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The asymmetric unit of the title compound, [Co(C5H5)2]2[RuCl3(C12H10ClSi)(CO)2], consists of a discrete ClPh2SiRu(CO)2Cl3 dianion and two (η-C5H5)2Co cations. The dianion has octahedral coordination geometry, with the three Cl atoms in cis positions. In addition, two carbonyl groups (cis) and a Ph2ClSi group (bonded through Si) complete the coordination. The Ru—Si bond length is 2.362 (3) Å and the longest Ru—Cl bond [2.566 (2) Å] is trans to the Si atom. In one cobaltocene cation, the cyclo­penta­dienyl (Cp) rings are staggered, while in the other, the Cp rings are almost eclipsed.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802019153/na6174sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536802019153/na6174Isup2.hkl
Contains datablock I

CCDC reference: 200741

Key indicators

  • Single-crystal X-ray study
  • T = 150 K
  • Mean [sigma](C-C) = 0.018 Å
  • R factor = 0.064
  • wR factor = 0.127
  • Data-to-parameter ratio = 14.2

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


Yellow Alert Alert Level C:
RINTA_01 Alert C The value of Rint is greater than 0.10 Rint given 0.109 General Notes
REFLT_03 From the CIF: _diffrn_reflns_theta_max 25.00 From the CIF: _reflns_number_total 5652 From the CIF: _diffrn_reflns_limit_ max hkl 11. 12. 36. From the CIF: _diffrn_reflns_limit_ min hkl -11. -12. -37. TEST1: Expected hkl limits for theta max Calculated maximum hkl 11. 12. 40. Calculated minimum hkl -11. -12. -40. ALERT: Expected hkl max differ from CIF values REFLT_03 From the CIF: _diffrn_reflns_theta_max 25.00 From the CIF: _reflns_number_total 5652 Count of symmetry unique reflns 3412 Completeness (_total/calc) 165.65% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 2240 Fraction of Friedel pairs measured 0.657 Are heavy atom types Z>Si present yes Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF.
0 Alert Level A = Potentially serious problem
0 Alert Level B = Potential problem
1 Alert Level C = Please check

Computing details top

Data collection: COLLECT (Nonius, 1997-2001); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXTL (Sheldrick, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

dicarbonyltrichloro(chlorodiphenylsilyl)ruthenium(II) bis[di-η5-cyclopentadienylcobalt(I)] top
Crystal data top
[Co(C5H5)2]2[RuCl3(C12H10ClSi)(CO)2]F(000) = 1720
Mr = 859.40Dx = 1.679 Mg m3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2abCell parameters from 3060 reflections
a = 9.7462 (5) Åθ = 2.6–25.0°
b = 10.2277 (6) ŵ = 1.78 mm1
c = 34.099 (2) ÅT = 150 K
V = 3399.0 (3) Å3Plate, dark orange
Z = 40.20 × 0.20 × 0.02 mm
