Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802019153/na6174sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802019153/na6174Isup2.hkl |
CCDC reference: 200741
Data collection: COLLECT (Nonius, 1997-2001); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXTL (Sheldrick, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
[Co(C5H5)2]2[RuCl3(C12H10ClSi)(CO)2] | F(000) = 1720 |
Mr = 859.40 | Dx = 1.679 Mg m−3 |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 3060 reflections |
a = 9.7462 (5) Å | θ = 2.6–25.0° |
b = 10.2277 (6) Å | µ = 1.78 mm−1 |
c = 34.099 (2) Å | T = 150 K |
V = 3399.0 (3) Å3 | Plate, dark orange |
Z = 4 | 0.20 × 0.20 × 0.02 mm |
Nonius KappaCCD diffractometer | 5652 independent reflections |
Radiation source: fine-focus sealed tube | 3558 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.109 |
Detector resolution: 9 pixels mm-1 | θmax = 25.0°, θmin = 2.7° |
φ scans and ω scans with κ offsets | h = −11→11 |
Absorption correction: multi-scan (DENZO-SMN; Otwinowski & Minor, 1997) | k = −12→12 |
Tmin = 0.717, Tmax = 0.965 | l = −37→36 |
12795 measured reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.064 | H-atom parameters constrained |
wR(F2) = 0.128 | w = 1/[σ2(Fo2) + (0.0371P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.01 | (Δ/σ)max = 0.001 |
5652 reflections | Δρmax = 0.84 e Å−3 |
397 parameters | Δρmin = −0.54 e Å−3 |
0 restraints | Absolute structure: (Flack, 1983), 2319 Friedel pairs |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: 0.03 (3) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Ru1 | 0.76741 (8) | 0.48626 (7) | 0.34656 (2) | 0.0406 (2) | |
Cl1 | 0.7378 (3) | 0.4406 (2) | 0.27306 (6) | 0.0507 (7) | |
Cl2 | 0.9653 (3) | 0.6236 (2) | 0.32940 (7) | 0.0482 (7) | |
Cl3 | 0.6065 (3) | 0.6703 (2) | 0.33936 (8) | 0.0490 (7) | |
Cl4 | 0.6548 (3) | 0.4860 (3) | 0.45106 (7) | 0.0643 (8) | |
Si1 | 0.8154 (3) | 0.5437 (3) | 0.41222 (8) | 0.0445 (8) | |
O1 | 0.5304 (8) | 0.3205 (8) | 0.3724 (2) | 0.067 (3) | |
O2 | 0.9436 (8) | 0.2481 (7) | 0.3578 (2) | 0.065 (2) | |
C1 | 0.6202 (13) | 0.3830 (12) | 0.3629 (3) | 0.053 (3) | |
C2 | 0.8796 (11) | 0.3401 (11) | 0.3527 (3) | 0.045 (3) | |
C3 | 0.9706 (12) | 0.4584 (10) | 0.4331 (3) | 0.053 (3) | |
