 |
C1—Ru1—Cl2 | 176.4 (3) | Co1—C20—H20A | 126.3 |
Si1—Ru1—Cl2 | 85.88 (10) | C20—C21—C22 | 108.5 (10) |
C2—Ru1—Cl3 | 176.4 (3) | C20—C21—Co1 | 69.3 (5) |
C1—Ru1—Cl3 | 88.4 (4) | C22—C21—Co1 | 69.9 (6) |
Si1—Ru1—Cl3 | 91.75 (10) | C20—C21—H21A | 125.7 |
Cl2—Ru1—Cl3 | 92.24 (9) | C22—C21—H21A | 125.7 |
C2—Ru1—Cl1 | 91.7 (3) | Co1—C21—H21A | 125.7 |
C1—Ru1—Cl1 | 95.9 (3) | C21—C22—C23 | 107.8 (9) |
Si1—Ru1—Cl1 | 173.57 (10) | C21—C22—Co1 | 69.4 (6) |
Cl2—Ru1—Cl1 | 87.69 (8) | C23—C22—Co1 | 69.4 (5) |
Cl3—Ru1—Cl1 | 88.29 (9) | C21—C22—H22A | 126.1 |
C3—Si1—C9 | 104.3 (5) | C23—C22—H22A | 126.1 |
C3—Si1—Cl4 | 103.1 (4) | Co1—C22—H22A | 126.1 |
C9—Si1—Cl4 | 100.7 (3) | C24—C23—C22 | 107.4 (9) |
C3—Si1—Ru1 | 113.7 (3) | C24—C23—Co1 | 68.9 (6) |
C9—Si1—Ru1 | 120.9 (3) | C22—C23—Co1 | 69.9 (6) |
Cl4—Si1—Ru1 | 111.99 (15) | C24—C23—H23A | 126.3 |
O1—C1—Ru1 | 179.2 (10) | C22—C23—H23A | 126.3 |
O2—C2—Ru1 | 176.5 (10) | Co1—C23—H23A | 126.3 |
C8—C3—C4 | 117.2 (11) | C20—C24—C23 | 108.9 (10) |
C8—C3—Si1 | 119.1 (8) | C20—C24—Co1 | 69.9 (6) |
C4—C3—Si1 | 123.6 (10) | C23—C24—Co1 | 70.2 (6) |
C3—C4—C5 | 121.9 (13) | C20—C24—H24A | 125.5 |
C3—C4—H4A | 119.1 | C23—C24—H24A | 125.5 |
C5—C4—H4A | 119.1 | Co1—C24—H24A | 125.5 |
C6—C5—C4 | 118.5 (12) | C30—Co2—C25 | 111.1 (6) |
C6—C5—H5A | 120.8 | C30—Co2—C28 | 178.5 (6) |
C4—C5—H5A | 120.8 | C25—Co2—C28 | 67.5 (6) |
C5—C6—C7 | 120.7 (13) | C30—Co2—C34 | 40.4 (5) |
C5—C6—H6A | 119.6 | C25—Co2—C34 | 112.6 (6) |
C7—C6—H6A | 119.6 | C28—Co2—C34 | 139.3 (7) |
C6—C7—C8 | 119.3 (13) | C30—Co2—C29 | 139.1 (7) |
C6—C7—H7A | 120.3 | C25—Co2—C29 | 40.9 (5) |
C8—C7—H7A | 120.3 | C28—Co2—C29 | 39.5 (5) |
C3—C8—C7 | 122.3 (11) | C34—Co2—C29 | 112.4 (5) |
C3—C8—H8A | 118.8 | C30—Co2—C26 | 111.7 (6) |
C7—C8—H8A | 118.8 | C25—Co2—C26 | 40.8 (5) |
C10—C9—C14 | 116.6 (9) | C28—Co2—C26 | 67.7 (6) |
C10—C9—Si1 | 119.4 (8) | C34—Co2—C26 | 140.5 (6) |
C14—C9—Si1 | 124.0 (8) | C29—Co2—C26 | 68.4 (6) |
C11—C10—C9 | 123.3 (10) | C30—Co2—C33 | 66.8 (5) |
C11—C10—H10A | 118.4 | C25—Co2—C33 | 140.3 (6) |
C9—C10—H10A | 118.4 | C28—Co2—C33 | 113.8 (6) |
C10—C11—C12 | 120.3 (11) | C34—Co2—C33 | 38.9 (5) |
C10—C11—H11A | 119.9 | C29—Co2—C33 | 113.3 (6) |
C12—C11—H11A | 119.9 | C26—Co2—C33 | 178.3 (6) |