Data collection top
Nonius KappaCCD
diffractometer
5652 independent reflections
Radiation source: fine-focus sealed tube3558 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.109
Detector resolution: 9 pixels mm-1θmax = 25.0°, θmin = 2.7°
φ scans and ω scans with κ offsetsh = 1111
Absorption correction: multi-scan
(DENZO-SMN; Otwinowski & Minor, 1997)
k = 1212
Tmin = 0.717, Tmax = 0.965l = 3736
12795 measured reflections
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.064H-atom parameters constrained
wR(F2) = 0.128 w = 1/[σ2(Fo2) + (0.0371P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.01(Δ/σ)max = 0.001
5652 reflectionsΔρmax = 0.84 e Å3
397 parametersΔρmin = 0.54 e Å3
0 restraintsAbsolute structure: (Flack, 1983), 2319 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.03 (3)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru10.76741 (8)0.48626 (7)0.34656 (2)0.0406 (2)
Cl10.7378 (3)0.4406 (2)0.27306 (6)0.0507 (7)
Cl20.9653 (3)0.6236 (2)0.32940 (7)0.0482 (7)
Cl30.6065 (3)0.6703 (2)0.33936 (8)0.0490 (7)
Cl40.6548 (3)0.4860 (3)0.45106 (7)0.0643 (8)
Si10.8154 (3)0.5437 (3)0.41222 (8)0.0445 (8)
O10.5304 (8)0.3205 (8)0.3724 (2)0.067 (3)
O20.9436 (8)0.2481 (7)0.3578 (2)0.065 (2)
C10.6202 (13)0.3830 (12)0.3629 (3)0.053 (3)
C20.8796 (11)0.3401 (11)0.3527 (3)0.045 (3)
C30.9706 (12)0.4584 (10)0.4331 (3)0.053 (3)
C40.9636 (15)0.3622 (11)0.4626 (3)0.071 (4)
H4A0.87690.34090.47370.085*
C51.0822 (17)0.2964 (12)0.4764 (4)0.078 (4)
H5A1.07540.23120.49620.093*
C61.2088 (18)0.3294 (12)0.4602 (4)0.082 (5)
H6A1.28970.28780.46960.098*
C71.2183 (13)0.4227 (11)0.4305 (3)0.067 (3)
H7A1.30480.44430.41950.080*
C81.0989 (12)0.4843 (11)0.4172 (3)0.060 (3)
H8A1.10580.54590.39640.072*
C90.8385 (10)0.7215 (9)0.4271 (3)0.041 (3)
C100.8681 (14)0.7513 (11)0.4654 (3)0.072 (4)
H10A0.88180.68140.48330.086*
C110.8784 (16)0.8725 (12)0.4786 (3)0.085 (5)
H11A0.89360.88780.50580.102*
C120.8668 (12)0.9786 (11)0.4528 (4)0.071 (4)
H12A0.87701.06550.46210.085*
C130.8411 (11)0.9562 (10)0.4143 (3)0.056 (3)
H13A0.83021.02690.39660.067*
C140.8308 (10)0.8255 (11)0.4012 (3)0.048 (3)
H14A0.81830.80870.37400.058*
Co10.23943 (15)0.44754 (11)0.24875 (4)0.0417 (4)
C150.3981 (16)0.3249 (14)0.2643 (3)0.076 (4)
H15A0.48160.30510.24840.091*
C160.3816 (14)0.4297 (12)0.2907 (3)0.065 (3)
H16A0.45300.49610.29750.078*
C170.2514 (15)0.4211 (11)0.3070 (3)0.062 (3)
H17A0.21260.48050.32750.074*
C180.1854 (14)0.3182 (14)0.2901 (4)0.074 (4)
H18A0.08920.29060.29600.089*
C190.2716 (17)0.2578 (11)0.2630 (3)0.065 (4)
H19A0.24940.17980.24640.079*
C200.2555 (11)0.4925 (9)0.1914 (3)0.049 (3)
H20A0.32230.45410.17230.059*