C4 | 0.9636 (15) | 0.3622 (11) | 0.4626 (3) | 0.071 (4) | |
H4A | 0.8769 | 0.3409 | 0.4737 | 0.085* | |
C5 | 1.0822 (17) | 0.2964 (12) | 0.4764 (4) | 0.078 (4) | |
H5A | 1.0754 | 0.2312 | 0.4962 | 0.093* | |
C6 | 1.2088 (18) | 0.3294 (12) | 0.4602 (4) | 0.082 (5) | |
H6A | 1.2897 | 0.2878 | 0.4696 | 0.098* | |
C7 | 1.2183 (13) | 0.4227 (11) | 0.4305 (3) | 0.067 (3) | |
H7A | 1.3048 | 0.4443 | 0.4195 | 0.080* | |
C8 | 1.0989 (12) | 0.4843 (11) | 0.4172 (3) | 0.060 (3) | |
H8A | 1.1058 | 0.5459 | 0.3964 | 0.072* | |
C9 | 0.8385 (10) | 0.7215 (9) | 0.4271 (3) | 0.041 (3) | |
C10 | 0.8681 (14) | 0.7513 (11) | 0.4654 (3) | 0.072 (4) | |
H10A | 0.8818 | 0.6814 | 0.4833 | 0.086* | |
C11 | 0.8784 (16) | 0.8725 (12) | 0.4786 (3) | 0.085 (5) | |
H11A | 0.8936 | 0.8878 | 0.5058 | 0.102* | |
C12 | 0.8668 (12) | 0.9786 (11) | 0.4528 (4) | 0.071 (4) | |
H12A | 0.8770 | 1.0655 | 0.4621 | 0.085* | |
C13 | 0.8411 (11) | 0.9562 (10) | 0.4143 (3) | 0.056 (3) | |
H13A | 0.8302 | 1.0269 | 0.3966 | 0.067* | |
C14 | 0.8308 (10) | 0.8255 (11) | 0.4012 (3) | 0.048 (3) | |
H14A | 0.8183 | 0.8087 | 0.3740 | 0.058* | |
Co1 | 0.23943 (15) | 0.44754 (11) | 0.24875 (4) | 0.0417 (4) | |
C15 | 0.3981 (16) | 0.3249 (14) | 0.2643 (3) | 0.076 (4) | |
H15A | 0.4816 | 0.3051 | 0.2484 | 0.091* | |
C16 | 0.3816 (14) | 0.4297 (12) | 0.2907 (3) | 0.065 (3) | |
H16A | 0.4530 | 0.4961 | 0.2975 | 0.078* | |
C17 | 0.2514 (15) | 0.4211 (11) | 0.3070 (3) | 0.062 (3) | |
H17A | 0.2126 | 0.4805 | 0.3275 | 0.074* | |
C18 | 0.1854 (14) | 0.3182 (14) | 0.2901 (4) | 0.074 (4) | |
H18A | 0.0892 | 0.2906 | 0.2960 | 0.089* | |
C19 | 0.2716 (17) | 0.2578 (11) | 0.2630 (3) | 0.065 (4) | |
H19A | 0.2494 | 0.1798 | 0.2464 | 0.079* | |
C20 | 0.2555 (11) | 0.4925 (9) | 0.1914 (3) | 0.049 (3) | |
H20A | 0.3223 | 0.4541 | 0.1723 | 0.059* | |
C21 | 0.2756 (13) | 0.6051 (10) | 0.2143 (3) | 0.054 (3) | |
H21A | 0.3604 | 0.6601 | 0.2147 | 0.065* | |
C22 | 0.1573 (12) | 0.6259 (10) | 0.2372 (3) | 0.049 (3) | |
H22A | 0.1433 | 0.6982 | 0.2565 | 0.058* | |
C23 | 0.0628 (11) | 0.5258 (10) | 0.2282 (3) | 0.049 (3) | |
H23A | −0.0307 | 0.5146 | 0.2398 | 0.058* | |
C24 | 0.1243 (11) | 0.4445 (11) | 0.1999 (3) | 0.053 (3) | |
H24A | 0.0816 | 0.3649 | 0.1881 | 0.063* | |