C13—C12—C11 | 119.5 (10) | C30—Co2—C31 | 42.5 (5) |
C13—C12—H12A | 120.2 | C25—Co2—C31 | 139.5 (7) |
C11—C12—H12A | 120.2 | C28—Co2—C31 | 139.0 (6) |
C12—C13—C14 | 118.7 (10) | C34—Co2—C31 | 69.0 (5) |
C12—C13—H13A | 120.6 | C29—Co2—C31 | 178.4 (6) |
C14—C13—H13A | 120.6 | C26—Co2—C31 | 111.0 (6) |
C9—C14—C13 | 121.4 (10) | C33—Co2—C31 | 67.3 (5) |
C9—C14—H14A | 119.3 | C30—Co2—C27 | 140.8 (6) |
C13—C14—H14A | 119.3 | C25—Co2—C27 | 68.5 (5) |
C16—Co1—C18 | 67.6 (5) | C28—Co2—C27 | 39.5 (5) |
C16—Co1—C24 | 168.2 (5) | C34—Co2—C27 | 178.3 (7) |
C18—Co1—C24 | 115.2 (5) | C29—Co2—C27 | 67.4 (5) |
C16—Co1—C17 | 40.5 (4) | C26—Co2—C27 | 41.2 (5) |
C18—Co1—C17 | 39.7 (4) | C33—Co2—C27 | 139.4 (6) |
C24—Co1—C17 | 148.3 (5) | C31—Co2—C27 | 111.2 (5) |
C16—Co1—C20 | 131.4 (5) | C30—Co2—C32 | 69.2 (5) |
C18—Co1—C20 | 148.6 (5) | C25—Co2—C32 | 179.3 (6) |
C24—Co1—C20 | 40.8 (4) | C28—Co2—C32 | 112.2 (6) |
C17—Co1—C20 | 170.5 (5) | C34—Co2—C32 | 68.1 (5) |
C16—Co1—C23 | 150.8 (5) | C29—Co2—C32 | 139.3 (7) |
C18—Co1—C23 | 106.3 (5) | C26—Co2—C32 | 138.5 (6) |
C24—Co1—C23 | 40.9 (4) | C33—Co2—C32 | 40.4 (4) |
C17—Co1—C23 | 116.4 (5) | C31—Co2—C32 | 40.2 (5) |
C20—Co1—C23 | 68.9 (4) | C27—Co2—C32 | 110.9 (5) |
C16—Co1—C21 | 111.5 (5) | C26—C25—C29 | 107.9 (13) |
C18—Co1—C21 | 168.3 (6) | C26—C25—Co2 | 70.3 (7) |
C24—Co1—C21 | 68.2 (4) | C29—C25—Co2 | 70.1 (7) |
C17—Co1—C21 | 132.1 (5) | C26—C25—H25A | 126.0 |
C20—Co1—C21 | 40.7 (4) | C29—C25—H25A | 126.0 |
C23—Co1—C21 | 68.5 (4) | Co2—C25—H25A | 126.0 |
C16—Co1—C19 | 68.5 (5) | C25—C26—C27 | 106.8 (14) |
C18—Co1—C19 | 40.5 (5) | C25—C26—Co2 | 68.9 (7) |
C24—Co1—C19 | 105.7 (5) | C27—C26—Co2 | 69.8 (7) |
C17—Co1—C19 | 68.0 (4) | C25—C26—H26A | 126.6 |
C20—Co1—C19 | 116.0 (4) | C27—C26—H26A | 126.6 |
C23—Co1—C19 | 126.4 (5) | Co2—C26—H26A | 126.6 |
C21—Co1—C19 | 151.0 (5) | C28—C27—C26 | 107.0 (13) |
C16—Co1—C22 | 119.6 (5) | C28—C27—Co2 | 69.4 (7) |
C18—Co1—C22 | 128.8 (5) | C26—C27—Co2 | 69.0 (7) |
C24—Co1—C22 | 68.4 (4) | C28—C27—H27A | 126.5 |
C17—Co1—C22 | 109.6 (4) | C26—C27—H27A | 126.5 |
C20—Co1—C22 | 68.7 (4) | Co2—C27—H27A | 126.5 |
C23—Co1—C22 | 40.7 (4) | C29—C28—C27 | 110.8 (14) |
C21—Co1—C22 | 40.6 (4) | C29—C28—Co2 | 70.5 (7) |