C210.2756 (13)0.6051 (10)0.2143 (3)0.054 (3)
H21A0.36040.66010.21470.065*
C220.1573 (12)0.6259 (10)0.2372 (3)0.049 (3)
H22A0.14330.69820.25650.058*
C230.0628 (11)0.5258 (10)0.2282 (3)0.049 (3)
H23A0.03070.51460.23980.058*
C240.1243 (11)0.4445 (11)0.1999 (3)0.053 (3)
H24A0.08160.36490.18810.063*
Co20.68687 (14)0.43589 (13)0.11062 (4)0.0463 (4)
C250.639 (2)0.2732 (14)0.0810 (4)0.090 (5)
H25A0.62800.18370.09250.108*
C260.7599 (16)0.3266 (14)0.0659 (3)0.080 (4)
H26A0.85160.28300.06450.096*
C270.7272 (17)0.4549 (14)0.0524 (3)0.074 (4)
H27A0.79180.51870.04010.088*
C280.5907 (17)0.4742 (15)0.0597 (4)0.080 (4)
H28A0.53990.55690.05390.096*
C290.5339 (15)0.3665 (19)0.0766 (4)0.084 (5)
H29A0.43570.35580.08450.101*
C300.7802 (16)0.3932 (13)0.1612 (3)0.078 (4)
H30A0.82820.30960.16770.094*
C310.8419 (12)0.5088 (15)0.1435 (3)0.070 (4)
H31A0.93980.51940.13530.083*
C320.7377 (17)0.6016 (12)0.1401 (3)0.077 (4)
H32A0.74620.69150.12880.092*
C330.6194 (14)0.5451 (14)0.1561 (4)0.077 (4)
H33A0.52780.58890.15710.093*
C340.6436 (13)0.4221 (14)0.1683 (3)0.065 (4)
H34A0.57480.36190.18040.078*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0454 (5)0.0299 (4)0.0465 (5)0.0018 (4)0.0005 (4)0.0016 (4)
Cl10.0658 (19)0.0370 (14)0.0494 (15)0.0010 (17)0.0028 (14)0.0035 (11)
Cl20.0481 (17)0.0347 (15)0.0618 (18)0.0030 (13)0.0038 (14)0.0021 (13)
Cl30.0521 (17)0.0340 (15)0.0609 (19)0.0088 (13)0.0033 (15)0.0015 (14)
Cl40.078 (2)0.062 (2)0.0526 (17)0.0130 (18)0.0139 (15)0.0029 (15)
Si10.0557 (19)0.0346 (18)0.0432 (18)0.0024 (16)0.0025 (14)0.0023 (13)
O10.059 (6)0.056 (6)0.086 (6)0.019 (5)0.006 (5)0.002 (4)
O20.067 (6)0.040 (5)0.087 (6)0.021 (4)0.000 (5)0.004 (4)
C10.052 (8)0.052 (8)0.056 (8)0.010 (7)0.016 (6)0.011 (6)
C20.050 (7)0.044 (8)0.040 (6)0.017 (6)0.009 (5)0.003 (6)
C30.060 (8)0.034 (7)0.065 (8)0.011 (6)0.013 (6)0.001 (6)
C40.102 (11)0.040 (8)0.069 (9)0.015 (8)0.013 (8)0.000 (7)
C50.115 (13)0.050 (9)0.068 (10)0.007 (10)0.007 (9)0.019 (7)
C60.124 (14)0.046 (8)0.076 (10)0.022 (9)0.052 (10)0.005 (7)
C70.057 (9)0.061 (8)0.082 (9)0.001 (8)0.016 (7)0.004 (7)
C80.047 (7)0.054 (8)0.080 (8)0.011 (7)0.014 (6)0.011 (7)
C90.048 (7)0.036 (7)0.040 (7)0.006 (5)0.008 (5)0.001 (5)
C100.139 (13)0.031 (7)0.044 (7)0.002 (7)0.013 (8)0.007 (6)
C110.166 (15)0.037 (8)0.051 (8)0.023 (9)0.014 (8)0.006 (6)
C120.104 (10)0.038 (7)0.069 (9)0.005 (7)0.014 (7)0.016 (7)
C130.076 (8)0.036 (7)0.056 (8)0.002 (6)0.007 (6)0.012 (6)
C140.048 (7)0.061 (8)0.037 (6)0.007 (6)0.002 (5)0.001 (6)
Co10.0433 (9)0.0321 (7)0.0498 (8)0.0007 (8)0.0021 (8)0.0014 (6)
C150.088 (11)0.077 (10)0.063 (9)0.052 (9)0.011 (8)0.002 (8)
C160.066 (9)0.057 (9)0.071 (9)0.001 (7)0.034 (7)0.003 (7)