Co2 | 0.68687 (14) | 0.43589 (13) | 0.11062 (4) | 0.0463 (4) | |
C25 | 0.639 (2) | 0.2732 (14) | 0.0810 (4) | 0.090 (5) | |
H25A | 0.6280 | 0.1837 | 0.0925 | 0.108* | |
C26 | 0.7599 (16) | 0.3266 (14) | 0.0659 (3) | 0.080 (4) | |
H26A | 0.8516 | 0.2830 | 0.0645 | 0.096* | |
C27 | 0.7272 (17) | 0.4549 (14) | 0.0524 (3) | 0.074 (4) | |
H27A | 0.7918 | 0.5187 | 0.0401 | 0.088* | |
C28 | 0.5907 (17) | 0.4742 (15) | 0.0597 (4) | 0.080 (4) | |
H28A | 0.5399 | 0.5569 | 0.0539 | 0.096* | |
C29 | 0.5339 (15) | 0.3665 (19) | 0.0766 (4) | 0.084 (5) | |
H29A | 0.4357 | 0.3558 | 0.0845 | 0.101* | |
C30 | 0.7802 (16) | 0.3932 (13) | 0.1612 (3) | 0.078 (4) | |
H30A | 0.8282 | 0.3096 | 0.1677 | 0.094* | |
C31 | 0.8419 (12) | 0.5088 (15) | 0.1435 (3) | 0.070 (4) | |
H31A | 0.9398 | 0.5194 | 0.1353 | 0.083* | |
C32 | 0.7377 (17) | 0.6016 (12) | 0.1401 (3) | 0.077 (4) | |
H32A | 0.7462 | 0.6915 | 0.1288 | 0.092* | |
C33 | 0.6194 (14) | 0.5451 (14) | 0.1561 (4) | 0.077 (4) | |
H33A | 0.5278 | 0.5889 | 0.1571 | 0.093* | |
C34 | 0.6436 (13) | 0.4221 (14) | 0.1683 (3) | 0.065 (4) | |
H34A | 0.5748 | 0.3619 | 0.1804 | 0.078* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ru1 | 0.0454 (5) | 0.0299 (4) | 0.0465 (5) | 0.0018 (4) | 0.0005 (4) | 0.0016 (4) |
Cl1 | 0.0658 (19) | 0.0370 (14) | 0.0494 (15) | 0.0010 (17) | 0.0028 (14) | −0.0035 (11) |
Cl2 | 0.0481 (17) | 0.0347 (15) | 0.0618 (18) | −0.0030 (13) | 0.0038 (14) | 0.0021 (13) |
Cl3 | 0.0521 (17) | 0.0340 (15) | 0.0609 (19) | 0.0088 (13) | −0.0033 (15) | −0.0015 (14) |
Cl4 | 0.078 (2) | 0.062 (2) | 0.0526 (17) | −0.0130 (18) | 0.0139 (15) | 0.0029 (15) |
Si1 | 0.0557 (19) | 0.0346 (18) | 0.0432 (18) | −0.0024 (16) | −0.0025 (14) | 0.0023 (13) |
O1 | 0.059 (6) | 0.056 (6) | 0.086 (6) | −0.019 (5) | −0.006 (5) | −0.002 (4) |
O2 | 0.067 (6) | 0.040 (5) | 0.087 (6) | 0.021 (4) | 0.000 (5) | 0.004 (4) |
C1 | 0.052 (8) | 0.052 (8) | 0.056 (8) | 0.010 (7) | −0.016 (6) | −0.011 (6) |
C2 | 0.050 (7) | 0.044 (8) | 0.040 (6) | −0.017 (6) | 0.009 (5) | −0.003 (6) |
C3 | 0.060 (8) | 0.034 (7) | 0.065 (8) | 0.011 (6) | −0.013 (6) | 0.001 (6) |
C4 | 0.102 (11) | 0.040 (8) | 0.069 (9) | 0.015 (8) | −0.013 (8) | 0.000 (7) |
C5 | 0.115 (13) | 0.050 (9) | 0.068 (10) | 0.007 (10) | −0.007 (9) | 0.019 (7) |