C19—Co1—C22 | 165.6 (6) | C27—C28—Co2 | 71.1 (7) |
C16—Co1—C15 | 40.6 (4) | C29—C28—H28A | 124.6 |
C18—Co1—C15 | 67.3 (5) | C27—C28—H28A | 124.6 |
C24—Co1—C15 | 128.6 (5) | Co2—C28—H28A | 124.6 |
C17—Co1—C15 | 67.7 (4) | C28—C29—C25 | 107.5 (13) |
C20—Co1—C15 | 109.3 (4) | C28—C29—Co2 | 70.0 (7) |
C23—Co1—C15 | 165.5 (6) | C25—C29—Co2 | 69.0 (8) |
C21—Co1—C15 | 120.2 (5) | C28—C29—H29A | 126.3 |
C19—Co1—C15 | 40.4 (5) | C25—C29—H29A | 126.3 |
C22—Co1—C15 | 153.2 (6) | Co2—C29—H29A | 126.3 |
C16—C15—C19 | 107.0 (11) | C34—C30—C31 | 107.2 (11) |
C16—C15—Co1 | 67.4 (7) | C34—C30—Co2 | 70.6 (7) |
C19—C15—Co1 | 68.4 (7) | C31—C30—Co2 | 69.8 (6) |
C16—C15—H15A | 126.5 | C34—C30—H30A | 126.4 |
C19—C15—H15A | 126.5 | C31—C30—H30A | 126.4 |
Co1—C15—H15A | 126.5 | Co2—C30—H30A | 126.4 |
C17—C16—C15 | 108.2 (12) | C32—C31—C30 | 106.6 (10) |
C17—C16—Co1 | 70.1 (6) | C32—C31—Co2 | 70.2 (6) |
C15—C16—Co1 | 72.0 (7) | C30—C31—Co2 | 67.8 (7) |
C17—C16—H16A | 125.9 | C32—C31—H31A | 126.7 |
C15—C16—H16A | 125.9 | C30—C31—H31A | 126.7 |
Co1—C16—H16A | 125.9 | Co2—C31—H31A | 126.7 |
C18—C17—C16 | 108.1 (11) | C31—C32—C33 | 106.6 (11) |
C18—C17—Co1 | 70.0 (7) | C31—C32—Co2 | 69.6 (7) |
C16—C17—Co1 | 69.4 (6) | C33—C32—Co2 | 69.4 (7) |
C18—C17—H17A | 126.0 | C31—C32—H32A | 126.7 |
C16—C17—H17A | 126.0 | C33—C32—H32A | 126.7 |
Co1—C17—H17A | 126.0 | Co2—C32—H32A | 126.7 |
C17—C18—C19 | 109.8 (12) | C34—C33—C32 | 111.2 (13) |
C17—C18—Co1 | 70.3 (7) | C34—C33—Co2 | 70.3 (8) |
C19—C18—Co1 | 70.6 (7) | C32—C33—Co2 | 70.2 (7) |
C17—C18—H18A | 125.1 | C34—C33—H33A | 124.3 |
C19—C18—H18A | 125.1 | C32—C33—H33A | 124.3 |
Co1—C18—H18A | 125.1 | Co2—C33—H33A | 124.3 |
C18—C19—C15 | 106.8 (11) | C33—C34—C30 | 108.3 (12) |
C18—C19—Co1 | 69.0 (7) | C33—C34—Co2 | 70.7 (8) |
C15—C19—Co1 | 71.2 (7) | C30—C34—Co2 | 69.0 (7) |
C18—C19—H19A | 126.6 | C33—C34—H34A | 125.9 |
C15—C19—H19A | 126.6 | C30—C34—H34A | 125.9 |
Co1—C19—H19A | 126.6 | Co2—C34—H34A | 125.9 |
C24—C20—C21 | 107.4 (10) | ||
C1—Ru1—Si1—Cl4 | −11.3 (4) |
Subscribe to Acta Crystallographica Section E: Crystallographic Communications
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- If you have already subscribed, you may need to register