C170.067 (9)0.061 (8)0.056 (7)0.023 (9)0.000 (7)0.005 (6)
C180.059 (9)0.079 (10)0.084 (10)0.027 (8)0.008 (8)0.025 (8)
C190.098 (12)0.040 (7)0.059 (8)0.003 (9)0.007 (8)0.008 (6)
C200.053 (7)0.040 (6)0.055 (6)0.014 (7)0.005 (6)0.001 (5)
C210.073 (9)0.042 (7)0.047 (7)0.004 (7)0.014 (7)0.007 (5)
C220.070 (9)0.023 (6)0.053 (7)0.001 (6)0.002 (6)0.004 (5)
C230.047 (7)0.039 (7)0.060 (7)0.007 (6)0.003 (5)0.007 (6)
C240.055 (8)0.053 (8)0.051 (7)0.003 (6)0.010 (6)0.007 (6)
Co20.0467 (9)0.0427 (9)0.0496 (9)0.0025 (7)0.0008 (7)0.0001 (7)
C250.135 (15)0.061 (10)0.076 (10)0.036 (11)0.014 (10)0.030 (8)
C260.085 (11)0.067 (9)0.087 (9)0.001 (10)0.024 (9)0.022 (7)
C270.084 (11)0.088 (11)0.049 (7)0.049 (10)0.017 (7)0.000 (6)
C280.084 (11)0.084 (12)0.071 (9)0.016 (10)0.044 (8)0.010 (8)
C290.066 (10)0.135 (15)0.052 (9)0.026 (12)0.007 (7)0.027 (10)
C300.105 (12)0.063 (9)0.068 (9)0.028 (9)0.023 (9)0.008 (7)
C310.046 (7)0.098 (12)0.065 (8)0.003 (9)0.014 (6)0.007 (8)
C320.109 (12)0.048 (7)0.074 (8)0.021 (10)0.005 (10)0.005 (6)
C330.079 (10)0.064 (9)0.089 (10)0.007 (8)0.008 (8)0.003 (9)
C340.069 (10)0.059 (9)0.066 (9)0.023 (8)0.007 (7)0.010 (7)
Geometric parameters (Å, º) top
Ru1—C21.864 (12)C16—H16A1.0000
Ru1—C11.867 (14)C17—C181.362 (15)
Ru1—Si12.362 (3)C17—H17A1.0000
Ru1—Cl22.456 (3)C18—C191.395 (16)
Ru1—Cl32.462 (3)C18—H18A1.0000
Ru1—Cl12.566 (2)C19—H19A1.0000
Cl4—Si12.134 (4)C20—C241.400 (13)
Si1—C31.886 (11)C20—C211.405 (12)
Si1—C91.901 (10)C20—H20A1.0000
O1—C11.131 (12)C21—C221.408 (14)
O2—C21.143 (11)C21—H21A1.0000
C3—C81.389 (14)C22—C231.411 (13)
C3—C41.409 (13)C22—H22A1.0000
C4—C51.417 (16)C23—C241.408 (13)
C4—H4A0.9500C23—H23A1.0000
C5—C61.393 (18)C24—H24A1.0000
C5—H5A0.9500Co2—C301.997 (11)
C6—C71.395 (15)Co2—C252.002 (12)
C6—H6A0.9500Co2—C282.011 (11)
C7—C81.399 (14)Co2—C342.017 (11)
C7—H7A0.9500Co2—C292.017 (12)
C8—H8A0.9500Co2—C262.021 (11)
C9—C101.373 (13)Co2—C332.021 (13)
C9—C141.384 (12)Co2—C312.024 (11)
C10—C111.323 (14)Co2—C272.032 (11)
C10—H10A0.9500Co2—C322.032 (11)
C11—C121.403 (15)C25—C261.402 (18)
C11—H11A0.9500C25—C291.405 (19)
C12—C131.353 (13)C25—H25A1.0000
C12—H12A0.9500C26—C271.425 (16)
C13—C141.413 (13)C26—H26A1.0000
C13—H13A0.9500C27—C281.367 (18)
C14—H14A0.9500C27—H27A1.0000
Co1—C162.001 (11)C28—C291.361 (17)
Co1—C182.004 (12)C28—H28A1.0000
Co1—C242.007 (10)C29—H29A1.0000
Co1—C172.009 (10)C30—C341.386 (16)
Co1—C202.015 (9)C30—C311.456 (16)
Co1—C232.024 (10)C30—H30A1.0000
Co1—C212.025 (10)C31—C321.395 (15)
Co1—C192.025 (11)C31—H31A1.0000
Co1—C222.031 (10)C32—C331.400 (16)
Co1—C152.061 (12)C32—H32A1.0000
C15—C161.409 (15)C33—C341.346 (16)
C15—C191.411 (17)C33—H33A1.0000