C6 | 0.124 (14) | 0.046 (8) | 0.076 (10) | 0.022 (9) | −0.052 (10) | −0.005 (7) |
C7 | 0.057 (9) | 0.061 (8) | 0.082 (9) | −0.001 (8) | −0.016 (7) | −0.004 (7) |
C8 | 0.047 (7) | 0.054 (8) | 0.080 (8) | 0.011 (7) | −0.014 (6) | 0.011 (7) |
C9 | 0.048 (7) | 0.036 (7) | 0.040 (7) | −0.006 (5) | 0.008 (5) | 0.001 (5) |
C10 | 0.139 (13) | 0.031 (7) | 0.044 (7) | 0.002 (7) | −0.013 (8) | 0.007 (6) |
C11 | 0.166 (15) | 0.037 (8) | 0.051 (8) | −0.023 (9) | −0.014 (8) | −0.006 (6) |
C12 | 0.104 (10) | 0.038 (7) | 0.069 (9) | −0.005 (7) | 0.014 (7) | −0.016 (7) |
C13 | 0.076 (8) | 0.036 (7) | 0.056 (8) | −0.002 (6) | 0.007 (6) | −0.012 (6) |
C14 | 0.048 (7) | 0.061 (8) | 0.037 (6) | 0.007 (6) | 0.002 (5) | 0.001 (6) |
Co1 | 0.0433 (9) | 0.0321 (7) | 0.0498 (8) | −0.0007 (8) | −0.0021 (8) | −0.0014 (6) |
C15 | 0.088 (11) | 0.077 (10) | 0.063 (9) | 0.052 (9) | 0.011 (8) | 0.002 (8) |
C16 | 0.066 (9) | 0.057 (9) | 0.071 (9) | 0.001 (7) | −0.034 (7) | −0.003 (7) |
C17 | 0.067 (9) | 0.061 (8) | 0.056 (7) | 0.023 (9) | 0.000 (7) | 0.005 (6) |
C18 | 0.059 (9) | 0.079 (10) | 0.084 (10) | −0.027 (8) | −0.008 (8) | 0.025 (8) |
C19 | 0.098 (12) | 0.040 (7) | 0.059 (8) | −0.003 (9) | −0.007 (8) | 0.008 (6) |
C20 | 0.053 (7) | 0.040 (6) | 0.055 (6) | 0.014 (7) | 0.005 (6) | −0.001 (5) |
C21 | 0.073 (9) | 0.042 (7) | 0.047 (7) | −0.004 (7) | 0.014 (7) | 0.007 (5) |
C22 | 0.070 (9) | 0.023 (6) | 0.053 (7) | 0.001 (6) | 0.002 (6) | 0.004 (5) |
C23 | 0.047 (7) | 0.039 (7) | 0.060 (7) | 0.007 (6) | 0.003 (5) | 0.007 (6) |
C24 | 0.055 (8) | 0.053 (8) | 0.051 (7) | 0.003 (6) | −0.010 (6) | −0.007 (6) |
Co2 | 0.0467 (9) | 0.0427 (9) | 0.0496 (9) | −0.0025 (7) | 0.0008 (7) | 0.0001 (7) |
C25 | 0.135 (15) | 0.061 (10) | 0.076 (10) | −0.036 (11) | 0.014 (10) | −0.030 (8) |
C26 | 0.085 (11) | 0.067 (9) | 0.087 (9) | −0.001 (10) | 0.024 (9) | −0.022 (7) |
C27 | 0.084 (11) | 0.088 (11) | 0.049 (7) | −0.049 (10) | −0.017 (7) | 0.000 (6) |
C28 | 0.084 (11) | 0.084 (12) | 0.071 (9) | −0.016 (10) | −0.044 (8) | 0.010 (8) |
C29 | 0.066 (10) | 0.135 (15) | 0.052 (9) | −0.026 (12) | −0.007 (7) | −0.027 (10) |
C30 | 0.105 (12) | 0.063 (9) | 0.068 (9) | 0.028 (9) | −0.023 (9) | 0.008 (7) |
C31 | 0.046 (7) | 0.098 (12) | 0.065 (8) | 0.003 (9) | −0.014 (6) | 0.007 (8) |
C32 | 0.109 (12) | 0.048 (7) | 0.074 (8) | −0.021 (10) | −0.005 (10) | 0.005 (6) |
C33 | 0.079 (10) | 0.064 (9) | 0.089 (10) | −0.007 (8) | 0.008 (8) | 0.003 (9) |
C34 | 0.069 (10) | 0.059 (9) | 0.066 (9) | −0.023 (8) | 0.007 (7) | 0.010 (7) |
Ru1—C2 | 1.864 (12) | C16—H16A | 1.0000 |
Ru1—C1 | 1.867 (14) | C17—C18 | 1.362 (15) |
Ru1—Si1 | 2.362 (3) | C17—H17A | 1.0000 |
Ru1—Cl2 | 2.456 (3) | C18—C19 | 1.395 (16) |
Ru1—Cl3 | 2.462 (3) | C18—H18A | 1.0000 |
Ru1—Cl1 | 2.566 (2) | C19—H19A | 1.0000 |
Cl4—Si1 | 2.134 (4) | C20—C24 | 1.400 (13) |
Si1—C3 | 1.886 (11) | C20—C21 | 1.405 (12) |
Si1—C9 | 1.901 (10) | C20—H20A | 1.0000 |
O1—C1 | 1.131 (12) | C21—C22 | 1.408 (14) |
O2—C2 | 1.143 (11) | C21—H21A | 1.0000 |
C3—C8 | 1.389 (14) | C22—C23 | 1.411 (13) |
C3—C4 | 1.409 (13) | C22—H22A | 1.0000 |
C4—C5 | 1.417 (16) | C23—C24 | 1.408 (13) |
C4—H4A | 0.9500 | C23—H23A | 1.0000 |
C5—C6 | 1.393 (18) | C24—H24A | 1.0000 |
C5—H5A | 0.9500 | Co2—C30 | 1.997 (11) |
C6—C7 | 1.395 (15) | Co2—C25 | 2.002 (12) |
C6—H6A | 0.9500 | Co2—C28 | 2.011 (11) |
C7—C8 | 1.399 (14) | Co2—C34 | 2.017 (11) |
C7—H7A | 0.9500 | Co2—C29 | 2.017 (12) |
C8—H8A | 0.9500 | Co2—C26 | 2.021 (11) |
C9—C10 | 1.373 (13) | Co2—C33 | 2.021 (13) |
C9—C14 | 1.384 (12) | Co2—C31 | 2.024 (11) |
C10—C11 | 1.323 (14) | Co2—C27 | 2.032 (11) |
C10—H10A | 0.9500 | Co2—C32 | 2.032 (11) |
C11—C12 | 1.403 (15) | C25—C26 | 1.402 (18) |
C11—H11A | 0.9500 | C25—C29 | 1.405 (19) |
C12—C13 | 1.353 (13) | C25—H25A | 1.0000 |
C12—H12A | 0.9500 | C26—C27 | 1.425 (16) |
C13—C14 | 1.413 (13) | C26—H26A | 1.0000 |
C13—H13A | 0.9500 | C27—C28 | 1.367 (18) |
C14—H14A | 0.9500 | C27—H27A | 1.0000 |
Co1—C16 | 2.001 (11) | C28—C29 | 1.361 (17) |
Co1—C18 | 2.004 (12) | C28—H28A | 1.0000 |
Co1—C24 | 2.007 (10) | C29—H29A | 1.0000 |
Co1—C17 | 2.009 (10) | C30—C34 | 1.386 (16) |
Co1—C20 | 2.015 (9) | C30—C31 | 1.456 (16) |
Co1—C23 | 2.024 (10) | C30—H30A | 1.0000 |
Co1—C21 | 2.025 (10) | C31—C32 | 1.395 (15) |
Co1—C19 | 2.025 (11) | C31—H31A | 1.0000 |
Co1—C22 | 2.031 (10) | C32—C33 | 1.400 (16) |
Co1—C15 | 2.061 (12) | C32—H32A | 1.0000 |
C15—C16 | 1.409 (15) | C33—C34 | 1.346 (16) |
C15—C19 | 1.411 (17) | C33—H33A | 1.0000 |