C15—H15A1.0000C34—H34A1.0000
C16—C171.389 (15)
C2—Ru1—C187.9 (4)C24—C20—Co169.3 (6)
C2—Ru1—Si188.7 (3)C21—C20—Co170.0 (5)
C1—Ru1—Si190.5 (3)C24—C20—H20A126.3
C2—Ru1—Cl291.4 (3)C21—C20—H20A126.3
C1—Ru1—Cl2176.4 (3)Co1—C20—H20A126.3
Si1—Ru1—Cl285.88 (10)C20—C21—C22108.5 (10)
C2—Ru1—Cl3176.4 (3)C20—C21—Co169.3 (5)
C1—Ru1—Cl388.4 (4)C22—C21—Co169.9 (6)
Si1—Ru1—Cl391.75 (10)C20—C21—H21A125.7
Cl2—Ru1—Cl392.24 (9)C22—C21—H21A125.7
C2—Ru1—Cl191.7 (3)Co1—C21—H21A125.7
C1—Ru1—Cl195.9 (3)C21—C22—C23107.8 (9)
Si1—Ru1—Cl1173.57 (10)C21—C22—Co169.4 (6)
Cl2—Ru1—Cl187.69 (8)C23—C22—Co169.4 (5)
Cl3—Ru1—Cl188.29 (9)C21—C22—H22A126.1
C3—Si1—C9104.3 (5)C23—C22—H22A126.1
C3—Si1—Cl4103.1 (4)Co1—C22—H22A126.1
C9—Si1—Cl4100.7 (3)C24—C23—C22107.4 (9)
C3—Si1—Ru1113.7 (3)C24—C23—Co168.9 (6)
C9—Si1—Ru1120.9 (3)C22—C23—Co169.9 (6)
Cl4—Si1—Ru1111.99 (15)C24—C23—H23A126.3
O1—C1—Ru1179.2 (10)C22—C23—H23A126.3
O2—C2—Ru1176.5 (10)Co1—C23—H23A126.3
C8—C3—C4117.2 (11)C20—C24—C23108.9 (10)
C8—C3—Si1119.1 (8)C20—C24—Co169.9 (6)
C4—C3—Si1123.6 (10)C23—C24—Co170.2 (6)
C3—C4—C5121.9 (13)C20—C24—H24A125.5
C3—C4—H4A119.1C23—C24—H24A125.5
C5—C4—H4A119.1Co1—C24—H24A125.5
C6—C5—C4118.5 (12)C30—Co2—C25111.1 (6)
C6—C5—H5A120.8C30—Co2—C28178.5 (6)
C4—C5—H5A120.8C25—Co2—C2867.5 (6)
C5—C6—C7120.7 (13)C30—Co2—C3440.4 (5)
C5—C6—H6A119.6C25—Co2—C34112.6 (6)
C7—C6—H6A119.6C28—Co2—C34139.3 (7)
C6—C7—C8119.3 (13)C30—Co2—C29139.1 (7)
C6—C7—H7A120.3C25—Co2—C2940.9 (5)
C8—C7—H7A120.3C28—Co2—C2939.5 (5)
C3—C8—C7122.3 (11)C34—Co2—C29112.4 (5)
C3—C8—H8A118.8C30—Co2—C26111.7 (6)
C7—C8—H8A118.8C25—Co2—C2640.8 (5)
C10—C9—C14116.6 (9)C28—Co2—C2667.7 (6)
C10—C9—Si1119.4 (8)C34—Co2—C26140.5 (6)
C14—C9—Si1124.0 (8)C29—Co2—C2668.4 (6)
C11—C10—C9123.3 (10)C30—Co2—C3366.8 (5)
C11—C10—H10A118.4C25—Co2—C33140.3 (6)
C9—C10—H10A118.4C28—Co2—C33113.8 (6)
C10—C11—C12120.3 (11)C34—Co2—C3338.9 (5)
C10—C11—H11A119.9C29—Co2—C33113.3 (6)
C12—C11—H11A119.9C26—Co2—C33178.3 (6)
C13—C12—C11119.5 (10)C30—Co2—C3142.5 (5)
C13—C12—H12A120.2C25—Co2—C31139.5 (7)
C11—C12—H12A120.2C28—Co2—C31139.0 (6)
C12—C13—C14118.7 (10)C34—Co2—C3169.0 (5)
C12—C13—H13A120.6C29—Co2—C31178.4 (6)
C14—C13—H13A120.6C26—Co2—C31111.0 (6)
C9—C14—C13121.4 (10)C33—Co2—C3167.3 (5)
C9—C14—H14A119.3C30—Co2—C27140.8 (6)
C13—C14—H14A119.3C25—Co2—C2768.5 (5)
C16—Co1—C1867.6 (5)C28—Co2—C2739.5 (5)
C16—Co1—C24168.2 (5)C34—Co2—C27178.3 (7)
C18—Co1—C24115.2 (5)C29—Co2—C2767.4 (5)
C16—Co1—C1740.5 (4)C26—Co2—C2741.2 (5)
C18—Co1—C1739.7 (4)C33—Co2—C27139.4 (6)
C24—Co1—C17148.3 (5)C31—Co2—C27111.2 (5)
C16—Co1—C20131.4 (5)C30—Co2—C3269.2 (5)
C18—Co1—C20148.6 (5)C25—Co2—C32179.3 (6)
C24—Co1—C2040.8 (4)C28—Co2—C32112.2 (6)