C15—H15A | 1.0000 | C34—H34A | 1.0000 |
C16—C17 | 1.389 (15) | ||
C2—Ru1—C1 | 87.9 (4) | C24—C20—Co1 | 69.3 (6) |
C2—Ru1—Si1 | 88.7 (3) | C21—C20—Co1 | 70.0 (5) |
C1—Ru1—Si1 | 90.5 (3) | C24—C20—H20A | 126.3 |
C2—Ru1—Cl2 | 91.4 (3) | C21—C20—H20A | 126.3 |
C1—Ru1—Cl2 | 176.4 (3) | Co1—C20—H20A | 126.3 |
Si1—Ru1—Cl2 | 85.88 (10) | C20—C21—C22 | 108.5 (10) |
C2—Ru1—Cl3 | 176.4 (3) | C20—C21—Co1 | 69.3 (5) |
C1—Ru1—Cl3 | 88.4 (4) | C22—C21—Co1 | 69.9 (6) |
Si1—Ru1—Cl3 | 91.75 (10) | C20—C21—H21A | 125.7 |
Cl2—Ru1—Cl3 | 92.24 (9) | C22—C21—H21A | 125.7 |
C2—Ru1—Cl1 | 91.7 (3) | Co1—C21—H21A | 125.7 |
C1—Ru1—Cl1 | 95.9 (3) | C21—C22—C23 | 107.8 (9) |
Si1—Ru1—Cl1 | 173.57 (10) | C21—C22—Co1 | 69.4 (6) |
Cl2—Ru1—Cl1 | 87.69 (8) | C23—C22—Co1 | 69.4 (5) |
Cl3—Ru1—Cl1 | 88.29 (9) | C21—C22—H22A | 126.1 |
C3—Si1—C9 | 104.3 (5) | C23—C22—H22A | 126.1 |
C3—Si1—Cl4 | 103.1 (4) | Co1—C22—H22A | 126.1 |
C9—Si1—Cl4 | 100.7 (3) | C24—C23—C22 | 107.4 (9) |
C3—Si1—Ru1 | 113.7 (3) | C24—C23—Co1 | 68.9 (6) |
C9—Si1—Ru1 | 120.9 (3) | C22—C23—Co1 | 69.9 (6) |
Cl4—Si1—Ru1 | 111.99 (15) | C24—C23—H23A | 126.3 |
O1—C1—Ru1 | 179.2 (10) | C22—C23—H23A | 126.3 |
O2—C2—Ru1 | 176.5 (10) | Co1—C23—H23A | 126.3 |
C8—C3—C4 | 117.2 (11) | C20—C24—C23 | 108.9 (10) |
C8—C3—Si1 | 119.1 (8) | C20—C24—Co1 | 69.9 (6) |
C4—C3—Si1 | 123.6 (10) | C23—C24—Co1 | 70.2 (6) |
C3—C4—C5 | 121.9 (13) | C20—C24—H24A | 125.5 |
C3—C4—H4A | 119.1 | C23—C24—H24A | 125.5 |
C5—C4—H4A | 119.1 | Co1—C24—H24A | 125.5 |
C6—C5—C4 | 118.5 (12) | C30—Co2—C25 | 111.1 (6) |
C6—C5—H5A | 120.8 | C30—Co2—C28 | 178.5 (6) |
C4—C5—H5A | 120.8 | C25—Co2—C28 | 67.5 (6) |
C5—C6—C7 | 120.7 (13) | C30—Co2—C34 | 40.4 (5) |
C5—C6—H6A | 119.6 | C25—Co2—C34 | 112.6 (6) |
C7—C6—H6A | 119.6 | C28—Co2—C34 | 139.3 (7) |
C6—C7—C8 | 119.3 (13) | C30—Co2—C29 | 139.1 (7) |
C6—C7—H7A | 120.3 | C25—Co2—C29 | 40.9 (5) |
C8—C7—H7A | 120.3 | C28—Co2—C29 | 39.5 (5) |
C3—C8—C7 | 122.3 (11) | C34—Co2—C29 | 112.4 (5) |
C3—C8—H8A | 118.8 | C30—Co2—C26 | 111.7 (6) |
C7—C8—H8A | 118.8 | C25—Co2—C26 | 40.8 (5) |
C10—C9—C14 | 116.6 (9) | C28—Co2—C26 | 67.7 (6) |
C10—C9—Si1 | 119.4 (8) | C34—Co2—C26 | 140.5 (6) |
C14—C9—Si1 | 124.0 (8) | C29—Co2—C26 | 68.4 (6) |
C11—C10—C9 | 123.3 (10) | C30—Co2—C33 | 66.8 (5) |
C11—C10—H10A | 118.4 | C25—Co2—C33 | 140.3 (6) |
C9—C10—H10A | 118.4 | C28—Co2—C33 | 113.8 (6) |
C10—C11—C12 | 120.3 (11) | C34—Co2—C33 | 38.9 (5) |
C10—C11—H11A | 119.9 | C29—Co2—C33 | 113.3 (6) |
C12—C11—H11A | 119.9 | C26—Co2—C33 | 178.3 (6) |
C13—C12—C11 | 119.5 (10) | C30—Co2—C31 | 42.5 (5) |
C13—C12—H12A | 120.2 | C25—Co2—C31 | 139.5 (7) |
C11—C12—H12A | 120.2 | C28—Co2—C31 | 139.0 (6) |
C12—C13—C14 | 118.7 (10) | C34—Co2—C31 | 69.0 (5) |
C12—C13—H13A | 120.6 | C29—Co2—C31 | 178.4 (6) |
C14—C13—H13A | 120.6 | C26—Co2—C31 | 111.0 (6) |
C9—C14—C13 | 121.4 (10) | C33—Co2—C31 | 67.3 (5) |
C9—C14—H14A | 119.3 | C30—Co2—C27 | 140.8 (6) |
C13—C14—H14A | 119.3 | C25—Co2—C27 | 68.5 (5) |
C16—Co1—C18 | 67.6 (5) | C28—Co2—C27 | 39.5 (5) |
C16—Co1—C24 | 168.2 (5) | C34—Co2—C27 | 178.3 (7) |
C18—Co1—C24 | 115.2 (5) | C29—Co2—C27 | 67.4 (5) |
C16—Co1—C17 | 40.5 (4) | C26—Co2—C27 | 41.2 (5) |
C18—Co1—C17 | 39.7 (4) | C33—Co2—C27 | 139.4 (6) |
C24—Co1—C17 | 148.3 (5) | C31—Co2—C27 | 111.2 (5) |
C16—Co1—C20 | 131.4 (5) | C30—Co2—C32 | 69.2 (5) |
C18—Co1—C20 | 148.6 (5) | C25—Co2—C32 | 179.3 (6) |
C24—Co1—C20 | 40.8 (4) | C28—Co2—C32 | 112.2 (6) |
C17—Co1—C20 | 170.5 (5) | C34—Co2—C32 | 68.1 (5) |
C16—Co1—C23 | 150.8 (5) | C29—Co2—C32 | 139.3 (7) |
C18—Co1—C23 | 106.3 (5) | C26—Co2—C32 | 138.5 (6) |
C24—Co1—C23 | 40.9 (4) | C33—Co2—C32 | 40.4 (4) |
C17—Co1—C23 | 116.4 (5) | C31—Co2—C32 | 40.2 (5) |
C20—Co1—C23 | 68.9 (4) | C27—Co2—C32 | 110.9 (5) |
C16—Co1—C21 | 111.5 (5) | C26—C25—C29 | 107.9 (13) |
C18—Co1—C21 | 168.3 (6) | C26—C25—Co2 | 70.3 (7) |
C24—Co1—C21 | 68.2 (4) | C29—C25—Co2 | 70.1 (7) |
C17—Co1—C21 | 132.1 (5) | C26—C25—H25A | 126.0 |
C20—Co1—C21 | 40.7 (4) | C29—C25—H25A | 126.0 |
C23—Co1—C21 | 68.5 (4) | Co2—C25—H25A | 126.0 |
C16—Co1—C19 | 68.5 (5) | C25—C26—C27 | 106.8 (14) |
C18—Co1—C19 | 40.5 (5) | C25—C26—Co2 | 68.9 (7) |
C24—Co1—C19 | 105.7 (5) | C27—C26—Co2 | 69.8 (7) |
C17—Co1—C19 | 68.0 (4) | C25—C26—H26A | 126.6 |
C20—Co1—C19 | 116.0 (4) | C27—C26—H26A | 126.6 |
C23—Co1—C19 | 126.4 (5) | Co2—C26—H26A | 126.6 |
C21—Co1—C19 | 151.0 (5) | C28—C27—C26 | 107.0 (13) |
C16—Co1—C22 | 119.6 (5) | C28—C27—Co2 | 69.4 (7) |
C18—Co1—C22 | 128.8 (5) | C26—C27—Co2 | 69.0 (7) |