C17—Co1—C20170.5 (5)C34—Co2—C3268.1 (5)
C16—Co1—C23150.8 (5)C29—Co2—C32139.3 (7)
C18—Co1—C23106.3 (5)C26—Co2—C32138.5 (6)
C24—Co1—C2340.9 (4)C33—Co2—C3240.4 (4)
C17—Co1—C23116.4 (5)C31—Co2—C3240.2 (5)
C20—Co1—C2368.9 (4)C27—Co2—C32110.9 (5)
C16—Co1—C21111.5 (5)C26—C25—C29107.9 (13)
C18—Co1—C21168.3 (6)C26—C25—Co270.3 (7)
C24—Co1—C2168.2 (4)C29—C25—Co270.1 (7)
C17—Co1—C21132.1 (5)C26—C25—H25A126.0
C20—Co1—C2140.7 (4)C29—C25—H25A126.0
C23—Co1—C2168.5 (4)Co2—C25—H25A126.0
C16—Co1—C1968.5 (5)C25—C26—C27106.8 (14)
C18—Co1—C1940.5 (5)C25—C26—Co268.9 (7)
C24—Co1—C19105.7 (5)C27—C26—Co269.8 (7)
C17—Co1—C1968.0 (4)C25—C26—H26A126.6
C20—Co1—C19116.0 (4)C27—C26—H26A126.6
C23—Co1—C19126.4 (5)Co2—C26—H26A126.6
C21—Co1—C19151.0 (5)C28—C27—C26107.0 (13)
C16—Co1—C22119.6 (5)C28—C27—Co269.4 (7)
C18—Co1—C22128.8 (5)C26—C27—Co269.0 (7)
C24—Co1—C2268.4 (4)C28—C27—H27A126.5
C17—Co1—C22109.6 (4)C26—C27—H27A126.5
C20—Co1—C2268.7 (4)Co2—C27—H27A126.5
C23—Co1—C2240.7 (4)C29—C28—C27110.8 (14)
C21—Co1—C2240.6 (4)C29—C28—Co270.5 (7)
C19—Co1—C22165.6 (6)C27—C28—Co271.1 (7)
C16—Co1—C1540.6 (4)C29—C28—H28A124.6
C18—Co1—C1567.3 (5)C27—C28—H28A124.6
C24—Co1—C15128.6 (5)Co2—C28—H28A124.6
C17—Co1—C1567.7 (4)C28—C29—C25107.5 (13)
C20—Co1—C15109.3 (4)C28—C29—Co270.0 (7)
C23—Co1—C15165.5 (6)C25—C29—Co269.0 (8)
C21—Co1—C15120.2 (5)C28—C29—H29A126.3
C19—Co1—C1540.4 (5)C25—C29—H29A126.3
C22—Co1—C15153.2 (6)Co2—C29—H29A126.3
C16—C15—C19107.0 (11)C34—C30—C31107.2 (11)
C16—C15—Co167.4 (7)C34—C30—Co270.6 (7)
C19—C15—Co168.4 (7)C31—C30—Co269.8 (6)
C16—C15—H15A126.5C34—C30—H30A126.4
C19—C15—H15A126.5C31—C30—H30A126.4
Co1—C15—H15A126.5Co2—C30—H30A126.4
C17—C16—C15108.2 (12)C32—C31—C30106.6 (10)
C17—C16—Co170.1 (6)C32—C31—Co270.2 (6)
C15—C16—Co172.0 (7)C30—C31—Co267.8 (7)
C17—C16—H16A125.9C32—C31—H31A126.7
C15—C16—H16A125.9C30—C31—H31A126.7
Co1—C16—H16A125.9Co2—C31—H31A126.7
C18—C17—C16108.1 (11)C31—C32—C33106.6 (11)
C18—C17—Co170.0 (7)C31—C32—Co269.6 (7)
C16—C17—Co169.4 (6)C33—C32—Co269.4 (7)
C18—C17—H17A126.0C31—C32—H32A126.7
C16—C17—H17A126.0C33—C32—H32A126.7
Co1—C17—H17A126.0Co2—C32—H32A126.7
C17—C18—C19109.8 (12)C34—C33—C32111.2 (13)
C17—C18—Co170.3 (7)C34—C33—Co270.3 (8)
C19—C18—Co170.6 (7)C32—C33—Co270.2 (7)
C17—C18—H18A125.1C34—C33—H33A124.3
C19—C18—H18A125.1C32—C33—H33A124.3
Co1—C18—H18A125.1Co2—C33—H33A124.3
C18—C19—C15106.8 (11)C33—C34—C30108.3 (12)
C18—C19—Co169.0 (7)C33—C34—Co270.7 (8)
C15—C19—Co171.2 (7)C30—C34—Co269.0 (7)
C18—C19—H19A126.6C33—C34—H34A125.9
C15—C19—H19A126.6C30—C34—H34A125.9
Co1—C19—H19A126.6Co2—C34—H34A125.9
C24—C20—C21107.4 (10)
C1—Ru1—Si1—Cl411.3 (4)
 

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