C24—Co1—C22 | 68.4 (4) | C28—C27—H27A | 126.5 |
C17—Co1—C22 | 109.6 (4) | C26—C27—H27A | 126.5 |
C20—Co1—C22 | 68.7 (4) | Co2—C27—H27A | 126.5 |
C23—Co1—C22 | 40.7 (4) | C29—C28—C27 | 110.8 (14) |
C21—Co1—C22 | 40.6 (4) | C29—C28—Co2 | 70.5 (7) |
C19—Co1—C22 | 165.6 (6) | C27—C28—Co2 | 71.1 (7) |
C16—Co1—C15 | 40.6 (4) | C29—C28—H28A | 124.6 |
C18—Co1—C15 | 67.3 (5) | C27—C28—H28A | 124.6 |
C24—Co1—C15 | 128.6 (5) | Co2—C28—H28A | 124.6 |
C17—Co1—C15 | 67.7 (4) | C28—C29—C25 | 107.5 (13) |
C20—Co1—C15 | 109.3 (4) | C28—C29—Co2 | 70.0 (7) |
C23—Co1—C15 | 165.5 (6) | C25—C29—Co2 | 69.0 (8) |
C21—Co1—C15 | 120.2 (5) | C28—C29—H29A | 126.3 |
C19—Co1—C15 | 40.4 (5) | C25—C29—H29A | 126.3 |
C22—Co1—C15 | 153.2 (6) | Co2—C29—H29A | 126.3 |
C16—C15—C19 | 107.0 (11) | C34—C30—C31 | 107.2 (11) |
C16—C15—Co1 | 67.4 (7) | C34—C30—Co2 | 70.6 (7) |
C19—C15—Co1 | 68.4 (7) | C31—C30—Co2 | 69.8 (6) |
C16—C15—H15A | 126.5 | C34—C30—H30A | 126.4 |
C19—C15—H15A | 126.5 | C31—C30—H30A | 126.4 |
Co1—C15—H15A | 126.5 | Co2—C30—H30A | 126.4 |
C17—C16—C15 | 108.2 (12) | C32—C31—C30 | 106.6 (10) |
C17—C16—Co1 | 70.1 (6) | C32—C31—Co2 | 70.2 (6) |
C15—C16—Co1 | 72.0 (7) | C30—C31—Co2 | 67.8 (7) |
C17—C16—H16A | 125.9 | C32—C31—H31A | 126.7 |
C15—C16—H16A | 125.9 | C30—C31—H31A | 126.7 |
Co1—C16—H16A | 125.9 | Co2—C31—H31A | 126.7 |
C18—C17—C16 | 108.1 (11) | C31—C32—C33 | 106.6 (11) |
C18—C17—Co1 | 70.0 (7) | C31—C32—Co2 | 69.6 (7) |
C16—C17—Co1 | 69.4 (6) | C33—C32—Co2 | 69.4 (7) |
C18—C17—H17A | 126.0 | C31—C32—H32A | 126.7 |
C16—C17—H17A | 126.0 | C33—C32—H32A | 126.7 |
Co1—C17—H17A | 126.0 | Co2—C32—H32A | 126.7 |
C17—C18—C19 | 109.8 (12) | C34—C33—C32 | 111.2 (13) |
C17—C18—Co1 | 70.3 (7) | C34—C33—Co2 | 70.3 (8) |
C19—C18—Co1 | 70.6 (7) | C32—C33—Co2 | 70.2 (7) |
C17—C18—H18A | 125.1 | C34—C33—H33A | 124.3 |
C19—C18—H18A | 125.1 | C32—C33—H33A | 124.3 |
Co1—C18—H18A | 125.1 | Co2—C33—H33A | 124.3 |
C18—C19—C15 | 106.8 (11) | C33—C34—C30 | 108.3 (12) |
C18—C19—Co1 | 69.0 (7) | C33—C34—Co2 | 70.7 (8) |
C15—C19—Co1 | 71.2 (7) | C30—C34—Co2 | 69.0 (7) |
C18—C19—H19A | 126.6 | C33—C34—H34A | 125.9 |
C15—C19—H19A | 126.6 | C30—C34—H34A | 125.9 |
Co1—C19—H19A | 126.6 | Co2—C34—H34A | 125.9 |
C24—C20—C21 | 107.4 (10) | ||
C1—Ru1—Si1—Cl4 | −11.3 (4) |